#------------------------------------------------------------------------------
#$Date: 2019-08-26 08:35:56 +0200 (lun 26 de ago de 2019) $
#$Revision: 217705 $
#$URL: svn://www.crystallography.net/cod/cif/7/23/34/7233435.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7233435
loop_
_publ_author_name
'Jia Li'
'Jin-Yun Wang'
'Zhong-Ning Chen'
_publ_section_title
;
 Sensitized EuIII luminescence through energy transfer from PtM2 (M = Ag
 or Au) alkynyl chromophores in PtM2Eu2 heteropentanuclear complexes
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              3661
_journal_page_last               3668
_journal_paper_doi               10.1039/C3TC30474D
_journal_volume                  1
_journal_year                    2013
_chemical_formula_sum            'C156 H132 Au2 Cl2 Eu2 F36 N6 O24 P6 Pt'
_chemical_formula_weight         4308.34
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                106.747(7)
_cell_angle_beta                 95.282(12)
_cell_angle_gamma                101.088(8)
_cell_formula_units_Z            1
_cell_length_a                   12.36520(10)
_cell_length_b                   16.9603(2)
_cell_length_c                   26.9859(2)
_cell_measurement_temperature    293(2)
_cell_volume                     5252.3(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0623
_diffrn_reflns_av_sigmaI/netI    0.0865
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            39786
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         4.32
_exptl_absorpt_coefficient_mu    2.800
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.4670
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_density_diffrn    1.362
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2112
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.829
_refine_diff_density_min         -1.984
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.006
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1169
_refine_ls_number_reflns         18157
_refine_ls_number_restraints     756
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0708
_refine_ls_R_factor_gt           0.0570
_refine_ls_shift/su_max          0.031
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
calc w=1/[σ²(Fo²)+(0.0622P)²+0.0000P] where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1409
_refine_ls_wR_factor_ref         0.1509
_reflns_number_gt                13937
_reflns_number_total             18157
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            J-Mater-Chem-C-1-3661-2.cif
_cod_data_source_block           a2
_cod_original_cell_volume        5252.32(8)
_cod_original_sg_symbol_H-M      p-1
_cod_original_formula_sum        'C156 H40 H92 Au2 Cl2 Eu2 F36 N6 O24 P6 Pt'
_cod_database_code               7233435
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 1.1995(2) 0.65555(16) 0.41538(13) 0.1169(9) Uani 1 1 d DU . .
Pt1 Pt 2.0000 1.0000 0.5000 0.04444(10) Uani 1 2 d S . .
Au1 Au 1.821109(19) 0.900699(15) 0.537387(11) 0.05800(10) Uani 1 1 d . . .
P1 P 1.78183(14) 1.02425(11) 0.58735(7) 0.0561(4) Uani 1 1 d . . .
C1 C 1.7405(6) 0.7111(4) 0.4373(3) 0.0669(18) Uani 1 1 d . . .
C2 C 1.7584(8) 0.6514(6) 0.3926(4) 0.102(3) Uani 1 1 d . . .
H2A H 1.8288 0.6407 0.3892 0.122 Uiso 1 1 calc R . .
C3 C 1.6697(12) 0.6095(7) 0.3546(4) 0.128(4) Uani 1 1 d . . .
H3A H 1.6803 0.5699 0.3245 0.153 Uiso 1 1 calc R . .
C4 C 1.5650(12) 0.6235(8) 0.3588(6) 0.132(5) Uani 1 1 d . . .
H4A H 1.5059 0.5936 0.3319 0.159 Uiso 1 1 calc R . .
C5 C 1.5479(9) 0.6792(9) 0.4008(6) 0.136(5) Uani 1 1 d . . .
H5A H 1.4766 0.6883 0.4037 0.164 Uiso 1 1 calc R . .
C6 C 1.6356(7) 0.7243(6) 0.4408(4) 0.092(3) Uani 1 1 d . . .
H6A H 1.6230 0.7640 0.4702 0.111 Uiso 1 1 calc R . .
C7 C 1.8690(8) 0.7052(5) 0.5307(4) 0.088(2) Uani 1 1 d U . .
C8 C 1.9024(10) 0.6329(6) 0.5139(4) 0.124(3) Uani 1 1 d U . .
H8A H 1.9228 0.6170 0.4808 0.149 Uiso 1 1 calc R . .
C9 C 1.9071(11) 0.5792(7) 0.5465(5) 0.139(3) Uani 1 1 d U . .
H9A H 1.9252 0.5274 0.5327 0.167 Uiso 1 1 calc R . .
C10 C 1.8875(12) 0.5999(8) 0.5930(5) 0.151(3) Uani 1 1 d U . .
H10A H 1.8848 0.5628 0.6127 0.181 Uiso 1 1 calc R . .
C11 C 1.8714(13) 0.6752(9) 0.6120(5) 0.156(3) Uani 1 1 d U . .
H11A H 1.8702 0.6954 0.6478 0.187 Uiso 1 1 calc R . .
C12 C 1.8553(11) 0.7295(7) 0.5812(4) 0.133(3) Uani 1 1 d U . .
H12A H 1.8357 0.7805 0.5960 0.160 Uiso 1 1 calc R . .
C13 C 1.9803(5) 0.7838(4) 0.4639(3) 0.0519(15) Uani 1 1 d . . .
H13A H 1.9772 0.7329 0.4353 0.062 Uiso 1 1 calc R . .
H13B H 2.0418 0.7893 0.4907 0.062 Uiso 1 1 calc R . .
C14 C 1.6353(6) 1.0226(5) 0.5817(3) 0.0684(19) Uani 1 1 d . . .
C15 C 1.5601(6) 0.9450(5) 0.5688(4) 0.094(3) Uani 1 1 d . . .
H15A H 1.5870 0.8962 0.5641 0.112 Uiso 1 1 calc R . .
C16 C 1.4470(7) 0.9385(7) 0.5627(5) 0.132(5) Uani 1 1 d . . .
H16A H 1.3974 0.8860 0.5533 0.158 Uiso 1 1 calc R . .
C17 C 1.4097(7) 1.0101(8) 0.5707(5) 0.122(4) Uani 1 1 d . . .
H17A H 1.3333 1.0063 0.5678 0.146 Uiso 1 1 calc R . .
C18 C 1.4794(7) 1.0873(7) 0.5828(4) 0.109(3) Uani 1 1 d . . .
H18A H 1.4507 1.1354 0.5883 0.131 Uiso 1 1 calc R . .
C19 C 1.5919(6) 1.0944(5) 0.5869(4) 0.089(3) Uani 1 1 d . . .
H19A H 1.6397 1.1469 0.5932 0.107 Uiso 1 1 calc R . .
C20 C 1.8356(6) 1.0500(4) 0.6561(3) 0.0631(17) Uani 1 1 d . . .
C21 C 1.9193(6) 1.0116(6) 0.6691(3) 0.080(2) Uani 1 1 d . . .
H21A H 1.9434 0.9716 0.6436 0.096 Uiso 1 1 calc R . .
C22 C 1.9664(8) 1.0361(8) 0.7228(4) 0.111(3) Uani 1 1 d . . .
H22A H 2.0231 1.0123 0.7328 0.134 Uiso 1 1 calc R . .
C23 C 1.9290(12) 1.0951(8) 0.7607(4) 0.123(4) Uani 1 1 d . . .
H23A H 1.9604 1.1108 0.7958 0.148 Uiso 1 1 calc R . .
C24 C 1.8452(10) 1.1299(8) 0.7457(4) 0.122(4) Uani 1 1 d . . .
H24A H 1.8191 1.1690 0.7707 0.147 Uiso 1 1 calc R . .
C25 C 1.8006(7) 1.1076(6) 0.6947(3) 0.088(2) Uani 1 1 d . . .
H25A H 1.7440 1.1321 0.6853 0.106 Uiso 1 1 calc R . .
C26 C 2.0761(5) 1.1651(4) 0.6238(3) 0.0588(16) Uani 1 1 d . . .
C27 C 2.1809(6) 1.1464(4) 0.6290(3) 0.0713(19) Uani 1 1 d . . .
H27A H 2.2018 1.1090 0.6009 0.086 Uiso 1 1 calc R . .
C28 C 2.2529(7) 1.1831(5) 0.6752(4) 0.091(3) Uani 1 1 d . . .
