#------------------------------------------------------------------------------
#$Date: 2020-07-06 05:15:49 +0200 (lun 06 de jul de 2020) $
#$Revision: 253924 $
#$URL: svn://www.crystallography.net/cod/cif/7/70/42/7704249.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7704249
loop_
_publ_author_name
'Mikhalyova, Elena A.'
'Zeller, Matthias'
'Jasinski, Jerry P.'
'Butcher, Raymond J.'
'Carrella, Luca M.'
'Sedykh, Alexander E.'
'Gavrilenko, Konstantin S.'
'Smola, Sergey S.'
'Frasso, Michael'
'Cazorla, Sebastian Calderon'
'Perera, Kuluni'
'Shi, Anni'
'Ranjbar, Habib G.'
'Smith, Casey'
'Deac, Alexandru'
'Liu, Youlin'
'McGee, Sean M.'
'Dotsenko, Vladimir P.'
'Kumke, Michael U.'
'Müller-Buschbaum, Klaus'
'Rentschler, Eva'
'Addison, Anthony W.'
'Pavlishchuk, Vitaly V.'
_publ_section_title
;
 Combination of single-molecule magnet behaviour and luminescence
 properties in a new series of lanthanide complexes with
 tris(pyrazolyl)borate and oligo(β-diketonate) ligands.
;
_journal_issue                   23
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7774
_journal_page_last               7789
_journal_paper_doi               10.1039/d0dt00600a
_journal_volume                  49
_journal_year                    2020
_chemical_formula_moiety         'C29 H31 B2 Eu N12 O2, C6 H14'
_chemical_formula_sum            'C35 H45 B2 Eu N12 O2'
_chemical_formula_weight         839.41
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2020-01-23 deposited with the CCDC.	2020-04-30 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 112.1960(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.9362(5)
_cell_length_b                   22.9093(7)
_cell_length_c                   11.4830(4)
_cell_measurement_reflns_used    9958
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      33.1568
_cell_measurement_theta_min      2.6147
_cell_volume                     3881.6(2)
_computing_cell_refinement       'SAINT V8.34A (Bruker, 2014)'
_computing_data_collection       'Apex2 v2014.1-1 (Bruker, 2014)'
_computing_data_reduction        'SAINT V8.34A (Bruker, 2014)'
_computing_structure_refinement
;  
SHELXL-2014/7 (Sheldrick, 2014), 
SHELXLE Rev656 (Hübschle et al., 2011)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker AXS D8 Quest CMOS diffractometer'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  'laterally graded multilayer (Goebel) mirror'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0895
_diffrn_reflns_av_unetI/netI     0.0661
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            24712
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.281
_diffrn_reflns_theta_min         2.614
_diffrn_source                   'I-mu-S microsource X-ray tube'
_exptl_absorpt_coefficient_mu    1.664
_exptl_absorpt_correction_T_max  0.7465
_exptl_absorpt_correction_T_min  0.3843
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Apex2 v2014.1-1 (Bruker, 2014)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.436
_exptl_crystal_description       plate
_exptl_crystal_F_000             1712
_exptl_crystal_size_max          0.350
_exptl_crystal_size_mid          0.210
_exptl_crystal_size_min          0.090
_refine_diff_density_max         1.890
_refine_diff_density_min         -2.414
_refine_diff_density_rms         0.149
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.154
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     239
_refine_ls_number_reflns         4829
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.154
_refine_ls_R_factor_all          0.0531
_refine_ls_R_factor_gt           0.0461
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0579P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1160
_refine_ls_wR_factor_ref         0.1208
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4099
_reflns_number_total             4829
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0dt00600a4.cif
_cod_data_source_block           quest15mz032_0m_sq
_cod_depositor_comments
'Adding full bibliography for 7704247--7704266.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7704249
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.594
_shelx_estimated_absorpt_t_max   0.865
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1463(3) 0.03159(17) 0.4415(4) 0.0282(9) Uani 1 1 d . . . . .
H1A H 0.1204 -0.0025 0.4673 0.042 Uiso 1 1 calc R U . . .
H1B H 0.1775 0.0562 0.5150 0.042 Uiso 1 1 calc R U . . .
H1C H 0.1896 0.0186 0.4049 0.042 Uiso 1 1 calc R U . . .
