#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:51:55 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180452 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/21/7212110.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7212110
loop_
_publ_author_name
'Bai, Yan'
'Gao, Hui'
'Dang, Dong-Bin'
'Guo, Xiang-Yang'
'An, Bing'
'Shang, Wei-Li'
_publ_section_title
;
 A series of metal--organic frameworks based on polydentate Schiff-base
 ligands derived from benzil dihydrazone: synthesis, crystal structures
 and luminescent properties
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              1422
_journal_paper_doi               10.1039/b919813j
_journal_volume                  12
_journal_year                    2010
_chemical_formula_sum            'C52 H40 Ag B F4 N12'
_chemical_formula_weight         1027.64
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.176(2)
_cell_angle_beta                 93.162(2)
_cell_angle_gamma                97.274(2)
_cell_formula_units_Z            2
_cell_length_a                   10.5733(4)
_cell_length_b                   11.1066(4)
_cell_length_c                   21.3032(8)
_cell_measurement_reflns_used    9650
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      24.83
_cell_measurement_theta_min      2.24
_cell_volume                     2449.52(16)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0274
_diffrn_reflns_av_sigmaI/netI    0.0311
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            33638
_diffrn_reflns_theta_full        27.57
_diffrn_reflns_theta_max         27.57
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    0.476
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.393
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.934
_refine_diff_density_min         -0.774
_refine_diff_density_rms         0.056
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         11265
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0656
_refine_ls_R_factor_gt           0.0453
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0526P)²+1.5950P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1113
_refine_ls_wR_factor_ref         0.1237
_reflns_number_gt                8278
_reflns_number_total             11265
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b919813j.txt
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7212110
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.10951(2) 0.95041(3) 0.742049(11) 0.06596(10) Uani 1 1 d .
N1 N -0.0430(2) 0.9575(2) 0.65952(11) 0.0548(6) Uani 1 1 d .
N2 N -0.3043(2) 1.1202(2) 0.49682(12) 0.0589(6) Uani 1 1 d .
N3 N -0.3972(3) 1.1223(2) 0.44709(11) 0.0574(6) Uani 1 1 d .
N4 N -0.3671(2) 1.3810(2) 0.53655(10) 0.0466(5) Uani 1 1 d .
N5 N -0.4688(2) 1.3100(2) 0.55938(10) 0.0503(5) Uani 1 1 d .
N6 N -0.7280(2) 1.0886(2) 0.70845(11) 0.0589(6) Uani 1 1 d .
C1 C -0.1661(3) 1.0903(3) 0.61126(14) 0.0554(7) Uani 1 1 d .
H1 H -0.1886 1.1686 0.6115 0.066 Uiso 1 1 calc R
C2 C -0.0813(3) 1.0673(3) 0.65754(14) 0.0599(7) Uani 1 1 d .
H2 H -0.0484 1.1316 0.6894 0.072 Uiso 1 1 calc R
C3 C -0.0944(3) 0.8666(3) 0.61508(15) 0.0614(8) Uani 1 1 d .
H3 H -0.0695 0.7894 0.6157 0.074 Uiso 1 1 calc R
C4 C -0.1834(3) 0.8806(3) 0.56771(15) 0.0624(8) Uani 1 1 d .
H4 H -0.2199 0.8133 0.5384 0.075 Uiso 1 1 calc R
C5 C -0.2178(3) 0.9956(2) 0.56426(13) 0.0498(6) Uani 1 1 d .
C6 C -0.3075(3) 1.0148(3) 0.51333(14) 0.0554(7) Uani 1 1 d .
H6 H -0.3667 0.9500 0.4931 0.067 Uiso 1 1 calc R
C7 C -0.4149(3) 1.2310(2) 0.43919(12) 0.0434(6) Uani 1 1 d .
C8 C -0.5093(3) 1.2448(2) 0.38808(12) 0.0449(6) Uani 1 1 d .
C9 C -0.5465(3) 1.1488(3) 0.33834(14) 0.0611(8) Uani 1 1 d .
H9 H -0.5105 1.0764 0.3368 0.073 Uiso 1 1 calc R
C10 C -0.6369(4) 1.1614(3) 0.29146(15) 0.0708(9) Uani 1 1 d .
