#------------------------------------------------------------------------------
#$Date: 2022-01-20 00:58:04 +0100 (jue 20 de ene de 2022) $
#$Revision: 272145 $
#$URL: svn://www.crystallography.net/cod/cif/7/70/93/7709338.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7709338
loop_
_publ_author_name
'Grützmacher, Hansjörg'
'Le Corre, Grégoire'
_publ_section_title
;
 Simple conversion of trisodium phosphide, Na3P, into silyl- and
 cyanophosphides and structure of a terminal silver phosphide
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/D1DT04223H
_journal_year                    2022
_chemical_absolute_configuration syn
_chemical_formula_moiety         '0.22(C46 H51 Ag N3 P Si)'
_chemical_formula_sum            'C10.22 H11.33 Ag0.22 N0.67 P0.22 Si0.22'
_chemical_formula_weight         180.63
_chemical_melting_point          453
_chemical_name_systematic
Cyano(triphenylsilyl)phosphanido[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver(I)
_chemical_properties_physical
Air-sensitive,Moisture-sensitive,Hygroscopic,Heat-sensitive,Oxygen-sensitive
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2020-09-28
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2021-12-06 deposited with the CCDC.	2022-01-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            18
_cell_length_a                   9.5649(2)
_cell_length_b                   20.0490(3)
_cell_length_c                   21.8272(3)
_cell_measurement_reflns_used    16719
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      28.6640
_cell_measurement_theta_min      2.0350
_cell_volume                     4185.73(12)
_computing_cell_refinement       'CrysAlisPro 1.171.40.16b (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.40.16b (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.40.16b (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.0839
_diffrn_detector_type            Sapphire3
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.909
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -15.00  19.30   0.70   19.57    --  -16.28 -99.00 150.00   49
  2  ω    -90.00 -58.50   0.70   19.57    --  -16.28-179.00 -60.00   45
  3  ω      3.00  84.20   0.70   19.57    --   16.36  57.00 120.00  116
  4  ω      4.00  84.50   0.70   19.57    --   16.36  57.00  30.00  115
  5  ω      2.00  84.60   0.70   19.57    --   16.36  57.00 -60.00  118
  6  ω     -2.00  84.10   0.70   19.57    --   16.36  57.00-150.00  123
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0365166000
_diffrn_orient_matrix_UB_12      0.0306958000
_diffrn_orient_matrix_UB_13      -0.0022639000
_diffrn_orient_matrix_UB_21      -0.0636967000
_diffrn_orient_matrix_UB_22      0.0175746000
_diffrn_orient_matrix_UB_23      0.0039617000
_diffrn_orient_matrix_UB_31      0.0103592000
_diffrn_orient_matrix_UB_32      0.0000054000
_diffrn_orient_matrix_UB_33      0.0321845000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0321
_diffrn_reflns_av_unetI/netI     0.0348
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.909
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            36466
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.877
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.014
_diffrn_reflns_theta_min         1.866
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.583
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.81879
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.40.16b (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.290
_exptl_crystal_description       block
_exptl_crystal_F_000             1696
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: Toluene'
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.407
_refine_diff_density_min         -0.255
_refine_diff_density_rms         0.057
_refine_ls_abs_structure_details
;
 Flack x determined using 3693 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.202(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     477
_refine_ls_number_reflns         9768
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0316
_refine_ls_R_factor_gt           0.0278
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0253P)²+1.1450P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0574
_refine_ls_wR_factor_ref         0.0590
_reflns_Friedel_coverage         0.742
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.837
_reflns_number_gt                9188
_reflns_number_total             9768
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1dt04223h2.cif
_cod_data_source_block           exp_5191
_cod_database_code               7709338
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.94
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     25.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C00A(H00A), C00R(H00R), C00W(H00W), C012(H012)
2.b Aromatic/amide H refined with riding coordinates:
 C006(H006), C009(H009), C00F(H00F), C00I(H00I), C00J(H00J), C00K(H00K),
 C00M(H00M), C00N(H00N), C00O(H00O), C00S(H00S), C00T(H00T), C00U(H00U),
 C00X(H00X), C010(H010), C011(H011), C014(H014), C015(H015), C016(H016),
 C017(H017), C019(H019), C01A(H01G), C01B(H01H), C01C(H01I)
2.c Idealised Me refined as rotating group:
 C00Q(H00B,H00C,H00D), C00Y(H00E,H00G,H00H), C013(H01A,H01B,H01C), C018(H01D,
 H01E,H01F), C01D(H01J,H01K,H01L), C01E(H01M,H01N,H01O), C01F(H01P,H01Q,H01R),
 C01G(H01S,H01T,H01U)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.149
_oxdiff_exptl_absorpt_empirical_full_min 0.897
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag00 Ag 0.61782(2) 0.38163(2) 0.68118(2) 0.01858(6) Uani 1 1 d . . . . .
