#------------------------------------------------------------------------------
#$Date: 2016-03-26 21:52:11 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180521 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/90/7219052.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7219052
loop_
_publ_author_name
'Zhang, Jian-Jun'
'Qi, Xiao-Xia'
'Ren, Ning'
'Xu, Su-Ling'
'Zong, Guang-Cai'
'Gao, Jie'
'geng, lina'
'Wang, Shu-Ping'
'Shi, Shikao'
_publ_section_title
;
 Lanthanide Complexes with 3, 4, 5-Triethoxybenzoic acid and
 1,10-phenanthroline: Synthesis, Crystal structures, Thermal decomposition
 mechanism and Phase transformation kinetics
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C4RA12063A
_journal_year                    2014
_chemical_formula_sum            'C102 H118 Eu2 N4 O30'
_chemical_formula_weight         2183.92
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2014-09-11 deposited with the CCDC.
2014-12-09 downloaded from the CCDC.
;
_cell_angle_alpha                83.4850(10)
_cell_angle_beta                 75.328(2)
_cell_angle_gamma                89.450(2)
_cell_formula_units_Z            1
_cell_length_a                   12.7320(11)
_cell_length_b                   14.3480(12)
_cell_length_c                   15.0480(14)
_cell_measurement_reflns_used    2443
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.665
_cell_measurement_theta_min      2.718
_cell_volume                     2641.6(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0661
_diffrn_reflns_av_sigmaI/netI    0.1400
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13550
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.72
_exptl_absorpt_coefficient_mu    1.253
_exptl_absorpt_correction_T_max  0.9174
_exptl_absorpt_correction_T_min  0.6682
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.373
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1124
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.298
_refine_diff_density_min         -1.140
_refine_diff_density_rms         0.154
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         9166
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1684
_refine_ls_R_factor_gt           0.1005
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1573P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2479
_refine_ls_wR_factor_ref         0.2903
_reflns_number_gt                4891
_reflns_number_total             9166
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ra12063a2.cif
_cod_data_source_block           131120d
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7219052
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.63132(5) 0.42157(5) 0.47327(5) 0.0608(3) Uani 1 1 d .
N1 N 0.8045(9) 0.5199(9) 0.4764(10) 0.077(3) Uani 1 1 d .
N2 N 0.8046(11) 0.4043(10) 0.3441(10) 0.086(4) Uani 1 1 d .
O1 O 0.4447(7) 0.4679(7) 0.4257(7) 0.071(2) Uani 1 1 d .
O2 O 0.5608(8) 0.3737(8) 0.3484(7) 0.084(3) Uani 1 1 d .
O3 O 0.3329(13) 0.6438(16) 0.1406(10) 0.133(5) Uani 1 1 d .
O4 O 0.2908(12) 0.5066(12) 0.0569(10) 0.135(5) Uani 1 1 d .
O5 O 0.3365(14) 0.3336(17) 0.1011(12) 0.153(6) Uani 1 1 d .
O6 O 0.4878(8) 0.3437(7) 0.5880(7) 0.082(3) Uani 1 1 d .
O7 O 0.3481(7) 0.4387(7) 0.6312(7) 0.076(3) Uani 1 1 d .
O8 O 0.0954(13) 0.2426(12) 0.8992(11) 0.146(6) Uani 1 1 d .
O9 O 0.1877(15) 0.0836(15) 0.9195(14) 0.179(8) Uani 1 1 d .
O10 O 0.3822(16) 0.0467(13) 0.8086(14) 0.181(8) Uani 1 1 d .
O11 O 0.7310(8) 0.3272(7) 0.5695(7) 0.078(3) Uani 1 1 d .
O12 O 0.6650(8) 0.2530(7) 0.4758(8) 0.084(3) Uani 1 1 d .
O13 O 0.9105(13) 0.0687(10) 0.7402(11) 0.133(5) Uani 1 1 d .
O14 O 0.8500(15) -0.0925(11) 0.6897(13) 0.147(6) Uani 1 1 d .
O15 O 0.7270(13) -0.0913(11) 0.5672(12) 0.141(5) Uani 1 1 d .
C1 C 0.4830(13) 0.4265(13) 0.3547(12) 0.085(5) Uani 1 1 d .
C2 C 0.4323(14) 0.4475(16) 0.2751(12) 0.098(6) Uani 1 1 d .
C3 C 0.4076(14) 0.5385(16) 0.2489(12) 0.103(6) Uani 1 1 d .
H3 H 0.4218 0.5875 0.2800 0.124 Uiso 1 1 calc R
C4 C 0.3616(16) 0.555(2) 0.1757(15) 0.120(7) Uani 1 1 d .
C5 C 0.3413(18) 0.483(2) 0.1293(15) 0.127(8) Uani 1 1 d .
C6 C 0.3656(18) 0.394(2) 0.1583(16) 0.125(8) Uani 1 1 d .
C7 C 0.4133(16) 0.3725(18) 0.2305(14) 0.116(7) Uani 1 1 d .
H7 H 0.4317 0.3115 0.2481 0.140 Uiso 1 1 calc R
C8 C 0.380(2) 0.721(2) 0.1680(17) 0.145(9) Uani 1 1 d .
