#------------------------------------------------------------------------------
#$Date: 2016-05-06 02:47:53 +0200 (vie 06 de may de 2016) $
#$Revision: 182639 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/45/7224533.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7224533
loop_
_publ_author_name
'Zhu, Yu'
'Fang, Wei-Hui'
'Wei, Qi'
'Yang, Guo-Yu'
_publ_section_title
;
 Extended hybrid architectures based on tetra-CoIIsandwiched
 polyoxotungstates
;
_journal_issue                   15
_journal_name_full               CrystEngComm
_journal_page_first              2712
_journal_paper_doi               10.1039/C6CE00374E
_journal_volume                  18
_journal_year                    2016
_chemical_formula_sum            'C30 H108 Co10 N20 O72 Si2 W18'
_chemical_formula_weight         5856.14
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2013-05-24 deposited with the CCDC.
2016-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                95.690(2)
_cell_angle_beta                 109.650(2)
_cell_angle_gamma                92.242(2)
_cell_formula_units_Z            1
_cell_length_a                   12.0203(2)
_cell_length_b                   14.7565(4)
_cell_length_c                   16.2297(4)
_cell_measurement_reflns_used    15412
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.3909
_cell_measurement_theta_min      2.9236
_cell_volume                     2689.70(11)
_computing_cell_refinement
'CrysAlisPro, Agilent Technologies,Version 1.171.36.20(release 27-06-2012 CrysAlis171 .NET)'
_computing_data_collection
'CrysAlisPro, Agilent Technologies,Version 1.171.36.20(release 27-06-2012 CrysAlis171 .NET)'
_computing_data_reduction
'CrysAlisPro, Agilent Technologies,Version 1.171.36.20(release 27-06-2012 CrysAlis171 .NET)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.3503
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0396
_diffrn_reflns_av_sigmaI/netI    0.0446
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            23690
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.93
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    20.771
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.45487
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    3.615
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2634
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.997
_refine_diff_density_min         -3.440
_refine_diff_density_rms         0.259
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     649
_refine_ls_number_reflns         9469
_refine_ls_number_restraints     23
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0365
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0297P)²+13.4698P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0714
_refine_ls_wR_factor_ref         0.0756
_reflns_number_gt                8307
_reflns_number_total             9469
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6ce00374e2.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7224532--7224534.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7224533
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.47375(3) 0.91497(3) 0.23958(2) 0.01598(9) Uani 1 1 d .
W2 W 0.01265(3) 0.69316(2) 0.01934(2) 0.01633(9) Uani 1 1 d .
W3 W 0.31305(3) 0.69297(3) 0.11476(2) 0.01645(9) Uani 1 1 d .
W4 W 0.27819(3) 0.78020(3) 0.32729(2) 0.01879(9) Uani 1 1 d .
W5 W 0.35179(3) 1.02344(2) 0.05808(2) 0.01318(9) Uani 1 1 d .
W6 W 0.18934(3) 0.80329(2) -0.06848(2) 0.01417(9) Uani 1 1 d .
W7 W 0.31941(3) 1.10465(3) 0.24708(2) 0.01639(9) Uani 1 1 d .
W8 W -0.02195(3) 0.77785(3) 0.22975(2) 0.01761(9) Uani 1 1 d .
W9 W 0.13121(3) 0.97215(3) 0.33612(2) 0.01742(9) Uani 1 1 d .
Si1 Si 0.15595(18) 0.89830(15) 0.13179(15) 0.0098(5) Uani 1 1 d .
Co1 Co 0.47510(10) 0.83089(9) 0.04324(8) 0.0201(3) Uani 1 1 d .
Co2 Co 0.09499(10) 1.01927(8) -0.12984(8) 0.0153(3) Uani 1 1 d .
Co3 Co 0.06745(10) 1.09100(8) 0.05232(8) 0.0147(3) Uani 1 1 d .
Co4 Co 0.25541(11) 1.06472(11) 0.57079(9) 0.0285(3) Uani 1 1 d .
Co5 Co -0.01771(13) 0.58401(10) -0.16761(10) 0.0342(3) Uani 1 1 d .
O1 O 0.2813(5) 0.9607(4) 0.1574(4) 0.0143(13) Uani 1 1 d .
O2 O 0.3101(5) 0.7243(4) 0.0025(4) 0.0160(13) Uani 1 1 d .
O3 O 0.2020(5) 1.0490(4) 0.0035(4) 0.0158(13) Uani 1 1 d .
