#------------------------------------------------------------------------------
#$Date: 2020-10-06 13:16:14 +0200 (mar 06 de oct de 2020) $
#$Revision: 257985 $
#$URL: svn://www.crystallography.net/cod/cif/7/24/03/7240381.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240381
loop_
_publ_author_name
'Shi, Ju-Feng'
'Chen, Zhi-Jin'
'Zhang, Liu-Jie'
'Zhou, Kun'
'Ji, Jiu-Yu'
'Bi, Yan-Feng'
_publ_section_title
;
 A one-dimensional infinite silver alkynyl assembly
 [Ag8(CCtBu)5(CF3COO)3(CH3CN)]n: synthesis, crystal structure and
 properties
;
_journal_issue                   27
_journal_name_full               'RSC Advances'
_journal_page_first              16045
_journal_page_last               16049
_journal_paper_doi               10.1039/D0RA01703E
_journal_volume                  10
_journal_year                    2020
_chemical_formula_sum            'C38 H48 Ag8 F9 N O6'
_chemical_formula_weight         1648.73
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2020-04-05 deposited with the CCDC.	2020-04-07 downloaded from the CCDC.
;
_cell_angle_alpha                101.9000(10)
_cell_angle_beta                 92.7640(10)
_cell_angle_gamma                115.5780(10)
_cell_formula_units_Z            2
_cell_length_a                   12.8132(6)
_cell_length_b                   14.3594(7)
_cell_length_c                   15.7145(7)
_cell_measurement_reflns_used    9975
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.0277
_cell_measurement_theta_min      2.3529
_cell_volume                     2520.9(2)
_computing_cell_refinement       'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_data_collection       'Bruker Instrument Service vV6.2.3'
_computing_data_reduction        'SAINT V8.38A (Bruker AXS Inc., 2017)'
_computing_structure_refinement  'SHELXL-2017/1 (Sheldrick, 2017)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker D8 QUEST'
_diffrn_measurement_method       'φ & ω with fast scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0195
_diffrn_reflns_av_unetI/netI     0.0235
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            21064
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.028
_diffrn_reflns_theta_max         25.028
_diffrn_reflns_theta_min         2.353
_exptl_absorpt_coefficient_mu    3.112
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6762
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 - Bruker AXS area detector scaling and absorption correction
;
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    2.172
_exptl_crystal_description       Block
_exptl_crystal_F_000             1576
_exptl_crystal_size_max          0.390
_exptl_crystal_size_mid          0.360
_exptl_crystal_size_min          0.360
_refine_diff_density_max         0.783
_refine_diff_density_min         -0.808
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     682
_refine_ls_number_reflns         8831
_refine_ls_number_restraints     145
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0336
_refine_ls_R_factor_gt           0.0264
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0280P)²+3.5034P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0612
_refine_ls_wR_factor_ref         0.0654
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7628
_reflns_number_total             8831
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ra01703e2.cif
_cod_data_source_block           Compound_1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-Scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7240381.cif.
;
_cod_database_code               7240381
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.377
_shelx_estimated_absorpt_t_max   0.400
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.51100(3) 0.58008(3) 1.07895(2) 0.05722(9) Uani 1 1 d . . . . .
Ag2 Ag 0.50179(3) 0.62795(3) 0.90342(2) 0.04822(8) Uani 1 1 d . . . . .
Ag3 Ag 0.68198(3) 0.57068(3) 0.82648(2) 0.06689(11) Uani 1 1 d . . . . .
Ag4 Ag 0.46198(3) 0.50440(2) 0.72547(2) 0.04495(8) Uani 1 1 d . . . . .
Ag5 Ag 0.66812(3) 0.60929(3) 0.60954(2) 0.05786(10) Uani 1 1 d . . . . .
Ag6 Ag 0.42646(3) 0.35091(3) 0.56152(2) 0.05280(9) Uani 1 1 d . . . . .
Ag7 Ag 0.58318(3) 0.43579(2) 0.44201(2) 0.04473(8) Uani 1 1 d . . . . .
Ag8 Ag 0.45494(3) 0.26686(3) 0.27484(2) 0.06059(10) Uani 1 1 d . . . . .
C1 C 0.6394(4) 0.6057(3) 0.9681(3) 0.0493(10) Uani 1 1 d . . . . .
C2 C 0.7355(4) 0.6226(3) 0.9988(3) 0.0505(10) Uani 1 1 d . . . . .
C3 C 0.8521(4) 0.6459(4) 1.0426(3) 0.0650(12) Uani 1 1 d . . . . .
