#------------------------------------------------------------------------------
#$Date: 2022-01-06 22:13:07 +0100 (jue 06 de ene de 2022) $
#$Revision: 271830 $
#$URL: svn://www.crystallography.net/cod/cif/7/24/38/7243884.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7243884
loop_
_publ_author_name
'Long, Jérôme'
'Tolpygin, Aleksei O.'
'Cherkasov, Anton V.'
'Nelyubina, Yulia V.'
'Guari, Yannick'
'Larionova, Joulia'
'Trifonov, Alexander A.'
_publ_section_title
;
 Tuning the coordination sphere of octahedral Dy(iii) complexes with
 silanolate/stannanolate ligands: synthesis, structures and slow
 relaxation of the magnetization
;
_journal_issue                   47
_journal_name_full               CrystEngComm
_journal_page_first              8351
_journal_page_last               8359
_journal_paper_doi               10.1039/D1CE01266E
_journal_volume                  23
_journal_year                    2021
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C68 H61 Dy N2 O4 Si3, C4 H8 O'
_chemical_formula_sum            'C72 H69 Dy N2 O5 Si3'
_chemical_formula_weight         1289.06
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2021-07-10 deposited with the CCDC.	2021-11-09 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 115.8060(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   14.2745(4)
_cell_length_b                   16.2901(5)
_cell_length_c                   15.0762(4)
_cell_measurement_reflns_used    9830
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.56
_cell_measurement_theta_min      2.72
_cell_volume                     3156.10(16)
_computing_cell_refinement       'Saint 8.37a'
_computing_data_collection       APEX3
_computing_data_reduction        'Saint 8.37a'
_computing_structure_refinement  'SHELXL 2018/3'
_computing_structure_solution    'SHELXT 2018/2'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 Quest (CMOS)'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_av_unetI/netI     0.0610
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            52387
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.111
_diffrn_reflns_theta_min         2.501
_diffrn_source                   'microfocus tube'
_exptl_absorpt_coefficient_mu    1.293
_exptl_absorpt_correction_T_max  0.875
_exptl_absorpt_correction_T_min  0.802
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.356
_exptl_crystal_description       plate
_exptl_crystal_F_000             1326
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.160
_exptl_crystal_size_min          0.050
_refine_diff_density_max         0.657
_refine_diff_density_min         -0.539
_refine_diff_density_rms         0.082
_refine_ls_abs_structure_details
;
 Flack x determined using 6626 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.024(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     796
_refine_ls_number_reflns         18482
_refine_ls_number_restraints     136
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0504
_refine_ls_R_factor_gt           0.0349
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0201P)²+0.6729P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0539
_refine_ls_wR_factor_ref         0.0572
_reflns_Friedel_coverage         0.930
_reflns_Friedel_fraction_full    0.992
_reflns_Friedel_fraction_max     0.992
_reflns_number_gt                15818
_reflns_number_total             18482
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1ce01266e2.cif
_cod_data_source_block           dyosiph3bipy
_cod_depositor_comments
'Adding full bibliography for 7243882--7243885.cif.'
_cod_original_sg_symbol_H-M      'P 21'
_cod_database_code               7243884
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.782
_shelx_estimated_absorpt_t_max   0.938
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.27877(2) 0.62812(2) 0.15833(2) 0.01534(4) Uani 1 1 d . . . . .
Si1 Si 0.54047(8) 0.55522(7) 0.20158(8) 0.0184(2) Uani 1 1 d . . . . .
Si2 Si 0.23585(8) 0.48330(7) 0.32694(8) 0.0198(2) Uani 1 1 d . . . . .
Si3 Si 0.13372(9) 0.54643(7) -0.09144(8) 0.0223(2) Uani 1 1 d . . . . .
O1 O 0.42688(19) 0.57811(17) 0.18827(19) 0.0224(6) Uani 1 1 d . . . . .
O2 O 0.2411(2) 0.54433(17) 0.24686(19) 0.0229(6) Uani 1 1 d . . . . .
O3 O 0.1982(2) 0.59906(16) 0.00531(18) 0.0266(7) Uani 1 1 d . . . . .
N1 N 0.3469(3) 0.7321(2) 0.2955(2) 0.0217(7) Uani 1 1 d . . . . .
N2 N 0.3455(3) 0.7625(2) 0.1214(2) 0.0257(8) Uani 1 1 d . . . . .
C1 C 0.5523(3) 0.5764(2) 0.0837(3) 0.0213(8) Uani 1 1 d . . . . .
C2 C 0.4633(3) 0.5969(2) -0.0020(3) 0.0253(9) Uani 1 1 d . . . . .
H2A H 0.397206 0.596107 -0.001015 0.030 Uiso 1 1 calc R U . . .
C3 C 0.4698(3) 0.6183(4) -0.0882(3) 0.0323(11) Uani 1 1 d . . . . .
H3A H 0.408355 0.632265 -0.145184 0.039 Uiso 1 1 calc R U . . .
C4 C 0.5646(3) 0.6195(4) -0.0920(3) 0.0366(11) Uani 1 1 d . . . . .
H4A H 0.568941 0.635185 -0.150764 0.044 Uiso 1 1 calc R U . . .
C5 C 0.6534(3) 0.5975(3) -0.0090(3) 0.0327(11) Uani 1 1 d . . . . .
H5A H 0.718765 0.596620 -0.011429 0.039 Uiso 1 1 calc R U . . .
C6 C 0.6473(3) 0.5767(3) 0.0776(3) 0.0274(9) Uani 1 1 d . . . . .
H6A H 0.709110 0.562426 0.134059 0.033 Uiso 1 1 calc R U . . .
C7 C 0.6416(2) 0.6190(4) 0.3005(2) 0.0195(9) Uani 1 1 d . . . . .
