#------------------------------------------------------------------------------
#$Date: 2019-09-19 08:43:13 +0200 (jue 19 de sep de 2019) $
#$Revision: 218527 $
#$URL: svn://www.crystallography.net/cod/cif/7/23/39/7233945.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7233945
loop_
_publ_author_name
'Anurach Poloek'
'Chiao-Wen Lin'
'Chin-Ti Chen'
'Chao-Tsen Chen'
_publ_section_title
;
 High colour rendering index and colour stable hybrid white efficient
 OLEDs with a double emitting layer structure using a single
 phosphorescence dopant of heteroleptic platinum complexes
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              10343
_journal_page_last               10356
_journal_paper_doi               10.1039/C4TC01791A
_journal_volume                  2
_journal_year                    2014
_chemical_formula_moiety         'C124 H72 F8 N16 O4 Pt4'
_chemical_formula_sum            'C124 H72 F8 N16 O4 Pt4'
_chemical_formula_weight         2782.33
_chemical_name_common            PtCz
_chemical_name_systematic        FPtCzND
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                90
_cell_angle_beta                 114.761(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   51.3810(14)
_cell_length_b                   7.9870(2)
_cell_length_c                   26.1603(7)
_cell_measurement_reflns_used    9605
_cell_measurement_temperature    100.0(2)
_cell_measurement_theta_max      27.75
_cell_measurement_theta_min      2.59
_cell_volume                     9748.7(5)
_computing_cell_refinement       'Bruker APEX2'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      100.0(2)
_diffrn_measured_fraction_theta_full 1
_diffrn_measured_fraction_theta_max 1
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0625
_diffrn_reflns_Laue_measured_fraction_full 1
_diffrn_reflns_Laue_measured_fraction_max 1
_diffrn_reflns_limit_h_max       64
_diffrn_reflns_limit_h_min       -64
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            105284
_diffrn_reflns_point_group_measured_fraction_full 1
_diffrn_reflns_point_group_measured_fraction_max 1
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         26.372
_diffrn_reflns_theta_min         0.873
_exptl_absorpt_coefficient_mu    5.807
_exptl_absorpt_correction_T_max  0.9591
_exptl_absorpt_correction_T_min  0.8284
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS, 1996'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.896
_exptl_crystal_density_meas      ?
_exptl_crystal_description       plate
_exptl_crystal_F_000             5376
_exptl_crystal_preparation       Luminescent
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: CH2Cl2/CH3OH'
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.01
_refine_diff_density_max         3.858
_refine_diff_density_min         -0.858
_refine_diff_density_rms         0.164
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.109
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     703
_refine_ls_number_reflns         9960
_refine_ls_number_restraints     251
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0332
_refine_ls_R_factor_gt           0.0282
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0366P)²+39.4148P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0707
_refine_ls_wR_factor_ref         0.0728
_reflns_number_gt                9016
_reflns_number_total             9960
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            1000001.cif
_cod_data_source_block           PCOD1000001
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7233945
_shelx_estimated_absorpt_t_min   0.654
_shelx_estimated_absorpt_t_max   0.944
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.37135(2) 0.70717(2) 0.03083(2) 0.01173(5) Uani 1 d . .
Pt2 Pt 0.36140(2) 0.35857(2) 0.07769(2) 0.01263(5) Uani 1 d . .
F1 F 0.38879(6) 1.0622(4) 0.21071(12) 0.0265(6) Uani 1 d . .
F2 F 0.47188(6) 0.8297(5) 0.21090(14) 0.0414(9) Uani 1 d . .
F3 F 0.46168(7) 0.4061(5) 0.24928(13) 0.0378(8) Uani 1 d . .
F4 F 0.46441(6) 0.1436(4) 0.09279(13) 0.0317(7) Uani 1 d . .
O1 O 0.33903(6) 0.6315(4) -0.04549(13) 0.0148(6) Uani 1 d . .
O2 O 0.31856(6) 0.4378(4) 0.04566(13) 0.0183(7) Uani 1 d . .
N1 N 0.34345(8) 0.8238(5) 0.05357(16) 0.0145(8) Uani 1 d . .
N2 N 0.39576(8) 0.5887(5) -0.00320(15) 0.0136(7) Uani 1 d . .
