#------------------------------------------------------------------------------
#$Date: 2019-11-28 16:39:08 +0100 (jue 28 de nov de 2019) $
#$Revision: 244199 $
#$URL: svn://www.crystallography.net/cod/cif/7/23/85/7238514.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7238514
loop_
_publ_author_name
'Antonova, Elena'
'Näther, Christian'
'Bensch, Wolfgang'
_publ_section_title
;
 Assembly of [V15Sb6O42(H2O)]6− cluster shells into higher
 dimensional aggregates via weak Sb⋯N/Sb⋯O intercluster
 interactions and a new polyoxovanadate with a discrete
 [V16Sb4O42(H2O)]8− cluster shell
;
_journal_issue                   20
_journal_name_full               CrystEngComm
_journal_page_first              6853
_journal_paper_doi               10.1039/c2ce25896j
_journal_volume                  14
_journal_year                    2012
_chemical_formula_moiety         'O42 Sb6 V15, 3(Co C6 H18 N4 O), 2(O)'
_chemical_formula_sum            'C18 H58 Co3 N12 O47 Sb6 V15'
_chemical_formula_weight         2872.96
_chemical_name_common            '(Co(N4C6H18)(H2O))3V15Sb6O42(H2O)H2O '
_space_group_IT_number           146
_space_group_name_Hall           'R 3'
_space_group_name_H-M_alt        'R 3 :H'
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_H-M   'R 3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   12.3811(5)
_cell_length_b                   12.3811(5)
_cell_length_c                   41.398(3)
_cell_measurement_reflns_used    16570
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      55.9
_cell_measurement_theta_min      5.5
_cell_volume                     5495.8(5)
_computing_cell_refinement       'STOE-IPDS Program Package'
_computing_data_collection       'STOE-IPDS Program Package'
_computing_data_reduction        'STOE-IPDS Program Package'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Stoe Imaging Plate Diffraction System'
_diffrn_measurement_method       'φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0464
_diffrn_reflns_av_sigmaI/netI    0.0402
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       54
_diffrn_reflns_limit_l_min       -54
_diffrn_reflns_number            16570
_diffrn_reflns_theta_full        27.94
_diffrn_reflns_theta_max         27.94
_diffrn_reflns_theta_min         2.74
_diffrn_standards_decay_%        none
_exptl_absorpt_coefficient_mu    4.737
_exptl_absorpt_correction_T_max  0.7001
_exptl_absorpt_correction_T_min  0.3560
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.608
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'plate crystal'
_exptl_crystal_F_000             4092
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.511
_refine_diff_density_min         -0.837
_refine_diff_density_rms         0.149
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.02(2)
_refine_ls_extinction_coef       0.00027(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.996
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     311
_refine_ls_number_reflns         5856
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.996
_refine_ls_R_factor_all          0.0355
_refine_ls_R_factor_gt           0.0301
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0484P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0703
_refine_ls_wR_factor_ref         0.0724
_reflns_number_gt                5371
_reflns_number_total             5856
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ce25896j.txt
_cod_data_source_block           ea430
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Numerical' was
changed to 'numerical' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        5495.7(5)
_cod_original_sg_symbol_H-M      R3
_cod_database_code               7238514
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sb1 Sb 0.22247(3) 0.08080(3) 0.675120(8) 0.01609(9) Uani 1 1 d .
Sb2 Sb 0.28281(3) 0.33830(3) 0.624551(8) 0.01526(9) Uani 1 1 d .
V1 V 0.47920(8) 0.17917(8) 0.72380(2) 0.01245(17) Uani 1 1 d .
V2 V 0.44297(8) 0.39647(8) 0.70380(2) 0.01291(17) Uani 1 1 d .
V3 V 0.56157(8) 0.58137(8) 0.64954(2) 0.01254(17) Uani 1 1 d .
V4 V 0.73639(8) 0.62351(8) 0.59568(2) 0.01210(17) Uani 1 1 d .