C8 C 0.6478(3) 0.7030(3) 0.2828(3) 0.0328(10) Uani 1 1 d . . . . .
H8A H 0.602446 0.725002 0.220376 0.039 Uiso 1 1 calc R U . . .
C9 C 0.7179(4) 0.7550(3) 0.3533(4) 0.0397(12) Uani 1 1 d . . . . .
H9A H 0.718838 0.811812 0.339629 0.048 Uiso 1 1 calc R U . . .
C10 C 0.7858(4) 0.7240(3) 0.4430(4) 0.0384(12) Uani 1 1 d . . . . .
H10A H 0.835881 0.758834 0.490682 0.046 Uiso 1 1 calc R U . . .
C11 C 0.7810(3) 0.6413(4) 0.4639(3) 0.0371(14) Uani 1 1 d . . . . .
H11A H 0.826913 0.619692 0.526347 0.045 Uiso 1 1 calc R U . . .
C12 C 0.7089(3) 0.5906(3) 0.3930(3) 0.0291(10) Uani 1 1 d . . . . .
H12A H 0.705593 0.534462 0.408546 0.035 Uiso 1 1 calc R U . . .
C13 C 0.5693(3) 0.4445(2) 0.2366(3) 0.0199(8) Uani 1 1 d . . . . .
C14 C 0.6565(3) 0.4042(3) 0.2390(3) 0.0289(10) Uani 1 1 d . . . . .
H14A H 0.704016 0.433952 0.222559 0.035 Uiso 1 1 calc R U . . .
C15 C 0.6760(4) 0.3222(3) 0.2647(3) 0.0343(11) Uani 1 1 d . . . . .
H15A H 0.736788 0.296673 0.266927 0.041 Uiso 1 1 calc R U . . .
C16 C 0.6069(4) 0.2777(3) 0.2871(3) 0.0311(10) Uani 1 1 d . . . . .
H16A H 0.619383 0.221230 0.304017 0.037 Uiso 1 1 calc R U . . .
C17 C 0.5197(3) 0.3156(3) 0.2849(3) 0.0319(10) Uani 1 1 d . . . . .
H17A H 0.472027 0.285337 0.300514 0.038 Uiso 1 1 calc R U . . .
C18 C 0.5015(3) 0.3976(3) 0.2599(3) 0.0263(9) Uani 1 1 d . . . . .
H18A H 0.440901 0.422809 0.258556 0.032 Uiso 1 1 calc R U . . .
C19 C 0.3434(3) 0.5100(3) 0.4514(3) 0.0242(10) Uani 1 1 d . . . . .
C20 C 0.4399(3) 0.5331(3) 0.4578(3) 0.0307(10) Uani 1 1 d . . . . .
H20A H 0.451717 0.530000 0.400581 0.037 Uiso 1 1 calc R U . . .
C21 C 0.5198(4) 0.5608(3) 0.5457(4) 0.0441(13) Uani 1 1 d . . . . .
H21A H 0.585169 0.575691 0.548049 0.053 Uiso 1 1 calc R U . . .
C22 C 0.5037(4) 0.5665(3) 0.6291(4) 0.0462(14) Uani 1 1 d . . . . .
H22A H 0.557573 0.586466 0.688649 0.055 Uiso 1 1 calc R U . . .
C23 C 0.4092(4) 0.5431(3) 0.6262(3) 0.0396(12) Uani 1 1 d . . . . .
H23A H 0.398424 0.546415 0.684064 0.048 Uiso 1 1 calc R U . . .
C24 C 0.3298(3) 0.5148(3) 0.5384(3) 0.0307(10) Uani 1 1 d . . . . .
H24A H 0.265352 0.498508 0.537224 0.037 Uiso 1 1 calc R U . . .
C25 C 0.1078(3) 0.4961(3) 0.3321(3) 0.0223(9) Uani 1 1 d . . . . .
C26 C 0.0849(3) 0.5658(3) 0.3722(3) 0.0312(10) Uani 1 1 d . . . . .
H26A H 0.138995 0.603921 0.406675 0.037 Uiso 1 1 calc R U . . .
C27 C -0.0141(3) 0.5816(3) 0.3634(3) 0.0356(11) Uani 1 1 d . . . . .
H27A H -0.027868 0.630226 0.390393 0.043 Uiso 1 1 calc R U . . .
C28 C -0.0925(3) 0.5257(3) 0.3150(3) 0.0422(13) Uani 1 1 d . . . . .
H28A H -0.160450 0.535378 0.309353 0.051 Uiso 1 1 calc R U . . .
C29 C -0.0725(4) 0.4564(4) 0.2750(4) 0.0468(14) Uani 1 1 d . . . . .
H29A H -0.127074 0.418460 0.241165 0.056 Uiso 1 1 calc R U . . .
C30 C 0.0263(3) 0.4407(3) 0.2832(3) 0.0323(10) Uani 1 1 d . . . . .
H30A H 0.038894 0.392031 0.255443 0.039 Uiso 1 1 calc R U . . .
C31 C 0.2481(3) 0.3741(2) 0.2941(3) 0.0245(9) Uani 1 1 d . . . . .
C32 C 0.2644(4) 0.3093(3) 0.3595(4) 0.0444(13) Uani 1 1 d . . . . .
H32A H 0.274664 0.320395 0.424930 0.053 Uiso 1 1 calc R U . . .
C33 C 0.2659(5) 0.2285(3) 0.3304(5) 0.0570(17) Uani 1 1 d . . . . .
H33A H 0.273944 0.184990 0.375032 0.068 Uiso 1 1 calc R U . . .
C34 C 0.2559(4) 0.2114(3) 0.2382(5) 0.0535(16) Uani 1 1 d . . . . .
