#------------------------------------------------------------------------------
#$Date: 2019-11-28 19:54:37 +0100 (jue 28 de nov de 2019) $
#$Revision: 244594 $
#$URL: svn://www.crystallography.net/cod/cif/7/23/91/7239190.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7239190
loop_
_publ_author_name
'Tang, Yun-Yu'
'Ding, Cai-Xia'
'Ng, Seik-Weng'
'Xie, Yong-Shu'
_publ_section_title
;
 Syntheses, structures and photoluminescence of Zn(ii), Ag(i), Cu(i) and
 Co(ii) coordination polymers of a tetrapyridyl ligand
;
_journal_issue                   39
_journal_name_full               'RSC Advances'
_journal_page_first              18134
_journal_paper_doi               10.1039/c3ra43405b
_journal_volume                  3
_journal_year                    2013
_chemical_formula_sum            'C52 H44 Ag4 N24 O2'
_chemical_formula_weight         1468.59
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.7650(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.1740(12)
_cell_length_b                   15.3189(17)
_cell_length_c                   15.2751(15)
_cell_measurement_reflns_used    1812
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      23.546
_cell_measurement_theta_min      2.563
_cell_volume                     2609.0(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.963
_diffrn_measured_fraction_theta_max 0.963
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1509
_diffrn_reflns_av_sigmaI/netI    0.1318
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            12040
_diffrn_reflns_theta_full        24.15
_diffrn_reflns_theta_max         24.15
_diffrn_reflns_theta_min         2.26
_exptl_absorpt_coefficient_mu    1.549
_exptl_absorpt_correction_T_max  0.9128
_exptl_absorpt_correction_T_min  0.5907
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.869
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1456
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.06
_refine_diff_density_max         3.780
_refine_diff_density_min         -1.530
_refine_diff_density_rms         0.323
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         4190
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.1478
_refine_ls_R_factor_gt           0.0899
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1994
_refine_ls_wR_factor_ref         0.2375
_reflns_number_gt                2201
_reflns_number_total             4190
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3ra43405b.txt
_cod_data_source_block           110504e
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      P2(1)/m
_cod_database_code               7239190
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.12214(14) 0.63553(10) 0.38057(12) 0.0531(7) Uani 1 1 d .
Ag2 Ag 0.64472(13) 0.63572(10) 0.13034(11) 0.0518(7) Uani 1 1 d .
N1 N 0.6215(12) 0.4318(9) 0.3707(9) 0.034(4) Uani 1 1 d .
N2 N 0.2864(14) 0.5576(9) 0.3523(10) 0.040(4) Uani 1 1 d .
N3 N 0.9544(14) 0.5553(10) 0.3954(10) 0.044(4) Uani 1 1 d .
N4 N 0.149(2) 0.7500 0.271(2) 0.051(7) Uani 1 2 d S
N5 N 0.149(2) 0.7500 0.200(3) 0.052(7) Uani 1 2 d S
N6 N 0.137(3) 0.7500 0.122(2) 0.071(9) Uani 1 2 d S
N7 N 0.081(2) 0.7500 0.4729(16) 0.047(6) Uani 1 2 d S
N8 N 0.027(2) 0.7500 0.5334(18) 0.051(6) Uani 1 2 d S
N9 N -0.027(3) 0.7500 0.5926(19) 0.071(8) Uani 1 2 d S
N10 N 0.1450(12) 0.4320(9) 0.1308(9) 0.036(4) Uani 1 1 d .
N11 N 0.4751(13) 0.5536(9) 0.1072(10) 0.039(4) Uani 1 1 d .
N12 N -0.1843(12) 0.5594(8) 0.1481(10) 0.032(3) Uani 1 1 d .
