#------------------------------------------------------------------------------
#$Date: 2016-02-14 05:40:26 +0100 (dom 14 de feb de 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/89/7208945.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7208945
loop_
_publ_author_name
'Peng, Guo'
'Ma, Li'
'Liang, Li'
'Ma, Yingzhao'
'Yang, Chengfeng'
'Deng, Hong'
_publ_section_title
;
 3d--4f Heterometallic coordination polymers constructed by tetranuclear
 lanthanide-based cluster as secondary building unit
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              922
_journal_paper_doi               10.1039/c2ce26277k
_journal_volume                  15
_journal_year                    2013
_chemical_formula_moiety         'C40 H36 Eu4 N6 O36 S2 Zn, 5H2O'
_chemical_formula_sum            'C40 H46 Eu4 N6 O41 S2 Zn'
_chemical_formula_weight         2004.16
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.8680(10)
_cell_angle_beta                 98.2301(10)
_cell_angle_gamma                115.6490(11)
_cell_formula_units_Z            1
_cell_length_a                   11.0516(8)
_cell_length_b                   12.4783(10)
_cell_length_c                   12.7662(10)
_cell_measurement_reflns_used    5136
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.20
_cell_measurement_theta_min      1.74
_cell_volume                     1455.5(2)
_computing_cell_refinement       'Apex2 (Bruker, 2005)'
_computing_data_collection       'Apex2 (Bruker, 2005)'
_computing_data_reduction        'Apex2 (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL 6.12'
_computing_publication_material  'SHELXTL 6.12'
_computing_structure_refinement  'SHELXTL 6.12'
_computing_structure_solution    'SHELXTL 6.12 (Bruker, 2000-2003)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker AXS SMART APEX CCD diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0168
_diffrn_reflns_av_sigmaI/netI    0.0344
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            7505
_diffrn_reflns_theta_full        25.20
_diffrn_reflns_theta_max         25.20
_diffrn_reflns_theta_min         1.74
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.841
_exptl_absorpt_correction_T_max  0.4161
_exptl_absorpt_correction_T_min  0.3274
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Apex2 (Bruker, 2005)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.286
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             970
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.031
_refine_diff_density_min         -1.014
_refine_diff_density_rms         0.131
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     440
_refine_ls_number_reflns         5136
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0359
_refine_ls_R_factor_gt           0.0280
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0357P)²+1.7396P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0653
_refine_ls_wR_factor_ref         0.0697
_reflns_number_gt                4346
_reflns_number_total             5136
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce26277k.txt
_cod_data_source_block           1
_cod_original_cell_volume        1455.50(19)
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7208945
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.4018(5) 0.0130(4) 0.1233(4) 0.0179(10) Uani 1 1 d . . .
C2 C 0.3751(5) -0.1048(5) 0.0491(4) 0.0234(11) Uani 1 1 d . . .
H2 H 0.2894 -0.1596 -0.0080 0.028 Uiso 1 1 calc R . .
C3 C 0.4771(6) -0.1390(5) 0.0613(5) 0.0285(13) Uani 1 1 d . . .
H3 H 0.4612 -0.2179 0.0135 0.034 Uiso 1 1 calc R . .
C4 C 0.6042(6) -0.0537(5) 0.1463(5) 0.0281(12) Uani 1 1 d . . .
H4 H 0.6757 -0.0739 0.1561 0.034 Uiso 1 1 calc R . .
C5 C 0.6227(5) 0.0613(5) 0.2157(4) 0.0209(11) Uani 1 1 d . . .
C6 C 0.7554(5) 0.1590(5) 0.3099(4) 0.0203(11) Uani 1 1 d . . .
C7 C 0.2992(5) 0.0619(5) 0.1163(4) 0.0208(11) Uani 1 1 d . . .
C8 C 0.8535(5) 0.5293(5) 0.2014(4) 0.0212(11) Uani 1 1 d . . .
C9 C 0.8285(6) 0.5068(5) 0.0869(5) 0.0271(12) Uani 1 1 d . . .
H9 H 0.7454 0.4370 0.0342 0.032 Uiso 1 1 calc R . .
C10 C 0.9290(6) 0.5897(5) 0.0506(5) 0.0334(14) Uani 1 1 d . . .
H10 H 0.9143 0.5769 -0.0264 0.040 Uiso 1 1 calc R . .