H34A H 0.257121 0.155956 0.219049 0.064 Uiso 1 1 calc R U . . .
C35 C 0.2440(4) 0.2737(3) 0.1728(4) 0.0460(14) Uani 1 1 d . . . . .
H35A H 0.239384 0.261976 0.109299 0.055 Uiso 1 1 calc R U . . .
C36 C 0.2388(3) 0.3545(3) 0.2012(3) 0.0334(11) Uani 1 1 d . . . . .
H36A H 0.228489 0.397432 0.155234 0.040 Uiso 1 1 calc R U . . .
C37 C 0.0014(3) 0.5193(2) -0.0999(3) 0.0269(9) Uani 1 1 d . . . . .
C38 C -0.0093(4) 0.5056(3) -0.0137(4) 0.0397(12) Uani 1 1 d . . . . .
H38A H 0.049809 0.510566 0.048061 0.048 Uiso 1 1 calc R U . . .
C39 C -0.1050(5) 0.4847(4) -0.0163(4) 0.0546(15) Uani 1 1 d . . . . .
H39A H -0.111046 0.477481 0.043561 0.066 Uiso 1 1 calc R U . . .
C40 C -0.1905(4) 0.4746(3) -0.1045(5) 0.0507(14) Uani 1 1 d . . . . .
H40A H -0.255289 0.459114 -0.105875 0.061 Uiso 1 1 calc R U . . .
C41 C -0.1825(4) 0.4869(3) -0.1910(4) 0.0438(13) Uani 1 1 d . . . . .
H41A H -0.241827 0.479965 -0.252340 0.053 Uiso 1 1 calc R U . . .
C42 C -0.0874(3) 0.5095(3) -0.1890(3) 0.0334(10) Uani 1 1 d . . . . .
H42A H -0.082820 0.518349 -0.249329 0.040 Uiso 1 1 calc R U . . .
C43 C 0.2027(3) 0.4478(3) -0.0893(3) 0.0276(9) Uani 1 1 d . . . . .
C44 C 0.2948(3) 0.4258(3) -0.0088(3) 0.0275(9) Uani 1 1 d . . . . .
H44A H 0.323389 0.461745 0.046242 0.033 Uiso 1 1 calc R U . . .
C45 C 0.3456(4) 0.3533(3) -0.0066(3) 0.0372(12) Uani 1 1 d . . . . .
H45A H 0.408077 0.339894 0.049614 0.045 Uiso 1 1 calc R U . . .
C46 C 0.3067(5) 0.3007(3) -0.0847(4) 0.0480(14) Uani 1 1 d . . . . .
H46A H 0.342340 0.251106 -0.083214 0.058 Uiso 1 1 calc R U . . .
C47 C 0.2149(5) 0.3200(3) -0.1664(4) 0.0547(16) Uani 1 1 d . . . . .
H47A H 0.187702 0.283791 -0.221190 0.066 Uiso 1 1 calc R U . . .
C48 C 0.1632(4) 0.3924(3) -0.1676(3) 0.0425(13) Uani 1 1 d . . . . .
H48A H 0.099393 0.404476 -0.222911 0.051 Uiso 1 1 calc R U . . .
C49 C 0.1124(3) 0.6043(2) -0.2070(3) 0.0212(9) Uani 1 1 d . . . . .
C50 C 0.1646(3) 0.5856(3) -0.2636(3) 0.0320(10) Uani 1 1 d . . . . .
H50A H 0.213383 0.541795 -0.243898 0.038 Uiso 1 1 calc R U . . .
C51 C 0.1473(3) 0.6293(5) -0.3481(3) 0.0364(9) Uani 1 1 d . . . . .
H51A H 0.183269 0.614827 -0.386061 0.044 Uiso 1 1 calc R U . . .
C52 C 0.0778(4) 0.6941(3) -0.3773(3) 0.0360(11) Uani 1 1 d . . . . .
H52A H 0.065682 0.724093 -0.435341 0.043 Uiso 1 1 calc R U . . .
C53 C 0.0267(4) 0.7146(3) -0.3224(3) 0.0382(12) Uani 1 1 d . . . . .
H53A H -0.020670 0.759434 -0.341765 0.046 Uiso 1 1 calc R U . . .
C54 C 0.0437(4) 0.6700(3) -0.2379(3) 0.0316(10) Uani 1 1 d . . . . .
H54A H 0.007368 0.684895 -0.200473 0.038 Uiso 1 1 calc R U . . .
C55 C 0.3373(4) 0.7181(3) 0.3790(3) 0.0307(10) Uani 1 1 d . . . . .
H55A H 0.295543 0.673154 0.380310 0.037 Uiso 1 1 calc R U . . .
C56 C 0.3848(4) 0.7652(3) 0.4630(4) 0.0399(14) Uani 1 1 d . . . . .
H56A H 0.375488 0.753822 0.520380 0.048 Uiso 1 1 calc R U . . .
C57 C 0.4460(4) 0.8291(3) 0.4603(4) 0.0524(15) Uani 1 1 d . . . . .
H57A H 0.481704 0.861907 0.517321 0.063 Uiso 1 1 calc R U . . .
C58 C 0.4561(4) 0.8462(3) 0.3750(3) 0.0459(14) Uani 1 1 d . . . . .
H58A H 0.497977 0.890628 0.372524 0.055 Uiso 1 1 calc R U . . .
C59 C 0.4035(3) 0.7967(2) 0.2926(3) 0.0258(9) Uani 1 1 d . . . . .
C60 C 0.4050(3) 0.8131(2) 0.1968(3) 0.0243(9) Uani 1 1 d . . . . .
C61 C 0.4611(4) 0.8767(3) 0.1815(4) 0.0342(11) Uani 1 1 d . . . . .