N13 N 0.662(3) 0.7500 0.239(2) 0.060(8) Uani 1 2 d S
N14 N 0.644(2) 0.7500 0.305(3) 0.057(8) Uani 1 2 d S
N15 N 0.617(2) 0.7500 0.3845(19) 0.060(8) Uani 1 2 d S
N16 N 0.600(2) 0.7500 0.0335(16) 0.043(6) Uani 1 2 d S
N17 N 0.526(2) 0.7500 -0.0272(18) 0.049(6) Uani 1 2 d S
N18 N 0.453(3) 0.7500 -0.082(2) 0.071(8) Uani 1 2 d S
O1 O 0.715(2) 0.7500 0.5640(15) 0.074(7) Uani 1 2 d S
H1C H 0.7917 0.7500 0.5685 0.089 Uiso 1 2 d SR
H1D H 0.6924 0.7500 0.5098 0.089 Uiso 1 2 d SR
O2 O 0.197(2) 0.7500 0.9419(18) 0.091(8) Uani 1 2 d S
H2C H 0.1822 0.7500 0.9959 0.110 Uiso 1 2 d SR
H2D H 0.2721 0.7500 0.9382 0.110 Uiso 1 2 d SR
C1 C 0.6207(15) 0.3395(12) 0.3702(11) 0.035(4) Uani 1 1 d .
C2 C 0.6390(16) 0.2946(11) 0.4459(12) 0.040(5) Uani 1 1 d .
H2 H 0.6517 0.3246 0.4986 0.048 Uiso 1 1 calc R
C3 C 0.5953(16) 0.2941(11) 0.2933(12) 0.039(4) Uani 1 1 d .
H3 H 0.5781 0.3243 0.2412 0.046 Uiso 1 1 calc R
C4 C 0.3058(17) 0.4775(12) 0.3859(12) 0.041(5) Uani 1 1 d .
H4 H 0.2414 0.4509 0.4108 0.049 Uiso 1 1 calc R
C5 C 0.4071(16) 0.4324(12) 0.3872(12) 0.038(4) Uani 1 1 d .
H5 H 0.4078 0.3734 0.4016 0.045 Uiso 1 1 calc R
C6 C 0.5129(16) 0.4742(11) 0.3669(12) 0.037(5) Uani 1 1 d .
C7 C 0.4935(15) 0.5575(10) 0.3299(11) 0.034(4) Uani 1 1 d .
H7 H 0.5574 0.5872 0.3077 0.041 Uiso 1 1 calc R
C8 C 0.3870(16) 0.5941(11) 0.3260(12) 0.039(4) Uani 1 1 d .
H8 H 0.3808 0.6502 0.3029 0.047 Uiso 1 1 calc R
C9 C 0.9341(18) 0.4701(13) 0.3685(13) 0.046(5) Uani 1 1 d .
H9 H 1.0013 0.4391 0.3535 0.055 Uiso 1 1 calc R
C10 C 0.8333(16) 0.4282(12) 0.3616(12) 0.039(5) Uani 1 1 d .
H10 H 0.8323 0.3694 0.3466 0.046 Uiso 1 1 calc R
C11 C 0.7265(16) 0.4708(12) 0.3766(11) 0.035(4) Uani 1 1 d .
C12 C 0.7476(17) 0.5593(12) 0.4078(13) 0.042(5) Uani 1 1 d .
H12 H 0.6835 0.5916 0.4265 0.051 Uiso 1 1 calc R
C13 C 0.8556(17) 0.5957(13) 0.4105(13) 0.045(5) Uani 1 1 d .
H13 H 0.8610 0.6547 0.4243 0.054 Uiso 1 1 calc R
C14 C 0.1399(15) 0.3395(11) 0.1311(12) 0.036(5) Uani 1 1 d .
C15 C 0.1314(16) 0.2942(11) 0.2084(13) 0.044(5) Uani 1 1 d .
H15 H 0.1256 0.3245 0.2607 0.052 Uiso 1 1 calc R
C16 C 0.1554(16) 0.2951(11) 0.0532(13) 0.041(5) Uani 1 1 d .
H16 H 0.1656 0.3258 0.0017 0.050 Uiso 1 1 calc R
C17 C 0.4647(16) 0.4704(11) 0.1285(12) 0.038(5) Uani 1 1 d .
H17 H 0.5352 0.4387 0.1388 0.046 Uiso 1 1 calc R
C18 C 0.3593(15) 0.4271(11) 0.1365(11) 0.035(4) Uani 1 1 d .
H18 H 0.3584 0.3681 0.1505 0.042 Uiso 1 1 calc R
C19 C 0.2547(16) 0.4735(11) 0.1233(12) 0.036(5) Uani 1 1 d .
