#------------------------------------------------------------------------------
#$Date: 2020-10-06 13:18:34 +0200 (mar 06 de oct de 2020) $
#$Revision: 257995 $
#$URL: svn://www.crystallography.net/cod/cif/7/24/07/7240785.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7240785
loop_
_publ_author_name
'Zhao, Yafeng'
'Xu, Yanhong'
'Xu, Bing'
'Cen, Peipei'
'Song, Weiming'
'Duan, Lijuan'
'Liu, Xiangyu'
_publ_section_title
;
 A dual-sensitized luminescent europium(iii) complex as a photoluminescent
 probe for selectively detecting Fe3+
;
_journal_issue                   41
_journal_name_full               'RSC Advances'
_journal_page_first              24244
_journal_page_last               24250
_journal_paper_doi               10.1039/D0RA03821K
_journal_volume                  10
_journal_year                    2020
_chemical_formula_moiety         'C70 H46 Eu2 F12 N8 O10'
_chemical_formula_sum            'C70 H46 Eu2 F12 N8 O10'
_chemical_formula_weight         1691.07
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2019-06-15
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-02-06 deposited with the CCDC.	2020-06-22 downloaded from the CCDC.
;
_cell_angle_alpha                112.234(8)
_cell_angle_beta                 106.909(10)
_cell_angle_gamma                94.287(8)
_cell_formula_units_Z            1
_cell_length_a                   10.2450(12)
_cell_length_b                   12.4101(10)
_cell_length_c                   14.5367(13)
_cell_measurement_reflns_used    3767
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      26.6650
_cell_measurement_theta_min      2.8750
_cell_volume                     1600.8(3)
_computing_cell_refinement       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      100.00(10)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.836
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0635
_diffrn_reflns_av_unetI/netI     0.1378
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.836
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            12478
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.836
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.506
_diffrn_reflns_theta_min         2.124
_exptl_absorpt_coefficient_mu    2.045
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.51376
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.754
_exptl_crystal_description       block
_exptl_crystal_F_000             836
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         3.917
_refine_diff_density_min         -2.843
_refine_diff_density_rms         0.215
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     461
_refine_ls_number_reflns         7443
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0979
_refine_ls_R_factor_gt           0.0714
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0621P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1437
_refine_ls_wR_factor_ref         0.1600
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5491
_reflns_number_total             7443
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0ra03821k2.cif
_cod_data_source_block           lxy190615
_cod_depositor_comments          'Adding full bibliography for 7240785.cif.'
_cod_database_code               7240785
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.806
_shelx_estimated_absorpt_t_min   0.777
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C6(H6), C7(H7), C8(H8), C9(H9), C10(H10), C13(H13), C16(H16),
 C17(H17), C18(H18), C19(H19), C20(H20), C21(H21), C22(H22), C23(H23), C26(H26),
  C27(H27), C30(H30), C31(H31), C32(H32)
2.b Idealised Me refined as rotating group:
 C35(H35A,H35B,H35C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.38809(4) 0.47693(3) 0.36303(3) 0.02139(13) Uani 1 1 d . . . . .
F1 F -0.1007(5) 0.2930(5) 0.2334(6) 0.0640(18) Uani 1 1 d . . . . .
F2 F -0.0468(5) 0.2016(6) 0.3310(5) 0.0665(19) Uani 1 1 d . . . . .
F3 F -0.0987(6) 0.1114(5) 0.1646(6) 0.080(2) Uani 1 1 d . . . . .
F4 F 0.6721(4) 0.5829(4) 0.1573(4) 0.0339(11) Uani 1 1 d . . . . .
F5 F 0.7190(4) 0.4240(4) 0.1731(4) 0.0389(11) Uani 1 1 d . . . . .
F6 F 0.5934(4) 0.4137(4) 0.0224(3) 0.0318(10) Uani 1 1 d . . . . .
O1 O 0.1814(5) 0.3490(4) 0.3356(4) 0.0252(11) Uani 1 1 d . . . . .
O2 O 0.4064(5) 0.2778(4) 0.2720(4) 0.0247(11) Uani 1 1 d . . . . .
O3 O 0.5147(5) 0.5081(4) 0.2573(4) 0.0258(11) Uani 1 1 d . . . . .
