#------------------------------------------------------------------------------
#$Date: 2020-05-05 15:28:21 +0200 (mar 05 de may de 2020) $
#$Revision: 251656 $
#$URL: svn://www.crystallography.net/cod/cif/7/70/37/7703773.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7703773
loop_
_publ_author_name
'Acharya, Joydev'
'Sarkar, Arup'
'Kumar, Pawan'
'Kumar, Vierandra'
'Flores Gonzalez, Jessica'
'Cador, Olivier'
'Pointillart, Fabrice'
'Rajaraman, Gopalan'
'Chandrasekhar, Vadapalli'
_publ_section_title
;
 Influence of ligand field on magnetic anisotropy in a family of
 pentacoordinate CoII complexes.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4785
_journal_page_last               4796
_journal_paper_doi               10.1039/d0dt00315h
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C24 H25 Co N5 S2'
_chemical_formula_sum            'C24 H25 Co N5 S2'
_chemical_formula_weight         506.54
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2019-03-22
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-08-29 deposited with the CCDC.	2020-03-18 downloaded from the CCDC.
;
_cell_angle_alpha                101.4480(10)
_cell_angle_beta                 91.1720(10)
_cell_angle_gamma                102.3220(10)
_cell_formula_units_Z            2
_cell_length_a                   8.47120(10)
_cell_length_b                   9.4205(2)
_cell_length_c                   15.8080(2)
_cell_measurement_reflns_used    10508
_cell_measurement_temperature    119.97(10)
_cell_measurement_theta_max      28.5940
_cell_measurement_theta_min      2.8460
_cell_volume                     1205.34(3)
_computing_cell_refinement       'CrysAlisPro 1.171.39.29d (Rigaku OD, 2017)'
_computing_data_collection       'CrysAlisPro 1.171.39.29d (Rigaku OD, 2017)'
_computing_data_reduction        'CrysAlisPro 1.171.39.29d (Rigaku OD, 2017)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      119.97(10)
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.877
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω      0.00  27.00   0.50    1.71    --   10.50 -24.00  28.00   54
  2  ω     35.00  61.00   0.50    1.71    --  -10.90  24.00-166.00   52
  3  ω    -12.00  24.00   0.50    1.71    --  -10.90 -24.00  28.00   72
  4  ω    -76.00 -51.00   0.50    1.71    --  -10.90 -24.00  28.00   50
  5  ω     50.00  99.00   0.50    1.71    --   10.50  77.00  60.00   98
  6  ω    -14.00  11.00   0.50    1.71    --   10.50  24.00-166.00   50
  7  ω    -19.00  97.00   0.50    1.71    --   10.50  57.00  60.00  232
  8  ω     51.00  99.00   0.50    1.71    --   10.50  77.00 120.00   96
  9  ω     50.00  96.00   0.50    1.71    --   10.50  77.00   0.00   92
 10  ω     52.00  83.00   0.50    1.71    --   10.50  77.00-150.00   62
 11  ω    -50.00   7.00   0.50    1.71    --  -10.90 -82.00   0.00  114
 12  ω    -27.00   5.00   0.50    1.71    --  -10.90 -82.00-120.00   64
 13  ω    -53.00  29.00   0.50    1.71    --  -10.90 -77.00 120.00  164
 14  ω    -50.00 -25.00   0.50    1.71    --  -10.90 -82.00-150.00   50
 15  ω    -59.00   6.00   0.50    1.71    --  -10.90 -82.00 -90.00  130
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0831137000
_diffrn_orient_matrix_UB_12      0.0009761000
_diffrn_orient_matrix_UB_13      -0.0051311000
_diffrn_orient_matrix_UB_21      0.0193552000
_diffrn_orient_matrix_UB_22      0.0785110000
_diffrn_orient_matrix_UB_23      0.0132445000
_diffrn_orient_matrix_UB_31      0.0097258000
_diffrn_orient_matrix_UB_32      0.0065131000
_diffrn_orient_matrix_UB_33      -0.0436254000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0398
_diffrn_reflns_av_unetI/netI     0.0366
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.877
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            20127
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.877
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.869
_diffrn_reflns_theta_min         2.719
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.907
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.75334
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.29d (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            blue
_exptl_crystal_colour_primary    blue
_exptl_crystal_density_diffrn    1.396
_exptl_crystal_description       block
_exptl_crystal_F_000             526
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.308
_exptl_crystal_size_min          0.179
_refine_diff_density_max         0.465
_refine_diff_density_min         -0.441
_refine_diff_density_rms         0.059
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     303
_refine_ls_number_reflns         5549
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.072
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0329
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0374P)²+0.4738P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0826
_refine_ls_wR_factor_ref         0.0857
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4887
_reflns_number_total             5549
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt00315h2.cif
_cod_data_source_block           CoNCS
_cod_depositor_comments
'Adding full bibliography for 7703772--7703776.cif.'