H8A H 0.4588 0.7162 0.1516 0.175 Uiso 1 1 calc R
H8B H 0.3561 0.7208 0.2346 0.175 Uiso 1 1 calc R
C9 C 0.349(3) 0.814(2) 0.121(2) 0.203(14) Uani 1 1 d .
H9A H 0.3819 0.8654 0.1401 0.305 Uiso 1 1 calc R
H9B H 0.2714 0.8195 0.1380 0.305 Uiso 1 1 calc R
H9C H 0.3739 0.8148 0.0550 0.305 Uiso 1 1 calc R
C10 C 0.360(2) 0.510(2) -0.0340(16) 0.145(9) Uani 1 1 d .
H10A H 0.4002 0.4521 -0.0402 0.174 Uiso 1 1 calc R
H10B H 0.4115 0.5617 -0.0452 0.174 Uiso 1 1 calc R
C11 C 0.292(2) 0.522(2) -0.1043(18) 0.188(13) Uani 1 1 d .
H11A H 0.2694 0.5857 -0.1107 0.282 Uiso 1 1 calc R
H11B H 0.2290 0.4810 -0.0835 0.282 Uiso 1 1 calc R
H11C H 0.3344 0.5062 -0.1629 0.282 Uiso 1 1 calc R
C12 C 0.350(2) 0.238(2) 0.1322(19) 0.161(10) Uani 1 1 d U
H12A H 0.3172 0.2265 0.1982 0.193 Uiso 1 1 calc R
H12B H 0.4269 0.2254 0.1218 0.193 Uiso 1 1 calc R
C13 C 0.297(3) 0.172(3) 0.081(2) 0.231(17) Uani 1 1 d U
H13A H 0.2863 0.2065 0.0254 0.346 Uiso 1 1 calc R
H13B H 0.2287 0.1493 0.1200 0.346 Uiso 1 1 calc R
H13C H 0.3442 0.1207 0.0653 0.346 Uiso 1 1 calc R
C14 C 0.3998(14) 0.3644(12) 0.6393(12) 0.088(5) Uani 1 1 d .
C15 C 0.3470(15) 0.2886(13) 0.7119(14) 0.108(6) Uani 1 1 d .
C16 C 0.2474(16) 0.3055(14) 0.7687(14) 0.115(7) Uani 1 1 d .
H16 H 0.2148 0.3632 0.7616 0.138 Uiso 1 1 calc R
C17 C 0.1968(19) 0.2362(18) 0.8360(17) 0.137(8) Uani 1 1 d .
C18 C 0.245(2) 0.1512(19) 0.8474(19) 0.152(10) Uani 1 1 d .
C19 C 0.345(2) 0.1370(18) 0.7899(19) 0.152(10) Uani 1 1 d .
C20 C 0.3981(17) 0.2042(15) 0.7213(16) 0.132(8) Uani 1 1 d .
H20 H 0.4657 0.1933 0.6830 0.159 Uiso 1 1 calc R
C21 C 0.0408(19) 0.3296(18) 0.8880(18) 0.147(9) Uani 1 1 d .
H21A H 0.0359 0.3432 0.8245 0.176 Uiso 1 1 calc R
H21B H 0.0811 0.3805 0.9023 0.176 Uiso 1 1 calc R
C22 C -0.073(2) 0.321(2) 0.9535(18) 0.175(12) Uani 1 1 d .
H22A H -0.1047 0.3814 0.9571 0.262 Uiso 1 1 calc R
H22B H -0.0683 0.2942 1.0139 0.262 Uiso 1 1 calc R
H22C H -0.1174 0.2803 0.9306 0.262 Uiso 1 1 calc R
C23 C 0.188(3) -0.015(2) 0.921(2) 0.193(13) Uani 1 1 d .
H23A H 0.2617 -0.0352 0.9006 0.231 Uiso 1 1 calc R
H23B H 0.1483 -0.0319 0.8774 0.231 Uiso 1 1 calc R
C24 C 0.135(3) -0.064(3) 1.017(3) 0.26(2) Uani 1 1 d .
H24A H 0.1896 -0.0975 1.0410 0.391 Uiso 1 1 calc R
H24B H 0.0804 -0.1080 1.0126 0.391 Uiso 1 1 calc R
H24C H 0.1027 -0.0189 1.0570 0.391 Uiso 1 1 calc R
C25 C 0.494(2) 0.0322(19) 0.767(2) 0.170(11) Uani 1 1 d .
H25A H 0.5361 0.0889 0.7637 0.204 Uiso 1 1 calc R
H25B H 0.5025 0.0161 0.7045 0.204 Uiso 1 1 calc R
C26 C 0.533(3) -0.049(3) 0.826(3) 0.26(2) Uani 1 1 d .
H26A H 0.5211 -0.1075 0.8053 0.393 Uiso 1 1 calc R
H26B H 0.4933 -0.0491 0.8899 0.393 Uiso 1 1 calc R
H26C H 0.6091 -0.0402 0.8214 0.393 Uiso 1 1 calc R
C27 C 0.7148(13) 0.2533(13) 0.5376(13) 0.088(5) Uani 1 1 d .
C28 C 0.7506(15) 0.1625(13) 0.5776(14) 0.101(6) Uani 1 1 d .
C29 C 0.8136(15) 0.1619(13) 0.6396(14) 0.106(6) Uani 1 1 d .