H61A H 0.502271 0.911862 0.234459 0.041 Uiso 1 1 calc R U . . .
C62 C 0.4567(4) 0.8888(3) 0.0892(4) 0.0383(12) Uani 1 1 d . . . . .
H62A H 0.495386 0.931824 0.078279 0.046 Uiso 1 1 calc R U . . .
C63 C 0.3958(4) 0.8377(3) 0.0130(4) 0.0387(12) Uani 1 1 d . . . . .
H63A H 0.391314 0.844912 -0.051303 0.046 Uiso 1 1 calc R U . . .
C64 C 0.3414(4) 0.7757(3) 0.0325(3) 0.0343(11) Uani 1 1 d . . . . .
H64A H 0.298810 0.740735 -0.020088 0.041 Uiso 1 1 calc R U . . .
O4 O 0.1209(7) 0.7003(5) 0.1282(6) 0.0297(19) Uani 0.726(15) 1 d D U P A 1
C65 C 0.0830(7) 0.7628(6) 0.0541(8) 0.062(3) Uani 0.726(15) 1 d D U P A 1
H65A H 0.079667 0.741086 -0.008561 0.074 Uiso 0.726(15) 1 calc R U P A 1
H65B H 0.131474 0.810037 0.074466 0.074 Uiso 0.726(15) 1 calc R U P A 1
C66 C -0.0186(6) 0.7895(5) 0.0394(9) 0.061(3) Uani 0.726(15) 1 d D U P A 1
H66A H -0.061087 0.809540 -0.028474 0.073 Uiso 0.726(15) 1 calc R U P A 1
H66B H -0.015857 0.831647 0.087749 0.073 Uiso 0.726(15) 1 calc R U P A 1
C67 C -0.0546(5) 0.7079(5) 0.0582(9) 0.059(3) Uani 0.726(15) 1 d D U P A 1
H67A H -0.070377 0.670150 0.002034 0.070 Uiso 0.726(15) 1 calc R U P A 1
H67B H -0.117350 0.713843 0.069840 0.070 Uiso 0.726(15) 1 calc R U P A 1
C68 C 0.0357(6) 0.6772(7) 0.1487(7) 0.038(2) Uani 0.726(15) 1 d D U P A 1
H68A H 0.039532 0.704522 0.208872 0.045 Uiso 0.726(15) 1 calc R U P A 1
H68B H 0.032502 0.617024 0.155866 0.045 Uiso 0.726(15) 1 calc R U P A 1
O4* O 0.1294(17) 0.7058(11) 0.1576(16) 0.028(5) Uani 0.274(15) 1 d D U P A 2
C65* C 0.0990(13) 0.7857(12) 0.116(2) 0.051(6) Uani 0.274(15) 1 d D U P A 2
H65C H 0.116864 0.793937 0.060165 0.062 Uiso 0.274(15) 1 calc R U P A 2
H65D H 0.133816 0.828728 0.166085 0.062 Uiso 0.274(15) 1 calc R U P A 2
C66* C -0.0143(13) 0.7884(12) 0.0823(17) 0.041(6) Uani 0.274(15) 1 d D U P A 2
H66C H -0.050388 0.785285 0.009554 0.049 Uiso 0.274(15) 1 calc R U P A 2
H66D H -0.034500 0.840397 0.103416 0.049 Uiso 0.274(15) 1 calc R U P A 2
C67* C -0.0439(13) 0.7175(11) 0.1264(19) 0.042(5) Uani 0.274(15) 1 d D U P A 2
H67C H -0.075828 0.736548 0.169274 0.050 Uiso 0.274(15) 1 calc R U P A 2
H67D H -0.094391 0.681996 0.074114 0.050 Uiso 0.274(15) 1 calc R U P A 2
C68* C 0.0535(15) 0.6718(18) 0.1847(19) 0.038(6) Uani 0.274(15) 1 d D U P A 2
H68C H 0.074954 0.679029 0.256147 0.046 Uiso 0.274(15) 1 calc R U P A 2
H68D H 0.044011 0.612519 0.168985 0.046 Uiso 0.274(15) 1 calc R U P A 2
O1S O 0.9934(3) 0.3121(2) 0.5916(3) 0.0569(10) Uani 1 1 d D . . . .
C1S C 1.0163(4) 0.3867(3) 0.5547(4) 0.0562(16) Uani 1 1 d D . . . .
H1SA H 1.007468 0.379081 0.486322 0.067 Uiso 1 1 calc R U . . .
H1SB H 1.088873 0.404123 0.596268 0.067 Uiso 1 1 calc R U . . .
C2S C 0.9413(4) 0.4496(3) 0.5578(4) 0.0472(13) Uani 1 1 d D . . . .
H2SA H 0.969828 0.478690 0.621835 0.057 Uiso 1 1 calc R U . . .
H2SB H 0.923812 0.490294 0.504106 0.057 Uiso 1 1 calc R U . . .
C3S C 0.8488(4) 0.3993(3) 0.5441(4) 0.0568(15) Uani 1 1 d D . . . .
H3SA H 0.808281 0.425871 0.575289 0.068 Uiso 1 1 calc R U . . .
H3SB H 0.802900 0.390540 0.473272 0.068 Uiso 1 1 calc R U . . .
C4S C 0.8950(5) 0.3207(4) 0.5938(5) 0.073(2) Uani 1 1 d D . . . .
H4SA H 0.904038 0.321474 0.662713 0.087 Uiso 1 1 calc R U . . .
H4SB H 0.848940 0.274255 0.559050 0.087 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Dy1 O2 96.91(10) . . ?
O1 Dy1 O3 99.37(10) . . ?
O2 Dy1 O3 111.70(10) . . ?