_cod_database_code               7703773
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         C12H14N2O2Co2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.70
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C00G(H00A,H00B), C00O(H00H,H00M), C00P(H00N,H00O)
2.b Aromatic/amide H refined with riding coordinates:
 C00C(H00C), C00F(H00F), C00I(H00I), C00J(H00J), C00K(H00K), C00L(H00L),
 C00S(H00S), C00T(H00T), C00U(H00U), C00V(H00V)
2.c Idealised Me refined as rotating group:
 C00N(H00D,H00E,H00G), C00R(H00P,H00Q,H00R)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.566
_oxdiff_exptl_absorpt_empirical_full_min 0.649
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.40295(3) 0.62418(2) 0.32639(2) 0.01818(8) Uani 1 1 d . . . . .
S002 S 0.84994(6) 0.65465(6) 0.50769(3) 0.03111(12) Uani 1 1 d . . . . .
S003 S 0.63468(7) 0.98259(6) 0.16358(4) 0.04114(14) Uani 1 1 d . . . . .
N3 N 0.33193(17) 0.74593(15) 0.43644(9) 0.0207(3) Uani 1 1 d . . . . .
N1 N 0.27335(16) 0.41093(15) 0.28795(9) 0.0179(3) Uani 1 1 d . . . . .
N2 N 0.15376(16) 0.65336(14) 0.28165(9) 0.0174(3) Uani 1 1 d . . . . .
N4 N 0.49738(18) 0.77019(17) 0.25620(10) 0.0248(3) Uani 1 1 d . . . . .
N5 N 0.60651(19) 0.58314(18) 0.37671(10) 0.0286(3) Uani 1 1 d . . . . .
C009 C 0.2284(2) 0.83007(18) 0.42324(11) 0.0213(3) Uani 1 1 d . . . . .
C00A C 0.1110(2) 0.39041(18) 0.28566(10) 0.0182(3) Uani 1 1 d . . . . .
C00B C 0.03930(19) 0.50910(18) 0.12993(10) 0.0185(3) Uani 1 1 d . . . . .
C00C C 0.3395(2) 0.29191(19) 0.26727(11) 0.0228(4) Uani 1 1 d . . . . .
H00C H 0.451728 0.306350 0.269502 0.027 Uiso 1 1 calc R . . . .
C00D C 0.1352(2) 0.42096(19) 0.08280(10) 0.0202(3) Uani 1 1 d . . . . .
C00E C -0.1308(2) 0.4611(2) 0.12012(11) 0.0216(4) Uani 1 1 d . . . . .
C00F C 0.0110(2) 0.24990(19) 0.26335(11) 0.0225(4) Uani 1 1 d . . . . .
H00F H -0.100913 0.237493 0.263250 0.027 Uiso 1 1 calc R . . . .
C00G C 0.04898(19) 0.52946(18) 0.31271(11) 0.0184(3) Uani 1 1 d . . . . .
H00A H -0.061189 0.513597 0.288696 0.022 Uiso 1 1 calc R . . . .
H00B H 0.048446 0.554187 0.375248 0.022 Uiso 1 1 calc R . . . .
C00H C 0.7067(2) 0.61214(19) 0.43030(12) 0.0243(4) Uani 1 1 d . . . . .
C00I C 0.0611(2) 0.2846(2) 0.03089(11) 0.0242(4) Uani 1 1 d . . . . .
H00I H 0.125423 0.226557 0.000047 0.029 Uiso 1 1 calc R . . . .
C00J C 0.2026(2) 0.9450(2) 0.48771(13) 0.0289(4) Uani 1 1 d . . . . .
H00J H 0.133722 1.004717 0.476448 0.035 Uiso 1 1 calc R . . . .
C00K C -0.1993(2) 0.3225(2) 0.06885(11) 0.0243(4) Uani 1 1 d . . . . .
H00K H -0.311332 0.289233 0.064702 0.029 Uiso 1 1 calc R . . . .
C00L C 0.4048(2) 0.7682(2) 0.51624(12) 0.0261(4) Uani 1 1 d . . . . .
H00L H 0.473852 0.707805 0.526122 0.031 Uiso 1 1 calc R . . . .
