#------------------------------------------------------------------------------
#$Date: 2020-10-06 13:13:24 +0200 (mar 06 de oct de 2020) $
#$Revision: 257972 $
#$URL: svn://www.crystallography.net/cod/cif/7/24/02/7240229.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240229
loop_
_publ_author_name
'Liang, Wenbin'
'Nakajima, Kazunari'
'Nishibayashi, Yoshiaki'
_publ_section_title
;
 Synthesis of 1,2,4-azadiphosphole derivatives based on vanadium-catalyzed
 [2+2+1] cycloaddition reactions of azobenzenes with phosphaalkynes
;
_journal_issue                   22
_journal_name_full               'RSC Advances'
_journal_page_first              12730
_journal_page_last               12733
_journal_paper_doi               10.1039/D0RA02503H
_journal_volume                  10
_journal_year                    2020
_chemical_formula_moiety         'C28 H35 N P2'
_chemical_formula_sum            'C28 H35 N P2'
_chemical_formula_weight         447.54
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2019-12-27 deposited with the CCDC.	2020-03-19 downloaded from the CCDC.
;
_cell_angle_alpha                90.0000
_cell_angle_beta                 90.0000
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   14.2420(9)
_cell_length_b                   10.3185(7)
_cell_length_c                   16.3776(9)
_cell_measurement_reflns_used    14314
_cell_measurement_temperature    178
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      1.90
_cell_volume                     2406.8(3)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, 2018)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.3'
_computing_publication_material  'CrystalStructure 4.3 (Rigaku, 2018)'
_computing_structure_refinement  'SHELXL Version 2016/6 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS Version 2013/1 (Sheldrick, 2008)'
_diffrn_ambient_temperature      178
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.949
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0812
_diffrn_reflns_av_unetI/netI     0.0833
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.949
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            19428
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.949
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.480
_diffrn_reflns_theta_min         1.895
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.197
_exptl_absorpt_correction_T_max  0.979
_exptl_absorpt_correction_T_min  0.560
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.235
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             960.00
_exptl_crystal_size_max          0.290
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.110
_refine_diff_density_max         0.82
_refine_diff_density_min         -0.82
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.000
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     152
_refine_ls_number_reflns         2989
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1625
_refine_ls_R_factor_gt           0.1398
_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+17.6500P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2387
_refine_ls_wR_factor_ref         0.2519
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2648
_reflns_number_total             2989
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            d0ra02503h2.cif
_cod_data_source_block           C28H35NP2
_cod_depositor_comments          'Adding full bibliography for 7240229.cif.'
_cod_database_code               7240229
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 1/2+X,1/2-Y,1/2-Z
3 -X,1/2+Y,-Z
4 1/2-X,-Y,1/2+Z
5 -X,-Y,-Z
6 -1/2-X,-1/2+Y,-1/2+Z
7 +X,-1/2-Y,+Z
8 -1/2+X,+Y,-1/2-Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.41761(13) 0.250000 0.60511(11) 0.0349(5) Uani 1 2 d S T P . .
P2 P 0.35476(13) 0.250000 0.43540(11) 0.0371(5) Uani 1 2 d S T P . .
N1 N 0.5023(4) 0.250000 0.5310(3) 0.0272(12) Uani 1 2 d S T P . .
C1 C 0.3255(4) 0.250000 0.5395(4) 0.0282(14) Uani 1 2 d S T P . .
C2 C 0.4756(4) 0.250000 0.4498(4) 0.0303(15) Uani 1 2 d S T P . .
C3 C 0.5972(4) 0.250000 0.5629(4) 0.0320(15) Uani 1 2 d S T P . .
C4 C 0.6404(4) 0.1332(6) 0.5814(3) 0.0457(14) Uani 1 1 d . . . . .
H4 H 0.609659 0.053111 0.570940 0.055 Uiso 1 1 calc R U . . .
C5 C 0.7295(5) 0.1362(9) 0.6154(4) 0.069(2) Uani 1 1 d . . . . .
H5 H 0.760779 0.057002 0.627077 0.083 Uiso 1 1 calc R U . . .
C6 C 0.7727(6) 0.250000 0.6324(5) 0.066(3) Uani 1 2 d S T P . .
H6 H 0.833488 0.250000 0.656347 0.079 Uiso 1 2 calc R U P . .
C7 C 0.2227(5) 0.250000 0.5683(4) 0.0316(15) Uani 1 2 d S T P . .
C8 C 0.2173(6) 0.250000 0.6624(5) 0.070(3) Uani 1 2 d S T P . .
H8A H 0.249285 0.172251 0.684296 0.084 Uiso 0.5 1 calc R U P . .
H8B H 0.249285 0.327749 0.684296 0.084 Uiso 0.5 1 calc R U P . .
C9 C 0.1141(6) 0.250000 0.6889(5) 0.061(3) Uani 1 2 d S T P . .
H9 H 0.111926 0.249999 0.749886 0.073 Uiso 1 2 calc R U P . .
C10 C 0.0684(5) 0.1372(9) 0.6606(6) 0.088(3) Uani 1 1 d . . . . .
H10A H 0.003388 0.135142 0.682053 0.106 Uiso 1 1 calc R U . . .
H10B H 0.101714 0.059659 0.681283 0.106 Uiso 1 1 calc R U . . .
C11 C 0.0660(6) 0.1338(10) 0.5650(7) 0.135(6) Uani 1 1 d . . . . .
H11 H 0.031233 0.056502 0.543966 0.162 Uiso 1 1 calc R U . . .
C12 C 0.1741(5) 0.1296(9) 0.5407(6) 0.097(3) Uani 1 1 d . . . . .
H12A H 0.204111 0.053239 0.566351 0.117 Uiso 1 1 calc R U . . .
H12B H 0.180134 0.120940 0.480773 0.117 Uiso 1 1 calc R U . . .