H29 H 0.8335 0.2180 0.6568 0.127 Uiso 1 1 calc R
C30 C 0.8468(17) 0.0780(15) 0.6760(17) 0.121(7) Uani 1 1 d .
C31 C 0.8174(18) -0.0056(16) 0.6516(18) 0.128(8) Uani 1 1 d .
C32 C 0.7542(19) -0.0036(16) 0.5894(18) 0.127(7) Uani 1 1 d .
C33 C 0.7197(15) 0.0798(14) 0.5519(15) 0.113(6) Uani 1 1 d .
H33 H 0.6766 0.0802 0.5104 0.135 Uiso 1 1 calc R
C34 C 0.977(2) 0.1460(16) 0.7432(19) 0.133(8) Uani 1 1 d .
H34A H 1.0015 0.1375 0.7998 0.159 Uiso 1 1 calc R
H34B H 0.9361 0.2032 0.7433 0.159 Uiso 1 1 calc R
C35 C 1.075(2) 0.1549(19) 0.661(2) 0.166(10) Uani 1 1 d .
H35A H 1.1145 0.2121 0.6593 0.249 Uiso 1 1 calc R
H35B H 1.0516 0.1559 0.6049 0.249 Uiso 1 1 calc R
H35C H 1.1217 0.1025 0.6656 0.249 Uiso 1 1 calc R
C36 C 0.946(2) -0.1161(17) 0.623(2) 0.153(10) Uani 1 1 d .
H36A H 0.9897 -0.0594 0.5987 0.184 Uiso 1 1 calc R
H36B H 0.9240 -0.1383 0.5713 0.184 Uiso 1 1 calc R
C38 C 0.649(2) -0.0979(16) 0.515(2) 0.143(8) Uani 1 1 d .
H38A H 0.6767 -0.0677 0.4526 0.171 Uiso 1 1 calc R
H38B H 0.5828 -0.0666 0.5435 0.171 Uiso 1 1 calc R
C39 C 0.624(2) -0.2017(18) 0.513(2) 0.179(11) Uani 1 1 d .
H39A H 0.6898 -0.2361 0.5049 0.268 Uiso 1 1 calc R
H39B H 0.5914 -0.2082 0.4632 0.268 Uiso 1 1 calc R
H39C H 0.5743 -0.2257 0.5707 0.268 Uiso 1 1 calc R
C40 C 0.8047(12) 0.5769(12) 0.5390(12) 0.081(4) Uani 1 1 d .
H40 H 0.7419 0.5799 0.5861 0.097 Uiso 1 1 calc R
C41 C 0.8934(14) 0.6329(13) 0.5388(14) 0.096(5) Uani 1 1 d .
H41 H 0.8903 0.6697 0.5864 0.115 Uiso 1 1 calc R
C42 C 0.9834(14) 0.6333(13) 0.4693(14) 0.092(5) Uani 1 1 d .
H42 H 1.0425 0.6715 0.4679 0.111 Uiso 1 1 calc R
C43 C 0.9883(13) 0.5780(13) 0.4011(14) 0.092(5) Uani 1 1 d .
C44 C 0.8941(13) 0.5186(12) 0.4048(13) 0.085(5) Uani 1 1 d .
C45 C 0.8923(13) 0.4604(13) 0.3402(13) 0.088(5) Uani 1 1 d .
C46 C 0.9883(15) 0.4590(15) 0.2638(14) 0.101(5) Uani 1 1 d .
C47 C 0.9870(17) 0.3923(16) 0.2016(15) 0.111(6) Uani 1 1 d .
H47 H 1.0479 0.3863 0.1532 0.133 Uiso 1 1 calc R
C48 C 0.8976(17) 0.3368(15) 0.2117(14) 0.109(6) Uani 1 1 d .
H48 H 0.8978 0.2932 0.1704 0.131 Uiso 1 1 calc R
C49 C 0.8065(14) 0.3451(13) 0.2832(13) 0.091(5) Uani 1 1 d .
H49 H 0.7453 0.3080 0.2884 0.110 Uiso 1 1 calc R
C50 C 1.0781(15) 0.5701(15) 0.3229(15) 0.103(6) Uani 1 1 d .
H50 H 1.1391 0.6079 0.3163 0.123 Uiso 1 1 calc R
C51 C 1.0806(15) 0.5136(15) 0.2600(16) 0.104(6) Uani 1 1 d .
H51 H 1.1434 0.5096 0.2130 0.125 Uiso 1 1 calc R
C37 C 1.016(3) -0.189(2) 0.658(3) 0.224(16) Uani 1 1 d .
H37A H 1.0646 -0.1594 0.6855 0.337 Uiso 1 1 calc R
H37B H 1.0565 -0.2202 0.6072 0.337 Uiso 1 1 calc R
H37C H 0.9703 -0.2340 0.7030 0.337 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O6 73.3(3) 2_666 .
O1 Eu1 O7 79.0(3) 2_666 2_666
O6 Eu1 O7 136.0(3) . 2_666
O1 Eu1 O2 126.6(3) 2_666 .
O6 Eu1 O2 92.3(4) . .
O7 Eu1 O2 77.6(4) 2_666 .
O1 Eu1 O11 99.8(3) 2_666 .