O4 O 0.3171(5) 0.8976(4) -0.0051(4) 0.0145(13) Uani 1 1 d .
O5 O -0.0787(5) 0.7806(4) -0.0193(4) 0.0175(13) Uani 1 1 d .
O6 O 0.4891(5) 0.9618(4) 0.1379(4) 0.0179(14) Uani 1 1 d .
O7 O 0.0205(5) 1.0211(4) 0.2546(4) 0.0200(14) Uani 1 1 d .
O8 O 0.1784(5) 1.1305(4) 0.1776(4) 0.0201(14) Uani 1 1 d .
O9 O 0.4631(5) 1.0320(4) 0.2889(4) 0.0209(14) Uani 1 1 d .
O10 O 0.0784(5) 0.7038(4) -0.0823(4) 0.0193(14) Uani 1 1 d .
O11 O 0.0826(5) 0.8882(4) -0.0910(4) 0.0163(13) Uani 1 1 d .
O12 O 0.2602(5) 1.0396(4) 0.3221(4) 0.0205(14) Uani 1 1 d .
O13 O 0.4014(5) 0.8603(4) 0.3090(4) 0.0197(14) Uani 1 1 d .
O14 O 0.0442(5) 0.9551(4) 0.0791(4) 0.0166(13) Uani 1 1 d .
O15 O 0.1659(5) 0.6281(4) 0.0635(4) 0.0212(14) Uani 1 1 d .
O16 O 0.3844(5) 1.1182(4) 0.1519(4) 0.0180(14) Uani 1 1 d .
O17 O 0.1418(5) 0.8685(4) 0.2229(4) 0.0165(13) Uani 1 1 d .
O18 O -0.1103(5) 0.8505(4) 0.1572(4) 0.0200(14) Uani 1 1 d .
O19 O 0.0192(5) 0.8688(4) 0.3293(4) 0.0203(14) Uani 1 1 d .
O20 O -0.0002(5) 0.6983(4) 0.1311(4) 0.0197(14) Uani 1 1 d .
O21 O 0.1326(5) 1.0294(5) 0.4357(4) 0.0226(15) Uani 1 1 d .
O22 O 0.4234(5) 0.8028(4) 0.1575(4) 0.0135(13) Uani 1 1 d .
O23 O 0.6216(5) 0.8993(4) 0.2944(4) 0.0213(14) Uani 1 1 d .
O24 O -0.0729(5) 0.5946(4) -0.0383(4) 0.0253(15) Uani 1 1 d .
O25 O 0.4242(5) 1.0733(4) -0.0035(4) 0.0216(14) Uani 1 1 d .
O26 O 0.1291(5) 0.7227(5) 0.3031(4) 0.0238(15) Uani 1 1 d .
O27 O 0.2487(5) 0.8820(5) 0.3916(4) 0.0230(15) Uani 1 1 d .
O28 O 0.1612(5) 0.8050(4) 0.0695(4) 0.0149(13) Uani 1 1 d .
O29 O 0.2188(5) 0.7839(5) -0.1655(4) 0.0258(16) Uani 1 1 d .
O30 O 0.4089(6) 0.6086(5) 0.1285(4) 0.0274(16) Uani 1 1 d .
O31 O -0.1237(5) 0.7083(5) 0.2525(4) 0.0278(16) Uani 1 1 d .
O32 O 0.3768(6) 1.2054(5) 0.3142(4) 0.0288(16) Uani 1 1 d .
O33 O 0.3642(6) 0.7227(5) 0.4096(4) 0.0322(17) Uani 1 1 d .
O34 O 0.2892(5) 0.7109(4) 0.2234(4) 0.0205(14) Uani 1 1 d .
OW1 O -0.031(2) 0.7844(13) -0.3164(19) 0.258(14) Uani 1 1 d .
OW2 O 0.2419(6) 0.9874(5) -0.1787(4) 0.0289(16) Uani 1 1 d .
N1 N 0.1829(9) 1.1926(8) 0.5776(7) 0.053(3) Uani 1 1 d .
H1C H 0.1125 1.1926 0.5343 0.064 Uiso 1 1 calc R
H1D H 0.1730 1.2061 0.6299 0.064 Uiso 1 1 calc R
N2 N 0.4908(7) 0.7470(6) -0.0663(6) 0.030(2) Uani 1 1 d .