C13 C 0.0265(12) 0.250000 0.5371(10) 0.110(5) Uiso 1 2 d S . P . .
H13A H 0.029645 0.250000 0.476752 0.132 Uiso 1 2 calc R U P . .
H13B H -0.040759 0.249999 0.552370 0.132 Uiso 1 2 calc R U P . .
C14 C 0.5439(5) 0.250000 0.3772(4) 0.0308(15) Uani 1 2 d S T P . .
C15 C 0.5808(8) 0.1143(12) 0.3661(7) 0.044(3) Uiso 0.5 1 d . . P . .
C16 C 0.4890(7) 0.2942(9) 0.2996(6) 0.034(2) Uiso 0.5 1 d . . P . .
C17 C 0.6302(8) 0.3446(12) 0.3877(7) 0.043(2) Uiso 0.5 1 d . . P . .
C18 C 0.6438(9) 0.1036(13) 0.2889(8) 0.051(3) Uiso 0.5 1 d . . P . .
C19 C 0.6923(9) 0.3401(14) 0.3074(7) 0.044(3) Uiso 0.5 1 d . . P . .
C20 C 0.5532(7) 0.2907(9) 0.2227(6) 0.035(2) Uiso 0.5 1 d . . P . .
C21 C 0.7280(9) 0.2002(12) 0.3033(7) 0.046(3) Uiso 0.5 1 d . . P . .
C22 C 0.6386(10) 0.3802(14) 0.2337(9) 0.057(3) Uiso 0.5 1 d . . P . .
C23 C 0.5889(9) 0.1499(13) 0.2144(7) 0.044(3) Uiso 0.5 1 d . . P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 P1 N1 95.5(3) . . ?
C2 P2 C1 95.9(3) . . ?
C2 N1 C3 127.1(5) . . ?
C2 N1 P1 119.2(4) . . ?
C3 N1 P1 113.7(4) . . ?
C7 C1 P1 122.8(5) . . ?
C7 C1 P2 121.6(5) . . ?
P1 C1 P2 115.6(4) . . ?
N1 C2 C14 124.8(6) . . ?
N1 C2 P2 113.8(4) . . ?
C14 C2 P2 121.4(5) . . ?
C4 C3 C4 120.8(7) . 7_565 ?
C4 C3 N1 119.4(4) . . ?
C4 C3 N1 119.4(3) 7_565 . ?
C5 C4 C3 118.3(7) . . ?
C5 C4 H4 120.9 . . ?
C3 C4 H4 120.9 . . ?
C6 C5 C4 121.2(7) . . ?
C6 C5 H5 119.4 . . ?
C4 C5 H5 119.4 . . ?
C5 C6 C5 120.2(8) . 7_565 ?
C5 C6 H6 119.9 . . ?
C5 C6 H6 119.9 7_565 . ?
C12 C7 C12 112.8(10) . 7_565 ?
C12 C7 C1 110.4(4) . . ?
C12 C7 C1 110.4(4) 7_565 . ?
C12 C7 C8 106.2(5) . . ?
C12 C7 C8 106.2(5) 7_565 . ?
C1 C7 C8 110.7(6) . . ?
C9 C8 C7 109.3(7) . . ?
C9 C8 H8A 109.8 . . ?
C7 C8 H8A 109.8 . . ?
C9 C8 H8B 109.8 . . ?
C7 C8 H8B 109.8 . . ?
H8A C8 H8B 108.3 . . ?
C10 C9 C10 111.1(10) 7_565 . ?
C10 C9 C8 110.5(5) 7_565 . ?
C10 C9 C8 110.5(5) . . ?
C10 C9 H9 108.2 7_565 . ?
C10 C9 H9 108.2 . . ?
C8 C9 H9 108.2 . . ?
C9 C10 C11 110.8(7) . . ?
C9 C10 H10A 109.5 . . ?
C11 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
C11 C10 H10B 109.5 . . ?
H10A C10 H10B 108.1 . . ?
C13 C11 C10 108.3(9) . . ?
C13 C11 C12 109.3(11) . . ?
C10 C11 C12 103.2(8) . . ?
C13 C11 H11 111.8 . . ?
C10 C11 H11 111.8 . . ?
C12 C11 H11 111.8 . . ?
C7 C12 C11 110.5(6) . . ?
C7 C12 H12A 109.5 . . ?
C11 C12 H12A 109.5 . . ?
C7 C12 H12B 109.5 . . ?
C11 C12 H12B 109.5 . . ?
H12A C12 H12B 108.1 . . ?
C11 C13 C11 117.7(14) 7_565 . ?
C11 C13 H13A 107.9 7_565 . ?
C11 C13 H13A 107.9 . . ?
C11 C13 H13B 107.9 7_565 . ?
C11 C13 H13B 107.9 . . ?
H13A C13 H13B 107.2 . . ?
C15 C14 C15 136.6(10) . 7_565 ?
C15 C14 C2 108.3(5) . . ?
C15 C14 C2 108.3(5) 7_565 . ?
C15 C14 C16 78.8(6) . 7_565 ?
C15 C14 C16 110.4(6) 7_565 7_565 ?
C2 C14 C16 108.3(6) . 7_565 ?
C15 C14 C16 110.4(6) . . ?
C15 C14 C16 78.8(6) 7_565 . ?
C2 C14 C16 108.3(6) . . ?
C16 C14 C16 34.0(7) 7_565 . ?
C15 C14 C17 33.6(5) . 7_565 ?
C15 C14 C17 108.4(8) 7_565 7_565 ?
C2 C14 C17 114.1(5) . 7_565 ?
C16 C14 C17 107.3(6) 7_565 7_565 ?
C16 C14 C17 131.3(6) . 7_565 ?
C15 C14 C17 108.4(8) . . ?
C15 C14 C17 33.6(5) 7_565 . ?