O6 Eu1 O11 78.6(3) . .
O7 Eu1 O11 140.3(3) 2_666 .
O2 Eu1 O11 128.0(4) . .
O1 Eu1 O12 140.0(4) 2_666 .
O6 Eu1 O12 72.8(4) . .
O7 Eu1 O12 141.0(4) 2_666 .
O2 Eu1 O12 75.3(3) . .
O11 Eu1 O12 53.0(3) . .
O1 Eu1 N2 138.1(4) 2_666 .
O6 Eu1 N2 146.5(4) . .
O7 Eu1 N2 73.2(4) 2_666 .
O2 Eu1 N2 76.9(4) . .
O11 Eu1 N2 83.3(4) . .
O12 Eu1 N2 73.8(4) . .
O1 Eu1 N1 78.1(4) 2_666 .
O6 Eu1 N1 134.4(4) . .
O7 Eu1 N1 68.9(3) 2_666 .
O2 Eu1 N1 133.3(4) . .
O11 Eu1 N1 72.1(3) . .
O12 Eu1 N1 112.6(4) . .
N2 Eu1 N1 63.1(5) . .
O1 Eu1 O1 76.7(3) 2_666 .
O6 Eu1 O1 72.8(3) . .
O7 Eu1 O1 68.0(3) 2_666 .
O2 Eu1 O1 50.1(3) . .
O11 Eu1 O1 151.0(3) . .
O12 Eu1 O1 112.1(3) . .
N2 Eu1 O1 118.8(4) . .
N1 Eu1 O1 133.2(3) . .
O1 Eu1 Eu1 41.5(2) 2_666 2_666
O6 Eu1 Eu1 68.2(2) . 2_666
O7 Eu1 Eu1 68.4(2) 2_666 2_666
O2 Eu1 Eu1 85.2(2) . 2_666
O11 Eu1 Eu1 134.1(3) . 2_666
O12 Eu1 Eu1 135.2(2) . 2_666
N2 Eu1 Eu1 140.2(3) . 2_666
N1 Eu1 Eu1 110.1(3) . 2_666
O1 Eu1 Eu1 35.2(2) . 2_666
C40 N1 C44 118.3(14) . .
C40 N1 Eu1 123.2(10) . .
C44 N1 Eu1 118.2(11) . .
C49 N2 C45 121.9(16) . .
C49 N2 Eu1 120.5(12) . .
C45 N2 Eu1 117.7(12) . .
C1 O1 Eu1 164.3(10) . 2_666
C1 O1 Eu1 85.8(8) . .
Eu1 O1 Eu1 103.3(3) 2_666 .
C1 O2 Eu1 99.0(9) . .
C4 O3 C8 115.6(18) . .
C5 O4 C10 115.6(16) . .
C6 O5 C12 111(2) . .
C14 O6 Eu1 137.6(10) . .
C14 O7 Eu1 136.9(10) . 2_666
C17 O8 C21 115.1(16) . .
C23 O9 C18 127(2) . .
C19 O10 C25 115.7(19) . .
C27 O11 Eu1 92.6(8) . .
C27 O12 Eu1 92.5(10) . .
C30 O13 C34 118.0(16) . .
C31 O14 C36 104.9(19) . .
C32 O15 C38 120.1(16) . .
O2 C1 O1 122.7(14) . .
O2 C1 C2 120.3(16) . .
O1 C1 C2 117.0(15) . .
C3 C2 C7 122.9(17) . .
C3 C2 C1 119.8(17) . .
C7 C2 C1 117.2(19) . .
C4 C3 C2 118(2) . .
C4 C3 H3 121.0 . .
C2 C3 H3 121.0 . .
C5 C4 C3 121(2) . .
C5 C4 O3 114(2) . .
C3 C4 O3 124(2) . .
C6 C5 C4 119(2) . .
C6 C5 O4 124(3) . .
C4 C5 O4 117(3) . .
C5 C6 C7 123(2) . .
C5 C6 O5 108(2) . .
C7 C6 O5 129(3) . .
C6 C7 C2 116(2) . .
C6 C7 H7 122.1 . .
C2 C7 H7 122.1 . .
O3 C8 C9 111(2) . .
O3 C8 H8A 109.5 . .
C9 C8 H8A 109.5 . .
O3 C8 H8B 109.5 . .
C9 C8 H8B 109.5 . .
H8A C8 H8B 108.1 . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
O4 C10 C11 110(2) . .
O4 C10 H10A 109.7 . .
C11 C10 H10A 109.7 . .
O4 C10 H10B 109.7 . .
C11 C10 H10B 109.7 . .
H10A C10 H10B 108.2 . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
O5 C12 C13 111(3) . .
O5 C12 H12A 109.5 . .
C13 C12 H12A 109.5 . .
O5 C12 H12B 109.5 . .
C13 C12 H12B 109.5 . .
H12A C12 H12B 108.1 . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
O6 C14 O7 127.0(15) . .
O6 C14 C15 115.2(16) . .
O7 C14 C15 117.5(16) . .
C16 C15 C20 121.8(17) . .
C16 C15 C14 118.2(16) . .
C20 C15 C14 120.0(18) . .
C17 C16 C15 119.2(19) . .
C17 C16 H16 120.4 . .
C15 C16 H16 120.4 . .
