#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:19:53 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180500 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/69/7216983.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7216983
loop_
_publ_author_name
'Sun, Duoli'
'Lindeman, Sergey V.'
'Rathore, Rajendra'
'Kochi, Jay K.'
_publ_section_title
;
 Intramolecular (electron) delocalization between aromatic donors and
 their tethered cation--radicals. Application of electrochemical and
 structural probes†
;
_journal_issue                   9
_journal_name_full
'Journal of the Chemical Society, Perkin Transactions 2'
_journal_page_first              1585
_journal_paper_doi               10.1039/b103139m
_journal_year                    2001
_chemical_compound_source        'chemical synthesis'
_chemical_formula_moiety
;
(C33 H34 O4)^+^, (Cl6 Sb)^-^, 1.76(C H2 Cl2)
;
_chemical_formula_sum            'C34.76 H37.53 Cl9.53 O4 Sb'
_chemical_formula_weight         978.95
_chemical_name_systematic
; 
2,7-Bis(2',5'-dimethoxy-4'-methylphenyl)-9,9-dimethylfluorene 
hexachloroantimonate dichlormethane solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                103.3750(10)
_cell_angle_beta                 101.8580(10)
_cell_angle_gamma                116.0560(10)
_cell_formula_units_Z            2
_cell_length_a                   13.1454(2)
_cell_length_b                   13.4568(3)
_cell_length_c                   14.1244(3)
_cell_measurement_reflns_used    5755
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      35
_cell_measurement_theta_min      2
_cell_volume                     2044.48(8)
_computing_cell_refinement       'SAINT V4.050 (Siemens, 1989-95)'
_computing_data_collection       'SMART V4.050 (Siemens, 1989-95)'
_computing_data_reduction        'SAINT & SADABS V2.03 (Sheldrick, 2000)'
_computing_molecular_graphics    'XP V5.06 (Siemens, 1996)'
_computing_publication_material  'SHELXL-93 & XCIF V5.05 (Siemens, 1996)'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measurement_device       'Siemens/Bruker SMART 1K'
_diffrn_measurement_method
;
ω-scan, frame range 0.3 deg, hemisphere
;
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0272
_diffrn_reflns_av_sigmaI/netI    0.0492
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            32329
_diffrn_reflns_theta_max         35.60
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    1.334
_exptl_absorpt_correction_T_max  0.863
_exptl_absorpt_correction_T_min  0.793
_exptl_absorpt_correction_type   'Semi-empirical (SADABS procedure)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.590
_exptl_crystal_density_method    none
_exptl_crystal_description       prism
_exptl_crystal_F_000             982
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.1
_refine_diff_density_max         1.613
_refine_diff_density_min         -1.511
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.008
_refine_ls_goodness_of_fit_obs   1.054
_refine_ls_hydrogen_treatment
;
riding and rotating model with Uiso=1.2Uiso/eq of an adjacent atom
(1.5Uiso/eq for Me-hydrogens)
;
_refine_ls_matrix_type           full
_refine_ls_number_parameters     491
_refine_ls_number_reflns         16870
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.016
_refine_ls_restrained_S_obs      1.054
_refine_ls_R_factor_all          0.0755
_refine_ls_R_factor_obs          0.0435
_refine_ls_shift/esd_max         0.012
_refine_ls_shift/esd_mean        0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0364P)²+2.7409P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1029
_refine_ls_wR_factor_obs         0.0894
_reflns_number_observed          11957
_reflns_number_total             16881
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            b103139m.txt
_cod_data_source_block           sungsy
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+2.7409P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+2.7409P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2044.47(7)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7216983
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Sb1 Sb 0.5000 0.5000 0.0000 0.01691(5) Uani 1 d S .
Sb2 Sb -0.5000 -0.5000 -0.5000 0.02312(5) Uani 1 d S .
Cl1 Cl 0.40662(6) 0.53029(7) 0.12092(5) 0.03488(15) Uani 1 d . .
Cl2 Cl 0.57186(8) 0.69933(7) 0.01167(9) 0.0415(3) Uani 0.869(2) d P .
Cl2A Cl 0.5086(5) 0.6570(5) -0.0533(5) 0.0323(12) Uiso 0.131(2) d P .