C11 C 1.0511(6) 0.6912(5) 0.1317(5) 0.0314(13) Uani 1 1 d . . .
H11 H 1.1198 0.7489 0.1102 0.038 Uiso 1 1 calc R . .
C12 C 1.0705(5) 0.7065(5) 0.2456(5) 0.0230(11) Uani 1 1 d . . .
C13 C 1.1999(6) 0.8159(5) 0.3409(5) 0.0327(14) Uani 1 1 d . . .
C14 C 0.7505(5) 0.4519(4) 0.2515(4) 0.0186(11) Uani 1 1 d . . .
C15 C 0.0247(6) -0.0138(6) 0.2356(5) 0.0361(14) Uani 1 1 d . . .
H15 H 0.1098 0.0612 0.2551 0.043 Uiso 1 1 calc R . .
C16 C -0.0131(7) -0.0595(6) 0.3203(5) 0.0378(15) Uani 1 1 d . . .
H16 H 0.0473 -0.0173 0.3946 0.045 Uiso 1 1 calc R . .
C17 C -0.1412(7) -0.1682(6) 0.2930(5) 0.0346(14) Uani 1 1 d . A .
C18 C -0.2263(6) -0.2310(6) 0.1796(5) 0.0336(14) Uani 1 1 d . . .
H18 H -0.3132 -0.3046 0.1584 0.040 Uiso 1 1 calc R . .
C19 C -0.1797(6) -0.1825(5) 0.0998(5) 0.0303(13) Uani 1 1 d . . .
H19 H -0.2354 -0.2266 0.0239 0.036 Uiso 1 1 calc R . .
C20 C -0.1885(8) -0.2188(7) 0.3823(7) 0.0499(19) Uani 1 1 d . . .
Eu1 Eu 0.55615(2) 0.29746(2) 0.35122(2) 0.01656(8) Uani 1 1 d . . .
Eu2 Eu 1.01082(2) 0.66984(2) 0.49045(2) 0.01743(8) Uani 1 1 d . . .
N1 N 0.5236(4) 0.0949(4) 0.2059(3) 0.0171(9) Uani 1 1 d . . .
N2 N 0.9732(4) 0.6276(4) 0.2801(3) 0.0200(9) Uani 1 1 d . . .
N3 N -0.0574(5) -0.0742(4) 0.1265(4) 0.0257(10) Uani 1 1 d . . .
O1 O 0.8545(4) 0.1386(3) 0.3311(3) 0.0318(9) Uani 1 1 d . . .
O2 O 0.7615(3) 0.2638(3) 0.3679(3) 0.0207(8) Uani 1 1 d . . .
O3 O 0.3374(4) 0.1698(3) 0.1924(3) 0.0266(8) Uani 1 1 d . . .
O4 O 0.1860(4) -0.0062(3) 0.0373(3) 0.0273(8) Uani 1 1 d . . .
O5 O 1.2885(5) 0.8986(4) 0.3168(4) 0.0556(14) Uani 1 1 d . . .
O6 O 1.2037(4) 0.8113(4) 0.4399(3) 0.0420(11) Uani 1 1 d . . .
O7 O 0.7807(3) 0.4932(3) 0.3608(3) 0.0202(7) Uani 1 1 d . . .
O8 O 0.6385(4) 0.3531(3) 0.1897(3) 0.0288(9) Uani 1 1 d . . .
O9 O -0.0980(5) -0.2150(4) 0.4566(3) 0.0362(10) Uani 1 1 d . . .
O10 O -0.281(4) -0.211(7) 0.409(4) 0.052(12) Uani 0.39(7) 1 d P A 1
O10' O -0.330(3) -0.288(4) 0.360(3) 0.052(7) Uani 0.61(7) 1 d P A 2
O11 O 0.9289(3) 0.4970(3) 0.5765(3) 0.0219(8) Uani 1 1 d . . .
O12 O 0.8470(4) 0.6443(3) 0.6140(3) 0.0301(9) Uani 1 1 d . . .
O13 O 0.8430(4) 0.5303(4) 0.7413(3) 0.0349(10) Uani 1 1 d . . .
O14 O 0.6802(4) 0.4188(3) 0.5517(3) 0.0316(9) Uani 1 1 d . . .