H2B H 0.4217 0.7138 -0.0953 0.036 Uiso 1 1 calc R
H2C H 0.5064 0.7825 -0.1037 0.036 Uiso 1 1 calc R
N3 N 0.1226(7) 0.5041(6) -0.1095(6) 0.036(2) Uani 1 1 d .
H3A H 0.1487 0.5179 -0.0505 0.043 Uiso 1 1 calc R
H3E H 0.0972 0.4445 -0.1224 0.043 Uiso 1 1 calc R
N4 N 0.6307(8) 0.7689(7) 0.1087(7) 0.042(3) Uani 1 1 d .
H4A H 0.6902 0.8120 0.1362 0.050 Uiso 1 1 calc R
H4C H 0.6187 0.7364 0.1494 0.050 Uiso 1 1 calc R
N5 N 0.1415(7) 0.9941(7) 0.6176(6) 0.042(3) Uani 1 1 d .
H5A H 0.1643 1.0076 0.6765 0.050 Uiso 1 1 calc R
H5B H 0.0677 1.0117 0.5939 0.050 Uiso 1 1 calc R
N6 N 0.3292(8) 0.9392(7) 0.5690(6) 0.044(3) Uani 1 1 d .
H6A H 0.3151 0.9148 0.5130 0.052 Uiso 1 1 calc R
H6C H 0.4081 0.9467 0.5968 0.052 Uiso 1 1 calc R
N7 N 0.0769(10) 0.5946(7) -0.2571(7) 0.053(3) Uani 1 1 d .
H7A H 0.0266 0.5832 -0.3130 0.063 Uiso 1 1 calc R
H7B H 0.1115 0.6515 -0.2493 0.063 Uiso 1 1 calc R
N8 N -0.1430(8) 0.4712(7) -0.2200(7) 0.049(3) Uani 1 1 d D
H8A H -0.1206 0.4337 -0.2578 0.059 Uiso 1 1 calc R
H8D H -0.1473 0.4398 -0.1762 0.059 Uiso 1 1 calc R
N9 N -0.1611(9) 0.6596(7) -0.2258(8) 0.068(4) Uani 1 1 d D
H9A H -0.1751 0.6971 -0.1837 0.082 Uiso 1 1 calc R
H9C H -0.1432 0.6942 -0.2629 0.082 Uiso 1 1 calc R
N10 N 0.3650(8) 1.1410(9) 0.5212(7) 0.054(3) Uani 1 1 d .
H10A H 0.4394 1.1472 0.5602 0.065 Uiso 1 1 calc R
H10E H 0.3666 1.1106 0.4707 0.065 Uiso 1 1 calc R
C1 C 0.6612(13) 0.7104(12) 0.0457(11) 0.084(5) Uani 1 1 d U
H1A H 0.7325 0.7387 0.0407 0.100 Uiso 1 1 calc R
H1B H 0.6830 0.6542 0.0713 0.100 Uiso 1 1 calc R
C2 C 0.5845(15) 0.6863(12) -0.0378(11) 0.084(5) Uani 1 1 d U
H2A H 0.5359 0.6426 -0.0200 0.101 Uiso 1 1 calc R
C3 C 0.2669(17) 0.5507(13) -0.2774(13) 0.101(7) Uani 1 1 d .
H3B H 0.2323 0.5530 -0.3397 0.152 Uiso 1 1 calc R
H3C H 0.3230 0.5049 -0.2667 0.152 Uiso 1 1 calc R
H3D H 0.3065 0.6091 -0.2493 0.152 Uiso 1 1 calc R
C4 C 0.2702(15) 0.8727(13) 0.6177(14) 0.093(6) Uani 1 1 d .
H4B H 0.3069 0.8921 0.6810 0.111 Uiso 1 1 calc R
C5 C 0.1410(17) 0.8879(15) 0.5939(15) 0.104(6) Uani 1 1 d U
H5C H 0.1049 0.8543 0.6280 0.125 Uiso 1 1 calc R
H5D H 0.0988 0.8696 0.5316 0.125 Uiso 1 1 calc R
C6 C 0.2743(16) 1.2603(12) 0.5665(13) 0.092 Uiso 1 1 d DU
H6B H 0.3385 1.2718 0.6235 0.111 Uiso 1 1 calc R
C7 C 0.6063(17) 0.6218(14) -0.0984(15) 0.129(9) Uani 1 1 d .