O4 O 0.2245(5) 0.4303(5) 0.1868(4) 0.0280(12) Uani 1 1 d . . . . .
O5 O 0.3942(5) 0.5282(4) 0.5348(4) 0.0214(10) Uani 1 1 d . . . . .
N1 N 0.2281(6) 0.6337(5) 0.3855(5) 0.0206(13) Uani 1 1 d . . . . .
N2 N 0.5086(6) 0.7019(5) 0.4548(5) 0.0224(13) Uani 1 1 d . . . . .
N3 N 0.1960(6) 1.0272(5) 0.6104(5) 0.0269(14) Uani 1 1 d . . . . .
N4 N 0.4885(6) 1.1002(5) 0.6743(5) 0.0257(14) Uani 1 1 d . . . . .
C1 C -0.0311(9) 0.2132(7) 0.2489(7) 0.037(2) Uani 1 1 d . . . . .
C2 C 0.1222(7) 0.2457(6) 0.2626(6) 0.0210(15) Uani 1 1 d . . . . .
C3 C 0.1789(8) 0.1617(7) 0.2008(6) 0.0276(17) Uani 1 1 d . . . . .
H3 H 0.118488 0.089535 0.146822 0.033 Uiso 1 1 calc R . . . .
C4 C 0.3219(8) 0.1781(6) 0.2141(6) 0.0238(16) Uani 1 1 d . . . . .
C5 C 0.3812(7) 0.0768(6) 0.1593(6) 0.0241(16) Uani 1 1 d . . . . .
C6 C 0.3004(9) -0.0355(7) 0.0854(7) 0.0351(19) Uani 1 1 d . . . . .
H6 H 0.202100 -0.049618 0.068735 0.042 Uiso 1 1 calc R . . . .
C7 C 0.3601(9) -0.1256(7) 0.0365(7) 0.037(2) Uani 1 1 d . . . . .
H7 H 0.302769 -0.199785 -0.016168 0.044 Uiso 1 1 calc R . . . .
C8 C 0.5025(9) -0.1087(7) 0.0634(7) 0.0345(19) Uani 1 1 d . . . . .
H8 H 0.543528 -0.171899 0.030580 0.041 Uiso 1 1 calc R . . . .
C9 C 0.5860(9) -0.0006(7) 0.1379(7) 0.0344(19) Uani 1 1 d . . . . .
H9 H 0.684557 0.010500 0.156788 0.041 Uiso 1 1 calc R . . . .
C10 C 0.5260(8) 0.0926(7) 0.1857(7) 0.0306(18) Uani 1 1 d . . . . .
H10 H 0.583960 0.167396 0.236537 0.037 Uiso 1 1 calc R . . . .
C11 C 0.6183(8) 0.4682(7) 0.1260(6) 0.0280(17) Uani 1 1 d . . . . .
C12 C 0.4888(7) 0.4549(6) 0.1576(6) 0.0229(15) Uani 1 1 d . . . . .
C13 C 0.3628(7) 0.3922(6) 0.0771(6) 0.0255(16) Uani 1 1 d . . . . .
H13 H 0.362384 0.352055 0.006909 0.031 Uiso 1 1 calc R . . . .
C14 C 0.2356(7) 0.3857(7) 0.0954(6) 0.0245(16) Uani 1 1 d . . . . .
C15 C 0.1018(8) 0.3324(7) 0.0014(6) 0.0251(16) Uani 1 1 d . . . . .
C16 C 0.0956(8) 0.2442(7) -0.0952(6) 0.0337(19) Uani 1 1 d . . . . .
H16 H 0.176662 0.214254 -0.101775 0.040 Uiso 1 1 calc R . . . .
C17 C -0.0280(8) 0.1996(8) -0.1822(7) 0.042(2) Uani 1 1 d . . . . .
H17 H -0.030547 0.139499 -0.247401 0.050 Uiso 1 1 calc R . . . .
C18 C -0.1472(9) 0.2426(8) -0.1741(7) 0.041(2) Uani 1 1 d . . . . .
H18 H -0.230936 0.214224 -0.233655 0.050 Uiso 1 1 calc R . . . .