C2 C14 C17 114.1(5) . . ?
C16 C14 C17 131.3(6) 7_565 . ?
C16 C14 C17 107.3(6) . . ?
C17 C14 C17 76.3(9) 7_565 . ?
C17 C15 C14 77.7(12) 7_565 . ?
C17 C15 C18 84.3(12) 7_565 . ?
C14 C15 C18 111.5(9) . . ?
C17 C15 C19 55.3(10) 7_565 7_565 ?
C14 C15 C19 97.0(8) . 7_565 ?
C18 C15 C19 29.6(6) . 7_565 ?
C17 C15 C16 121.4(13) 7_565 7_565 ?
C14 C15 C16 51.9(5) . 7_565 ?
C18 C15 C16 88.1(7) . 7_565 ?
C19 C15 C16 99.0(7) 7_565 7_565 ?
C16 C16 C20 88.7(5) 7_565 . ?
C16 C16 C14 73.0(3) 7_565 . ?
C20 C16 C14 111.0(7) . . ?
C16 C16 C20 60.6(4) 7_565 7_565 ?
C20 C16 C20 28.1(7) . 7_565 ?
C14 C16 C20 100.0(6) . 7_565 ?
C16 C16 C15 119.0(4) 7_565 7_565 ?
C20 C16 C15 94.0(7) . 7_565 ?
C14 C16 C15 49.4(4) . 7_565 ?
C20 C16 C15 106.8(6) 7_565 7_565 ?
C15 C17 C14 68.7(11) 7_565 . ?
C15 C17 C19 97.1(12) 7_565 . ?
C14 C17 C19 109.0(8) . . ?
C15 C17 C18 64.4(11) 7_565 7_565 ?
C14 C17 C18 100.2(8) . 7_565 ?
C19 C17 C18 33.2(6) . 7_565 ?
C15 C17 C17 118.3(11) 7_565 7_565 ?
C14 C17 C17 51.8(5) . 7_565 ?
C19 C17 C17 88.3(7) . 7_565 ?
C18 C17 C17 108.1(6) 7_565 7_565 ?
C15 C17 C21 112.4(12) 7_565 7_565 ?
C14 C17 C21 108.7(7) . 7_565 ?
C19 C17 C21 16.1(6) . 7_565 ?
C18 C17 C21 49.2(6) 7_565 7_565 ?
C17 C17 C21 76.7(5) 7_565 7_565 ?
C22 C18 C19 105.1(18) 7_565 7_565 ?
C22 C18 C23 28.1(11) 7_565 . ?
C19 C18 C23 115.7(15) 7_565 . ?
C22 C18 C15 137.5(16) 7_565 . ?
C19 C18 C15 96.7(13) 7_565 . ?
C23 C18 C15 109.4(10) . . ?
C22 C18 C21 95.4(15) 7_565 . ?
C19 C18 C21 9.9(10) 7_565 . ?
C23 C18 C21 108.1(10) . . ?
C15 C18 C21 105.8(10) . . ?
C22 C18 C17 149.2(17) 7_565 7_565 ?
C19 C18 C17 65.9(11) 7_565 7_565 ?
C23 C18 C17 126.8(10) . 7_565 ?
C15 C18 C17 31.3(6) . 7_565 ?
C21 C18 C17 75.4(9) . 7_565 ?
C22 C18 C20 47.2(12) 7_565 7_565 ?
C19 C18 C20 107.8(13) 7_565 7_565 ?
C23 C18 C20 21.4(5) . 7_565 ?
C15 C18 C20 91.7(8) . 7_565 ?
C21 C18 C20 103.1(8) . 7_565 ?
C17 C18 C20 105.5(8) 7_565 7_565 ?
C21 C19 C18 156(2) 7_565 7_565 ?
C21 C19 C22 119(2) 7_565 . ?
C18 C19 C22 36.8(10) 7_565 . ?
C21 C19 C21 31.5(14) 7_565 . ?
C18 C19 C21 143.4(16) 7_565 . ?
C22 C19 C21 113.5(12) . . ?
C21 C19 C17 122(2) 7_565 . ?
C18 C19 C17 80.9(13) 7_565 . ?
C22 C19 C17 112.2(11) . . ?
C21 C19 C17 104.4(11) . . ?
C21 C19 C19 51.0(17) 7_565 7_565 ?
C18 C19 C19 127.7(12) 7_565 7_565 ?
C22 C19 C19 106.2(8) . 7_565 ?
C21 C19 C19 19.6(6) . 7_565 ?
C17 C19 C19 91.7(7) . 7_565 ?
C21 C19 C15 148(2) 7_565 7_565 ?
C18 C19 C15 53.7(11) 7_565 7_565 ?
C22 C19 C15 85.0(9) . 7_565 ?
C21 C19 C15 121.9(10) . 7_565 ?
C17 C19 C15 27.6(5) . 7_565 ?
C19 C19 C15 104.2(5) 7_565 7_565 ?
C23 C20 C20 139.3(12) 7_565 7_565 ?
C23 C20 C22 21.0(11) 7_565 . ?
C20 C20 C22 126.9(6) 7_565 . ?
C23 C20 C23 119.3(16) 7_565 . ?
C20 C20 C23 20.0(6) 7_565 . ?
C22 C20 C23 108.3(9) . . ?
C23 C20 C16 119.3(13) 7_565 . ?
C20 C20 C16 91.3(5) 7_565 . ?
C22 C20 C16 110.8(8) . . ?
C23 C20 C16 106.7(8) . . ?
C23 C20 C16 144.4(13) 7_565 7_565 ?
C20 C20 C16 60.6(4) 7_565 7_565 ?
C22 C20 C16 128.1(8) . 7_565 ?
C23 C20 C16 76.7(6) . 7_565 ?
C16 C20 C16 30.7(6) . 7_565 ?
