#------------------------------------------------------------------------------
#$Date: 2021-11-16 01:07:44 +0100 (mar 16 de nov de 2021) $
#$Revision: 270668 $
#$URL: svn://www.crystallography.net/cod/cif/7/70/88/7708819.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7708819
loop_
_publ_author_name
'Xie, Siyuan L.'
'Sanz, Corey A.'
'Fryzuk, Michael D.'
_publ_section_title
;
 Heterobimetallic complexes stabilized by the P2N2 macrocyclic ligand
 system: synthesis and reactivity of a rhodium--copper system that
 activates molecular hydrogen
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT03129E
_journal_year                    2021
_chemical_formula_moiety         'C32 H56 Cu N2 P2 Rh Si4'
_chemical_formula_sum            'C32 H56 Cu N2 P2 Rh Si4'
_chemical_formula_weight         809.53
_chemical_name_systematic        Rh(COE)[P2N2]Cu
_chemical_properties_physical
Air-sensitive,Moisture-sensitive,Oxygen-sensitive
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2021-04-14
_audit_creation_method
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_audit_update_record
;
2021-06-03 deposited with the CCDC.	2021-11-02 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 102.314(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.9598(7)
_cell_length_b                   13.5924(6)
_cell_length_c                   18.3198(8)
_cell_measurement_reflns_used    9890
_cell_measurement_temperature    90
_cell_measurement_theta_max      59.15
_cell_measurement_theta_min      2.834
_cell_volume                     3882.7(3)
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_diffrn_ambient_temperature      90.0
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.1088
_diffrn_reflns_av_unetI/netI     0.0591
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            43620
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        59.368
_diffrn_reflns_theta_max         59.368
_diffrn_reflns_theta_min         2.834
_exptl_absorpt_coefficient_mu    6.250
_exptl_absorpt_correction_T_max  0.607
_exptl_absorpt_correction_T_min  0.399
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1076 before and 0.0791 after correction.
The Ratio of minimum to maximum transmission is 0.6583.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.385
_exptl_crystal_description       plate
_exptl_crystal_F_000             1688
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.964
_refine_diff_density_min         -0.934
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         5623
_refine_ls_number_restraints     896
_refine_ls_restrained_S_all      0.958
_refine_ls_R_factor_all          0.0651
_refine_ls_R_factor_gt           0.0450
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0537P)²+6.7052P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1075
_refine_ls_wR_factor_ref         0.1171
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4348
_reflns_number_total             5623
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt03129e2.cif
_cod_data_source_block           mf1444
_cod_database_code               7708819
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.635
_shelx_estimated_absorpt_t_min   0.368
_olex2_refinement_description
;
1. Restrained distances
 C27A-C26A
 1.54 with sigma of 0.02
 C25A-C26A
 1.54 with sigma of 0.02
 C30A-C31A
 1.54 with sigma of 0.02
 C29A-C30A
 1.54 with sigma of 0.02
2. Uiso/Uaniso restraints and constraints
All non-hydrogen atoms have similar U: within 2A with sigma of 0.04 and sigma
for terminal atoms of 0.08 within 2A
3. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4. Others
 Sof(C25A)=Sof(H25A)=Sof(C26A)=Sof(H26C)=Sof(H26D)=Sof(C27A)=Sof(H27C)=
 Sof(H27D)=Sof(C28A)=Sof(H28C)=Sof(H28D)=Sof(C29A)=Sof(H29C)=Sof(H29D)=
 Sof(C30A)=Sof(H30C)=Sof(H30D)=Sof(C31A)=Sof(H31C)=Sof(H31D)=Sof(C32A)=
 Sof(H32A)=1-FVAR(1)
 Sof(C25)=Sof(H25)=Sof(C26)=Sof(H26A)=Sof(H26B)=Sof(C27)=Sof(H27A)=Sof(H27B)=
 Sof(C28)=Sof(H28A)=Sof(H28B)=Sof(C29)=Sof(H29A)=Sof(H29B)=Sof(C30)=Sof(H30A)=
 Sof(H30B)=Sof(C31)=Sof(H31A)=Sof(H31B)=Sof(C32)=Sof(H32)=FVAR(1)
5.a Ternary CH refined with riding coordinates:
 C25(H25), C25A(H25A), C32(H32), C32A(H32A)
5.b Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C2(H2A,H2B), C3(H3A,H3B), C4(H4A,H4B), C26(H26A,H26B), C26A(H26C,
 H26D), C27(H27A,H27B), C27A(H27C,H27D), C28(H28A,H28B), C28A(H28C,H28D),
 C29(H29A,H29B), C29A(H29C,H29D), C30(H30A,H30B), C30A(H30C,H30D), C31(H31A,
 H31B), C31A(H31C,H31D)
5.c Aromatic/amide H refined with riding coordinates:
 C6(H6), C7(H7), C8(H8), C9(H9), C10(H10), C12(H12), C13(H13), C14(H14),
 C15(H15), C16(H16)
5.d Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C), C18(H18A,H18B,H18C), C19(H19A,H19B,H19C), C20(H20A,H20B,
 H20C), C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C23(H23A,H23B,H23C), C24(H24A,
 H24B,H24C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.24739(2) 0.56917(3) 0.69346(2) 0.03011(14) Uani 1 1 d . . . . .