N3 N 0.37310(8) 0.3471(5) -0.13582(16) 0.0157(8) Uani 1 d . .
N4 N 0.43298(8) 0.2883(4) -0.08807(16) 0.0146(8) Uani 1 d . .
N5 N 0.37234(8) 0.4752(5) 0.15156(15) 0.0152(8) Uani 1 d . .
N6 N 0.34539(8) 0.2278(4) 0.00419(15) 0.0128(7) Uani 1 d . .
N7 N 0.27422(8) 0.2463(5) -0.11603(16) 0.0171(8) Uani 1 d . .
N8 N 0.29792(7) -0.0387(5) -0.14553(15) 0.0141(7) Uani 1 d . .
C1 C 0.31501(9) 0.8218(6) 0.0203(2) 0.0176(9) Uani 1 d . .
H1 H 0.308 0.7585 -0.0136 0.021 Uiso 1 calc . .
C2 C 0.29589(10) 0.9100(6) 0.0345(2) 0.0213(10) Uani 1 d . .
H2 H 0.2759 0.9068 0.0109 0.026 Uiso 1 calc . .
C3 C 0.30623(11) 1.0032(6) 0.0838(2) 0.0239(11) Uani 1 d . .
H3 H 0.2934 1.0661 0.0939 0.029 Uiso 1 calc . .
C4 C 0.33562(10) 1.0042(6) 0.1185(2) 0.0203(10) Uani 1 d . .
H4 H 0.3429 1.0665 0.1525 0.024 Uiso 1 calc . .
C5 C 0.35407(9) 0.9126(5) 0.10242(19) 0.0151(9) Uani 1 d . .
C6 C 0.38511(10) 0.8962(5) 0.13218(19) 0.0148(9) Uani 1 d . .
C7 C 0.40145(10) 0.9672(5) 0.1842(2) 0.0170(9) Uani 1 d . .
C8 C 0.43064(10) 0.9483(6) 0.2123(2) 0.0199(10) Uani 1 d . .
H8 H 0.4414 0.9979 0.248 0.024 Uiso 1 calc . .
C9 C 0.44315(10) 0.8512(7) 0.1847(2) 0.0231(11) Uani 1 d . .
C10 C 0.42817(10) 0.7763(6) 0.1333(2) 0.0206(10) Uani 1 d . .
H10 H 0.438 0.7095 0.117 0.025 Uiso 1 calc . .
C11 C 0.39875(10) 0.7979(5) 0.10521(19) 0.0141(9) Uani 1 d . .
C12 C 0.34869(9) 0.5425(5) -0.07520(19) 0.0139(9) Uani 1 d . .
C13 C 0.33207(9) 0.4761(6) -0.12814(19) 0.0158(9) Uani 1 d . .
H13 H 0.312 0.4948 -0.1454 0.019 Uiso 1 calc . .
C14 C 0.34522(10) 0.3820(6) -0.15550(19) 0.0172(9) Uani 1 d . .
H14 H 0.3332 0.3386 -0.1915 0.021 Uiso 1 calc . .
C15 C 0.38999(9) 0.4130(5) -0.08475(18) 0.0126(8) Uani 1 d . .
C16 C 0.42047(9) 0.3898(5) -0.06073(19) 0.0143(9) Uani 1 d . .
C17 C 0.43685(9) 0.4758(6) -0.01239(19) 0.0177(9) Uani 1 d . .
H17 H 0.4572 0.4683 0.0029 0.021 Uiso 1 calc . .
C18 C 0.42390(9) 0.5740(6) 0.01439(19) 0.0180(9) Uani 1 d . .
H18 H 0.4359 0.6339 0.0472 0.022 Uiso 1 calc . .
C19 C 0.37893(9) 0.5107(5) -0.05350(18) 0.0121(8) Uani 1 d . .
C20 C 0.42559(9) 0.1219(6) -0.10507(19) 0.0159(9) Uani 1 d . .
C21 C 0.40639(9) 0.0182(6) -0.0955(2) 0.0181(9) Uani 1 d . .
H21 H 0.3956 0.0575 -0.076 0.022 Uiso 1 calc . .
C22 C 0.40347(10) -0.1440(6) -0.1155(2) 0.0194(10) Uani 1 d . .
H22 H 0.3902 -0.2168 -0.1102 0.023 Uiso 1 calc . .