C20 C 0.2633(17) 0.5587(11) 0.0969(12) 0.040(5) Uani 1 1 d .
H20 H 0.1947 0.5915 0.0829 0.048 Uiso 1 1 calc R
C21 C 0.3750(16) 0.5944(12) 0.0915(13) 0.041(5) Uani 1 1 d .
H21 H 0.3789 0.6527 0.0751 0.050 Uiso 1 1 calc R
C22 C -0.0828(15) 0.5975(12) 0.1752(12) 0.039(5) Uani 1 1 d .
H22 H -0.0848 0.6538 0.1979 0.047 Uiso 1 1 calc R
C23 C 0.0240(16) 0.5572(10) 0.1710(12) 0.036(4) Uani 1 1 d .
H23 H 0.0928 0.5847 0.1949 0.043 Uiso 1 1 calc R
C24 C 0.0344(16) 0.4766(11) 0.1325(12) 0.036(5) Uani 1 1 d .
C25 C -0.0677(15) 0.4348(11) 0.1097(12) 0.037(4) Uani 1 1 d .
H25 H -0.0673 0.3774 0.0898 0.044 Uiso 1 1 calc R
C26 C -0.1737(17) 0.4795(11) 0.1164(12) 0.040(5) Uani 1 1 d .
H26 H -0.2440 0.4511 0.0970 0.048 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N3 114.9(6) . 1_455
N2 Ag1 N7 135.6(7) . .
N3 Ag1 N7 98.7(7) 1_455 .
N2 Ag1 N4 96.4(7) . .
N3 Ag1 N4 126.4(7) 1_455 .
N7 Ag1 N4 85.0(7) . .
N12 Ag2 N11 115.0(5) 1_655 .
N12 Ag2 N16 127.9(7) 1_655 .
N11 Ag2 N16 100.2(6) . .
N12 Ag2 N13 105.4(7) 1_655 .
N11 Ag2 N13 122.3(8) . .
N16 Ag2 N13 84.1(7) . .
C11 N1 C6 124.8(16) . .
C11 N1 C1 117.3(15) . .
C6 N1 C1 117.9(14) . .
C8 N2 C4 112.2(16) . .
C8 N2 Ag1 123.1(11) . .
C4 N2 Ag1 121.6(13) . .
C13 N3 C9 112.2(17) . .
C13 N3 Ag1 118.5(13) . 1_655
C9 N3 Ag1 127.1(13) . 1_655
N5 N4 Ag1 133.6(6) . 4_575
N5 N4 Ag1 133.6(6) . .
Ag1 N4 Ag1 91.1(10) 4_575 .
N4 N5 N6 173(3) . .
N8 N7 Ag1 129.3(7) . .
N8 N7 Ag1 129.3(7) . 4_575
Ag1 N7 Ag1 98.5(9) . 4_575
N9 N8 N7 179(4) . .
C19 N10 C24 123.8(15) . .
C19 N10 C14 119.5(14) . .
C24 N10 C14 116.6(13) . .
C21 N11 C17 115.1(16) . .
C21 N11 Ag2 117.6(12) . .
C17 N11 Ag2 125.3(12) . .
C22 N12 C26 115.3(15) . .
C22 N12 Ag2 121.1(11) . 1_455
C26 N12 Ag2 122.3(12) . 1_455
N14 N13 Ag2 131.1(10) . .
N14 N13 Ag2 131.1(10) . 4_575
Ag2 N13 Ag2 92.9(11) . 4_575
N13 N14 N15 177(4) . .
N17 N16 Ag2 126.7(8) . 4_575
N17 N16 Ag2 126.7(8) . .
Ag2 N16 Ag2 97.7(9) 4_575 .
N18 N17 N16 177(3) . .
H1C O1 H1D 108.5 . .
H2C O2 H2D 108.5 . .
C2 C1 C3 118.9(18) . .
C2 C1 N1 120.3(16) . .
C3 C1 N1 120.7(16) . .
C1 C2 C2 120.7(11) . 4_565
C1 C2 H2 119.6 . .
C2 C2 H2 119.6 4_565 .
C3 C3 C1 120.3(11) 4_565 .
C3 C3 H3 119.8 4_565 .