C00M C 0.5548(2) 0.85737(19) 0.21724(11) 0.0223(4) Uani 1 1 d . . . . .
C00N C 0.3169(2) 0.4712(2) 0.08456(12) 0.0268(4) Uani 1 1 d . . . . .
H00D H 0.344064 0.554158 0.056725 0.040 Uiso 1 1 calc GR . . . .
H00E H 0.361342 0.391109 0.054611 0.040 Uiso 1 1 calc GR . . . .
H00G H 0.360859 0.500203 0.143450 0.040 Uiso 1 1 calc GR . . . .
C00O C 0.1460(2) 0.79925(18) 0.33427(12) 0.0232(4) Uani 1 1 d . . . . .
H00H H 0.033365 0.804130 0.339662 0.028 Uiso 1 1 calc R . . . .
H00M H 0.196135 0.876183 0.304412 0.028 Uiso 1 1 calc R . . . .
C00P C 0.1151(2) 0.65639(18) 0.18791(11) 0.0208(3) Uani 1 1 d . . . . .
H00N H 0.042646 0.723056 0.186683 0.025 Uiso 1 1 calc R . . . .
H00O H 0.214710 0.698100 0.163881 0.025 Uiso 1 1 calc R . . . .
C00Q C -0.1059(2) 0.2321(2) 0.02365(11) 0.0249(4) Uani 1 1 d . . . . .
C00R C -0.2428(2) 0.5574(2) 0.15948(13) 0.0292(4) Uani 1 1 d . . . . .
H00P H -0.212625 0.593588 0.220060 0.044 Uiso 1 1 calc GR . . . .
H00Q H -0.352194 0.500075 0.152038 0.044 Uiso 1 1 calc GR . . . .
H00R H -0.234698 0.639939 0.131387 0.044 Uiso 1 1 calc GR . . . .
C00S C 0.2799(2) 0.9695(2) 0.56825(13) 0.0339(5) Uani 1 1 d . . . . .
H00S H 0.265105 1.046811 0.611902 0.041 Uiso 1 1 calc R . . . .
C00T C 0.2472(2) 0.1496(2) 0.24291(12) 0.0280(4) Uani 1 1 d . . . . .
H00T H 0.295960 0.069277 0.227888 0.034 Uiso 1 1 calc R . . . .
C00U C 0.3802(2) 0.8775(2) 0.58355(12) 0.0323(4) Uani 1 1 d . . . . .
H00U H 0.430055 0.889244 0.638235 0.039 Uiso 1 1 calc R . . . .
C00V C 0.0800(2) 0.12840(19) 0.24125(12) 0.0277(4) Uani 1 1 d . . . . .
H00V H 0.014880 0.033247 0.225394 0.033 Uiso 1 1 calc R . . . .
C00W C -0.1838(3) 0.0837(2) -0.03241(14) 0.0375(5) Uani 1 1 d . . . . .
H00W H -0.223(3) 0.016(3) 0.0030(17) 0.053(7) Uiso 1 1 d . . . . .
H00X H -0.102(3) 0.041(3) -0.0690(18) 0.058(8) Uiso 1 1 d . . . . .
H00Y H -0.268(4) 0.093(3) -0.069(2) 0.070(9) Uiso 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
10 -3 -11 0.1902
3 -5 21 0.0903
-10 2 13 0.1275
-5 6 -20 0.0664
0 -3 -20 0.0920
-3 -11 14 0.1579
0 4 19 0.1181
2 12 -4 0.0791
1 -13 0 0.1804
9 -7 -11 0.1815
-1 -3 22 0.0885
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Co1 N2 77.34(5) . . ?
N1 Co1 N3 115.76(5) . . ?
N1 Co1 N2 76.90(5) . . ?
N4 Co1 N3 105.86(6) . . ?
N4 Co1 N1 129.89(6) . . ?
N4 Co1 N2 86.69(5) . . ?
N4 Co1 N5 100.77(6) . . ?
N5 Co1 N3 99.20(6) . . ?
N5 Co1 N1 98.93(6) . . ?
N5 Co1 N2 172.44(6) . . ?
C009 N3 Co1 115.57(11) . . ?
C009 N3 C00L 118.64(15) . . ?
C00L N3 Co1 124.44(12) . . ?
C00A N1 Co1 116.62(11) . . ?
C00C N1 Co1 124.36(12) . . ?
C00C N1 C00A 119.00(14) . . ?
C00G N2 Co1 99.28(9) . . ?
C00G N2 C00P 114.05(13) . . ?