Cu1 Cu 0.35205(5) 0.71425(6) 0.71843(4) 0.0363(2) Uani 1 1 d . U . . .
P1 P 0.25310(9) 0.59643(11) 0.81787(8) 0.0373(4) Uani 1 1 d . U . . .
P2 P 0.30075(9) 0.56392(11) 0.58441(8) 0.0351(3) Uani 1 1 d . U . . .
Si1 Si 0.49364(10) 0.60925(13) 0.68228(10) 0.0434(4) Uani 1 1 d . U . . .
Si2 Si 0.45987(11) 0.63395(14) 0.84729(9) 0.0493(5) Uani 1 1 d . U . . .
Si3 Si 0.17417(10) 0.77613(11) 0.73729(9) 0.0371(4) Uani 1 1 d . U . . .
Si4 Si 0.22282(11) 0.76946(13) 0.58491(9) 0.0423(4) Uani 1 1 d . U . . .
N1 N 0.2348(3) 0.7337(3) 0.6769(2) 0.0323(10) Uani 1 1 d . U . . .
N2 N 0.4553(3) 0.6519(4) 0.7561(3) 0.0453(12) Uani 1 1 d . U . . .
C1 C 0.4152(3) 0.5351(5) 0.6082(3) 0.0437(15) Uani 1 1 d . U . . .
H1A H 0.436488 0.539033 0.561321 0.052 Uiso 1 1 calc R U . . .
H1B H 0.420374 0.465379 0.624257 0.052 Uiso 1 1 calc R U . . .
C2 C 0.3612(4) 0.5739(5) 0.8710(3) 0.0483(16) Uani 1 1 d . U . . .
H2A H 0.370420 0.501938 0.870170 0.058 Uiso 1 1 calc R U . . .
H2B H 0.361369 0.591548 0.923498 0.058 Uiso 1 1 calc R U . . .
C3 C 0.2263(4) 0.7250(5) 0.8317(3) 0.0448(15) Uani 1 1 d . U . . .
H3A H 0.278814 0.762670 0.853269 0.054 Uiso 1 1 calc R U . . .
H3B H 0.186455 0.729343 0.866211 0.054 Uiso 1 1 calc R U . . .
C4 C 0.2953(4) 0.6877(5) 0.5427(3) 0.0428(14) Uani 1 1 d . U . . .
H4A H 0.273084 0.682913 0.488035 0.051 Uiso 1 1 calc R U . . .
H4B H 0.353469 0.716601 0.551464 0.051 Uiso 1 1 calc R U . . .
C5 C 0.2570(4) 0.4867(5) 0.5031(3) 0.0382(13) Uani 1 1 d . U . . .
C6 C 0.2991(4) 0.4074(5) 0.4811(4) 0.0505(16) Uani 1 1 d . U . . .
H6 H 0.356296 0.393496 0.506338 0.061 Uiso 1 1 calc R U . . .
C7 C 0.2593(5) 0.3475(6) 0.4226(4) 0.0637(19) Uani 1 1 d . U . . .
H7 H 0.289536 0.293418 0.407884 0.076 Uiso 1 1 calc R U . . .
C8 C 0.1767(5) 0.3660(6) 0.3861(3) 0.0590(18) Uani 1 1 d . U . . .
H8 H 0.149129 0.323797 0.346932 0.071 Uiso 1 1 calc R U . . .
C9 C 0.1340(4) 0.4453(5) 0.4060(3) 0.0517(16) Uani 1 1 d . U . . .
H9 H 0.077015 0.458779 0.380016 0.062 Uiso 1 1 calc R U . . .
C10 C 0.1734(4) 0.5060(5) 0.4637(3) 0.0453(15) Uani 1 1 d . U . . .
H10 H 0.143380 0.561366 0.476756 0.054 Uiso 1 1 calc R U . . .
C11 C 0.1856(4) 0.5261(5) 0.8688(3) 0.0429(14) Uani 1 1 d . U . . .
C12 C 0.1014(4) 0.5537(6) 0.8651(4) 0.0578(18) Uani 1 1 d . U . . .
H12 H 0.078330 0.608660 0.835429 0.069 Uiso 1 1 calc R U . . .
C13 C 0.0502(5) 0.5016(6) 0.9045(4) 0.070(2) Uani 1 1 d . U . . .
H13 H -0.006953 0.522530 0.902758 0.084 Uiso 1 1 calc R U . . .
C14 C 0.0816(6) 0.4209(6) 0.9456(4) 0.072(2) Uani 1 1 d . U . . .
H14 H 0.046864 0.385797 0.972856 0.087 Uiso 1 1 calc R U . . .
C15 C 0.1628(6) 0.3917(6) 0.9470(4) 0.073(2) Uani 1 1 d . U . . .
H15 H 0.184335 0.334735 0.974889 0.088 Uiso 1 1 calc R U . . .
C16 C 0.2166(5) 0.4431(5) 0.9085(3) 0.0554(17) Uani 1 1 d . U . . .
H16 H 0.273306 0.420827 0.909843 0.067 Uiso 1 1 calc R U . . .
C17 C 0.5863(4) 0.5218(5) 0.7078(4) 0.0598(19) Uani 1 1 d . U . . .
H17A H 0.631928 0.552407 0.745231 0.090 Uiso 1 1 calc R U . . .