C4 C 0.9367(16) 0.7623(16) 1.0494(14) 0.110(4) Uani 0.56(2) 1 d . U P A 1
H4A H 0.939070 0.774939 0.991743 0.165 Uiso 0.56(2) 1 calc R U P A 1
H4B H 0.910717 0.807882 1.085922 0.165 Uiso 0.56(2) 1 calc R U P A 1
H4C H 1.013641 0.777130 1.074882 0.165 Uiso 0.56(2) 1 calc R U P A 1
C5 C 0.8976(17) 0.5768(17) 0.9792(16) 0.095(5) Uani 0.56(2) 1 d . U P A 1
H5A H 0.897107 0.591706 0.922410 0.142 Uiso 0.56(2) 1 calc R U P A 1
H5B H 0.976020 0.593918 1.002952 0.142 Uiso 0.56(2) 1 calc R U P A 1
H5C H 0.847555 0.502481 0.973424 0.142 Uiso 0.56(2) 1 calc R U P A 1
C6 C 0.8499(16) 0.6286(18) 1.1295(14) 0.097(4) Uani 0.56(2) 1 d . U P A 1
H6A H 0.927314 0.644720 1.154940 0.145 Uiso 0.56(2) 1 calc R U P A 1
H6B H 0.823324 0.674055 1.165515 0.145 Uiso 0.56(2) 1 calc R U P A 1
H6C H 0.797691 0.555369 1.126117 0.145 Uiso 0.56(2) 1 calc R U P A 1
C4' C 0.917(2) 0.762(2) 1.0927(18) 0.110(5) Uani 0.44(2) 1 d . U P A 2
H4'A H 0.870681 0.778273 1.133444 0.166 Uiso 0.44(2) 1 calc R U P A 2
H4'B H 0.990083 0.774252 1.124473 0.166 Uiso 0.44(2) 1 calc R U P A 2
H4'C H 0.932841 0.805967 1.052174 0.166 Uiso 0.44(2) 1 calc R U P A 2
C5' C 0.927(2) 0.626(2) 0.982(2) 0.105(5) Uani 0.44(2) 1 d . U P A 2
H5'A H 1.001168 0.643024 1.015382 0.158 Uiso 0.44(2) 1 calc R U P A 2
H5'B H 0.890615 0.552520 0.950598 0.158 Uiso 0.44(2) 1 calc R U P A 2
H5'C H 0.940418 0.670258 0.941822 0.158 Uiso 0.44(2) 1 calc R U P A 2
C6' C 0.8228(19) 0.574(2) 1.1121(17) 0.084(5) Uani 0.44(2) 1 d . U P A 2
H6'A H 0.773000 0.590534 1.149708 0.127 Uiso 0.44(2) 1 calc R U P A 2
H6'B H 0.783514 0.499971 1.081144 0.127 Uiso 0.44(2) 1 calc R U P A 2
H6'C H 0.894182 0.588555 1.146989 0.127 Uiso 0.44(2) 1 calc R U P A 2
C7 C 0.3882(4) 0.6064(3) 0.7812(3) 0.0472(9) Uani 1 1 d . . . . .
C8 C 0.3276(4) 0.6498(3) 0.7752(3) 0.0480(9) Uani 1 1 d . . . . .
C9 C 0.2488(4) 0.6982(5) 0.7681(4) 0.0705(14) Uani 1 1 d . . . . .
C10 C 0.1482(6) 0.6509(6) 0.8181(5) 0.120(3) Uani 1 1 d . . . . .
H10A H 0.096385 0.682600 0.813555 0.181 Uiso 1 1 calc R U . . .
H10B H 0.106005 0.575262 0.793516 0.181 Uiso 1 1 calc R U . . .
H10C H 0.178435 0.664991 0.878945 0.181 Uiso 1 1 calc R U . . .
C11 C 0.2059(8) 0.6787(9) 0.6733(5) 0.165(4) Uani 1 1 d . . . . .
H11A H 0.154015 0.710093 0.667848 0.248 Uiso 1 1 calc R U . . .
H11B H 0.271297 0.710142 0.643621 0.248 Uiso 1 1 calc R U . . .
H11C H 0.164724 0.603273 0.647291 0.248 Uiso 1 1 calc R U . . .
C12 C 0.3163(7) 0.8183(5) 0.8112(6) 0.123(3) Uani 1 1 d . . . . .
H12A H 0.265367 0.850921 0.806956 0.184 Uiso 1 1 calc R U . . .
H12B H 0.344081 0.829426 0.872026 0.184 Uiso 1 1 calc R U . . .
H12C H 0.381689 0.849786 0.781496 0.184 Uiso 1 1 calc R U . . .
C13 C 0.6004(3) 0.4702(3) 0.6812(2) 0.0436(9) Uani 1 1 d . . . . .
C14 C 0.6727(3) 0.4386(3) 0.6707(2) 0.0441(9) Uani 1 1 d . . . . .
C15 C 0.7575(4) 0.3941(4) 0.6568(3) 0.0583(11) Uani 1 1 d . . . . .
C16 C 0.8444(6) 0.4546(7) 0.6015(5) 0.130(3) Uani 1 1 d . . . . .
H16A H 0.899725 0.426362 0.592058 0.195 Uiso 1 1 calc R U . . .
H16B H 0.803134 0.446632 0.545750 0.195 Uiso 1 1 calc R U . . .
H16C H 0.885153 0.528801 0.631746 0.195 Uiso 1 1 calc R U . . .
C17 C 0.6912(7) 0.2793(6) 0.6102(6) 0.150(4) Uani 1 1 d . . . . .
H17A H 0.744595 0.248960 0.600609 0.225 Uiso 1 1 calc R U . . .
H17B H 0.635799 0.242547 0.645395 0.225 Uiso 1 1 calc R U . . .
H17C H 0.650256 0.272180 0.554628 0.225 Uiso 1 1 calc R U . . .
C18 C 0.8244(6) 0.4096(6) 0.7441(4) 0.108(2) Uani 1 1 d . . . . .
H18A H 0.879142 0.380741 0.734949 0.162 Uiso 1 1 calc R U . . .
H18B H 0.865930 0.484404 0.772503 0.162 Uiso 1 1 calc R U . . .
H18C H 0.770740 0.373609 0.780586 0.162 Uiso 1 1 calc R U . . .
C19 C 0.7163(4) 0.5902(3) 0.4664(3) 0.0493(10) Uani 1 1 d . . . . .
C20 C 0.8089(4) 0.6655(3) 0.4697(3) 0.0474(9) Uani 1 1 d . . . . .
C21 C 0.9250(4) 0.7521(4) 0.4696(4) 0.0690(13) Uani 1 1 d . . . . .
C22 C 0.9223(6) 0.8573(5) 0.5038(7) 0.141(3) Uani 1 1 d . . . . .
H22A H 0.997538 0.914798 0.504208 0.211 Uiso 1 1 calc R U . . .
H22B H 0.863777 0.861364 0.466389 0.211 Uiso 1 1 calc R U . . .
H22C H 0.903898 0.862450 0.562574 0.211 Uiso 1 1 calc R U . . .
C23 C 0.9523(6) 0.7371(7) 0.3763(5) 0.141(3) Uani 1 1 d . . . . .