P002 P 0.75666(8) 0.46553(4) 0.63421(3) 0.01886(16) Uani 1 1 d . . . . .
Si00 Si 0.62346(10) 0.51574(4) 0.56357(3) 0.01776(16) Uani 1 1 d . . . . .
N004 N 0.3754(3) 0.29802(11) 0.74046(10) 0.0178(5) Uani 1 1 d . . . . .
N005 N 0.5591(2) 0.23850(12) 0.73118(10) 0.0172(5) Uani 1 1 d . . . . .
C006 C 0.3415(3) 0.23517(15) 0.76196(13) 0.0214(6) Uani 1 1 d . . . . .
H006 H 0.255425 0.221564 0.777354 0.026 Uiso 1 1 calc R . . . .
C007 C 0.6969(3) 0.60179(14) 0.55313(12) 0.0202(6) Uani 1 1 d . . . . .
N008 N 0.7505(3) 0.57215(14) 0.72570(12) 0.0319(6) Uani 1 1 d . . . . .
C009 C 0.4564(3) 0.19783(15) 0.75629(13) 0.0213(6) Uani 1 1 d . . . . .
H009 H 0.465898 0.153187 0.767075 0.026 Uiso 1 1 calc R . . . .
C00A C 0.6346(4) 0.17058(15) 0.61899(13) 0.0273(7) Uani 1 1 d . . . . .
H00A H 0.539579 0.170741 0.635750 0.033 Uiso 1 1 calc R . . . .
C00B C 0.6542(3) 0.46674(15) 0.49165(13) 0.0217(6) Uani 1 1 d . . . . .
C00C C 0.2783(3) 0.35359(15) 0.74155(13) 0.0203(6) Uani 1 1 d . . . . .
C00D C 0.5098(3) 0.30092(14) 0.72112(12) 0.0168(6) Uani 1 1 d . . . . .
C00E C 0.7018(3) 0.21584(14) 0.72395(13) 0.0188(6) Uani 1 1 d . . . . .
C00F C 0.3954(4) 0.54288(15) 0.64303(14) 0.0265(7) Uani 1 1 d . . . . .
H00F H 0.463680 0.546883 0.673146 0.032 Uiso 1 1 calc R . . . .
C00G C 0.7957(3) 0.22879(16) 0.77135(13) 0.0229(7) Uani 1 1 d . . . . .
C00H C 0.7353(3) 0.17752(14) 0.67208(13) 0.0230(6) Uani 1 1 d . . . . .
C00I C 0.8684(4) 0.14947(14) 0.67087(13) 0.0277(7) Uani 1 1 d . . . . .
H00I H 0.895291 0.123612 0.637512 0.033 Uiso 1 1 calc R . . . .
C00J C 0.9270(3) 0.19914(17) 0.76726(15) 0.0285(7) Uani 1 1 d . . . . .
H00J H 0.992223 0.206403 0.798139 0.034 Uiso 1 1 calc R . . . .
C00K C 0.2561(4) 0.55556(17) 0.65763(16) 0.0325(8) Uani 1 1 d . . . . .
H00K H 0.232254 0.569498 0.696907 0.039 Uiso 1 1 calc R . . . .
C00L C 0.2837(3) 0.39758(15) 0.79060(14) 0.0243(7) Uani 1 1 d . . . . .
C00M C 0.6397(4) 0.49596(16) 0.43422(13) 0.0281(7) Uani 1 1 d . . . . .
H00M H 0.604636 0.539122 0.431384 0.034 Uiso 1 1 calc R . . . .
C00N C 0.1842(4) 0.44824(16) 0.79238(16) 0.0293(7) Uani 1 1 d . . . . .
H00N H 0.185447 0.479016 0.824249 0.035 Uiso 1 1 calc R . . . .
C00O C 0.1541(4) 0.54747(18) 0.61409(16) 0.0348(8) Uani 1 1 d . . . . .