H17B H 0.608274 0.506053 0.663101 0.090 Uiso 1 1 calc R U . . .
H17C H 0.567200 0.461275 0.728305 0.090 Uiso 1 1 calc R U . . .
C18 C 0.5286(4) 0.7173(5) 0.6315(4) 0.0515(16) Uani 1 1 d . U . . .
H18A H 0.481552 0.764963 0.619488 0.077 Uiso 1 1 calc R U . . .
H18B H 0.543763 0.694490 0.585294 0.077 Uiso 1 1 calc R U . . .
H18C H 0.578524 0.748676 0.663442 0.077 Uiso 1 1 calc R U . . .
C19 C 0.5495(5) 0.5524(7) 0.8947(5) 0.092(3) Uani 1 1 d . U . . .
H19A H 0.545570 0.488902 0.868752 0.139 Uiso 1 1 calc R U . . .
H19B H 0.545379 0.541947 0.946704 0.139 Uiso 1 1 calc R U . . .
H19C H 0.604554 0.583491 0.893324 0.139 Uiso 1 1 calc R U . . .
C20 C 0.4750(5) 0.7524(6) 0.8992(4) 0.079(2) Uani 1 1 d . U . . .
H20A H 0.531513 0.779622 0.897796 0.119 Uiso 1 1 calc R U . . .
H20B H 0.471212 0.741083 0.951239 0.119 Uiso 1 1 calc R U . . .
H20C H 0.430330 0.798929 0.875981 0.119 Uiso 1 1 calc R U . . .
C21 C 0.0611(4) 0.7319(5) 0.7098(4) 0.0464(15) Uani 1 1 d . U . . .
H21A H 0.032807 0.763551 0.662967 0.070 Uiso 1 1 calc R U . . .
H21B H 0.030418 0.748658 0.749153 0.070 Uiso 1 1 calc R U . . .
H21C H 0.060686 0.660429 0.702989 0.070 Uiso 1 1 calc R U . . .
C22 C 0.1715(5) 0.9134(5) 0.7428(4) 0.0621(19) Uani 1 1 d . U . . .
H22A H 0.139071 0.933177 0.780174 0.093 Uiso 1 1 calc R U . . .
H22B H 0.143792 0.940212 0.693945 0.093 Uiso 1 1 calc R U . . .
H22C H 0.230199 0.938693 0.757127 0.093 Uiso 1 1 calc R U . . .
C23 C 0.1103(4) 0.7523(7) 0.5333(4) 0.080(3) Uani 1 1 d . U . . .
H23A H 0.088442 0.689508 0.547724 0.119 Uiso 1 1 calc R U . . .
H23B H 0.108271 0.752302 0.479467 0.119 Uiso 1 1 calc R U . . .
H23C H 0.074833 0.806205 0.545514 0.119 Uiso 1 1 calc R U . . .
C24 C 0.2543(7) 0.8989(6) 0.5744(5) 0.095(3) Uani 1 1 d . U . . .
H24A H 0.216615 0.942631 0.595258 0.143 Uiso 1 1 calc R U . . .
H24B H 0.249171 0.913801 0.521272 0.143 Uiso 1 1 calc R U . . .
H24C H 0.313821 0.908676 0.601024 0.143 Uiso 1 1 calc R U . . .
C25 C 0.1669(4) 0.4448(5) 0.6924(4) 0.0346(16) Uani 0.852(7) 1 d . U P A 1
H25 H 0.131323 0.447921 0.731107 0.042 Uiso 0.852(7) 1 calc R U P A 1
C25A C 0.178(2) 0.447(3) 0.636(2) 0.039(6) Uani 0.148(7) 1 d D U P A 2
H25A H 0.165202 0.451204 0.579971 0.047 Uiso 0.148(7) 1 calc R U P A 2
C26 C 0.1184(5) 0.4098(6) 0.6186(4) 0.054(2) Uani 0.852(7) 1 d . U P A 1
H26A H 0.158538 0.395374 0.585596 0.065 Uiso 0.852(7) 1 calc R U P A 1
H26B H 0.078144 0.461565 0.594659 0.065 Uiso 0.852(7) 1 calc R U P A 1
C26A C 0.102(2) 0.427(3) 0.671(2) 0.038(7) Uani 0.148(7) 1 d D U P A 2
H26C H 0.071462 0.489650 0.676625 0.045 Uiso 0.148(7) 1 calc R U P A 2
H26D H 0.120113 0.396285 0.720475 0.045 Uiso 0.148(7) 1 calc R U P A 2
C27 C 0.0669(6) 0.3138(8) 0.6298(5) 0.055(3) Uani 0.852(7) 1 d . U P A 1
H27A H 0.019051 0.332374 0.653663 0.066 Uiso 0.852(7) 1 calc R U P A 1
H27B H 0.041538 0.285929 0.580070 0.066 Uiso 0.852(7) 1 calc R U P A 1
C27A C 0.043(3) 0.357(3) 0.616(2) 0.035(7) Uani 0.148(7) 1 d D U P A 2
H27C H 0.032122 0.385265 0.564558 0.042 Uiso 0.148(7) 1 calc R U P A 2
