#------------------------------------------------------------------------------
#$Date: 2016-03-26 17:15:34 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180419 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/88/7208807.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208807
loop_
_publ_author_name
'Sun, Di'
'Liu, Fu-Jing'
'Huang, Rong-Bin'
'Zheng, Lan-Sun'
_publ_section_title
;
 Three guest-dependent nitrate--water aggregations encapsulated in
 silver(i)--bipyridine supramolecular frameworks
;
_journal_issue                   23
_journal_name_full               CrystEngComm
_journal_page_first              7872
_journal_paper_doi               10.1039/c2ce26161h
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety
'C10 H8 Ag N3 O3, 3(C10 H8 Ag N2), C7 H6 N2, 3(N O3), 6(H2 O)'
_chemical_formula_sum            'C47 H50 Ag4 N14 O18'
_chemical_formula_weight         1530.49
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.019(4)
_cell_angle_beta                 100.171(4)
_cell_angle_gamma                102.572(3)
_cell_formula_units_Z            2
_cell_length_a                   11.328(2)
_cell_length_b                   13.975(3)
_cell_length_c                   18.270(3)
_cell_measurement_temperature    173(2)
_cell_volume                     2625.6(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0315
_diffrn_reflns_av_sigmaI/netI    0.0715
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13452
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.20
_exptl_absorpt_coefficient_mu    1.559
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5743
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.936
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1524
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.292
_refine_diff_density_min         -1.100
_refine_diff_density_rms         0.136
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.169
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     757
_refine_ls_number_reflns         9130
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.169
_refine_ls_R_factor_all          0.0828
_refine_ls_R_factor_gt           0.0661
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0365P)²+2.4051P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1228
_refine_ls_wR_factor_ref         0.1308
_reflns_number_gt                7503
_reflns_number_total             9130
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce26161h.txt
_cod_data_source_block           p1
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               7208807
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.21873(5) 0.62122(4) 0.47141(3) 0.02370(16) Uani 1 1 d .
Ag2 Ag 1.25532(5) 0.86248(4) 0.49018(3) 0.02195(16) Uani 1 1 d .
Ag3 Ag 0.26087(5) 0.62977(5) 0.99269(4) 0.02585(16) Uani 1 1 d .
Ag4 Ag 0.30673(5) 0.87270(4) 1.02031(3) 0.02367(16) Uani 1 1 d .
C1 C 0.9952(7) 0.6520(5) 0.5367(4) 0.0213(17) Uani 1 1 d .
H1 H 1.0599 0.6882 0.5835 0.026 Uiso 1 1 calc R
C2 C 0.8757(6) 0.6521(6) 0.5390(4) 0.0187(16) Uani 1 1 d .
H2 H 0.8592 0.6874 0.5869 0.022 Uiso 1 1 calc R
C3 C 0.7775(6) 0.6009(5) 0.4719(4) 0.0156(15) Uani 1 1 d .
C4 C 0.8093(7) 0.5466(5) 0.4054(4) 0.0195(16) Uani 1 1 d .
H4 H 0.7458 0.5072 0.3586 0.023 Uiso 1 1 calc R
C5 C 0.9317(7) 0.5497(5) 0.4072(4) 0.0202(16) Uani 1 1 d .
H5 H 0.9506 0.5123 0.3609 0.024 Uiso 1 1 calc R
C6 C 0.4903(6) 0.6322(5) 0.5398(4) 0.0183(16) Uani 1 1 d .
H6 H 0.4644 0.6446 0.5874 0.022 Uiso 1 1 calc R
C7 C 0.6089(7) 0.6248(5) 0.5416(4) 0.0197(16) Uani 1 1 d .
H7 H 0.6633 0.6307 0.5896 0.024 Uiso 1 1 calc R
C8 C 0.6506(6) 0.6084(5) 0.4719(4) 0.0147(15) Uani 1 1 d .
C9 C 0.5633(6) 0.5977(5) 0.4036(4) 0.0187(16) Uani 1 1 d .