O1W O 0.5028(4) 0.1379(3) 0.4360(3) 0.0365(10) Uani 1 1 d . . .
H1A H 0.5657 0.1269 0.4703 0.055 Uiso 1 1 d R . .
H1B H 0.4352 0.0644 0.3914 0.055 Uiso 1 1 d R . .
O2W O 0.4966(4) 0.4597(4) 0.3328(4) 0.0503(13) Uani 1 1 d . . .
H2A H 0.4310 0.4777 0.3224 0.075 Uiso 1 1 d R . .
H2B H 0.5723 0.5236 0.3375 0.075 Uiso 1 1 d R . .
O4W O 0.1054(4) 0.1962(3) 0.1249(3) 0.0350(9) Uani 1 1 d . . .
H4B H 0.0884 0.2510 0.1653 0.052 Uiso 1 1 d R . .
H4A H 0.1871 0.2203 0.1647 0.052 Uiso 1 1 d R . .
O5W O 0.6284(8) 0.3595(7) 0.8078(5) 0.146(4) Uani 1 1 d . . .
H5A H 0.6608 0.3127 0.8223 0.219 Uiso 1 1 d R . .
H5B H 0.6727 0.3953 0.7669 0.219 Uiso 1 1 d R . .
O7W O 0.4358(12) 0.0959(11) 0.6216(10) 0.077(3) Uani 0.50 1 d P . .
H7A H 0.3840 0.0472 0.5533 0.115 Uiso 0.50 1 d PR . .
H7B H 0.4045 0.1457 0.6477 0.115 Uiso 0.50 1 d PR . .
S1 S 0.82261(13) 0.52156(12) 0.62422(10) 0.0199(3) Uani 1 1 d . . .
Zn3 Zn 0.0000 0.0000 0.0000 0.02112(19) Uani 1 2 d S . .
O3W O 0.3681(5) 0.2909(5) 0.4346(4) 0.0595(15) Uani 1 1 d . . .
H3A H 0.3309 0.2353 0.4635 0.089 Uiso 1 1 d R . .
H3B H 0.3100 0.3156 0.4175 0.089 Uiso 1 1 d R . .
O6W O 0.5495(7) 0.5275(8) 0.9080(7) 0.144(4) Uani 1 1 d . . .
H6A H 0.5260 0.5829 0.9035 0.216 Uiso 1 1 d R . .
H6B H 0.6379 0.5669 0.9396 0.216 Uiso 1 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 122.5(5) . .
N1 C1 C7 113.9(4) . .
C2 C1 C7 123.6(4) . .
C3 C2 C1 119.0(5) . .
C3 C2 H2 120.5 . .
C1 C2 H2 120.5 . .
C2 C3 C4 118.7(5) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.6 . .
C5 C4 C3 118.8(5) . .
C5 C4 H4 120.6 . .
C3 C4 H4 120.6 . .
N1 C5 C4 123.1(5) . .
N1 C5 C6 114.2(4) . .
C4 C5 C6 122.7(5) . .
O1 C6 O2 121.7(4) . .
O1 C6 C5 121.1(4) . .
O2 C6 C5 117.2(4) . .
O4 C7 O3 126.3(5) . .
O4 C7 C1 117.7(4) . .
O3 C7 C1 116.1(4) . .
N2 C8 C9 122.3(5) . .
N2 C8 C14 113.4(4) . .
C9 C8 C14 124.3(5) . .
C8 C9 C10 119.2(5) . .
C8 C9 H9 120.4 . .
C10 C9 H9 120.4 . .
C11 C10 C9 118.3(5) . .
C11 C10 H10 120.8 . .
C9 C10 H10 120.8 . .
C10 C11 C12 119.4(5) . .
C10 C11 H11 120.3 . .
C12 C11 H11 120.3 . .
N2 C12 C11 122.1(5) . .
N2 C12 C13 114.6(5) . .
C11 C12 C13 123.3(5) . .
O5 C13 O6 126.8(5) . .
O5 C13 C12 118.3(5) . .
O6 C13 C12 114.9(5) . .
O8 C14 O7 121.3(4) . .
O8 C14 C8 121.2(5) . .
O7 C14 C8 117.5(4) . .
N3 C15 C16 122.2(5) . .
N3 C15 H15 118.9 . .
C16 C15 H15 118.9 . .