V5 V 0.86007(7) 0.47457(8) 0.57511(2) 0.01132(16) Uani 1 1 d .
O1 O 0.1773(3) 0.1863(4) 0.64925(11) 0.0212(8) Uani 1 1 d .
O2 O 0.3225(4) 0.0642(4) 0.64076(9) 0.0204(8) Uani 1 1 d .
O3 O 0.3673(4) 0.2161(4) 0.69691(11) 0.0201(8) Uani 1 1 d .
O4 O 0.3747(4) 0.2698(3) 0.60131(10) 0.0174(8) Uani 1 1 d .
O5 O 0.4058(4) 0.4222(4) 0.65841(10) 0.0187(8) Uani 1 1 d .
O6 O 0.4021(4) 0.1123(4) 0.75619(10) 0.0254(9) Uani 1 1 d .
O7 O 0.6418(3) 0.1941(4) 0.72724(9) 0.0154(7) Uani 1 1 d .
O8 O 0.3579(4) 0.4234(4) 0.72850(11) 0.0282(9) Uani 1 1 d .
O9 O 0.5955(3) 0.5485(3) 0.69278(9) 0.0147(7) Uani 1 1 d .
O10 O 0.5226(4) 0.6884(4) 0.64986(11) 0.0250(9) Uani 1 1 d .
O11 O 0.5604(3) 0.5216(3) 0.60616(9) 0.0134(7) Uani 1 1 d .
O12 O 0.7586(4) 0.7380(4) 0.57220(11) 0.0236(9) Uani 1 1 d .
O13 O 0.7058(3) 0.4781(4) 0.57176(9) 0.0153(7) Uani 1 1 d .
O14 O 0.9444(4) 0.5325(4) 0.54331(10) 0.0221(8) Uani 1 1 d .
Co1 Co 0.3333 0.6667 0.75032(3) 0.0209(3) Uani 1 3 d S
O15 O 0.3333 0.6667 0.7002(2) 0.047(2) Uani 1 3 d S
N1 N 0.3333 0.6667 0.8040(2) 0.0255(18) Uani 1 3 d S
C1 C 0.3508(10) 0.7886(8) 0.8145(2) 0.049(2) Uani 1 1 d .
H1A H 0.3184 0.7807 0.8363 0.059 Uiso 1 1 calc R
H1B H 0.4393 0.8491 0.8151 0.059 Uiso 1 1 calc R
C2 C 0.2884(10) 0.8345(8) 0.7933(2) 0.052(2) Uani 1 1 d .
H2A H 0.3188 0.9219 0.7978 0.063 Uiso 1 1 calc R
H2B H 0.1994 0.7889 0.7976 0.063 Uiso 1 1 calc R
N2 N 0.3106(5) 0.8199(5) 0.75838(14) 0.0282(11) Uani 1 1 d .
H2C H 0.3793 0.8894 0.7516 0.034 Uiso 1 1 calc R
H2D H 0.2456 0.8114 0.7466 0.034 Uiso 1 1 calc R
Co2 Co 0.0000 0.0000 0.54510(3) 0.0217(3) Uani 1 3 d S
O16 O 0.0000 0.0000 0.5955(3) 0.049(2) Uani 1 3 d S
N11 N 0.0000 0.0000 0.4911(2) 0.029(2) Uani 1 3 d S
C11 C -0.1222(7) -0.0168(8) 0.48044(16) 0.0349(15) Uani 1 1 d .
H11A H -0.1826 -0.1051 0.4788 0.042 Uiso 1 1 calc R
H11B H -0.1134 0.0205 0.4593 0.042 Uiso 1 1 calc R
C12 C -0.1678(7) 0.0435(7) 0.50431(18) 0.0358(15) Uani 1 1 d .