H23A H 1.027861 0.792815 0.374511 0.212 Uiso 1 1 calc R U . . .
H23B H 0.952365 0.669128 0.357549 0.212 Uiso 1 1 calc R U . . .
H23C H 0.893832 0.739859 0.337670 0.212 Uiso 1 1 calc R U . . .
C24 C 1.0152(5) 0.7445(6) 0.5319(5) 0.110(2) Uani 1 1 d . . . . .
H24A H 1.091603 0.800610 0.532563 0.164 Uiso 1 1 calc R U . . .
H24B H 0.995367 0.751640 0.590217 0.164 Uiso 1 1 calc R U . . .
H24C H 1.015136 0.676680 0.511868 0.164 Uiso 1 1 calc R U . . .
C25 C 0.4618(4) 0.2753(3) 0.4240(2) 0.0457(9) Uani 1 1 d . . . . .
C26 C 0.4150(4) 0.1797(3) 0.4054(3) 0.0463(9) Uani 1 1 d . . . . .
C27 C 0.3649(4) 0.0623(3) 0.3919(3) 0.0555(11) Uani 1 1 d . . . . .
C28 C 0.4563(6) 0.0298(5) 0.3583(5) 0.112(2) Uani 1 1 d . . . . .
H28A H 0.426811 -0.045986 0.348740 0.168 Uiso 1 1 calc R U . . .
H28B H 0.473607 0.049293 0.303907 0.168 Uiso 1 1 calc R U . . .
H28C H 0.526370 0.065486 0.401002 0.168 Uiso 1 1 calc R U . . .
C29 C 0.2560(6) 0.0052(4) 0.3252(5) 0.111(2) Uani 1 1 d . . . . .
H29A H 0.225816 -0.070336 0.317942 0.167 Uiso 1 1 calc R U . . .
H29B H 0.198515 0.027235 0.344917 0.167 Uiso 1 1 calc R U . . .
H29C H 0.273776 0.022023 0.269984 0.167 Uiso 1 1 calc R U . . .
C30 C 0.3403(7) 0.0350(4) 0.4793(4) 0.102(2) Uani 1 1 d . . . . .
H30A H 0.307846 -0.040880 0.470996 0.153 Uiso 1 1 calc R U . . .
H30B H 0.411920 0.069430 0.520273 0.153 Uiso 1 1 calc R U . . .
H30C H 0.285514 0.059055 0.501912 0.153 Uiso 1 1 calc R U . . .
C31 C 0.4069(5) 0.7339(4) 1.0640(3) 0.0703(14) Uani 1 1 d . . . . .
C32 C 0.3517(9) 0.8072(7) 1.0963(5) 0.107(2) Uani 1 1 d . . . . .
C33 C 0.8608(4) 0.7766(4) 0.7722(3) 0.0624(12) Uani 1 1 d . . . . .
C34 C 0.9644(6) 0.8869(6) 0.8067(5) 0.099(2) Uani 1 1 d . . . . .
C35 C 0.3536(4) 0.2478(3) 0.7226(3) 0.0531(10) Uani 1 1 d . U . . .
C36 C 0.3101(7) 0.1493(5) 0.7586(4) 0.090(2) Uani 1 1 d . U . . .
C37 C 0.3172(5) 0.0956(4) 0.0802(4) 0.0784(15) Uani 1 1 d . . . . .
C38 C 0.2664(8) 0.0326(6) -0.0086(4) 0.141(3) Uani 1 1 d . . . . .
H38A H 0.229451 0.066025 -0.037249 0.212 Uiso 1 1 calc R U . . .
H38B H 0.209147 -0.037458 -0.007545 0.212 Uiso 1 1 calc R U . . .
H38C H 0.326704 0.027297 -0.040152 0.212 Uiso 1 1 calc R U . . .
O1 O 0.4032(4) 0.6733(3) 1.1099(3) 0.0885(12) Uani 1 1 d . . . . .
O2 O 0.4469(4) 0.7448(4) 0.9953(2) 0.0993(14) Uani 1 1 d . . . . .
O3 O 0.8606(16) 0.7080(18) 0.8096(17) 0.089(4) Uani 0.81(9) 1 d . . P B 1
O3' O 0.831(7) 0.737(6) 0.830(3) 0.07(2) Uani 0.19(9) 1 d . . P B 2
O4 O 0.7970(3) 0.7666(3) 0.7072(3) 0.0871(12) Uani 1 1 d . . . . .
O5 O 0.3729(3) 0.3338(2) 0.77421(18) 0.0557(7) Uani 1 1 d . . . . .
O6 O 0.3602(3) 0.2289(2) 0.6442(2) 0.0748(10) Uani 1 1 d . . . . .
N1 N 0.3558(4) 0.1453(4) 0.1485(3) 0.0887(14) Uani 1 1 d . . . . .