H00O H 0.060982 0.555462 0.623982 0.042 Uiso 1 1 calc R . . . .
C00P C 0.1780(3) 0.35762(15) 0.69499(14) 0.0240(7) Uani 1 1 d . . . . .
C00Q C 0.2801(4) 0.33640(19) 0.59181(16) 0.0378(9) Uani 1 1 d . . . . .
H00B H 0.252572 0.380419 0.579412 0.057 Uiso 1 1 calc GR . . . .
H00C H 0.278437 0.307170 0.556982 0.057 Uiso 1 1 calc GR . . . .
H00D H 0.372963 0.337817 0.608462 0.057 Uiso 1 1 calc GR . . . .
C00R C 0.7594(3) 0.27246(16) 0.82607(14) 0.0291(7) Uani 1 1 d . . . . .
H00R H 0.661981 0.286763 0.821382 0.035 Uiso 1 1 calc R . . . .
C00S C 0.8348(3) 0.61016(17) 0.53387(14) 0.0275(7) Uani 1 1 d . . . . .
H00S H 0.886725 0.572892 0.522693 0.033 Uiso 1 1 calc R . . . .
C00T C 0.6761(4) 0.46227(18) 0.38103(14) 0.0324(8) Uani 1 1 d . . . . .
H00T H 0.665238 0.482965 0.343195 0.039 Uiso 1 1 calc R . . . .
C00U C 0.1894(4) 0.52755(19) 0.55579(16) 0.0346(8) Uani 1 1 d . . . . .
H00U H 0.119992 0.521428 0.526493 0.041 Uiso 1 1 calc R . . . .
C00V C 0.7473(3) 0.53032(15) 0.68965(13) 0.0225(6) Uani 1 1 d . . . . .
C00W C 0.1791(3) 0.31066(16) 0.64035(14) 0.0276(7) Uani 1 1 d . . . . .
H00W H 0.213386 0.267223 0.654431 0.033 Uiso 1 1 calc R . . . .
C00X C 0.8208(4) 0.72854(17) 0.54642(15) 0.0332(8) Uani 1 1 d . . . . .
H00X H 0.862229 0.770451 0.544590 0.040 Uiso 1 1 calc R . . . .
C00Y C 0.6484(4) 0.23099(17) 0.57620(14) 0.0368(9) Uani 1 1 d . . . . .
H00E H 0.632952 0.271221 0.599071 0.055 Uiso 1 1 calc GR . . . .
H00G H 0.580298 0.227732 0.544023 0.055 Uiso 1 1 calc GR . . . .
H00H H 0.740490 0.231793 0.558745 0.055 Uiso 1 1 calc GR . . . .
C00Z C 0.4339(3) 0.52414(15) 0.58343(14) 0.0211(6) Uani 1 1 d . . . . .
C010 C 0.6222(4) 0.65912(15) 0.56795(14) 0.0311(7) Uani 1 1 d . . . . .
H010 H 0.529514 0.655351 0.580345 0.037 Uiso 1 1 calc R . . . .
C011 C 0.7280(4) 0.39878(18) 0.38395(15) 0.0333(8) Uani 1 1 d . . . . .
H011 H 0.753910 0.376492 0.348351 0.040 Uiso 1 1 calc R . . . .
C012 C 0.3936(4) 0.39325(16) 0.84060(14) 0.0342(8) Uani 1 1 d . . . . .
H012 H 0.434973 0.348577 0.838822 0.041 Uiso 1 1 calc R . . . .
C013 C 0.0335(4) 0.30032(19) 0.61291(17) 0.0376(9) Uani 1 1 d . . . . .
H01A H -0.031031 0.288760 0.644875 0.056 Uiso 1 1 calc GR . . . .
H01B H 0.036872 0.264977 0.583266 0.056 Uiso 1 1 calc GR . . . .
H01C H 0.003319 0.340720 0.593359 0.056 Uiso 1 1 calc GR . . . .
C014 C 0.0817(3) 0.40888(17) 0.69937(15) 0.0294(8) Uani 1 1 d . . . . .
H014 H 0.013906 0.413432 0.669123 0.035 Uiso 1 1 calc R . . . .
C015 C 0.3290(3) 0.51653(17) 0.54055(14) 0.0280(7) Uani 1 1 d . . . . .
H015 H 0.351823 0.503820 0.500813 0.034 Uiso 1 1 calc R . . . .