H9 H 0.5854 0.5847 0.3548 0.022 Uiso 1 1 calc R
C10 C 0.4472(7) 0.6058(6) 0.4069(4) 0.0227(17) Uani 1 1 d .
H10 H 0.3905 0.5990 0.3596 0.027 Uiso 1 1 calc R
C11 C 1.0405(7) 0.9164(5) 0.5536(4) 0.0185(16) Uani 1 1 d .
H11 H 1.1068 0.9511 0.5997 0.022 Uiso 1 1 calc R
C12 C 0.9218(6) 0.9240(5) 0.5567(4) 0.0168(16) Uani 1 1 d .
H12 H 0.9075 0.9629 0.6042 0.020 Uiso 1 1 calc R
C13 C 0.8231(7) 0.8742(5) 0.4895(4) 0.0167(16) Uani 1 1 d .
C14 C 0.8515(6) 0.8173(5) 0.4222(4) 0.0175(16) Uani 1 1 d .
H14 H 0.7868 0.7805 0.3755 0.021 Uiso 1 1 calc R
C15 C 0.9718(6) 0.8142(5) 0.4230(4) 0.0186(16) Uani 1 1 d .
H15 H 0.9890 0.7770 0.3760 0.022 Uiso 1 1 calc R
C16 C 0.5339(7) 0.8968(6) 0.5588(4) 0.0208(17) Uani 1 1 d .
H16 H 0.5098 0.9116 0.6070 0.025 Uiso 1 1 calc R
C17 C 0.6570(7) 0.8994(6) 0.5614(4) 0.0207(17) Uani 1 1 d .
H17 H 0.7161 0.9167 0.6102 0.025 Uiso 1 1 calc R
C18 C 0.6929(7) 0.8761(6) 0.4905(5) 0.0265(19) Uani 1 1 d .
C19 C 0.6040(6) 0.8606(5) 0.4226(4) 0.0162(15) Uani 1 1 d .
H19 H 0.6264 0.8512 0.3739 0.019 Uiso 1 1 calc R
C20 C 0.4830(7) 0.8589(5) 0.4257(4) 0.0209(17) Uani 1 1 d .
H20 H 0.4227 0.8458 0.3782 0.025 Uiso 1 1 calc R
C21 C 0.4753(7) 0.5738(6) 0.9325(4) 0.0215(17) Uani 1 1 d .
H21 H 0.4096 0.5386 0.8861 0.026 Uiso 1 1 calc R
C22 C 0.5952(6) 0.5663(5) 0.9308(4) 0.0192(16) Uani 1 1 d .
H22 H 0.6095 0.5250 0.8842 0.023 Uiso 1 1 calc R
C23 C 0.6940(6) 0.6186(5) 0.9967(4) 0.0142(15) Uani 1 1 d .
C24 C 0.6659(7) 0.6761(5) 1.0633(4) 0.0178(16) Uani 1 1 d .
H24 H 0.7303 0.7129 1.1101 0.021 Uiso 1 1 calc R
C25 C 0.5439(6) 0.6799(5) 1.0615(4) 0.0182(16) Uani 1 1 d .
H25 H 0.5266 0.7198 1.1075 0.022 Uiso 1 1 calc R
C26 C 0.9792(7) 0.5805(6) 0.9276(4) 0.0212(17) Uani 1 1 d .
H26 H 0.9997 0.5545 0.8791 0.025 Uiso 1 1 calc R
C27 C 0.8565(6) 0.5762(5) 0.9260(4) 0.0171(16) Uani 1 1 d .
H27 H 0.7946 0.5474 0.8773 0.021 Uiso 1 1 calc R
C28 C 0.8226(6) 0.6146(5) 0.9966(4) 0.0158(15) Uani 1 1 d .
C29 C 0.9188(6) 0.6521(5) 1.0656(4) 0.0196(16) Uani 1 1 d .