C19 C 0.3611(5) 0.0520(3) 0.3880(9) 0.090(3) Uani 1 1 d . . . . .
H19A H 0.3312 0.0900 0.3642 0.135 Uiso 1 1 calc R U . . .
H19B H 0.3698 0.0433 0.4754 0.135 Uiso 1 1 calc R U . . .
H19C H 0.3232 0.0217 0.3327 0.135 Uiso 1 1 calc R U . . .
C18 C 0.4527(5) 0.0537(4) 0.3753(10) 0.113(4) Uani 1 1 d . . . . .
H18A H 0.4863 0.0880 0.4224 0.136 Uiso 1 1 calc R U . . .
H18B H 0.4870 0.0185 0.4171 0.136 Uiso 1 1 calc R U . . .
C17 C 0.4527(5) 0.0562(3) 0.2505(10) 0.089(3) Uani 1 1 d . . . . .
H17A H 0.4207 0.0921 0.2085 0.107 Uiso 1 1 calc R U . . .
H17B H 0.4189 0.0223 0.2018 0.107 Uiso 1 1 calc R U . . .
C2 C 0.0711(2) 0.06630(16) 0.3445(4) 0.0201(7) Uani 1 1 d . . . . .
C3 C 0.0000 0.0369(2) 0.2500 0.0211(11) Uani 1 2 d S T P . .
C4 C 0.0000 -0.0285(2) 0.2500 0.0190(10) Uani 1 2 d S T P . .
C5 C -0.0406(3) -0.05983(17) 0.3178(4) 0.0295(9) Uani 1 1 d . . . . .
H5 H -0.0694 -0.0393 0.3644 0.035 Uiso 1 1 calc R U . . .
C6 C -0.0403(3) -0.12120(18) 0.3195(4) 0.0334(10) Uani 1 1 d . . . . .
H6 H -0.0674 -0.1421 0.3677 0.040 Uiso 1 1 calc R U . . .
C7 C 0.0000 -0.1501(2) 0.2500 0.0335(15) Uani 1 2 d S T P . .
H7 H 0.0000 -0.1915 0.2500 0.040 Uiso 1 2 calc R U P . .
C8 C 0.1544(2) 0.12926(16) 0.1385(4) 0.0221(8) Uani 1 1 d . . . . .
H8 H 0.1574 0.0965 0.1906 0.027 Uiso 1 1 calc R U . . .
C9 C 0.1998(3) 0.13323(17) 0.0570(4) 0.0263(9) Uani 1 1 d . . . . .
H9 H 0.2387 0.1051 0.0429 0.032 Uiso 1 1 calc R U . . .
C10 C 0.1759(3) 0.18723(18) 0.0008(4) 0.0229(8) Uani 1 1 d . . . . .
H10 H 0.1957 0.2035 -0.0606 0.028 Uiso 1 1 calc R U . . .
C11 C -0.1595(2) 0.23095(16) -0.0507(4) 0.0208(8) Uani 1 1 d . . . . .
H11 H -0.2047 0.2116 -0.0300 0.025 Uiso 1 1 calc R U . . .
C12 C -0.1756(3) 0.25940(17) -0.1646(4) 0.0251(8) Uani 1 1 d . . . . .
H12 H -0.2315 0.2634 -0.2342 0.030 Uiso 1 1 calc R U . . .
C13 C -0.0918(3) 0.28025(18) -0.1528(4) 0.0247(8) Uani 1 1 d . . . . .
H13 H -0.0791 0.3019 -0.2148 0.030 Uiso 1 1 calc R U . . .
C14 C 0.1203(3) 0.33849(16) 0.3222(4) 0.0225(8) Uani 1 1 d . . . . .
H14 H 0.1195 0.3388 0.4045 0.027 Uiso 1 1 calc R U . . .
C15 C 0.1519(3) 0.38396(17) 0.2694(4) 0.0285(9) Uani 1 1 d . . . . .
H15 H 0.1763 0.4202 0.3073 0.034 Uiso 1 1 calc R U . . .
C16 C 0.1404(3) 0.36522(17) 0.1511(4) 0.0260(9) Uani 1 1 d . . . . .
H16 H 0.1558 0.3866 0.0911 0.031 Uiso 1 1 calc R U . . .