Cl3 Cl 0.67662(7) 0.56232(8) 0.13991(6) 0.0349(2) Uani 0.869(2) d P .
Cl3A Cl 0.7031(5) 0.6264(5) 0.1160(4) 0.0339(13) Uiso 0.131(2) d P .
Cl4 Cl -0.58355(6) -0.37730(5) -0.51913(6) 0.03416(15) Uani 1 d . .
Cl5 Cl -0.69838(6) -0.66710(6) -0.57118(7) 0.0425(2) Uani 1 d . .
Cl6 Cl -0.49003(9) -0.52726(8) -0.66801(6) 0.0487(2) Uani 1 d . .
O32 O 0.29297(15) 0.97226(14) 0.35052(14) 0.0259(4) Uani 1 d . .
O35 O 0.68737(15) 0.9167(2) 0.38036(14) 0.0269(4) Uani 1 d . .
O42 O -0.2378(2) -0.0099(2) -0.0949(2) 0.0299(4) Uani 1 d . .
O45 O -0.70779(15) -0.1044(2) -0.19117(14) 0.0266(4) Uani 1 d . .
C11 C 0.0150(2) 0.5415(2) 0.1356(2) 0.0198(4) Uani 1 d . .
C12 C 0.1053(2) 0.5259(2) 0.1936(2) 0.0201(4) Uani 1 d . .
C13 C 0.2191(2) 0.6231(2) 0.2523(2) 0.0200(4) Uani 1 d . .
H13A H 0.2799(2) 0.6130(2) 0.2907(2) 0.024 Uiso 1 calc R .
C14 C 0.2452(2) 0.7389(2) 0.2551(2) 0.0195(4) Uani 1 d . .
C15 C 0.1519(2) 0.7513(2) 0.1968(2) 0.0206(4) Uani 1 d . .
H15A H 0.1684(2) 0.8280(2) 0.1987(2) 0.025 Uiso 1 calc R .
C16 C 0.0389(2) 0.6546(2) 0.1381(2) 0.0209(4) Uani 1 d . .
H16A H -0.0224(2) 0.6641(2) 0.0997(2) 0.025 Uiso 1 calc R .
C17 C 0.0540(2) 0.3945(2) 0.1790(2) 0.0216(4) Uani 1 d . .
C18 C 0.1299(2) 0.3446(2) 0.1424(2) 0.0279(5) Uani 1 d . .
H18A H 0.1378(16) 0.3566(17) 0.0779(9) 0.042 Uiso 1 calc R .
H18B H 0.0901(10) 0.2594(4) 0.1300(16) 0.042 Uiso 1 calc R .
H18C H 0.2104(7) 0.3858(13) 0.1960(7) 0.042 Uiso 1 calc R .
C19 C 0.0414(2) 0.3760(2) 0.2810(2) 0.0312(5) Uani 1 d . .
H19A H -0.0085(17) 0.4066(18) 0.3033(9) 0.047 Uiso 1 calc R .
H19B H 0.1216(3) 0.4186(16) 0.3351(5) 0.047 Uiso 1 calc R .
H19C H 0.0029(18) 0.2910(3) 0.2692(5) 0.047 Uiso 1 calc R .
C21 C -0.0924(2) 0.4278(2) 0.0779(2) 0.0190(4) Uani 1 d . .
C22 C -0.0713(2) 0.3381(2) 0.0966(2) 0.0191(4) Uani 1 d . .
C23 C -0.1591(2) 0.2195(2) 0.0442(2) 0.0201(4) Uani 1 d . .
H23A H -0.1442(2) 0.1594(2) 0.0556(2) 0.024 Uiso 1 calc R .
C24 C -0.2717(2) 0.1879(2) -0.0269(2) 0.0189(4) Uani 1 d . .
C25 C -0.2916(2) 0.2805(2) -0.0405(2) 0.0194(4) Uani 1 d . .
H25A H -0.3678(2) 0.2600(2) -0.0859(2) 0.023 Uiso 1 calc R .
C26 C -0.2036(2) 0.3989(2) 0.0102(2) 0.0196(4) Uani 1 d . .