H10 H -0.6606 1.0977 0.2579 0.085 Uiso 1 1 calc R
C11 C -0.6922(3) 1.2674(3) 0.29390(15) 0.0626(8) Uani 1 1 d .
H11 H -0.7533 1.2752 0.2622 0.075 Uiso 1 1 calc R
C12 C -0.6574(3) 1.3612(3) 0.34288(15) 0.0584(7) Uani 1 1 d .
H12 H -0.6957 1.4324 0.3448 0.070 Uiso 1 1 calc R
C13 C -0.5654(3) 1.3507(2) 0.38975(13) 0.0495(6) Uani 1 1 d .
H13 H -0.5411 1.4155 0.4226 0.059 Uiso 1 1 calc R
C14 C -0.3437(2) 1.3446(2) 0.47920(11) 0.0407(5) Uani 1 1 d .
C15 C -0.2418(3) 1.4180(2) 0.45082(12) 0.0461(6) Uani 1 1 d .
C16 C -0.1974(4) 1.3750(4) 0.39331(15) 0.0763(10) Uani 1 1 d .
H16 H -0.2329 1.2987 0.3713 0.092 Uiso 1 1 calc R
C17 C -0.1008(4) 1.4442(5) 0.36828(18) 0.1022(15) Uani 1 1 d .
H17 H -0.0722 1.4141 0.3294 0.123 Uiso 1 1 calc R
C18 C -0.0466(4) 1.5560(4) 0.39953(19) 0.0896(12) Uani 1 1 d .
H18 H 0.0183 1.6021 0.3820 0.108 Uiso 1 1 calc R
C19 C -0.0883(4) 1.5995(4) 0.4566(2) 0.0841(11) Uani 1 1 d .
H19 H -0.0514 1.6756 0.4783 0.101 Uiso 1 1 calc R
C20 C -0.1848(3) 1.5314(3) 0.48252(16) 0.0661(9) Uani 1 1 d .
H20 H -0.2121 1.5619 0.5217 0.079 Uiso 1 1 calc R
C21 C -0.4475(3) 1.2975(2) 0.61706(12) 0.0453(6) Uani 1 1 d .
H21 H -0.3701 1.3324 0.6390 0.054 Uiso 1 1 calc R
C22 C -0.5446(3) 1.2283(2) 0.64935(12) 0.0442(6) Uani 1 1 d .
C23 C -0.6696(3) 1.2004(3) 0.62410(14) 0.0672(9) Uani 1 1 d .
H23 H -0.6949 1.2288 0.5870 0.081 Uiso 1 1 calc R
C24 C -0.7559(3) 1.1307(4) 0.65408(16) 0.0785(11) Uani 1 1 d .
H24 H -0.8391 1.1113 0.6357 0.094 Uiso 1 1 calc R
C25 C -0.6089(3) 1.1204(2) 0.73385(12) 0.0490(6) Uani 1 1 d .
H25 H -0.5874 1.0953 0.7724 0.059 Uiso 1 1 calc R
C26 C -0.5154(3) 1.1883(2) 0.70631(12) 0.0454(6) Uani 1 1 d .
H26 H -0.4330 1.2072 0.7259 0.055 Uiso 1 1 calc R
N7 N 0.1952(2) 0.8012(2) 0.78706(11) 0.0543(6) Uani 1 1 d .
N8 N 0.4093(2) 0.6840(2) 0.98112(10) 0.0475(5) Uani 1 1 d .
N9 N 0.4270(2) 0.62288(19) 1.03372(10) 0.0424(5) Uani 1 1 d .
N10 N 0.57663(19) 0.89592(19) 1.07448(10) 0.0423(5) Uani 1 1 d .
N11 N 0.4634(2) 0.89558(19) 1.10608(10) 0.0441(5) Uani 1 1 d .
N12 N 0.0422(2) 0.9991(2) 1.17924(10) 0.0526(6) Uani 1 1 d .
C27 C 0.3497(3) 0.7872(3) 0.87093(17) 0.0745(10) Uani 1 1 d .
H27 H 0.4285 0.8177 0.8926 0.089 Uiso 1 1 calc R
C28 C 0.3076(4) 0.8385(3) 0.82054(19) 0.0813(12) Uani 1 1 d .
