#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:36:37 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180441 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/10/7211084.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7211084
loop_
_publ_author_name
'Gao, Yanfei'
'Cao, Jianwei'
'Song, Ye'
'Zhang, Guonan'
'Wang, Yanqin'
'Liu, Zhiliang'
_publ_section_title
;
 Structure control and crystal-to-crystal transformation for two series of
 lanthanide--organic coordination polymers
;
_journal_issue                   42
_journal_name_full               CrystEngComm
_journal_page_first              8522
_journal_paper_doi               10.1039/c3ce41207e
_journal_volume                  15
_journal_year                    2013
_chemical_formula_sum            'C28 H17 Eu O10'
_chemical_formula_weight         665.38
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.847(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.3601(7)
_cell_length_b                   18.4170(15)
_cell_length_c                   14.3938(10)
_cell_measurement_reflns_used    1871
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.3774
_cell_measurement_theta_min      2.4877
_cell_volume                     2475.7(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0499
_diffrn_reflns_av_sigmaI/netI    0.0774
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            9443
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.52
_exptl_absorpt_coefficient_mu    2.594
_exptl_absorpt_correction_T_max  0.9732
_exptl_absorpt_correction_T_min  0.8984
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   multi-scan
_exptl_crystal_density_diffrn    1.785
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1312
_exptl_crystal_size_max          0.04
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.01
_refine_diff_density_max         1.118
_refine_diff_density_min         -0.569
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     364
_refine_ls_number_reflns         4364
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.0665
_refine_ls_R_factor_gt           0.0396
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0199P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0683
_refine_ls_wR_factor_ref         0.0789
_reflns_number_gt                3230
_reflns_number_total             4364
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ce41207e.txt
_cod_data_source_block           exp_1354
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7211084
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.71323(3) 0.973391(16) 0.01069(2) 0.02121(10) Uani 1 1 d . . .
O1 O 0.8724(4) 0.8807(2) 0.0890(3) 0.0363(11) Uani 1 1 d . A .
O3 O 1.3623(5) 0.6769(2) 0.2734(3) 0.0477(13) Uani 1 1 d . A .
O4 O 1.3710(4) 0.5605(2) 0.3997(3) 0.0383(11) Uani 1 1 d . . .
O5 O 1.6055(4) 0.5393(2) 0.4220(3) 0.0331(10) Uani 1 1 d . . .
O6 O 0.6047(4) 0.9444(2) 0.1482(3) 0.0357(11) Uani 1 1 d . . .
O7 O 0.3768(4) 0.9777(3) 0.1285(3) 0.0528(14) Uani 1 1 d . . .
O8 O 0.6855(5) 0.8862(2) 0.3121(3) 0.0434(12) Uani 1 1 d . . .
O9 O 0.9203(5) 0.5781(2) 0.4557(3) 0.0462(12) Uani 1 1 d . . .
O10 O 1.1176(4) 0.6426(2) 0.4634(3) 0.0362(11) Uani 1 1 d . . .
C1 C 0.8873(8) 0.8155(4) 0.0930(5) 0.0454(19) Uani 1 1 d . . .
C2 C 1.0099(7) 0.7775(4) 0.1418(4) 0.0356(16) Uani 1 1 d . A .
C3 C 1.1287(7) 0.8174(4) 0.1693(5) 0.051(2) Uani 1 1 d . . .
H3 H 1.1297 0.8673 0.1596 0.061 Uiso 1 1 calc R A .
C4 C 1.2481(8) 0.7828(4) 0.2121(5) 0.054(2) Uani 1 1 d . A .
H4 H 1.3300 0.8094 0.2298 0.064 Uiso 1 1 calc R . .
C5 C 1.2446(7) 0.7104(4) 0.2278(5) 0.0406(18) Uani 1 1 d . . .
C6 C 1.1260(8) 0.6705(4) 0.2026(5) 0.049(2) Uani 1 1 d . A .
H6 H 1.1252 0.6209 0.2142 0.059 Uiso 1 1 calc R . .
C7 C 1.0074(8) 0.7035(4) 0.1599(5) 0.053(2) Uani 1 1 d . . .