H7C H 0.6692 0.5863 -0.0680 0.194 Uiso 1 1 calc R
H7D H 0.6287 0.6526 -0.1405 0.194 Uiso 1 1 calc R
H7E H 0.5359 0.5823 -0.1284 0.194 Uiso 1 1 calc R
C8 C -0.2624(16) 0.5040(12) -0.2672(13) 0.092 Uiso 1 1 d D
H8B H -0.2922 0.4720 -0.3265 0.110 Uiso 1 1 calc R
H8C H -0.3163 0.4866 -0.2374 0.110 Uiso 1 1 calc R
C9 C -0.2658(17) 0.6008(12) -0.2734(11) 0.098 Uiso 1 1 d D
H9B H -0.3331 0.6233 -0.2583 0.118 Uiso 1 1 calc R
C10 C 0.2925(16) 0.7650(13) 0.6021(13) 0.098 Uiso 1 1 d .
H10B H 0.2562 0.7305 0.6348 0.147 Uiso 1 1 calc R
H10C H 0.3761 0.7579 0.6219 0.147 Uiso 1 1 calc R
H10D H 0.2582 0.7432 0.5405 0.147 Uiso 1 1 calc R
C11 C 0.1691(13) 0.5268(10) -0.2401(10) 0.062(4) Uani 1 1 d .
H11A H 0.1305 0.4668 -0.2691 0.074 Uiso 1 1 calc R
C12 C 0.2151(15) 1.3457(12) 0.5523(12) 0.087 Uiso 1 1 d DU
H12A H 0.2678 1.3916 0.5439 0.131 Uiso 1 1 calc R
H12B H 0.1939 1.3659 0.6027 0.131 Uiso 1 1 calc R
H12C H 0.1449 1.3352 0.5009 0.131 Uiso 1 1 calc R
C13 C 0.3250(17) 1.2273(13) 0.5053(15) 0.098(6) Uani 1 1 d .
H13A H 0.3910 1.2692 0.5085 0.117 Uiso 1 1 calc R
H13B H 0.2670 1.2236 0.4464 0.117 Uiso 1 1 calc R
C14 C -0.2851(14) 0.6113(12) -0.3718(9) 0.095 Uiso 1 1 d D
H14A H -0.2865 0.6748 -0.3799 0.143 Uiso 1 1 calc R
H14B H -0.3591 0.5795 -0.4085 0.143 Uiso 1 1 calc R
H14C H -0.2216 0.5859 -0.3875 0.143 Uiso 1 1 calc R
C15 C 0.2179(11) 0.5218(9) -0.1427(10) 0.055(4) Uani 1 1 d .
H15A H 0.2715 0.4735 -0.1307 0.067 Uiso 1 1 calc R
H15B H 0.2622 0.5790 -0.1129 0.067 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O23 W1 O9 100.9(3) . .
O23 W1 O13 101.2(3) . .
O9 W1 O13 92.9(3) . .
O23 W1 O6 98.9(3) . .
O9 W1 O6 90.9(3) . .
O13 W1 O6 158.5(2) . .
O23 W1 O22 101.5(3) . .
O9 W1 O22 157.2(2) . .
O13 W1 O22 86.8(3) . .
O6 W1 O22 81.7(2) . .
O23 W1 O1 170.1(3) . .
O9 W1 O1 73.2(2) . .
O13 W1 O1 87.2(2) . .
O6 W1 O1 73.6(2) . .
O22 W1 O1 84.0(2) . .
O24 W2 O5 103.4(3) . .
O24 W2 O20 104.4(3) . .
O5 W2 O20 97.8(3) . .
O24 W2 O15 94.2(3) . .
O5 W2 O15 158.3(2) . .
O20 W2 O15 89.8(3) . .
O24 W2 O10 89.9(3) . .
O5 W2 O10 88.2(3) . .
O20 W2 O10 162.6(2) . .
O15 W2 O10 79.1(3) . .
O24 W2 O28 161.4(3) . .
O5 W2 O28 85.4(2) . .
O20 W2 O28 90.3(2) . .
O15 W2 O28 74.2(2) . .
O10 W2 O28 73.9(2) . .
O30 W3 O15 102.7(3) . .
O30 W3 O34 103.4(3) . .
O15 W3 O34 90.8(3) . .
O30 W3 O2 100.1(3) . .
O15 W3 O2 91.0(3) . .
O34 W3 O2 155.4(3) . .
O30 W3 O22 101.4(3) . .
O15 W3 O22 155.8(3) . .
O34 W3 O22 86.0(2) . .