C1 C3 H3 119.8 . .
C5 C4 N2 126.8(19) . .
C5 C4 H4 116.6 . .
N2 C4 H4 116.6 . .
C4 C5 C6 119.4(18) . .
C4 C5 H5 120.3 . .
C6 C5 H5 120.3 . .
N1 C6 C5 122.1(16) . .
N1 C6 C7 123.9(17) . .
C5 C6 C7 113.3(17) . .
C8 C7 C6 121.4(18) . .
C8 C7 H7 119.3 . .
C6 C7 H7 119.3 . .
C7 C8 N2 125.7(17) . .
C7 C8 H8 117.2 . .
N2 C8 H8 117.2 . .
C10 C9 N3 128.1(19) . .
C10 C9 H9 115.9 . .
N3 C9 H9 115.9 . .
C9 C10 C11 120.3(19) . .
C9 C10 H10 119.8 . .
C11 C10 H10 119.8 . .
N1 C11 C10 123.2(17) . .
N1 C11 C12 124.8(17) . .
C10 C11 C12 111.7(17) . .
C13 C12 C11 122.0(19) . .
C13 C12 H12 119.0 . .
C11 C12 H12 119.0 . .
N3 C13 C12 125(2) . .
N3 C13 H13 117.4 . .
C12 C13 H13 117.4 . .
C15 C14 C16 120.5(17) . .
C15 C14 N10 120.6(16) . .
C16 C14 N10 118.6(16) . .
C15 C15 C14 120.2(11) 4_565 .
C15 C15 H15 119.9 4_565 .
C14 C15 H15 119.9 . .
C16 C16 C14 119.2(10) 4_565 .
C16 C16 H16 120.4 4_565 .
C14 C16 H16 120.4 . .
N11 C17 C18 125.5(17) . .
N11 C17 H17 117.3 . .
C18 C17 H17 117.3 . .
C17 C18 C19 117.9(17) . .
C17 C18 H18 121.0 . .
C19 C18 H18 121.0 . .
C20 C19 C18 117.4(17) . .
C20 C19 N10 122.5(17) . .
C18 C19 N10 119.9(16) . .
C21 C20 C19 118.6(18) . .
C21 C20 H20 120.7 . .
C19 C20 H20 120.7 . .
N11 C21 C20 125.3(18) . .
N11 C21 H21 117.4 . .
C20 C21 H21 117.4 . .
N12 C22 C23 121.9(17) . .
N12 C22 H22 119.1 . .
C23 C22 H22 119.1 . .
C22 C23 C24 122.1(17) . .
C22 C23 H23 119.0 . .
C24 C23 H23 119.0 . .
C25 C24 C23 116.6(17) . .
C25 C24 N10 119.7(16) . .
C23 C24 N10 122.7(16) . .
C24 C25 C26 117.7(17) . .
C24 C25 H25 121.1 . .
C26 C25 H25 121.1 . .
N12 C26 C25 125.8(17) . .
N12 C26 H26 117.1 . .
C25 C26 H26 117.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.255(15) .
Ag1 N3 2.265(16) 1_455
Ag1 N7 2.316(16) .
Ag1 N4 2.46(2) .
Ag2 N12 2.241(14) 1_655
Ag2 N11 2.283(14) .
Ag2 N16 2.324(16) .
Ag2 N13 2.42(2) .
N1 C11 1.31(2) .
N1 C6 1.37(2) .
N1 C1 1.41(2) .
N2 C8 1.34(2) .
N2 C4 1.34(2) .
N3 C13 1.30(2) .
N3 C9 1.38(2) .
N3 Ag1 2.265(16) 1_655
N4 N5 1.08(3) .
N4 Ag1 2.46(2) 4_575
N5 N6 1.19(4) .
N7 N8 1.13(3) .
N7 Ag1 2.316(16) 4_575
N8 N9 1.12(3) .
N10 C19 1.39(2) .
N10 C24 1.41(2) .
N10 C14 1.42(2) .
N11 C21 1.29(2) .
N11 C17 1.32(2) .
N12 C22 1.32(2) .
N12 C26 1.32(2) .
N12 Ag2 2.241(13) 1_455
N13 N14 1.03(4) .