B1 B 0.0740(3) 0.27303(18) 0.0147(4) 0.0192(8) Uani 1 1 d . . . . .
H1 H 0.0929 0.2924 -0.0497 0.023 Uiso 1 1 calc R U . . .
N1 N 0.1062(2) 0.17695(14) 0.1349(3) 0.0191(6) Uani 1 1 d . . . . .
N2 N 0.1199(2) 0.21281(14) 0.0480(3) 0.0182(6) Uani 1 1 d . . . . .
N3 N -0.0728(2) 0.23448(13) 0.0251(3) 0.0179(6) Uani 1 1 d . . . . .
N4 N -0.0309(2) 0.26503(13) -0.0393(3) 0.0198(7) Uani 1 1 d . . . . .
N5 N 0.0912(2) 0.29447(11) 0.2409(3) 0.0173(6) Uani 1 1 d . . . . .
N6 N 0.1033(2) 0.31090(14) 0.1339(3) 0.0194(7) Uani 1 1 d . . . . .
O1 O 0.07926(17) 0.12135(11) 0.3540(2) 0.0211(6) Uani 1 1 d . . . . .
Eu1 Eu 0.0000 0.20215(2) 0.2500 0.01716(11) Uani 1 2 d S T P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 H1A 109.5 . . ?
C2 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
C2 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C18 C19 117.3(8) . . ?
C17 C18 H18A 108.0 . . ?
C19 C18 H18A 108.0 . . ?
C17 C18 H18B 108.0 . . ?
C19 C18 H18B 108.0 . . ?
H18A C18 H18B 107.2 . . ?
C18 C17 C17 112.6(11) . 2_655 ?
C18 C17 H17A 109.1 . . ?
C17 C17 H17A 109.1 2_655 . ?
C18 C17 H17B 109.1 . . ?
C17 C17 H17B 109.1 2_655 . ?
H17A C17 H17B 107.8 . . ?
O1 C2 C3 124.6(3) . . ?
O1 C2 C1 115.6(3) . . ?
C3 C2 C1 119.9(3) . . ?
C2 C3 C2 123.0(4) . 2 ?
C2 C3 C4 118.5(2) . . ?
C2 C3 C4 118.5(2) 2 . ?
C5 C4 C5 117.7(5) . 2 ?
C5 C4 C3 121.2(2) . . ?
C5 C4 C3 121.2(2) 2 . ?
C4 C5 C6 121.7(4) . . ?
C4 C5 H5 119.1 . . ?
C6 C5 H5 119.1 . . ?
C7 C6 C5 118.3(4) . . ?
C7 C6 H6 120.8 . . ?
C5 C6 H6 120.8 . . ?
C6 C7 C6 122.3(5) . 2 ?
C6 C7 H7 118.9 . . ?
C6 C7 H7 118.9 2 . ?
N1 C8 C9 111.7(4) . . ?
N1 C8 H8 124.2 . . ?
C9 C8 H8 124.2 . . ?
C10 C9 C8 104.6(3) . . ?
C10 C9 H9 127.7 . . ?
C8 C9 H9 127.7 . . ?
N2 C10 C9 108.1(4) . . ?
N2 C10 H10 126.0 . . ?
C9 C10 H10 126.0 . . ?
N3 C11 C12 111.2(3) . . ?
N3 C11 H11 124.4 . . ?
C12 C11 H11 124.4 . . ?
C13 C12 C11 104.0(3) . . ?
C13 C12 H12 128.0 . . ?
C11 C12 H12 128.0 . . ?
N4 C13 C12 108.9(4) . . ?
N4 C13 H13 125.6 . . ?
C12 C13 H13 125.6 . . ?
N5 C14 C15 110.4(4) . . ?
N5 C14 H14 124.8 . . ?
C15 C14 H14 124.8 . . ?
C16 C15 C14 105.2(3) . . ?
C16 C15 H15 127.4 . . ?
C14 C15 H15 127.4 . . ?
N6 C16 C15 108.6(4) . . ?
N6 C16 H16 125.7 . . ?
C15 C16 H16 125.7 . . ?
N6 B1 N2 109.2(3) . . ?
N6 B1 N4 109.8(3) . . ?
N2 B1 N4 109.3(3) . . ?
N6 B1 H1 109.5 . . ?
N2 B1 H1 109.5 . . ?