C23 C 0.41960(10) -0.2028(6) -0.14300(19) 0.0192(10) Uani 1 d . .
H23 H 0.4169 -0.3144 -0.1569 0.023 Uiso 1 calc . .
C24 C 0.43941(10) -0.1014(6) -0.15044(19) 0.0189(10) Uani 1 d . .
H24 H 0.4508 -0.1435 -0.1684 0.023 Uiso 1 calc . .
C25 C 0.44264(9) 0.0641(6) -0.13141(18) 0.0142(9) Uani 1 d . .
C26 C 0.46138(9) 0.2001(5) -0.13050(19) 0.0147(9) Uani 1 d . .
C27 C 0.48244(10) 0.2206(6) -0.15053(19) 0.0182(9) Uani 1 d . .
H27 H 0.487 0.131 -0.1692 0.022 Uiso 1 calc . .
C28 C 0.49658(10) 0.3717(6) -0.1431(2) 0.0191(10) Uani 1 d . .
H28 H 0.5107 0.3862 -0.1572 0.023 Uiso 1 calc . .
C29 C 0.49034(9) 0.5036(6) -0.11502(19) 0.0174(9) Uani 1 d . .
H29 H 0.5005 0.606 -0.1099 0.021 Uiso 1 calc . .
C30 C 0.46955(9) 0.4883(6) -0.09443(19) 0.0160(9) Uani 1 d . .
H30 H 0.4652 0.5783 -0.0755 0.019 Uiso 1 calc . .
C31 C 0.45528(9) 0.3357(6) -0.10265(19) 0.0152(9) Uani 1 d . .
C32 C 0.35300(10) 0.5557(6) 0.1644(2) 0.0197(10) Uani 1 d . .
H32 H 0.3336 0.5597 0.1374 0.024 Uiso 1 calc . .
C33 C 0.36040(11) 0.6330(6) 0.2159(2) 0.0232(11) Uani 1 d . .
H33 H 0.3463 0.6883 0.2244 0.028 Uiso 1 calc . .
C34 C 0.38872(12) 0.6281(6) 0.2546(2) 0.0249(11) Uani 1 d . .
H34 H 0.3944 0.682 0.29 0.03 Uiso 1 calc . .
C35 C 0.40883(11) 0.5450(6) 0.2419(2) 0.0216(10) Uani 1 d . .
H35 H 0.4283 0.5411 0.2684 0.026 Uiso 1 calc . .
C36 C 0.40025(10) 0.4668(6) 0.18955(19) 0.0180(9) Uani 1 d . .
C37 C 0.41801(10) 0.3752(5) 0.16757(19) 0.0166(9) Uani 1 d . .
C38 C 0.44749(10) 0.3520(6) 0.1953(2) 0.0222(10) Uani 1 d . .
C39 C 0.46370(10) 0.2752(6) 0.1720(2) 0.0232(10) Uani 1 d . .
H39 H 0.4838 0.2611 0.1922 0.028 Uiso 1 calc . .
C40 C 0.44925(10) 0.2195(6) 0.1176(2) 0.0208(10) Uani 1 d . .
C41 C 0.41996(10) 0.2372(6) 0.0874(2) 0.0187(10) Uani 1 d . .
H41 H 0.4111 0.1978 0.0497 0.022 Uiso 1 calc . .
C42 C 0.40339(9) 0.3120(5) 0.11158(19) 0.0143(9) Uani 1 d . .
C43 C 0.35715(9) 0.1093(5) -0.01486(19) 0.0131(9) Uani 1 d . .
H43 H 0.3768 0.0826 0.0066 0.016 Uiso 1 calc . .
C44 C 0.34206(9) 0.0220(5) -0.06488(18) 0.0141(9) Uani 1 d . .
H44 H 0.3515 -0.0625 -0.0763 0.017 Uiso 1 calc . .
C45 C 0.31382(9) 0.0566(5) -0.09768(18) 0.0136(9) Uani 1 d . .
C46 C 0.30078(9) 0.1922(5) -0.08168(19) 0.0145(9) Uani 1 d . .
C47 C 0.26371(10) 0.3687(6) -0.0959(2) 0.0188(10) Uani 1 d . .
H47 H 0.2457 0.414 -0.1207 0.023 Uiso 1 calc . .