C19 C -0.1415(8) 0.3281(8) -0.0768(7) 0.039(2) Uani 1 1 d . . . . .
H19 H -0.223072 0.357073 -0.070047 0.047 Uiso 1 1 calc R . . . .
C20 C -0.0210(8) 0.3714(7) 0.0092(7) 0.0341(19) Uani 1 1 d . . . . .
H20 H -0.020567 0.428617 0.075008 0.041 Uiso 1 1 calc R . . . .
C21 C 0.0893(8) 0.6006(7) 0.3489(6) 0.0271(17) Uani 1 1 d . . . . .
H21 H 0.047581 0.520984 0.298581 0.033 Uiso 1 1 calc R . . . .
C22 C 0.0027(8) 0.6769(6) 0.3808(6) 0.0264(16) Uani 1 1 d . . . . .
H22 H -0.095725 0.649402 0.352267 0.032 Uiso 1 1 calc R . . . .
C23 C 0.0606(7) 0.7924(6) 0.4539(6) 0.0227(15) Uani 1 1 d . . . . .
H23 H 0.002544 0.845251 0.476749 0.027 Uiso 1 1 calc R . . . .
C24 C 0.2058(7) 0.8316(6) 0.4943(6) 0.0222(15) Uani 1 1 d . . . . .
C25 C 0.2754(7) 0.9517(6) 0.5727(5) 0.0183(14) Uani 1 1 d . . . . .
C26 C 0.2651(8) 1.1377(7) 0.6807(6) 0.0300(18) Uani 1 1 d . . . . .
H26 H 0.214386 1.193530 0.711167 0.036 Uiso 1 1 calc R . . . .
C27 C 0.4110(8) 1.1736(7) 0.7107(6) 0.0298(18) Uani 1 1 d . . . . .
H27 H 0.454571 1.253627 0.759014 0.036 Uiso 1 1 calc R . . . .
C28 C 0.4205(7) 0.9883(6) 0.6064(6) 0.0206(15) Uani 1 1 d . . . . .
C29 C 0.5034(7) 0.9028(6) 0.5646(5) 0.0197(15) Uani 1 1 d . . . . .
C30 C 0.6496(7) 0.9349(6) 0.5968(6) 0.0253(16) Uani 1 1 d . . . . .
H30 H 0.697877 1.013550 0.646047 0.030 Uiso 1 1 calc R . . . .
C31 C 0.7208(8) 0.8509(7) 0.5558(6) 0.0266(17) Uani 1 1 d . . . . .
H31 H 0.819165 0.871060 0.574696 0.032 Uiso 1 1 calc R . . . .
C32 C 0.6468(7) 0.7344(6) 0.4853(6) 0.0223(15) Uani 1 1 d . . . . .
H32 H 0.697403 0.676363 0.458324 0.027 Uiso 1 1 calc R . . . .
C33 C 0.2858(7) 0.7492(6) 0.4565(6) 0.0196(15) Uani 1 1 d . . . . .
C34 C 0.4369(7) 0.7852(6) 0.4937(5) 0.0190(15) Uani 1 1 d . . . . .
C35 C 0.2829(8) 0.5593(7) 0.5743(6) 0.0274(16) Uani 1 1 d . . . . .
H35A H 0.284168 0.644265 0.593937 0.041 Uiso 1 1 calc GR . . . .
H35B H 0.295134 0.542632 0.636611 0.041 Uiso 1 1 calc GR . . . .
H35C H 0.193490 0.512412 0.519210 0.041 Uiso 1 1 calc GR . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O3 137.29(17) . . ?
O1 Eu1 O4 71.98(16) . . ?
O1 Eu1 N1 82.05(16) . . ?
O1 Eu1 N2 140.49(18) . . ?
O2 Eu1 O1 72.27(17) . . ?
O2 Eu1 O3 80.94(16) . . ?
O2 Eu1 O4 79.92(17) . . ?
O2 Eu1 N1 147.41(18) . . ?
O2 Eu1 N2 147.08(18) . . ?
O3 Eu1 O4 71.00(16) . . ?
O3 Eu1 N1 106.56(16) . . ?
O3 Eu1 N2 73.24(18) . . ?
O4 Eu1 N1 73.17(18) . . ?