C23 C20 C18 43.5(11) 7_565 7_565 ?
C20 C20 C18 122.9(5) 7_565 7_565 ?
C22 C20 C18 26.1(6) . 7_565 ?
C23 C20 C18 110.2(8) . 7_565 ?
C16 C20 C18 85.9(7) . 7_565 ?
C16 C20 C18 102.4(6) 7_565 7_565 ?
C19 C21 C21 129.0(17) 7_565 7_565 ?
C19 C21 C19 109(2) 7_565 . ?
C21 C21 C19 19.6(6) 7_565 . ?
C19 C21 C18 14.4(14) 7_565 . ?
C21 C21 C18 129.2(6) 7_565 . ?
C19 C21 C18 110.5(10) . . ?
C19 C21 C22 43.0(15) 7_565 7_565 ?
C21 C21 C22 115.9(6) 7_565 7_565 ?
C19 C21 C22 102.4(9) . 7_565 ?
C18 C21 C22 28.9(6) . 7_565 ?
C19 C21 C17 41.8(15) 7_565 7_565 ?
C21 C21 C17 103.3(5) 7_565 7_565 ?
C19 C21 C17 87.5(8) . 7_565 ?
C18 C21 C17 55.4(7) . 7_565 ?
C22 C21 C17 81.3(7) 7_565 7_565 ?
C23 C22 C18 121(2) 7_565 7_565 ?
C23 C22 C19 129.8(18) 7_565 . ?
C18 C22 C19 38.2(11) 7_565 . ?
C23 C22 C20 20.3(11) 7_565 . ?
C18 C22 C20 106.7(15) 7_565 . ?
C19 C22 C20 109.5(11) . . ?
C23 C22 C21 129.3(17) 7_565 7_565 ?
C18 C22 C21 55.7(12) 7_565 7_565 ?
C19 C22 C21 17.6(6) . 7_565 ?
C20 C22 C21 109.8(9) . 7_565 ?
C20 C23 C22 139(2) 7_565 7_565 ?
C20 C23 C18 115.2(14) 7_565 . ?
C22 C23 C18 31.3(12) 7_565 . ?
C20 C23 C20 20.8(8) 7_565 . ?
C22 C23 C20 126.6(17) 7_565 . ?
C18 C23 C20 113.1(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 C1 1.696(7) . ?
P1 N1 1.710(5) . ?
P2 C2 1.737(7) . ?
P2 C1 1.755(7) . ?
N1 C2 1.383(8) . ?
N1 C3 1.450(8) . ?
C1 C7 1.539(9) . ?
C2 C14 1.536(9) . ?
C3 C4 1.386(7) . ?
C3 C4 1.386(7) 7_565 ?
C4 C5 1.387(8) . ?
C4 H4 0.9500 . ?
C5 C6 1.355(9) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C12 1.492(8) . ?
C7 C12 1.492(8) 7_565 ?
C7 C8 1.544(10) . ?
C8 C9 1.532(11) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.411(10) 7_565 ?
C9 C10 1.411(10) . ?
C9 H9 1.0000 . ?
C10 C11 1.568(13) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 C13 1.400(16) . ?
C11 C12 1.590(10) . ?
C11 H11 1.0000 . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.507(12) . ?
C14 C15 1.507(12) 7_565 ?
C14 C16 1.561(11) 7_565 ?
C14 C16 1.561(11) . ?
C14 C17 1.580(12) 7_565 ?
C14 C17 1.580(13) . ?
C15 C17 0.895(14) 7_565 ?
C15 C18 1.554(16) . ?
C15 C19 1.915(17) 7_565 ?
C15 C16 1.947(15) 7_565 ?
C16 C16 0.913(18) 7_565 ?
C16 C20 1.556(13) . ?
C16 C20 1.785(13) 7_565 ?
C17 C19 1.586(16) . ?
C17 C18 1.715(17) 7_565 ?
C17 C17 1.95(2) 7_565 ?
C17 C21 2.016(16) 7_565 ?
C18 C22 0.922(15) 7_565 ?
C18 C19 0.951(16) 7_565 ?
C18 C23 1.526(17) . ?
C18 C21 1.576(17) . ?
C18 C20 2.008(16) 7_565 ?
C19 C21 0.660(15) 7_565 ?
C19 C22 1.487(19) . ?
C19 C21 1.532(18) . ?
C19 C19 1.86(3) 7_565 ?
C20 C23 0.809(14) 7_565 ?
C20 C20 0.840(19) 7_565 ?
C20 C22 1.538(17) . ?
C20 C23 1.546(17) . ?
C21 C21 1.03(2) 7_565 ?
C21 C22 1.899(19) 7_565 ?
C22 C23 0.834(15) 7_565 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 P1 N1 C2 0.000(1) . . . . ?
C1 P1 N1 C3 180.000(1) . . . . ?
N1 P1 C1 C7 180.000(1) . . . . ?
N1 P1 C1 P2 0.000(1) . . . . ?
C2 P2 C1 C7 180.000(1) . . . . ?
C2 P2 C1 P1 0.000(0) . . . . ?
C3 N1 C2 C14 0.000(1) . . . . ?
P1 N1 C2 C14 180.000(1) . . . . ?
C3 N1 C2 P2 180.000(1) . . . . ?
P1 N1 C2 P2 0.000(1) . . . . ?
C1 P2 C2 N1 0.000(1) . . . . ?
C1 P2 C2 C14 180.000(1) . . . . ?
C2 N1 C3 C4 -92.9(5) . . . . ?
P1 N1 C3 C4 87.1(5) . . . . ?
C2 N1 C3 C4 92.9(5) . . . 7_565 ?
P1 N1 C3 C4 -87.1(5) . . . 7_565 ?
C4 C3 C4 C5 -2.8(10) 7_565 . . . ?
N1 C3 C4 C5 -177.0(5) . . . . ?