O1 Dy1 O4 173.2(2) . . ?
O2 Dy1 O4 87.74(19) . . ?
O3 Dy1 O4 83.3(2) . . ?
O1 Dy1 O4* 166.7(6) . . ?
O2 Dy1 O4* 83.0(4) . . ?
O3 Dy1 O4* 92.9(5) . . ?
O1 Dy1 N1 95.22(11) . . ?
O2 Dy1 N1 91.67(10) . . ?
O3 Dy1 N1 150.48(10) . . ?
O4 Dy1 N1 79.7(2) . . ?
O4* Dy1 N1 71.6(5) . . ?
O1 Dy1 N2 86.75(10) . . ?
O2 Dy1 N2 155.12(11) . . ?
O3 Dy1 N2 91.80(11) . . ?
O4 Dy1 N2 87.0(2) . . ?
O4* Dy1 N2 87.9(4) . . ?
N1 Dy1 N2 63.46(11) . . ?
O1 Si1 C13 110.38(16) . . ?
O1 Si1 C7 111.11(17) . . ?
C13 Si1 C7 108.1(2) . . ?
O1 Si1 C1 110.04(16) . . ?
C13 Si1 C1 110.01(17) . . ?
C7 Si1 C1 107.10(17) . . ?
O2 Si2 C25 109.34(16) . . ?
O2 Si2 C31 110.62(17) . . ?
C25 Si2 C31 108.72(18) . . ?
O2 Si2 C19 108.94(18) . . ?
C25 Si2 C19 108.59(19) . . ?
C31 Si2 C19 110.60(19) . . ?
O3 Si3 C43 110.79(17) . . ?
O3 Si3 C49 111.94(16) . . ?
C43 Si3 C49 108.43(18) . . ?
O3 Si3 C37 110.46(17) . . ?
C43 Si3 C37 107.58(19) . . ?
C49 Si3 C37 107.48(18) . . ?
Si1 O1 Dy1 169.71(17) . . ?
Si2 O2 Dy1 169.07(17) . . ?
Si3 O3 Dy1 158.89(17) . . ?
C59 N1 C55 118.2(3) . . ?
C59 N1 Dy1 121.7(3) . . ?
C55 N1 Dy1 119.6(3) . . ?
C64 N2 C60 118.7(4) . . ?
C64 N2 Dy1 120.1(3) . . ?
C60 N2 Dy1 119.7(3) . . ?
C6 C1 C2 117.0(4) . . ?
C6 C1 Si1 123.3(3) . . ?
C2 C1 Si1 119.6(3) . . ?
C3 C2 C1 121.3(4) . . ?
C3 C2 H2A 119.3 . . ?
C1 C2 H2A 119.3 . . ?
C4 C3 C2 120.6(4) . . ?
C4 C3 H3A 119.7 . . ?
C2 C3 H3A 119.7 . . ?
C3 C4 C5 119.2(4) . . ?
C3 C4 H4A 120.4 . . ?
C5 C4 H4A 120.4 . . ?
C4 C5 C6 120.4(4) . . ?
C4 C5 H5A 119.8 . . ?
C6 C5 H5A 119.8 . . ?
C5 C6 C1 121.5(4) . . ?
C5 C6 H6A 119.3 . . ?
C1 C6 H6A 119.3 . . ?
C12 C7 C8 116.3(4) . . ?
C12 C7 Si1 124.9(4) . . ?
C8 C7 Si1 118.7(3) . . ?
C9 C8 C7 122.2(4) . . ?
C9 C8 H8A 118.9 . . ?
C7 C8 H8A 118.9 . . ?
C10 C9 C8 119.7(5) . . ?
C10 C9 H9A 120.1 . . ?
C8 C9 H9A 120.1 . . ?
C9 C10 C11 119.7(4) . . ?
C9 C10 H10A 120.1 . . ?
C11 C10 H10A 120.1 . . ?
C12 C11 C10 119.7(4) . . ?
C12 C11 H11A 120.2 . . ?
C10 C11 H11A 120.2 . . ?
C7 C12 C11 122.2(5) . . ?
C7 C12 H12A 118.9 . . ?
C11 C12 H12A 118.9 . . ?
C14 C13 C18 116.5(4) . . ?
C14 C13 Si1 123.0(3) . . ?
C18 C13 Si1 120.5(3) . . ?
C15 C14 C13 122.0(4) . . ?
C15 C14 H14A 119.0 . . ?
C13 C14 H14A 119.0 . . ?
C16 C15 C14 119.9(4) . . ?
C16 C15 H15A 120.1 . . ?
C14 C15 H15A 120.1 . . ?
C17 C16 C15 119.5(4) . . ?
C17 C16 H16A 120.2 . . ?
C15 C16 H16A 120.2 . . ?
C16 C17 C18 120.1(4) . . ?
C16 C17 H17A 119.9 . . ?
C18 C17 H17A 119.9 . . ?
C17 C18 C13 122.0(4) . . ?
C17 C18 H18A 119.0 . . ?
C13 C18 H18A 119.0 . . ?
C20 C19 C24 117.0(4) . . ?
C20 C19 Si2 118.9(3) . . ?
C24 C19 Si2 123.8(3) . . ?
C19 C20 C21 122.0(4) . . ?
C19 C20 H20A 119.0 . . ?
C21 C20 H20A 119.0 . . ?
C22 C21 C20 119.8(5) . . ?
C22 C21 H21A 120.1 . . ?
C20 C21 H21A 120.1 . . ?
C21 C22 C23 120.1(5) . . ?
C21 C22 H22A 120.0 . . ?
C23 C22 H22A 120.0 . . ?
C22 C23 C24 119.9(4) . . ?
C22 C23 H23A 120.1 . . ?