H28 H 0.3604 0.9036 0.8087 0.098 Uiso 1 1 calc R
C29 C 0.1256(2) 0.7027(2) 0.80326(12) 0.0464(6) Uani 1 1 d .
H29 H 0.0490 0.6717 0.7796 0.056 Uiso 1 1 calc R
C30 C 0.1614(2) 0.6449(2) 0.85302(12) 0.0425(5) Uani 1 1 d .
H30 H 0.1099 0.5762 0.8621 0.051 Uiso 1 1 calc R
C31 C 0.2742(2) 0.6895(2) 0.88939(12) 0.0423(5) Uani 1 1 d .
C32 C 0.3111(2) 0.6361(2) 0.94547(12) 0.0435(6) Uani 1 1 d .
H32 H 0.2618 0.5665 0.9550 0.052 Uiso 1 1 calc R
C33 C 0.5236(2) 0.6749(2) 1.07125(11) 0.0367(5) Uani 1 1 d .
C34 C 0.5533(2) 0.6219(2) 1.12945(11) 0.0396(5) Uani 1 1 d .
C35 C 0.4580(3) 0.5476(3) 1.15345(13) 0.0578(7) Uani 1 1 d .
H35 H 0.3761 0.5316 1.1332 0.069 Uiso 1 1 calc R
C36 C 0.4848(4) 0.4975(3) 1.20743(15) 0.0737(10) Uani 1 1 d .
H36 H 0.4204 0.4484 1.2235 0.088 Uiso 1 1 calc R
C37 C 0.6053(4) 0.5191(3) 1.23786(15) 0.0734(10) Uani 1 1 d .
H37 H 0.6228 0.4837 1.2739 0.088 Uiso 1 1 calc R
C38 C 0.6995(3) 0.5932(3) 1.21463(14) 0.0626(8) Uani 1 1 d .
H38 H 0.7812 0.6085 1.2351 0.075 Uiso 1 1 calc R
C39 C 0.6742(3) 0.6455(3) 1.16103(12) 0.0493(6) Uani 1 1 d .
H39 H 0.7384 0.6967 1.1460 0.059 Uiso 1 1 calc R
C40 C 0.6069(2) 0.7882(2) 1.05895(10) 0.0355(5) Uani 1 1 d .
C41 C 0.7288(2) 0.7741(2) 1.02998(11) 0.0369(5) Uani 1 1 d .
C42 C 0.7416(3) 0.6675(2) 0.98970(12) 0.0468(6) Uani 1 1 d .
H42 H 0.6721 0.6062 0.9794 0.056 Uiso 1 1 calc R
C43 C 0.8576(3) 0.6521(3) 0.96483(15) 0.0618(8) Uani 1 1 d .
H43 H 0.8657 0.5811 0.9373 0.074 Uiso 1 1 calc R
C44 C 0.9608(3) 0.7418(3) 0.98090(15) 0.0649(8) Uani 1 1 d .
H44 H 1.0392 0.7307 0.9649 0.078 Uiso 1 1 calc R
C45 C 0.9484(3) 0.8478(3) 1.02063(14) 0.0594(8) Uani 1 1 d .
H45 H 1.0185 0.9083 1.0312 0.071 Uiso 1 1 calc R
C46 C 0.8333(2) 0.8649(3) 1.04474(13) 0.0498(6) Uani 1 1 d .
H46 H 0.8253 0.9375 1.0710 0.060 Uiso 1 1 calc R
C47 C 0.3878(2) 0.9647(2) 1.08777(12) 0.0422(5) Uani 1 1 d .
H47 H 0.4077 1.0091 1.0549 0.051 Uiso 1 1 calc R
C48 C 0.2676(2) 0.9748(2) 1.11870(11) 0.0401(5) Uani 1 1 d .
C49 C 0.2084(3) 0.8806(3) 1.14748(13) 0.0501(6) Uani 1 1 d .
H49 H 0.2435 0.8080 1.1474 0.060 Uiso 1 1 calc R
C50 C 0.0972(3) 0.8961(3) 1.17619(13) 0.0555(7) Uani 1 1 d .
H50 H 0.0576 0.8315 1.1946 0.067 Uiso 1 1 calc R
C51 C 0.0998(3) 1.0880(3) 1.15078(13) 0.0517(6) Uani 1 1 d .