C48 C 0.27655(10) 0.4376(6) -0.0419(2) 0.0205(10) Uani 1 d . .
H48 H 0.2667 0.5181 -0.03 0.025 Uiso 1 calc . .
C49 C 0.30416(9) 0.3861(5) -0.00573(19) 0.0155(9) Uani 1 d . .
C50 C 0.31700(9) 0.2663(6) -0.02865(19) 0.0142(9) Uani 1 d . .
C51 C 0.30756(9) -0.0990(5) -0.18517(18) 0.0147(9) Uani 1 d . .
C52 C 0.33276(10) -0.0608(6) -0.19094(19) 0.0179(9) Uani 1 d . .
H52 H 0.3466 0.0136 -0.1657 0.022 Uiso 1 calc . .
C53 C 0.33666(10) -0.1363(6) -0.2350(2) 0.0206(10) Uani 1 d . .
H53 H 0.3536 -0.1138 -0.2399 0.025 Uiso 1 calc . .
C54 C 0.31613(10) -0.2447(6) -0.2725(2) 0.0217(10) Uani 1 d . .
H54 H 0.3196 -0.2961 -0.3018 0.026 Uiso 1 calc . .
C55 C 0.29091(10) -0.2779(6) -0.2675(2) 0.0209(10) Uani 1 d . .
H55 H 0.2768 -0.3491 -0.2937 0.025 Uiso 1 calc . .
C56 C 0.28664(10) -0.2047(5) -0.22329(19) 0.0160(9) Uani 1 d . .
C57 C 0.26343(10) -0.2143(5) -0.2055(2) 0.0171(9) Uani 1 d . .
C58 C 0.23775(10) -0.3014(6) -0.2260(2) 0.0216(10) Uani 1 d . .
H58 H 0.232 -0.3654 -0.2595 0.026 Uiso 1 calc . .
C59 C 0.22062(10) -0.2941(6) -0.1970(2) 0.0237(11) Uani 1 d . .
H59 H 0.203 -0.3537 -0.2106 0.028 Uiso 1 calc . .
C60 C 0.22909(10) -0.1995(6) -0.1478(2) 0.0218(10) Uani 1 d . .
H60 H 0.2173 -0.1977 -0.128 0.026 Uiso 1 calc . .
C61 C 0.25442(10) -0.1077(6) -0.1273(2) 0.0173(9) Uani 1 d . .
H61 H 0.26 -0.0429 -0.0939 0.021 Uiso 1 calc . .
C62 C 0.27126(9) -0.1140(5) -0.15714(19) 0.0154(9) Uani 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Pt1 C11 80.90(17) . .
N1 Pt1 N2 172.36(15) . .
C11 Pt1 N2 106.29(16) . .
N1 Pt1 O1 92.14(14) . .
C11 Pt1 O1 172.92(15) . .
N2 Pt1 O1 80.60(13) . .
N1 Pt1 Pt2 92.44(10) . .
C11 Pt1 Pt2 95.97(12) . .
N2 Pt1 Pt2 89.40(10) . .
O1 Pt1 Pt2 85.58(8) . .
C42 Pt2 N5 81.00(17) . .
C42 Pt2 N6 104.96(16) . .
N5 Pt2 N6 171.88(14) . .
C42 Pt2 O2 172.94(15) . .
N5 Pt2 O2 93.93(14) . .
N6 Pt2 O2 80.58(13) . .
C42 Pt2 Pt1 90.92(12) . .
N5 Pt2 Pt1 86.50(10) . .
N6 Pt2 Pt1 98.77(10) . .
O2 Pt2 Pt1 83.83(9) . .
C12 O1 Pt1 112.5(3) . .
C49 O2 Pt2 111.4(3) . .
C1 N1 C5 120.8(4) . .
C1 N1 Pt1 121.3(3) . .
C5 N1 Pt1 117.9(3) . .
C18 N2 C19 116.5(4) . .
C18 N2 Pt1 131.8(3) . .
C19 N2 Pt1 111.6(3) . .
C14 N3 C15 116.1(4) . .
C20 N4 C16 126.1(4) . .
C20 N4 C31 108.2(4) . .
C16 N4 C31 125.7(4) . .
C32 N5 C36 120.3(4) . .
C32 N5 Pt2 121.9(3) . .