H12A H -0.1146 0.1334 0.5035 0.043 Uiso 1 1 calc R
H12B H -0.2520 0.0233 0.4988 0.043 Uiso 1 1 calc R
N12 N -0.1659(5) -0.0015(5) 0.53687(13) 0.0268(11) Uani 1 1 d .
H12C H -0.2304 -0.0796 0.5392 0.032 Uiso 1 1 calc R
H12D H -0.1746 0.0475 0.5515 0.032 Uiso 1 1 calc R
Co3 Co 1.0000 1.0000 0.89097(3) 0.0203(3) Uani 1 3 d S
O17 O 1.0000 1.0000 0.9404(2) 0.061(3) Uani 1 3 d S
N21 N 1.0000 1.0000 0.8366(2) 0.0223(17) Uani 1 3 d S
C21 C 0.8781(6) 0.8955(6) 0.82568(17) 0.0325(15) Uani 1 1 d .
H21A H 0.8866 0.8675 0.8044 0.039 Uiso 1 1 calc R
H21B H 0.8172 0.9228 0.8243 0.039 Uiso 1 1 calc R
C22 C 0.8349(7) 0.7885(6) 0.85017(18) 0.0341(15) Uani 1 1 d .
H22A H 0.7516 0.7223 0.8448 0.041 Uiso 1 1 calc R
H22B H 0.8906 0.7546 0.8496 0.041 Uiso 1 1 calc R
N22 N 0.8354(5) 0.8371(5) 0.88274(14) 0.0274(11) Uani 1 1 d .
H22C H 0.8257 0.7800 0.8976 0.033 Uiso 1 1 calc R
H22D H 0.7711 0.8512 0.8846 0.033 Uiso 1 1 calc R
O18 O 0.2515(12) 0.2216(11) 0.7732(3) 0.097(5) Uani 0.70 1 d P
O19 O 0.6667 0.3333 0.6471(7) 0.089(9) Uani 0.50 3 d SP
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.3005 0.5294 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Sb1 O2 93.89(19) . .
O3 Sb1 O1 97.19(17) . .
O2 Sb1 O1 94.50(17) . .
O5 Sb2 O1 96.03(17) . .
O5 Sb2 O4 96.61(17) . .
O1 Sb2 O4 95.29(16) . .
O6 V1 O7 108.0(2) . .
O6 V1 O7 110.2(2) . 3_665
O7 V1 O7 90.9(2) . 3_665
O6 V1 O9 107.6(2) . 2_655
O7 V1 O9 82.41(16) . 2_655
O7 V1 O9 141.83(17) 3_665 2_655
O6 V1 O3 106.3(2) . .
O7 V1 O3 145.75(18) . .
O7 V1 O3 76.11(16) 3_665 .
O9 V1 O3 88.53(16) 2_655 .
O6 V1 V2 107.11(17) . 2_655
O7 V1 V2 41.15(12) . 2_655
O7 V1 V2 126.68(12) 3_665 2_655
O9 V1 V2 42.20(11) 2_655 2_655
O3 V1 V2 126.85(13) . 2_655
O6 V1 V2 111.56(17) . .
O7 V1 V2 122.70(12) . .
O7 V1 V2 37.05(11) 3_665 .
O9 V1 V2 120.88(12) 2_655 .
O3 V1 V2 39.13(11) . .
V2 V1 V2 141.32(4) 2_655 .
O8 V2 O7 110.2(2) . 3_665
O8 V2 O9 111.5(2) . .
O7 V2 O9 83.84(16) 3_665 .
O8 V2 O3 109.7(2) . .
O7 V2 O3 77.64(16) 3_665 .
O9 V2 O3 138.50(18) . .
O8 V2 O5 109.6(2) . .
O7 V2 O5 140.04(18) 3_665 .
O9 V2 O5 79.29(16) . .
O3 V2 O5 91.60(17) . .
O8 V2 V1 111.57(18) . 3_665
O7 V2 V1 41.79(11) 3_665 3_665
O9 V2 V1 43.01(11) . 3_665
O3 V2 V1 114.94(12) . 3_665
O5 V2 V1 117.80(12) . 3_665
O8 V2 V3 115.75(18) . .