H51 H 0.0634 1.1602 1.1520 0.062 Uiso 1 1 calc R
C52 C 0.2097(3) 1.0798(2) 1.11970(12) 0.0457(6) Uani 1 1 d .
H52 H 0.2446 1.1441 1.0996 0.055 Uiso 1 1 calc R
B1 B 0.1266(3) 0.5896(3) 0.23480(18) 0.0583(8) Uani 1 1 d .
F1 F 0.2219(3) 0.6758(3) 0.25555(19) 0.1475(13) Uani 1 1 d .
F3 F 0.1230(4) 0.5749(4) 0.17144(15) 0.1699(15) Uani 1 1 d .
F4 F 0.0136(2) 0.6280(3) 0.24804(17) 0.1322(11) Uani 1 1 d .
F2 F 0.1341(3) 0.4833(3) 0.2539(2) 0.1697(17) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N7 Ag1 N1 136.55(9) . .
N7 Ag1 N6 110.83(9) . 1_655
N1 Ag1 N6 96.25(9) . 1_655
N7 Ag1 N12 98.83(9) . 2_577
N1 Ag1 N12 90.70(8) . 2_577
N6 Ag1 N12 126.52(9) 1_655 2_577
C3 N1 C2 117.0(2) . .
C3 N1 Ag1 127.6(2) . .
C2 N1 Ag1 115.34(19) . .
C6 N2 N3 112.2(2) . .
C7 N3 N2 113.0(2) . .
C14 N4 N5 115.0(2) . .
C21 N5 N4 112.6(2) . .
C25 N6 C24 116.1(2) . .
C25 N6 Ag1 127.54(19) . 1_455
C24 N6 Ag1 116.1(2) . 1_455
C2 C1 C5 119.0(3) . .
C2 C1 H1 120.5 . .
C5 C1 H1 120.5 . .
N1 C2 C1 123.7(3) . .
N1 C2 H2 118.2 . .
C1 C2 H2 118.2 . .
N1 C3 C4 123.2(3) . .
N1 C3 H3 118.4 . .
C4 C3 H3 118.4 . .
C3 C4 C5 119.4(3) . .
C3 C4 H4 120.3 . .
C5 C4 H4 120.3 . .
C1 C5 C4 117.6(3) . .
C1 C5 C6 121.5(3) . .
C4 C5 C6 120.9(3) . .
N2 C6 C5 119.7(3) . .
N2 C6 H6 120.1 . .
C5 C6 H6 120.1 . .
N3 C7 C8 117.9(2) . .
N3 C7 C14 123.2(2) . .
C8 C7 C14 118.9(2) . .
C13 C8 C9 119.0(3) . .
C13 C8 C7 120.8(2) . .
C9 C8 C7 120.2(2) . .
C10 C9 C8 119.8(3) . .
C10 C9 H9 120.1 . .
C8 C9 H9 120.1 . .
C11 C10 C9 120.5(3) . .
C11 C10 H10 119.8 . .
C9 C10 H10 119.8 . .
C12 C11 C10 120.0(3) . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C11 C12 C13 120.2(3) . .
C11 C12 H12 119.9 . .
C13 C12 H12 119.9 . .
C8 C13 C12 120.5(3) . .
C8 C13 H13 119.8 . .
C12 C13 H13 119.8 . .
N4 C14 C15 118.2(2) . .
N4 C14 C7 123.4(2) . .
C15 C14 C7 118.4(2) . .
C16 C15 C20 117.9(3) . .
C16 C15 C14 121.5(3) . .
C20 C15 C14 120.6(2) . .
C17 C16 C15 120.4(3) . .
C17 C16 H16 119.8 . .
C15 C16 H16 119.8 . .
C18 C17 C16 121.1(3) . .
C18 C17 H17 119.4 . .
C16 C17 H17 119.4 . .
C19 C18 C17 119.3(3) . .
C19 C18 H18 120.3 . .
C17 C18 H18 120.3 . .
C18 C19 C20 120.4(3) . .
C18 C19 H19 119.8 . .
C20 C19 H19 119.8 . .
C19 C20 C15 120.8(3) . .
C19 C20 H20 119.6 . .
C15 C20 H20 119.6 . .
N5 C21 C22 120.2(2) . .
N5 C21 H21 119.9 . .
C22 C21 H21 119.9 . .
C23 C22 C26 117.1(2) . .