C3 C4 C5 C6 1.7(9) . . . . ?
C4 C5 C6 C5 -0.7(13) . . . 7_565 ?
P1 C1 C7 C12 -117.3(6) . . . . ?
P2 C1 C7 C12 62.7(6) . . . . ?
P1 C1 C7 C12 117.3(6) . . . 7_565 ?
P2 C1 C7 C12 -62.7(6) . . . 7_565 ?
P1 C1 C7 C8 0.000(2) . . . . ?
P2 C1 C7 C8 180.000(1) . . . . ?
C12 C7 C8 C9 -60.1(5) . . . . ?
C12 C7 C8 C9 60.1(5) 7_565 . . . ?
C1 C7 C8 C9 180.000(2) . . . . ?
C7 C8 C9 C10 -61.7(6) . . . 7_565 ?
C7 C8 C9 C10 61.7(6) . . . . ?
C10 C9 C10 C11 59.2(10) 7_565 . . . ?
C8 C9 C10 C11 -63.8(9) . . . . ?
C9 C10 C11 C13 -53.7(11) . . . . ?
C9 C10 C11 C12 62.2(10) . . . . ?
C12 C7 C12 C11 -51.9(12) 7_565 . . . ?
C1 C7 C12 C11 -176.0(8) . . . . ?
C8 C7 C12 C11 63.9(10) . . . . ?
C13 C11 C12 C7 52.0(12) . . . . ?
C10 C11 C12 C7 -63.2(11) . . . . ?
C10 C11 C13 C11 53.5(17) . . . 7_565 ?
C12 C11 C13 C11 -58.3(17) . . . 7_565 ?
N1 C2 C14 C15 78.2(6) . . . . ?
P2 C2 C14 C15 -101.8(6) . . . . ?
N1 C2 C14 C15 -78.2(6) . . . 7_565 ?
P2 C2 C14 C15 101.8(6) . . . 7_565 ?
N1 C2 C14 C16 162.1(4) . . . 7_565 ?
P2 C2 C14 C16 -17.9(4) . . . 7_565 ?
N1 C2 C14 C16 -162.1(4) . . . . ?
P2 C2 C14 C16 17.9(4) . . . . ?
N1 C2 C14 C17 42.6(6) . . . 7_565 ?
P2 C2 C14 C17 -137.4(6) . . . 7_565 ?
N1 C2 C14 C17 -42.6(6) . . . . ?
P2 C2 C14 C17 137.4(6) . . . . ?
C15 C14 C15 C17 40.2(19) 7_565 . . 7_565 ?
C2 C14 C15 C17 -106.2(11) . . . 7_565 ?
C16 C14 C15 C17 148.1(11) 7_565 . . 7_565 ?
C16 C14 C15 C17 135.4(11) . . . 7_565 ?
C17 C14 C15 C17 18.1(10) . . . 7_565 ?
C15 C14 C15 C18 -38.6(19) 7_565 . . . ?
C2 C14 C15 C18 175.0(8) . . . . ?
C16 C14 C15 C18 69.3(9) 7_565 . . . ?
C16 C14 C15 C18 56.6(11) . . . . ?
C17 C14 C15 C18 -78.8(13) 7_565 . . . ?
C17 C14 C15 C18 -60.7(11) . . . . ?
C15 C14 C15 C19 -11.9(17) 7_565 . . 7_565 ?
C2 C14 C15 C19 -158.3(6) . . . 7_565 ?
C16 C14 C15 C19 96.0(7) 7_565 . . 7_565 ?
C16 C14 C15 C19 83.3(8) . . . 7_565 ?
C17 C14 C15 C19 -52.1(10) 7_565 . . 7_565 ?
C17 C14 C15 C19 -34.0(9) . . . 7_565 ?
C15 C14 C15 C16 -107.9(13) 7_565 . . 7_565 ?
C2 C14 C15 C16 105.7(6) . . . 7_565 ?
C16 C14 C15 C16 -12.7(4) . . . 7_565 ?
C17 C14 C15 C16 -148.1(11) 7_565 . . 7_565 ?
C17 C14 C15 C16 -130.0(7) . . . 7_565 ?
C15 C14 C16 C16 22.6(5) . . . 7_565 ?
C15 C14 C16 C16 158.4(5) 7_565 . . 7_565 ?
C2 C14 C16 C16 -95.8(2) . . . 7_565 ?
C17 C14 C16 C16 53.7(7) 7_565 . . 7_565 ?
C17 C14 C16 C16 140.6(6) . . . 7_565 ?
C15 C14 C16 C20 -59.1(9) . . . . ?
C15 C14 C16 C20 76.6(8) 7_565 . . . ?
C2 C14 C16 C20 -177.6(6) . . . . ?
C16 C14 C16 C20 -81.8(7) 7_565 . . . ?
C17 C14 C16 C20 -28.0(11) 7_565 . . . ?
C17 C14 C16 C20 58.8(9) . . . . ?
C15 C14 C16 C20 -32.2(8) . . . 7_565 ?
C15 C14 C16 C20 103.5(7) 7_565 . . 7_565 ?
C2 C14 C16 C20 -150.7(4) . . . 7_565 ?
C16 C14 C16 C20 -54.9(5) 7_565 . . 7_565 ?
C17 C14 C16 C20 -1.1(10) 7_565 . . 7_565 ?
C17 C14 C16 C20 85.7(7) . . . 7_565 ?
C15 C14 C16 C15 -135.8(10) . . . 7_565 ?
C2 C14 C16 C15 105.8(5) . . . 7_565 ?
C16 C14 C16 C15 -158.4(5) 7_565 . . 7_565 ?
C17 C14 C16 C15 -104.7(10) 7_565 . . 7_565 ?
C17 C14 C16 C15 -17.8(6) . . . 7_565 ?
C15 C14 C17 C15 152.1(14) . . . 7_565 ?