O2 W3 O22 82.4(2) . .
O30 W3 O28 170.8(3) . .
O15 W3 O28 72.1(2) . .
O34 W3 O28 84.5(2) . .
O2 W3 O28 72.8(2) . .
O22 W3 O28 83.7(2) . .
O33 W4 O26 102.0(3) . .
O33 W4 O27 101.5(3) . .
O26 W4 O27 93.8(3) . .
O33 W4 O34 101.9(3) . .
O26 W4 O34 89.3(3) . .
O27 W4 O34 155.2(3) . .
O33 W4 O13 100.4(3) . .
O26 W4 O13 157.1(3) . .
O27 W4 O13 86.3(3) . .
O34 W4 O13 81.5(3) . .
O33 W4 O17 172.6(3) . .
O26 W4 O17 74.6(2) . .
O27 W4 O17 72.4(2) . .
O34 W4 O17 84.8(2) . .
O13 W4 O17 83.7(2) . .
O25 W5 O3 101.3(3) . .
O25 W5 O16 98.8(3) . .
O3 W5 O16 95.6(3) . .
O25 W5 O4 99.7(3) . .
O3 W5 O4 90.6(2) . .
O16 W5 O4 158.9(3) . .
O25 W5 O6 99.1(3) . .
O3 W5 O6 158.8(2) . .
O16 W5 O6 86.8(3) . .
O4 W5 O6 80.4(2) . .
O25 W5 O1 171.5(2) . .
O3 W5 O1 86.2(2) . .
O16 W5 O1 76.4(2) . .
O4 W5 O1 84.0(2) . .
O6 W5 O1 73.9(2) . .
O29 W6 O11 103.4(3) . .
O29 W6 O10 100.8(3) . .
O11 W6 O10 95.8(3) . .
O29 W6 O4 99.2(3) . .
O11 W6 O4 90.8(3) . .
O10 W6 O4 156.9(2) . .
O29 W6 O2 97.5(3) . .
O11 W6 O2 158.5(2) . .
O10 W6 O2 85.4(3) . .
O4 W6 O2 80.6(2) . .
O29 W6 O28 170.2(3) . .
O11 W6 O28 85.8(2) . .
O10 W6 O28 74.5(2) . .
O4 W6 O28 84.0(2) . .
O2 W6 O28 73.8(2) . .
O32 W7 O8 103.9(3) . .
O32 W7 O12 100.9(3) . .
O8 W7 O12 95.3(3) . .
O32 W7 O16 100.5(3) . .
O8 W7 O16 90.2(3) . .
O12 W7 O16 156.0(3) . .
O32 W7 O9 98.4(3) . .
O8 W7 O9 157.1(3) . .
O12 W7 O9 85.4(2) . .
O16 W7 O9 80.6(2) . .
O32 W7 O1 168.2(2) . .
O8 W7 O1 86.1(2) . .
O12 W7 O1 84.1(2) . .
O16 W7 O1 73.0(2) . .
O9 W7 O1 71.2(2) . .
O31 W8 O18 103.9(3) . .
O31 W8 O19 100.2(3) . .
O18 W8 O19 93.3(3) . .
O31 W8 O20 99.5(3) . .
O18 W8 O20 92.4(3) . .
O19 W8 O20 157.5(2) . .
O31 W8 O26 98.1(3) . .
O18 W8 O26 158.0(3) . .
O19 W8 O26 83.6(3) . .
O20 W8 O26 83.0(3) . .
O31 W8 O17 169.9(3) . .
O18 W8 O17 85.2(2) . .
O19 W8 O17 74.5(2) . .
O20 W8 O17 84.3(2) . .
O26 W8 O17 72.9(2) . .
O21 W9 O7 104.7(3) . .
O21 W9 O12 99.3(3) . .
O7 W9 O12 95.1(3) . .
O21 W9 O19 97.7(3) . .
O7 W9 O19 90.8(3) . .
O12 W9 O19 159.9(3) . .
O21 W9 O27 95.3(3) . .
O7 W9 O27 159.3(3) . .
O12 W9 O27 86.9(3) . .
O19 W9 O27 81.0(3) . .
O21 W9 O17 166.8(3) . .
O7 W9 O17 86.6(2) . .
O12 W9 O17 86.1(2) . .
O19 W9 O17 75.1(2) . .
O27 W9 O17 72.9(2) . .
O1 Si1 O14 110.5(3) . .