C36 N5 Pt2 117.8(3) . .
C43 N6 C50 117.0(4) . .
C43 N6 Pt2 130.8(3) . .
C50 N6 Pt2 112.1(3) . .
C47 N7 C46 115.9(4) . .
C45 N8 C62 125.2(4) . .
C45 N8 C51 126.2(4) . .
C62 N8 C51 107.8(4) . .
N1 C1 C2 121.3(4) . .
N1 C1 H1 119.4 . .
C2 C1 H1 119.4 . .
C1 C2 C3 119.1(4) . .
C1 C2 H2 120.5 . .
C3 C2 H2 120.5 . .
C2 C3 C4 119.7(4) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C5 C4 C3 119.1(4) . .
C5 C4 H4 120.4 . .
C3 C4 H4 120.4 . .
N1 C5 C4 120.0(4) . .
N1 C5 C6 111.9(4) . .
C4 C5 C6 128.0(4) . .
C7 C6 C11 119.5(4) . .
C7 C6 C5 124.4(4) . .
C11 C6 C5 116.2(4) . .
F1 C7 C8 115.8(4) . .
F1 C7 C6 120.4(4) . .
C8 C7 C6 123.8(4) . .
C7 C8 C9 115.0(4) . .
C7 C8 H8 122.5 . .
C9 C8 H8 122.5 . .
F2 C9 C10 119.0(4) . .
F2 C9 C8 116.9(4) . .
C10 C9 C8 124.1(4) . .
C9 C10 C11 120.3(4) . .
C9 C10 H10 119.9 . .
C11 C10 H10 119.9 . .
C10 C11 C6 117.4(4) . .
C10 C11 Pt1 129.6(3) . .
C6 C11 Pt1 113.0(3) . .
O1 C12 C13 125.2(4) . .
O1 C12 C19 118.8(4) . .
C13 C12 C19 115.9(4) . .
C12 C13 C14 119.3(4) . .
C12 C13 H13 120.3 . .
C14 C13 H13 120.3 . .
N3 C14 C13 126.1(4) . .
N3 C14 H14 117 . .
C13 C14 H14 117 . .
N3 C15 C19 122.6(4) . .
N3 C15 C16 120.8(4) . .
C19 C15 C16 116.6(4) . .
C17 C16 N4 121.6(4) . .
C17 C16 C15 118.3(4) . .
N4 C16 C15 120.0(4) . .
C16 C17 C18 120.5(4) . .
C16 C17 H17 119.8 . .
C18 C17 H17 119.8 . .
N2 C18 C17 123.8(4) . .
N2 C18 H18 118.1 . .
C17 C18 H18 118.1 . .
N2 C19 C15 123.9(4) . .
N2 C19 C12 116.0(4) . .
C15 C19 C12 120.0(4) . .
C21 C20 C25 122.0(4) . .
C21 C20 N4 128.8(4) . .
C25 C20 N4 109.1(4) . .
C22 C21 C20 117.7(4) . .
C22 C21 H21 121.1 . .
C20 C21 H21 121.1 . .
C21 C22 C23 121.3(4) . .
C21 C22 H22 119.4 . .
C23 C22 H22 119.4 . .
C24 C23 C22 120.8(4) . .
C24 C23 H23 119.6 . .
C22 C23 H23 119.6 . .
C23 C24 C25 119.4(4) . .
C23 C24 H24 120.3 . .
C25 C24 H24 120.3 . .
C24 C25 C20 118.8(4) . .
C24 C25 C26 134.1(4) . .
C20 C25 C26 107.1(4) . .
C27 C26 C31 118.6(4) . .
C27 C26 C25 134.3(4) . .
C31 C26 C25 107.2(4) . .
C28 C27 C26 119.6(4) . .
C28 C27 H27 120.2 . .
C26 C27 H27 120.2 . .
C27 C28 C29 120.8(4) . .
C27 C28 H28 119.6 . .
C29 C28 H28 119.6 . .
C30 C29 C28 121.4(4) . .
C30 C29 H29 119.3 . .
C28 C29 H29 119.3 . .
C29 C30 C31 117.3(4) . .
C29 C30 H30 121.4 . .
C31 C30 H30 121.4 . .
C30 C31 N4 129.2(4) . .
C30 C31 C26 122.4(4) . .