H29 H 0.9010 0.6772 1.1152 0.023 Uiso 1 1 calc R
C30 C 1.0390(7) 0.6526(6) 1.0619(4) 0.0236(17) Uani 1 1 d .
H30 H 1.1023 0.6777 1.1098 0.028 Uiso 1 1 calc R
C31 C 0.5279(6) 0.8383(6) 0.9528(4) 0.0186(16) Uani 1 1 d .
H31 H 0.4624 0.7994 0.9069 0.022 Uiso 1 1 calc R
C32 C 0.6481(7) 0.8384(5) 0.9507(4) 0.0216(17) Uani 1 1 d .
H32 H 0.6641 0.7992 0.9039 0.026 Uiso 1 1 calc R
C33 C 0.7472(6) 0.8955(5) 1.0165(4) 0.0138(15) Uani 1 1 d .
C34 C 0.7157(7) 0.9540(5) 1.0825(4) 0.0187(16) Uani 1 1 d .
H34 H 0.7795 0.9966 1.1283 0.022 Uiso 1 1 calc R
C35 C 0.5922(6) 0.9493(5) 1.0807(4) 0.0196(16) Uani 1 1 d .
H35 H 0.5726 0.9886 1.1260 0.023 Uiso 1 1 calc R
C36 C 1.0334(6) 0.8517(6) 0.9528(4) 0.0213(17) Uani 1 1 d .
H36 H 1.0563 0.8289 0.9047 0.026 Uiso 1 1 calc R
C37 C 0.9128(7) 0.8582(5) 0.9499(4) 0.0181(16) Uani 1 1 d .
H37 H 0.8547 0.8396 0.9004 0.022 Uiso 1 1 calc R
C38 C 0.8769(6) 0.8915(5) 1.0183(4) 0.0177(16) Uani 1 1 d .
C39 C 0.9665(7) 0.9161(5) 1.0891(4) 0.0205(17) Uani 1 1 d .
H39 H 0.9461 0.9394 1.1380 0.025 Uiso 1 1 calc R
C40 C 1.0820(7) 0.9066(5) 1.0871(4) 0.0180(16) Uani 1 1 d .
H40 H 1.1409 0.9223 1.1358 0.022 Uiso 1 1 calc R
C41 C 0.6884(8) 0.7977(6) 0.7457(4) 0.0297(19) Uani 1 1 d .
C42 C 0.8089(9) 0.8495(6) 0.7440(4) 0.033(2) Uani 1 1 d .
H42 H 0.8256 0.9187 0.7429 0.040 Uiso 1 1 calc R
C43 C 0.9030(8) 0.8013(7) 0.7438(4) 0.039(2) Uani 1 1 d .
H43 H 0.9835 0.8379 0.7427 0.046 Uiso 1 1 calc R
C44 C 0.8817(8) 0.6995(7) 0.7452(4) 0.035(2) Uani 1 1 d .
H44 H 0.9471 0.6671 0.7454 0.042 Uiso 1 1 calc R
C45 C 0.7641(7) 0.6470(6) 0.7461(4) 0.0251(18) Uani 1 1 d .
H45 H 0.7476 0.5773 0.7458 0.030 Uiso 1 1 calc R
C46 C 0.6693(7) 0.6962(6) 0.7476(4) 0.0256(18) Uani 1 1 d .
C47 C 0.5476(8) 0.6438(6) 0.7530(4) 0.0241(18) Uani 1 1 d .
N1 N 1.0262(5) 0.6034(5) 0.4715(3) 0.0205(14) Uani 1 1 d .
N2 N 0.4081(5) 0.6226(4) 0.4727(3) 0.0176(13) Uani 1 1 d .
N3 N 1.0664(5) 0.8619(4) 0.4881(3) 0.0188(14) Uani 1 1 d .
N4 N 0.4468(5) 0.8749(4) 0.4927(3) 0.0192(14) Uani 1 1 d .
N5 N 0.4493(5) 0.6285(5) 0.9966(3) 0.0201(14) Uani 1 1 d .