H27D H -0.013140 0.350367 0.630289 0.042 Uiso 0.148(7) 1 calc R U P A 2
C28 C 0.1209(6) 0.2328(10) 0.6778(8) 0.052(3) Uani 0.852(7) 1 d . U P A 1
H28A H 0.138358 0.257515 0.729642 0.062 Uiso 0.852(7) 1 calc R U P A 1
H28B H 0.083591 0.174886 0.678857 0.062 Uiso 0.852(7) 1 calc R U P A 1
C28A C 0.085(3) 0.253(3) 0.615(2) 0.032(7) Uani 0.148(7) 1 d . U P A 2
H28C H 0.038693 0.203916 0.602800 0.038 Uiso 0.148(7) 1 calc R U P A 2
H28D H 0.117194 0.252197 0.574607 0.038 Uiso 0.148(7) 1 calc R U P A 2
C29 C 0.2007(6) 0.1988(6) 0.6527(5) 0.058(2) Uani 0.852(7) 1 d . U P A 1
H29A H 0.201644 0.126006 0.653452 0.069 Uiso 0.852(7) 1 calc R U P A 1
H29B H 0.195963 0.219724 0.600220 0.069 Uiso 0.852(7) 1 calc R U P A 1
C29A C 0.146(3) 0.221(6) 0.687(5) 0.039(8) Uani 0.148(7) 1 d D U P A 2
H29C H 0.136548 0.150044 0.693044 0.047 Uiso 0.148(7) 1 calc R U P A 2
H29D H 0.126794 0.254904 0.728794 0.047 Uiso 0.148(7) 1 calc R U P A 2
C30 C 0.2850(6) 0.2352(6) 0.6976(5) 0.053(2) Uani 0.852(7) 1 d . U P A 1
H30A H 0.331750 0.194724 0.685410 0.064 Uiso 0.852(7) 1 calc R U P A 1
H30B H 0.285817 0.225908 0.751396 0.064 Uiso 0.852(7) 1 calc R U P A 1
C30A C 0.243(3) 0.238(3) 0.698(3) 0.040(7) Uani 0.148(7) 1 d D U P A 2
H30C H 0.258479 0.226050 0.649245 0.048 Uiso 0.148(7) 1 calc R U P A 2
H30D H 0.271808 0.186702 0.732755 0.048 Uiso 0.148(7) 1 calc R U P A 2
C31 C 0.3027(5) 0.3443(5) 0.6837(4) 0.0462(19) Uani 0.852(7) 1 d . U P A 1
H31A H 0.364653 0.357484 0.701786 0.055 Uiso 0.852(7) 1 calc R U P A 1
H31B H 0.288423 0.356977 0.629231 0.055 Uiso 0.852(7) 1 calc R U P A 1
C31A C 0.282(3) 0.340(3) 0.728(3) 0.040(7) Uani 0.148(7) 1 d D U P A 2
H31C H 0.255626 0.361999 0.769312 0.048 Uiso 0.148(7) 1 calc R U P A 2
H31D H 0.344333 0.332883 0.747153 0.048 Uiso 0.148(7) 1 calc R U P A 2
C32 C 0.2525(4) 0.4140(5) 0.7215(4) 0.0305(15) Uani 0.852(7) 1 d . U P A 1
H32 H 0.263753 0.403035 0.776689 0.037 Uiso 0.852(7) 1 calc R U P A 1
C32A C 0.266(2) 0.409(3) 0.671(3) 0.035(6) Uani 0.148(7) 1 d . U P A 2
H32A H 0.303038 0.398857 0.633279 0.041 Uiso 0.148(7) 1 calc R U P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 0.5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Rh1 Cu1 79.15(4) . . ?
P1 Rh1 P2 155.77(5) . . ?
P2 Rh1 Cu1 80.41(4) . . ?
N1 Rh1 Cu1 45.44(11) . . ?
N1 Rh1 P1 87.55(12) . . ?
N1 Rh1 P2 87.34(12) . . ?
C25 Rh1 Cu1 170.36(18) . . ?
C25 Rh1 P1 91.93(19) . . ?
C25 Rh1 P2 107.4(2) . . ?
C25 Rh1 N1 138.7(2) . . ?
C25 Rh1 C32 38.6(2) . . ?
C25A Rh1 Cu1 158.7(9) . . ?
C25A Rh1 P1 121.5(10) . . ?
C25A Rh1 P2 78.3(9) . . ?
C25A Rh1 N1 132.8(11) . . ?
C25A Rh1 C32A 40.0(14) . . ?
C32 Rh1 Cu1 135.75(17) . . ?
C32 Rh1 P1 86.01(19) . . ?
C32 Rh1 P2 99.83(19) . . ?
C32 Rh1 N1 172.8(2) . . ?
C32A Rh1 Cu1 132.0(10) . . ?
C32A Rh1 P1 111.3(12) . . ?
C32A Rh1 P2 73.9(12) . . ?
C32A Rh1 N1 160.8(13) . . ?
N1 Cu1 Rh1 58.78(14) . . ?
N2 Cu1 Rh1 102.08(16) . . ?
N2 Cu1 N1 160.8(2) . . ?
C2 P1 Rh1 109.7(2) . . ?
C2 P1 C3 108.1(3) . . ?
C2 P1 C11 103.5(3) . . ?
C3 P1 Rh1 109.3(2) . . ?
C3 P1 C11 104.3(3) . . ?
C11 P1 Rh1 121.17(18) . . ?