N4 B1 H1 109.5 . . ?
C8 N1 N2 105.4(3) . . ?
C8 N1 Eu1 130.8(3) . . ?
N2 N1 Eu1 123.7(2) . . ?
C10 N2 N1 110.2(3) . . ?
C10 N2 B1 128.0(3) . . ?
N1 N2 B1 121.8(3) . . ?
C11 N3 N4 106.1(3) . . ?
C11 N3 Eu1 128.2(3) . . ?
N4 N3 Eu1 125.4(2) . . ?
C13 N4 N3 109.7(3) . . ?
C13 N4 B1 128.9(3) . . ?
N3 N4 B1 121.1(3) . . ?
C14 N5 N6 106.9(3) . . ?
C14 N5 Eu1 129.9(3) . . ?
N6 N5 Eu1 122.2(2) . . ?
C16 N6 N5 108.9(3) . . ?
C16 N6 B1 127.9(3) . . ?
N5 N6 B1 123.2(3) . . ?
C2 O1 Eu1 137.4(2) . . ?
O1 Eu1 O1 73.07(12) 2 . ?
O1 Eu1 N3 75.76(9) 2 . ?
O1 Eu1 N3 136.05(9) . . ?
O1 Eu1 N3 136.05(9) 2 2 ?
O1 Eu1 N3 75.76(9) . 2 ?
N3 Eu1 N3 145.69(13) . 2 ?
O1 Eu1 N1 83.80(10) 2 . ?
O1 Eu1 N1 75.39(10) . . ?
N3 Eu1 N1 71.10(10) . . ?
N3 Eu1 N1 117.14(10) 2 . ?
O1 Eu1 N1 75.39(10) 2 2 ?
O1 Eu1 N1 83.80(10) . 2 ?
N3 Eu1 N1 117.14(10) . 2 ?
N3 Eu1 N1 71.10(10) 2 2 ?
N1 Eu1 N1 154.10(14) . 2 ?
O1 Eu1 N5 147.26(10) 2 . ?
O1 Eu1 N5 118.08(9) . . ?
N3 Eu1 N5 76.46(10) . . ?
N3 Eu1 N5 75.67(10) 2 . ?
N1 Eu1 N5 71.03(10) . . ?
N1 Eu1 N5 133.72(10) 2 . ?
O1 Eu1 N5 118.08(9) 2 2 ?
O1 Eu1 N5 147.26(10) . 2 ?
N3 Eu1 N5 75.67(10) . 2 ?
N3 Eu1 N5 76.46(10) 2 2 ?
N1 Eu1 N5 133.72(10) . 2 ?
N1 Eu1 N5 71.03(10) 2 2 ?
N5 Eu1 N5 70.55(14) . 2 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.517(5) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
C19 C18 1.521(10) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C18 C17 1.434(13) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C17 C17 1.512(15) 2_655 ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C2 O1 1.268(4) . ?
C2 C3 1.409(4) . ?
C3 C2 1.409(4) 2 ?
C3 C4 1.499(6) . ?
C4 C5 1.386(5) . ?
C4 C5 1.386(5) 2 ?
C5 C6 1.406(6) . ?
C5 H5 0.9500 . ?
C6 C7 1.369(6) . ?
C6 H6 0.9500 . ?
C7 C6 1.369(6) 2 ?
C7 H7 0.9500 . ?
C8 N1 1.328(5) . ?
C8 C9 1.386(6) . ?
C8 H8 0.9500 . ?
C9 C10 1.381(6) . ?
C9 H9 0.9500 . ?
C10 N2 1.343(5) . ?
C10 H10 0.9500 . ?
C11 N3 1.328(5) . ?
C11 C12 1.396(6) . ?
C11 H11 0.9500 . ?
C12 C13 1.376(6) . ?
C12 H12 0.9500 . ?
C13 N4 1.344(5) . ?
C13 H13 0.9500 . ?
C14 N5 1.333(5) . ?
C14 C15 1.392(5) . ?
C14 H14 0.9500 . ?
C15 C16 1.369(6) . ?
C15 H15 0.9500 . ?
C16 N6 1.360(5) . ?
C16 H16 0.9500 . ?
B1 N6 1.537(5) . ?
B1 N2 1.540(5) . ?
B1 N4 1.559(5) . ?