C00O N2 Co1 102.49(10) . . ?
C00O N2 C00G 112.04(13) . . ?
C00O N2 C00P 107.49(12) . . ?
C00P N2 Co1 120.91(10) . . ?
C00M N4 Co1 178.21(15) . . ?
C00H N5 Co1 149.24(15) . . ?
N3 C009 C00J 121.69(17) . . ?
N3 C009 C00O 117.17(14) . . ?
C00J C009 C00O 121.09(16) . . ?
N1 C00A C00F 121.58(15) . . ?
N1 C00A C00G 114.98(14) . . ?
C00F C00A C00G 123.38(15) . . ?
C00D C00B C00E 119.27(16) . . ?
C00D C00B C00P 120.98(15) . . ?
C00E C00B C00P 119.71(15) . . ?
N1 C00C C00T 122.39(17) . . ?
C00B C00D C00N 122.09(16) . . ?
C00I C00D C00B 119.39(16) . . ?
C00I C00D C00N 118.49(15) . . ?
C00B C00E C00R 122.56(16) . . ?
C00K C00E C00B 119.19(15) . . ?
C00K C00E C00R 118.18(16) . . ?
C00V C00F C00A 119.00(17) . . ?
N2 C00G C00A 109.74(13) . . ?
N5 C00H S002 179.58(18) . . ?
C00Q C00I C00D 122.11(16) . . ?
C00S C00J C009 119.38(18) . . ?
C00Q C00K C00E 122.14(16) . . ?
N3 C00L C00U 122.27(18) . . ?
N4 C00M S003 178.95(17) . . ?
N2 C00O C009 113.43(14) . . ?
C00B C00P N2 116.13(13) . . ?
C00I C00Q C00W 121.33(18) . . ?
C00K C00Q C00I 117.76(16) . . ?
C00K C00Q C00W 120.90(18) . . ?
C00J C00S C00U 119.07(17) . . ?
C00C C00T C00V 118.57(16) . . ?
C00L C00U C00S 118.80(18) . . ?
C00F C00V C00T 119.43(16) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 N3 2.0614(14) . ?
Co1 N1 2.0389(14) . ?
Co1 N2 2.3012(14) . ?
Co1 N4 1.9838(16) . ?
Co1 N5 2.0264(16) . ?
S002 C00H 1.633(2) . ?
S003 C00M 1.6276(19) . ?
N3 C009 1.340(2) . ?
N3 C00L 1.350(2) . ?
N1 C00A 1.346(2) . ?
N1 C00C 1.345(2) . ?
N2 C00G 1.481(2) . ?
N2 C00O 1.474(2) . ?
N2 C00P 1.518(2) . ?
N4 C00M 1.154(2) . ?
N5 C00H 1.137(2) . ?
C009 C00J 1.389(2) . ?
C009 C00O 1.503(2) . ?
C00A C00F 1.385(2) . ?
C00A C00G 1.502(2) . ?
C00B C00D 1.404(2) . ?
C00B C00E 1.411(2) . ?
C00B C00P 1.506(2) . ?
C00C C00T 1.376(3) . ?
C00D C00I 1.391(3) . ?
C00D C00N 1.508(2) . ?
C00E C00K 1.391(3) . ?
C00E C00R 1.510(2) . ?
C00F C00V 1.382(3) . ?
C00I C00Q 1.390(3) . ?
C00J C00S 1.374(3) . ?
C00K C00Q 1.389(3) . ?
C00L C00U 1.379(3) . ?
C00Q C00W 1.505(3) . ?
C00S C00U 1.386(3) . ?
C00T C00V 1.387(3) . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
10.4050 -2.5650 -11.0616 -0.8105 -0.1465 0.5671
3.3539 -5.2715 20.9896 -0.3916 -0.0710 -0.9174
-9.6653 1.8327 13.3135 0.7368 0.1331 -0.6629
-5.1351 5.7930 -19.5517 0.5328 0.0965 0.8407
0.1238 -3.0117 -20.1526 0.0902 -0.5010 0.8608
-2.5262 -10.7962 13.5082 0.1301 -0.7176 -0.6842
0.1887 4.4171 18.8657 -0.1082 0.6003 -0.7924
2.4624 12.1117 -4.4279 -0.1701 0.9399 0.2960
1.0065 -13.0119 -0.0010 -0.0963 -1.0021 -0.0749
9.0097 -7.0039 -11.0063 -0.6992 -0.5213 0.5222
-0.9888 -3.0072 22.0138 -0.0337 0.0363 -0.9896