O4 Eu1 N2 109.57(17) . . ?
O5 Eu1 O1 78.38(16) . . ?
O5 Eu1 O1 121.73(15) 2_666 . ?
O5 Eu1 O2 115.03(16) . . ?
O5 Eu1 O2 77.82(17) 2_666 . ?
O5 Eu1 O3 144.10(17) . . ?
O5 Eu1 O3 82.63(16) 2_666 . ?
O5 Eu1 O4 140.70(16) . . ?
O5 Eu1 O4 147.74(18) 2_666 . ?
O5 Eu1 O5 70.80(19) . 2_666 ?
O5 Eu1 N1 77.74(16) . . ?
O5 Eu1 N1 133.99(18) 2_666 . ?
O5 Eu1 N2 78.18(17) . . ?
O5 Eu1 N2 78.91(17) 2_666 . ?
N2 Eu1 N1 62.14(17) . . ?
C2 O1 Eu1 129.1(4) . . ?
C4 O2 Eu1 136.1(5) . . ?
C12 O3 Eu1 129.7(4) . . ?
C14 O4 Eu1 132.0(5) . . ?
Eu1 O5 Eu1 109.20(19) . 2_666 ?
C35 O5 Eu1 124.3(4) . 2_666 ?
C35 O5 Eu1 126.5(4) . . ?
C21 N1 Eu1 121.7(5) . . ?
C21 N1 C33 117.4(6) . . ?
C33 N1 Eu1 119.2(4) . . ?
C32 N2 Eu1 120.2(5) . . ?
C32 N2 C34 118.3(6) . . ?
C34 N2 Eu1 119.8(4) . . ?
C26 N3 C25 115.7(6) . . ?
C27 N4 C28 115.9(6) . . ?
F1 C1 F3 104.7(7) . . ?
F1 C1 C2 112.2(6) . . ?
F2 C1 F1 107.5(8) . . ?
F2 C1 F3 106.8(7) . . ?
F2 C1 C2 112.3(7) . . ?
F3 C1 C2 112.8(8) . . ?
O1 C2 C1 112.2(7) . . ?
O1 C2 C3 129.2(6) . . ?
C3 C2 C1 118.5(7) . . ?
C2 C3 H3 118.5 . . ?
C2 C3 C4 123.1(7) . . ?
C4 C3 H3 118.5 . . ?
O2 C4 C3 122.8(7) . . ?
O2 C4 C5 116.6(6) . . ?
C3 C4 C5 120.5(7) . . ?
C6 C5 C4 123.7(7) . . ?
C10 C5 C4 118.6(7) . . ?
C10 C5 C6 117.7(7) . . ?
C5 C6 H6 119.3 . . ?
C7 C6 C5 121.4(8) . . ?
C7 C6 H6 119.3 . . ?
C6 C7 H7 119.9 . . ?
C6 C7 C8 120.1(8) . . ?
C8 C7 H7 119.9 . . ?
C7 C8 H8 119.9 . . ?
C7 C8 C9 120.3(8) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 120.0 . . ?
C8 C9 C10 120.0(8) . . ?
C10 C9 H9 120.0 . . ?
C5 C10 H10 119.8 . . ?
C9 C10 C5 120.4(8) . . ?
C9 C10 H10 119.8 . . ?
F4 C11 F5 106.6(6) . . ?
F4 C11 C12 110.7(6) . . ?
F5 C11 C12 111.0(6) . . ?
F6 C11 F4 107.4(6) . . ?
F6 C11 F5 106.9(6) . . ?
F6 C11 C12 114.0(6) . . ?
O3 C12 C11 113.1(6) . . ?
O3 C12 C13 129.2(7) . . ?
C13 C12 C11 117.7(7) . . ?
C12 C13 H13 118.7 . . ?
C12 C13 C14 122.5(7) . . ?
C14 C13 H13 118.7 . . ?
O4 C14 C13 124.2(7) . . ?
O4 C14 C15 117.0(6) . . ?
C13 C14 C15 118.7(7) . . ?
C16 C15 C14 121.9(7) . . ?
C16 C15 C20 118.0(7) . . ?
C20 C15 C14 120.1(7) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 C15 120.9(8) . . ?