C016 C 0.7054(4) 0.40144(17) 0.49322(15) 0.0334(8) Uani 1 1 d . . . . .
H016 H 0.715250 0.379952 0.530732 0.040 Uiso 1 1 calc R . . . .
C017 C 0.0838(4) 0.45314(17) 0.74726(17) 0.0351(8) Uani 1 1 d . . . . .
H017 H 0.016997 0.486750 0.749323 0.042 Uiso 1 1 calc R . . . .
C018 C 0.6524(5) 0.10677(18) 0.58211(17) 0.0447(10) Uani 1 1 d . . . . .
H01D H 0.740862 0.107636 0.561343 0.067 Uiso 1 1 calc GR . . . .
H01E H 0.578444 0.103355 0.552552 0.067 Uiso 1 1 calc GR . . . .
H01F H 0.649153 0.069057 0.609172 0.067 Uiso 1 1 calc GR . . . .
C019 C 0.8960(4) 0.67234(17) 0.53099(15) 0.0331(7) Uani 1 1 d . . . . .
H019 H 0.988580 0.676391 0.518561 0.040 Uiso 1 1 calc R . . . .
C01A C 0.9615(4) 0.15952(17) 0.71861(15) 0.0313(8) Uani 1 1 d . . . . .
H01G H 1.048692 0.139030 0.717542 0.038 Uiso 1 1 calc R . . . .
C01B C 0.7415(4) 0.36821(18) 0.44003(16) 0.0405(9) Uani 1 1 d . . . . .
H01H H 0.775275 0.324774 0.442205 0.049 Uiso 1 1 calc R . . . .
C01C C 0.6834(4) 0.72196(17) 0.56461(17) 0.0375(9) Uani 1 1 d . . . . .
H01I H 0.631490 0.759632 0.574663 0.045 Uiso 1 1 calc R . . . .
C01D C 0.3306(4) 0.40234(18) 0.90457(15) 0.0411(10) Uani 1 1 d . . . . .
H01J H 0.299871 0.447608 0.909411 0.062 Uiso 1 1 calc GR . . . .
H01K H 0.400086 0.392345 0.934969 0.062 Uiso 1 1 calc GR . . . .
H01L H 0.252505 0.372752 0.909433 0.062 Uiso 1 1 calc GR . . . .
C01E C 0.5103(4) 0.4435(2) 0.8306(2) 0.0546(12) Uani 1 1 d . . . . .
H01M H 0.555075 0.434784 0.792041 0.082 Uiso 1 1 calc GR . . . .
H01N H 0.577505 0.439718 0.863042 0.082 Uiso 1 1 calc GR . . . .
H01O H 0.471954 0.487758 0.830303 0.082 Uiso 1 1 calc GR . . . .
C01F C 0.7707(6) 0.2352(2) 0.88604(17) 0.0603(13) Uani 1 1 d . . . . .
H01P H 0.708445 0.197667 0.885551 0.090 Uiso 1 1 calc GR . . . .
H01Q H 0.745901 0.264417 0.919163 0.090 Uiso 1 1 calc GR . . . .
H01R H 0.864981 0.219910 0.891521 0.090 Uiso 1 1 calc GR . . . .
C01G C 0.8496(5) 0.3345(2) 0.8271(2) 0.0684(15) Uani 1 1 d . . . . .
H01S H 0.946163 0.321842 0.830276 0.103 Uiso 1 1 calc GR . . . .
H01T H 0.824470 0.361540 0.861660 0.103 Uiso 1 1 calc GR . . . .
H01U H 0.835450 0.359315 0.790029 0.103 Uiso 1 1 calc GR . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C00D Ag00 P002 174.67(8) . . ?
Si00 P002 Ag00 107.30(4) . . ?
C00V P002 Ag00 101.26(10) . . ?
C00V P002 Si00 96.40(10) . . ?
C007 Si00 P002 106.49(10) . . ?
C00B Si00 P002 104.58(10) . . ?
C00B Si00 C007 108.74(13) . . ?
C00Z Si00 P002 115.60(10) . . ?
C00Z Si00 C007 107.94(14) . . ?
C00Z Si00 C00B 113.14(14) . . ?
C006 N004 C00C 122.9(3) . . ?
C00D N004 C006 111.6(2) . . ?
C00D N004 C00C 125.4(2) . . ?
C009 N005 C00E 121.7(2) . . ?