C23 C22 C21 121.2(2) . .
C26 C22 C21 121.7(2) . .
C24 C23 C22 119.4(3) . .
C24 C23 H23 120.3 . .
C22 C23 H23 120.3 . .
N6 C24 C23 124.1(3) . .
N6 C24 H24 118.0 . .
C23 C24 H24 118.0 . .
N6 C25 C26 123.7(3) . .
N6 C25 H25 118.2 . .
C26 C25 H25 118.2 . .
C25 C26 C22 119.6(3) . .
C25 C26 H26 120.2 . .
C22 C26 H26 120.2 . .
C29 N7 C28 115.9(2) . .
C29 N7 Ag1 123.84(18) . .
C28 N7 Ag1 114.9(2) . .
C32 N8 N9 112.4(2) . .
C33 N9 N8 112.2(2) . .
C40 N10 N11 113.0(2) . .
C47 N11 N10 114.6(2) . .
C51 N12 C50 116.2(2) . .
C51 N12 Ag1 119.08(18) . 2_577
C50 N12 Ag1 122.05(18) . 2_577
C28 C27 C31 119.4(3) . .
C28 C27 H27 120.3 . .
C31 C27 H27 120.3 . .
N7 C28 C27 124.3(3) . .
N7 C28 H28 117.9 . .
C27 C28 H28 117.9 . .
N7 C29 C30 123.5(2) . .
N7 C29 H29 118.2 . .
C30 C29 H29 118.2 . .
C29 C30 C31 119.6(2) . .
C29 C30 H30 120.2 . .
C31 C30 H30 120.2 . .
C27 C31 C30 117.2(2) . .
C27 C31 C32 121.6(2) . .
C30 C31 C32 121.3(2) . .
N8 C32 C31 120.5(2) . .
N8 C32 H32 119.7 . .
C31 C32 H32 119.7 . .
N9 C33 C34 118.5(2) . .
N9 C33 C40 122.7(2) . .
C34 C33 C40 118.8(2) . .
C35 C34 C39 119.0(2) . .
C35 C34 C33 119.4(2) . .
C39 C34 C33 121.6(2) . .
C36 C35 C34 119.8(3) . .
C36 C35 H35 120.1 . .
C34 C35 H35 120.1 . .
C37 C36 C35 121.1(3) . .
C37 C36 H36 119.5 . .
C35 C36 H36 119.5 . .
C38 C37 C36 119.3(3) . .
C38 C37 H37 120.3 . .
C36 C37 H37 120.3 . .
C37 C38 C39 120.5(3) . .
C37 C38 H38 119.7 . .
C39 C38 H38 119.7 . .
C38 C39 C34 120.3(3) . .
C38 C39 H39 119.9 . .
C34 C39 H39 119.9 . .
N10 C40 C41 119.4(2) . .
N10 C40 C33 121.9(2) . .
C41 C40 C33 118.6(2) . .
C42 C41 C46 119.2(2) . .
C42 C41 C40 120.2(2) . .
C46 C41 C40 120.5(2) . .
C43 C42 C41 120.1(3) . .
C43 C42 H42 119.9 . .
C41 C42 H42 119.9 . .
C44 C43 C42 119.9(3) . .
C44 C43 H43 120.0 . .
C42 C43 H43 120.0 . .
C43 C44 C45 120.2(3) . .
C43 C44 H44 119.9 . .
C45 C44 H44 119.9 . .
C46 C45 C44 120.4(3) . .
C46 C45 H45 119.8 . .
C44 C45 H45 119.8 . .
C45 C46 C41 120.1(3) . .
C45 C46 H46 119.9 . .
C41 C46 H46 119.9 . .
N11 C47 C48 119.6(2) . .
N11 C47 H47 120.2 . .
C48 C47 H47 120.2 . .
C52 C48 C49 117.7(2) . .
C52 C48 C47 120.5(2) . .
C49 C48 C47 121.8(2) . .
C50 C49 C48 119.1(3) . .
C50 C49 H49 120.5 . .
C48 C49 H49 120.5 . .
N12 C50 C49 123.8(3) . .
N12 C50 H50 118.1 . .
C49 C50 H50 118.1 . .
N12 C51 C52 124.1(3) . .
N12 C51 H51 117.9 . .
