#------------------------------------------------------------------------------
#$Date: 2015-06-05 07:41:20 +0200 (vie 05 de jun de 2015) $
#$Revision: 138289 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/96/1519687.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1519687
loop_
_publ_author_name
'Hasegawa, Yasuchika'
'Sato, Nao'
'Hirai, Yuichi'
'Nakanishi, Takayuki'
'Kitagawa, Yuichi'
'Kobayashi, Atsushi'
'Kato, Masako'
'Seki, Tomohiro'
'Ito, Hajime'
'Fushimi, Koji'
_publ_section_title
;
 Enhanced electric dipole transition in lanthanide complex with
 organometallic ruthenocene units.
;
_journal_issue                   20
_journal_name_full               'The journal of physical chemistry. A'
_journal_page_first              4825
_journal_page_last               4833
_journal_paper_doi               10.1021/acs.jpca.5b01809
_journal_volume                  119
_journal_year                    2015
_chemical_formula_moiety         'C59 H41 Eu F18 O8 P2 Ru2'
_chemical_formula_sum            'C59 H41 Eu F18 O8 P2 Ru2'
_chemical_formula_weight         1635.99
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000(13)
_cell_angle_beta                 93.9113(12)
_cell_angle_gamma                90.000(3)
_cell_formula_units_Z            4
_cell_length_a                   19.8829(6)
_cell_length_b                   17.3599(6)
_cell_length_c                   17.7114(7)
_cell_measurement_reflns_used    25144
_cell_measurement_temperature    123
_cell_measurement_theta_max      27.47
_cell_measurement_theta_min      3.12
_cell_volume                     6099.1(4)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.1'
_computing_publication_material  'CrystalStructure 4.1 (Rigaku, 2014)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      123
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0340
_diffrn_reflns_laue_measured_fraction_full 0.997
_diffrn_reflns_laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            28784
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.473
_diffrn_reflns_theta_min         3.119
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.663
_exptl_absorpt_correction_T_max  0.705
_exptl_absorpt_correction_T_min  0.510
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.782
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3208.00
_exptl_crystal_size_max          0.230
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.210
_refine_diff_density_max         1.54
_refine_diff_density_min         -1.06
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     407
_refine_ls_number_reflns         6962
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0367
_refine_ls_R_factor_gt           0.0328
_refine_ls_shift/su_max          0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0489P)²+19.5899P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0887
_refine_ls_wR_factor_ref         0.0912
_reflns_number_gt                6367
_reflns_number_total             6962
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            jp5b01809_si_002.cif
_cod_data_source_block           EuRcPO
_cod_depositor_comments
'Adding full bibliography for 1519687--1519688.cif.'
_cod_database_code               1519687
loop_
_symmetry_equiv_pos_site_id
_space_group_symop_operation_xyz
1 +X,+Y,+Z
2 -X,+Y,1/2-Z
3 -X,-Y,-Z
4 +X,-Y,1/2+Z
5 1/2+X,1/2+Y,+Z
6 1/2-X,1/2+Y,1/2-Z
7 1/2-X,1/2-Y,-Z
8 1/2+X,1/2-Y,1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.5 0.30260(2) 0.25 0.01864(7) Uani 1 4 d .
Ru2 Ru 0.45339(2) 0.25880(2) 0.56877(2) 0.02376(8) Uani 1 8 d .
P3 P 0.37602(4) 0.24724(4) 0.39004(4) 0.01882(15) Uani 1 8 d .
F27 F 0.65005(19) 0.06941(16) 0.28848(15) 0.0746(10) Uani 1 8 d .
F28 F 0.58789(17) 0.05345(16) 0.3800(2) 0.0772(10) Uani 1 8 d .
F29 F 0.68902(17) 0.08687(18) 0.40129(19) 0.0777(10) Uani 1 8 d .
F38 F 0.37648(19) 0.51432(17) 0.38032(17) 0.0784(11) Uani 1 8 d .
F39 F 0.40091(15) 0.61014(13) 0.3114(2) 0.0657(8) Uani 1 8 d .
F40 F 0.33379(15) 0.52286(19) 0.2682(2) 0.0766(9) Uani 1 8 d .
F42 F 0.7069(5) 0.4027(7) 0.4063(4) 0.335(8) Uani 1 8 d .
F43 F 0.6341(4) 0.4200(4) 0.4676(4) 0.216(4) Uani 1 8 d .
F44 F 0.6972(5) 0.3429(3) 0.4970(5) 0.252(6) Uani 1 8 d .
O20 O 0.43722(12) 0.26327(12) 0.34735(13) 0.0249(5) Uani 1 8 d .
O21 O 0.57939(13) 0.34296(14) 0.35018(14) 0.0339(5) Uani 1 8 d .
O22 O 0.56356(12) 0.19136(12) 0.29975(13) 0.0265(5) Uani 1 8 d .
O46 O 0.44214(13) 0.41649(13) 0.29195(14) 0.0316(5) Uani 1 8 d .
C4 C 0.3089(2) 0.0368(2) 0.4540(2) 0.0373(8) Uani 1 8 d .
C5 C 0.3575(2) -0.0115(2) 0.4278(2) 0.0390(9) Uani 1 8 d .
C6 C 0.4098(2) 0.01764(19) 0.3900(2) 0.0355(8) Uani 1 8 d .
C7 C 0.41527(17) 0.09666(18) 0.37827(18) 0.0270(6) Uani 1 8 d .
C8 C 0.36672(16) 0.14554(17) 0.40451(17) 0.0229(6) Uani 1 8 d .
C9 C 0.31311(17) 0.11563(18) 0.4420(2) 0.0290(7) Uani 1 8 d .
C10 C 0.55971(19) 0.2266(3) 0.5838(2) 0.0404(9) Uani 1 8 d .
C11 C 0.53066(19) 0.2229(2) 0.6553(2) 0.0357(8) Uani 1 8 d .
C12 C 0.47819(19) 0.1667(2) 0.64949(19) 0.0335(7) Uani 1 8 d .
C13 C 0.4747(2) 0.1364(2) 0.5743(2) 0.0364(8) Uani 1 8 d .
C14 C 0.5250(2) 0.1732(3) 0.5341(2) 0.0413(9) Uani 1 8 d .
C15 C 0.34762(17) 0.2838(2) 0.54598(19) 0.0291(7) Uani 1 8 d .
C16 C 0.38329(16) 0.29598(17) 0.47834(17) 0.0227(6) Uani 1 8 d .
C17 C 0.43130(18) 0.35665(18) 0.49420(19) 0.0293(7) Uani 1 8 d .
C18 C 0.4246(2) 0.3816(2) 0.5704(2) 0.0379(8) Uani 1 8 d .
C19 C 0.3735(2) 0.3369(2) 0.6015(2) 0.0380(8) Uani 1 8 d .
C23 C 0.61159(17) 0.1811(2) 0.34759(18) 0.0270(6) Uani 1 8 d .