C1 P2 Rh1 109.3(2) . . ?
C1 P2 C4 104.6(3) . . ?
C1 P2 C5 105.0(3) . . ?
C4 P2 Rh1 109.50(19) . . ?
C5 P2 Rh1 124.59(19) . . ?
C5 P2 C4 102.1(3) . . ?
N2 Si1 C1 116.7(3) . . ?
N2 Si1 C17 114.6(3) . . ?
N2 Si1 C18 108.7(3) . . ?
C17 Si1 C1 101.7(3) . . ?
C17 Si1 C18 108.4(3) . . ?
C18 Si1 C1 106.1(3) . . ?
N2 Si2 C2 115.4(3) . . ?
N2 Si2 C19 114.5(4) . . ?
N2 Si2 C20 110.9(3) . . ?
C19 Si2 C2 103.2(3) . . ?
C20 Si2 C2 106.1(3) . . ?
C20 Si2 C19 105.8(4) . . ?
N1 Si3 C3 105.6(3) . . ?
N1 Si3 C21 111.3(3) . . ?
N1 Si3 C22 113.1(3) . . ?
C21 Si3 C3 109.9(3) . . ?
C21 Si3 C22 107.7(3) . . ?
C22 Si3 C3 109.2(3) . . ?
N1 Si4 C4 106.6(2) . . ?
N1 Si4 C23 110.8(3) . . ?
N1 Si4 C24 113.2(3) . . ?
C23 Si4 C4 109.2(3) . . ?
C24 Si4 C4 108.3(4) . . ?
C24 Si4 C23 108.7(4) . . ?
Cu1 N1 Rh1 75.78(15) . . ?
Si3 N1 Rh1 107.0(2) . . ?
Si3 N1 Cu1 115.7(2) . . ?
Si3 N1 Si4 125.1(3) . . ?
Si4 N1 Rh1 113.5(2) . . ?
Si4 N1 Cu1 109.1(2) . . ?
Si1 N2 Cu1 107.6(2) . . ?
Si2 N2 Cu1 106.5(3) . . ?
Si2 N2 Si1 142.9(3) . . ?
P2 C1 Si1 121.5(3) . . ?
P2 C1 H1A 107.0 . . ?
P2 C1 H1B 107.0 . . ?
Si1 C1 H1A 107.0 . . ?
Si1 C1 H1B 107.0 . . ?
H1A C1 H1B 106.7 . . ?
P1 C2 Si2 122.8(3) . . ?
P1 C2 H2A 106.6 . . ?
P1 C2 H2B 106.6 . . ?
Si2 C2 H2A 106.6 . . ?
Si2 C2 H2B 106.6 . . ?
H2A C2 H2B 106.6 . . ?
P1 C3 Si3 107.2(3) . . ?
P1 C3 H3A 110.3 . . ?
P1 C3 H3B 110.3 . . ?
Si3 C3 H3A 110.3 . . ?
Si3 C3 H3B 110.3 . . ?
H3A C3 H3B 108.5 . . ?
P2 C4 Si4 110.3(3) . . ?
P2 C4 H4A 109.6 . . ?
P2 C4 H4B 109.6 . . ?
Si4 C4 H4A 109.6 . . ?
Si4 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C6 C5 P2 124.1(5) . . ?
C6 C5 C10 117.9(6) . . ?
C10 C5 P2 117.9(4) . . ?
C5 C6 H6 119.5 . . ?
C5 C6 C7 120.9(6) . . ?
C7 C6 H6 119.5 . . ?
C6 C7 H7 119.8 . . ?
C8 C7 C6 120.3(7) . . ?
C8 C7 H7 119.8 . . ?
C7 C8 H8 120.1 . . ?
C9 C8 C7 119.9(6) . . ?
C9 C8 H8 120.1 . . ?
C8 C9 H9 119.9 . . ?
C8 C9 C10 120.3(6) . . ?
C10 C9 H9 119.9 . . ?
C5 C10 H10 119.6 . . ?
C9 C10 C5 120.7(6) . . ?
C9 C10 H10 119.6 . . ?
C12 C11 P1 120.2(5) . . ?
C16 C11 P1 120.8(5) . . ?
C16 C11 C12 119.0(6) . . ?
C11 C12 H12 119.8 . . ?
C11 C12 C13 120.5(7) . . ?
C13 C12 H12 119.8 . . ?
C12 C13 H13 119.7 . . ?
C14 C13 C12 120.5(8) . . ?
C14 C13 H13 119.7 . . ?
C13 C14 H14 120.5 . . ?
C15 C14 C13 119.0(7) . . ?
C15 C14 H14 120.5 . . ?
C14 C15 H15 119.0 . . ?
C14 C15 C16 122.0(8) . . ?
C16 C15 H15 119.0 . . ?
C11 C16 C15 118.9(8) . . ?
C11 C16 H16 120.5 . . ?
C15 C16 H16 120.5 . . ?
Si1 C17 H17A 109.5 . . ?
Si1 C17 H17B 109.5 . . ?
Si1 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
Si1 C18 H18A 109.5 . . ?
Si1 C18 H18B 109.5 . . ?
Si1 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
Si2 C19 H19A 109.5 . . ?
Si2 C19 H19B 109.5 . . ?
Si2 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
Si2 C20 H20A 109.5 . . ?