C17 C16 C15 119.4(6) . .
C17 C16 H16 120.3 . .
C15 C16 H16 120.3 . .
C16 C17 C18 118.4(5) . .
C16 C17 C20 121.2(6) . .
C18 C17 C20 120.4(6) . .
C19 C18 C17 119.0(5) . .
C19 C18 H18 120.5 . .
C17 C18 H18 120.5 . .
N3 C19 C18 122.9(6) . .
N3 C19 H19 118.5 . .
C18 C19 H19 118.5 . .
O10 C20 O9 117.1(15) . .
O9 C20 O10' 125.9(7) . .
O10 C20 C17 118.2(12) . .
O9 C20 C17 117.6(6) . .
O10' C20 C17 115.0(10) . .
O14 Eu1 O1W 75.44(13) . .
O14 Eu1 O2W 92.33(15) . .
O1W Eu1 O2W 141.21(14) . .
O14 Eu1 O3 150.82(12) . .
O1W Eu1 O3 95.00(13) . .
O2W Eu1 O3 77.87(14) . .
O14 Eu1 O3W 76.94(14) . .
O1W Eu1 O3W 72.84(15) . .
O2W Eu1 O3W 68.54(15) . .
O3 Eu1 O3W 73.90(14) . .
O14 Eu1 O2 79.21(12) . .
O1W Eu1 O2 75.58(12) . .
O2W Eu1 O2 139.00(12) . .
O3 Eu1 O2 125.74(11) . .
O3W Eu1 O2 144.20(13) . .
O14 Eu1 O8 125.82(11) . .
O1W Eu1 O8 142.65(13) . .
O2W Eu1 O8 73.82(14) . .
O3 Eu1 O8 78.16(12) . .
O3W Eu1 O8 136.75(14) . .
O2 Eu1 O8 79.04(12) . .
O14 Eu1 N1 134.81(13) . .
O1W Eu1 N1 71.70(13) . .
O2W Eu1 N1 132.45(15) . .
O3 Eu1 N1 63.08(12) . .
O3W Eu1 N1 120.11(16) . .
O2 Eu1 N1 63.27(11) . .
O8 Eu1 N1 72.56(12) . .
O14 Eu1 O7 74.62(11) . .
O1W Eu1 O7 135.82(12) . .
O2W Eu1 O7 71.58(12) . .
O3 Eu1 O7 125.96(11) . .
O3W Eu1 O7 129.25(15) . .
O2 Eu1 O7 67.47(11) . .
O8 Eu1 O7 51.21(10) . .
N1 Eu1 O7 109.77(11) . .
O14 Eu1 H2B 87.1 . .
O1W Eu1 H2B 152.6 . .
O2W Eu1 H2B 16.9 . .
O3 Eu1 H2B 90.1 . .
O3W Eu1 H2B 82.9 . .
O2 Eu1 H2B 122.2 . .
O8 Eu1 H2B 64.7 . .
N1 Eu1 H2B 133.5 . .
O7 Eu1 H2B 54.7 . .
O9 Eu2 O6 86.66(15) 1_665 .
O9 Eu2 O11 151.17(13) 1_665 2_766
O6 Eu2 O11 89.24(13) . 2_766
O9 Eu2 O7 80.01(13) 1_665 .
O6 Eu2 O7 127.28(12) . .
O11 Eu2 O7 79.91(11) 2_766 .
O9 Eu2 O1 81.47(13) 1_665 2_766
O6 Eu2 O1 76.98(13) . 2_766
O11 Eu2 O1 125.24(12) 2_766 2_766
O7 Eu2 O1 148.09(12) . 2_766
O9 Eu2 O2 131.75(13) 1_665 2_766
O6 Eu2 O2 71.56(13) . 2_766
O11 Eu2 O2 72.97(11) 2_766 2_766
O7 Eu2 O2 146.97(11) . 2_766
O1 Eu2 O2 52.33(11) 2_766 2_766
O9 Eu2 N2 76.26(13) 1_665 .
O6 Eu2 N2 63.68(13) . .
O11 Eu2 N2 76.36(12) 2_766 .
O7 Eu2 N2 63.62(11) . .
O1 Eu2 N2 135.37(13) 2_766 .
O2 Eu2 N2 125.18(12) 2_766 .