C24 C23 H23A 120.1 . . ?
C23 C24 C19 121.2(4) . . ?
C23 C24 H24A 119.4 . . ?
C19 C24 H24A 119.4 . . ?
C26 C25 C30 117.1(4) . . ?
C26 C25 Si2 121.8(3) . . ?
C30 C25 Si2 120.5(3) . . ?
C27 C26 C25 122.2(4) . . ?
C27 C26 H26A 118.9 . . ?
C25 C26 H26A 118.9 . . ?
C28 C27 C26 119.1(4) . . ?
C28 C27 H27A 120.4 . . ?
C26 C27 H27A 120.4 . . ?
C29 C28 C27 120.1(4) . . ?
C29 C28 H28A 119.9 . . ?
C27 C28 H28A 119.9 . . ?
C28 C29 C30 120.8(5) . . ?
C28 C29 H29A 119.6 . . ?
C30 C29 H29A 119.6 . . ?
C29 C30 C25 120.6(4) . . ?
C29 C30 H30A 119.7 . . ?
C25 C30 H30A 119.7 . . ?
C36 C31 C32 116.9(4) . . ?
C36 C31 Si2 120.4(3) . . ?
C32 C31 Si2 122.6(4) . . ?
C33 C32 C31 121.0(5) . . ?
C33 C32 H32A 119.5 . . ?
C31 C32 H32A 119.5 . . ?
C34 C33 C32 120.5(5) . . ?
C34 C33 H33A 119.8 . . ?
C32 C33 H33A 119.8 . . ?
C33 C34 C35 120.4(5) . . ?
C33 C34 H34A 119.8 . . ?
C35 C34 H34A 119.8 . . ?
C34 C35 C36 118.9(5) . . ?
C34 C35 H35A 120.5 . . ?
C36 C35 H35A 120.5 . . ?
C31 C36 C35 122.2(5) . . ?
C31 C36 H36A 118.9 . . ?
C35 C36 H36A 118.9 . . ?
C38 C37 C42 117.2(4) . . ?
C38 C37 Si3 119.2(3) . . ?
C42 C37 Si3 123.6(3) . . ?
C39 C38 C37 121.3(5) . . ?
C39 C38 H38A 119.4 . . ?
C37 C38 H38A 119.4 . . ?
C40 C39 C38 120.3(5) . . ?
C40 C39 H39A 119.8 . . ?
C38 C39 H39A 119.8 . . ?
C39 C40 C41 119.9(5) . . ?
C39 C40 H40A 120.1 . . ?
C41 C40 H40A 120.1 . . ?
C40 C41 C42 120.1(5) . . ?
C40 C41 H41A 120.0 . . ?
C42 C41 H41A 120.0 . . ?
C41 C42 C37 121.2(4) . . ?
C41 C42 H42A 119.4 . . ?
C37 C42 H42A 119.4 . . ?
C44 C43 C48 116.8(4) . . ?
C44 C43 Si3 121.6(3) . . ?
C48 C43 Si3 121.5(3) . . ?
C45 C44 C43 121.9(4) . . ?
C45 C44 H44A 119.1 . . ?
C43 C44 H44A 119.1 . . ?
C46 C45 C44 120.3(5) . . ?
C46 C45 H45A 119.8 . . ?
C44 C45 H45A 119.8 . . ?
C45 C46 C47 119.8(4) . . ?
C45 C46 H46A 120.1 . . ?
C47 C46 H46A 120.1 . . ?
C48 C47 C46 119.7(5) . . ?
C48 C47 H47A 120.2 . . ?
C46 C47 H47A 120.2 . . ?
C47 C48 C43 121.5(5) . . ?
C47 C48 H48A 119.3 . . ?
C43 C48 H48A 119.3 . . ?
C54 C49 C50 116.9(4) . . ?
C54 C49 Si3 120.1(3) . . ?
C50 C49 Si3 123.0(3) . . ?
C51 C50 C49 121.6(4) . . ?
C51 C50 H50A 119.2 . . ?
C49 C50 H50A 119.2 . . ?
C50 C51 C52 120.1(4) . . ?
C50 C51 H51A 120.0 . . ?
C52 C51 H51A 120.0 . . ?
C53 C52 C51 119.6(4) . . ?
C53 C52 H52A 120.2 . . ?
C51 C52 H52A 120.2 . . ?
C52 C53 C54 120.0(4) . . ?
C52 C53 H53A 120.0 . . ?
C54 C53 H53A 120.0 . . ?
C49 C54 C53 121.8(4) . . ?
C49 C54 H54A 119.1 . . ?
C53 C54 H54A 119.1 . . ?
N1 C55 C56 123.7(4) . . ?
N1 C55 H55A 118.1 . . ?
C56 C55 H55A 118.1 . . ?
C57 C56 C55 117.4(5) . . ?
C57 C56 H56A 121.3 . . ?
C55 C56 H56A 121.3 . . ?
C56 C57 C58 120.3(5) . . ?
C56 C57 H57A 119.8 . . ?
C58 C57 H57A 119.8 . . ?
C57 C58 C59 118.6(4) . . ?
C57 C58 H58A 120.7 . . ?
C59 C58 H58A 120.7 . . ?
N1 C59 C58 121.6(4) . . ?
N1 C59 C60 116.1(4) . . ?
C58 C59 C60 122.3(4) . . ?
N2 C60 C61 120.6(4) . . ?
N2 C60 C59 115.9(3) . . ?
C61 C60 C59 123.5(4) . . ?
C62 C61 C60 119.8(4) . . ?
C62 C61 H61A 120.1 . . ?
C60 C61 H61A 120.1 . . ?
C63 C62 C61 119.3(4) . . ?
C63 C62 H62A 120.3 . . ?