C00D N005 C009 111.1(2) . . ?
C00D N005 C00E 126.9(2) . . ?
N004 C006 H006 126.7 . . ?
C009 C006 N004 106.6(3) . . ?
C009 C006 H006 126.7 . . ?
C00S C007 Si00 120.1(2) . . ?
C010 C007 Si00 122.6(2) . . ?
C010 C007 C00S 117.1(3) . . ?
N005 C009 H009 126.6 . . ?
C006 C009 N005 106.8(3) . . ?
C006 C009 H009 126.6 . . ?
C00H C00A H00A 107.7 . . ?
C00H C00A C00Y 109.8(3) . . ?
C00H C00A C018 114.3(3) . . ?
C00Y C00A H00A 107.7 . . ?
C018 C00A H00A 107.7 . . ?
C018 C00A C00Y 109.4(3) . . ?
C00M C00B Si00 121.2(2) . . ?
C00M C00B C016 116.8(3) . . ?
C016 C00B Si00 121.7(2) . . ?
C00L C00C N004 118.5(3) . . ?
C00L C00C C00P 123.3(3) . . ?
C00P C00C N004 118.1(3) . . ?
N004 C00D Ag00 128.8(2) . . ?
N004 C00D N005 103.9(2) . . ?
N005 C00D Ag00 127.2(2) . . ?
C00G C00E N005 117.9(3) . . ?
C00G C00E C00H 123.6(3) . . ?
C00H C00E N005 118.3(3) . . ?
C00K C00F H00F 119.6 . . ?
C00K C00F C00Z 120.8(3) . . ?
C00Z C00F H00F 119.6 . . ?
C00E C00G C00R 122.9(3) . . ?
C00J C00G C00E 117.0(3) . . ?
C00J C00G C00R 120.1(3) . . ?
C00E C00H C00A 121.5(3) . . ?
C00I C00H C00A 122.0(3) . . ?
C00I C00H C00E 116.4(3) . . ?
C00H C00I H00I 119.5 . . ?
C01A C00I C00H 121.0(3) . . ?
C01A C00I H00I 119.5 . . ?
C00G C00J H00J 119.5 . . ?
C01A C00J C00G 121.1(3) . . ?
C01A C00J H00J 119.5 . . ?
C00F C00K H00K 120.0 . . ?
C00O C00K C00F 120.0(3) . . ?
C00O C00K H00K 120.0 . . ?
C00C C00L C00N 117.4(3) . . ?
C00C C00L C012 123.0(3) . . ?
C00N C00L C012 119.7(3) . . ?
C00B C00M H00M 119.2 . . ?
C00T C00M C00B 121.6(3) . . ?
C00T C00M H00M 119.2 . . ?
C00L C00N H00N 119.7 . . ?
C017 C00N C00L 120.5(3) . . ?
C017 C00N H00N 119.7 . . ?
C00K C00O H00O 120.0 . . ?
C00K C00O C00U 120.0(3) . . ?
C00U C00O H00O 120.0 . . ?
C00C C00P C00W 122.0(3) . . ?
C014 C00P C00C 116.7(3) . . ?
C014 C00P C00W 121.3(3) . . ?
H00B C00Q H00C 109.5 . . ?
H00B C00Q H00D 109.5 . . ?
H00C C00Q H00D 109.5 . . ?
C00W C00Q H00B 109.5 . . ?
C00W C00Q H00C 109.5 . . ?
C00W C00Q H00D 109.5 . . ?
C00G C00R H00R 107.7 . . ?
C01F C00R C00G 112.3(3) . . ?
C01F C00R H00R 107.7 . . ?
C01F C00R C01G 110.6(3) . . ?
C01G C00R C00G 110.7(3) . . ?
C01G C00R H00R 107.7 . . ?
C007 C00S H00S 119.2 . . ?
C019 C00S C007 121.6(3) . . ?
C019 C00S H00S 119.2 . . ?
C00M C00T H00T 119.8 . . ?
C011 C00T C00M 120.3(3) . . ?
C011 C00T H00T 119.8 . . ?
C00O C00U H00U 119.9 . . ?
C00O C00U C015 120.2(3) . . ?
C015 C00U H00U 119.9 . . ?
N008 C00V P002 175.6(3) . . ?
C00P C00W C00Q 109.9(3) . . ?
C00P C00W H00W 107.9 . . ?