N13 Ag2 2.42(2) 4_575
N14 N15 1.27(4) .
N16 N17 1.20(3) .
N16 Ag2 2.324(16) 4_575
N17 N18 1.14(3) .
O1 H1C 0.8501 .
O1 H1D 0.8500 .
O2 H2C 0.8501 .
O2 H2D 0.8500 .
C1 C2 1.35(2) .
C1 C3 1.38(2) .
C2 C2 1.37(3) 4_565
C2 H2 0.9300 .
C3 C3 1.35(3) 4_565
C3 H3 0.9300 .
C4 C5 1.33(3) .
C4 H4 0.9300 .
C5 C6 1.40(2) .
C5 H5 0.9300 .
C6 C7 1.41(2) .
C7 C8 1.31(2) .
C7 H7 0.9300 .
C8 H8 0.9300 .
C9 C10 1.30(3) .
C9 H9 0.9300 .
C10 C11 1.39(2) .
C10 H10 0.9300 .
C11 C12 1.45(2) .
C12 C13 1.33(3) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 C15 1.38(2) .
C14 C16 1.39(2) .
C15 C15 1.35(3) 4_565
C15 H15 0.9300 .
C16 C16 1.38(3) 4_565
C16 H16 0.9300 .
C17 C18 1.36(2) .
C17 H17 0.9300 .
C18 C19 1.37(2) .
C18 H18 0.9300 .
C19 C20 1.37(2) .
C20 C21 1.37(2) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 C23 1.35(2) .
C22 H22 0.9300 .
C23 C24 1.37(2) .
C23 H23 0.9300 .
C24 C25 1.33(2) .
C25 C26 1.38(2) .
C25 H25 0.9300 .
C26 H26 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N3 Ag1 N2 C8 167.5(14) 1_455 .
N7 Ag1 N2 C8 -57.1(17) . .
N4 Ag1 N2 C8 32.2(15) . .
N3 Ag1 N2 C4 -33.9(15) 1_455 .
N7 Ag1 N2 C4 101.5(15) . .
N4 Ag1 N2 C4 -169.2(15) . .
N2 Ag1 N4 N5 63(3) . .
N3 Ag1 N4 N5 -64(3) 1_455 .
N7 Ag1 N4 N5 -161(3) . .
N2 Ag1 N4 Ag1 -130.3(7) . 4_575
N3 Ag1 N4 Ag1 102.2(8) 1_455 4_575
N7 Ag1 N4 Ag1 5.1(8) . 4_575
Ag1 N4 N5 N6 -81(3) 4_575 .
Ag1 N4 N5 N6 81(3) . .
N2 Ag1 N7 N8 -110(3) . .
N3 Ag1 N7 N8 30(3) 1_455 .
N4 Ag1 N7 N8 156(3) . .
N2 Ag1 N7 Ag1 88.5(11) . 4_575
N3 Ag1 N7 Ag1 -131.6(8) 1_455 4_575
N4 Ag1 N7 Ag1 -5.4(9) . 4_575
Ag1 N7 N8 N9 -78(3) . .
Ag1 N7 N8 N9 78(2) 4_575 .
N12 Ag2 N11 C21 -176.0(14) 1_655 .
N16 Ag2 N11 C21 -35.4(16) . .
N13 Ag2 N11 C21 54.0(17) . .
N12 Ag2 N11 C17 21.0(17) 1_655 .
N16 Ag2 N11 C17 161.6(15) . .
N13 Ag2 N11 C17 -109.0(16) . .
N12 Ag2 N13 N14 -84(4) 1_655 .
N11 Ag2 N13 N14 50(4) . .
N16 Ag2 N13 N14 148(4) . .
N12 Ag2 N13 Ag2 119.7(8) 1_655 4_575
N11 Ag2 N13 Ag2 -106.4(9) . 4_575
N16 Ag2 N13 Ag2 -8.0(9) . 4_575
Ag2 N13 N14 N15 -74(3) . .
Ag2 N13 N14 N15 74(3) 4_575 .
N12 Ag2 N16 N17 115(2) 1_655 .
N11 Ag2 N16 N17 -18(2) . .
N13 Ag2 N16 N17 -140(2) . .