Si2 C20 H20B 109.5 . . ?
Si2 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
Si3 C21 H21A 109.5 . . ?
Si3 C21 H21B 109.5 . . ?
Si3 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
Si3 C22 H22A 109.5 . . ?
Si3 C22 H22B 109.5 . . ?
Si3 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
Si4 C23 H23A 109.5 . . ?
Si4 C23 H23B 109.5 . . ?
Si4 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
Si4 C24 H24A 109.5 . . ?
Si4 C24 H24B 109.5 . . ?
Si4 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
Rh1 C25 H25 113.2 . . ?
C26 C25 Rh1 117.4(5) . . ?
C26 C25 H25 113.2 . . ?
C32 C25 Rh1 72.5(4) . . ?
C32 C25 H25 113.2 . . ?
C32 C25 C26 121.4(7) . . ?
Rh1 C25A H25A 115.4 . . ?
C26A C25A Rh1 107(3) . . ?
C26A C25A H25A 115.4 . . ?
C32A C25A Rh1 74(2) . . ?
C32A C25A H25A 115.4 . . ?
C32A C25A C26A 122(4) . . ?
C25 C26 H26A 109.8 . . ?
C25 C26 H26B 109.8 . . ?
C25 C26 C27 109.3(6) . . ?
H26A C26 H26B 108.3 . . ?
C27 C26 H26A 109.8 . . ?
C27 C26 H26B 109.8 . . ?
C25A C26A H26C 110.7 . . ?
C25A C26A H26D 110.7 . . ?
C25A C26A C27A 105(3) . . ?
H26C C26A H26D 108.8 . . ?
C27A C26A H26C 110.7 . . ?
C27A C26A H26D 110.7 . . ?
C26 C27 H27A 108.6 . . ?
C26 C27 H27B 108.6 . . ?
H27A C27 H27B 107.6 . . ?
C28 C27 C26 114.7(7) . . ?
C28 C27 H27A 108.6 . . ?
C28 C27 H27B 108.6 . . ?
C26A C27A H27C 109.5 . . ?
C26A C27A H27D 109.5 . . ?
C26A C27A C28A 111(3) . . ?
H27C C27A H27D 108.1 . . ?
C28A C27A H27C 109.5 . . ?
C28A C27A H27D 109.5 . . ?
C27 C28 H28A 108.2 . . ?
C27 C28 H28B 108.2 . . ?
H28A C28 H28B 107.3 . . ?
C29 C28 C27 116.5(10) . . ?
C29 C28 H28A 108.2 . . ?
C29 C28 H28B 108.2 . . ?
C27A C28A H28C 108.1 . . ?
C27A C28A H28D 108.1 . . ?
H28C C28A H28D 107.3 . . ?
C29A C28A C27A 117(5) . . ?
C29A C28A H28C 108.1 . . ?
C29A C28A H28D 108.1 . . ?
C28 C29 H29A 108.2 . . ?
C28 C29 H29B 108.2 . . ?
H29A C29 H29B 107.3 . . ?
C30 C29 C28 116.5(9) . . ?
C30 C29 H29A 108.2 . . ?
C30 C29 H29B 108.2 . . ?
C28A C29A H29C 107.2 . . ?
C28A C29A H29D 107.2 . . ?
C28A C29A C30A 121(6) . . ?
H29C C29A H29D 106.8 . . ?
C30A C29A H29C 107.2 . . ?
C30A C29A H29D 107.2 . . ?
C29 C30 H30A 108.9 . . ?
C29 C30 H30B 108.9 . . ?
C29 C30 C31 113.5(7) . . ?
H30A C30 H30B 107.7 . . ?
C31 C30 H30A 108.9 . . ?
C31 C30 H30B 108.9 . . ?
C29A C30A H30C 107.5 . . ?
C29A C30A H30D 107.5 . . ?
C29A C30A C31A 119(5) . . ?
H30C C30A H30D 107.0 . . ?
C31A C30A H30C 107.5 . . ?
C31A C30A H30D 107.5 . . ?
C30 C31 H31A 108.9 . . ?
C30 C31 H31B 108.9 . . ?
H31A C31 H31B 107.7 . . ?
C32 C31 C30 113.4(7) . . ?
C32 C31 H31A 108.9 . . ?
C32 C31 H31B 108.9 . . ?
C30A C31A H31C 109.6 . . ?
C30A C31A H31D 109.6 . . ?
H31C C31A H31D 108.2 . . ?
C32A C31A C30A 110(4) . . ?
C32A C31A H31C 109.6 . . ?
C32A C31A H31D 109.6 . . ?
Rh1 C32 H32 112.0 . . ?
C25 C32 Rh1 68.9(4) . . ?
C25 C32 C31 125.3(6) . . ?
C25 C32 H32 112.0 . . ?
C31 C32 Rh1 120.1(5) . . ?
C31 C32 H32 112.0 . . ?
Rh1 C32A H32A 112.7 . . ?
C25A C32A Rh1 66(2) . . ?
C25A C32A H32A 112.7 . . ?
C31A C32A Rh1 122(4) . . ?
C31A C32A C25A 123(4) . . ?
C31A C32A H32A 112.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 Cu1 2.5617(9) . ?
Rh1 P1 2.2917(15) . ?
Rh1 P2 2.3338(15) . ?
Rh1 N1 2.260(4) . ?