C61 C62 H62A 120.3 . . ?
C62 C63 C64 118.2(4) . . ?
C62 C63 H63A 120.9 . . ?
C64 C63 H63A 120.9 . . ?
N2 C64 C63 123.3(5) . . ?
N2 C64 H64A 118.3 . . ?
C63 C64 H64A 118.3 . . ?
C68 O4 C65 106.7(7) . . ?
C68 O4 Dy1 130.3(5) . . ?
C65 O4 Dy1 120.0(6) . . ?
O4 C65 C66 110.5(7) . . ?
O4 C65 H65A 109.6 . . ?
C66 C65 H65A 109.6 . . ?
O4 C65 H65B 109.6 . . ?
C66 C65 H65B 109.6 . . ?
H65A C65 H65B 108.1 . . ?
C65 C66 C67 96.2(7) . . ?
C65 C66 H66A 112.5 . . ?
C67 C66 H66A 112.5 . . ?
C65 C66 H66B 112.5 . . ?
C67 C66 H66B 112.5 . . ?
H66A C66 H66B 110.0 . . ?
C66 C67 C68 103.8(7) . . ?
C66 C67 H67A 111.0 . . ?
C68 C67 H67A 111.0 . . ?
C66 C67 H67B 111.0 . . ?
C68 C67 H67B 111.0 . . ?
H67A C67 H67B 109.0 . . ?
O4 C68 C67 101.0(6) . . ?
O4 C68 H68A 111.6 . . ?
C67 C68 H68A 111.6 . . ?
O4 C68 H68B 111.6 . . ?
C67 C68 H68B 111.6 . . ?
H68A C68 H68B 109.4 . . ?
C68* O4* C65* 110.9(19) . . ?
C68* O4* Dy1 124.1(14) . . ?
C65* O4* Dy1 124.4(14) . . ?
O4* C65* C66* 104.9(16) . . ?
O4* C65* H65C 110.8 . . ?
C66* C65* H65C 110.8 . . ?
O4* C65* H65D 110.8 . . ?
C66* C65* H65D 110.8 . . ?
H65C C65* H65D 108.8 . . ?
C65* C66* C67* 107.9(14) . . ?
C65* C66* H66C 110.1 . . ?
C67* C66* H66C 110.1 . . ?
C65* C66* H66D 110.1 . . ?
C67* C66* H66D 110.1 . . ?
H66C C66* H66D 108.4 . . ?
C68* C67* C66* 106.3(15) . . ?
C68* C67* H67C 110.5 . . ?
C66* C67* H67C 110.5 . . ?
C68* C67* H67D 110.5 . . ?
C66* C67* H67D 110.5 . . ?
H67C C67* H67D 108.7 . . ?
O4* C68* C67* 105.6(17) . . ?
O4* C68* H68C 110.6 . . ?
C67* C68* H68C 110.6 . . ?
O4* C68* H68D 110.6 . . ?
C67* C68* H68D 110.6 . . ?
H68C C68* H68D 108.8 . . ?
C4S O1S C1S 108.6(4) . . ?
O1S C1S C2S 106.3(4) . . ?
O1S C1S H1SA 110.5 . . ?
C2S C1S H1SA 110.5 . . ?
O1S C1S H1SB 110.5 . . ?
C2S C1S H1SB 110.5 . . ?
H1SA C1S H1SB 108.7 . . ?
C3S C2S C1S 102.8(4) . . ?
C3S C2S H2SA 111.2 . . ?
C1S C2S H2SA 111.2 . . ?
C3S C2S H2SB 111.2 . . ?
C1S C2S H2SB 111.2 . . ?
H2SA C2S H2SB 109.1 . . ?
C4S C3S C2S 103.4(4) . . ?
C4S C3S H3SA 111.1 . . ?
C2S C3S H3SA 111.1 . . ?
C4S C3S H3SB 111.1 . . ?
C2S C3S H3SB 111.1 . . ?
H3SA C3S H3SB 109.0 . . ?
O1S C4S C3S 107.4(5) . . ?
O1S C4S H4SA 110.2 . . ?
C3S C4S H4SA 110.2 . . ?
O1S C4S H4SB 110.2 . . ?
C3S C4S H4SB 110.2 . . ?
H4SA C4S H4SB 108.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O1 2.123(2) . ?
Dy1 O2 2.135(3) . ?
Dy1 O3 2.135(2) . ?
Dy1 O4 2.402(8) . ?
Dy1 O4* 2.48(2) . ?
Dy1 N1 2.518(3) . ?
Dy1 N2 2.543(3) . ?
Si1 O1 1.589(3) . ?
Si1 C13 1.875(4) . ?
Si1 C7 1.874(4) . ?
Si1 C1 1.888(4) . ?
Si2 O2 1.591(3) . ?
Si2 C25 1.874(4) . ?
Si2 C31 1.875(4) . ?
Si2 C19 1.886(5) . ?
Si3 O3 1.594(3) . ?
Si3 C43 1.877(4) . ?
Si3 C49 1.885(4) . ?
Si3 C37 1.889(4) . ?
N1 C59 1.338(5) . ?
N1 C55 1.344(5) . ?
N2 C64 1.333(5) . ?
N2 C60 1.360(5) . ?
C1 C6 1.399(5) . ?
C1 C2 1.402(5) . ?
C2 C3 1.387(5) . ?
C2 H2A 0.9500 . ?
C3 C4 1.379(5) . ?
C3 H3A 0.9500 . ?
C4 C5 1.385(6) . ?
C4 H4A 0.9500 . ?
C5 C6 1.388(6) . ?
C5 H5A 0.9500 . ?
C6 H6A 0.9500 . ?
C7 C12 1.385(5) . ?
C7 C8 1.405(7) . ?