H28A H 2.3230 1.1712 0.6787 0.109 Uiso 1 1 calc R . .
C29 C 2.2199(11) 1.2385(7) 0.7167(4) 0.115(4) Uani 1 1 d . . .
H29A H 2.2674 1.2616 0.7486 0.138 Uiso 1 1 calc R . .
C30 C 2.1193(10) 1.2599(6) 0.7118(4) 0.103(3) Uani 1 1 d . . .
H30A H 2.1001 1.2991 0.7395 0.123 Uiso 1 1 calc R . .
C31 C 2.0488(7) 1.2235(5) 0.6666(3) 0.081(2) Uani 1 1 d . . .
H31A H 1.9798 1.2374 0.6634 0.097 Uiso 1 1 calc R . .
C32 C 1.9212(4) 1.0436(4) 0.4474(2) 0.0493(14) Uani 1 1 d . . .
C33 C 1.8798(5) 1.0733(4) 0.4183(3) 0.0591(16) Uani 1 1 d . . .
C34 C 1.8299(6) 1.1075(4) 0.3811(3) 0.0624(17) Uani 1 1 d . . .
C35 C 1.7909(7) 1.0560(5) 0.3296(3) 0.086(2) Uani 1 1 d . . .
H35A H 1.7999 1.0008 0.3190 0.103 Uiso 1 1 calc R . .
C36 C 1.7389(7) 1.0873(6) 0.2946(3) 0.092(3) Uani 1 1 d . . .
H36A H 1.7129 1.0523 0.2604 0.110 Uiso 1 1 calc R . .
C37 C 1.7239(6) 1.1697(5) 0.3088(3) 0.0721(19) Uani 1 1 d . . .
C38 C 1.7610(7) 1.2205(5) 0.3601(3) 0.088(2) Uani 1 1 d . . .
H38A H 1.7507 1.2754 0.3707 0.106 Uiso 1 1 calc R . .
C39 C 1.8140(7) 1.1896(5) 0.3962(3) 0.082(2) Uani 1 1 d . . .
H39A H 1.8388 1.2243 0.4306 0.098 Uiso 1 1 calc R . .
C40 C 1.5940(7) 1.1925(6) 0.1831(3) 0.080(2) Uani 1 1 d . . .
C41 C 1.6616(7) 1.1694(6) 0.2171(3) 0.085(2) Uani 1 1 d . . .
H41A H 1.7075 1.1331 0.2044 0.102 Uiso 1 1 calc R . .
C42 C 1.6608(6) 1.2008(5) 0.2709(3) 0.082(2) Uani 1 1 d . . .
C43 C 1.5918(6) 1.2544(5) 0.2876(3) 0.079(2) Uani 1 1 d . . .
H43A H 1.5887 1.2758 0.3231 0.095 Uiso 1 1 calc R . .
C44 C 1.5269(6) 1.2769(5) 0.2515(3) 0.074(2) Uani 1 1 d . . .
C45 C 1.5936(8) 1.1597(6) 0.1254(3) 0.094(3) Uani 1 1 d . B .
C46 C 1.6687(11) 1.1168(10) 0.1045(4) 0.163(6) Uani 1 1 d . . .
H46A H 1.7234 1.1069 0.1264 0.195 Uiso 1 1 calc R . .
C47 C 1.6650(14) 1.0880(12) 0.0517(5) 0.198(8) Uani 1 1 d . . .
H47A H 1.7179 1.0601 0.0371 0.237 Uiso 1 1 calc R . .
C48 C 1.5794(13) 1.1015(11) 0.0201(5) 0.164(6) Uani 1 1 d . . .
H48A H 1.5698 1.0785 -0.0162 0.197 Uiso 1 1 calc R . .
C49 C 1.5100(10) 1.1492(8) 0.0435(4) 0.123(4) Uani 1 1 d . B .
H49A H 1.4578 1.1630 0.0223 0.148 Uiso 1 1 calc R . .
C50 C 1.4479(7) 1.3324(5) 0.2675(4) 0.085(2) Uani 1 1 d . C .
C51 C 1.4576(8) 1.3834(6) 0.3201(4) 0.102(3) Uani 1 1 d . . .
H51A H 1.5147 1.3853 0.3457 0.122 Uiso 1 1 calc R . .
C52 C 1.3795(10) 1.4296(7) 0.3313(5) 0.115(3) Uani 1 1 d . . .
H52A H 1.3809 1.4621 0.3657 0.139 Uiso 1 1 calc R . .
C53 C 1.3000(10) 1.4289(7) 0.2935(5) 0.115(3) Uani 1 1 d . . .
H53A H 1.2487 1.4625 0.3011 0.138 Uiso 1 1 calc R . .
C54 C 1.2969(9) 1.3781(7) 0.2441(5) 0.115(3) Uani 1 1 d . C .
H54A H 1.2407 1.3773 0.2185 0.139 Uiso 1 1 calc R . .
C55 C 1.4549(16) 1.3588(10) -0.0118(11) 0.407(13) Uani 1 1 d DU . .
C56 C 1.4636(18) 1.3655(10) 0.0521(5) 0.208(9) Uani 1 1 d D C .
C57 C 1.5181(16) 1.4409(9) 0.0910(5) 0.196(8) Uani 1 1 d . . .
H57A H 1.5478 1.4876 0.0811 0.235 Uiso 1 1 calc R D .
C58 C 1.5292(13) 1.4483(9) 0.1419(6) 0.153(5) Uani 1 1 d . C .
C59 C 1.5771(13) 1.5322(10) 0.1820(6) 0.188(6) Uani 1 1 d DU . .
C60 C 1.2646(9) 0.9643(7) 0.1181(4) 0.134(3) Uani 1 1 d DU . .
C61 C 1.2437(10) 1.0529(7) 0.1325(5) 0.125(3) Uani 1 1 d DU A .
C62 C 1.1438(10) 1.0659(9) 0.1413(6) 0.154(4) Uani 1 1 d DU . .
H62A H 1.0844 1.0188 0.1324 0.185 Uiso 1 1 calc R A .
C63 C 1.1221(9) 1.1445(11) 0.1629(7) 0.174(4) Uani 1 1 d DU A .
C66 C 1.8447(5) 1.1175(4) 0.5692(3) 0.0569(16) Uani 1 1 d . . .
H66A H 1.8017 1.1159 0.5369 0.068 Uiso 1 1 calc R . .
H66B H 1.8393 1.1680 0.5962 0.068 Uiso 1 1 calc R . .
C76 C 1.1576(12) 1.4274(10) 0.0830(6) 0.224(5) Uani 1 1 d DU . .
C77 C 1.1938(11) 1.3431(9) 0.0793(6) 0.217(4) Uani 1 1 d DU B .
C78 C 1.1504(15) 1.2721(10) 0.0337(7) 0.227(5) Uani 1 1 d DU . .
H78A H 1.1019 1.2779 0.0072 0.272 Uiso 1 1 calc R B .
C79 C 1.1790(16) 1.1915(10) 0.0271(7) 0.214(4) Uani 1 1 d DU B .
C80 C 1.1118(14) 1.1199(10) -0.0239(6) 0.237(6) Uani 1 1 d DU . .
N1 N 1.5246(5) 1.2436(4) 0.1989(3) 0.0765(17) Uani 1 1 d . . .
Eu1 Eu 1.36718(4) 1.25375(3) 0.13384(2) 0.10015(18) Uani 1 1 d . A .
O1 O 1.5008(6) 1.3905(4) 0.1610(3) 0.119(2) Uani 1 1 d . . .