N6 N 1.0720(5) 0.6196(4) 0.9940(4) 0.0201(14) Uani 1 1 d .
N7 N 0.4992(5) 0.8911(4) 1.0171(3) 0.0197(14) Uani 1 1 d .
N8 N 1.1188(5) 0.8761(4) 1.0200(3) 0.0178(13) Uani 1 1 d .
N9 N 0.5967(7) 0.8453(5) 0.7452(4) 0.042(2) Uani 1 1 d .
H9A H 0.5216 0.8124 0.7461 0.051 Uiso 1 1 calc R
H9B H 0.6120 0.9093 0.7439 0.051 Uiso 1 1 calc R
N10 N 0.4524(7) 0.6043(6) 0.7575(4) 0.0371(18) Uani 1 1 d .
N11 N 0.1785(6) 0.1159(5) 0.7533(3) 0.0241(15) Uani 1 1 d .
N12 N 0.6155(6) 0.1351(6) 0.7994(4) 0.0271(16) Uani 1 1 d .
N13 N 0.2133(6) 0.7284(6) 0.8059(4) 0.0336(17) Uani 1 1 d .
N14 N 0.1308(6) 0.6440(5) 0.2934(4) 0.0244(15) Uani 1 1 d .
O1 O 0.1288(5) 0.0206(4) 0.7376(3) 0.0299(13) Uani 1 1 d .
O2 O 0.1164(5) 0.1796(4) 0.7657(3) 0.0304(13) Uani 1 1 d .
O3 O 0.2918(5) 0.1484(4) 0.7568(3) 0.0321(13) Uani 1 1 d .
O4 O 0.6250(5) 0.0598(4) 0.8228(3) 0.0332(14) Uani 1 1 d .
O5 O 0.5519(5) 0.1178(5) 0.7321(3) 0.0413(16) Uani 1 1 d .
O6 O 0.6663(5) 0.2251(4) 0.8436(3) 0.0394(15) Uani 1 1 d .
O7 O 0.2118(6) 0.7144(5) 0.8700(3) 0.0442(16) Uani 1 1 d .
O8 O 0.1816(5) 0.6534(4) 0.7438(3) 0.0384(15) Uani 1 1 d .
O9A O 0.2107(18) 0.8153(18) 0.8003(17) 0.056(5) Uani 0.50 1 d PU
O9B O 0.2792(18) 0.8148(18) 0.8072(17) 0.066(6) Uani 0.50 1 d PU
O10 O 0.2092(5) 0.7219(5) 0.3434(3) 0.0456(17) Uani 1 1 d .
O11 O 0.0551(5) 0.6543(5) 0.2400(3) 0.0440(17) Uani 1 1 d .
O12 O 0.1282(5) 0.5570(5) 0.2983(4) 0.0425(16) Uani 1 1 d .
O1W O 0.1493(5) 0.9051(4) 0.2840(3) 0.0405(15) Uani 1 1 d .
H1WA H 0.0701 0.8852 0.2679 0.049 Uiso 1 1 d R
H1WB H 0.1727 0.8596 0.3009 0.049 Uiso 1 1 d R
O2W O 0.6081(5) 0.3884(4) 0.7740(3) 0.0348(14) Uani 1 1 d .
H2WA H 0.6267 0.3434 0.7935 0.042 Uiso 1 1 d R
H2WB H 0.5299 0.3804 0.7672 0.042 Uiso 1 1 d R
O3W O 0.6533(5) 0.6433(4) 0.2475(3) 0.0297(13) Uani 1 1 d .
H3WA H 0.6741 0.7042 0.2448 0.036 Uiso 1 1 d R
H3WB H 0.7035 0.6110 0.2303 0.036 Uiso 1 1 d R
O4W O 0.8089(5) 0.5224(4) 0.1918(3) 0.0352(14) Uani 1 1 d .