C16 C17 C18 121(2) . .
C16 C17 O8 126(2) . .
C18 C17 O8 113(2) . .
C19 C18 C17 119(2) . .
C19 C18 O9 124(2) . .
C17 C18 O9 117(2) . .
C18 C19 C20 123(2) . .
C18 C19 O10 112(2) . .
C20 C19 O10 125(2) . .
C19 C20 C15 117(2) . .
C19 C20 H20 121.5 . .
C15 C20 H20 121.5 . .
O8 C21 C22 108.4(19) . .
O8 C21 H21A 110.0 . .
C22 C21 H21A 110.0 . .
O8 C21 H21B 110.0 . .
C22 C21 H21B 110.0 . .
H21A C21 H21B 108.4 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
O9 C23 C24 112(3) . .
O9 C23 H23A 109.2 . .
C24 C23 H23A 109.2 . .
O9 C23 H23B 109.2 . .
C24 C23 H23B 109.2 . .
H23A C23 H23B 107.9 . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
O10 C25 C26 108(2) . .
O10 C25 H25A 110.1 . .
C26 C25 H25A 110.1 . .
O10 C25 H25B 110.1 . .
C26 C25 H25B 110.1 . .
H25A C25 H25B 108.4 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
O11 C27 O12 121.8(14) . .
O11 C27 C28 119.1(15) . .
O12 C27 C28 119.0(17) . .
C29 C28 C33 120.8(16) . .
C29 C28 C27 119.9(17) . .
C33 C28 C27 119.3(16) . .
C30 C29 C28 119.7(18) . .
C30 C29 H29 120.1 . .
C28 C29 H29 120.1 . .
C29 C30 C31 120.9(19) . .
C29 C30 O13 125(2) . .
C31 C30 O13 114.4(17) . .
C30 C31 C32 118.6(19) . .
C30 C31 O14 121.3(19) . .
C32 C31 O14 120(2) . .
C31 C32 C33 122(2) . .
C31 C32 O15 115.9(19) . .
C33 C32 O15 123(2) . .
C32 C33 C28 118.5(19) . .
C32 C33 H33 120.8 . .
C28 C33 H33 120.8 . .
O13 C34 C35 110(2) . .
O13 C34 H34A 109.6 . .
C35 C34 H34A 109.6 . .
O13 C34 H34B 109.6 . .
C35 C34 H34B 109.6 . .
H34A C34 H34B 108.1 . .
C34 C35 H35A 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C34 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
O14 C36 C37 115(3) . .
O14 C36 H36A 108.5 . .
C37 C36 H36A 108.5 . .
O14 C36 H36B 108.5 . .
C37 C36 H36B 108.5 . .
H36A C36 H36B 107.5 . .
O15 C38 C39 109(2) . .
O15 C38 H38A 110.0 . .
C39 C38 H38A 110.0 . .
O15 C38 H38B 110.0 . .
C39 C38 H38B 110.0 . .
H38A C38 H38B 108.3 . .
C38 C39 H39A 109.5 . .
C38 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C38 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
N1 C40 C41 124.0(17) . .
N1 C40 H40 118.0 . .
C41 C40 H40 118.0 . .
C42 C41 C40 119.4(19) . .
C42 C41 H41 120.3 . .
C40 C41 H41 120.3 . .
C41 C42 C43 120.0(18) . .
C41 C42 H42 120.0 . .
C43 C42 H42 120.0 . .
C42 C43 C50 126.8(19) . .
C42 C43 C44 119.0(17) . .
C50 C43 C44 114.2(19) . .
C45 C44 N1 117.8(16) . .
C45 C44 C43 122.9(18) . .
N1 C44 C43 119.3(17) . .
C44 C45 N2 122.8(17) . .
C44 C45 C46 117.7(18) . .
N2 C45 C46 119.5(18) . .
C51 C46 C47 123(2) . .
C51 C46 C45 120(2) . .
C47 C46 C45 116.1(19) . .
C48 C47 C46 121(2) . .
C48 C47 H47 119.6 . .
C46 C47 H47 119.6 . .
C47 C48 C49 120(2) . .
C47 C48 H48 119.9 . .
C49 C48 H48 119.9 . .
N2 C49 C48 121.4(18) . .
N2 C49 H49 119.3 . .
C48 C49 H49 119.3 . .
C51 C50 C43 125(2) . .
C51 C50 H50 117.6 . .
C43 C50 H50 117.6 . .
C50 C51 C46 120(2) . .
C50 C51 H51 120.1 . .
C46 C51 H51 120.1 . .
C36 C37 H37A 109.5 . .
C36 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C36 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.353(10) 2_666
Eu1 O6 2.360(11) .
Eu1 O7 2.377(9) 2_666
Eu1 O2 2.442(9) .
Eu1 O11 2.449(9) .
Eu1 O12 2.449(10) .
Eu1 N2 2.575(14) .
Eu1 N1 2.642(13) .
Eu1 O1 2.706(9) .
Eu1 Eu1 3.9746(13) 2_666
N1 C40 1.317(19) .
N1 C44 1.36(2) .
N2 C49 1.31(2) .
N2 C45 1.37(2) .
O1 C1 1.267(17) .
O1 Eu1 2.353(10) 2_666
O2 C1 1.233(17) .