C24 C 0.6451(2) 0.2356(2) 0.3934(2) 0.0386(8) Uani 1 8 d .
C25 C 0.6260(2) 0.3123(2) 0.3896(2) 0.0378(8) Uani 1 8 d .
C26 C 0.63461(19) 0.0968(2) 0.3547(2) 0.0354(8) Uani 1 8 d .
C30 C 0.30016(16) 0.28067(18) 0.33958(17) 0.0239(6) Uani 1 8 d .
C31 C 0.26711(19) 0.2353(2) 0.2838(2) 0.0339(8) Uani 1 8 d .
C32 C 0.27688(19) 0.3554(2) 0.3518(2) 0.0382(8) Uani 1 8 d .
C33 C 0.2223(2) 0.3840(2) 0.3068(3) 0.0522(11) Uani 1 8 d .
C34 C 0.1910(2) 0.3391(3) 0.2509(3) 0.0456(10) Uani 1 8 d .
C35 C 0.2128(2) 0.2649(3) 0.2397(2) 0.0414(9) Uani 1 8 d .
C36 C 0.44843(18) 0.48724(18) 0.28306(18) 0.0279(7) Uani 1 8 d .
C37 C 0.3905(2) 0.5349(2) 0.3118(3) 0.0423(9) Uani 1 8 d .
C41 C 0.6672(3) 0.3690(3) 0.4401(4) 0.0743(18) Uani 1 8 d .
C45 C 0.5 0.5264(3) 0.25 0.0299(10) Uani 1 4 d .
H4 H 0.27275 0.01618 0.48006 0.0447 Uiso 1 8 calc R
H5 H 0.35462 -0.06547 0.43608 0.0468 Uiso 1 8 calc R
H6 H 0.44252 -0.01625 0.37178 0.0426 Uiso 1 8 calc R
H7 H 0.45179 0.1169 0.35259 0.0324 Uiso 1 8 calc R
H9 H 0.27959 0.14907 0.45923 0.0348 Uiso 1 8 calc R
H10 H 0.59878 0.2594 0.57142 0.0484 Uiso 1 8 calc R
H11 H 0.54586 0.25251 0.70175 0.0428 Uiso 1 8 calc R
H12 H 0.45019 0.14983 0.6913 0.0401 Uiso 1 8 calc R
H13 H 0.44393 0.09443 0.55445 0.0437 Uiso 1 8 calc R
H14 H 0.53562 0.16176 0.48084 0.0496 Uiso 1 8 calc R
H15 H 0.30949 0.24711 0.55142 0.0349 Uiso 1 8 calc R
H17 H 0.46214 0.37925 0.45776 0.0352 Uiso 1 8 calc R
H18 H 0.45107 0.42371 0.59696 0.0454 Uiso 1 8 calc R
H19 H 0.35782 0.34255 0.65365 0.0456 Uiso 1 8 calc R
H24 H 0.6815 0.22025 0.42757 0.0463 Uiso 1 8 calc R
H31 H 0.28179 0.18404 0.27595 0.0407 Uiso 1 8 calc R
H32 H 0.29821 0.38653 0.39053 0.0458 Uiso 1 8 calc R
H33 H 0.20657 0.43481 0.31486 0.0627 Uiso 1 8 calc R
H34 H 0.15429 0.35934 0.21991 0.0547 Uiso 1 8 calc R
H35 H 0.19056 0.23381 0.20158 0.0497 Uiso 1 8 calc R
H45 H 0.50001 0.58117 0.25 0.0358 Uiso 1 4 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(Vol. C, Table 6.1.1.4)
;
Eu Eu -0.1578 3.6682
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
F F 0.0171 0.0103
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.0106 0.0060
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
P P 0.1023 0.0942
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Ru Ru -1.2594 0.8363
;
International Tables for Crystallography
(Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O20 Eu1 O20 145.47(8) yes . 2_655
O20 Eu1 O21 84.01(8) yes . .
O20 Eu1 O21 106.12(8) yes . 2_655
O20 Eu1 O22 77.81(8) yes . .
O20 Eu1 O22 75.03(8) yes . 2_655
O20 Eu1 O46 73.71(8) yes . .
O20 Eu1 O46 139.75(8) yes . 2_655
O20 Eu1 O21 106.15(8) yes 2_655 .
O20 Eu1 O21 84.00(8) yes 2_655 2_655
O20 Eu1 O22 75.01(8) yes 2_655 .
O20 Eu1 O22 77.77(8) yes 2_655 2_655
O20 Eu1 O46 139.78(8) yes 2_655 .
O20 Eu1 O46 73.74(8) yes 2_655 2_655
O21 Eu1 O21 146.02(8) yes . 2_655
O21 Eu1 O22 70.47(8) yes . .
O21 Eu1 O22 142.89(8) yes . 2_655
O21 Eu1 O46 80.62(8) yes . .
O21 Eu1 O46 71.73(8) yes . 2_655
O21 Eu1 O22 142.86(8) yes 2_655 .
O21 Eu1 O22 70.43(8) yes 2_655 2_655
O21 Eu1 O46 71.78(8) yes 2_655 .
O21 Eu1 O46 80.67(8) yes 2_655 2_655
O22 Eu1 O22 75.32(7) yes . 2_655
O22 Eu1 O46 141.10(8) yes . .
O22 Eu1 O46 120.67(8) yes . 2_655
O22 Eu1 O46 120.69(8) yes 2_655 .
O22 Eu1 O46 141.11(8) yes 2_655 2_655
O46 Eu1 O46 71.04(8) yes . 2_655
C10 Ru2 C11 38.14(15) yes . .
C10 Ru2 C12 63.79(15) yes . .
C10 Ru2 C13 63.85(16) yes . .
C10 Ru2 C14 38.15(15) yes . .
C10 Ru2 C15 175.12(14) yes . .
C10 Ru2 C16 137.76(14) yes . .
C10 Ru2 C17 115.28(15) yes . .
C10 Ru2 C18 119.66(16) yes . .
C10 Ru2 C19 146.79(15) yes . .
C11 Ru2 C12 38.18(14) yes . .
C11 Ru2 C13 64.10(14) yes . .
C11 Ru2 C14 63.98(14) yes . .
C11 Ru2 C15 144.88(14) yes . .
C11 Ru2 C16 175.76(13) yes . .
C11 Ru2 C17 138.64(14) yes . .
C11 Ru2 C18 115.86(14) yes . .
C11 Ru2 C19 118.50(14) yes . .
C12 Ru2 C13 38.40(13) yes . .
C12 Ru2 C14 63.95(14) yes . .
C12 Ru2 C15 116.37(14) yes . .
C12 Ru2 C16 144.62(13) yes . .
C12 Ru2 C17 175.93(13) yes . .
C12 Ru2 C18 138.32(13) yes . .
C12 Ru2 C19 114.53(14) yes . .
C13 Ru2 C14 38.12(16) yes . .