C2 C14 C17 C15 -87.1(11) . . . 7_565 ?
C16 C14 C17 C15 61.1(13) 7_565 . . 7_565 ?
C16 C14 C17 C15 32.9(12) . . . 7_565 ?
C17 C14 C17 C15 162.3(9) 7_565 . . 7_565 ?
C15 C14 C17 C19 61.7(11) . . . . ?
C15 C14 C17 C19 -90.4(13) 7_565 . . . ?
C2 C14 C17 C19 -177.5(7) . . . . ?
C16 C14 C17 C19 -29.3(12) 7_565 . . . ?
C16 C14 C17 C19 -57.5(10) . . . . ?
C17 C14 C17 C19 71.9(10) 7_565 . . . ?
C15 C14 C17 C18 94.9(9) . . . 7_565 ?
C15 C14 C17 C18 -57.2(11) 7_565 . . 7_565 ?
C2 C14 C17 C18 -144.3(7) . . . 7_565 ?
C16 C14 C17 C18 3.9(11) 7_565 . . 7_565 ?
C16 C14 C17 C18 -24.3(9) . . . 7_565 ?
C17 C14 C17 C18 105.1(7) 7_565 . . 7_565 ?
C15 C14 C17 C17 -10.2(5) . . . 7_565 ?
C15 C14 C17 C17 -162.3(9) 7_565 . . 7_565 ?
C2 C14 C17 C17 110.6(6) . . . 7_565 ?
C16 C14 C17 C17 -101.2(8) 7_565 . . 7_565 ?
C16 C14 C17 C17 -129.4(7) . . . 7_565 ?
C15 C14 C17 C21 44.7(9) . . . 7_565 ?
C15 C14 C17 C21 -107.4(12) 7_565 . . 7_565 ?
C2 C14 C17 C21 165.5(5) . . . 7_565 ?
C16 C14 C17 C21 -46.3(11) 7_565 . . 7_565 ?
C16 C14 C17 C21 -74.5(8) . . . 7_565 ?
C17 C14 C17 C21 54.9(8) 7_565 . . 7_565 ?
C17 C15 C18 C22 -131(3) 7_565 . . 7_565 ?
C14 C15 C18 C22 -56(3) . . . 7_565 ?
C19 C15 C18 C22 -121(3) 7_565 . . 7_565 ?
C16 C15 C18 C22 -9(3) 7_565 . . 7_565 ?
C17 C15 C18 C19 -9.7(16) 7_565 . . 7_565 ?
C14 C15 C18 C19 64.7(15) . . . 7_565 ?
C16 C15 C18 C19 112.1(13) 7_565 . . 7_565 ?
C17 C15 C18 C23 -130.1(14) 7_565 . . . ?
C14 C15 C18 C23 -55.7(13) . . . . ?
C19 C15 C18 C23 -120.3(17) 7_565 . . . ?
C16 C15 C18 C23 -8.3(10) 7_565 . . . ?
C17 C15 C18 C21 -13.8(14) 7_565 . . . ?
C14 C15 C18 C21 60.6(11) . . . . ?
C19 C15 C18 C21 -4.1(10) 7_565 . . . ?
C16 C15 C18 C21 108.0(9) 7_565 . . . ?
C14 C15 C18 C17 74.4(12) . . . 7_565 ?
C19 C15 C18 C17 9.7(16) 7_565 . . 7_565 ?
C16 C15 C18 C17 121.8(13) 7_565 . . 7_565 ?
C17 C15 C18 C20 -117.9(12) 7_565 . . 7_565 ?
C14 C15 C18 C20 -43.5(10) . . . 7_565 ?
C19 C15 C18 C20 -108.2(14) 7_565 . . 7_565 ?
C16 C15 C18 C20 3.9(7) 7_565 . . 7_565 ?
C15 C17 C19 C21 -162(2) 7_565 . . 7_565 ?
C14 C17 C19 C21 -92(2) . . . 7_565 ?
C18 C17 C19 C21 -171(3) 7_565 . . 7_565 ?
C17 C17 C19 C21 -44(2) 7_565 . . 7_565 ?
C15 C17 C19 C18 9.6(16) 7_565 . . 7_565 ?
C14 C17 C19 C18 79.5(13) . . . 7_565 ?
C17 C17 C19 C18 127.9(11) 7_565 . . 7_565 ?
C21 C17 C19 C18 171(3) 7_565 . . 7_565 ?
C15 C17 C19 C22 -10.0(17) 7_565 . . . ?
C14 C17 C19 C22 59.9(13) . . . . ?
C18 C17 C19 C22 -19.6(11) 7_565 . . . ?
C17 C17 C19 C22 108.3(10) 7_565 . . . ?
C21 C17 C19 C22 152(3) 7_565 . . . ?
C15 C17 C19 C21 -133.3(14) 7_565 . . . ?
C14 C17 C19 C21 -63.5(11) . . . . ?
C18 C17 C19 C21 -142.9(16) 7_565 . . . ?
C17 C17 C19 C21 -15.1(8) 7_565 . . . ?
C21 C17 C19 C21 28.5(17) 7_565 . . . ?
C15 C17 C19 C19 -118.3(12) 7_565 . . 7_565 ?
C14 C17 C19 C19 -48.4(7) . . . 7_565 ?
C18 C17 C19 C19 -127.9(11) 7_565 . . 7_565 ?
C17 C17 C19 C19 -0.001(1) 7_565 . . 7_565 ?
C21 C17 C19 C19 44(2) 7_565 . . 7_565 ?
C14 C17 C19 C15 69.9(12) . . . 7_565 ?
C18 C17 C19 C15 -9.6(16) 7_565 . . 7_565 ?
C17 C17 C19 C15 118.3(12) 7_565 . . 7_565 ?
C21 C17 C19 C15 162(2) 7_565 . . 7_565 ?