O1 Si1 O28 108.7(3) . .
O14 Si1 O28 110.0(3) . .
O1 Si1 O17 108.6(3) . .
O14 Si1 O17 110.9(3) . .
O28 Si1 O17 108.2(3) . .
O25 Co1 N4 90.1(3) 2_675 .
O25 Co1 O4 93.4(2) 2_675 .
N4 Co1 O4 172.1(3) . .
O25 Co1 N2 82.2(3) 2_675 .
N4 Co1 N2 80.8(4) . .
O4 Co1 N2 106.6(3) . .
O25 Co1 O22 141.5(2) 2_675 .
N4 Co1 O22 84.4(3) . .
O4 Co1 O22 88.5(2) . .
N2 Co1 O22 133.8(3) . .
O25 Co1 O6 76.2(2) 2_675 .
N4 Co1 O6 102.4(3) . .
O4 Co1 O6 71.7(2) . .
N2 Co1 O6 158.2(3) . .
O22 Co1 O6 68.0(2) . .
O25 Co1 O2 147.6(2) 2_675 .
N4 Co1 O2 110.0(3) . .
O4 Co1 O2 70.1(2) . .
N2 Co1 O2 76.6(3) . .
O22 Co1 O2 68.0(2) . .
O6 Co1 O2 121.1(2) . .
O18 Co2 O7 91.6(3) 2_575 2_575
O18 Co2 O3 94.3(2) 2_575 .
O7 Co2 O3 173.0(2) 2_575 .
O18 Co2 O11 175.5(2) 2_575 .
O7 Co2 O11 92.5(2) 2_575 .
O3 Co2 O11 81.6(2) . .
O18 Co2 O14 93.5(2) 2_575 2_575
O7 Co2 O14 92.8(2) 2_575 2_575
O3 Co2 O14 83.0(2) . 2_575
O11 Co2 O14 84.4(2) . 2_575
O18 Co2 OW2 88.9(3) 2_575 .
O7 Co2 OW2 88.2(2) 2_575 .
O3 Co2 OW2 95.7(2) . .
O11 Co2 OW2 93.2(2) . .
O14 Co2 OW2 177.3(3) 2_575 .
O5 Co3 O8 91.6(2) 2_575 .
O5 Co3 O3 92.7(2) 2_575 .
O8 Co3 O3 95.3(2) . .
O5 Co3 O14 175.9(2) 2_575 .
O8 Co3 O14 92.3(2) . .
O3 Co3 O14 88.4(2) . .
O5 Co3 O11 94.3(2) 2_575 2_575
O8 Co3 O11 90.9(2) . 2_575
O3 Co3 O11 170.5(2) . 2_575
O14 Co3 O11 84.2(2) . 2_575
O5 Co3 O14 90.0(2) 2_575 2_575
O8 Co3 O14 177.6(2) . 2_575
O3 Co3 O14 82.7(2) . 2_575
O14 Co3 O14 86.2(2) . 2_575
O11 Co3 O14 90.8(2) 2_575 2_575
N5 Co4 N6 83.0(4) . .
N5 Co4 N10 177.3(4) . .
N6 Co4 N10 99.5(5) . .
N5 Co4 N1 96.3(4) . .
N6 Co4 N1 178.0(4) . .
N10 Co4 N1 81.2(5) . .
N5 Co4 O23 90.1(3) . 2_676
N6 Co4 O23 88.5(3) . 2_676
N10 Co4 O23 91.0(3) . 2_676
N1 Co4 O23 89.6(3) . 2_676
N5 Co4 O21 90.1(3) . .
N6 Co4 O21 91.7(3) . .
N10 Co4 O21 88.8(3) . .
N1 Co4 O21 90.3(3) . .
O23 Co4 O21 179.7(3) 2_676 .
N9 Co5 N8 84.0(4) . .
N9 Co5 N3 178.1(4) . .
N8 Co5 N3 94.2(4) . .
N9 Co5 N7 99.8(5) . .
N8 Co5 N7 106.7(4) . .
N3 Co5 N7 81.2(4) . .
N9 Co5 O10 91.0(3) . .
N8 Co5 O10 160.2(3) . .
N3 Co5 O10 90.6(3) . .
N7 Co5 O10 93.0(3) . .
N9 Co5 O24 88.1(4) . .
N8 Co5 O24 88.2(3) . .
N3 Co5 O24 91.3(3) . .
N7 Co5 O24 163.6(3) . .