Rh1 C25 2.121(6) . ?
Rh1 C25A 2.15(4) . ?
Rh1 C32 2.168(6) . ?
Rh1 C32A 2.25(4) . ?
Cu1 N1 1.883(4) . ?
Cu1 N2 1.851(5) . ?
P1 C2 1.816(6) . ?
P1 C3 1.829(6) . ?
P1 C11 1.837(6) . ?
P2 C1 1.828(6) . ?
P2 C4 1.842(6) . ?
P2 C5 1.835(6) . ?
Si1 N2 1.701(5) . ?
Si1 C1 1.924(6) . ?
Si1 C17 1.878(6) . ?
Si1 C18 1.885(7) . ?
Si2 N2 1.674(5) . ?
Si2 C2 1.905(6) . ?
Si2 C19 1.871(8) . ?
Si2 C20 1.859(8) . ?
Si3 N1 1.717(5) . ?
Si3 C3 1.884(6) . ?
Si3 C21 1.866(6) . ?
Si3 C22 1.869(6) . ?
Si4 N1 1.725(4) . ?
Si4 C4 1.885(6) . ?
Si4 C23 1.857(7) . ?
Si4 C24 1.851(8) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 C6 1.375(8) . ?
C5 C10 1.400(8) . ?
C6 H6 0.9500 . ?
C6 C7 1.387(9) . ?
C7 H7 0.9500 . ?
C7 C8 1.369(10) . ?
C8 H8 0.9500 . ?
C8 C9 1.365(10) . ?
C9 H9 0.9500 . ?
C9 C10 1.382(8) . ?
C10 H10 0.9500 . ?
C11 C12 1.383(9) . ?
C11 C16 1.376(9) . ?
C12 H12 0.9500 . ?
C12 C13 1.394(9) . ?
C13 H13 0.9500 . ?
C13 C14 1.364(12) . ?
C14 H14 0.9500 . ?
C14 C15 1.351(12) . ?
C15 H15 0.9500 . ?
C15 C16 1.407(9) . ?
C16 H16 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25 1.0000 . ?
C25 C26 1.486(10) . ?
C25 C32 1.419(9) . ?
C25A H25A 1.0000 . ?
C25A C26A 1.52(2) . ?
C25A C32A 1.50(5) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C26 C27 1.578(11) . ?
C26A H26C 0.9900 . ?
C26A H26D 0.9900 . ?
C26A C27A 1.56(2) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C28 1.551(15) . ?
C27A H27C 0.9900 . ?
C27A H27D 0.9900 . ?
C27A C28A 1.56(6) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C28 C29 1.515(15) . ?
C28A H28C 0.9900 . ?
C28A H28D 0.9900 . ?
C28A C29A 1.52(8) . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C29 C30 1.503(12) . ?
C29A H29C 0.9900 . ?
C29A H29D 0.9900 . ?
C29A C30A 1.54(2) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C30 C31 1.541(11) . ?
C30A H30C 0.9900 . ?
C30A H30D 0.9900 . ?
C30A C31A 1.57(2) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C31 C32 1.502(11) . ?
C31A H31C 0.9900 . ?
C31A H31D 0.9900 . ?
C31A C32A 1.39(6) . ?
C32 H32 1.0000 . ?
C32A H32A 1.0000 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 Cu1 N1 Si3 102.3(3) . . . . ?
Rh1 Cu1 N1 Si4 -110.3(2) . . . . ?
Rh1 Cu1 N2 Si1 81.6(2) . . . . ?
Rh1 Cu1 N2 Si2 -83.5(3) . . . . ?
Rh1 P1 C2 Si2 52.5(5) . . . . ?
Rh1 P1 C3 Si3 15.9(3) . . . . ?
Rh1 P1 C11 C12 -82.5(5) . . . . ?
Rh1 P1 C11 C16 94.8(5) . . . . ?
Rh1 P2 C1 Si1 -52.3(4) . . . . ?
Rh1 P2 C4 Si4 -15.2(3) . . . . ?
Rh1 P2 C5 C6 -111.2(5) . . . . ?
Rh1 P2 C5 C10 64.6(5) . . . . ?
Rh1 C25 C26 C27 176.9(6) . . . . ?
Rh1 C25 C32 C31 -112.7(7) . . . . ?
Rh1 C25A C26A C27A 166(3) . . . . ?
Rh1 C25A C32A C31A 114(5) . . . . ?
P1 C11 C12 C13 -179.0(5) . . . . ?
P1 C11 C16 C15 179.6(5) . . . . ?
P2 C5 C6 C7 174.7(5) . . . . ?
P2 C5 C10 C9 -174.3(5) . . . . ?
N1 Cu1 N2 Si1 78.2(7) . . . . ?
N1 Cu1 N2 Si2 -86.8(7) . . . . ?
N1 Si3 C3 P1 -43.3(3) . . . . ?
N1 Si4 C4 P2 33.7(4) . . . . ?
N2 Cu1 N1 Rh1 3.8(7) . . . . ?
N2 Cu1 N1 Si3 106.1(6) . . . . ?
N2 Cu1 N1 Si4 -106.5(6) . . . . ?
C1 P2 C4 Si4 -132.3(3) . . . . ?
C1 P2 C5 C6 15.8(6) . . . . ?