B1 H1 1.0000 . ?
N1 N2 1.372(4) . ?
N1 Eu1 2.575(3) . ?
N3 N4 1.362(4) . ?
N3 Eu1 2.510(3) . ?
N5 N6 1.366(5) . ?
N5 Eu1 2.591(3) . ?
O1 Eu1 2.304(2) . ?
Eu1 O1 2.304(2) 2 ?
Eu1 N3 2.510(3) 2 ?
Eu1 N1 2.575(3) 2 ?
Eu1 N5 2.591(3) 2 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C19 C18 C17 C17 -178.6(6) . . . 2_655 ?
O1 C2 C3 C2 -0.7(3) . . . 2 ?
C1 C2 C3 C2 -178.8(4) . . . 2 ?
O1 C2 C3 C4 179.3(3) . . . . ?
C1 C2 C3 C4 1.2(4) . . . . ?
C2 C3 C4 C5 88.3(3) . . . . ?
C2 C3 C4 C5 -91.7(3) 2 . . . ?
C2 C3 C4 C5 -91.7(3) . . . 2 ?
C2 C3 C4 C5 88.3(3) 2 . . 2 ?
C5 C4 C5 C6 0.6(3) 2 . . . ?
C3 C4 C5 C6 -179.4(3) . . . . ?
C4 C5 C6 C7 -1.2(6) . . . . ?
C5 C6 C7 C6 0.6(3) . . . 2 ?
N1 C8 C9 C10 -0.4(5) . . . . ?
C8 C9 C10 N2 0.1(4) . . . . ?
N3 C11 C12 C13 0.4(4) . . . . ?
C11 C12 C13 N4 -0.1(4) . . . . ?
N5 C14 C15 C16 0.1(5) . . . . ?
C14 C15 C16 N6 0.1(5) . . . . ?
C9 C8 N1 N2 0.5(4) . . . . ?
C9 C8 N1 Eu1 177.5(2) . . . . ?
C9 C10 N2 N1 0.2(4) . . . . ?
C9 C10 N2 B1 -179.4(3) . . . . ?
C8 N1 N2 C10 -0.4(4) . . . . ?
Eu1 N1 N2 C10 -177.7(2) . . . . ?
C8 N1 N2 B1 179.2(3) . . . . ?
Eu1 N1 N2 B1 1.9(4) . . . . ?
N6 B1 N2 C10 -120.7(4) . . . . ?
N4 B1 N2 C10 119.1(4) . . . . ?
N6 B1 N2 N1 59.7(4) . . . . ?
N4 B1 N2 N1 -60.4(4) . . . . ?
C12 C11 N3 N4 -0.5(4) . . . . ?
C12 C11 N3 Eu1 173.4(2) . . . . ?
C12 C13 N4 N3 -0.2(4) . . . . ?
C12 C13 N4 B1 173.8(4) . . . . ?
C11 N3 N4 C13 0.4(4) . . . . ?
Eu1 N3 N4 C13 -173.7(2) . . . . ?
C11 N3 N4 B1 -174.1(3) . . . . ?
Eu1 N3 N4 B1 11.8(4) . . . . ?
N6 B1 N4 C13 120.3(4) . . . . ?
N2 B1 N4 C13 -120.0(4) . . . . ?
N6 B1 N4 N3 -66.4(4) . . . . ?
N2 B1 N4 N3 53.4(4) . . . . ?
C15 C14 N5 N6 -0.2(4) . . . . ?
C15 C14 N5 Eu1 -169.1(3) . . . . ?
C15 C16 N6 N5 -0.3(5) . . . . ?
C15 C16 N6 B1 177.1(4) . . . . ?
C14 N5 N6 C16 0.3(4) . . . . ?
Eu1 N5 N6 C16 170.2(2) . . . . ?
C14 N5 N6 B1 -177.2(3) . . . . ?
Eu1 N5 N6 B1 -7.3(5) . . . . ?
N2 B1 N6 C16 126.4(4) . . . . ?
N4 B1 N6 C16 -113.8(4) . . . . ?
N2 B1 N6 N5 -56.6(5) . . . . ?
N4 B1 N6 N5 63.2(4) . . . . ?
C3 C2 O1 Eu1 1.5(6) . . . . ?
C1 C2 O1 Eu1 179.7(2) . . . . ?