H26A H -0.2181(2) 0.4593(2) -0.0007(2) 0.024 Uiso 1 calc R .
C31 C 0.3674(2) 0.8419(2) 0.3110(2) 0.0183(4) Uani 1 d . .
C32 C 0.3901(2) 0.9603(2) 0.3525(2) 0.0204(4) Uani 1 d . .
C33 C 0.5088(2) 1.0570(2) 0.3973(2) 0.0218(4) Uani 1 d . .
H33A H 0.5220(2) 1.1351(2) 0.4224(2) 0.026 Uiso 1 calc R .
C34 C 0.6073(2) 1.0420(2) 0.4060(2) 0.0224(4) Uani 1 d . .
C35 C 0.5854(2) 0.9239(2) 0.3680(2) 0.0215(4) Uani 1 d . .
C36 C 0.4687(2) 0.8275(2) 0.3221(2) 0.0204(4) Uani 1 d . .
H36A H 0.4565(2) 0.7497(2) 0.2974(2) 0.025 Uiso 1 calc R .
C37 C 0.3115(2) 1.0902(2) 0.3824(2) 0.0273(5) Uani 1 d . .
H37A H 0.2333(3) 1.0855(2) 0.3725(15) 0.041 Uiso 1 calc R .
H37B H 0.3511(16) 1.1319(6) 0.3405(11) 0.041 Uiso 1 calc R .
H37C H 0.3629(15) 1.1336(6) 0.4559(5) 0.041 Uiso 1 calc R .
C38 C 0.7344(2) 1.1460(2) 0.4548(2) 0.0304(5) Uani 1 d . .
H38A H 0.7329(2) 1.2194(3) 0.4805(15) 0.046 Uiso 1 calc R .
H38B H 0.7740(7) 1.1505(11) 0.4029(5) 0.046 Uiso 1 calc R .
H38C H 0.7794(6) 1.1361(9) 0.5129(10) 0.046 Uiso 1 calc R .
C39 C 0.6714(3) 0.8004(3) 0.3427(2) 0.0347(6) Uani 1 d . .
H39A H 0.7505(3) 0.8064(3) 0.3613(15) 0.052 Uiso 1 calc R .
H39B H 0.6319(18) 0.7653(8) 0.2669(3) 0.052 Uiso 1 calc R .
H39C H 0.6209(17) 0.7500(6) 0.3740(13) 0.052 Uiso 1 calc R .
C41 C -0.3711(2) 0.0643(2) -0.0847(2) 0.0201(4) Uani 1 d . .
C42 C -0.3539(2) -0.0342(2) -0.1159(2) 0.0223(4) Uani 1 d . .
C43 C -0.4533(2) -0.1498(2) -0.1679(2) 0.0249(5) Uani 1 d . .
H43A H -0.4400(2) -0.2143(2) -0.1873(2) 0.030 Uiso 1 calc R .
C44 C -0.5713(2) -0.1723(2) -0.1920(2) 0.0239(4) Uani 1 d . .
C45 C -0.5894(2) -0.0751(2) -0.1640(2) 0.0219(4) Uani 1 d . .
C46 C -0.4917(2) 0.0398(2) -0.1109(2) 0.0207(4) Uani 1 d . .
H46A H -0.5061(2) 0.1036(2) -0.0916(2) 0.025 Uiso 1 calc R .
C47 C -0.2173(3) -0.1080(2) -0.1145(2) 0.0331(6) Uani 1 d . .
H47A H -0.1301(3) -0.0777(2) -0.0913(16) 0.050 Uiso 1 calc R .
H47B H -0.2539(17) -0.1554(11) -0.1891(3) 0.050 Uiso 1 calc R .
H47C H -0.2539(17) -0.1578(11) -0.0764(14) 0.050 Uiso 1 calc R .
C48 C -0.6776(2) -0.2972(2) -0.2457(2) 0.0341(6) Uani 1 d . .
H48A H -0.6486(3) -0.3527(3) -0.2609(16) 0.051 Uiso 1 calc R .
H48B H -0.7287(11) -0.3037(6) -0.3108(9) 0.051 Uiso 1 calc R .