O7 V2 V3 115.53(12) 3_665 .
O9 V2 V3 38.69(11) . .
O3 V2 V3 122.02(14) . .
O5 V2 V3 40.64(11) . .
V1 V2 V3 79.61(3) 3_665 .
O8 V2 V1 114.07(18) . .
O7 V2 V1 37.69(11) 3_665 .
O9 V2 V1 114.68(11) . .
O3 V2 V1 40.03(12) . .
O5 V2 V1 122.85(12) . .
V1 V2 V1 77.48(4) 3_665 .
V3 V2 V1 129.85(4) . .
O10 V3 O9 110.5(2) . .
O10 V3 O11 111.8(2) . .
O9 V3 O11 137.69(15) . .
O10 V3 O2 102.6(2) . 3_665
O9 V3 O2 89.90(17) . 3_665
O11 V3 O2 81.36(16) . 3_665
O10 V3 O5 105.8(2) . .
O9 V3 O5 79.90(17) . .
O11 V3 O5 88.52(16) . .
O2 V3 O5 151.66(17) 3_665 .
O10 V3 V4 110.58(16) . .
O9 V3 V4 121.18(12) . .
O11 V3 V4 40.26(11) . .
O2 V3 V4 41.22(11) 3_665 .
O5 V3 V4 125.11(13) . .
O10 V3 V2 112.57(16) . .
O9 V3 V2 38.97(11) . .
O11 V3 V2 119.49(11) . .
O2 V3 V2 124.89(13) 3_665 .
O5 V3 V2 40.98(12) . .
V4 V3 V2 136.84(4) . .
O12 V4 O13 112.2(2) . .
O12 V4 O11 110.24(19) . .
O13 V4 O11 82.80(16) . .
O12 V4 O4 109.2(2) . 3_665
O13 V4 O4 78.44(16) . 3_665
O11 V4 O4 140.33(17) . 3_665
O12 V4 O2 107.9(2) . 3_665
O13 V4 O2 139.81(18) . 3_665
O11 V4 O2 81.12(16) . 3_665
O4 V4 O2 91.16(17) 3_665 3_665
O12 V4 V5 112.44(16) . 2_655
O13 V4 V5 41.03(11) . 2_655
O11 V4 V5 42.57(11) . 2_655
O4 V4 V5 115.47(12) 3_665 2_655
O2 V4 V5 118.64(13) 3_665 2_655
O12 V4 V3 113.19(16) . .
O13 V4 V3 116.00(12) . .
O11 V4 V3 40.15(11) . .
O4 V4 V3 123.34(13) 3_665 .
O2 V4 V3 41.08(12) 3_665 .
V5 V4 V3 80.56(3) 2_655 .
O12 V4 V5 116.31(17) . .
O13 V4 V5 37.99(11) . .
O11 V4 V5 114.12(12) . .
O4 V4 V5 40.46(11) 3_665 .
O2 V4 V5 121.85(13) 3_665 .
V5 V4 V5 76.97(4) 2_655 .
V3 V4 V5 130.28(4) . .
O14 V5 O13 111.0(2) . .
O14 V5 O13 108.6(2) . 3_665
O13 V5 O13 91.7(2) . 3_665
O14 V5 O11 106.68(19) . 3_665
O13 V5 O11 141.90(17) . 3_665
O13 V5 O11 81.17(15) 3_665 3_665
O14 V5 O4 103.7(2) . 3_665
O13 V5 O4 76.99(15) . 3_665
O13 V5 O4 147.64(18) 3_665 3_665
O11 V5 O4 89.22(15) 3_665 3_665
O14 V5 V4 107.32(15) . 3_665
O13 V5 V4 126.60(12) . 3_665
O13 V5 V4 40.52(11) 3_665 3_665
O11 V5 V4 41.44(10) 3_665 3_665
O4 V5 V4 127.24(12) 3_665 3_665
O14 V5 V4 111.69(16) . .