C13 Ru2 C15 112.97(15) yes . .
C13 Ru2 C16 116.26(13) yes . .
C13 Ru2 C17 145.34(13) yes . .
C13 Ru2 C18 174.80(15) yes . .
C13 Ru2 C19 137.39(15) yes . .
C14 Ru2 C15 137.07(14) yes . .
C14 Ru2 C16 113.44(13) yes . .
C14 Ru2 C17 118.05(14) yes . .
C14 Ru2 C18 147.00(16) yes . .
C14 Ru2 C19 174.48(15) yes . .
C15 Ru2 C16 39.30(13) yes . .
C15 Ru2 C17 64.93(13) yes . .
C15 Ru2 C18 63.80(14) yes . .
C15 Ru2 C19 38.04(13) yes . .
C16 Ru2 C17 38.78(12) yes . .
C16 Ru2 C18 64.21(13) yes . .
C16 Ru2 C19 64.39(12) yes . .
C17 Ru2 C18 38.13(13) yes . .
C17 Ru2 C19 63.84(14) yes . .
C18 Ru2 C19 37.58(15) yes . .
O20 P3 C8 110.41(14) yes . .
O20 P3 C16 109.57(14) yes . .
O20 P3 C30 111.81(14) yes . .
C8 P3 C16 110.26(14) yes . .
C8 P3 C30 107.29(15) yes . .
C16 P3 C30 107.42(15) yes . .
Eu1 O20 P3 158.78(14) yes . .
Eu1 O21 C25 136.0(2) yes . .
Eu1 O22 C23 135.5(2) yes . .
Eu1 O46 C36 135.2(2) yes . .
C5 C4 C9 119.7(4) yes . .
C4 C5 C6 120.6(3) yes . .
C5 C6 C7 120.4(3) yes . .
C6 C7 C8 119.3(3) yes . .
P3 C8 C7 118.2(2) yes . .
P3 C8 C9 121.6(2) yes . .
C7 C8 C9 120.2(3) yes . .
C4 C9 C8 119.8(3) yes . .
Ru2 C10 C11 70.9(2) yes . .
Ru2 C10 C14 70.5(2) yes . .
C11 C10 C14 108.1(3) yes . .
Ru2 C11 C10 70.9(2) yes . .
Ru2 C11 C12 70.7(2) yes . .
C10 C11 C12 107.7(3) yes . .
Ru2 C12 C11 71.2(2) yes . .
Ru2 C12 C13 70.38(19) yes . .
C11 C12 C13 107.9(3) yes . .
Ru2 C13 C12 71.2(2) yes . .
Ru2 C13 C14 71.3(2) yes . .
C12 C13 C14 108.2(3) yes . .
Ru2 C14 C10 71.3(2) yes . .
Ru2 C14 C13 70.6(2) yes . .
C10 C14 C13 108.1(3) yes . .
Ru2 C15 C16 70.01(18) yes . .
Ru2 C15 C19 72.4(2) yes . .
C16 C15 C19 107.7(3) yes . .
Ru2 C16 P3 121.54(16) yes . .
Ru2 C16 C15 70.69(18) yes . .
Ru2 C16 C17 71.67(18) yes . .
P3 C16 C15 130.1(2) yes . .
P3 C16 C17 122.4(2) yes . .
C15 C16 C17 107.5(3) yes . .
Ru2 C17 C16 69.55(17) yes . .
Ru2 C17 C18 72.1(2) yes . .
C16 C17 C18 107.6(3) yes . .
Ru2 C18 C17 69.81(19) yes . .
Ru2 C18 C19 70.8(2) yes . .
C17 C18 C19 108.4(3) yes . .
Ru2 C19 C15 69.6(2) yes . .
Ru2 C19 C18 71.6(2) yes . .
C15 C19 C18 108.8(3) yes . .
O22 C23 C24 127.9(3) yes . .
O22 C23 C26 113.7(3) yes . .
C24 C23 C26 118.3(3) yes . .
C23 C24 C25 120.6(3) yes . .
O21 C25 C24 129.1(4) yes . .
O21 C25 C41 113.6(4) yes . .
C24 C25 C41 117.2(4) yes . .
F27 C26 F28 108.2(3) yes . .
F27 C26 F29 106.1(3) yes . .
F27 C26 C23 110.9(3) yes . .
F28 C26 F29 106.4(3) yes . .
F28 C26 C23 111.3(3) yes . .
F29 C26 C23 113.6(3) yes . .
P3 C30 C31 120.7(3) yes . .
P3 C30 C32 119.8(2) yes . .
C31 C30 C32 119.3(3) yes . .
C30 C31 C35 120.1(3) yes . .
C30 C32 C33 119.6(3) yes . .
C32 C33 C34 120.4(4) yes . .
C33 C34 C35 120.1(4) yes . .
C31 C35 C34 120.3(4) yes . .
O46 C36 C37 114.0(3) yes . .
O46 C36 C45 128.1(4) yes . .
C37 C36 C45 117.9(3) yes . .
F38 C37 F39 108.4(4) yes . .
F38 C37 F40 105.5(4) yes . .
F38 C37 C36 111.8(3) yes . .
F39 C37 F40 106.2(3) yes . .
F39 C37 C36 114.2(3) yes . .
F40 C37 C36 110.3(3) yes . .
F42 C41 F43 103.9(8) yes . .
F42 C41 F44 107.2(8) yes . .
F42 C41 C25 111.9(7) yes . .
F43 C41 F44 100.7(7) yes . .
F43 C41 C25 114.7(6) yes . .
F44 C41 C25 117.0(5) yes . .
C36 C45 C36 121.5(4) yes . 2_655
C5 C4 H4 120.150 no . .
C9 C4 H4 120.160 no . .
C4 C5 H5 119.676 no . .
C6 C5 H5 119.676 no . .
C5 C6 H6 119.795 no . .
C7 C6 H6 119.803 no . .
C6 C7 H7 120.371 no . .
C8 C7 H7 120.374 no . .
C4 C9 H9 120.114 no . .
C8 C9 H9 120.112 no . .
Ru2 C10 H10 125.925 no . .
C11 C10 H10 125.931 no . .
C14 C10 H10 125.917 no . .
Ru2 C11 H11 126.101 no . .
C10 C11 H11 126.098 no . .
C12 C11 H11 126.116 no . .
Ru2 C12 H12 126.012 no . .
C11 C12 H12 126.012 no . .
C13 C12 H12 126.020 no . .
Ru2 C13 H13 125.881 no . .
C12 C13 H13 125.884 no . .
C14 C13 H13 125.875 no . .
Ru2 C14 H14 125.934 no . .
C10 C14 H14 125.927 no . .
C13 C14 H14 125.926 no . .
Ru2 C15 H15 126.118 no . .
C16 C15 H15 126.121 no . .
C19 C15 H15 126.100 no . .
Ru2 C17 H17 126.151 no . .
C16 C17 H17 126.143 no . .