N4 C31 C26 108.4(4) . .
N5 C32 C33 121.9(5) . .
N5 C32 H32 119 . .
C33 C32 H32 119 . .
C32 C33 C34 118.5(5) . .
C32 C33 H33 120.8 . .
C34 C33 H33 120.8 . .
C35 C34 C33 120.1(5) . .
C35 C34 H34 120 . .
C33 C34 H34 120 . .
C34 C35 C36 119.3(5) . .
C34 C35 H35 120.3 . .
C36 C35 H35 120.3 . .
N5 C36 C35 119.8(4) . .
N5 C36 C37 112.2(4) . .
C35 C36 C37 128.0(4) . .
C38 C37 C42 118.6(4) . .
C38 C37 C36 125.7(4) . .
C42 C37 C36 115.6(4) . .
F3 C38 C39 116.4(4) . .
F3 C38 C37 119.5(4) . .
C39 C38 C37 124.1(4) . .
C38 C39 C40 116.2(4) . .
C38 C39 H39 121.9 . .
C40 C39 H39 121.9 . .
F4 C40 C39 118.2(4) . .
F4 C40 C41 118.8(4) . .
C39 C40 C41 123.0(5) . .
C40 C41 C42 120.8(4) . .
C40 C41 H41 119.6 . .
C42 C41 H41 119.6 . .
C41 C42 C37 117.3(4) . .
C41 C42 Pt2 129.2(3) . .
C37 C42 Pt2 113.3(3) . .
N6 C43 C44 123.1(4) . .
N6 C43 H43 118.4 . .
C44 C43 H43 118.4 . .
C45 C44 C43 120.9(4) . .
C45 C44 H44 119.6 . .
C43 C44 H44 119.6 . .
C44 C45 N8 121.3(4) . .
C44 C45 C46 118.3(4) . .
N8 C45 C46 120.4(4) . .
N7 C46 C50 122.2(4) . .
N7 C46 C45 121.0(4) . .
C50 C46 C45 116.7(4) . .
N7 C47 C48 126.3(4) . .
N7 C47 H47 116.8 . .
C48 C47 H47 116.8 . .
C49 C48 C47 119.0(4) . .
C49 C48 H48 120.5 . .
C47 C48 H48 120.5 . .
O2 C49 C48 125.7(4) . .
O2 C49 C50 118.9(4) . .
C48 C49 C50 115.4(4) . .
N6 C50 C46 123.4(4) . .
N6 C50 C49 116.2(4) . .
C46 C50 C49 120.4(4) . .
C52 C51 C56 121.6(4) . .
C52 C51 N8 129.2(4) . .
C56 C51 N8 109.1(4) . .
C53 C52 C51 117.2(4) . .
C53 C52 H52 121.4 . .
C51 C52 H52 121.4 . .
C52 C53 C54 121.5(5) . .
C52 C53 H53 119.3 . .
C54 C53 H53 119.3 . .
C55 C54 C53 121.0(4) . .
C55 C54 H54 119.5 . .
C53 C54 H54 119.5 . .
C54 C55 C56 118.5(4) . .
C54 C55 H55 120.7 . .
C56 C55 H55 120.7 . .
C55 C56 C51 120.2(4) . .
C55 C56 C57 132.8(4) . .
C51 C56 C57 107.0(4) . .
C58 C57 C62 120.1(4) . .
C58 C57 C56 132.8(4) . .
C62 C57 C56 107.1(4) . .
C59 C58 C57 119.2(5) . .
C59 C58 H58 120.4 . .
C57 C58 H58 120.4 . .
C58 C59 C60 120.3(4) . .
C58 C59 H59 119.9 . .
C60 C59 H59 119.9 . .
C61 C60 C59 121.5(5) . .
C61 C60 H60 119.3 . .
C59 C60 H60 119.3 . .
C62 C61 C60 117.8(4) . .
C62 C61 H61 121.1 . .
C60 C61 H61 121.1 . .
C61 C62 C57 121.0(4) . .
C61 C62 N8 130.0(4) . .
C57 C62 N8 108.9(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N1 1.998(4) .
Pt1 C11 2.000(4) .
Pt1 N2 2.049(4) .
Pt1 O1 2.081(3) .
Pt1 Pt2 3.1687(2) .