F1 F 0.2622(10) 0.7933(10) 1.0441(7) 0.148(3) Uani 0.645(11) 1 d . U P C 1
F2 F 0.4320(11) 0.9117(8) 1.1018(9) 0.150(3) Uani 0.645(11) 1 d . U P C 1
F3 F 0.3236(11) 0.8111(9) 1.1747(7) 0.131(3) Uani 0.645(11) 1 d . U P C 1
F1' F 0.367(2) 0.8771(19) 1.0552(14) 0.141(4) Uani 0.355(11) 1 d . U P C 2
F2' F 0.395(2) 0.8541(17) 1.1802(15) 0.147(4) Uani 0.355(11) 1 d . U P C 2
F3' F 0.2305(17) 0.7395(16) 1.0878(13) 0.144(4) Uani 0.355(11) 1 d . U P C 2
F4 F 0.9605(8) 0.9300(6) 0.8906(6) 0.157(3) Uani 0.718(9) 1 d . U P D 1
F5 F 0.9720(7) 0.9562(6) 0.7604(7) 0.147(3) Uani 0.718(9) 1 d . U P D 1
F6 F 1.0663(5) 0.8871(6) 0.8107(7) 0.133(3) Uani 0.718(9) 1 d . U P D 1
F4' F 1.032(2) 0.893(2) 0.8715(17) 0.156(5) Uani 0.282(9) 1 d . U P D 2
F5' F 0.938(2) 0.9604(16) 0.8183(19) 0.135(5) Uani 0.282(9) 1 d . U P D 2
F6' F 1.0442(18) 0.8822(17) 0.7477(17) 0.156(5) Uani 0.282(9) 1 d . U P D 2
F7 F 0.2192(13) 0.0688(9) 0.7093(8) 0.137(4) Uani 0.590(13) 1 d . U P E 1
F8 F 0.2872(13) 0.1617(12) 0.8385(10) 0.124(4) Uani 0.590(13) 1 d . U P E 1
F9 F 0.3962(11) 0.1118(9) 0.7554(7) 0.116(3) Uani 0.590(13) 1 d . U P E 1
F7' F 0.327(2) 0.0766(11) 0.7238(11) 0.125(4) Uani 0.410(13) 1 d . U P E 2
F8' F 0.1872(17) 0.1066(13) 0.7441(12) 0.140(5) Uani 0.410(13) 1 d . U P E 2
F9' F 0.3416(15) 0.1768(15) 0.8466(13) 0.110(4) Uani 0.410(13) 1 d . U P E 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 C1 123.19(14) . . ?
O1 Ag1 O5 90.41(13) . 2_667 ?
C1 Ag1 O5 109.93(12) . 2_667 ?
O1 Ag1 C1 103.09(15) . 2_667 ?
C1 Ag1 C1 106.32(12) . 2_667 ?
O5 Ag1 C1 124.70(11) 2_667 2_667 ?
O1 Ag1 Ag1 130.12(11) . 2_667 ?
C1 Ag1 Ag1 53.45(10) . 2_667 ?
O5 Ag1 Ag1 139.43(7) 2_667 2_667 ?
C1 Ag1 Ag1 52.87(9) 2_667 2_667 ?
O1 Ag1 Ag2 83.91(10) . . ?
C1 Ag1 Ag2 45.73(10) . . ?
O5 Ag1 Ag2 138.69(7) 2_667 . ?
C1 Ag1 Ag2 96.33(9) 2_667 . ?
Ag1 Ag1 Ag2 60.823(13) 2_667 . ?
O1 Ag1 Ag2 137.35(10) . 2_667 ?
C1 Ag1 Ag2 96.59(10) . 2_667 ?
O5 Ag1 Ag2 89.57(7) 2_667 2_667 ?
C1 Ag1 Ag2 45.58(10) 2_667 2_667 ?
Ag1 Ag1 Ag2 60.625(13) 2_667 2_667 ?
Ag2 Ag1 Ag2 121.448(12) . 2_667 ?
O1 Ag1 Ag3 79.44(10) . 2_667 ?
C1 Ag1 Ag3 151.02(10) . 2_667 ?
O5 Ag1 Ag3 85.54(7) 2_667 2_667 ?
C1 Ag1 Ag3 46.64(9) 2_667 2_667 ?
Ag1 Ag1 Ag3 98.738(18) 2_667 2_667 ?
Ag2 Ag1 Ag3 132.776(16) . 2_667 ?
Ag2 Ag1 Ag3 58.035(12) 2_667 2_667 ?
C1 Ag2 C7 150.41(14) . . ?
C1 Ag2 O2 113.49(15) . . ?
C7 Ag2 O2 95.65(15) . . ?
C1 Ag2 Ag4 103.40(11) . . ?
C7 Ag2 Ag4 47.35(10) . . ?
O2 Ag2 Ag4 143.00(10) . . ?
C1 Ag2 Ag1 53.41(10) . . ?
C7 Ag2 Ag1 146.46(10) . . ?
O2 Ag2 Ag1 75.21(9) . . ?
Ag4 Ag2 Ag1 133.597(15) . . ?
C1 Ag2 Ag1 53.80(11) . 2_667 ?
C7 Ag2 Ag1 111.30(11) . 2_667 ?
O2 Ag2 Ag1 129.52(10) . 2_667 ?
Ag4 Ag2 Ag1 75.255(12) . 2_667 ?
Ag1 Ag2 Ag1 58.552(12) . 2_667 ?
C1 Ag2 Ag3 50.42(10) . . ?
C7 Ag2 Ag3 100.90(10) . . ?
O2 Ag2 Ag3 152.04(13) . . ?
Ag4 Ag2 Ag3 57.579(10) . . ?
Ag1 Ag2 Ag3 101.443(13) . . ?
Ag1 Ag2 Ag3 64.017(12) 2_667 . ?
O3' Ag3 C1 99(2) . . ?
O3' Ag3 C13 111.0(12) . . ?
C1 Ag3 C13 143.87(14) . . ?
C1 Ag3 O3 111.5(8) . . ?
C13 Ag3 O3 102.8(7) . . ?
O3' Ag3 C2 87.0(10) . . ?
C1 Ag3 C2 27.23(13) . . ?
C13 Ag3 C2 161.50(13) . . ?
O3 Ag3 C2 93.2(6) . . ?
O3' Ag3 Ag4 118(2) . . ?
C1 Ag3 Ag4 100.72(11) . . ?
C13 Ag3 Ag4 47.88(10) . . ?
O3 Ag3 Ag4 125.0(3) . . ?
C2 Ag3 Ag4 127.81(10) . . ?
O3' Ag3 Ag2 102(3) . . ?
C1 Ag3 Ag2 45.94(11) . . ?
C13 Ag3 Ag2 106.96(10) . . ?
O3 Ag3 Ag2 119.1(10) . . ?
C2 Ag3 Ag2 72.11(10) . . ?
Ag4 Ag3 Ag2 59.079(11) . . ?
C1 Ag3 Ag1 49.99(11) . 2_667 ?