C18 C17 H17 126.151 no . .
Ru2 C18 H18 125.796 no . .
C17 C18 H18 125.798 no . .
C19 C18 H18 125.808 no . .
Ru2 C19 H19 125.604 no . .
C15 C19 H19 125.615 no . .
C18 C19 H19 125.598 no . .
C23 C24 H24 119.687 no . .
C25 C24 H24 119.688 no . .
C30 C31 H31 119.941 no . .
C35 C31 H31 119.936 no . .
C30 C32 H32 120.182 no . .
C33 C32 H32 120.185 no . .
C32 C33 H33 119.777 no . .
C34 C33 H33 119.777 no . .
C33 C34 H34 119.922 no . .
C35 C34 H34 119.930 no . .
C31 C35 H35 119.830 no . .
C34 C35 H35 119.837 no . .
C36 C45 H45 119.231 no . .
C36 C45 H45 119.226 no 2_655 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_2
Eu1 O20 2.300(2) yes .
Eu1 O20 2.300(2) yes 2_655
Eu1 O21 2.398(2) yes .
Eu1 O21 2.397(2) yes 2_655
Eu1 O22 2.439(2) yes .
Eu1 O22 2.440(2) yes 2_655
Eu1 O46 2.429(2) yes .
Eu1 O46 2.429(2) yes 2_655
Ru2 C10 2.185(4) yes .
Ru2 C11 2.185(4) yes .
Ru2 C12 2.178(3) yes .
Ru2 C13 2.167(4) yes .
Ru2 C14 2.175(4) yes .
Ru2 C15 2.158(3) yes .
Ru2 C16 2.149(3) yes .
Ru2 C17 2.177(3) yes .
Ru2 C18 2.207(4) yes .
Ru2 C19 2.196(4) yes .
P3 O20 1.502(3) yes .
P3 C8 1.795(3) yes .
P3 C16 1.776(3) yes .
P3 C30 1.796(3) yes .
F27 C26 1.321(5) yes .
F28 C26 1.299(5) yes .
F29 C26 1.326(5) yes .
F38 C37 1.314(5) yes .
F39 C37 1.322(4) yes .
F40 C37 1.339(5) yes .
F42 C41 1.179(12) yes .
F43 C41 1.223(9) yes .
F44 C41 1.223(10) yes .
O21 C25 1.241(5) yes .
O22 C23 1.246(4) yes .
O46 C36 1.246(4) yes .
C4 C5 1.385(6) yes .
C4 C9 1.388(5) yes .
C5 C6 1.371(6) yes .
C6 C7 1.393(5) yes .
C7 C8 1.389(5) yes .
C8 C9 1.394(5) yes .
C10 C11 1.428(6) yes .
C10 C14 1.425(6) yes .
C11 C12 1.427(5) yes .
C12 C13 1.429(5) yes .
C13 C14 1.418(6) yes .
C15 C16 1.449(5) yes .
C15 C19 1.419(5) yes .
C16 C17 1.436(4) yes .
C17 C18 1.432(5) yes .
C18 C19 1.418(6) yes .
C23 C24 1.388(5) yes .
C23 C26 1.535(5) yes .
C24 C25 1.383(6) yes .
C25 C41 1.531(7) yes .
C30 C31 1.393(5) yes .
C30 C32 1.400(5) yes .
C31 C35 1.387(5) yes .
C32 C33 1.392(6) yes .
C33 C34 1.376(6) yes .
C34 C35 1.378(6) yes .
C36 C37 1.533(5) yes .
C36 C45 1.392(4) yes .
C4 H4 0.950 no .
C5 H5 0.950 no .
C6 H6 0.950 no .
C7 H7 0.950 no .
C9 H9 0.950 no .
C10 H10 1.000 no .
C11 H11 1.000 no .
C12 H12 1.000 no .
C13 H13 1.000 no .
C14 H14 1.000 no .
C15 H15 1.000 no .
C17 H17 1.000 no .
C18 H18 1.000 no .
C19 H19 1.000 no .
C24 H24 0.950 no .
C31 H31 0.950 no .
C32 H32 0.950 no .
C33 H33 0.950 no .
C34 H34 0.950 no .
C35 H35 0.950 no .
C45 H45 0.951 no .
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_publ_flag
_geom_contact_site_symmetry_2
Eu1 C23 3.442(3) no 2_655
Eu1 C25 3.402(4) no 2_655
Eu1 C36 3.428(3) no 2_655
F27 O22 2.743(4) no .
F27 C6 3.422(5) no 2_655
F27 C7 3.179(4) no 2_655
F27 C24 3.438(5) no .
F27 C31 3.596(5) no 2_655
F28 O22 2.809(4) no .
F28 C7 3.511(5) no .
F28 C24 3.364(5) no .
F29 O22 3.483(4) no .
F29 C24 2.727(5) no .
F38 O46 2.705(4) no .
F38 C17 3.527(4) no .
F38 C32 3.413(5) no .
F38 C45 3.489(4) no .
F39 O46 3.483(3) no .
F39 C45 2.733(4) no .
F40 O46 2.846(4) no .
F40 C32 3.485(5) no .
F40 C33 3.376(5) no .
F40 C45 3.343(3) no .
F42 O21 2.855(10) no .
F42 C24 3.152(12) no .
F43 O21 2.645(8) no .
F43 C24 3.474(8) no .
F44 O21 3.380(9) no .
F44 C24 2.768(8) no .
O20 C7 2.981(4) no .
O20 C17 3.075(4) no .
O20 C31 3.525(4) no .
O20 C32 3.573(4) no .
O21 C23 2.884(4) no .
O21 C36 3.459(4) no 2_655
O22 C25 2.866(4) no .
O46 C36 2.898(4) no 2_655
C4 C7 2.782(5) no .
C5 C8 2.766(5) no .
C6 C9 2.771(5) no .
C8 C13 3.577(5) no .
C8 C15 3.510(5) no .
C8 C31 3.216(5) no .
C9 C15 3.496(5) no .
C9 C16 3.471(4) no .
C9 C30 3.390(4) no .
C9 C31 3.556(5) no .
C16 C32 3.149(5) no .
C23 C31 3.589(5) no 2_655
C30 C34 2.782(5) no .
C31 C33 2.770(6) no .
C32 C35 2.774(6) no .
F27 C33 3.530(5) no 5_545
F28 C5 3.576(5) no 3_656
F29 F44 3.048(9) no 7_656
F29 C4 3.341(5) no 3_656
F29 C5 3.479(5) no 3_656
F38 F43 2.946(8) no 3_666
F39 C10 3.450(5) no 3_666
F39 C11 3.240(5) no 3_666
F39 C35 3.587(5) no 6_555
F42 C4 3.165(12) no 5_555
F42 C5 3.343(11) no 5_555
F43 F38 2.946(8) no 3_666
F44 F29 3.048(9) no 7_656
C4 F29 3.341(5) no 3_656
C4 F42 3.165(12) no 5_445
C5 F28 3.576(5) no 3_656
C5 F29 3.479(5) no 3_656
C5 F42 3.343(11) no 5_445
C6 C13 3.553(5) no 3_656
C10 F39 3.450(5) no 3_666
C11 F39 3.240(5) no 3_666
C13 C6 3.553(5) no 3_656
C33 F27 3.530(5) no 5_455
C35 F39 3.588(5) no 6_545
P3 H7 2.8225 no .