C17 C16 H16 119.6 . . ?
C16 C17 H17 119.9 . . ?
C18 C17 C16 120.3(8) . . ?
C18 C17 H17 119.9 . . ?
C17 C18 H18 120.7 . . ?
C17 C18 C19 118.6(8) . . ?
C19 C18 H18 120.7 . . ?
C18 C19 H19 119.3 . . ?
C20 C19 C18 121.3(8) . . ?
C20 C19 H19 119.3 . . ?
C15 C20 H20 119.6 . . ?
C19 C20 C15 120.8(8) . . ?
C19 C20 H20 119.6 . . ?
N1 C21 H21 118.4 . . ?
N1 C21 C22 123.3(7) . . ?
C22 C21 H21 118.4 . . ?
C21 C22 H22 120.3 . . ?
C23 C22 C21 119.4(7) . . ?
C23 C22 H22 120.3 . . ?
C22 C23 H23 120.3 . . ?
C22 C23 C24 119.5(7) . . ?
C24 C23 H23 120.3 . . ?
C23 C24 C25 122.9(6) . . ?
C23 C24 C33 117.5(7) . . ?
C33 C24 C25 119.6(6) . . ?
N3 C25 C24 118.1(6) . . ?
N3 C25 C28 121.2(6) . . ?
C28 C25 C24 120.7(6) . . ?
N3 C26 H26 119.0 . . ?
N3 C26 C27 122.1(8) . . ?
C27 C26 H26 119.0 . . ?
N4 C27 C26 122.3(7) . . ?
N4 C27 H27 118.8 . . ?
C26 C27 H27 118.8 . . ?
N4 C28 C25 122.7(7) . . ?
N4 C28 C29 117.7(6) . . ?
C25 C28 C29 119.5(6) . . ?
C30 C29 C28 121.7(6) . . ?
C34 C29 C28 119.7(6) . . ?
C34 C29 C30 118.6(7) . . ?
C29 C30 H30 120.6 . . ?
C31 C30 C29 118.8(7) . . ?
C31 C30 H30 120.6 . . ?
C30 C31 H31 120.4 . . ?
C30 C31 C32 119.2(7) . . ?
C32 C31 H31 120.4 . . ?
N2 C32 C31 122.8(7) . . ?
N2 C32 H32 118.6 . . ?
C31 C32 H32 118.6 . . ?
N1 C33 C24 122.9(6) . . ?
N1 C33 C34 117.0(6) . . ?
C24 C33 C34 120.1(6) . . ?
N2 C34 C29 122.2(6) . . ?
N2 C34 C33 117.5(6) . . ?
C29 C34 C33 120.3(6) . . ?
O5 C35 H35A 109.5 . . ?
O5 C35 H35B 109.5 . . ?
O5 C35 H35C 109.5 . . ?
H35A C35 H35B 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.385(5) . ?
Eu1 O2 2.373(5) . ?
Eu1 O3 2.393(5) . ?
Eu1 O4 2.437(5) . ?
Eu1 O5 2.312(5) . ?
Eu1 O5 2.313(4) 2_666 ?
Eu1 N1 2.624(6) . ?
Eu1 N2 2.609(6) . ?
F1 C1 1.312(9) . ?
F2 C1 1.307(10) . ?
F3 C1 1.334(10) . ?
F4 C11 1.336(8) . ?
F5 C11 1.339(9) . ?
F6 C11 1.331(8) . ?
O1 C2 1.272(9) . ?
O2 C4 1.272(8) . ?
O3 C12 1.278(9) . ?
O4 C14 1.275(9) . ?
O5 C35 1.434(8) . ?
N1 C21 1.335(9) . ?
N1 C33 1.367(9) . ?
N2 C32 1.334(9) . ?
N2 C34 1.356(9) . ?
N3 C25 1.351(9) . ?
N3 C26 1.341(10) . ?
N4 C27 1.314(10) . ?
N4 C28 1.345(9) . ?
C1 C2 1.527(11) . ?
C2 C3 1.385(10) . ?
C3 H3 0.9500 . ?
C3 C4 1.409(10) . ?
C4 C5 1.490(10) . ?
C5 C6 1.400(10) . ?
C5 C10 1.399(10) . ?