C00P C00W C013 112.6(3) . . ?
C00Q C00W H00W 107.9 . . ?
C00Q C00W C013 110.5(3) . . ?
C013 C00W H00W 107.9 . . ?
C019 C00X H00X 120.4 . . ?
C019 C00X C01C 119.3(3) . . ?
C01C C00X H00X 120.4 . . ?
C00A C00Y H00E 109.5 . . ?
C00A C00Y H00G 109.5 . . ?
C00A C00Y H00H 109.5 . . ?
H00E C00Y H00G 109.5 . . ?
H00E C00Y H00H 109.5 . . ?
H00G C00Y H00H 109.5 . . ?
C00F C00Z Si00 119.5(2) . . ?
C015 C00Z Si00 122.5(2) . . ?
C015 C00Z C00F 117.9(3) . . ?
C007 C010 H010 119.3 . . ?
C01C C010 C007 121.3(3) . . ?
C01C C010 H010 119.3 . . ?
C00T C011 H011 120.3 . . ?
C00T C011 C01B 119.4(3) . . ?
C01B C011 H011 120.3 . . ?
C00L C012 H012 107.7 . . ?
C00L C012 C01D 112.1(3) . . ?
C00L C012 C01E 111.5(3) . . ?
C01D C012 H012 107.7 . . ?
C01E C012 H012 107.7 . . ?
C01E C012 C01D 109.9(3) . . ?
C00W C013 H01A 109.5 . . ?
C00W C013 H01B 109.5 . . ?
C00W C013 H01C 109.5 . . ?
H01A C013 H01B 109.5 . . ?
H01A C013 H01C 109.5 . . ?
H01B C013 H01C 109.5 . . ?
C00P C014 H014 119.2 . . ?
C017 C014 C00P 121.6(3) . . ?
C017 C014 H014 119.2 . . ?
C00U C015 H015 119.4 . . ?
C00Z C015 C00U 121.1(3) . . ?
C00Z C015 H015 119.4 . . ?
C00B C016 H016 119.4 . . ?
C01B C016 C00B 121.2(3) . . ?
C01B C016 H016 119.4 . . ?
C00N C017 H017 119.7 . . ?
C014 C017 C00N 120.6(3) . . ?
C014 C017 H017 119.7 . . ?
C00A C018 H01D 109.5 . . ?
C00A C018 H01E 109.5 . . ?
C00A C018 H01F 109.5 . . ?
H01D C018 H01E 109.5 . . ?
H01D C018 H01F 109.5 . . ?
H01E C018 H01F 109.5 . . ?
C00S C019 H019 119.8 . . ?
C00X C019 C00S 120.4(3) . . ?
C00X C019 H019 119.8 . . ?
C00I C01A H01G 119.5 . . ?
C00J C01A C00I 120.9(3) . . ?
C00J C01A H01G 119.5 . . ?
C011 C01B C016 120.6(3) . . ?
C011 C01B H01H 119.7 . . ?
C016 C01B H01H 119.7 . . ?
C00X C01C C010 120.2(3) . . ?
C00X C01C H01I 119.9 . . ?
C010 C01C H01I 119.9 . . ?
C012 C01D H01J 109.5 . . ?
C012 C01D H01K 109.5 . . ?
C012 C01D H01L 109.5 . . ?
H01J C01D H01K 109.5 . . ?
H01J C01D H01L 109.5 . . ?
H01K C01D H01L 109.5 . . ?
C012 C01E H01M 109.5 . . ?
C012 C01E H01N 109.5 . . ?
C012 C01E H01O 109.5 . . ?
H01M C01E H01N 109.5 . . ?
H01M C01E H01O 109.5 . . ?
H01N C01E H01O 109.5 . . ?
C00R C01F H01P 109.5 . . ?
C00R C01F H01Q 109.5 . . ?
C00R C01F H01R 109.5 . . ?
H01P C01F H01Q 109.5 . . ?
H01P C01F H01R 109.5 . . ?
H01Q C01F H01R 109.5 . . ?
C00R C01G H01S 109.5 . . ?
C00R C01G H01T 109.5 . . ?
C00R C01G H01U 109.5 . . ?
H01S C01G H01T 109.5 . . ?
H01S C01G H01U 109.5 . . ?
H01T C01G H01U 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag00 P002 2.3758(8) . ?
Ag00 C00D 2.108(3) . ?