C8 C9 1.386(6) . ?
C8 H8A 0.9500 . ?
C9 C10 1.372(7) . ?
C9 H9A 0.9500 . ?
C10 C11 1.392(8) . ?
C10 H10A 0.9500 . ?
C11 C12 1.388(6) . ?
C11 H11A 0.9500 . ?
C12 H12A 0.9500 . ?
C13 C14 1.393(6) . ?
C13 C18 1.392(5) . ?
C14 C15 1.386(6) . ?
C14 H14A 0.9500 . ?
C15 C16 1.380(6) . ?
C15 H15A 0.9500 . ?
C16 C17 1.376(6) . ?
C16 H16A 0.9500 . ?
C17 C18 1.382(6) . ?
C17 H17A 0.9500 . ?
C18 H18A 0.9500 . ?
C19 C20 1.390(6) . ?
C19 C24 1.409(6) . ?
C20 C21 1.395(6) . ?
C20 H20A 0.9500 . ?
C21 C22 1.375(7) . ?
C21 H21A 0.9500 . ?
C22 C23 1.385(7) . ?
C22 H22A 0.9500 . ?
C23 C24 1.394(6) . ?
C23 H23A 0.9500 . ?
C24 H24A 0.9500 . ?
C25 C26 1.390(6) . ?
C25 C30 1.402(6) . ?
C26 C27 1.385(6) . ?
C26 H26A 0.9500 . ?
C27 C28 1.379(7) . ?
C27 H27A 0.9500 . ?
C28 C29 1.367(7) . ?
C28 H28A 0.9500 . ?
C29 C30 1.384(6) . ?
C29 H29A 0.9500 . ?
C30 H30A 0.9500 . ?
C31 C36 1.386(6) . ?
C31 C32 1.393(6) . ?
C32 C33 1.389(7) . ?
C32 H32A 0.9500 . ?
C33 C34 1.363(8) . ?
C33 H33A 0.9500 . ?
C34 C35 1.373(8) . ?
C34 H34A 0.9500 . ?
C35 C36 1.396(7) . ?
C35 H35A 0.9500 . ?
C36 H36A 0.9500 . ?
C37 C38 1.391(6) . ?
C37 C42 1.398(6) . ?
C38 C39 1.392(7) . ?
C38 H38A 0.9500 . ?
C39 C40 1.368(7) . ?
C39 H39A 0.9500 . ?
C40 C41 1.373(7) . ?
C40 H40A 0.9500 . ?
C41 C42 1.395(7) . ?
C41 H41A 0.9500 . ?
C42 H42A 0.9500 . ?
C43 C44 1.393(6) . ?
C43 C48 1.395(6) . ?
C44 C45 1.379(6) . ?
C44 H44A 0.9500 . ?
C45 C46 1.363(7) . ?
C45 H45A 0.9500 . ?
C46 C47 1.388(7) . ?
C46 H46A 0.9500 . ?
C47 C48 1.388(7) . ?
C47 H47A 0.9500 . ?
C48 H48A 0.9500 . ?
C49 C54 1.388(5) . ?
C49 C50 1.389(6) . ?
C50 C51 1.384(6) . ?
C50 H50A 0.9500 . ?
C51 C52 1.383(8) . ?
C51 H51A 0.9500 . ?
C52 C53 1.362(6) . ?
C52 H52A 0.9500 . ?
C53 C54 1.393(6) . ?
C53 H53A 0.9500 . ?
C54 H54A 0.9500 . ?
C55 C56 1.380(6) . ?
C55 H55A 0.9500 . ?
C56 C57 1.371(7) . ?
C56 H56A 0.9500 . ?
C57 C58 1.383(7) . ?
C57 H57A 0.9500 . ?
C58 C59 1.394(6) . ?
C58 H58A 0.9500 . ?
C59 C60 1.479(6) . ?
C60 C61 1.389(6) . ?
C61 C62 1.380(6) . ?
C61 H61A 0.9500 . ?
C62 C63 1.378(7) . ?
C62 H62A 0.9500 . ?
C63 C64 1.382(6) . ?
C63 H63A 0.9500 . ?
C64 H64A 0.9500 . ?
O4 C68 1.430(6) . ?
O4 C65 1.432(6) . ?
C65 C66 1.436(7) . ?
C65 H65A 0.9900 . ?
C65 H65B 0.9900 . ?
C66 C67 1.497(7) . ?
C66 H66A 0.9900 . ?
C66 H66B 0.9900 . ?
C67 C68 1.496(6) . ?
C67 H67A 0.9900 . ?
C67 H67B 0.9900 . ?
C68 H68A 0.9900 . ?
C68 H68B 0.9900 . ?
O4* C68* 1.425(8) . ?
O4* C65* 1.429(8) . ?
C65* C66* 1.470(8) . ?
C65* H65C 0.9900 . ?
C65* H65D 0.9900 . ?
C66* C67* 1.482(8) . ?
C66* H66C 0.9900 . ?
C66* H66D 0.9900 . ?
C67* C68* 1.482(8) . ?
C67* H67C 0.9900 . ?
C67* H67D 0.9900 . ?
C68* H68C 0.9900 . ?
C68* H68D 0.9900 . ?
O1S C4S 1.426(5) . ?
O1S C1S 1.433(5) . ?
C1S C2S 1.497(5) . ?
C1S H1SA 0.9900 . ?
C1S H1SB 0.9900 . ?
C2S C3S 1.490(6) . ?
C2S H2SA 0.9900 . ?
C2S H2SB 0.9900 . ?
C3S C4S 1.485(6) . ?
C3S H3SA 0.9900 . ?
C3S H3SB 0.9900 . ?
C4S H4SA 0.9900 . ?
C4S H4SB 0.9900 . ?