C6 H6 0.9500 . ?
C6 C7 1.373(12) . ?
C7 H7 0.9500 . ?
C7 C8 1.373(11) . ?
C8 H8 0.9500 . ?
C8 C9 1.376(11) . ?
C9 H9 0.9500 . ?
C9 C10 1.395(11) . ?
C10 H10 0.9500 . ?
C11 C12 1.543(10) . ?
C12 C13 1.387(9) . ?
C13 H13 0.9500 . ?
C13 C14 1.406(10) . ?
C14 C15 1.508(10) . ?
C15 C16 1.396(11) . ?
C15 C20 1.401(10) . ?
C16 H16 0.9500 . ?
C16 C17 1.394(11) . ?
C17 H17 0.9500 . ?
C17 C18 1.387(12) . ?
C18 H18 0.9500 . ?
C18 C19 1.391(13) . ?
C19 H19 0.9500 . ?
C19 C20 1.368(11) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C21 C22 1.389(11) . ?
C22 H22 0.9500 . ?
C22 C23 1.375(10) . ?
C23 H23 0.9500 . ?
C23 C24 1.401(9) . ?
C24 C25 1.453(10) . ?
C24 C33 1.407(10) . ?
C25 C28 1.401(9) . ?
C26 H26 0.9500 . ?
C26 C27 1.413(11) . ?
C27 H27 0.9500 . ?
C28 C29 1.471(10) . ?
C29 C30 1.408(10) . ?
C29 C34 1.400(9) . ?
C30 H30 0.9500 . ?
C30 C31 1.368(10) . ?
C31 H31 0.9500 . ?
C31 C32 1.407(10) . ?
C32 H32 0.9500 . ?
C33 C34 1.455(9) . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1 C2 C1 -158.9(4) . . . . ?
Eu1 O1 C2 C3 24.2(10) . . . . ?
Eu1 O2 C4 C3 -9.2(10) . . . . ?
Eu1 O2 C4 C5 170.7(4) . . . . ?
Eu1 O3 C12 C11 -159.3(4) . . . . ?
Eu1 O3 C12 C13 22.9(11) . . . . ?
Eu1 O4 C14 C13 -25.0(10) . . . . ?
Eu1 O4 C14 C15 160.4(4) . . . . ?
Eu1 N1 C21 C22 163.6(5) . . . . ?
Eu1 N1 C33 C24 -162.9(5) . . . . ?
Eu1 N1 C33 C34 16.5(7) . . . . ?
Eu1 N2 C32 C31 -164.9(5) . . . . ?
Eu1 N2 C34 C29 164.6(5) . . . . ?
Eu1 N2 C34 C33 -17.2(7) . . . . ?
F1 C1 C2 O1 54.4(9) . . . . ?
F1 C1 C2 C3 -128.3(8) . . . . ?
F2 C1 C2 O1 -66.7(9) . . . . ?
F2 C1 C2 C3 110.5(8) . . . . ?
F3 C1 C2 O1 172.4(6) . . . . ?
F3 C1 C2 C3 -10.3(10) . . . . ?
F4 C11 C12 O3 -58.6(8) . . . . ?
F4 C11 C12 C13 119.5(7) . . . . ?
F5 C11 C12 O3 59.5(8) . . . . ?
F5 C11 C12 C13 -122.4(7) . . . . ?
F6 C11 C12 O3 -179.8(6) . . . . ?
F6 C11 C12 C13 -1.7(9) . . . . ?
O1 C2 C3 C4 3.0(12) . . . . ?
O2 C4 C5 C6 -173.9(7) . . . . ?
O2 C4 C5 C10 8.6(9) . . . . ?
O3 C12 C13 C14 5.0(12) . . . . ?
O4 C14 C15 C16 -155.2(7) . . . . ?
O4 C14 C15 C20 25.1(10) . . . . ?
N1 C21 C22 C23 -0.3(11) . . . . ?
N1 C33 C34 N2 0.3(9) . . . . ?
N1 C33 C34 C29 178.5(6) . . . . ?
N3 C25 C28 N4 -2.5(10) . . . . ?
N3 C25 C28 C29 179.0(6) . . . . ?
N3 C26 C27 N4 -2.1(11) . . . . ?