H48C H -0.7249(12) -0.3166(7) -0.2005(7) 0.051 Uiso 1 calc R .
C49 C -0.7315(2) -0.0091(2) -0.1680(2) 0.0299(5) Uani 1 d . .
H49A H -0.8190(2) -0.0414(3) -0.1928(15) 0.045 Uiso 1 calc R .
H49B H -0.6940(16) 0.0450(10) -0.2025(13) 0.045 Uiso 1 calc R .
H49C H -0.6977(17) 0.0343(12) -0.0926(3) 0.045 Uiso 1 calc R .
Cl1X Cl 1.04927(15) 1.11900(14) 0.86716(13) 0.0728(5) Uani 0.797(3) d P .
Cl2X Cl 1.01678(12) 0.99952(14) 0.65436(14) 0.0769(5) Uani 0.797(3) d P .
C1X C 1.0530(7) 1.1321(6) 0.7485(6) 0.092(2) Uani 0.797(3) d P .
H1XA H 1.1349(7) 1.1953(6) 0.7584(6) 0.110 Uiso 0.797(3) calc PR .
H1XB H 0.9951(7) 1.1566(6) 0.7231(6) 0.110 Uiso 0.797(3) calc PR .
Cl3X Cl 1.0618(2) 1.3936(2) 0.6583(2) 0.0606(7) Uani 0.481(4) d P 1
Cl4X Cl 1.0501(2) 1.2090(3) 0.4984(4) 0.0903(11) Uani 0.481(4) d P 1
C2X C 1.1280(9) 1.3762(8) 0.5703(8) 0.057(2) Uiso 0.481(4) d P 1
H2XA H 1.2157(9) 1.4105(8) 0.6054(8) 0.069 Uiso 0.481(4) calc PR 1
H2XB H 1.1168(9) 1.4158(8) 0.5215(8) 0.069 Uiso 0.481(4) calc PR 1
Cl3Y Cl 1.0463(3) 1.4346(3) 0.5417(3) 0.123(2) Uani 0.490(4) d P 2
Cl4Y Cl 1.0504(3) 1.2339(3) 0.5828(6) 0.180(3) Uani 0.490(4) d P 2
C2Y C 1.1243(18) 1.3845(17) 0.6177(15) 0.136(7) Uiso 0.490(4) d P 2
H2YA H 1.2050(18) 1.4120(17) 0.6113(15) 0.163 Uiso 0.490(4) calc PR 2
H2YB H 1.1368(18) 1.4211(17) 0.6916(15) 0.163 Uiso 0.490(4) calc PR 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cl1 Sb1 Cl1 180.0 . 2_665
Cl1 Sb1 Cl2A 94.50(13) . .
Cl1 Sb1 Cl2A 85.51(13) 2_665 .
Cl1 Sb1 Cl2A 85.51(13) . 2_665
Cl1 Sb1 Cl2A 94.49(13) 2_665 2_665
Cl2A Sb1 Cl2A 179.997(1) . 2_665
Cl1 Sb1 Cl2 88.70(3) . .
Cl1 Sb1 Cl2 91.30(3) 2_665 .
Cl2A Sb1 Cl2 22.92(14) . .
Cl2A Sb1 Cl2 157.08(14) 2_665 .
Cl1 Sb1 Cl2 91.30(3) . 2_665
Cl1 Sb1 Cl2 88.70(3) 2_665 2_665
Cl2A Sb1 Cl2 157.08(14) . 2_665
Cl2A Sb1 Cl2 22.92(14) 2_665 2_665
Cl2 Sb1 Cl2 180.0 . 2_665
Cl1 Sb1 Cl3A 82.85(13) . 2_665
Cl1 Sb1 Cl3A 97.15(13) 2_665 2_665
Cl2A Sb1 Cl3A 89.7(2) . 2_665
Cl2A Sb1 Cl3A 90.3(2) 2_665 2_665
Cl2 Sb1 Cl3A 110.99(14) . 2_665
Cl2 Sb1 Cl3A 69.01(14) 2_665 2_665
Cl1 Sb1 Cl3A 97.15(13) . .
Cl1 Sb1 Cl3A 82.85(13) 2_665 .
Cl2A Sb1 Cl3A 90.3(2) . .