H7 H 0.9259 0.6764 0.1432 0.064 Uiso 1 1 calc R A .
C8 C 1.4410(7) 0.6286(4) 0.2240(4) 0.0361(16) Uani 1 1 d . . .
C9 C 1.4560(8) 0.6389(4) 0.1309(5) 0.053(2) Uani 1 1 d . A .
H9 H 1.4073 0.6766 0.0996 0.064 Uiso 1 1 calc R . .
C10 C 1.5444(8) 0.5928(4) 0.0827(5) 0.057(2) Uani 1 1 d . . .
H10 H 1.5544 0.5996 0.0195 0.069 Uiso 1 1 calc R A .
C11 C 1.6159(8) 0.5376(4) 0.1295(5) 0.052(2) Uani 1 1 d . A .
H11 H 1.6726 0.5059 0.0978 0.063 Uiso 1 1 calc R . .
C12 C 1.6036(6) 0.5292(4) 0.2242(4) 0.0374(16) Uani 1 1 d . . .
H12 H 1.6565 0.4933 0.2563 0.045 Uiso 1 1 calc R A .
C13 C 1.5130(6) 0.5736(3) 0.2721(4) 0.0260(14) Uani 1 1 d . A .
C14 C 1.4934(6) 0.5580(3) 0.3722(4) 0.0256(14) Uani 1 1 d . . .
C15 C 0.4837(7) 0.9558(3) 0.1772(4) 0.0330(16) Uani 1 1 d . . .
C16 C 0.4594(6) 0.9421(3) 0.2779(4) 0.0287(15) Uani 1 1 d . . .
C17 C 0.3315(7) 0.9667(3) 0.3086(4) 0.0399(17) Uani 1 1 d . . .
H17 H 0.2674 0.9904 0.2666 0.048 Uiso 1 1 calc R . .
C18 C 0.2955(8) 0.9576(4) 0.3985(5) 0.061(2) Uani 1 1 d U . .
H18 H 0.2082 0.9741 0.4175 0.073 Uiso 1 1 calc R . .
C19 C 0.3924(9) 0.9231(5) 0.4604(6) 0.078(3) Uani 1 1 d U . .
H19 H 0.3698 0.9162 0.5217 0.094 Uiso 1 1 calc R . .
C20 C 0.5226(8) 0.8988(4) 0.4324(5) 0.062(2) Uani 1 1 d U . .
H20 H 0.5875 0.8762 0.4749 0.074 Uiso 1 1 calc R . .
C21 C 0.5553(7) 0.9081(3) 0.3417(5) 0.0379(17) Uani 1 1 d . . .
C22 C 0.7525(7) 0.8249(3) 0.3504(5) 0.0350(16) Uani 1 1 d . . .
C23 C 0.8987(7) 0.8269(3) 0.3612(4) 0.0341(16) Uani 1 1 d . . .
H23 H 0.9480 0.8690 0.3474 0.041 Uiso 1 1 calc R . .
C24 C 0.9720(6) 0.7660(3) 0.3926(4) 0.0324(16) Uani 1 1 d . . .
H24 H 1.0715 0.7672 0.3993 0.039 Uiso 1 1 calc R . .
C25 C 0.9022(6) 0.7040(3) 0.4142(4) 0.0285(15) Uani 1 1 d . . .
C26 C 0.7542(7) 0.7028(4) 0.4014(6) 0.053(2) Uani 1 1 d . . .
H26 H 0.7049 0.6605 0.4139 0.063 Uiso 1 1 calc R . .
C27 C 0.6798(7) 0.7626(4) 0.3708(6) 0.056(2) Uani 1 1 d . . .
H27 H 0.5804 0.7614 0.3637 0.067 Uiso 1 1 calc R . .
C28 C 0.9818(7) 0.6382(3) 0.4459(4) 0.0316(16) Uani 1 1 d . . .