H4WA H 0.8101 0.4723 0.2095 0.042 Uiso 1 1 d R
H4WB H 0.8825 0.5630 0.2058 0.042 Uiso 1 1 d R
O5W O 0.3054(5) 0.7309(4) 0.6382(3) 0.0365(14) Uani 1 1 d .
H5WA H 0.2689 0.7085 0.6695 0.044 Uiso 1 1 d R
H5WB H 0.3132 0.7955 0.6498 0.044 Uiso 1 1 d R
O6W O 0.3320(5) 0.9431(4) 0.6750(3) 0.0337(14) Uani 1 1 d .
H6WA H 0.3978 0.9939 0.6914 0.040 Uiso 1 1 d R
H6WB H 0.2739 0.9639 0.6923 0.040 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N1 173.7(2) 1_655 .
N2 Ag1 Ag2 96.42(15) 1_655 .
N1 Ag1 Ag2 89.72(16) . .
N4 Ag2 N3 175.7(2) 1_655 .
N4 Ag2 Ag1 87.47(16) 1_655 .
N3 Ag2 Ag1 96.78(16) . .
N6 Ag3 N5 174.4(2) 1_455 .
N6 Ag3 Ag4 88.32(15) 1_455 .
N5 Ag3 Ag4 96.32(16) . .
N8 Ag4 N7 171.4(2) 1_455 .
N8 Ag4 Ag3 96.77(15) 1_455 .
N7 Ag4 Ag3 91.37(16) . .
N1 C1 C2 123.3(7) . .
N1 C1 H1 118.4 . .
C2 C1 H1 118.4 . .
C1 C2 C3 120.7(6) . .
C1 C2 H2 119.7 . .
C3 C2 H2 119.7 . .
C2 C3 C4 115.8(6) . .
C2 C3 C8 121.0(6) . .
C4 C3 C8 123.1(6) . .
C5 C4 C3 120.5(6) . .
C5 C4 H4 119.8 . .
C3 C4 H4 119.8 . .
N1 C5 C4 122.9(7) . .
N1 C5 H5 118.5 . .
C4 C5 H5 118.5 . .
N2 C6 C7 122.5(6) . .
N2 C6 H6 118.7 . .
C7 C6 H6 118.7 . .
C6 C7 C8 119.9(6) . .
C6 C7 H7 120.1 . .
C8 C7 H7 120.1 . .
C9 C8 C7 116.1(6) . .
C9 C8 C3 122.6(6) . .
C7 C8 C3 121.2(6) . .
C10 C9 C8 120.3(6) . .
C10 C9 H9 119.9 . .
C8 C9 H9 119.9 . .
N2 C10 C9 123.7(7) . .
N2 C10 H10 118.1 . .
C9 C10 H10 118.1 . .
N3 C11 C12 123.0(6) . .
N3 C11 H11 118.5 . .
C12 C11 H11 118.5 . .
C11 C12 C13 119.4(6) . .
C11 C12 H12 120.3 . .
C13 C12 H12 120.3 . .
C12 C13 C14 116.8(7) . .
C12 C13 C18 121.6(6) . .
C14 C13 C18 121.5(6) . .
C15 C14 C13 120.6(7) . .
C15 C14 H14 119.7 . .
C13 C14 H14 119.7 . .
N3 C15 C14 122.3(6) . .
N3 C15 H15 118.9 . .
C14 C15 H15 118.9 . .
N4 C16 C17 123.8(6) . .
N4 C16 H16 118.1 . .
C17 C16 H16 118.1 . .
C16 C17 C18 118.6(7) . .
C16 C17 H17 120.7 . .
C18 C17 H17 120.7 . .
C19 C18 C17 117.1(7) . .
C19 C18 C13 121.8(7) . .
C17 C18 C13 121.0(7) . .
C20 C19 C18 119.9(7) . .
C20 C19 H19 120.0 . .
C18 C19 H19 120.0 . .
N4 C20 C19 122.7(7) . .
N4 C20 H20 118.6 . .
C19 C20 H20 118.6 . .
N5 C21 C22 122.4(7) . .