Cl2A Sb1 Cl3A 89.7(2) 2_665 .
Cl2 Sb1 Cl3A 69.01(14) . .
Cl2 Sb1 Cl3A 110.99(14) 2_665 .
Cl3A Sb1 Cl3A 180.0 2_665 .
Cl1 Sb1 Cl3 90.71(2) . 2_665
Cl1 Sb1 Cl3 89.29(2) 2_665 2_665
Cl2A Sb1 Cl3 67.44(14) . 2_665
Cl2A Sb1 Cl3 112.56(15) 2_665 2_665
Cl2 Sb1 Cl3 89.64(3) . 2_665
Cl2 Sb1 Cl3 90.36(3) 2_665 2_665
Cl3A Sb1 Cl3 23.05(13) 2_665 2_665
Cl3A Sb1 Cl3 156.95(13) . 2_665
Cl1 Sb1 Cl3 89.29(2) . .
Cl1 Sb1 Cl3 90.71(2) 2_665 .
Cl2A Sb1 Cl3 112.56(14) . .
Cl2A Sb1 Cl3 67.44(15) 2_665 .
Cl2 Sb1 Cl3 90.36(3) . .
Cl2 Sb1 Cl3 89.64(3) 2_665 .
Cl3A Sb1 Cl3 156.95(13) 2_665 .
Cl3A Sb1 Cl3 23.05(13) . .
Cl3 Sb1 Cl3 180.0 2_665 .
Cl6 Sb2 Cl6 180.0 2_444 .
Cl6 Sb2 Cl5 90.14(3) 2_444 .
Cl6 Sb2 Cl5 89.86(3) . .
Cl6 Sb2 Cl5 89.86(3) 2_444 2_444
Cl6 Sb2 Cl5 90.14(3) . 2_444
Cl5 Sb2 Cl5 180.0 . 2_444
Cl6 Sb2 Cl4 89.74(3) 2_444 .
Cl6 Sb2 Cl4 90.26(3) . .
Cl5 Sb2 Cl4 88.97(2) . .
Cl5 Sb2 Cl4 91.03(2) 2_444 .
Cl6 Sb2 Cl4 90.26(3) 2_444 2_444
Cl6 Sb2 Cl4 89.74(3) . 2_444
Cl5 Sb2 Cl4 91.03(2) . 2_444
Cl5 Sb2 Cl4 88.97(2) 2_444 2_444
Cl4 Sb2 Cl4 180.0 . 2_444
Cl2A Cl2 Sb1 78.3(3) . .
Cl2 Cl2A Sb1 78.7(3) . .
Cl3A Cl3 Sb1 78.4(3) . .
Cl3 Cl3A Sb1 78.6(3) . .
C32 O32 C37 118.2(2) . .
C35 O35 C39 117.2(2) . .
C42 O42 C47 118.2(2) . .
C45 O45 C49 117.4(2) . .
C16 C11 C12 121.1(2) . .
C16 C11 C21 129.7(2) . .
C12 C11 C21 109.1(2) . .
C13 C12 C11 119.8(2) . .
C13 C12 C17 130.1(2) . .
C11 C12 C17 110.2(2) . .
C12 C13 C14 119.8(2) . .
C15 C14 C13 118.8(2) . .
C15 C14 C31 120.3(2) . .
C13 C14 C31 120.7(2) . .
C16 C15 C14 121.3(2) . .
C15 C16 C11 119.1(2) . .
C22 C17 C18 112.3(2) . .
C22 C17 C12 100.9(2) . .
C18 C17 C12 113.1(2) . .
C22 C17 C19 110.1(2) . .
C18 C17 C19 109.8(2) . .
C12 C17 C19 110.3(2) . .
C26 C21 C22 121.1(2) . .
C26 C21 C11 129.7(2) . .
C22 C21 C11 109.2(2) . .
C23 C22 C21 120.2(2) . .
C23 C22 C17 129.5(2) . .
C21 C22 C17 110.2(2) . .
C22 C23 C24 119.6(2) . .
C23 C24 C25 118.6(2) . .
C23 C24 C41 123.4(2) . .
C25 C24 C41 118.0(2) . .