F1 F 1.231(2) 0.9164(18) 0.1467(11) 0.228(12) Uani 0.50 1 d PDU A 1
F1' F 1.3435(17) 0.9615(15) 0.1524(9) 0.221(10) Uani 0.50 1 d PDU A 2
F2 F 1.3689(10) 0.9597(12) 0.1151(8) 0.146(5) Uani 0.50 1 d PDU A 1
F2' F 1.288(2) 0.9406(18) 0.0713(7) 0.229(10) Uani 0.50 1 d PDU A 2
F3 F 1.2115(15) 0.9253(15) 0.0693(6) 0.189(8) Uani 0.50 1 d PDU A 1
F3' F 1.1748(15) 0.9111(12) 0.1209(9) 0.170(8) Uani 0.50 1 d PDU A 2
F4 F 1.066(2) 1.4083(17) 0.0492(11) 0.267(13) Uani 0.50 1 d PDU B 1
F4' F 1.132(4) 1.435(2) 0.0372(9) 0.354(18) Uani 0.50 1 d PDU B 2
F5 F 1.238(2) 1.474(2) 0.0680(17) 0.329(14) Uani 0.50 1 d PDU B 1
F5' F 1.241(2) 1.4896(14) 0.1114(16) 0.319(17) Uani 0.50 1 d PDU B 2
F6 F 1.141(3) 1.466(2) 0.1302(7) 0.291(13) Uani 0.50 1 d PDU B 1
F6' F 1.072(3) 1.426(2) 0.1088(15) 0.344(16) Uani 0.50 1 d PDU B 2
F10 F 1.648(2) 1.5261(16) 0.2194(10) 0.235(12) Uani 0.50 1 d PDU C 1
F10' F 1.6845(15) 1.540(2) 0.1936(14) 0.254(12) Uani 0.50 1 d PDU C 2
F11 F 1.629(3) 1.5881(19) 0.1625(12) 0.257(14) Uani 0.50 1 d PDU C 1
F11' F 1.561(3) 1.5934(18) 0.1637(15) 0.280(14) Uani 0.50 1 d PDU C 2
F12 F 1.494(2) 1.560(2) 0.2026(14) 0.281(15) Uani 0.50 1 d PDU C 1
F12' F 1.534(3) 1.543(2) 0.2257(8) 0.248(14) Uani 0.50 1 d PDU C 2
F13 F 1.026(2) 1.2145(18) 0.2230(12) 0.333(18) Uani 0.50 1 d PDU A 1
F13' F 1.014(3) 1.158(3) 0.2309(8) 0.396(19) Uani 0.50 1 d PDU A 2
F14 F 0.958(2) 1.0793(15) 0.1897(14) 0.290(13) Uani 0.50 1 d PDU A 1
F14' F 0.9324(16) 1.0782(14) 0.1526(16) 0.321(18) Uani 0.50 1 d PDU A 2
F15 F 0.949(2) 1.161(3) 0.1400(13) 0.330(15) Uani 0.50 1 d PDU A 1
F15' F 0.978(2) 1.2140(17) 0.1689(17) 0.293(13) Uani 0.50 1 d PDU A 2
F16 F 1.097(3) 1.1513(16) -0.0624(10) 0.284(13) Uani 0.50 1 d PDU B 1
F17 F 1.010(2) 1.082(3) -0.0213(17) 0.407(19) Uani 0.50 1 d PDU B 1
F18 F 1.161(3) 1.0580(16) -0.0421(14) 0.370(19) Uani 0.50 1 d PDU B 1
F16' F 1.033(2) 1.130(2) -0.0550(14) 0.345(18) Uani 0.50 1 d PDU B 2
F17' F 1.076(3) 1.0498(18) -0.0138(15) 0.379(19) Uani 0.50 1 d PDU B 2
F18' F 1.1943(19) 1.109(2) -0.0506(11) 0.312(15) Uani 0.50 1 d PDU B 2
O2 O 1.4181(10) 1.2960(5) 0.0601(3) 0.173(4) Uani 1 1 d . . .
P2 P 1.98996(13) 1.12541(10) 0.56036(6) 0.0478(4) Uani 1 1 d . . .
N2 N 1.3674(6) 1.3297(5) 0.2296(3) 0.095(2) Uani 1 1 d . . .
O3 O 1.2499(9) 1.3417(6) 0.1189(4) 0.192(4) Uani 1 1 d DU . .
P3 P 1.85194(14) 0.77103(10) 0.49103(7) 0.0538(4) Uani 1 1 d . . .
N3 N 1.5130(7) 1.1767(5) 0.0945(3) 0.102(2) Uani 1 1 d . . .
O4 O 1.2409(8) 1.1731(5) 0.0574(4) 0.183(4) Uani 1 1 d DU . .
O5 O 1.3315(5) 1.1097(4) 0.1359(3) 0.112(2) Uani 1 1 d DU . .
O6 O 1.1857(6) 1.2093(6) 0.1605(4) 0.156(3) Uani 1 1 d . . .
C64 C 1.0052(10) 1.1487(9) 0.1800(6) 0.206(5) Uani 1 1 d DU . .
F7 F 1.550(2) 1.4093(17) -0.0122(10) 0.405(14) Uani 0.50 1 d PDU D 1
F8 F 1.444(3) 1.2790(13) -0.0372(11) 0.425(14) Uani 0.50 1 d PDU D 1
F9 F 1.368(2) 1.390(2) -0.0195(8) 0.409(14) Uani 0.50 1 d PDU D 1
F7' F 1.523(3) 1.3071(17) -0.0246(10) 0.414(14) Uani 0.50 1 d PDU D 2
F8' F 1.3491(18) 1.321(2) -0.0306(9) 0.412(14) Uani 0.50 1 d PDU D 2
F9' F 1.487(3) 1.4327(14) -0.0176(11) 0.413(14) Uani 0.50 1 d PDU D 2
O7 O 1.2629(15) 0.5929(10) 0.4078(8) 0.132(6) Uani 0.509(10) 1 d PDU E 1
O8 O 1.2263(16) 0.7109(11) 0.4674(4) 0.164(6) Uani 0.509(10) 1 d PDU E 1
O9 O 1.2267(17) 0.7034(9) 0.3806(6) 0.165(5) Uani 0.509(10) 1 d PDU E 1
O10 O 1.0844(8) 0.6178(10) 0.4036(8) 0.163(6) Uani 0.509(10) 1 d PDU E 1
O7' O 1.2480(17) 0.5893(10) 0.3900(8) 0.137(6) Uani 0.491(10) 1 d PDU E 2
O8' O 1.2854(13) 0.7305(8) 0.4400(8) 0.173(6) Uani 0.491(10) 1 d PDU E 2
O9' O 1.1245(15) 0.6734(11) 0.3797(5) 0.151(5) Uani 0.491(10) 1 d PDU E 2
O10' O 1.1445(15) 0.6354(11) 0.4561(6) 0.154(5) Uani 0.491(10) 1 d PDU E 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O10 Cl1 O7' 103.2(12) . .
O10 Cl1 O9' 56.5(8) . .
O7' Cl1 O9' 111.6(9) . .
O10 Cl1 O8 110.0(8) . .
O7' Cl1 O8 129.7(13) . .
O9' Cl1 O8 118.1(10) . .
O10 Cl1 O7 110.6(9) . .
O7' Cl1 O7 19.6(15) . .
O9' Cl1 O7 131.0(12) . .
O8 Cl1 O7 110.6(9) . .
O10 Cl1 O9 108.8(9) . .
O7' Cl1 O9 94.5(12) . .
O9' Cl1 O9 52.8(8) . .
O8 Cl1 O9 108.7(8) . .
O7 Cl1 O9 108.0(8) . .
O10 Cl1 O10' 61.7(8) . .
O7' Cl1 O10' 110.3(9) . .
O9' Cl1 O10' 110.6(8) . .
O8 Cl1 O10' 59.2(9) . .
O7 Cl1 O10' 97.2(11) . .
O9 Cl1 O10' 154.7(10) . .
O10 Cl1 O8' 147.4(10) . .
O7' Cl1 O8' 109.3(9) . .
O9' Cl1 O8' 108.1(8) . .
O8 Cl1 O8' 48.0(8) . .
O7 Cl1 O8' 100.7(13) . .
O9 Cl1 O8' 67.7(9) . .
O10' Cl1 O8' 106.8(8) . .
C32 Pt1 C32 180.000(2) 2_976 .
C32 Pt1 P2 95.48(17) 2_976 .
C32 Pt1 P2 84.52(17) . .
C32 Pt1 P2 84.52(17) 2_976 2_976
C32 Pt1 P2 95.48(17) . 2_976
P2 Pt1 P2 180.000(2) . 2_976
C32 Pt1 Au1 105.71(15) 2_976 2_976
C32 Pt1 Au1 74.29(15) . 2_976
P2 Pt1 Au1 87.61(4) . 2_976
P2 Pt1 Au1 92.39(4) 2_976 2_976
C32 Pt1 Au1 74.29(15) 2_976 .
C32 Pt1 Au1 105.71(15) . .
P2 Pt1 Au1 92.39(4) . .
P2 Pt1 Au1 87.61(4) 2_976 .