N5 C21 H21 118.8 . .
C22 C21 H21 118.8 . .
C23 C22 C21 120.4(7) . .
C23 C22 H22 119.8 . .
C21 C22 H22 119.8 . .
C22 C23 C24 116.7(7) . .
C22 C23 C28 122.0(6) . .
C24 C23 C28 121.3(6) . .
C25 C24 C23 120.2(7) . .
C25 C24 H24 119.9 . .
C23 C24 H24 119.9 . .
N5 C25 C24 122.1(6) . .
N5 C25 H25 119.0 . .
C24 C25 H25 119.0 . .
N6 C26 C27 123.6(7) . .
N6 C26 H26 118.2 . .
C27 C26 H26 118.2 . .
C26 C27 C28 119.8(7) . .
C26 C27 H27 120.1 . .
C28 C27 H27 120.1 . .
C29 C28 C27 116.2(7) . .
C29 C28 C23 122.4(6) . .
C27 C28 C23 121.4(6) . .
C30 C29 C28 120.1(7) . .
C30 C29 H29 120.0 . .
C28 C29 H29 120.0 . .
N6 C30 C29 123.5(7) . .
N6 C30 H30 118.2 . .
C29 C30 H30 118.2 . .
N7 C31 C32 122.5(7) . .
N7 C31 H31 118.8 . .
C32 C31 H31 118.8 . .
C31 C32 C33 120.6(7) . .
C31 C32 H32 119.7 . .
C33 C32 H32 119.7 . .
C32 C33 C34 116.1(6) . .
C32 C33 C38 122.1(6) . .
C34 C33 C38 121.8(6) . .
C35 C34 C33 120.1(7) . .
C35 C34 H34 120.0 . .
C33 C34 H34 120.0 . .
N7 C35 C34 122.1(6) . .
N7 C35 H35 119.0 . .
C34 C35 H35 119.0 . .
N8 C36 C37 122.8(7) . .
N8 C36 H36 118.6 . .
C37 C36 H36 118.6 . .
C38 C37 C36 120.1(7) . .
C38 C37 H37 119.9 . .
C36 C37 H37 119.9 . .
C37 C38 C39 117.1(7) . .
C37 C38 C33 121.0(6) . .
C39 C38 C33 121.8(6) . .
C40 C39 C38 119.3(7) . .
C40 C39 H39 120.3 . .
C38 C39 H39 120.3 . .
C39 C40 N8 123.9(7) . .
C39 C40 H40 118.1 . .
N8 C40 H40 118.1 . .
N9 C41 C46 122.4(8) . .
N9 C41 C42 120.6(8) . .
C46 C41 C42 117.0(8) . .
C43 C42 C41 121.1(8) . .
C43 C42 H42 119.5 . .
C41 C42 H42 119.5 . .
C42 C43 C44 121.0(8) . .
C42 C43 H43 119.5 . .
C44 C43 H43 119.5 . .
C45 C44 C43 119.0(8) . .
C45 C44 H44 120.5 . .
C43 C44 H44 120.5 . .
C44 C45 C46 120.1(8) . .
C44 C45 H45 119.9 . .
C46 C45 H45 119.9 . .
C45 C46 C41 121.8(8) . .
C45 C46 C47 120.6(7) . .
C41 C46 C47 117.6(7) . .
N10 C47 C46 179.0(9) . .
C5 N1 C1 116.7(6) . .
C5 N1 Ag1 123.1(5) . .
C1 N1 Ag1 120.0(5) . .
C10 N2 C6 117.4(6) . .
C10 N2 Ag1 121.5(5) . 1_455
C6 N2 Ag1 120.9(5) . 1_455
C15 N3 C11 117.8(6) . .
C15 N3 Ag2 123.1(5) . .
C11 N3 Ag2 119.0(5) . .
C16 N4 C20 117.5(6) . .
C16 N4 Ag2 122.8(5) . 1_455
C20 N4 Ag2 119.7(5) . 1_455
C21 N5 C25 118.2(6) . .