P3 H9 2.8985 no .
P3 H15 3.2304 no .
P3 H17 3.0572 no .
P3 H31 2.8782 no .
P3 H32 2.8708 no .
F27 H6 3.5984 no 2_655
F27 H7 3.2139 no 2_655
F27 H31 2.7033 no 2_655
F28 H6 3.1278 no .
F28 H7 2.9311 no .
F28 H14 2.8391 no .
F28 H24 3.5141 no .
F29 H24 2.3688 no .
F38 H17 3.1554 no .
F38 H32 2.7230 no .
F39 H45 2.3689 no .
F40 H32 3.3164 no .
F40 H33 3.1148 no .
F40 H45 3.4925 no .
F42 H24 3.2334 no .
F43 H10 3.4383 no .
F43 H17 3.4843 no .
F44 H10 2.8320 no .
F44 H24 2.4692 no .
O20 H7 2.5583 no .
O20 H14 3.4476 no .
O20 H17 2.8278 no .
O20 H31 3.5372 no .
O21 H17 3.1732 no .
O21 H24 3.1866 no .
O22 H7 2.7872 no .
O22 H7 2.9893 no 2_655
O22 H14 3.3318 no .
O22 H24 3.1864 no .
O22 H31 3.4397 no 2_655
O46 H17 3.0065 no .
O46 H32 3.4914 no .
O46 H45 3.1881 no .
C4 H6 3.2498 no .
C4 H13 3.2755 no .
C5 H7 3.2555 no .
C5 H9 3.2561 no .
C5 H13 3.2937 no .
C6 H4 3.2500 no .
C6 H13 3.2331 no .
C7 H5 3.2543 no .
C7 H9 3.2696 no .
C7 H13 3.1337 no .
C7 H14 3.1167 no .
C7 H31 3.4595 no .
C8 H4 3.2654 no .
C8 H6 3.2582 no .
C8 H13 3.1044 no .
C8 H14 3.5448 no .
C8 H15 3.4034 no .
C8 H31 2.8207 no .
C9 H5 3.2538 no .
C9 H7 3.2719 no .
C9 H13 3.1877 no .
C9 H15 2.9994 no .
C9 H31 3.1924 no .
C10 H12 3.2716 no .
C10 H13 3.2665 no .
C11 H13 3.2743 no .
C11 H14 3.2750 no .
C12 H10 3.2714 no .
C12 H14 3.2710 no .
C13 H10 3.2661 no .
C13 H11 3.2756 no .
C14 H7 3.5730 no .
C14 H11 3.2754 no .
C14 H12 3.2700 no .
C15 H9 3.0632 no .
C15 H17 3.2946 no .
C15 H18 3.2703 no .
C15 H32 3.3690 no .
C16 H9 3.2829 no .
C16 H18 3.2813 no .
C16 H19 3.2815 no .
C16 H32 2.7182 no .
C17 H15 3.2928 no .
C17 H19 3.2760 no .
C17 H32 3.1589 no .
C18 H15 3.2709 no .
C19 H17 3.2765 no .
C23 H7 3.3738 no .
C23 H14 2.9068 no .
C23 H31 3.1491 no 2_655
C24 H10 3.3707 no .
C24 H14 3.0400 no .
C24 H31 3.5364 no 2_655
C25 H10 3.4256 no .
C26 H14 3.2770 no .
C26 H24 2.6397 no .
C26 H31 3.3066 no 2_655
C30 H9 3.1607 no .
C30 H33 3.2712 no .
C30 H35 3.2651 no .
C31 H9 3.4419 no .
C31 H32 3.2701 no .
C31 H34 3.2553 no .
C32 H31 3.2696 no .
C32 H34 3.2595 no .
C33 H35 3.2431 no .
C34 H31 3.2542 no .
C34 H32 3.2589 no .
C35 H33 3.2430 no .
C37 H32 3.5065 no .
C37 H45 2.6280 no .
C41 H10 3.3623 no .
C41 H24 2.6101 no .
H4 H5 2.3322 no .
H4 H9 2.3415 no .
H5 H6 2.3135 no .
H6 H7 2.3452 no .
H7 H14 2.8338 no .
H9 H15 2.4057 no .
H9 H31 3.3053 no .
H10 H11 2.6040 no .
H10 H14 2.5986 no .
H10 H24 3.1987 no .
H11 H12 2.6045 no .
H12 H13 2.6033 no .
H13 H14 2.5908 no .
H14 H24 3.2722 no .
H15 H19 2.5911 no .
H17 H18 2.6074 no .
H17 H32 3.3953 no .
H18 H19 2.5853 no .
H24 H35 3.5429 no 2_655
H31 H35 2.3332 no .
H32 H33 2.3417 no .
H33 H34 2.3216 no .
H34 H35 2.3252 no .