Au1 Pt1 Au1 180.000(8) 2_976 .
P1 Au1 P3 175.40(6) . .
P1 Au1 Pt1 90.04(4) . .
P3 Au1 Pt1 94.43(4) . .
C14 P1 C20 107.7(3) . .
C14 P1 C66 104.5(3) . .
C20 P1 C66 104.9(3) . .
C14 P1 Au1 113.6(3) . .
C20 P1 Au1 112.2(3) . .
C66 P1 Au1 113.2(2) . .
C6 C1 C2 119.0(8) . .
C6 C1 P3 118.8(6) . .
C2 C1 P3 122.1(6) . .
C3 C2 C1 117.8(10) . .
C2 C3 C4 122.3(12) . .
C5 C4 C3 120.0(12) . .
C4 C5 C6 120.2(13) . .
C1 C6 C5 120.7(10) . .
C8 C7 C12 116.0(9) . .
C8 C7 P3 123.4(8) . .
C12 C7 P3 120.5(7) . .
C7 C8 C9 120.8(11) . .
C10 C9 C8 122.6(12) . .
C9 C10 C11 116.7(12) . .
C10 C11 C12 124.0(13) . .
C7 C12 C11 118.7(11) . .
P3 C13 P2 115.0(3) . 2_976
C15 C14 C19 117.7(7) . .
C15 C14 P1 118.2(6) . .
C19 C14 P1 124.0(6) . .
C16 C15 C14 121.6(9) . .
C17 C16 C15 118.3(9) . .
C16 C17 C18 122.5(8) . .
C17 C18 C19 119.8(9) . .
C18 C19 C14 120.0(8) . .
C25 C20 C21 120.0(7) . .
C25 C20 P1 122.6(6) . .
C21 C20 P1 117.3(6) . .
C20 C21 C22 117.1(8) . .
C23 C22 C21 121.1(10) . .
C24 C23 C22 119.2(10) . .
C25 C24 C23 120.2(10) . .
C24 C25 C20 122.4(9) . .
C27 C26 C31 118.2(7) . .
C27 C26 P2 118.8(5) . .
C31 C26 P2 122.3(6) . .
C28 C27 C26 120.1(7) . .
C27 C28 C29 119.1(9) . .
C30 C29 C28 121.6(8) . .
C31 C30 C29 119.1(9) . .
C30 C31 C26 121.8(9) . .
C33 C32 Pt1 176.1(5) . .
C32 C33 C34 178.0(8) . .
C39 C34 C35 118.9(7) . .
C39 C34 C33 121.4(7) . .
C35 C34 C33 119.6(7) . .
C36 C35 C34 119.8(8) . .
C35 C36 C37 122.1(8) . .
C38 C37 C36 118.2(7) . .
C38 C37 C42 120.5(8) . .
C36 C37 C42 121.1(7) . .
C37 C38 C39 120.4(8) . .
C34 C39 C38 120.6(7) . .
N1 C40 C41 123.2(8) . .
N1 C40 C45 116.5(7) . .
C41 C40 C45 120.2(9) . .
C40 C41 C42 119.3(8) . .
C43 C42 C41 117.9(7) . .
C43 C42 C37 120.9(8) . .
C41 C42 C37 120.9(8) . .
C42 C43 C44 120.2(8) . .
N1 C44 C43 121.7(8) . .
N1 C44 C50 115.9(7) . .
C43 C44 C50 122.2(8) . .
C46 C45 N3 121.5(9) . .
C46 C45 C40 122.7(9) . .
N3 C45 C40 115.8(9) . .
C45 C46 C47 120.7(11) . .
C46 C47 C48 117.9(13) . .
C49 C48 C47 118.6(12) . .
N3 C49 C48 123.3(11) . .
N2 C50 C51 122.8(9) . .
N2 C50 C44 116.4(8) . .
C51 C50 C44 120.8(8) . .
C52 C51 C50 116.6(10) . .
C53 C52 C51 121.1(11) . .
C52 C53 C54 118.2(11) . .
N2 C54 C53 125.2(10) . .
F9' C55 F8 140(4) . .
F9' C55 F9 70.1(14) . .
F8 C55 F9 116.1(15) . .
F9' C55 F7 42.9(17) . .
F8 C55 F7 115.3(16) . .
F9 C55 F7 112.9(15) . .
F9' C55 F8' 114.8(15) . .
F8 C55 F8' 69.3(14) . .
F9 C55 F8' 48.9(12) . .
F7 C55 F8' 152(3) . .
F9' C55 F7' 115.2(16) . .
F8 C55 F7' 43.5(17) . .
F9 C55 F7' 155(3) . .
F7 C55 F7' 75.9(17) . .
F8' C55 F7' 112.8(16) . .
F9' C55 C56 111(2) . .
F8 C55 C56 106(2) . .
F9 C55 C56 102.7(18) . .
F7 C55 C56 101.7(19) . .
F8' C55 C56 103.1(18) . .
F7' C55 C56 97.4(19) . .
O2 C56 C57 125.6(11) . .
O2 C56 C55 113.8(11) . .
C57 C56 C55 120.6(12) . .
C58 C57 C56 122.5(13) . .
O1 C58 C57 126.2(14) . .
O1 C58 C59 113.5(12) . .
C57 C58 C59 120.3(12) . .
F11 C59 F10' 71.8(14) . .
F11 C59 F11' 38.9(19) . .
F10' C59 F11' 109.1(15) . .
F11 C59 F10 107.8(13) . .
F10' C59 F10 41.4(13) . .
F11' C59 F10 135(3) . .
F11 C59 F12 108.2(15) . .
F10' C59 F12 140(3) . .
F11' C59 F12 73(2) . .
F10 C59 F12 108.7(15) . .
F11 C59 F12' 130(3) . .
F10' C59 F12' 108.1(15) . .
F11' C59 F12' 106.8(14) . .
F10 C59 F12' 69.6(15) . .
F12 C59 F12' 40.3(18) . .
F11 C59 C58 113(2) . .
F10' C59 C58 108(2) . .
F11' C59 C58 111(2) . .
F10 C59 C58 111.2(16) . .
F12 C59 C58 108(2) . .
F12' C59 C58 113.8(18) . .
F2' C60 F1' 111.3(12) . .
F2' C60 F1 127(2) . .
F1' C60 F1 65.9(12) . .
F2' C60 F3' 108.7(12) . .
F1' C60 F3' 106.3(12) . .
F1 C60 F3' 40.6(13) . .
F2' C60 F2 64.5(11) . .
F1' C60 F2 48.6(11) . .
F1 C60 F2 104.5(11) . .
F3' C60 F2 133.9(18) . .
F2' C60 F3 41.3(10) . .
F1' C60 F3 142.7(18) . .
F1 C60 F3 107.7(12) . .
F3' C60 F3 73.0(12) . .
F2 C60 F3 104.1(10) . .
F2' C60 C61 111.8(16) . .
F1' C60 C61 109.4(14) . .
F1 C60 C61 118.3(17) . .
F3' C60 C61 109.1(14) . .
F2 C60 C61 115.6(12) . .
F3 C60 C61 105.6(13) . .
O5 C61 C62 126.5(12) . .
O5 C61 C60 112.7(10) . .
C62 C61 C60 120.8(12) . .
C61 C62 C63 124.4(12) . .
O6 C63 C62 120.3(12) . .
O6 C63 C64 120.2(13) . .
C62 C63 C64 118.3(13) . .
P2 C66 P1 114.5(4) . .
F4' C76 F6 134(3) . .
F4' C76 F4 44.0(16) . .
F6 C76 F4 110.8(13) . .
F4' C76 F5 65.5(16) . .
F6 C76 F5 111.4(14) . .
F4 C76 F5 108.9(13) . .
F4' C76 F6' 111.8(14) . .
F6 C76 F6' 44.5(14) . .
F4 C76 F6' 71.8(14) . .
F5 C76 F6' 147(3) . .
F4' C76 F5' 111.2(13) . .
F6 C76 F5' 64.9(15) . .
F4 C76 F5' 144(2) . .
F5 C76 F5' 50.3(16) . .
F6' C76 F5' 109.0(13) . .
F4' C76 C77 112.0(19) . .
F6 C76 C77 112.5(16) . .
F4 C76 C77 106.9(15) . .
F5 C76 C77 106.0(16) . .