C26 C25 C24 122.1(2) . .
C25 C26 C21 118.3(2) . .
C36 C31 C32 117.4(2) . .
C36 C31 C14 120.1(2) . .
C32 C31 C14 122.5(2) . .
O32 C32 C33 122.7(2) . .
O32 C32 C31 116.9(2) . .
C33 C32 C31 120.3(2) . .
C34 C33 C32 121.8(2) . .
C33 C34 C35 118.1(2) . .
C33 C34 C38 121.5(2) . .
C35 C34 C38 120.3(2) . .
O35 C35 C36 124.7(2) . .
O35 C35 C34 114.5(2) . .
C36 C35 C34 120.9(2) . .
C35 C36 C31 121.5(2) . .
C46 C41 C42 117.2(2) . .
C46 C41 C24 118.8(2) . .
C42 C41 C24 124.0(2) . .
O42 C42 C43 122.3(2) . .
O42 C42 C41 117.1(2) . .
C43 C42 C41 120.6(2) . .
C44 C43 C42 121.4(2) . .
C43 C44 C45 118.5(2) . .
C43 C44 C48 121.0(2) . .
C45 C44 C48 120.5(2) . .
O45 C45 C46 124.3(2) . .
O45 C45 C44 114.9(2) . .
C46 C45 C44 120.7(2) . .
C45 C46 C41 121.6(2) . .
Cl1X C1X Cl2X 112.8(3) . .
Cl3X C2X Cl4X 105.7(5) . .
Cl4Y C2Y Cl3Y 113.6(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb1 Cl1 2.3599(6) .
Sb1 Cl1 2.3599(6) 2_665
Sb1 Cl2A 2.367(5) .
Sb1 Cl2A 2.367(5) 2_665
Sb1 Cl2 2.3706(7) .
Sb1 Cl2 2.3707(7) 2_665
Sb1 Cl3A 2.372(5) 2_665
Sb1 Cl3A 2.372(5) .
Sb1 Cl3 2.3740(7) 2_665
Sb1 Cl3 2.3741(7) .
Sb2 Cl6 2.3559(8) 2_444
Sb2 Cl6 2.3560(8) .
Sb2 Cl5 2.3649(7) .
Sb2 Cl5 2.3649(7) 2_444
Sb2 Cl4 2.3839(6) .
Sb2 Cl4 2.3840(6) 2_444
Cl2 Cl2A 0.942(6) .
Cl3 Cl3A 0.948(6) .
O32 C32 1.351(3) .
O32 C37 1.437(3) .
O35 C35 1.365(3) .
O35 C39 1.435(3) .
O42 C42 1.362(3) .
O42 C47 1.438(3) .
O45 C45 1.368(3) .
O45 C49 1.431(3) .
C11 C16 1.402(3) .
C11 C12 1.422(3) .
C11 C21 1.432(3) .
C12 C13 1.380(3) .
C12 C17 1.534(3) .
C13 C14 1.429(3) .
C14 C15 1.428(3) .
C14 C31 1.464(3) .
C15 C16 1.373(3) .
C17 C22 1.533(3) .
C17 C18 1.534(3) .
C17 C19 1.546(3) .
C21 C26 1.400(3) .
C21 C22 1.420(3) .
C22 C23 1.382(3) .
C23 C24 1.422(3) .
C24 C25 1.425(3) .
C24 C41 1.471(3) .
C25 C26 1.379(3) .
C31 C36 1.411(3) .
C31 C32 1.431(3) .
C32 C33 1.399(3) .
C33 C34 1.382(3) .
C34 C35 1.427(3) .
C34 C38 1.500(3) .
C35 C36 1.382(3) .
C41 C46 1.415(3) .
C41 C42 1.427(3) .
C42 C43 1.399(3) .
C43 C44 1.391(3) .
C44 C45 1.413(3) .
C44 C48 1.505(3) .
C45 C46 1.388(3) .
Cl1X C1X 1.733(7) .
Cl2X C1X 1.754(7) .
Cl3X C2X 1.687(10) .
Cl4X C2X 1.906(10) .
Cl3Y C2Y 1.77(2) .
Cl4Y C2Y 1.70(2) .