F27 H33 2.6206 no 5_545
F28 H5 3.3841 no 3_656
F28 H13 2.9043 no 3_656
F28 H33 3.3934 no 5_545
F29 H4 2.8234 no 3_656
F29 H5 3.0866 no 3_656
F29 H33 3.0840 no 5_545
F38 H18 3.5902 no 3_666
F39 H10 3.0723 no 3_666
F39 H11 2.6256 no 3_666
F39 H18 3.3147 no 3_666
F39 H19 2.9811 no 4_564
F39 H35 2.8127 no 6_555
F40 H19 3.1514 no 4_564
F42 H4 2.6594 no 5_555
F42 H5 3.0001 no 5_555
F43 H4 3.2176 no 5_555
F43 H18 3.3559 no 3_666
F44 H4 3.3843 no 5_555
F44 H24 2.8910 no 7_656
C5 H34 3.4420 no 6_545
C6 H13 3.5798 no 3_656
C6 H34 3.5548 no 6_545
C9 H15 3.4163 no 7_556
C10 H5 3.3056 no 3_656
C10 H34 3.3086 no 8_555
C10 H35 3.2947 no 8_555
C11 H11 3.0853 no 2_656
C11 H12 2.9988 no 2_656
C11 H34 3.0007 no 8_555
C11 H35 3.3153 no 8_555
C12 H6 3.0869 no 3_656
C12 H11 3.0930 no 2_656
C12 H12 3.0848 no 2_656
C13 H6 2.7850 no 3_656
C14 H5 3.0550 no 3_656
C14 H6 3.2352 no 3_656
C15 H9 2.7804 no 7_556
C15 H15 3.5055 no 7_556
C18 H45 3.4832 no 3_666
C19 H9 3.1687 no 7_556
C26 H33 3.2544 no 5_545
C30 H15 3.0473 no 7_556
C31 H15 3.3967 no 7_556
C31 H19 3.0983 no 7_556
C32 H15 3.0751 no 7_556
C33 H12 3.4822 no 7_556
C33 H15 3.4774 no 7_556
C34 H11 3.3583 no 8_454
C34 H12 3.0595 no 7_556
C35 H11 3.3557 no 8_454
C35 H19 3.0623 no 7_556
C36 H18 3.2131 no 3_666
C37 H18 3.5156 no 3_666
C37 H19 3.5402 no 4_564
C41 H4 3.3516 no 5_555
C45 H18 2.9474 no 3_666
C45 H18 2.9463 no 4_564
H4 F29 2.8234 no 3_656
H4 F42 2.6594 no 5_445
H4 F43 3.2176 no 5_445
H4 F44 3.3843 no 5_445
H4 C41 3.3516 no 5_445
H4 H32 3.2468 no 7_556
H5 F28 3.3841 no 3_656
H5 F29 3.0866 no 3_656
H5 F42 3.0001 no 5_445
H5 C10 3.3056 no 3_656
H5 C14 3.0550 no 3_656
H5 H10 3.4967 no 3_656
H5 H14 3.0463 no 3_656
H5 H34 3.0506 no 6_545
H6 C12 3.0869 no 3_656
H6 C13 2.7850 no 3_656
H6 C14 3.2352 no 3_656
H6 H12 3.3916 no 3_656
H6 H13 2.8707 no 3_656
H6 H34 3.2536 no 6_545
H9 C15 2.7804 no 7_556
H9 C19 3.1687 no 7_556
H9 H15 2.5247 no 7_556
H9 H19 3.2767 no 7_556
H9 H32 3.2273 no 7_556
H10 F39 3.0723 no 3_666
H10 H5 3.4967 no 3_656
H10 H34 3.4613 no 8_555
H10 H35 2.8434 no 8_555
H11 F39 2.6256 no 3_666
H11 C11 3.0849 no 2_656
H11 C12 3.0915 no 2_656
H11 C34 3.3574 no 8_555
H11 C35 3.3555 no 8_555
H11 H11 2.5831 no 2_656
H11 H12 2.5975 no 2_656
H11 H19 3.4650 no 2_656
H11 H34 2.9026 no 8_555
H11 H35 2.8871 no 8_555
H11 H45 3.1634 no 3_666
H12 C11 3.0002 no 2_656
H12 C12 3.0852 no 2_656
H12 C33 3.4822 no 7_556
H12 C34 3.0595 no 7_556
H12 H6 3.3916 no 3_656
H12 H11 2.5991 no 2_656
H12 H12 2.7722 no 2_656
H12 H33 3.4410 no 7_556
H12 H34 2.6943 no 7_556
H13 F28 2.9043 no 3_656
H13 C6 3.5798 no 3_656
H13 H6 2.8707 no 3_656
H14 H5 3.0463 no 3_656
H15 C9 3.4163 no 7_556
H15 C15 3.5055 no 7_556
H15 C30 3.0473 no 7_556
H15 C31 3.3967 no 7_556
H15 C32 3.0751 no 7_556
H15 C33 3.4774 no 7_556
H15 H9 2.5247 no 7_556
H15 H15 2.8872 no 7_556
H15 H32 3.3651 no 7_556
H18 F38 3.5902 no 3_666
H18 F39 3.3147 no 3_666
H18 F43 3.3559 no 3_666
H18 C36 3.2131 no 3_666
H18 C37 3.5156 no 3_666
H18 C45 2.9474 no 3_666
H18 H45 2.8179 no 3_666
H19 F39 2.9821 no 4_565
H19 F40 3.1531 no 4_565
H19 C31 3.0983 no 7_556
H19 C35 3.0623 no 7_556
H19 C37 3.5423 no 4_565
H19 H9 3.2767 no 7_556
H19 H11 3.4634 no 2_656
H19 H31 3.1536 no 7_556
H19 H35 3.0967 no 7_556
H19 H45 3.4644 no 3_666
H24 F44 2.8910 no 7_656
H31 H19 3.1536 no 7_556
H32 H4 3.2468 no 7_556
H32 H9 3.2273 no 7_556
H32 H15 3.3651 no 7_556
H33 F27 2.6206 no 5_455
H33 F28 3.3934 no 5_455
H33 F29 3.0840 no 5_455
H33 C26 3.2544 no 5_455
H33 H12 3.4410 no 7_556
H34 C5 3.4399 no 6_555
H34 C6 3.5527 no 6_555
H34 C10 3.3101 no 8_454
H34 C11 3.0016 no 8_454
H34 H5 3.0491 no 6_555
H34 H6 3.2519 no 6_555
H34 H10 3.4634 no 8_454
H34 H11 2.9033 no 8_454
H34 H12 2.6943 no 7_556
H35 F39 2.8132 no 6_545
H35 C10 3.2940 no 8_454
H35 C11 3.3149 no 8_454
H35 H10 2.8433 no 8_454
H35 H11 2.8870 no 8_454
H35 H19 3.0967 no 7_556
H45 C18 3.4832 no 3_666
H45 C18 3.4826 no 4_564
H45 H11 3.1634 no 3_666
H45 H11 3.1626 no 4_564
H45 H18 2.8179 no 3_666
H45 H18 2.8181 no 4_564
H45 H19 3.4644 no 3_666
H45 H19 3.4636 no 4_564
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O20 Eu1 O20 P3 -105.4(4) no . 2_655 2_655
O20 Eu1 O20 P3 -105.3(4) no 2_655 . .
O20 Eu1 O21 C25 85.7(2) no . . .
O21 Eu1 O20 P3 144.8(4) no . . .
O20 Eu1 O21 C25 -60.6(3) no . 2_655 2_655
O21 Eu1 O20 P3 -2.1(4) no 2_655 . .
O20 Eu1 O22 C23 -92.4(2) no . . .
O22 Eu1 O20 P3 -144.0(4) no . . .
O20 Eu1 O22 C23 109.1(2) no . 2_655 2_655
O22 Eu1 O20 P3 -66.1(4) no 2_655 . .
O20 Eu1 O46 C36 164.3(2) no . . .
O46 Eu1 O20 P3 62.8(4) no . . .
O20 Eu1 O46 C36 -26.1(3) no . 2_655 2_655
O46 Eu1 O20 P3 92.5(4) no 2_655 . .
O20 Eu1 O21 C25 -60.6(3) no 2_655 . .
O21 Eu1 O20 P3 -2.1(4) no . 2_655 2_655
O20 Eu1 O21 C25 85.7(2) no 2_655 2_655 2_655
O21 Eu1 O20 P3 144.8(4) no 2_655 2_655 2_655
O20 Eu1 O22 C23 109.1(2) no 2_655 . .