C13 Ag3 Ag1 97.55(9) . 2_667 ?
O3 Ag3 Ag1 159.1(5) . 2_667 ?
C2 Ag3 Ag1 65.89(9) . 2_667 ?
Ag4 Ag3 Ag1 73.051(13) . 2_667 ?
Ag2 Ag3 Ag1 57.947(11) . 2_667 ?
C7 Ag4 C13 154.62(16) . . ?
C7 Ag4 O5 109.85(13) . . ?
C13 Ag4 O5 91.04(12) . . ?
C7 Ag4 Ag3 109.10(11) . . ?
C13 Ag4 Ag3 54.14(10) . . ?
O5 Ag4 Ag3 91.99(7) . . ?
C7 Ag4 Ag2 50.44(11) . . ?
C13 Ag4 Ag2 117.48(10) . . ?
O5 Ag4 Ag2 90.84(7) . . ?
Ag3 Ag4 Ag2 63.343(11) . . ?
C7 Ag4 Ag6 137.94(11) . . ?
C13 Ag4 Ag6 58.06(10) . . ?
O5 Ag4 Ag6 79.72(7) . . ?
Ag3 Ag4 Ag6 111.410(14) . . ?
Ag2 Ag4 Ag6 169.214(14) . . ?
C7 Ag4 Ag8 53.02(11) . 2_666 ?
C13 Ag4 Ag8 103.58(10) . 2_666 ?
O5 Ag4 Ag8 160.50(7) . 2_666 ?
Ag3 Ag4 Ag8 86.406(15) . 2_666 ?
Ag2 Ag4 Ag8 71.078(11) . 2_666 ?
Ag6 Ag4 Ag8 118.915(13) . 2_666 ?
C7 Ag4 Ag7 83.23(10) . 2_666 ?
C13 Ag4 Ag7 92.96(10) . 2_666 ?
O5 Ag4 Ag7 133.27(7) . 2_666 ?
Ag3 Ag4 Ag7 126.957(15) . 2_666 ?
Ag2 Ag4 Ag7 127.129(13) . 2_666 ?
Ag6 Ag4 Ag7 63.656(11) . 2_666 ?
Ag8 Ag4 Ag7 59.768(10) 2_666 2_666 ?
C7 Ag4 Ag5 114.14(11) . . ?
C13 Ag4 Ag5 45.82(10) . . ?
O5 Ag4 Ag5 135.90(7) . . ?
Ag3 Ag4 Ag5 71.241(12) . . ?
Ag2 Ag4 Ag5 114.766(14) . . ?
Ag6 Ag4 Ag5 70.010(11) . . ?
Ag8 Ag4 Ag5 61.534(11) 2_666 . ?
Ag7 Ag4 Ag5 57.228(10) 2_666 . ?
O4 Ag5 C13 110.15(14) . . ?
O4 Ag5 C19 113.86(15) . . ?
C13 Ag5 C19 123.81(14) . . ?
O4 Ag5 Ag7 156.39(11) . . ?
C13 Ag5 Ag7 85.73(9) . . ?
C19 Ag5 Ag7 43.48(10) . . ?
O4 Ag5 Ag7 120.50(11) . 2_666 ?
C13 Ag5 Ag7 89.10(10) . 2_666 ?
C19 Ag5 Ag7 96.99(11) . 2_666 ?
Ag7 Ag5 Ag7 75.578(13) . 2_666 ?
O4 Ag5 Ag6 111.73(9) . 2_666 ?
C13 Ag5 Ag6 134.90(10) . 2_666 ?
C19 Ag5 Ag6 48.60(10) . 2_666 ?
Ag7 Ag5 Ag6 61.092(11) . 2_666 ?
Ag7 Ag5 Ag6 55.293(10) 2_666 2_666 ?
O4 Ag5 Ag8 65.75(11) . 2_666 ?
C13 Ag5 Ag8 92.53(9) . 2_666 ?
C19 Ag5 Ag8 136.74(10) . 2_666 ?
Ag7 Ag5 Ag8 132.944(15) . 2_666 ?
Ag7 Ag5 Ag8 57.369(11) 2_666 2_666 ?
Ag6 Ag5 Ag8 89.797(13) 2_666 2_666 ?
O4 Ag5 Ag4 102.59(11) . . ?
C13 Ag5 Ag4 40.84(9) . . ?
C19 Ag5 Ag4 143.07(10) . . ?
Ag7 Ag5 Ag4 100.791(12) . . ?
Ag7 Ag5 Ag4 57.408(10) 2_666 . ?
Ag6 Ag5 Ag4 112.669(14) 2_666 . ?
Ag8 Ag5 Ag4 54.786(10) 2_666 . ?
O6 Ag6 C25 111.12(12) . . ?
O6 Ag6 C19 109.97(14) . 2_666 ?
C25 Ag6 C19 107.80(14) . 2_666 ?
O6 Ag6 C13 89.80(12) . . ?
C25 Ag6 C13 118.17(13) . . ?
C19 Ag6 C13 118.48(14) 2_666 . ?
O6 Ag6 Ag7 147.19(10) . . ?
C25 Ag6 Ag7 45.99(9) . . ?
C19 Ag6 Ag7 100.75(10) 2_666 . ?
C13 Ag6 Ag7 85.39(8) . . ?
O6 Ag6 Ag4 84.22(8) . . ?
C25 Ag6 Ag4 159.54(10) . . ?
C19 Ag6 Ag4 77.74(10) 2_666 . ?
C13 Ag6 Ag4 45.96(9) . . ?
Ag7 Ag6 Ag4 114.082(14) . . ?
O6 Ag6 Ag7 135.84(9) . 2_666 ?
C25 Ag6 Ag7 110.34(9) . 2_666 ?
C19 Ag6 Ag7 41.44(10) 2_666 2_666 ?
C13 Ag6 Ag7 83.77(9) . 2_666 ?
Ag7 Ag6 Ag7 75.872(12) . 2_666 ?