O9 Eu2 O12 75.27(13) 1_665 .
O6 Eu2 O12 148.40(13) . .
O11 Eu2 O12 118.85(11) 2_766 .
O7 Eu2 O12 75.40(11) . .
O1 Eu2 O12 74.88(12) 2_766 .
O2 Eu2 O12 101.45(12) 2_766 .
N2 Eu2 O12 133.20(13) . .
O9 Eu2 O11 127.25(12) 1_665 .
O6 Eu2 O11 145.34(14) . .
O11 Eu2 O11 64.68(12) 2_766 .
O7 Eu2 O11 72.66(11) . .
O1 Eu2 O11 98.99(12) 2_766 .
O2 Eu2 O11 78.83(11) 2_766 .
N2 Eu2 O11 125.28(11) . .
O12 Eu2 O11 54.77(11) . .
O9 Eu2 C6 105.68(14) 1_665 2_766
O6 Eu2 C6 70.49(14) . 2_766
O11 Eu2 C6 99.74(13) 2_766 2_766
O7 Eu2 C6 162.07(13) . 2_766
O1 Eu2 C6 25.69(12) 2_766 2_766
O2 Eu2 C6 26.79(12) 2_766 2_766
N2 Eu2 C6 133.99(13) . 2_766
O12 Eu2 C6 89.44(13) . 2_766
O11 Eu2 C6 90.87(13) . 2_766
O9 Eu2 Eu2 150.72(10) 1_665 2_766
O6 Eu2 Eu2 119.48(11) . 2_766
O11 Eu2 Eu2 33.32(8) 2_766 2_766
O7 Eu2 Eu2 73.62(8) . 2_766
O1 Eu2 Eu2 115.29(9) 2_766 2_766
O2 Eu2 Eu2 73.36(7) 2_766 2_766
N2 Eu2 Eu2 102.42(9) . 2_766
O12 Eu2 Eu2 85.83(8) . 2_766
O11 Eu2 Eu2 31.37(7) . 2_766
C6 Eu2 Eu2 96.12(10) 2_766 2_766
C5 N1 C1 118.0(4) . .
C5 N1 Eu1 120.9(3) . .
C1 N1 Eu1 120.8(3) . .
C12 N2 C8 118.7(4) . .
C12 N2 Eu2 120.1(3) . .
C8 N2 Eu2 121.2(3) . .
C15 N3 C19 118.1(5) . .
C15 N3 Zn3 121.5(4) . .
C19 N3 Zn3 120.4(4) . .
C6 O1 Eu2 94.5(3) . 2_766
C6 O2 Eu1 123.4(3) . .
C6 O2 Eu2 90.8(3) . 2_766
Eu1 O2 Eu2 141.65(14) . 2_766
C7 O3 Eu1 125.6(3) . .
C7 O4 Zn3 133.9(3) . .
C13 O6 Eu2 125.9(3) . .
C14 O7 Eu2 123.7(3) . .
C14 O7 Eu1 91.8(3) . .
Eu2 O7 Eu1 142.77(14) . .
C14 O8 Eu1 95.6(3) . .
C20 O9 Eu2 141.9(4) . 1_445
S1 O11 Eu2 141.86(19) . 2_766
S1 O11 Eu2 99.34(17) . .
Eu2 O11 Eu2 115.32(12) 2_766 .
S1 O12 Eu2 100.89(17) . .
S1 O14 Eu1 138.1(2) . .
Eu1 O1W H1A 122.8 . .
Eu1 O1W H1B 113.0 . .
H1A O1W H1B 107.7 . .
Eu1 O2W H2A 145.6 . .
Eu1 O2W H2B 106.7 . .
H2A O2W H2B 107.7 . .
Zn3 O4W H4B 141.6 . .
Zn3 O4W H4A 113.3 . .
H4B O4W H4A 100.9 . .
H5A O5W H5B 107.7 . .
H7A O7W H7B 107.7 . .
O13 S1 O14 111.0(2) . .
O13 S1 O12 112.1(2) . .
O14 S1 O12 109.4(2) . .
O13 S1 O11 111.4(2) . .
O14 S1 O11 109.0(2) . .
O12 S1 O11 103.7(2) . .
O4 Zn3 O4 180.00(18) . 2
O4 Zn3 N3 90.80(16) . 2
O4 Zn3 N3 89.20(16) 2 2
O4 Zn3 N3 89.20(16) . .