O22 Eu1 O20 P3 -66.1(4) no . 2_655 2_655
O20 Eu1 O22 C23 -92.4(2) no 2_655 2_655 2_655
O22 Eu1 O20 P3 -144.0(4) no 2_655 2_655 2_655
O20 Eu1 O46 C36 -26.1(3) no 2_655 . .
O46 Eu1 O20 P3 92.5(4) no . 2_655 2_655
O20 Eu1 O46 C36 164.3(2) no 2_655 2_655 2_655
O46 Eu1 O20 P3 62.8(4) no 2_655 2_655 2_655
O21 Eu1 O21 C25 -164.19(19) no . 2_655 2_655
O21 Eu1 O21 C25 -164.19(19) no 2_655 . .
O21 Eu1 O22 C23 -4.5(2) no . . .
O22 Eu1 O21 C25 6.5(2) no . . .
O21 Eu1 O22 C23 166.93(18) no . 2_655 2_655
O22 Eu1 O21 C25 30.4(3) no 2_655 . .
O21 Eu1 O46 C36 77.9(2) no . . .
O46 Eu1 O21 C25 160.1(3) no . . .
O21 Eu1 O46 C36 -82.0(2) no . 2_655 2_655
O46 Eu1 O21 C25 -126.9(3) no 2_655 . .
O21 Eu1 O22 C23 166.94(18) no 2_655 . .
O22 Eu1 O21 C25 30.4(3) no . 2_655 2_655
O21 Eu1 O22 C23 -4.5(2) no 2_655 2_655 2_655
O22 Eu1 O21 C25 6.5(2) no 2_655 2_655 2_655
O21 Eu1 O46 C36 -82.1(2) no 2_655 . .
O46 Eu1 O21 C25 -126.9(3) no . 2_655 2_655
O21 Eu1 O46 C36 77.9(2) no 2_655 2_655 2_655
O46 Eu1 O21 C25 160.1(3) no 2_655 2_655 2_655
O22 Eu1 O22 C23 -169.9(2) no . 2_655 2_655
O22 Eu1 O22 C23 -169.9(2) no 2_655 . .
O22 Eu1 O46 C36 119.8(2) no . . .
O46 Eu1 O22 C23 -48.8(3) no . . .
O22 Eu1 O46 C36 -134.8(2) no . 2_655 2_655
O46 Eu1 O22 C23 48.9(2) no 2_655 . .
O22 Eu1 O46 C36 -134.8(2) no 2_655 . .
O46 Eu1 O22 C23 48.9(2) no . 2_655 2_655
O22 Eu1 O46 C36 119.8(2) no 2_655 2_655 2_655
O46 Eu1 O22 C23 -48.9(3) no 2_655 2_655 2_655
O46 Eu1 O46 C36 4.1(2) no . 2_655 2_655
O46 Eu1 O46 C36 4.1(2) no 2_655 . .
C10 Ru2 C11 C10 -0.00(18) no . . .
C10 Ru2 C11 C12 -117.6(3) no . . .
C11 Ru2 C10 C11 -0.00(17) no . . .
C11 Ru2 C10 C14 118.1(3) no . . .
C10 Ru2 C12 C11 37.61(15) no . . .
C10 Ru2 C12 C13 -80.21(18) no . . .
C12 Ru2 C10 C11 -37.65(15) no . . .
C12 Ru2 C10 C14 80.46(18) no . . .
C10 Ru2 C13 C12 80.07(18) no . . .
C10 Ru2 C13 C14 -37.50(15) no . . .
C13 Ru2 C10 C11 -80.65(18) no . . .
C13 Ru2 C10 C14 37.47(15) no . . .
C10 Ru2 C14 C10 0.00(18) no . . .
C10 Ru2 C14 C13 117.8(3) no . . .
C14 Ru2 C10 C11 -118.1(3) no . . .
C14 Ru2 C10 C14 0.00(18) no . . .
C10 Ru2 C16 P3 48.2(3) no . . .
C10 Ru2 C16 C15 174.01(17) no . . .
C10 Ru2 C16 C17 -69.1(2) no . . .
C16 Ru2 C10 C11 178.27(12) no . . .
C16 Ru2 C10 C14 -63.6(3) no . . .
C10 Ru2 C17 C16 136.02(15) no . . .
C10 Ru2 C17 C18 -106.55(17) no . . .
C17 Ru2 C10 C11 137.95(15) no . . .
C17 Ru2 C10 C14 -103.94(17) no . . .
C10 Ru2 C18 C17 94.03(19) no . . .
C10 Ru2 C18 C19 -147.01(15) no . . .
C18 Ru2 C10 C11 95.02(19) no . . .
C18 Ru2 C10 C14 -146.87(15) no . . .
C10 Ru2 C19 C15 178.8(2) no . . .
C10 Ru2 C19 C18 59.8(3) no . . .
C19 Ru2 C10 C11 57.7(3) no . . .
C19 Ru2 C10 C14 175.79(19) no . . .
C11 Ru2 C12 C11 -0.00(16) no . . .
C11 Ru2 C12 C13 -117.8(3) no . . .
C12 Ru2 C11 C10 117.6(3) no . . .
C12 Ru2 C11 C12 -0.00(15) no . . .
C11 Ru2 C13 C12 37.43(15) no . . .
C11 Ru2 C13 C14 -80.14(17) no . . .
C13 Ru2 C11 C10 79.92(18) no . . .
C13 Ru2 C11 C12 -37.64(15) no . . .
C11 Ru2 C14 C10 -37.32(15) no . . .
C11 Ru2 C14 C13 80.49(17) no . . .
C14 Ru2 C11 C10 37.32(16) no . . .
C14 Ru2 C11 C12 -80.23(18) no . . .
C11 Ru2 C15 C16 178.89(18) no . . .
C11 Ru2 C15 C19 61.9(3) no . . .
C15 Ru2 C11 C10 173.57(17) no . . .
C15 Ru2 C11 C12 56.0(3) no . . .
C11 Ru2 C17 C16 174.77(16) no . . .
C11 Ru2 C17 C18 -67.8(2) no . . .
C17 Ru2 C11 C10 -66.4(3) no . . .
C17 Ru2 C11 C12 176.03(14) no . . .
C11 Ru2 C18 C17 137.16(15) no . . .
C11 Ru2 C18 C19 -103.87(17) no . . .
C18 Ru2 C11 C10 -105.86(17) no . . .
C18 Ru2 C11 C12 136.59(16) no . . .
C11 Ru2 C19 C15 -144.74(15) no . . .
C11 Ru2 C19 C18 96.21(17) no . . .
C19 Ru2 C11 C10 -148.22(15) no . . .
C19 Ru2 C11 C12 94.23(18) no . . .
C12 Ru2 C13 C12 0.00(16) no . . .
C12 Ru2 C13 C14 -117.6(3) no . . .
C13 Ru2 C12 C11 117.8(3) no . . .