C21 N5 Ag3 118.8(5) . .
C25 N5 Ag3 123.0(5) . .
C26 N6 C30 116.6(6) . .
C26 N6 Ag3 122.0(5) . 1_655
C30 N6 Ag3 121.3(5) . 1_655
C31 N7 C35 118.6(6) . .
C31 N7 Ag4 120.2(5) . .
C35 N7 Ag4 121.1(5) . .
C36 N8 C40 116.8(6) . .
C36 N8 Ag4 120.8(5) . 1_655
C40 N8 Ag4 122.4(5) . 1_655
C41 N9 H9A 120.0 . .
C41 N9 H9B 120.0 . .
H9A N9 H9B 120.0 . .
O2 N11 O3 118.8(7) . .
O2 N11 O1 121.1(7) . .
O3 N11 O1 120.1(6) . .
O6 N12 O5 120.5(7) . .
O6 N12 O4 120.3(6) . .
O5 N12 O4 119.2(7) . .
O7 N13 O8 120.6(7) . .
O7 N13 O9A 118.7(14) . .
O8 N13 O9A 117.5(14) . .
O7 N13 O9B 117.6(15) . .
O8 N13 O9B 118.8(15) . .
O9A N13 O9B 35.4(12) . .
O12 N14 O11 120.7(7) . .
O12 N14 O10 119.3(7) . .
O11 N14 O10 120.0(7) . .
O9B O9A N13 73(3) . .
O9A O9B N13 71(3) . .
H1WA O1W H1WB 108.2 . .
H2WA O2W H2WB 108.3 . .
H3WA O3W H3WB 108.6 . .
H4WA O4W H4WB 108.3 . .
H5WA O5W H5WB 108.4 . .
H6WA O6W H6WB 108.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.137(6) 1_655
Ag1 N1 2.141(6) .
Ag1 Ag2 3.2187(10) .
Ag2 N4 2.130(6) 1_655
Ag2 N3 2.132(6) .
Ag3 N6 2.119(6) 1_455
Ag3 N5 2.127(6) .
Ag3 Ag4 3.2006(11) .
Ag4 N8 2.138(6) 1_455
Ag4 N7 2.152(6) .
C1 N1 1.346(9) .
C1 C2 1.361(10) .
C1 H1 0.9500 .
C2 C3 1.394(9) .
C2 H2 0.9500 .
C3 C4 1.395(10) .
C3 C8 1.463(9) .
C4 C5 1.373(10) .
C4 H4 0.9500 .
C5 N1 1.345(8) .
C5 H5 0.9500 .
C6 N2 1.357(8) .
C6 C7 1.365(10) .
C6 H6 0.9500 .
C7 C8 1.413(9) .
C7 H7 0.9500 .
C8 C9 1.397(9) .
C9 C10 1.354(10) .
C9 H9 0.9500 .
C10 N2 1.332(9) .
C10 H10 0.9500 .
C11 N3 1.348(9) .
C11 C12 1.381(10) .
C11 H11 0.9500 .
C12 C13 1.396(9) .
C12 H12 0.9500 .
C13 C14 1.399(9) .
C13 C18 1.484(10) .
C14 C15 1.371(10) .
C14 H14 0.9500 .
C15 N3 1.344(8) .
C15 H15 0.9500 .
C16 N4 1.329(8) .
C16 C17 1.379(10) .
C16 H16 0.9500 .
C17 C18 1.400(10) .
C17 H17 0.9500 .
C18 C19 1.384(9) .
C19 C20 1.377(10) .
C19 H19 0.9500 .
C20 N4 1.335(9) .
C20 H20 0.9500 .
C21 N5 1.330(9) .
C21 C22 1.390(10) .
C21 H21 0.9500 .
C22 C23 1.385(9) .
C22 H22 0.9500 .
C23 C24 1.392(9) .
C23 C28 1.470(10) .
C24 C25 1.389(9) .