O4 Zn3 N3 90.80(16) 2 .
N3 Zn3 N3 180.0(2) 2 .
O4 Zn3 O4W 90.12(14) . .
O4 Zn3 O4W 89.88(14) 2 .
N3 Zn3 O4W 88.83(15) 2 .
N3 Zn3 O4W 91.17(15) . .
O4 Zn3 O4W 89.88(14) . 2
O4 Zn3 O4W 90.12(14) 2 2
N3 Zn3 O4W 91.17(15) 2 2
N3 Zn3 O4W 88.83(15) . 2
O4W Zn3 O4W 180.0(3) . 2
Eu1 O3W H3A 120.2 . .
Eu1 O3W H3B 127.6 . .
H3A O3W H3B 107.7 . .
H6A O6W H6B 107.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.335(6) .
C1 C2 1.388(7) .
C1 C7 1.505(7) .
C2 C3 1.370(7) .
C2 H2 0.9300 .
C3 C4 1.386(7) .
C3 H3 0.9300 .
C4 C5 1.373(7) .
C4 H4 0.9300 .
C5 N1 1.333(6) .
C5 C6 1.492(7) .
C6 O1 1.237(6) .
C6 O2 1.282(6) .
C6 Eu2 2.845(5) 2_766
C7 O4 1.247(6) .
C7 O3 1.269(6) .
C8 N2 1.344(6) .
C8 C9 1.373(7) .
C8 C14 1.494(7) .
C9 C10 1.390(7) .
C9 H9 0.9300 .
C10 C11 1.379(8) .
C10 H10 0.9300 .
C11 C12 1.385(7) .
C11 H11 0.9300 .
C12 N2 1.333(6) .
C12 C13 1.514(8) .
C13 O5 1.227(7) .
C13 O6 1.276(7) .
C14 O8 1.242(6) .
C14 O7 1.284(6) .
C15 N3 1.343(7) .
C15 C16 1.389(8) .
C15 H15 0.9300 .
C16 C17 1.380(8) .
C16 H16 0.9300 .
C17 C18 1.395(9) .
C17 C20 1.500(8) .
C18 C19 1.373(8) .
C18 H18 0.9300 .
C19 N3 1.343(7) .
C19 H19 0.9300 .
C20 O10 1.161(18) .
C20 O9 1.250(8) .
Eu1 O14 2.408(4) .
Eu1 O1W 2.414(4) .
Eu1 O2W 2.441(4) .
Eu1 O3 2.447(3) .
Eu1 O3W 2.448(4) .
Eu1 O2 2.471(3) .
Eu1 O8 2.517(3) .
Eu1 N1 2.534(4) .
Eu1 O7 2.576(3) .
Eu1 H2B 2.8052 .
Eu2 O9 2.321(4) 1_665
Eu2 O6 2.416(4) .
Eu2 O11 2.429(3) 2_766
Eu2 O7 2.452(3) .
Eu2 O1 2.468(3) 2_766
Eu2 O2 2.522(3) 2_766
Eu2 N2 2.526(4) .
Eu2 O12 2.541(4) .
Eu2 O11 2.563(3) .
N3 Zn3 2.115(4) .
O1 Eu2 2.468(3) 2_766
O2 Eu2 2.522(3) 2_766
O4 Zn3 2.082(3) .
O9 Eu2 2.321(4) 1_445
O11 S1 1.504(3) .
O11 Eu2 2.429(3) 2_766
O12 S1 1.482(4) .
O13 S1 1.445(4) .
O14 S1 1.472(4) .
O1W H1A 0.8500 .
O1W H1B 0.8500 .
O2W H2A 0.8501 .
O2W H2B 0.8500 .
O4W Zn3 2.181(4) .
O4W H4B 0.8457 .
O4W H4A 0.8458 .
O5W H5A 0.8500 .
O5W H5B 0.8501 .
O7W H7A 0.8500 .
O7W H7B 0.8501 .
Zn3 O4 2.082(3) 2
Zn3 N3 2.115(4) 2
Zn3 O4W 2.181(4) 2
O3W H3A 0.8500 .
O3W H3B 0.8500 .
O6W H6A 0.8501 .
O6W H6B 0.8500 .