O2A O 0.780(2) 0.7683(10) 0.066(3) 0.063(7) Uani 0.58(8) 1 d PU A 1
H2A H 0.7153 0.7903 0.0370 0.095 Uiso 0.58(8) 1 calc PR A 1
O2B O 0.817(5) 0.7710(13) 0.031(3) 0.058(9) Uani 0.42(8) 1 d PU A 2
H2B H 0.7629 0.7950 -0.0040 0.087 Uiso 0.42(8) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Eu1 O7 112.62(16) 2_755 3_675
O5 Eu1 O4 86.87(14) 2_755 4_575
O7 Eu1 O4 73.76(15) 3_675 4_575
O5 Eu1 O6 96.67(14) 2_755 .
O7 Eu1 O6 131.97(14) 3_675 .
O4 Eu1 O6 147.88(15) 4_575 .
O5 Eu1 O9 82.29(14) 2_755 2_655
O7 Eu1 O9 72.06(16) 3_675 2_655
O4 Eu1 O9 136.53(16) 4_575 2_655
O6 Eu1 O9 75.42(15) . 2_655
O5 Eu1 O10 149.17(14) 2_755 4_575
O7 Eu1 O10 89.64(16) 3_675 4_575
O4 Eu1 O10 78.98(15) 4_575 4_575
O6 Eu1 O10 82.06(15) . 4_575
O9 Eu1 O10 126.31(15) 2_655 4_575
O5 Eu1 O1 76.32(14) 2_755 .
O7 Eu1 O1 146.71(15) 3_675 .
O4 Eu1 O1 74.88(15) 4_575 .
O6 Eu1 O1 75.02(14) . .
O9 Eu1 O1 140.87(15) 2_655 .
O10 Eu1 O1 73.61(14) 4_575 .
O5 Eu1 O9 161.07(13) 2_755 4_575
O7 Eu1 O9 67.30(14) 3_675 4_575
O4 Eu1 O9 110.44(13) 4_575 4_575
O6 Eu1 O9 72.95(14) . 4_575
O9 Eu1 O9 79.80(14) 2_655 4_575
O10 Eu1 O9 46.91(13) 4_575 4_575
O1 Eu1 O9 114.71(13) . 4_575
O5 Eu1 C28 169.38(15) 2_755 4_575
O7 Eu1 C28 77.81(17) 3_675 4_575
O4 Eu1 C28 94.53(16) 4_575 4_575
O6 Eu1 C28 76.61(15) . 4_575
O9 Eu1 C28 103.58(16) 2_655 4_575
O10 Eu1 C28 22.96(15) 4_575 4_575
O1 Eu1 C28 93.86(15) . 4_575
O9 Eu1 C28 23.95(13) 4_575 4_575
O5 Eu1 Eu1 127.22(10) 2_755 3_675
O7 Eu1 Eu1 62.87(10) 3_675 3_675
O4 Eu1 Eu1 132.09(10) 4_575 3_675
O6 Eu1 Eu1 69.11(10) . 3_675
O9 Eu1 Eu1 45.22(11) 2_655 3_675
O10 Eu1 Eu1 81.30(10) 4_575 3_675
O1 Eu1 Eu1 138.49(10) . 3_675
O9 Eu1 Eu1 34.58(8) 4_575 3_675
C28 Eu1 Eu1 58.42(12) 4_575 3_675
C1 O1 Eu1 140.0(5) . .
C8 O3 C5 118.5(5) . .
C14 O4 Eu1 148.4(4) . 4_676
C14 O5 Eu1 162.5(4) . 2_745
C15 O6 Eu1 134.1(4) . .
C15 O7 Eu1 147.8(4) . 3_675
C21 O8 C22 120.0(5) . .
C28 O9 Eu1 172.2(4) . 2_645
C28 O9 Eu1 83.7(4) . 4_676
Eu1 O9 Eu1 100.20(14) 2_645 4_676
C28 O10 Eu1 110.2(4) . 4_676
O1 C1 O2B 121.4(11) . .
O1 C1 O2A 122.6(9) . .
O2B C1 O2A 27.3(12) . .
O1 C1 C2 125.0(7) . .
O2B C1 C2 110.8(13) . .
O2A C1 C2 111.5(9) . .
C3 C2 C7 119.8(6) . .
C3 C2 C1 118.2(6) . .
C7 C2 C1 122.0(6) . .
C2 C3 C4 119.6(6) . .
C2 C3 H3 120.2 . .