F6' C76 C77 105.4(17) . .
F5' C76 C77 107.2(15) . .
O3 C77 C78 125.1(13) . .
O3 C77 C76 115.7(12) . .
C78 C77 C76 118.8(12) . .
C77 C78 C79 122.4(13) . .
O4 C79 C78 127.4(14) . .
O4 C79 C80 119.1(14) . .
C78 C79 C80 113.3(13) . .
F16' C80 F17' 108.4(14) . .
F16' C80 F16 38.7(16) . .
F17' C80 F16 138(2) . .
F16' C80 F18' 106.5(15) . .
F17' C80 F18' 106.5(15) . .
F16 C80 F18' 74(2) . .
F16' C80 F18 118(3) . .
F17' C80 F18 63(2) . .
F16 C80 F18 105.2(14) . .
F18' C80 F18 43.6(19) . .
F16' C80 F17 65.1(15) . .
F17' C80 F17 49.8(15) . .
F16 C80 F17 103.5(14) . .
F18' C80 F17 141(3) . .
F18 C80 F17 104.7(15) . .
F16' C80 C79 124(2) . .
F17' C80 C79 111(2) . .
F16 C80 C79 110.4(16) . .
F18' C80 C79 99.1(16) . .
F18 C80 C79 114.7(18) . .
F17 C80 C79 117(2) . .
C40 N1 C44 117.5(6) . .
C40 N1 Eu1 121.0(5) . .
C44 N1 Eu1 120.3(5) . .
O4 Eu1 O3 74.1(3) . .
O4 Eu1 O2 69.2(3) . .
O3 Eu1 O2 72.8(4) . .
O4 Eu1 O5 74.1(3) . .
O3 Eu1 O5 133.2(3) . .
O2 Eu1 O5 124.5(3) . .
O4 Eu1 O1 134.8(3) . .
O3 Eu1 O1 79.4(3) . .
O2 Eu1 O1 68.2(3) . .
O5 Eu1 O1 145.8(2) . .
O4 Eu1 O6 72.5(4) . .
O3 Eu1 O6 71.1(4) . .
O2 Eu1 O6 132.8(4) . .
O5 Eu1 O6 67.2(3) . .
O1 Eu1 O6 131.2(3) . .
O4 Eu1 N2 139.9(3) . .
O3 Eu1 N2 84.0(3) . .
O2 Eu1 N2 135.3(3) . .
O5 Eu1 N2 99.3(2) . .
O1 Eu1 N2 70.3(2) . .
O6 Eu1 N2 68.7(3) . .
O4 Eu1 N3 87.8(3) . .
O3 Eu1 N3 142.6(3) . .
O2 Eu1 N3 70.2(3) . .
O5 Eu1 N3 68.2(2) . .
O1 Eu1 N3 91.8(3) . .
O6 Eu1 N3 134.5(3) . .
N2 Eu1 N3 127.3(2) . .
O4 Eu1 N1 142.1(3) . .
O3 Eu1 N1 143.5(3) . .
O2 Eu1 N1 117.6(3) . .
O5 Eu1 N1 72.5(2) . .
O1 Eu1 N1 73.8(2) . .
O6 Eu1 N1 109.5(3) . .
N2 Eu1 N1 64.0(2) . .
N3 Eu1 N1 63.5(2) . .
C58 O1 Eu1 136.5(8) . .
C56 O2 Eu1 136.5(8) . .
C26 P2 C66 108.8(3) . .
C26 P2 C13 102.0(3) . 2_976
C66 P2 C13 102.7(3) . 2_976
C26 P2 Pt1 121.3(2) . .
C66 P2 Pt1 107.3(2) . .
C13 P2 Pt1 113.2(2) 2_976 .
C54 N2 C50 116.1(9) . .
C54 N2 Eu1 121.3(7) . .
C50 N2 Eu1 122.0(6) . .
C77 O3 Eu1 132.9(9) . .
C7 P3 C13 104.4(4) . .
C7 P3 C1 107.2(4) . .
C13 P3 C1 107.5(3) . .
C7 P3 Au1 113.2(3) . .
C13 P3 Au1 111.3(2) . .
C1 P3 Au1 112.7(3) . .
C49 N3 C45 117.7(10) . .
C49 N3 Eu1 120.7(8) . .
C45 N3 Eu1 121.5(6) . .
C79 O4 Eu1 133.1(10) . .
C61 O5 Eu1 134.9(7) . .
C63 O6 Eu1 140.3(8) . .
F14 C64 F15 112.9(12) . .
F14 C64 F14' 45.3(15) . .
F15 C64 F14' 70.3(14) . .
F14 C64 F15' 140(2) . .
F15 C64 F15' 43.8(14) . .
F14' C64 F15' 110.4(12) . .
F14 C64 F13 110.5(12) . .
F15 C64 F13 113.0(13) . .
F14' C64 F13 145(2) . .
F15' C64 F13 70.2(15) . .
F14 C64 F13' 67.4(15) . .
F15 C64 F13' 145(2) . .
F14' C64 F13' 110.9(12) . .
F15' C64 F13' 112.0(13) . .
F13 C64 F13' 45.4(16) . .
F14 C64 C63 112.0(15) . .
F15 C64 C63 103.3(15) . .
F14' C64 C63 108.9(14) . .
F15' C64 C63 105.9(15) . .
F13 C64 C63 104.6(14) . .
F13' C64 C63 108.6(18) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cl1 O10 1.408(8) .
Cl1 O7' 1.409(8) .
Cl1 O9' 1.410(8) .
Cl1 O8 1.413(8) .
Cl1 O7 1.419(8) .
Cl1 O9 1.431(8) .
Cl1 O10' 1.432(8) .
Cl1 O8' 1.432(8) .
Pt1 C32 2.035(7) 2_976
Pt1 C32 2.035(7) .
Pt1 P2 2.3097(16) .
Pt1 P2 2.3097(16) 2_976
Pt1 Au1 2.9504(3) 2_976
Pt1 Au1 2.9504(3) .
Au1 P1 2.3084(18) .
Au1 P3 2.3176(17) .
P1 C14 1.799(7) .
P1 C20 1.807(7) .
P1 C66 1.840(6) .
C1 C6 1.365(11) .
C1 C2 1.401(11) .
C1 P3 1.810(7) .
C2 C3 1.355(13) .
C3 C4 1.370(17) .
C4 C5 1.314(17) .
C5 C6 1.383(13) .
C7 C8 1.339(12) .
C7 C12 1.342(12) .
C7 P3 1.782(8) .
C8 C9 1.441(13) .
C9 C10 1.260(14) .
C10 C11 1.294(16) .
C11 C12 1.435(14) .
C13 P3 1.810(6) .
C13 P2 1.828(6) 2_976
C14 C15 1.386(10) .
C14 C19 1.400(10) .
C15 C16 1.372(11) .
C16 C17 1.348(14) .
C17 C18 1.353(13) .
C18 C19 1.364(10) .
C20 C25 1.373(10) .
C20 C21 1.394(10) .
C21 C22 1.421(11) .
C22 C23 1.391(14) .
C23 C24 1.372(15) .
C24 C25 1.350(12) .
C26 C27 1.397(10) .
C26 C31 1.403(10) .
C26 P2 1.801(7) .
C27 C28 1.367(10) .
C28 C29 1.389(14) .
C29 C30 1.366(14) .
C30 C31 1.339(11) .
C32 C33 1.176(8) .
C33 C34 1.443(9) .
C34 C39 1.392(10) .
C34 C35 1.393(10) .
C35 C36 1.376(10) .
C36 C37 1.393(11) .
C37 C38 1.383(10) .
C37 C42 1.501(10) .
C38 C39 1.400(10) .
C40 N1 1.345(10) .
C40 C41 1.373(10) .
C40 C45 1.495(11) .
C41 C42 1.399(11) .
C42 C43 1.375(11) .
C43 C44 1.386(10) .
C44 N1 1.364(9) .
C44 C50 1.491(11) .
C45 C46 1.353(13) .
C45 N3 1.364(11) .
C46 C47 1.359(14) .
C47 C48 1.393(16) .
C48 C49 1.365(15) .
C49 N3 1.316(12) .
C50 N2 1.344(10) .
C50 C51 1.414(12) .
C51 C52 1.359(13) .
C52 C53 1.346(14) .
C53 C54 1.354(14) .
C54 N2 1.319(11) .