Ag4 Ag6 Ag7 60.356(10) . 2_666 ?
O6 Ag6 Ag5 137.61(9) . 2_666 ?
C25 Ag6 Ag5 61.62(10) . 2_666 ?
C19 Ag6 Ag5 47.90(10) 2_666 2_666 ?
C13 Ag6 Ag5 131.65(9) . 2_666 ?
Ag7 Ag6 Ag5 60.171(11) . 2_666 ?
Ag4 Ag6 Ag5 116.339(14) . 2_666 ?
Ag7 Ag6 Ag5 57.046(10) 2_666 2_666 ?
C19 Ag7 C25 173.68(16) . . ?
C19 Ag7 Ag6 125.66(11) . . ?
C25 Ag7 Ag6 54.26(10) . . ?
C19 Ag7 Ag8 132.38(11) . . ?
C25 Ag7 Ag8 50.35(10) . . ?
Ag6 Ag7 Ag8 99.840(13) . . ?
C19 Ag7 Ag5 51.43(11) . . ?
C25 Ag7 Ag5 127.30(10) . . ?
Ag6 Ag7 Ag5 74.449(12) . . ?
Ag8 Ag7 Ag5 168.781(16) . . ?
C19 Ag7 Ag5 119.93(12) . 2_666 ?
C25 Ag7 Ag5 66.21(12) . 2_666 ?
Ag6 Ag7 Ag5 64.536(11) . 2_666 ?
Ag8 Ag7 Ag5 64.374(12) . 2_666 ?
Ag5 Ag7 Ag5 104.421(12) . 2_666 ?
C19 Ag7 Ag4 79.07(11) . 2_666 ?
C25 Ag7 Ag4 105.83(10) . 2_666 ?
Ag6 Ag7 Ag4 129.855(14) . 2_666 ?
Ag8 Ag7 Ag4 59.280(11) . 2_666 ?
Ag5 Ag7 Ag4 116.779(13) . 2_666 ?
Ag5 Ag7 Ag4 65.365(10) 2_666 2_666 ?
C19 Ag7 Ag6 49.50(12) . 2_666 ?
C25 Ag7 Ag6 136.57(12) . 2_666 ?
Ag6 Ag7 Ag6 104.128(12) . 2_666 ?
Ag8 Ag7 Ag6 111.401(13) . 2_666 ?
Ag5 Ag7 Ag6 61.860(11) . 2_666 ?
Ag5 Ag7 Ag6 70.439(12) 2_666 2_666 ?
Ag4 Ag7 Ag6 55.989(9) 2_666 2_666 ?
N1 Ag8 C25 137.05(15) . . ?
N1 Ag8 C7 99.64(16) . 2_666 ?
C25 Ag8 C7 121.55(14) . 2_666 ?
N1 Ag8 C26 110.36(15) . . ?
C25 Ag8 C26 27.69(12) . . ?
C7 Ag8 C26 141.24(13) 2_666 . ?
N1 Ag8 Ag4 116.94(13) . 2_666 ?
C25 Ag8 Ag4 101.73(9) . 2_666 ?
C7 Ag8 Ag4 45.06(9) 2_666 2_666 ?
C26 Ag8 Ag4 129.17(9) . 2_666 ?
N1 Ag8 Ag7 177.49(15) . . ?
C25 Ag8 Ag7 44.21(9) . . ?
C7 Ag8 Ag7 79.80(10) 2_666 . ?
C26 Ag8 Ag7 71.20(9) . . ?
Ag4 Ag8 Ag7 60.952(11) 2_666 . ?
N1 Ag8 Ag5 119.85(14) . 2_666 ?
C25 Ag8 Ag5 60.92(10) . 2_666 ?
C7 Ag8 Ag5 108.39(10) 2_666 2_666 ?
C26 Ag8 Ag5 77.67(9) . 2_666 ?
Ag4 Ag8 Ag5 63.683(11) 2_666 2_666 ?
Ag7 Ag8 Ag5 58.257(11) . 2_666 ?
C2 C1 Ag2 160.2(4) . . ?
C2 C1 Ag3 90.7(3) . . ?
Ag2 C1 Ag3 83.63(13) . . ?
C2 C1 Ag1 110.4(3) . . ?
Ag2 C1 Ag1 80.86(14) . . ?
Ag3 C1 Ag1 154.0(2) . . ?
C2 C1 Ag1 117.6(3) . 2_667 ?
Ag2 C1 Ag1 80.63(14) . 2_667 ?
Ag3 C1 Ag1 83.37(13) . 2_667 ?
Ag1 C1 Ag1 73.68(12) . 2_667 ?
C1 C2 C3 176.2(5) . . ?
C1 C2 Ag3 62.1(3) . . ?
C3 C2 Ag3 121.7(3) . . ?
C6 C3 C2 112.7(8) . . ?
C5' C3 C2 114.2(12) . . ?
C5' C3 C4' 106.5(12) . . ?
C2 C3 C4' 110.4(10) . . ?
C6 C3 C4 108.6(9) . . ?
C2 C3 C4 108.8(8) . . ?
C6 C3 C5 113.3(13) . . ?
C2 C3 C5 106.8(8) . . ?
C4 C3 C5 106.3(10) . . ?
C5' C3 C6' 113.4(16) . . ?
C2 C3 C6' 103.9(8) . . ?
C4' C3 C6' 108.4(11) . . ?
C3 C4 H4A 109.5 . . ?
C3 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C3 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C3 C6 H6A 109.5 . . ?
C3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C3 C4' H4'A 109.5 . . ?
C3 C4' H4'B 109.5 . . ?
H4'A C4' H4'B 109.5 . . ?
C3 C4' H4'C 109.5 . . ?
H4'A C4' H4'C 109.5 . . ?
H4'B C4' H4'C 109.5 . . ?
C3 C5' H5'A 109.5 . . ?
C3 C5' H5'B 109.5 . . ?