C4 C3 H3 120.2 . .
C5 C4 C3 119.8(7) . .
C5 C4 H4 120.1 . .
C3 C4 H4 120.1 . .
C4 C5 C6 121.1(6) . .
C4 C5 O3 119.3(7) . .
C6 C5 O3 119.6(6) . .
C5 C6 C7 120.1(6) . .
C5 C6 H6 120.0 . .
C7 C6 H6 119.9 . .
C6 C7 C2 119.6(7) . .
C6 C7 H7 120.2 . .
C2 C7 H7 120.2 . .
C9 C8 C13 120.9(6) . .
C9 C8 O3 120.5(6) . .
C13 C8 O3 118.4(5) . .
C8 C9 C10 120.2(7) . .
C8 C9 H9 119.9 . .
C10 C9 H9 119.9 . .
C11 C10 C9 119.5(6) . .
C11 C10 H10 120.3 . .
C9 C10 H10 120.3 . .
C10 C11 C12 119.8(6) . .
C10 C11 H11 120.1 . .
C12 C11 H11 120.1 . .
C11 C12 C13 121.0(6) . .
C11 C12 H12 119.5 . .
C13 C12 H12 119.5 . .
C8 C13 C12 118.5(6) . .
C8 C13 C14 122.6(5) . .
C12 C13 C14 118.9(5) . .
O4 C14 O5 125.0(5) . .
O4 C14 C13 118.5(5) . .
O5 C14 C13 116.4(5) . .
O7 C15 O6 125.2(6) . .
O7 C15 C16 115.3(5) . .
O6 C15 C16 119.5(6) . .
C17 C16 C21 118.2(6) . .
C17 C16 C15 116.3(6) . .
C21 C16 C15 125.5(6) . .
C18 C17 C16 122.3(7) . .
C18 C17 H17 118.8 . .
C16 C17 H17 118.8 . .
C17 C18 C19 118.2(7) . .
C17 C18 H18 120.9 . .
C19 C18 H18 120.9 . .
C18 C19 C20 121.0(8) . .
C18 C19 H19 119.5 . .
C20 C19 H19 119.5 . .
C21 C20 C19 119.6(7) . .
C21 C20 H20 120.2 . .
C19 C20 H20 120.2 . .
C20 C21 O8 121.1(6) . .
C20 C21 C16 120.7(6) . .
O8 C21 C16 118.2(6) . .
C23 C22 C27 120.2(6) . .
C23 C22 O8 116.5(6) . .
C27 C22 O8 123.1(6) . .
C22 C23 C24 119.3(6) . .
C22 C23 H23 120.4 . .
C24 C23 H23 120.4 . .
C25 C24 C23 121.5(6) . .
C25 C24 H24 119.3 . .
C23 C24 H24 119.3 . .
C24 C25 C26 118.2(6) . .
C24 C25 C28 121.2(6) . .
C26 C25 C28 120.5(6) . .
C27 C26 C25 121.1(7) . .
C27 C26 H26 119.5 . .
C25 C26 H26 119.5 . .
C26 C27 C22 119.7(7) . .
C26 C27 H27 120.2 . .
C22 C27 H27 120.2 . .
O9 C28 O10 119.2(6) . .
O9 C28 C25 122.0(6) . .
O10 C28 C25 118.8(6) . .
O9 C28 Eu1 72.4(3) . 4_676
O10 C28 Eu1 46.8(3) . 4_676
C25 C28 Eu1 165.6(4) . 4_676
C1 O2A H2A 109.5 . .
C1 O2B H2B 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.252(4) 2_755
Eu1 O7 2.303(4) 3_675
Eu1 O4 2.332(4) 4_575
Eu1 O6 2.347(4) .
Eu1 O9 2.365(4) 2_655
Eu1 O10 2.397(4) 4_575
Eu1 O1 2.485(4) .
Eu1 O9 2.958(4) 4_575
Eu1 C28 3.085(6) 4_575
Eu1 Eu1 4.1018(6) 3_675
O1 C1 1.211(7) .
O3 C8 1.381(7) .
O3 C5 1.389(7) .
O4 C14 1.238(6) .