P002 Si00 2.2392(11) . ?
P002 C00V 1.778(3) . ?
Si00 C007 1.877(3) . ?
Si00 C00B 1.875(3) . ?
Si00 C00Z 1.872(3) . ?
N004 C006 1.383(4) . ?
N004 C00C 1.451(4) . ?
N004 C00D 1.354(4) . ?
N005 C009 1.389(4) . ?
N005 C00D 1.355(4) . ?
N005 C00E 1.447(4) . ?
C006 H006 0.9300 . ?
C006 C009 1.336(4) . ?
C007 C00S 1.394(4) . ?
C007 C010 1.392(4) . ?
N008 C00V 1.150(4) . ?
C009 H009 0.9300 . ?
C00A H00A 0.9800 . ?
C00A C00H 1.513(4) . ?
C00A C00Y 1.535(4) . ?
C00A C018 1.521(4) . ?
C00B C00M 1.391(4) . ?
C00B C016 1.398(4) . ?
C00C C00L 1.388(4) . ?
C00C C00P 1.400(4) . ?
C00E C00G 1.394(4) . ?
C00E C00H 1.405(4) . ?
C00F H00F 0.9300 . ?
C00F C00K 1.394(5) . ?
C00F C00Z 1.403(4) . ?
C00G C00J 1.392(4) . ?
C00G C00R 1.521(4) . ?
C00H C00I 1.393(4) . ?
C00I H00I 0.9300 . ?
C00I C01A 1.385(5) . ?
C00J H00J 0.9300 . ?
C00J C01A 1.367(5) . ?
C00K H00K 0.9300 . ?
C00K C00O 1.372(5) . ?
C00L C00N 1.392(4) . ?
C00L C012 1.517(4) . ?
C00M H00M 0.9300 . ?
C00M C00T 1.388(4) . ?
C00N H00N 0.9300 . ?
C00N C017 1.379(5) . ?
C00O H00O 0.9300 . ?
C00O C00U 1.376(5) . ?
C00P C00W 1.519(4) . ?
C00P C014 1.384(4) . ?
C00Q H00B 0.9600 . ?
C00Q H00C 0.9600 . ?
C00Q H00D 0.9600 . ?
C00Q C00W 1.524(5) . ?
C00R H00R 0.9800 . ?
C00R C01F 1.511(5) . ?
C00R C01G 1.513(5) . ?
C00S H00S 0.9300 . ?
C00S C019 1.379(5) . ?
C00T H00T 0.9300 . ?
C00T C011 1.368(5) . ?
C00U H00U 0.9300 . ?
C00U C015 1.393(5) . ?
C00W H00W 0.9800 . ?
C00W C013 1.530(5) . ?
C00X H00X 0.9300 . ?
C00X C019 1.379(5) . ?
C00X C01C 1.379(5) . ?
C00Y H00E 0.9600 . ?
C00Y H00G 0.9600 . ?
C00Y H00H 0.9600 . ?
C00Z C015 1.381(4) . ?
C010 H010 0.9300 . ?
C010 C01C 1.391(5) . ?
C011 H011 0.9300 . ?
C011 C01B 1.375(5) . ?
C012 H012 0.9800 . ?
C012 C01D 1.531(5) . ?
C012 C01E 1.519(5) . ?
C013 H01A 0.9600 . ?
C013 H01B 0.9600 . ?
C013 H01C 0.9600 . ?
C014 H014 0.9300 . ?
C014 C017 1.371(5) . ?
C015 H015 0.9300 . ?
C016 H016 0.9300 . ?
C016 C01B 1.382(5) . ?
C017 H017 0.9300 . ?
C018 H01D 0.9600 . ?
C018 H01E 0.9600 . ?
C018 H01F 0.9600 . ?
C019 H019 0.9300 . ?
C01A H01G 0.9300 . ?
C01B H01H 0.9300 . ?
C01C H01I 0.9300 . ?
C01D H01J 0.9600 . ?
C01D H01K 0.9600 . ?
C01D H01L 0.9600 . ?
C01E H01M 0.9600 . ?
C01E H01N 0.9600 . ?
C01E H01O 0.9600 . ?
C01F H01P 0.9600 . ?
C01F H01Q 0.9600 . ?
C01F H01R 0.9600 . ?
C01G H01S 0.9600 . ?
C01G H01T 0.9600 . ?
C01G H01U 0.9600 . ?