O3 C4 1.41(3) .
O3 C8 1.42(3) .
O4 C5 1.41(2) .
O4 C10 1.42(2) .
O5 C6 1.40(3) .
O5 C12 1.42(3) .
O6 C14 1.243(19) .
O7 C14 1.258(18) .
O7 Eu1 2.377(9) 2_666
O8 C17 1.40(3) .
O8 C21 1.44(3) .
O9 C23 1.41(3) .
O9 C18 1.42(3) .
O10 C19 1.40(3) .
O10 C25 1.42(3) .
O11 C27 1.251(19) .
O12 C27 1.252(18) .
O13 C30 1.41(2) .
O13 C34 1.42(2) .
O14 C31 1.42(2) .
O14 C36 1.44(3) .
O15 C32 1.41(2) .
O15 C38 1.43(2) .
C1 C2 1.50(2) .
C2 C3 1.38(3) .
C2 C7 1.38(3) .
C3 C4 1.37(2) .
C3 H3 0.9300 .
C4 C5 1.37(3) .
C5 C6 1.36(3) .
C6 C7 1.38(3) .
C7 H7 0.9300 .
C8 C9 1.53(3) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 C11 1.52(3) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 C13 1.54(4) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 C15 1.48(2) .
C15 C16 1.37(2) .
C15 C20 1.38(2) .
C16 C17 1.37(3) .
C16 H16 0.9300 .
C17 C18 1.38(3) .
C18 C19 1.37(3) .
C19 C20 1.37(3) .
C20 H20 0.9300 .
C21 C22 1.53(3) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C24 1.53(4) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 C26 1.54(4) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
C27 C28 1.49(2) .
C28 C29 1.37(2) .
C28 C33 1.38(2) .
C29 C30 1.37(2) .
C29 H29 0.9300 .
C30 C31 1.38(3) .
C31 C32 1.38(3) .
C32 C33 1.38(3) .
C33 H33 0.9300 .
C34 C35 1.51(3) .
C34 H34A 0.9700 .
C34 H34B 0.9700 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 C37 1.50(3) .
C36 H36A 0.9700 .
C36 H36B 0.9700 .
C38 C39 1.53(3) .
C38 H38A 0.9700 .
C38 H38B 0.9700 .
C39 H39A 0.9600 .
C39 H39B 0.9600 .
C39 H39C 0.9600 .
C40 C41 1.39(2) .
C40 H40 0.9300 .
C41 C42 1.34(2) .
C41 H41 0.9300 .
C42 C43 1.36(2) .
C42 H42 0.9300 .
C43 C50 1.43(2) .
C43 C44 1.46(2) .
C44 C45 1.35(2) .
C45 C46 1.45(2) .
C46 C51 1.40(3) .
C46 C47 1.42(3) .
C47 C48 1.36(3) .
C47 H47 0.9300 .
C48 C49 1.38(2) .
C48 H48 0.9300 .
C49 H49 0.9300 .
C50 C51 1.31(3) .
C50 H50 0.9300 .
C51 H51 0.9300 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Eu1 N1 C40 15.0(11) 2_666 .
O6 Eu1 N1 C40 -36.9(13) . .
O7 Eu1 N1 C40 97.7(12) 2_666 .
O2 Eu1 N1 C40 144.7(11) . .
O11 Eu1 N1 C40 -89.5(12) . .
O12 Eu1 N1 C40 -124.5(11) . .
N2 Eu1 N1 C40 178.9(13) . .
O1 Eu1 N1 C40 73.6(13) . .
Eu1 Eu1 N1 C40 41.9(12) 2_666 .
O1 Eu1 N1 C44 -158.2(11) 2_666 .
O6 Eu1 N1 C44 149.9(9) . .
O7 Eu1 N1 C44 -75.6(10) 2_666 .
O2 Eu1 N1 C44 -28.5(12) . .
O11 Eu1 N1 C44 97.2(10) . .
O12 Eu1 N1 C44 62.3(11) . .
N2 Eu1 N1 C44 5.7(10) . .
O1 Eu1 N1 C44 -99.6(11) . .
Eu1 Eu1 N1 C44 -131.4(10) 2_666 .
O1 Eu1 N2 C49 -159.5(11) 2_666 .
O6 Eu1 N2 C49 45.6(15) . .
O7 Eu1 N2 C49 -109.1(12) 2_666 .
O2 Eu1 N2 C49 -28.4(12) . .
O11 Eu1 N2 C49 103.2(12) . .
O12 Eu1 N2 C49 49.8(12) . .
N1 Eu1 N2 C49 176.5(13) . .
O1 Eu1 N2 C49 -56.9(13) . .
Eu1 Eu1 N2 C49 -94.0(13) 2_666 .
O1 Eu1 N2 C45 18.8(13) 2_666 .
O6 Eu1 N2 C45 -136.1(11) . .
O7 Eu1 N2 C45 69.2(11) 2_666 .
O2 Eu1 N2 C45 150.0(12) . .
O11 Eu1 N2 C45 -78.4(11) . .
O12 Eu1 N2 C45 -131.8(11) . .
N1 Eu1 N2 C45 -5.2(10) . .
O1 Eu1 N2 C45 121.4(10) . .