O4 Eu1 2.332(4) 4_676
O5 C14 1.277(6) .
O5 Eu1 2.252(4) 2_745
O6 C15 1.250(7) .
O7 C15 1.250(7) .
O7 Eu1 2.303(4) 3_675
O8 C21 1.379(7) .
O8 C22 1.386(7) .
O9 C28 1.260(7) .
O9 Eu1 2.365(4) 2_645
O9 Eu1 2.958(4) 4_676
O10 C28 1.282(7) .
O10 Eu1 2.397(4) 4_676
C1 O2B 1.35(2) .
C1 O2A 1.365(17) .
C1 C2 1.480(9) .
C2 C3 1.369(9) .
C2 C7 1.388(9) .
C3 C4 1.393(9) .
C3 H3 0.9300 .
C4 C5 1.354(9) .
C4 H4 0.9300 .
C5 C6 1.360(9) .
C6 C7 1.374(9) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C9 1.371(8) .
C8 C13 1.377(8) .
C9 C10 1.401(9) .
C9 H9 0.9300 .
C10 C11 1.369(9) .
C10 H10 0.9300 .
C11 C12 1.384(9) .
C11 H11 0.9300 .
C12 C13 1.394(8) .
C12 H12 0.9300 .
C13 C14 1.493(8) .
C15 C16 1.504(8) .
C16 C17 1.381(8) .
C16 C21 1.390(8) .
C17 C18 1.370(9) .
C17 H17 0.9300 .
C18 C19 1.382(10) .
C18 H18 0.9300 .
C19 C20 1.383(10) .
C19 H19 0.9300 .
C20 C21 1.371(9) .
C20 H20 0.9300 .
C22 C23 1.367(8) .
C22 C27 1.376(8) .
C23 C24 1.376(8) .
C23 H23 0.9300 .
C24 C25 1.363(8) .
C24 H24 0.9300 .
C25 C26 1.385(8) .
C25 C28 1.478(8) .
C26 C27 1.361(9) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 Eu1 3.085(6) 4_676
O2A H2A 0.8200 .
O2B H2B 0.8200 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Eu1 O1 C1 -170.3(7) 2_755 .
O7 Eu1 O1 C1 -59.8(8) 3_675 .
O4 Eu1 O1 C1 -79.9(7) 4_575 .
O6 Eu1 O1 C1 88.8(7) . .
O9 Eu1 O1 C1 130.9(7) 2_655 .
O10 Eu1 O1 C1 2.8(7) 4_575 .
O9 Eu1 O1 C1 26.0(8) 4_575 .
C28 Eu1 O1 C1 13.8(7) 4_575 .
Eu1 Eu1 O1 C1 58.1(8) 3_675 .
O5 Eu1 O6 C15 120.1(6) 2_755 .
O7 Eu1 O6 C15 -8.7(7) 3_675 .
O4 Eu1 O6 C15 -145.1(5) 4_575 .
O9 Eu1 O6 C15 39.9(6) 2_655 .
O10 Eu1 O6 C15 -91.0(6) 4_575 .
O1 Eu1 O6 C15 -166.0(6) . .
O9 Eu1 O6 C15 -43.7(6) 4_575 .
C28 Eu1 O6 C15 -68.3(6) 4_575 .
Eu1 Eu1 O6 C15 -7.3(5) 3_675 .
Eu1 O1 C1 O2B 13(3) . .
Eu1 O1 C1 O2A -19(3) . .
Eu1 O1 C1 C2 172.6(4) . .
O1 C1 C2 C3 -13.3(11) . .
O2B C1 C2 C3 148(3) . .
O2A C1 C2 C3 177(2) . .
O1 C1 C2 C7 166.8(7) . .
O2B C1 C2 C7 -32(3) . .
O2A C1 C2 C7 -3(2) . .
C7 C2 C3 C4 2.4(11) . .
C1 C2 C3 C4 -177.4(7) . .
C2 C3 C4 C5 -1.4(11) . .
C3 C4 C5 C6 0.0(11) . .
C3 C4 C5 O3 -177.8(6) . .
C8 O3 C5 C4 -112.6(7) . .