C55 F9' 1.300(10) .
C55 F8 1.304(10) .
C55 F9 1.316(10) .
C55 F7 1.320(10) .
C55 F8' 1.321(10) .
C55 F7' 1.326(10) .
C55 C56 1.69(3) .
C56 O2 1.290(15) .
C56 C57 1.399(17) .
C57 C58 1.334(16) .
C58 O1 1.241(13) .
C58 C59 1.49(2) .
C59 F11 1.306(10) .
C59 F10' 1.309(10) .
C59 F11' 1.311(10) .
C59 F10 1.313(10) .
C59 F12 1.316(10) .
C59 F12' 1.318(10) .
C60 F2' 1.288(9) .
C60 F1' 1.301(9) .
C60 F1 1.310(10) .
C60 F3' 1.313(9) .
C60 F2 1.316(9) .
C60 F3 1.332(9) .
C60 C61 1.519(9) .
C61 O5 1.282(12) .
C61 C62 1.326(14) .
C62 C63 1.382(18) .
C63 O6 1.245(16) .
C63 C64 1.565(9) .
C66 P2 1.818(6) .
C76 F4' 1.296(10) .
C76 F6 1.307(10) .
C76 F4 1.313(9) .
C76 F5 1.315(10) .
C76 F6' 1.317(10) .
C76 F5' 1.318(10) .
C76 C77 1.557(14) .
C77 O3 1.230(15) .
C77 C78 1.423(18) .
C78 C79 1.444(19) .
C79 O4 1.214(15) .
C79 C80 1.580(15) .
C80 F16' 1.295(10) .
C80 F17' 1.298(10) .
C80 F16 1.311(10) .
C80 F18' 1.314(10) .
C80 F18 1.314(10) .
C80 F17 1.322(10) .
N1 Eu1 2.565(6) .
Eu1 O4 2.350(8) .
Eu1 O3 2.358(8) .
Eu1 O2 2.398(9) .
Eu1 O5 2.416(7) .
Eu1 O1 2.444(7) .
Eu1 O6 2.466(9) .
Eu1 N2 2.533(8) .
Eu1 N3 2.558(9) .
F13 C64 1.322(10) .
F13' C64 1.329(10) .
F14 C64 1.318(9) .
F14' C64 1.319(10) .
F15 C64 1.318(10) .
F15' C64 1.319(10) .
P2 C13 1.828(6) 2_976
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C32 Pt1 Au1 P1 105.36(18) 2_976 . . .
C32 Pt1 Au1 P1 -74.64(18) . . . .
P2 Pt1 Au1 P1 10.33(6) . . . .
P2 Pt1 Au1 P1 -169.67(6) 2_976 . . .
Au1 Pt1 Au1 P1 -126(100) 2_976 . . .
C32 Pt1 Au1 P3 -73.53(18) 2_976 . . .
C32 Pt1 Au1 P3 106.47(18) . . . .
P2 Pt1 Au1 P3 -168.55(6) . . . .
P2 Pt1 Au1 P3 11.45(6) 2_976 . . .
Au1 Pt1 Au1 P3 55(100) 2_976 . . .
P3 Au1 P1 C14 -60.1(8) . . . .
Pt1 Au1 P1 C14 134.0(3) . . . .
P3 Au1 P1 C20 62.5(8) . . . .
Pt1 Au1 P1 C20 -103.5(2) . . . .
P3 Au1 P1 C66 -179(100) . . . .
Pt1 Au1 P1 C66 15.0(2) . . . .
C6 C1 C2 C3 0.3(13) . . . .
P3 C1 C2 C3 179.9(8) . . . .
C1 C2 C3 C4 -0.5(17) . . . .
C2 C3 C4 C5 0(2) . . . .
C3 C4 C5 C6 0(2) . . . .
C2 C1 C6 C5 0.2(13) . . . .
P3 C1 C6 C5 -179.3(8) . . . .
C4 C5 C6 C1 -0.6(18) . . . .
C12 C7 C8 C9 8.6(17) . . . .
P3 C7 C8 C9 -175.5(9) . . . .
C7 C8 C9 C10 -5(2) . . . .
C8 C9 C10 C11 -5(2) . . . .
C9 C10 C11 C12 11(3) . . . .
C8 C7 C12 C11 -3.1(18) . . . .
P3 C7 C12 C11 -179.1(10) . . . .
C10 C11 C12 C7 -7(2) . . . .
C20 P1 C14 C15 -98.3(7) . . . .
C66 P1 C14 C15 150.5(7) . . . .
Au1 P1 C14 C15 26.6(8) . . . .
C20 P1 C14 C19 85.1(8) . . . .
C66 P1 C14 C19 -26.1(8) . . . .
Au1 P1 C14 C19 -149.9(7) . . . .
C19 C14 C15 C16 -1.8(14) . . . .
P1 C14 C15 C16 -178.6(9) . . . .
C14 C15 C16 C17 -1.4(18) . . . .
C15 C16 C17 C18 2(2) . . . .
C16 C17 C18 C19 0.4(19) . . . .
C17 C18 C19 C14 -3.8(16) . . . .
C15 C14 C19 C18 4.4(14) . . . .
P1 C14 C19 C18 -179.0(7) . . . .
C14 P1 C20 C25 -38.0(7) . . . .
C66 P1 C20 C25 72.9(7) . . . .
Au1 P1 C20 C25 -163.8(6) . . . .
C14 P1 C20 C21 144.8(6) . . . .
C66 P1 C20 C21 -104.2(6) . . . .
Au1 P1 C20 C21 19.0(6) . . . .
C25 C20 C21 C22 -1.2(11) . . . .
P1 C20 C21 C22 176.1(6) . . . .
C20 C21 C22 C23 0.8(14) . . . .
C21 C22 C23 C24 0.1(17) . . . .
C22 C23 C24 C25 -0.6(19) . . . .
C23 C24 C25 C20 0.2(18) . . . .
C21 C20 C25 C24 0.7(14) . . . .
P1 C20 C25 C24 -176.4(8) . . . .
C31 C26 C27 C28 1.6(11) . . . .
P2 C26 C27 C28 172.9(6) . . . .
C26 C27 C28 C29 0.4(13) . . . .
C27 C28 C29 C30 -2.8(15) . . . .
C28 C29 C30 C31 3.1(16) . . . .
C29 C30 C31 C26 -1.0(15) . . . .
C27 C26 C31 C30 -1.3(12) . . . .
P2 C26 C31 C30 -172.3(7) . . . .
C32 Pt1 C32 C33 5(100) 2_976 . . .
P2 Pt1 C32 C33 45(9) . . . .
P2 Pt1 C32 C33 -135(9) 2_976 . . .
Au1 Pt1 C32 C33 -44(9) 2_976 . . .
Au1 Pt1 C32 C33 136(9) . . . .
Pt1 C32 C33 C34 123(19) . . . .
C32 C33 C34 C39 -162(21) . . . .
C32 C33 C34 C35 22(22) . . . .
C39 C34 C35 C36 0.8(13) . . . .
C33 C34 C35 C36 177.2(8) . . . .
C34 C35 C36 C37 0.2(14) . . . .
C35 C36 C37 C38 -1.3(14) . . . .
C35 C36 C37 C42 -176.2(8) . . . .
C36 C37 C38 C39 1.2(13) . . . .
C42 C37 C38 C39 176.2(8) . . . .
C35 C34 C39 C38 -0.9(12) . . . .
C33 C34 C39 C38 -177.2(7) . . . .
C37 C38 C39 C34 -0.2(13) . . . .
N1 C40 C41 C42 -1.1(13) . . . .
C45 C40 C41 C42 180.0(8) . . . .
C40 C41 C42 C43 -0.3(12) . . . .
C40 C41 C42 C37 173.4(7) . . . .
C38 C37 C42 C43 -32.6(12) . . . .
C36 C37 C42 C43 142.2(9) . . . .
C38 C37 C42 C41 153.9(8) . . . .
C36 C37 C42 C41 -31.3(12) . . . .
C41 C42 C43 C44 -0.9(12) . . . .
C37 C42 C43 C44 -174.6(7) . . . .
C42 C43 C44 N1 3.5(12) . . . .
C42 C43 C44 C50 177.8(7) . . . .
N1 C40 C45 C46 171.5(11) . . . .
C41 C40 C45 C46 -9.5(16) . . . .