C16 C16 C20 C23 -151.9(15) 7_565 . . 7_565 ?
C14 C16 C20 C23 -80.7(16) . . . 7_565 ?
C20 C16 C20 C23 -151.9(15) 7_565 . . 7_565 ?
C15 C16 C20 C23 -32.9(16) 7_565 . . 7_565 ?
C16 C16 C20 C20 0.003(2) 7_565 . . 7_565 ?
C14 C16 C20 C20 71.2(5) . . . 7_565 ?
C15 C16 C20 C20 119.0(5) 7_565 . . 7_565 ?
C16 C16 C20 C22 -130.7(8) 7_565 . . . ?
C14 C16 C20 C22 -59.5(10) . . . . ?
C20 C16 C20 C22 -130.7(8) 7_565 . . . ?
C15 C16 C20 C22 -11.7(10) 7_565 . . . ?
C16 C16 C20 C23 -13.0(7) 7_565 . . . ?
C14 C16 C20 C23 58.3(9) . . . . ?
C20 C16 C20 C23 -13.0(7) 7_565 . . . ?
C15 C16 C20 C23 106.0(8) 7_565 . . . ?
C14 C16 C20 C16 71.2(5) . . . 7_565 ?
C20 C16 C20 C16 -0.003(4) 7_565 . . 7_565 ?
C15 C16 C20 C16 119.0(5) 7_565 . . 7_565 ?
C16 C16 C20 C18 -122.9(5) 7_565 . . 7_565 ?
C14 C16 C20 C18 -51.7(7) . . . 7_565 ?
C20 C16 C20 C18 -122.9(5) 7_565 . . 7_565 ?
C15 C16 C20 C18 -3.9(7) 7_565 . . 7_565 ?
C21 C19 C21 C19 -179.993(3) 7_565 . . 7_565 ?
C18 C19 C21 C19 -43(4) 7_565 . . 7_565 ?
C22 C19 C21 C19 -72(2) . . . 7_565 ?
C17 C19 C21 C19 51(2) . . . 7_565 ?
C15 C19 C21 C19 27(3) 7_565 . . 7_565 ?
C18 C19 C21 C21 137(4) 7_565 . . 7_565 ?
C22 C19 C21 C21 108(2) . . . 7_565 ?
C17 C19 C21 C21 -129(2) . . . 7_565 ?
C19 C19 C21 C21 179.993(3) 7_565 . . 7_565 ?
C15 C19 C21 C21 -153(3) 7_565 . . 7_565 ?
C21 C19 C21 C18 -164.7(15) 7_565 . . . ?
C18 C19 C21 C18 -28(3) 7_565 . . . ?
C22 C19 C21 C18 -56.4(13) . . . . ?
C17 C19 C21 C18 66.1(12) . . . . ?
C19 C19 C21 C18 15.3(15) 7_565 . . . ?
C15 C19 C21 C18 42.7(15) 7_565 . . . ?
C21 C19 C21 C22 -135.7(18) 7_565 . . 7_565 ?
C18 C19 C21 C22 1(3) 7_565 . . 7_565 ?
C22 C19 C21 C22 -27.5(11) . . . 7_565 ?
C17 C19 C21 C22 95.1(10) . . . 7_565 ?
C19 C19 C21 C22 44.3(18) 7_565 . . 7_565 ?
C15 C19 C21 C22 71.6(12) 7_565 . . 7_565 ?
C21 C19 C21 C17 143.8(19) 7_565 . . 7_565 ?
C18 C19 C21 C17 -80(3) 7_565 . . 7_565 ?
C22 C19 C21 C17 -107.9(10) . . . 7_565 ?
C17 C19 C21 C17 14.6(8) . . . 7_565 ?
C19 C19 C21 C17 -36.2(19) 7_565 . . 7_565 ?
C15 C19 C21 C17 -8.8(11) 7_565 . . 7_565 ?
C22 C18 C21 C19 167(7) 7_565 . . 7_565 ?
C23 C18 C21 C19 141(6) . . . 7_565 ?
C15 C18 C21 C19 24(6) . . . 7_565 ?
C17 C18 C21 C19 17(6) 7_565 . . 7_565 ?
C20 C18 C21 C19 120(6) 7_565 . . 7_565 ?
C22 C18 C21 C21 71.9(15) 7_565 . . 7_565 ?
C19 C18 C21 C21 -95(6) 7_565 . . 7_565 ?
C23 C18 C21 C21 46.2(12) . . . 7_565 ?
C15 C18 C21 C21 -70.9(10) . . . 7_565 ?
C17 C18 C21 C21 -78.3(8) 7_565 . . 7_565 ?
C20 C18 C21 C21 24.6(10) 7_565 . . 7_565 ?
C22 C18 C21 C19 78.4(16) 7_565 . . . ?
C19 C18 C21 C19 -88(6) 7_565 . . . ?
C23 C18 C21 C19 52.8(13) . . . . ?
C15 C18 C21 C19 -64.4(13) . . . . ?
C17 C18 C21 C19 -71.7(10) 7_565 . . . ?
C20 C18 C21 C19 31.2(12) 7_565 . . . ?
C19 C18 C21 C22 -167(7) 7_565 . . 7_565 ?
C23 C18 C21 C22 -25.6(11) . . . 7_565 ?
C15 C18 C21 C22 -142.8(19) . . . 7_565 ?
C17 C18 C21 C22 -150.2(16) 7_565 . . 7_565 ?
C20 C18 C21 C22 -47.2(12) 7_565 . . 7_565 ?
C22 C18 C21 C17 150.2(16) 7_565 . . 7_565 ?
C19 C18 C21 C17 -17(6) 7_565 . . 7_565 ?
C23 C18 C21 C17 124.5(11) . . . 7_565 ?
C15 C18 C21 C17 7.4(7) . . . 7_565 ?