H5'A C5' H5'B 109.5 . . ?
C3 C5' H5'C 109.5 . . ?
H5'A C5' H5'C 109.5 . . ?
H5'B C5' H5'C 109.5 . . ?
C3 C6' H6'A 109.5 . . ?
C3 C6' H6'B 109.5 . . ?
H6'A C6' H6'B 109.5 . . ?
C3 C6' H6'C 109.5 . . ?
H6'A C6' H6'C 109.5 . . ?
H6'B C6' H6'C 109.5 . . ?
C8 C7 Ag4 151.9(3) . . ?
C8 C7 Ag2 125.8(3) . . ?
Ag4 C7 Ag2 82.21(13) . . ?
C8 C7 Ag8 93.0(3) . 2_666 ?
Ag4 C7 Ag8 81.92(13) . 2_666 ?
Ag2 C7 Ag8 94.28(15) . 2_666 ?
C7 C8 C9 177.2(5) . . ?
C8 C9 C11 108.7(5) . . ?
C8 C9 C10 109.4(4) . . ?
C11 C9 C10 111.4(6) . . ?
C8 C9 C12 108.7(5) . . ?
C11 C9 C12 110.6(6) . . ?
C10 C9 C12 107.9(5) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C9 C11 H11A 109.5 . . ?
C9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C9 C12 H12A 109.5 . . ?
C9 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C9 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C14 C13 Ag4 165.3(3) . . ?
C14 C13 Ag3 95.5(3) . . ?
Ag4 C13 Ag3 77.98(12) . . ?
C14 C13 Ag5 100.7(3) . . ?
Ag4 C13 Ag5 93.34(15) . . ?
Ag3 C13 Ag5 99.07(14) . . ?
C14 C13 Ag6 107.2(3) . . ?
Ag4 C13 Ag6 75.98(12) . . ?
Ag3 C13 Ag6 151.73(17) . . ?
Ag5 C13 Ag6 93.26(13) . . ?
C13 C14 C15 177.2(4) . . ?
C14 C15 C17 108.2(4) . . ?
C14 C15 C18 109.6(4) . . ?
C17 C15 C18 111.5(6) . . ?
C14 C15 C16 108.8(4) . . ?
C17 C15 C16 110.5(6) . . ?
C18 C15 C16 108.2(5) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 Ag7 162.6(4) . . ?
C20 C19 Ag5 106.5(3) . . ?
Ag7 C19 Ag5 85.09(14) . . ?
C20 C19 Ag6 104.9(3) . 2_666 ?
Ag7 C19 Ag6 89.06(15) . 2_666 ?
Ag5 C19 Ag6 83.50(14) . 2_666 ?
C19 C20 C21 175.6(5) . . ?
C20 C21 C22 108.3(4) . . ?
C20 C21 C23 107.9(5) . . ?
C22 C21 C23 112.8(6) . . ?
C20 C21 C24 108.4(4) . . ?
C22 C21 C24 109.0(6) . . ?
C23 C21 C24 110.3(6) . . ?
C21 C22 H22A 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C21 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C21 C23 H23A 109.5 . . ?
C21 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C21 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C26 C25 Ag7 163.5(4) . . ?
C26 C25 Ag8 88.4(3) . . ?
Ag7 C25 Ag8 85.45(13) . . ?
C26 C25 Ag6 112.9(3) . . ?
Ag7 C25 Ag6 79.75(12) . . ?
Ag8 C25 Ag6 147.05(19) . . ?
C25 C26 C27 173.5(4) . . ?
C25 C26 Ag8 63.9(2) . . ?
C27 C26 Ag8 121.5(3) . . ?
C26 C27 C29 111.5(4) . . ?
C26 C27 C30 109.0(4) . . ?
C29 C27 C30 110.7(5) . . ?
C26 C27 C28 107.1(4) . . ?
C29 C27 C28 108.8(5) . . ?
C30 C27 C28 109.6(5) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
O2 C31 O1 130.6(5) . . ?
O2 C31 C32 114.1(5) . . ?
O1 C31 C32 115.3(5) . . ?
F1 C32 F3 107.3(10) . . ?
F1' C32 F2' 109.2(15) . . ?
F1 C32 F2 103.4(9) . . ?
F3 C32 F2 103.3(9) . . ?
F1' C32 F3' 109.3(15) . . ?
F2' C32 F3' 109.5(13) . . ?
F1' C32 C31 115.3(10) . . ?
F1 C32 C31 115.3(7) . . ?
F3 C32 C31 117.0(7) . . ?
F2' C32 C31 107.8(11) . . ?
F2 C32 C31 109.0(8) . . ?
F3' C32 C31 105.6(9) . . ?
O3' C33 O4 126(3) . . ?
O4 C33 O3 129.7(8) . . ?
O3' C33 C34 110(2) . . ?
O4 C33 C34 115.1(5) . . ?
O3 C33 C34 114.8(7) . . ?
F5' C34 F4' 113.4(18) . . ?
F6 C34 F5 104.9(8) . . ?
F6 C34 F4 103.8(7) . . ?
F5 C34 F4 107.6(9) . . ?
F5' C34 F6' 120.3(18) . . ?
F4' C34 F6' 91.9(16) . . ?
F5' C34 C33 114.3(12) . . ?
F4' C34 C33 113.3(12) . . ?
F6 C34 C33 114.3(7) . . ?
F5 C34 C33 114.7(6) . . ?
F4 C34 C33 110.6(7) . . ?
F6' C34 C33 101.4(10) . . ?
O6 C35 O5 129.2(4) . . ?
O6 C35 C36 113.4(4) . . ?
O5 C35 C36 117.4(4) . . ?
F7 C36 F8 107.6(8) . . ?
F7' C36 F9' 112.0(14) . . ?
F7' C36 F8' 103.2(11) . . ?
F9' C36 F8' 105.8(11) . . ?
F7 C36 F9 102.7(9) . . ?