O13 V5 V4 37.55(11) . .
O13 V5 V4 123.72(12) 3_665 .
O11 V5 V4 120.85(11) 3_665 .
O4 V5 V4 39.45(11) 3_665 .
V4 V5 V4 140.91(4) 3_665 .
Sb2 O1 Sb1 130.21(19) . .
Sb1 O2 V3 120.11(19) . 2_655
Sb1 O2 V4 142.1(2) . 2_655
V3 O2 V4 97.70(18) 2_655 2_655
Sb1 O3 V2 138.8(2) . .
Sb1 O3 V1 120.2(2) . .
V2 O3 V1 100.83(18) . .
V4 O4 Sb2 140.8(2) 2_655 .
V4 O4 V5 100.09(17) 2_655 2_655
Sb2 O4 V5 119.04(18) . 2_655
Sb2 O5 V3 120.7(2) . .
Sb2 O5 V2 140.7(2) . .
V3 O5 V2 98.38(17) . .
V2 O7 V1 97.07(17) 2_655 .
V2 O7 V1 105.26(18) 2_655 2_655
V1 O7 V1 147.6(2) . 2_655
V3 O9 V2 102.34(17) . .
V3 O9 V1 150.9(2) . 3_665
V2 O9 V1 94.79(16) . 3_665
V3 O11 V4 99.60(17) . .
V3 O11 V5 151.6(2) . 2_655
V4 O11 V5 95.99(16) . 2_655
V4 O13 V5 104.46(18) . .
V4 O13 V5 98.45(17) . 2_655
V5 O13 V5 147.0(2) . 2_655
O15 Co1 N2 99.23(16) . .
O15 Co1 N2 99.23(16) . 2_665
N2 Co1 N2 117.48(9) . 2_665
O15 Co1 N2 99.23(16) . 3_565
N2 Co1 N2 117.48(9) . 3_565
N2 Co1 N2 117.48(9) 2_665 3_565
O15 Co1 N1 180.000(3) . .
N2 Co1 N1 80.77(16) . .
N2 Co1 N1 80.77(16) 2_665 .
N2 Co1 N1 80.77(16) 3_565 .
C1 N1 C1 111.8(5) . 2_665
C1 N1 C1 111.8(5) . 3_565
C1 N1 C1 111.8(5) 2_665 3_565
C1 N1 Co1 107.1(5) . .
C1 N1 Co1 107.1(5) 2_665 .
C1 N1 Co1 107.1(5) 3_565 .
C2 C1 N1 112.6(7) . .
C1 C2 N2 111.7(7) . .
C2 N2 Co1 112.4(4) . .
N12 Co2 N12 117.35(8) 3 .
N12 Co2 N12 117.35(8) 3 2
N12 Co2 N12 117.35(9) . 2
N12 Co2 O16 99.46(15) 3 .
N12 Co2 O16 99.46(15) . .
N12 Co2 O16 99.46(15) 2 .
N12 Co2 N11 80.54(15) 3 .
N12 Co2 N11 80.54(15) . .
N12 Co2 N11 80.54(15) 2 .
O16 Co2 N11 180.000(2) . .
C11 N11 C11 111.7(4) . 3
C11 N11 C11 111.7(4) . 2
C11 N11 C11 111.7(4) 3 2
C11 N11 Co2 107.2(4) . .
C11 N11 Co2 107.2(4) 3 .
C11 N11 Co2 107.2(4) 2 .
N11 C11 C12 110.1(6) . .
N12 C12 C11 109.6(6) . .
C12 N12 Co2 110.6(4) . .
O17 Co3 N22 99.54(17) . .