C24 H24 0.9500 .
C25 N5 1.348(9) .
C25 H25 0.9500 .
C26 N6 1.345(9) .
C26 C27 1.373(10) .
C26 H26 0.9500 .
C27 C28 1.408(9) .
C27 H27 0.9500 .
C28 C29 1.398(9) .
C29 C30 1.374(10) .
C29 H29 0.9500 .
C30 N6 1.347(9) .
C30 H30 0.9500 .
C31 N7 1.337(9) .
C31 C32 1.369(10) .
C31 H31 0.9500 .
C32 C33 1.396(9) .
C32 H32 0.9500 .
C33 C34 1.408(9) .
C33 C38 1.478(9) .
C34 C35 1.380(10) .
C34 H34 0.9500 .
C35 N7 1.340(8) .
C35 H35 0.9500 .
C36 N8 1.329(8) .
C36 C37 1.381(10) .
C36 H36 0.9500 .
C37 C38 1.373(9) .
C37 H37 0.9500 .
C38 C39 1.400(9) .
C39 C40 1.349(10) .
C39 H39 0.9500 .
C40 N8 1.353(9) .
C40 H40 0.9500 .
C41 N9 1.350(10) .
C41 C46 1.400(11) .
C41 C42 1.409(12) .
C42 C43 1.378(12) .
C42 H42 0.9500 .
C43 C44 1.398(12) .
C43 H43 0.9500 .
C44 C45 1.379(11) .
C44 H44 0.9500 .
C45 C46 1.395(11) .
C45 H45 0.9500 .
C46 C47 1.447(11) .
C47 N10 1.128(10) .
N2 Ag1 2.137(6) 1_455
N4 Ag2 2.130(6) 1_455
N6 Ag3 2.119(6) 1_655
N8 Ag4 2.138(6) 1_655
N9 H9A 0.8800 .
N9 H9B 0.8800 .
N11 O2 1.247(8) .
N11 O3 1.249(8) .
N11 O1 1.257(8) .
N12 O6 1.235(8) .
N12 O5 1.239(7) .
N12 O4 1.258(8) .
N13 O7 1.243(8) .
N13 O8 1.246(8) .
N13 O9A 1.25(2) .
N13 O9B 1.27(2) .
N14 O12 1.239(8) .
N14 O11 1.241(8) .
N14 O10 1.246(7) .
O9A O9B 0.77(3) .
O1W H1WA 0.8499 .
O1W H1WB 0.8500 .
O2W H2WA 0.8501 .
O2W H2WB 0.8500 .
O3W H3WA 0.8501 .
O3W H3WB 0.8499 .
O4W H4WA 0.8500 .
O4W H4WB 0.8500 .
O5W H5WA 0.8501 .
O5W H5WB 0.8499 .
O6W H6WA 0.8501 .
O6W H6WB 0.8498 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N9 H9A O5W 0.88 2.65 3.311(9) 132.8 .
N9 H9B O4 0.88 2.15 2.860(9) 136.7 1_565
O1W H1WA O2 0.85 2.02 2.859(8) 171.9 2_566
O1W H1WB O10 0.85 2.35 3.198(9) 172.4 .
O2W H2WA O6 0.85 2.19 3.038(8) 177.6 .
O2W H2WB O3W 0.85 1.99 2.835(8) 177.7 2_666
O3W H3WA O3 0.85 2.02 2.868(7) 173.9 2_666
O3W H3WB O4W 0.85 1.98 2.824(8) 173.6 .
O4W H4WA O8 0.85 2.17 3.016(8) 178.5 2_666
O4W H4WB O11 0.85 1.97 2.820(8) 178.1 1_655
O5W H5WA O8 0.85 2.03 2.882(8) 179.4 .
O5W H5WB O6W 0.85 1.94 2.789(8) 179.1 .
O6W H6WA O5 0.85 2.03 2.878(8) 178.3 1_565
O6W H6WB O1 0.85 2.17 3.019(8) 178.6 1_565