F8 C36 F9 107.7(10) . . ?
F7' C36 C35 118.9(8) . . ?
F7 C36 C35 113.2(7) . . ?
F8 C36 C35 116.3(9) . . ?
F9' C36 C35 110.7(9) . . ?
F8' C36 C35 104.9(9) . . ?
F9 C36 C35 108.4(6) . . ?
N1 C37 C38 179.0(7) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C31 O1 Ag1 117.3(3) . . ?
C31 O2 Ag2 126.8(4) . . ?
C33 O3 Ag3 120.3(13) . . ?
C33 O3' Ag3 129(3) . . ?
C33 O4 Ag5 126.7(3) . . ?
C35 O5 Ag1 130.2(3) . 2_667 ?
C35 O5 Ag4 120.0(2) . . ?
Ag1 O5 Ag4 92.46(10) 2_667 . ?
C35 O6 Ag6 126.4(3) . . ?
C37 N1 Ag8 169.9(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.309(4) . ?
Ag1 C1 2.428(4) . ?
Ag1 O5 2.443(3) 2_667 ?
Ag1 C1 2.447(4) 2_667 ?
Ag1 Ag1 2.9232(6) 2_667 ?
Ag1 Ag2 2.9859(4) . ?
Ag1 Ag2 2.9917(5) 2_667 ?
Ag1 Ag3 3.1730(5) 2_667 ?
Ag2 C1 2.165(4) . ?
Ag2 C7 2.237(4) . ?
Ag2 O2 2.348(3) . ?
Ag2 Ag4 2.8746(4) . ?
Ag2 Ag3 2.9946(5) . ?
Ag3 O3' 2.32(4) . ?
Ag3 C1 2.322(4) . ?
Ag3 C13 2.344(4) . ?
Ag3 O3 2.361(14) . ?
Ag3 C2 2.629(4) . ?
Ag3 Ag4 2.8285(5) . ?
Ag4 C7 2.134(4) . ?
Ag4 C13 2.145(4) . ?
Ag4 O5 2.517(3) . ?
Ag4 Ag6 2.8949(4) . ?
Ag4 Ag8 2.9849(5) 2_666 ?
Ag4 Ag7 3.0353(4) 2_666 ?
Ag4 Ag5 3.2747(5) . ?
Ag5 O4 2.300(3) . ?
Ag5 C13 2.353(4) . ?
Ag5 C19 2.354(4) . ?
Ag5 Ag7 3.0000(5) . ?
Ag5 Ag7 3.0292(5) 2_666 ?
Ag5 Ag6 3.1526(5) 2_666 ?
Ag5 Ag8 3.2117(5) 2_666 ?
Ag6 O6 2.288(3) . ?
Ag6 C25 2.368(4) . ?
Ag6 C19 2.380(4) 2_666 ?
Ag6 C13 2.532(4) . ?
Ag6 Ag7 2.8706(4) . ?
Ag6 Ag7 3.1297(5) 2_666 ?
Ag7 C19 2.072(4) . ?
Ag7 C25 2.098(4) . ?
Ag7 Ag8 2.9998(5) . ?
Ag8 N1 2.239(5) . ?
Ag8 C25 2.317(4) . ?
Ag8 C7 2.408(4) 2_666 ?
Ag8 C26 2.578(4) . ?
C1 C2 1.203(6) . ?
C2 C3 1.480(6) . ?
C3 C6 1.44(2) . ?
C3 C5' 1.46(3) . ?
C3 C4' 1.51(3) . ?
C3 C4 1.53(2) . ?
C3 C5 1.57(2) . ?
C3 C6' 1.60(2) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C4' H4'A 0.9600 . ?
C4' H4'B 0.9600 . ?
C4' H4'C 0.9600 . ?
C5' H5'A 0.9600 . ?
C5' H5'B 0.9600 . ?
C5' H5'C 0.9600 . ?
C6' H6'A 0.9600 . ?
C6' H6'B 0.9600 . ?
C6' H6'C 0.9600 . ?
C7 C8 1.197(5) . ?
C8 C9 1.464(6) . ?
C9 C11 1.489(8) . ?
C9 C10 1.517(8) . ?
C9 C12 1.535(9) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 C14 1.199(5) . ?
C14 C15 1.483(6) . ?
C15 C17 1.486(8) . ?
C15 C18 1.504(7) . ?
C15 C16 1.523(7) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.202(6) . ?
C20 C21 1.470(6) . ?
C21 C22 1.511(8) . ?
C21 C23 1.518(9) . ?
C21 C24 1.532(8) . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 C26 1.199(5) . ?
C26 C27 1.484(5) . ?
C27 C29 1.495(7) . ?
C27 C30 1.516(7) . ?
C27 C28 1.516(7) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 O2 1.226(6) . ?
C31 O1 1.227(6) . ?
C31 C32 1.525(8) . ?
C32 F1' 1.25(2) . ?
C32 F1 1.293(12) . ?
C32 F3 1.297(11) . ?
C32 F2' 1.32(2) . ?
C32 F2 1.387(13) . ?
C32 F3' 1.41(2) . ?
C33 O3' 1.16(4) . ?
C33 O4 1.220(6) . ?
C33 O3 1.246(15) . ?
C33 C34 1.525(8) . ?
C34 F5' 1.22(2) . ?
C34 F4' 1.27(3) . ?
C34 F6 1.303(10) . ?
C34 F5 1.323(10) . ?
C34 F4 1.349(11) . ?
C34 F6' 1.43(3) . ?
C35 O6 1.222(5) . ?
C35 O5 1.243(5) . ?
C35 C36 1.520(6) . ?
C36 F7' 1.184(16) . ?
C36 F7 1.294(13) . ?
C36 F8 1.297(15) . ?
C36 F9' 1.35(2) . ?
C36 F8' 1.41(2) . ?
C36 F9 1.421(13) . ?
C37 N1 1.111(6) . ?
C37 C38 1.439(8) . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