O17 Co3 N22 99.54(17) . 3_675
N22 Co3 N22 117.31(9) . 3_675
O17 Co3 N22 99.54(17) . 2_765
N22 Co3 N22 117.31(9) . 2_765
N22 Co3 N22 117.31(9) 3_675 2_765
O17 Co3 N21 180.000(4) . .
N22 Co3 N21 80.46(16) . .
N22 Co3 N21 80.46(16) 3_675 .
N22 Co3 N21 80.46(16) 2_765 .
C21 N21 C21 111.2(4) . 3_675
C21 N21 C21 111.2(4) . 2_765
C21 N21 C21 111.2(4) 3_675 2_765
C21 N21 Co3 107.7(4) . .
C21 N21 Co3 107.7(4) 3_675 .
C21 N21 Co3 107.7(4) 2_765 .
N21 C21 C22 108.3(6) . .
N22 C22 C21 108.8(5) . .
C22 N22 Co3 110.6(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sb1 O3 1.957(4) .
Sb1 O2 1.963(4) .
Sb1 O1 1.974(4) .
Sb2 O5 1.945(4) .
Sb2 O1 1.959(4) .
Sb2 O4 1.976(4) .
V1 O6 1.614(4) .
V1 O7 1.932(4) .
V1 O7 1.936(4) 3_665
V1 O9 1.970(4) 2_655
V1 O3 2.001(4) .
V1 V2 2.8778(12) 2_655
V1 V2 3.0548(12) .
V2 O8 1.618(4) .
V2 O7 1.908(4) 3_665
V2 O9 1.940(4) .
V2 O3 1.963(4) .
V2 O5 1.997(4) .
V2 V1 2.8778(12) 3_665
V2 V3 3.0133(12) .
V3 O10 1.622(4) .
V3 O9 1.928(4) .
V3 O11 1.940(4) .
V3 O2 1.967(4) 3_665
V3 O5 1.984(4) .
V3 V4 2.9665(12) .
V4 O12 1.624(4) .
V4 O13 1.919(4) .
V4 O11 1.944(4) .
V4 O4 1.967(4) 3_665
V4 O2 1.972(4) 3_665
V4 V5 2.9214(12) 2_655
V4 V5 3.0485(12) .
V5 O14 1.609(4) .
V5 O13 1.938(4) .
V5 O13 1.939(4) 3_665
V5 O11 1.987(4) 3_665
V5 O4 2.009(4) 3_665
V5 V4 2.9214(12) 3_665
O2 V3 1.967(4) 2_655
O2 V4 1.972(4) 2_655
O4 V4 1.967(4) 2_655
O4 V5 2.009(4) 2_655
O7 V2 1.908(4) 2_655
O7 V1 1.936(4) 2_655
O9 V1 1.970(4) 3_665
O11 V5 1.987(4) 2_655
O13 V5 1.939(4) 2_655
Co1 O15 2.075(10) .
Co1 N2 2.080(5) .
Co1 N2 2.080(6) 2_665
Co1 N2 2.080(5) 3_565
Co1 N1 2.224(9) .
N1 C1 1.479(8) .
N1 C1 1.479(8) 2_665
N1 C1 1.479(8) 3_565
C1 C2 1.461(13) .
C2 N2 1.498(10) .
Co2 N12 2.074(6) 3
Co2 N12 2.074(6) .
Co2 N12 2.074(6) 2
Co2 O16 2.088(10) .
Co2 N11 2.237(10) .
N11 C11 1.487(8) .
N11 C11 1.487(8) 3
N11 C11 1.487(8) 2
C11 C12 1.507(11) .
C12 N12 1.463(9) .
Co3 O17 2.045(10) .
Co3 N22 2.056(5) .
Co3 N22 2.056(5) 3_675
Co3 N22 2.056(5) 2_765
Co3 N21 2.251(9) .
N21 C21 1.485(7) .
N21 C21 1.485(7) 3_675
N21 C21 1.485(7) 2_765
C21 C22 1.536(10) .
C22 N22 1.475(9) .