Eu1 Eu1 N2 C45 84.4(11) 2_666 .
O1 Eu1 O1 C1 167.0(11) 2_666 .
O6 Eu1 O1 C1 -116.6(10) . .
O7 Eu1 O1 C1 83.7(10) 2_666 .
O2 Eu1 O1 C1 -8.3(10) . .
O11 Eu1 O1 C1 -106.8(11) . .
O12 Eu1 O1 C1 -54.0(10) . .
N2 Eu1 O1 C1 29.0(11) . .
N1 Eu1 O1 C1 107.9(10) . .
Eu1 Eu1 O1 C1 167.0(11) 2_666 .
O1 Eu1 O1 Eu1 0.0 2_666 2_666
O6 Eu1 O1 Eu1 76.4(4) . 2_666
O7 Eu1 O1 Eu1 -83.3(4) 2_666 2_666
O2 Eu1 O1 Eu1 -175.3(6) . 2_666
O11 Eu1 O1 Eu1 86.2(7) . 2_666
O12 Eu1 O1 Eu1 138.9(4) . 2_666
N2 Eu1 O1 Eu1 -138.0(5) . 2_666
N1 Eu1 O1 Eu1 -59.1(6) . 2_666
O1 Eu1 O2 C1 2.9(12) 2_666 .
O6 Eu1 O2 C1 73.7(11) . .
O7 Eu1 O2 C1 -63.0(11) 2_666 .
O11 Eu1 O2 C1 151.1(10) . .
O12 Eu1 O2 C1 145.2(11) . .
N2 Eu1 O2 C1 -138.3(11) . .
N1 Eu1 O2 C1 -107.4(11) . .
O1 Eu1 O2 C1 8.6(10) . .
Eu1 Eu1 O2 C1 5.9(10) 2_666 .
O1 Eu1 O6 C14 28.6(15) 2_666 .
O7 Eu1 O6 C14 -24.6(18) 2_666 .
O2 Eu1 O6 C14 -99.0(16) . .
O11 Eu1 O6 C14 132.6(16) . .
O12 Eu1 O6 C14 -172.8(16) . .
N2 Eu1 O6 C14 -168.6(14) . .
N1 Eu1 O6 C14 82.1(16) . .
O1 Eu1 O6 C14 -52.2(15) . .
Eu1 Eu1 O6 C14 -15.1(15) 2_666 .
O1 Eu1 O11 C27 146.3(10) 2_666 .
O6 Eu1 O11 C27 75.7(10) . .
O7 Eu1 O11 C27 -129.2(10) 2_666 .
O2 Eu1 O11 C27 -8.2(11) . .
O12 Eu1 O11 C27 -1.1(10) . .
N2 Eu1 O11 C27 -75.9(10) . .
N1 Eu1 O11 C27 -139.7(11) . .
O1 Eu1 O11 C27 66.2(12) . .
Eu1 Eu1 O11 C27 119.4(10) 2_666 .
O1 Eu1 O12 C27 -54.4(12) 2_666 .
O6 Eu1 O12 C27 -87.4(10) . .
O7 Eu1 O12 C27 128.1(10) 2_666 .
O2 Eu1 O12 C27 175.3(11) . .
O11 Eu1 O12 C27 1.1(10) . .
N2 Eu1 O12 C27 95.0(11) . .
N1 Eu1 O12 C27 44.2(11) . .
O1 Eu1 O12 C27 -150.0(10) . .
Eu1 Eu1 O12 C27 -117.5(10) 2_666 .
Eu1 O2 C1 O1 -16.9(19) . .
Eu1 O2 C1 C2 160.5(15) . .
Eu1 O1 C1 O2 141(3) 2_666 .
Eu1 O1 C1 O2 15.1(17) . .
Eu1 O1 C1 C2 -36(5) 2_666 .
Eu1 O1 C1 C2 -162.4(16) . .
O2 C1 C2 C3 -134.7(19) . .
O1 C1 C2 C3 43(2) . .
O2 C1 C2 C7 45(3) . .
O1 C1 C2 C7 -137.7(18) . .
C7 C2 C3 C4 0(3) . .
C1 C2 C3 C4 179.8(17) . .
C2 C3 C4 C5 0(3) . .
C2 C3 C4 O3 -179.4(18) . .
C8 O3 C4 C5 -162(2) . .
C8 O3 C4 C3 17(3) . .
C3 C4 C5 C6 1(3) . .
O3 C4 C5 C6 -180(2) . .
C3 C4 C5 O4 178.1(18) . .
O3 C4 C5 O4 -3(3) . .
C10 O4 C5 C6 -79(3) . .
C10 O4 C5 C4 104(3) . .
C4 C5 C6 C7 -2(4) . .
O4 C5 C6 C7 -179(2) . .
C4 C5 C6 O5 179(2) . .
O4 C5 C6 O5 3(3) . .
C12 O5 C6 C5 -175(2) . .
C12 O5 C6 C7 7(3) . .
C5 C6 C7 C2 2(3) . .
O5 C6 C7 C2 -180(2) . .
C3 C2 C7 C6 -1(3) . .
C1 C2 C7 C6 179.3(18) . .
C4 O3 C8 C9 176.4(19) . .
C5 O4 C10 C11 172(3) . .
C6 O5 C12 C13 169(2) . .