C20 C18 C21 C17 102.9(8) 7_565 . . 7_565 ?
C21 C19 C22 C23 96(3) 7_565 . . 7_565 ?
C18 C19 C22 C23 -91(3) 7_565 . . 7_565 ?
C21 C19 C22 C23 61(2) . . . 7_565 ?
C17 C19 C22 C23 -57(3) . . . 7_565 ?
C19 C19 C22 C23 42(2) 7_565 . . 7_565 ?
C15 C19 C22 C23 -62(2) 7_565 . . 7_565 ?
C21 C19 C22 C18 -174(3) 7_565 . . 7_565 ?
C21 C19 C22 C18 152(2) . . . 7_565 ?
C17 C19 C22 C18 33.6(19) . . . 7_565 ?
C19 C19 C22 C18 132.4(18) 7_565 . . 7_565 ?
C15 C19 C22 C18 29.0(17) 7_565 . . 7_565 ?
C21 C19 C22 C20 94(2) 7_565 . . . ?
C18 C19 C22 C20 -92.5(19) 7_565 . . . ?
C21 C19 C22 C20 59.3(13) . . . . ?
C17 C19 C22 C20 -58.8(14) . . . . ?
C19 C19 C22 C20 39.9(10) 7_565 . . . ?
C15 C19 C22 C20 -63.4(10) 7_565 . . . ?
C18 C19 C22 C21 174(3) 7_565 . . 7_565 ?
C21 C19 C22 C21 -34.6(17) . . . 7_565 ?
C17 C19 C22 C21 -153(3) . . . 7_565 ?
C19 C19 C22 C21 -54(2) 7_565 . . 7_565 ?
C15 C19 C22 C21 -157(3) 7_565 . . 7_565 ?
C20 C20 C22 C23 134(3) 7_565 . . 7_565 ?
C23 C20 C22 C23 125(4) . . . 7_565 ?
C16 C20 C22 C23 -118(3) . . . 7_565 ?
C16 C20 C22 C23 -147(3) 7_565 . . 7_565 ?
C18 C20 C22 C23 -136(4) 7_565 . . 7_565 ?
C23 C20 C22 C18 136(4) 7_565 . . 7_565 ?
C20 C20 C22 C18 -90.6(16) 7_565 . . 7_565 ?
C23 C20 C22 C18 -98.8(16) . . . 7_565 ?
C16 C20 C22 C18 17.9(18) . . . 7_565 ?
C16 C20 C22 C18 -12(2) 7_565 . . 7_565 ?
C23 C20 C22 C19 176(4) 7_565 . . . ?
C20 C20 C22 C19 -50.5(13) 7_565 . . . ?
C23 C20 C22 C19 -58.7(13) . . . . ?
C16 C20 C22 C19 58.0(13) . . . . ?
C16 C20 C22 C19 28.5(15) 7_565 . . . ?
C18 C20 C22 C19 40.1(12) 7_565 . . . ?
C23 C20 C22 C21 -165(3) 7_565 . . 7_565 ?
C20 C20 C22 C21 -31.7(11) 7_565 . . 7_565 ?
C23 C20 C22 C21 -39.9(11) . . . 7_565 ?
C16 C20 C22 C21 76.8(11) . . . 7_565 ?
C16 C20 C22 C21 47.3(13) 7_565 . . 7_565 ?
C18 C20 C22 C21 58.9(14) 7_565 . . 7_565 ?
C22 C18 C23 C20 -146(3) 7_565 . . 7_565 ?
C19 C18 C23 C20 -73(2) 7_565 . . 7_565 ?
C15 C18 C23 C20 35.4(19) . . . 7_565 ?
C21 C18 C23 C20 -79.5(17) . . . 7_565 ?
C17 C18 C23 C20 6(2) 7_565 . . 7_565 ?
C19 C18 C23 C22 73(3) 7_565 . . 7_565 ?
C15 C18 C23 C22 -179(3) . . . 7_565 ?
C21 C18 C23 C22 66(3) . . . 7_565 ?
C17 C18 C23 C22 151(3) 7_565 . . 7_565 ?
C20 C18 C23 C22 146(3) 7_565 . . 7_565 ?
C22 C18 C23 C20 -123(3) 7_565 . . . ?
C19 C18 C23 C20 -49.9(18) 7_565 . . . ?
C15 C18 C23 C20 58.0(13) . . . . ?
C21 C18 C23 C20 -56.8(12) . . . . ?
C17 C18 C23 C20 28.3(17) 7_565 . . . ?
C20 C18 C23 C20 22.7(9) 7_565 . . . ?
C23 C20 C23 C20 -179.993(8) 7_565 . . 7_565 ?
C22 C20 C23 C20 160.5(14) . . . 7_565 ?
C16 C20 C23 C20 41(2) . . . 7_565 ?
C16 C20 C23 C20 34.3(17) 7_565 . . 7_565 ?
C18 C20 C23 C20 132.9(14) 7_565 . . 7_565 ?
C23 C20 C23 C22 47(3) 7_565 . . 7_565 ?
C20 C20 C23 C22 -133(3) 7_565 . . 7_565 ?
C22 C20 C23 C22 27.2(19) . . . 7_565 ?
C16 C20 C23 C22 -92(2) . . . 7_565 ?
C16 C20 C23 C22 -98.9(19) 7_565 . . 7_565 ?
C18 C20 C23 C22 0(2) 7_565 . . 7_565 ?
C23 C20 C23 C18 79.7(19) 7_565 . . . ?
C20 C20 C23 C18 -100.3(19) 7_565 . . . ?
C22 C20 C23 C18 60.2(11) . . . . ?
C16 C20 C23 C18 -59.2(11) . . . . ?
C16 C20 C23 C18 -66.0(9) 7_565 . . . ?
C18 C20 C23 C18 32.6(11) 7_565 . . . ?