C52 C51 H51 117.9 . .
C51 C52 C48 119.0(3) . .
C51 C52 H52 120.5 . .
C48 C52 H52 120.5 . .
F1 B1 F2 115.3(3) . .
F1 B1 F3 106.5(4) . .
F2 B1 F3 109.1(4) . .
F1 B1 F4 111.0(4) . .
F2 B1 F4 110.4(3) . .
F3 B1 F4 103.7(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N7 2.285(2) .
Ag1 N1 2.336(2) .
Ag1 N6 2.366(2) 1_655
Ag1 N12 2.441(2) 2_577
N1 C3 1.320(4) .
N1 C2 1.338(4) .
N2 C6 1.266(4) .
N2 N3 1.409(3) .
N3 C7 1.278(3) .
N4 C14 1.279(3) .
N4 N5 1.402(3) .
N5 C21 1.267(3) .
N6 C25 1.327(4) .
N6 C24 1.341(4) .
N6 Ag1 2.366(2) 1_455
C1 C2 1.369(4) .
C1 C5 1.379(4) .
C1 H1 0.9300 .
C2 H2 0.9300 .
C3 C4 1.380(4) .
C3 H3 0.9300 .
C4 C5 1.382(4) .
C4 H4 0.9300 .
C5 C6 1.458(4) .
C6 H6 0.9300 .
C7 C8 1.474(4) .
C7 C14 1.505(3) .
C8 C13 1.380(4) .
C8 C9 1.393(4) .
C9 C10 1.378(4) .
C9 H9 0.9300 .
C10 C11 1.376(5) .
C10 H10 0.9300 .
C11 C12 1.364(4) .
C11 H11 0.9300 .
C12 C13 1.383(4) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.477(4) .
C15 C16 1.380(4) .
C15 C20 1.389(4) .
C16 C17 1.377(5) .
C16 H16 0.9300 .
C17 C18 1.362(6) .
C17 H17 0.9300 .
C18 C19 1.361(5) .
C18 H18 0.9300 .
C19 C20 1.379(4) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.464(3) .
C21 H21 0.9300 .
C22 C23 1.379(4) .
C22 C26 1.383(4) .
C23 C24 1.366(4) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.375(4) .
C25 H25 0.9300 .
C26 H26 0.9300 .
N7 C29 1.337(4) .
N7 C28 1.338(4) .
N8 C32 1.263(3) .
N8 N9 1.406(3) .
N9 C33 1.283(3) .
N10 C40 1.280(3) .
N10 N11 1.406(3) .
N11 C47 1.260(3) .
N12 C51 1.331(4) .
N12 C50 1.341(4) .
N12 Ag1 2.441(2) 2_577
C27 C28 1.364(4) .
C27 C31 1.380(4) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 C30 1.375(4) .
C29 H29 0.9300 .
C30 C31 1.381(3) .
C30 H30 0.9300 .
C31 C32 1.462(4) .
C32 H32 0.9300 .
C33 C34 1.481(3) .
C33 C40 1.505(3) .
C34 C35 1.387(4) .
C34 C39 1.388(4) .
C35 C36 1.378(4) .
C35 H35 0.9300 .
C36 C37 1.374(5) .
C36 H36 0.9300 .
C37 C38 1.370(5) .
C37 H37 0.9300 .
C38 C39 1.381(4) .
C38 H38 0.9300 .
C39 H39 0.9300 .
C40 C41 1.476(3) .
C41 C42 1.386(3) .
C41 C46 1.388(4) .
C42 C43 1.383(4) .
C42 H42 0.9300 .
C43 C44 1.373(5) .
C43 H43 0.9300 .
C44 C45 1.374(5) .
C44 H44 0.9300 .
C45 C46 1.371(4) .
C45 H45 0.9300 .
C46 H46 0.9300 .
C47 C48 1.473(3) .
C47 H47 0.9300 .
C48 C52 1.382(4) .
C48 C49 1.386(4) .
C49 C50 1.374(4) .
C49 H49 0.9300 .
C50 H50 0.9300 .
C51 C52 1.375(4) .
C51 H51 0.9300 .
C52 H52 0.9300 .
B1 F1 1.309(4) .
B1 F2 1.313(4) .
B1 F3 1.334(5) .
B1 F4 1.350(4) .