O10 Co5 O24 72.5(2) . .
Si1 O1 W5 125.3(3) . .
Si1 O1 W7 122.2(3) . .
W5 O1 W7 90.4(2) . .
Si1 O1 W1 125.3(3) . .
W5 O1 W1 92.39(18) . .
W7 O1 W1 91.31(19) . .
W3 O2 W6 122.6(3) . .
W3 O2 Co1 101.5(2) . .
W6 O2 Co1 97.4(2) . .
W5 O3 Co2 129.6(3) . .
W5 O3 Co3 131.9(3) . .
Co2 O3 Co3 97.3(2) . .
W6 O4 W5 143.8(3) . .
W6 O4 Co1 107.4(3) . .
W5 O4 Co1 106.0(2) . .
W2 O5 Co3 139.9(3) . 2_575
W1 O6 W5 119.3(3) . .
W1 O6 Co1 102.8(3) . .
W5 O6 Co1 97.9(2) . .
W9 O7 Co2 137.1(4) . 2_575
W7 O8 Co3 137.6(3) . .
W1 O9 W7 124.3(3) . .
W6 O10 W2 117.1(3) . .
W6 O10 Co5 145.0(3) . .
W2 O10 Co5 97.9(2) . .
W6 O11 Co2 130.1(3) . .
W6 O11 Co3 131.9(3) . 2_575
Co2 O11 Co3 95.8(2) . 2_575
W9 O12 W7 147.9(3) . .
W1 O13 W4 153.5(3) . .
Si1 O14 Co3 122.4(3) . .
Si1 O14 Co3 121.7(3) . 2_575
Co3 O14 Co3 93.8(2) . 2_575
Si1 O14 Co2 120.8(3) . 2_575
Co3 O14 Co2 95.2(2) . 2_575
Co3 O14 Co2 96.1(2) 2_575 2_575
W3 O15 W2 121.6(3) . .
W5 O16 W7 119.3(3) . .
Si1 O17 W9 123.5(3) . .
Si1 O17 W8 124.8(3) . .
W9 O17 W8 90.35(19) . .
Si1 O17 W4 126.0(3) . .
W9 O17 W4 91.6(2) . .
W8 O17 W4 90.1(2) . .
W8 O18 Co2 137.1(3) . 2_575
W8 O19 W9 118.4(3) . .
W2 O20 W8 145.8(4) . .
W9 O21 Co4 139.0(3) . .
W1 O22 W3 147.1(3) . .
W1 O22 Co1 104.9(2) . .
W3 O22 Co1 104.7(2) . .
W1 O23 Co4 134.9(3) . 2_676
W2 O24 Co5 99.8(3) . .
W5 O25 Co1 160.7(4) . 2_675
W4 O26 W8 121.7(3) . .
W4 O27 W9 122.9(3) . .
Si1 O28 W2 123.1(3) . .
Si1 O28 W6 124.3(3) . .
W2 O28 W6 93.6(2) . .
Si1 O28 W3 124.1(3) . .
W2 O28 W3 92.0(2) . .
W6 O28 W3 90.37(19) . .
W3 O34 W4 156.3(4) . .
C6 N1 Co4 104.2(8) . .
C2 N2 Co1 111.0(8) . .
C15 N3 Co5 109.3(8) . .
C1 N4 Co1 109.0(8) . .
C5 N5 Co4 111.0(9) . .
C4 N6 Co4 108.3(8) . .
C11 N7 Co5 108.8(8) . .
C8 N8 Co5 109.5(9) . .
C9 N9 Co5 111.2(10) . .
C13 N10 Co4 111.5(9) . .
C2 C1 N4 122.0(12) . .
C1 C2 C7 123.6(15) . .
C1 C2 N2 114.3(12) . .
C7 C2 N2 120.7(15) . .
C5 C4 N6 109.1(15) . .
C5 C4 C10 112.2(16) . .
N6 C4 C10 115.0(14) . .
C4 C5 N5 103.2(14) . .
C13 C6 C12 117.4(18) . .
C13 C6 N1 113.7(15) . .
C12 C6 N1 105.0(14) . .
C9 C8 N8 116.3(15) . .
N9 C9 C8 118.6(16) . .
N9 C9 C14 103.7(13) . .
C8 C9 C14 105.5(15) . .
N7 C11 C15 108.2(10) . .
N7 C11 C3 112.0(13) . .
C15 C11 C3 112.1(13) . .