C8 O3 C5 C6 69.6(9) . .
C4 C5 C6 C7 0.4(11) . .
O3 C5 C6 C7 178.1(6) . .
C5 C6 C7 C2 0.7(11) . .
C3 C2 C7 C6 -2.1(11) . .
C1 C2 C7 C6 177.8(7) . .
C5 O3 C8 C9 32.9(10) . .
C5 O3 C8 C13 -152.2(6) . .
C13 C8 C9 C10 0.6(11) . .
O3 C8 C9 C10 175.4(7) . .
C8 C9 C10 C11 -0.2(12) . .
C9 C10 C11 C12 -1.9(12) . .
C10 C11 C12 C13 3.6(11) . .
C9 C8 C13 C12 1.0(10) . .
O3 C8 C13 C12 -173.9(6) . .
C9 C8 C13 C14 -176.5(6) . .
O3 C8 C13 C14 8.6(9) . .
C11 C12 C13 C8 -3.1(10) . .
C11 C12 C13 C14 174.5(6) . .
Eu1 O4 C14 O5 -17.0(12) 4_676 .
Eu1 O4 C14 C13 159.1(5) 4_676 .
Eu1 O5 C14 O4 95.2(13) 2_745 .
Eu1 O5 C14 C13 -81.1(13) 2_745 .
C8 C13 C14 O4 41.2(9) . .
C12 C13 C14 O4 -136.3(6) . .
C8 C13 C14 O5 -142.2(6) . .
C12 C13 C14 O5 40.3(8) . .
Eu1 O7 C15 O6 -12.2(14) 3_675 .
Eu1 O7 C15 C16 168.5(6) 3_675 .
Eu1 O6 C15 O7 12.9(10) . .
Eu1 O6 C15 C16 -167.9(4) . .
O7 C15 C16 C17 -10.8(9) . .
O6 C15 C16 C17 169.9(6) . .
O7 C15 C16 C21 170.3(6) . .
O6 C15 C16 C21 -9.0(10) . .
C21 C16 C17 C18 -1.2(10) . .
C15 C16 C17 C18 179.8(6) . .
C16 C17 C18 C19 0.8(11) . .
C17 C18 C19 C20 0.3(13) . .
C18 C19 C20 C21 -0.8(13) . .
C19 C20 C21 O8 178.3(7) . .
C19 C20 C21 C16 0.4(12) . .
C22 O8 C21 C20 34.0(10) . .
C22 O8 C21 C16 -148.1(6) . .
C17 C16 C21 C20 0.6(10) . .
C15 C16 C21 C20 179.5(7) . .
C17 C16 C21 O8 -177.3(6) . .
C15 C16 C21 O8 1.6(10) . .
C21 O8 C22 C23 -144.8(6) . .
C21 O8 C22 C27 39.9(10) . .
C27 C22 C23 C24 0.0(11) . .
O8 C22 C23 C24 -175.5(5) . .
C22 C23 C24 C25 -0.7(10) . .
C23 C24 C25 C26 1.7(10) . .
C23 C24 C25 C28 178.5(6) . .
C24 C25 C26 C27 -2.0(12) . .
C28 C25 C26 C27 -178.9(7) . .
C25 C26 C27 C22 1.3(12) . .
C23 C22 C27 C26 -0.3(12) . .
O8 C22 C27 C26 174.8(7) . .
Eu1 O9 C28 O10 120(3) 2_645 .
Eu1 O9 C28 O10 -0.4(5) 4_676 .
Eu1 O9 C28 C25 -61(3) 2_645 .
Eu1 O9 C28 C25 179.3(6) 4_676 .
Eu1 O9 C28 Eu1 120(3) 2_645 4_676
Eu1 O10 C28 O9 0.5(7) 4_676 .
Eu1 O10 C28 C25 -179.2(4) 4_676 .
C24 C25 C28 O9 -171.5(6) . .
C26 C25 C28 O9 5.2(10) . .
C24 C25 C28 O10 8.2(9) . .
C26 C25 C28 O10 -175.1(6) . .
C24 C25 C28 Eu1 6(2) . 4_676
C26 C25 C28 Eu1 -177.4(13) . 4_676