N1 C40 C45 N3 -7.8(12) . . . .
C41 C40 C45 N3 171.2(8) . . . .
N3 C45 C46 C47 -1(2) . . . .
C40 C45 C46 C47 179.9(14) . . . .
C45 C46 C47 C48 -2(3) . . . .
C46 C47 C48 C49 6(3) . . . .
C47 C48 C49 N3 -6(2) . . . .
N1 C44 C50 N2 13.6(11) . . . .
C43 C44 C50 N2 -161.0(8) . . . .
N1 C44 C50 C51 -167.4(8) . . . .
C43 C44 C50 C51 18.0(12) . . . .
N2 C50 C51 C52 1.2(14) . . . .
C44 C50 C51 C52 -177.7(8) . . . .
C50 C51 C52 C53 -2.7(16) . . . .
C51 C52 C53 C54 2.8(18) . . . .
C52 C53 C54 N2 -1.4(19) . . . .
F9' C55 C56 O2 171(2) . . . .
F8 C55 C56 O2 -25(2) . . . .
F9 C55 C56 O2 97.5(19) . . . .
F7 C55 C56 O2 -145.5(19) . . . .
F8' C55 C56 O2 47(2) . . . .
F7' C55 C56 O2 -68(2) . . . .
F9' C55 C56 C57 -10(3) . . . .
F8 C55 C56 C57 154(2) . . . .
F9 C55 C56 C57 -84(2) . . . .
F7 C55 C56 C57 33(2) . . . .
F8' C55 C56 C57 -134(2) . . . .
F7' C55 C56 C57 111(2) . . . .
O2 C56 C57 C58 0(4) . . . .
C55 C56 C57 C58 -178.3(16) . . . .
C56 C57 C58 O1 5(3) . . . .
C56 C57 C58 C59 -173.4(17) . . . .
O1 C58 C59 F11 165.5(19) . . . .
C57 C58 C59 F11 -16(3) . . . .
O1 C58 C59 F10' 88(2) . . . .
C57 C58 C59 F10' -93(2) . . . .
O1 C58 C59 F11' -153(2) . . . .
C57 C58 C59 F11' 26(3) . . . .
O1 C58 C59 F10 44(2) . . . .
C57 C58 C59 F10 -137(2) . . . .
O1 C58 C59 F12 -75(2) . . . .
C57 C58 C59 F12 104(2) . . . .
O1 C58 C59 F12' -32(3) . . . .
C57 C58 C59 F12' 146(2) . . . .
F2' C60 C61 O5 -66.4(17) . . . .
F1' C60 C61 O5 57.3(17) . . . .
F1 C60 C61 O5 129.7(17) . . . .
F3' C60 C61 O5 173.2(14) . . . .
F2 C60 C61 O5 4.8(16) . . . .
F3 C60 C61 O5 -109.7(13) . . . .
F2' C60 C61 C62 114.9(18) . . . .
F1' C60 C61 C62 -121.4(18) . . . .
F1 C60 C61 C62 -49(2) . . . .
F3' C60 C61 C62 -5.4(19) . . . .
F2 C60 C61 C62 -173.9(14) . . . .
F3 C60 C61 C62 71.6(17) . . . .
O5 C61 C62 C63 -10(3) . . . .
C60 C61 C62 C63 168.8(14) . . . .
C61 C62 C63 O6 23(3) . . . .
C61 C62 C63 C64 -169.4(14) . . . .
C14 P1 C66 P2 -169.9(4) . . . .
C20 P1 C66 P2 76.8(4) . . . .
Au1 P1 C66 P2 -45.8(4) . . . .
F4' C76 C77 O3 159(2) . . . .
F6 C76 C77 O3 -32(2) . . . .
F4 C76 C77 O3 -154(2) . . . .
F5 C76 C77 O3 90(2) . . . .
F6' C76 C77 O3 -79(2) . . . .
F5' C76 C77 O3 37(2) . . . .
F4' C76 C77 C78 -27(2) . . . .
F6 C76 C77 C78 141(2) . . . .
F4 C76 C77 C78 19(2) . . . .
F5 C76 C77 C78 -97(2) . . . .
F6' C76 C77 C78 94(2) . . . .
F5' C76 C77 C78 -150(2) . . . .
O3 C77 C78 C79 -7(3) . . . .
C76 C77 C78 C79 -179.6(17) . . . .
C77 C78 C79 O4 0(4) . . . .
C77 C78 C79 C80 174.3(16) . . . .
O4 C79 C80 F16' 171(3) . . . .
C78 C79 C80 F16' -4(3) . . . .
O4 C79 C80 F17' 39(3) . . . .
C78 C79 C80 F17' -136(3) . . . .
O4 C79 C80 F16 -148(3) . . . .
C78 C79 C80 F16 37(3) . . . .
O4 C79 C80 F18' -72(3) . . . .
C78 C79 C80 F18' 113(3) . . . .
O4 C79 C80 F18 -30(3) . . . .
C78 C79 C80 F18 155(3) . . . .
O4 C79 C80 F17 94(3) . . . .
C78 C79 C80 F17 -81(3) . . . .
C41 C40 N1 C44 3.6(12) . . . .
C45 C40 N1 C44 -177.4(7) . . . .
C41 C40 N1 Eu1 -164.2(6) . . . .
C45 C40 N1 Eu1 14.8(10) . . . .
C43 C44 N1 C40 -4.8(11) . . . .
C50 C44 N1 C40 -179.4(7) . . . .
C43 C44 N1 Eu1 163.1(6) . . . .
C50 C44 N1 Eu1 -11.5(9) . . . .
C40 N1 Eu1 O4 33.2(8) . . . .
C44 N1 Eu1 O4 -134.3(7) . . . .
C40 N1 Eu1 O3 -156.3(7) . . . .
C44 N1 Eu1 O3 36.3(8) . . . .
C40 N1 Eu1 O2 -58.0(6) . . . .
C44 N1 Eu1 O2 134.6(5) . . . .
C40 N1 Eu1 O5 62.4(6) . . . .
C44 N1 Eu1 O5 -105.1(6) . . . .
C40 N1 Eu1 O1 -111.9(6) . . . .
C44 N1 Eu1 O1 80.6(6) . . . .
C40 N1 Eu1 O6 119.5(6) . . . .
C44 N1 Eu1 O6 -48.0(6) . . . .
C40 N1 Eu1 N2 172.5(6) . . . .
C44 N1 Eu1 N2 5.0(5) . . . .
C40 N1 Eu1 N3 -11.4(6) . . . .
C44 N1 Eu1 N3 -178.9(6) . . . .
C57 C58 O1 Eu1 -24(3) . . . .
C59 C58 O1 Eu1 154.6(9) . . . .
O4 Eu1 O1 C58 2.9(16) . . . .
O3 Eu1 O1 C58 -51.9(15) . . . .
O2 Eu1 O1 C58 23.7(14) . . . .
O5 Eu1 O1 C58 143.4(14) . . . .
O6 Eu1 O1 C58 -104.9(15) . . . .
N2 Eu1 O1 C58 -139.3(15) . . . .
N3 Eu1 O1 C58 91.5(15) . . . .
N1 Eu1 O1 C58 153.2(15) . . . .
C57 C56 O2 Eu1 13(3) . . . .
C55 C56 O2 Eu1 -168.5(9) . . . .
O4 Eu1 O2 C56 146.7(18) . . . .
O3 Eu1 O2 C56 67.6(17) . . . .
O5 Eu1 O2 C56 -161.4(17) . . . .
O1 Eu1 O2 C56 -17.7(17) . . . .
O6 Eu1 O2 C56 108.9(17) . . . .
N2 Eu1 O2 C56 5(2) . . . .
N3 Eu1 O2 C56 -118.1(18) . . . .
N1 Eu1 O2 C56 -74.4(18) . . . .
C27 C26 P2 C66 155.3(5) . . . .
C31 C26 P2 C66 -33.8(7) . . . .
C27 C26 P2 C13 -96.7(6) . . . 2_976
C31 C26 P2 C13 74.2(6) . . . 2_976
C27 C26 P2 Pt1 30.3(6) . . . .
C31 C26 P2 Pt1 -158.8(5) . . . .
P1 C66 P2 C26 -78.4(4) . . . .
P1 C66 P2 C13 174.0(3) . . . 2_976
P1 C66 P2 Pt1 54.5(4) . . . .