Eu1 O6 C14 O7 16(3) . .
Eu1 O6 C14 C15 -170.3(12) . .
Eu1 O7 C14 O6 1(3) 2_666 .
Eu1 O7 C14 C15 -172.3(12) 2_666 .
O6 C14 C15 C16 -177.5(18) . .
O7 C14 C15 C16 -3(3) . .
O6 C14 C15 C20 3(3) . .
O7 C14 C15 C20 177.3(19) . .
C20 C15 C16 C17 -1(4) . .
C14 C15 C16 C17 180(2) . .
C15 C16 C17 C18 1(4) . .
C15 C16 C17 O8 -180(2) . .
C21 O8 C17 C16 2(4) . .
C21 O8 C17 C18 -178(3) . .
C16 C17 C18 C19 0(5) . .
O8 C17 C18 C19 -180(3) . .
C16 C17 C18 O9 179(2) . .
O8 C17 C18 O9 0(4) . .
C23 O9 C18 C19 -33(5) . .
C23 O9 C18 C17 147(3) . .
C17 C18 C19 C20 0(5) . .
O9 C18 C19 C20 -180(3) . .
C17 C18 C19 O10 -179(3) . .
O9 C18 C19 O10 2(5) . .
C25 O10 C19 C18 -167(3) . .
C25 O10 C19 C20 14(4) . .
C18 C19 C20 C15 0(5) . .
O10 C19 C20 C15 178(3) . .
C16 C15 C20 C19 1(4) . .
C14 C15 C20 C19 -180(2) . .
C17 O8 C21 C22 173(2) . .
C18 O9 C23 C24 168(3) . .
C19 O10 C25 C26 155(3) . .
Eu1 O11 C27 O12 2.1(18) . .
Eu1 O11 C27 C28 -174.7(15) . .
Eu1 O12 C27 O11 -2.1(18) . .
Eu1 O12 C27 C28 174.7(15) . .
O11 C27 C28 C29 -9(3) . .
O12 C27 C28 C29 174.3(18) . .
O11 C27 C28 C33 171.0(18) . .
O12 C27 C28 C33 -6(3) . .
C33 C28 C29 C30 0(3) . .
C27 C28 C29 C30 -180(2) . .
C28 C29 C30 C31 0(4) . .
C28 C29 C30 O13 -180(2) . .
C34 O13 C30 C29 -24(3) . .
C34 O13 C30 C31 157(2) . .
C29 C30 C31 C32 0(4) . .
O13 C30 C31 C32 180(2) . .
C29 C30 C31 O14 -179(2) . .
O13 C30 C31 O14 0(3) . .
C36 O14 C31 C30 -96(3) . .
C36 O14 C31 C32 84(3) . .
C30 C31 C32 C33 0(4) . .
O14 C31 C32 C33 179(2) . .
C30 C31 C32 O15 180(2) . .
O14 C31 C32 O15 -1(4) . .
C38 O15 C32 C31 170(2) . .
C38 O15 C32 C33 -10(4) . .
C31 C32 C33 C28 0(4) . .
O15 C32 C33 C28 -180(2) . .
C29 C28 C33 C32 -1(3) . .
C27 C28 C33 C32 180(2) . .
C30 O13 C34 C35 -74(2) . .
C31 O14 C36 C37 162(3) . .
C32 O15 C38 C39 -172(2) . .
C44 N1 C40 C41 -3(2) . .
Eu1 N1 C40 C41 -176.5(12) . .
N1 C40 C41 C42 3(3) . .
C40 C41 C42 C43 -1(3) . .
C41 C42 C43 C50 -179.6(16) . .
C41 C42 C43 C44 0(2) . .
C40 N1 C44 C45 -179.3(14) . .
Eu1 N1 C44 C45 -5.7(18) . .
C40 N1 C44 C43 2(2) . .
Eu1 N1 C44 C43 175.3(10) . .
C42 C43 C44 C45 -179.2(16) . .
C50 C43 C44 C45 1(2) . .
C42 C43 C44 N1 0(2) . .
C50 C43 C44 N1 179.5(14) . .
N1 C44 C45 N2 1(2) . .
C43 C44 C45 N2 179.5(14) . .
N1 C44 C45 C46 -179.9(14) . .
C43 C44 C45 C46 -1(2) . .
C49 N2 C45 C44 -176.7(16) . .
Eu1 N2 C45 C44 5(2) . .
C49 N2 C45 C46 4(2) . .
Eu1 N2 C45 C46 -174.5(11) . .
C44 C45 C46 C51 3(3) . .
N2 C45 C46 C51 -177.9(16) . .
C44 C45 C46 C47 175.3(16) . .
N2 C45 C46 C47 -5(2) . .
C51 C46 C47 C48 175.8(19) . .
C45 C46 C47 C48 3(3) . .
C46 C47 C48 C49 0(3) . .
C45 N2 C49 C48 0(3) . .
Eu1 N2 C49 C48 178.0(13) . .
C47 C48 C49 N2 -2(3) . .
C42 C43 C50 C51 177.8(19) . .
C44 C43 C50 C51 -2(3) . .
C43 C50 C51 C46 4(3) . .
C47 C46 C51 C50 -176.1(19) . .
C45 C46 C51 C50 -4(3) . .