C6 C13 N10 110.9(16) . .
N3 C15 C11 110.2(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O23 1.736(6) .
W1 O9 1.858(6) .
W1 O13 1.861(6) .
W1 O6 1.912(6) .
W1 O22 1.955(6) .
W1 O1 2.411(5) .
W2 O24 1.736(6) .
W2 O5 1.752(6) .
W2 O20 1.866(6) .
W2 O15 2.054(6) .
W2 O10 2.071(6) .
W2 O28 2.259(5) .
W3 O30 1.709(6) .
W3 O15 1.859(6) .
W3 O34 1.875(6) .
W3 O2 1.913(6) .
W3 O22 1.964(5) .
W3 O28 2.486(6) .
W4 O33 1.714(7) .
W4 O26 1.851(6) .
W4 O27 1.858(6) .
W4 O34 1.930(6) .
W4 O13 1.976(6) .
W4 O17 2.448(6) .
W5 O25 1.726(6) .
W5 O3 1.793(6) .
W5 O16 1.887(6) .
W5 O4 1.987(6) .
W5 O6 2.036(6) .
W5 O1 2.308(6) .
W6 O29 1.726(6) .
W6 O11 1.803(6) .
W6 O10 1.887(6) .
W6 O4 1.959(5) .
W6 O2 2.017(6) .
W6 O28 2.372(6) .
W7 O32 1.722(6) .
W7 O8 1.772(6) .
W7 O12 1.915(6) .
W7 O16 1.974(6) .
W7 O9 2.023(6) .
W7 O1 2.388(6) .
W8 O31 1.722(6) .
W8 O18 1.778(6) .
W8 O19 1.907(6) .
W8 O20 1.985(6) .
W8 O26 2.057(6) .
W8 O17 2.376(6) .
W9 O21 1.743(6) .
W9 O7 1.767(6) .
W9 O12 1.900(6) .
W9 O19 1.964(6) .
W9 O27 2.026(6) .
W9 O17 2.312(6) .
Si1 O1 1.638(6) .
Si1 O14 1.642(6) .
Si1 O28 1.642(6) .
Si1 O17 1.644(6) .
Co1 O25 2.110(6) 2_675
Co1 N4 2.111(9) .
Co1 O4 2.119(6) .
Co1 N2 2.130(8) .
Co1 O22 2.214(6) .
Co1 O6 2.309(6) .
Co1 O2 2.348(6) .
Co2 O18 2.031(6) 2_575
Co2 O7 2.046(6) 2_575
Co2 O3 2.104(6) .
Co2 O11 2.108(6) .
Co2 O14 2.129(6) 2_575
Co2 OW2 2.214(6) .
Co3 O5 2.032(6) 2_575
Co3 O8 2.033(6) .
Co3 O3 2.115(6) .
Co3 O14 2.121(6) .
Co3 O11 2.123(6) 2_575
Co3 O14 2.129(6) 2_575
Co4 N5 2.070(9) .
Co4 N6 2.087(10) .
Co4 N10 2.104(10) .
Co4 N1 2.118(11) .
Co4 O23 2.188(6) 2_676
Co4 O21 2.189(6) .
Co5 N9 2.091(10) .
Co5 N8 2.103(10) .
Co5 N3 2.105(9) .
Co5 N7 2.137(10) .
Co5 O10 2.159(6) .
Co5 O24 2.397(7) .
O5 Co3 2.032(6) 2_575
O7 Co2 2.046(6) 2_575
O11 Co3 2.123(6) 2_575
O14 Co3 2.129(6) 2_575
O14 Co2 2.129(6) 2_575
O18 Co2 2.031(6) 2_575
O23 Co4 2.188(6) 2_676
O25 Co1 2.110(6) 2_675
N1 C6 1.52(2) .
N2 C2 1.447(16) .
N3 C15 1.445(14) .
N4 C1 1.422(17) .
N5 C5 1.58(2) .
N6 C4 1.60(2) .
N7 C11 1.498(17) .
N8 C8 1.507(19) .
N9 C9 1.43(2) .
N10 C13 1.40(2) .
C1 C2 1.36(2) .
C2 C7 1.40(2) .
C3 C11 1.537(19) .
C4 C5 1.50(2) .
C4 C10 1.63(2) .
C6 C13 1.39(2) .
C6 C12 1.470(16) .
C8 C9 1.444(16) .
C9 C14 1.559(16) .
C11 C15 1.50(2) .