C32 Pt1 P2 C26 17.2(3) 2_976 . . .
C32 Pt1 P2 C26 -162.8(3) . . . .
P2 Pt1 P2 C26 -150(100) 2_976 . . .
Au1 Pt1 P2 C26 -88.4(3) 2_976 . . .
Au1 Pt1 P2 C26 91.6(3) . . . .
C32 Pt1 P2 C66 -108.5(3) 2_976 . . .
C32 Pt1 P2 C66 71.5(3) . . . .
P2 Pt1 P2 C66 84(100) 2_976 . . .
Au1 Pt1 P2 C66 145.9(2) 2_976 . . .
Au1 Pt1 P2 C66 -34.1(2) . . . .
C32 Pt1 P2 C13 138.9(3) 2_976 . . 2_976
C32 Pt1 P2 C13 -41.1(3) . . . 2_976
P2 Pt1 P2 C13 -29(100) 2_976 . . 2_976
Au1 Pt1 P2 C13 33.3(2) 2_976 . . 2_976
Au1 Pt1 P2 C13 -146.7(2) . . . 2_976
C53 C54 N2 C50 -0.1(17) . . . .
C53 C54 N2 Eu1 -171.5(9) . . . .
C51 C50 N2 C54 0.2(14) . . . .
C44 C50 N2 C54 179.1(8) . . . .
C51 C50 N2 Eu1 171.5(7) . . . .
C44 C50 N2 Eu1 -9.6(10) . . . .
O4 Eu1 N2 C54 -44.8(10) . . . .
O3 Eu1 N2 C54 11.8(8) . . . .
O2 Eu1 N2 C54 69.9(9) . . . .
O5 Eu1 N2 C54 -121.1(8) . . . .
O1 Eu1 N2 C54 92.7(8) . . . .
O6 Eu1 N2 C54 -60.2(8) . . . .
N3 Eu1 N2 C54 169.3(7) . . . .
N1 Eu1 N2 C54 173.7(9) . . . .
O4 Eu1 N2 C50 144.4(6) . . . .
O3 Eu1 N2 C50 -159.1(7) . . . .
O2 Eu1 N2 C50 -101.0(8) . . . .
O5 Eu1 N2 C50 68.0(7) . . . .
O1 Eu1 N2 C50 -78.2(7) . . . .
O6 Eu1 N2 C50 128.9(7) . . . .
N3 Eu1 N2 C50 -1.5(8) . . . .
N1 Eu1 N2 C50 2.8(6) . . . .
C78 C77 O3 Eu1 26(2) . . . .
C76 C77 O3 Eu1 -161.8(8) . . . .
O4 Eu1 O3 C77 -24.5(12) . . . .
O2 Eu1 O3 C77 48.2(13) . . . .
O5 Eu1 O3 C77 -73.3(15) . . . .
O1 Eu1 O3 C77 118.4(14) . . . .
O6 Eu1 O3 C77 -101.0(13) . . . .
N2 Eu1 O3 C77 -170.5(14) . . . .
N3 Eu1 O3 C77 39.5(16) . . . .
N1 Eu1 O3 C77 161.5(11) . . . .
C8 C7 P3 C13 -49.5(10) . . . .
C12 C7 P3 C13 126.2(9) . . . .
C8 C7 P3 C1 64.4(10) . . . .
C12 C7 P3 C1 -119.9(9) . . . .
C8 C7 P3 Au1 -170.7(8) . . . .
C12 C7 P3 Au1 5.0(10) . . . .
P2 C13 P3 C7 -160.3(4) 2_976 . . .
P2 C13 P3 C1 86.1(4) 2_976 . . .
P2 C13 P3 Au1 -37.8(4) 2_976 . . .
C6 C1 P3 C7 97.9(7) . . . .
C2 C1 P3 C7 -81.7(8) . . . .
C6 C1 P3 C13 -150.4(6) . . . .
C2 C1 P3 C13 30.1(7) . . . .
C6 C1 P3 Au1 -27.4(7) . . . .
C2 C1 P3 Au1 153.1(6) . . . .
P1 Au1 P3 C7 -37.9(9) . . . .
Pt1 Au1 P3 C7 128.1(3) . . . .
P1 Au1 P3 C13 -155.2(7) . . . .
Pt1 Au1 P3 C13 10.8(2) . . . .
P1 Au1 P3 C1 84.0(8) . . . .
Pt1 Au1 P3 C1 -110.1(3) . . . .
C48 C49 N3 C45 3.3(18) . . . .
C48 C49 N3 Eu1 -174.2(11) . . . .
C46 C45 N3 C49 0.5(16) . . . .
C40 C45 N3 C49 179.8(9) . . . .
C46 C45 N3 Eu1 178.0(10) . . . .
C40 C45 N3 Eu1 -2.7(11) . . . .
O4 Eu1 N3 C49 30.0(8) . . . .
O3 Eu1 N3 C49 -29.9(10) . . . .
O2 Eu1 N3 C49 -38.7(8) . . . .
O5 Eu1 N3 C49 103.7(8) . . . .
O1 Eu1 N3 C49 -104.8(8) . . . .
O6 Eu1 N3 C49 92.5(8) . . . .
N2 Eu1 N3 C49 -171.2(7) . . . .
N1 Eu1 N3 C49 -175.6(8) . . . .
O4 Eu1 N3 C45 -147.5(8) . . . .
O3 Eu1 N3 C45 152.6(7) . . . .
O2 Eu1 N3 C45 143.8(8) . . . .
O5 Eu1 N3 C45 -73.8(7) . . . .
O1 Eu1 N3 C45 77.8(7) . . . .
O6 Eu1 N3 C45 -84.9(8) . . . .
N2 Eu1 N3 C45 11.3(8) . . . .
N1 Eu1 N3 C45 6.9(7) . . . .
C78 C79 O4 Eu1 -11(4) . . . .
C80 C79 O4 Eu1 174.8(10) . . . .
O3 Eu1 O4 C79 16.9(19) . . . .
O2 Eu1 O4 C79 -60.3(19) . . . .
O5 Eu1 O4 C79 162(2) . . . .
O1 Eu1 O4 C79 -40(2) . . . .
O6 Eu1 O4 C79 91.6(19) . . . .
N2 Eu1 O4 C79 77(2) . . . .
N3 Eu1 O4 C79 -129.9(19) . . . .
N1 Eu1 O4 C79 -168.9(17) . . . .
C62 C61 O5 Eu1 -21(2) . . . .
C60 C61 O5 Eu1 160.8(7) . . . .
O4 Eu1 O5 C61 -53.8(11) . . . .
O3 Eu1 O5 C61 -5.0(12) . . . .
O2 Eu1 O5 C61 -103.7(11) . . . .
O1 Eu1 O5 C61 154.2(10) . . . .
O6 Eu1 O5 C61 23.6(10) . . . .
N2 Eu1 O5 C61 85.6(10) . . . .
N3 Eu1 O5 C61 -147.8(11) . . . .
N1 Eu1 O5 C61 144.4(11) . . . .
C62 C63 O6 Eu1 -7(3) . . . .
C64 C63 O6 Eu1 -175.1(9) . . . .
O4 Eu1 O6 C63 69.7(17) . . . .
O3 Eu1 O6 C63 148.5(18) . . . .
O2 Eu1 O6 C63 106.6(17) . . . .
O5 Eu1 O6 C63 -9.9(16) . . . .
O1 Eu1 O6 C63 -155.4(16) . . . .
N2 Eu1 O6 C63 -120.6(17) . . . .
N3 Eu1 O6 C63 1.3(19) . . . .
N1 Eu1 O6 C63 -70.2(17) . . . .
O6 C63 C64 F14 -168(2) . . . .
C62 C63 C64 F14 24(3) . . . .
O6 C63 C64 F15 70(2) . . . .
C62 C63 C64 F15 -98(2) . . . .
O6 C63 C64 F14' 143(2) . . . .
C62 C63 C64 F14' -25(3) . . . .
O6 C63 C64 F15' 25(2) . . . .
C62 C63 C64 F15' -143(2) . . . .
O6 C63 C64 F13 -49(3) . . . .
C62 C63 C64 F13 144(2) . . . .
O6 C63 C64 F13' -96(3) . . . .
C62 C63 C64 F13' 96(3) . . . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.050 0.500 0.029 1950 178 ' '