N12 Ag2 N16 Ag2 -96.6(8) 1_655 4_575
N11 Ag2 N16 Ag2 130.2(7) . 4_575
N13 Ag2 N16 Ag2 8.4(9) . 4_575
Ag2 N16 N17 N18 -70.0(17) 4_575 .
Ag2 N16 N17 N18 70.0(17) . .
C11 N1 C1 C2 79(2) . .
C6 N1 C1 C2 -99.4(19) . .
C11 N1 C1 C3 -104.1(19) . .
C6 N1 C1 C3 77(2) . .
C3 C1 C2 C2 3.6(19) . 4_565
N1 C1 C2 C2 -179.7(10) . 4_565
C2 C1 C3 C3 -3.6(19) . 4_565
N1 C1 C3 C3 179.7(10) . 4_565
C8 N2 C4 C5 -6(3) . .
Ag1 N2 C4 C5 -167.0(15) . .
N2 C4 C5 C6 12(3) . .
C11 N1 C6 C5 -160.2(17) . .
C1 N1 C6 C5 18(2) . .
C11 N1 C6 C7 30(3) . .
C1 N1 C6 C7 -151.2(17) . .
C4 C5 C6 N1 177.2(16) . .
C4 C5 C6 C7 -12(3) . .
N1 C6 C7 C8 178.3(17) . .
C5 C6 C7 C8 8(3) . .
C6 C7 C8 N2 -3(3) . .
C4 N2 C8 C7 1(3) . .
Ag1 N2 C8 C7 161.5(15) . .
C13 N3 C9 C10 -4(3) . .
Ag1 N3 C9 C10 -166.3(16) 1_655 .
N3 C9 C10 C11 5(3) . .
C6 N1 C11 C10 -165.8(17) . .
C1 N1 C11 C10 16(3) . .
C6 N1 C11 C12 21(3) . .
C1 N1 C11 C12 -157.7(17) . .
C9 C10 C11 N1 -179.9(18) . .
C9 C10 C11 C12 -6(3) . .
N1 C11 C12 C13 -178.6(18) . .
C10 C11 C12 C13 7(3) . .
C9 N3 C13 C12 5(3) . .
Ag1 N3 C13 C12 169.4(16) 1_655 .
C11 C12 C13 N3 -8(3) . .
C19 N10 C14 C15 102(2) . .
C24 N10 C14 C15 -82(2) . .
C19 N10 C14 C16 -71(2) . .
C24 N10 C14 C16 104.4(19) . .
C16 C14 C15 C15 -4(2) . 4_565
N10 C14 C15 C15 -177.4(10) . 4_565
C15 C14 C16 C16 4(2) . 4_565
N10 C14 C16 C16 177.5(10) . 4_565
C21 N11 C17 C18 -2(3) . .
Ag2 N11 C17 C18 161.8(14) . .
N11 C17 C18 C19 -1(3) . .
C17 C18 C19 C20 5(3) . .
C17 C18 C19 N10 180.0(15) . .
C24 N10 C19 C20 -15(3) . .
C14 N10 C19 C20 160.2(18) . .
C24 N10 C19 C18 169.4(16) . .
C14 N10 C19 C18 -15(2) . .
C18 C19 C20 C21 -5(3) . .
N10 C19 C20 C21 179.9(17) . .
C17 N11 C21 C20 1(3) . .
Ag2 N11 C21 C20 -163.4(15) . .
C19 C20 C21 N11 2(3) . .
C26 N12 C22 C23 0(3) . .
Ag2 N12 C22 C23 -167.6(13) 1_455 .
N12 C22 C23 C24 5(3) . .
C22 C23 C24 C25 -9(3) . .
C22 C23 C24 N10 -177.3(17) . .
C19 N10 C24 C25 156.9(17) . .
C14 N10 C24 C25 -19(2) . .
C19 N10 C24 C23 -35(3) . .
C14 N10 C24 C23 149.6(17) . .
C23 C24 C25 C26 8(3) . .
N10 C24 C25 C26 176.9(15) . .
C22 N12 C26 C25 0(3) . .
Ag2 N12 C26 C25 166.9(14) 1_455 .
C24 C25 C26 N12 -4(3) . .