Pt2 C42 1.994(4) .
Pt2 N5 2.002(4) .
Pt2 N6 2.035(4) .
Pt2 O2 2.098(3) .
F1 C7 1.363(5) .
F2 C9 1.353(5) .
F3 C38 1.359(5) .
F4 C40 1.348(6) .
O1 C12 1.296(5) .
O2 C49 1.301(5) .
N1 C1 1.352(6) .
N1 C5 1.360(6) .
N2 C18 1.326(6) .
N2 C19 1.383(6) .
N3 C14 1.333(6) .
N3 C15 1.358(6) .
N4 C20 1.402(6) .
N4 C16 1.403(5) .
N4 C31 1.403(6) .
N5 C32 1.339(6) .
N5 C36 1.362(6) .
N6 C43 1.327(6) .
N6 C50 1.383(6) .
N7 C47 1.327(6) .
N7 C46 1.353(6) .
N8 C45 1.399(6) .
N8 C62 1.407(5) .
N8 C51 1.408(6) .
C1 C2 1.380(6) .
C1 H1 0.95 .
C2 C3 1.387(7) .
C2 H2 0.95 .
C3 C4 1.399(7) .
C3 H3 0.95 .
C4 C5 1.394(6) .
C4 H4 0.95 .
C5 C6 1.458(6) .
C6 C7 1.386(6) .
C6 C11 1.421(6) .
C7 C8 1.374(6) .
C8 C9 1.388(7) .
C8 H8 0.95 .
C9 C10 1.374(7) .
C10 C11 1.387(6) .
C10 H10 0.95 .
C12 C13 1.392(6) .
C12 C19 1.436(6) .
C13 C14 1.392(6) .
C13 H13 0.95 .
C14 H14 0.95 .
C15 C19 1.411(6) .
C15 C16 1.434(6) .
C16 C17 1.374(6) .
C17 C18 1.392(6) .
C17 H17 0.95 .
C18 H18 0.95 .
C20 C21 1.389(6) .
C20 C25 1.400(6) .
C21 C22 1.381(7) .
C21 H21 0.95 .
C22 C23 1.388(7) .
C22 H22 0.95 .
C23 C24 1.377(7) .
C23 H23 0.95 .
C24 C25 1.398(6) .
C24 H24 0.95 .
C25 C26 1.445(6) .
C26 C27 1.395(6) .
C26 C31 1.412(6) .
C27 C28 1.380(7) .
C27 H27 0.95 .
C28 C29 1.395(6) .
C28 H28 0.95 .
C29 C30 1.388(6) .
C29 H29 0.95 .
C30 C31 1.392(6) .
C30 H30 0.95 .
C32 C33 1.381(7) .
C32 H32 0.95 .
C33 C34 1.382(7) .
C33 H33 0.95 .
C34 C35 1.381(7) .
C34 H34 0.95 .
C35 C36 1.397(6) .
C35 H35 0.95 .
C36 C37 1.462(7) .
C37 C38 1.391(7) .
C37 C42 1.429(6) .
C38 C39 1.368(7) .
C39 C40 1.375(7) .
C39 H39 0.95 .
C40 C41 1.383(6) .
C41 C42 1.391(6) .
C41 H41 0.95 .
C43 C44 1.396(6) .
C43 H43 0.95 .
C44 C45 1.369(6) .
C44 H44 0.95 .
C45 C46 1.425(6) .
C46 C50 1.415(6) .
C47 C48 1.398(7) .
C47 H47 0.95 .
C48 C49 1.397(6) .
C48 H48 0.95 .
C49 C50 1.429(6) .
C51 C52 1.398(6) .
C51 C56 1.402(6) .
C52 C53 1.389(7) .
C52 H52 0.95 .
C53 C54 1.399(7) .
C53 H53 0.95 .
C54 C55 1.381(7) .
C54 H54 0.95 .
C55 C56 1.394(7) .
C55 H55 0.95 .
C56 C57 1.453(7) .
C57 C58 1.386(6) .
C57 C62 1.406(6) .
C58 C59 1.382(7) .
C58 H58 0.95 .
C59 C60 1.395(7) .
C59 H59 0.95 .
C60 C61 1.391(6) .
C60 H60 0.95 .
C61 C62 1.389(6) .
C61 H61 0.95 .