N4 C28 C29 C30 2.0(9) . . . . ?
N4 C28 C29 C34 179.9(6) . . . . ?
C1 C2 C3 C4 -173.7(7) . . . . ?
C2 C3 C4 O2 -11.4(11) . . . . ?
C2 C3 C4 C5 168.7(6) . . . . ?
C3 C4 C5 C6 6.0(11) . . . . ?
C3 C4 C5 C10 -171.4(6) . . . . ?
C4 C5 C6 C7 179.4(7) . . . . ?
C4 C5 C10 C9 178.7(7) . . . . ?
C5 C6 C7 C8 3.3(13) . . . . ?
C6 C5 C10 C9 1.1(11) . . . . ?
C6 C7 C8 C9 -1.5(12) . . . . ?
C7 C8 C9 C10 -0.5(12) . . . . ?
C8 C9 C10 C5 0.7(12) . . . . ?
C10 C5 C6 C7 -3.1(11) . . . . ?
C11 C12 C13 C14 -172.7(6) . . . . ?
C12 C13 C14 O4 -4.0(11) . . . . ?
C12 C13 C14 C15 170.4(6) . . . . ?
C13 C14 C15 C16 29.9(10) . . . . ?
C13 C14 C15 C20 -149.7(7) . . . . ?
C14 C15 C16 C17 -177.4(7) . . . . ?
C14 C15 C20 C19 176.7(7) . . . . ?
C15 C16 C17 C18 0.2(12) . . . . ?
C16 C15 C20 C19 -2.9(11) . . . . ?
C16 C17 C18 C19 -1.9(12) . . . . ?
C17 C18 C19 C20 1.2(12) . . . . ?
C18 C19 C20 C15 1.2(12) . . . . ?
C20 C15 C16 C17 2.2(11) . . . . ?
C21 N1 C33 C24 2.2(9) . . . . ?
C21 N1 C33 C34 -178.3(6) . . . . ?
C21 C22 C23 C24 0.5(10) . . . . ?
C22 C23 C24 C25 -179.2(6) . . . . ?
C22 C23 C24 C33 0.5(10) . . . . ?
C23 C24 C25 N3 2.3(10) . . . . ?
C23 C24 C25 C28 -176.6(6) . . . . ?
C23 C24 C33 N1 -2.0(10) . . . . ?
C23 C24 C33 C34 178.6(6) . . . . ?
C24 C25 C28 N4 176.3(6) . . . . ?
C24 C25 C28 C29 -2.1(9) . . . . ?
C24 C33 C34 N2 179.8(6) . . . . ?
C24 C33 C34 C29 -2.0(9) . . . . ?
C25 N3 C26 C27 1.8(10) . . . . ?
C25 C24 C33 N1 177.8(6) . . . . ?
C25 C24 C33 C34 -1.6(9) . . . . ?
C25 C28 C29 C30 -179.4(6) . . . . ?
C25 C28 C29 C34 -1.5(9) . . . . ?
C26 N3 C25 C24 -178.5(6) . . . . ?
C26 N3 C25 C28 0.3(9) . . . . ?
C27 N4 C28 C25 2.2(10) . . . . ?
C27 N4 C28 C29 -179.3(6) . . . . ?
C28 N4 C27 C26 0.0(10) . . . . ?
C28 C29 C30 C31 179.4(6) . . . . ?
C28 C29 C34 N2 -178.3(6) . . . . ?
C28 C29 C34 C33 3.6(9) . . . . ?
C29 C30 C31 C32 -1.8(10) . . . . ?
C30 C29 C34 N2 -0.3(9) . . . . ?
C30 C29 C34 C33 -178.5(6) . . . . ?
C30 C31 C32 N2 1.1(11) . . . . ?
C32 N2 C34 C29 -0.4(9) . . . . ?
C32 N2 C34 C33 177.8(6) . . . . ?
C33 N1 C21 C22 -1.1(10) . . . . ?
C33 C24 C25 N3 -177.4(6) . . . . ?
C33 C24 C25 C28 3.7(9) . . . . ?
C34 N2 C32 C31 0.0(10) . . . . ?
C34 C29 C30 C31 1.4(10) . . . . ?