C1 P2 C5 C10 -168.4(5) . . . . ?
C1 Si1 N2 Cu1 -49.5(4) . . . . ?
C1 Si1 N2 Si2 106.3(5) . . . . ?
C2 P1 C3 Si3 135.3(3) . . . . ?
C2 P1 C11 C12 154.1(5) . . . . ?
C2 P1 C11 C16 -28.6(6) . . . . ?
C2 Si2 N2 Cu1 50.2(4) . . . . ?
C2 Si2 N2 Si1 -105.8(5) . . . . ?
C3 P1 C2 Si2 -66.6(5) . . . . ?
C3 P1 C11 C12 41.1(5) . . . . ?
C3 P1 C11 C16 -141.5(5) . . . . ?
C3 Si3 N1 Rh1 51.3(3) . . . . ?
C3 Si3 N1 Cu1 -30.8(3) . . . . ?
C3 Si3 N1 Si4 -172.3(3) . . . . ?
C4 P2 C1 Si1 64.8(4) . . . . ?
C4 P2 C5 C6 124.6(6) . . . . ?
C4 P2 C5 C10 -59.5(5) . . . . ?
C4 Si4 N1 Rh1 -38.6(3) . . . . ?
C4 Si4 N1 Cu1 43.8(3) . . . . ?
C4 Si4 N1 Si3 -172.6(3) . . . . ?
C5 P2 C1 Si1 171.9(4) . . . . ?
C5 P2 C4 Si4 118.5(3) . . . . ?
C5 C6 C7 C8 -0.6(11) . . . . ?
C6 C5 C10 C9 1.8(9) . . . . ?
C6 C7 C8 C9 1.7(11) . . . . ?
C7 C8 C9 C10 -1.1(10) . . . . ?
C8 C9 C10 C5 -0.7(9) . . . . ?
C10 C5 C6 C7 -1.1(10) . . . . ?
C11 P1 C2 Si2 -176.9(4) . . . . ?
C11 P1 C3 Si3 -115.1(3) . . . . ?
C11 C12 C13 C14 -1.9(10) . . . . ?
C12 C11 C16 C15 -3.0(9) . . . . ?
C12 C13 C14 C15 -0.6(10) . . . . ?
C13 C14 C15 C16 1.2(11) . . . . ?
C14 C15 C16 C11 0.6(10) . . . . ?
C16 C11 C12 C13 3.7(9) . . . . ?
C17 Si1 N2 Cu1 -168.2(3) . . . . ?
C17 Si1 N2 Si2 -12.4(6) . . . . ?
C18 Si1 N2 Cu1 70.3(3) . . . . ?
C18 Si1 N2 Si2 -133.8(5) . . . . ?
C19 Si2 N2 Cu1 169.8(3) . . . . ?
C19 Si2 N2 Si1 13.8(7) . . . . ?
C20 Si2 N2 Cu1 -70.5(4) . . . . ?
C20 Si2 N2 Si1 133.5(6) . . . . ?
C21 Si3 N1 Rh1 -67.9(3) . . . . ?
C21 Si3 N1 Cu1 -150.0(3) . . . . ?
C21 Si3 N1 Si4 68.4(4) . . . . ?
C21 Si3 C3 P1 76.8(4) . . . . ?
C22 Si3 N1 Rh1 170.7(3) . . . . ?
C22 Si3 N1 Cu1 88.6(4) . . . . ?
C22 Si3 N1 Si4 -52.9(4) . . . . ?
C22 Si3 C3 P1 -165.2(3) . . . . ?
C23 Si4 N1 Rh1 80.0(4) . . . . ?
C23 Si4 N1 Cu1 162.4(3) . . . . ?
C23 Si4 N1 Si3 -53.9(4) . . . . ?
C23 Si4 C4 P2 -86.0(4) . . . . ?
C24 Si4 N1 Rh1 -157.5(4) . . . . ?
C24 Si4 N1 Cu1 -75.2(4) . . . . ?
C24 Si4 N1 Si3 68.5(5) . . . . ?
C24 Si4 C4 P2 155.8(4) . . . . ?
C25 C26 C27 C28 -50.4(13) . . . . ?
C25A C26A C27A C28A 69(4) . . . . ?
C26 C25 C32 Rh1 111.9(6) . . . . ?
C26 C25 C32 C31 -0.8(11) . . . . ?
C26 C27 C28 C29 -54.8(15) . . . . ?
C26A C25A C32A Rh1 -101(4) . . . . ?
C26A C25A C32A C31A 13(7) . . . . ?
C26A C27A C28A C29A 29(5) . . . . ?
C27 C28 C29 C30 104.7(11) . . . . ?
C27A C28A C29A C30A -95(7) . . . . ?
C28 C29 C30 C31 -74.0(10) . . . . ?
C28A C29A C30A C31A 85(9) . . . . ?
C29 C30 C31 C32 76.2(9) . . . . ?
C29A C30A C31A C32A -78(7) . . . . ?
C30 C31 C32 Rh1 -168.2(5) . . . . ?
C30 C31 C32 C25 -83.9(9) . . . . ?
C30A C31A C32A Rh1 148(3) . . . . ?
C30A C31A C32A C25A 67(6) . . . . ?
C32 C25 C26 C27 91.5(9) . . . . ?
C32A C25A C26A C27A -112(4) . . . . ?