C13 Ru2 C12 C13 -0.00(18) no . . .
C12 Ru2 C14 C10 -80.01(17) no . . .
C12 Ru2 C14 C13 37.80(14) no . . .
C14 Ru2 C12 C11 80.31(17) no . . .
C14 Ru2 C12 C13 -37.52(15) no . . .
C12 Ru2 C15 C16 -146.21(13) no . . .
C12 Ru2 C15 C19 96.79(16) no . . .
C15 Ru2 C12 C11 -147.83(14) no . . .
C15 Ru2 C12 C13 94.34(17) no . . .
C12 Ru2 C16 P3 -66.4(3) no . . .
C12 Ru2 C16 C15 59.4(2) no . . .
C12 Ru2 C16 C17 176.29(17) no . . .
C16 Ru2 C12 C11 174.68(15) no . . .
C16 Ru2 C12 C13 56.9(3) no . . .
C12 Ru2 C18 C17 176.88(15) no . . .
C12 Ru2 C18 C19 -64.2(3) no . . .
C18 Ru2 C12 C11 -68.4(3) no . . .
C18 Ru2 C12 C13 173.72(17) no . . .
C12 Ru2 C19 C15 -102.08(16) no . . .
C12 Ru2 C19 C18 138.87(14) no . . .
C19 Ru2 C12 C11 -105.56(16) no . . .
C19 Ru2 C12 C13 136.61(15) no . . .
C13 Ru2 C14 C10 -117.8(3) no . . .
C13 Ru2 C14 C13 0.00(15) no . . .
C14 Ru2 C13 C12 117.6(3) no . . .
C14 Ru2 C13 C14 0.00(16) no . . .
C13 Ru2 C15 C16 -103.93(16) no . . .
C13 Ru2 C15 C19 139.07(14) no . . .
C15 Ru2 C13 C12 -104.00(17) no . . .
C15 Ru2 C13 C14 138.43(14) no . . .
C13 Ru2 C16 P3 -31.0(2) no . . .
C13 Ru2 C16 C15 94.84(16) no . . .
C13 Ru2 C16 C17 -148.27(14) no . . .
C16 Ru2 C13 C12 -147.28(14) no . . .
C16 Ru2 C13 C14 95.15(17) no . . .
C13 Ru2 C17 C16 56.1(3) no . . .
C13 Ru2 C17 C18 173.5(2) no . . .
C17 Ru2 C13 C12 177.32(17) no . . .
C17 Ru2 C13 C14 59.7(3) no . . .
C13 Ru2 C19 C15 -63.0(2) no . . .
C13 Ru2 C19 C18 177.94(14) no . . .
C19 Ru2 C13 C12 -67.4(2) no . . .
C19 Ru2 C13 C14 175.04(14) no . . .
C14 Ru2 C15 C16 -67.0(2) no . . .
C14 Ru2 C15 C19 176.04(16) no . . .
C15 Ru2 C14 C10 178.42(14) no . . .
C15 Ru2 C14 C13 -63.8(2) no . . .
C14 Ru2 C16 P3 11.1(2) no . . .
C14 Ru2 C16 C15 136.92(15) no . . .
C14 Ru2 C16 C17 -106.19(16) no . . .
C16 Ru2 C14 C10 138.98(14) no . . .
C16 Ru2 C14 C13 -103.22(16) no . . .
C14 Ru2 C17 C16 93.22(18) no . . .
C14 Ru2 C17 C18 -149.34(15) no . . .
C17 Ru2 C14 C10 96.02(17) no . . .
C17 Ru2 C14 C13 -146.18(14) no . . .
C14 Ru2 C18 C17 55.7(3) no . . .
C14 Ru2 C18 C19 174.68(19) no . . .
C18 Ru2 C14 C10 60.7(3) no . . .
C18 Ru2 C14 C13 178.50(18) no . . .
C15 Ru2 C16 P3 -125.8(3) no . . .
C15 Ru2 C16 C15 -0.00(15) no . . .
C15 Ru2 C16 C17 116.9(2) no . . .
C16 Ru2 C15 C16 0.00(12) no . . .
C16 Ru2 C15 C19 -117.0(2) no . . .
C15 Ru2 C17 C16 -38.59(13) no . . .
C15 Ru2 C17 C18 78.84(16) no . . .
C17 Ru2 C15 C16 38.07(13) no . . .
C17 Ru2 C15 C19 -78.93(15) no . . .
C15 Ru2 C18 C17 -82.07(17) no . . .
C15 Ru2 C18 C19 36.90(14) no . . .
C18 Ru2 C15 C16 80.54(16) no . . .
C18 Ru2 C15 C19 -36.46(14) no . . .
C15 Ru2 C19 C15 -0.00(15) no . . .
C15 Ru2 C19 C18 -119.1(3) no . . .
C19 Ru2 C15 C16 117.0(3) no . . .
C19 Ru2 C15 C19 -0.00(16) no . . .
C16 Ru2 C17 C16 0.00(13) no . . .
C16 Ru2 C17 C18 117.4(2) no . . .
C17 Ru2 C16 P3 117.3(3) no . . .
C17 Ru2 C16 C15 -116.9(2) no . . .
C17 Ru2 C16 C17 0.00(15) no . . .
C16 Ru2 C18 C17 -38.12(14) no . . .
C16 Ru2 C18 C19 80.84(16) no . . .
C18 Ru2 C16 P3 154.8(2) no . . .
C18 Ru2 C16 C15 -79.40(15) no . . .
C18 Ru2 C16 C17 37.49(14) no . . .
C16 Ru2 C19 C15 38.74(13) no . . .
C16 Ru2 C19 C18 -80.31(15) no . . .
C19 Ru2 C16 P3 -163.3(2) no . . .
C19 Ru2 C16 C15 -37.51(14) no . . .
C19 Ru2 C16 C17 79.39(15) no . . .
C17 Ru2 C18 C17 -0.00(15) no . . .
C17 Ru2 C18 C19 119.0(3) no . . .
C18 Ru2 C17 C16 -117.4(3) no . . .
C18 Ru2 C17 C18 -0.00(17) no . . .
C17 Ru2 C19 C15 82.05(16) no . . .
C17 Ru2 C19 C18 -37.01(13) no . . .
C19 Ru2 C17 C16 -80.95(16) no . . .
C19 Ru2 C17 C18 36.48(14) no . . .
C18 Ru2 C19 C15 119.1(3) no . . .
C18 Ru2 C19 C18 0.00(16) no . . .
C19 Ru2 C18 C17 -119.0(3) no . . .
C19 Ru2 C18 C19 -0.00(15) no . . .
O20 P3 C8 C7 1.8(2) no . . .
O20 P3 C8 C9 -179.15(19) no . . .
C8 P3 O20 Eu1 114.4(4) no . . .
O20 P3 C16 Ru2 -71.8(2) no . . .
O20 P3 C16 C15 -162.3(2) no . . .
O20 P3 C16 C17 15.5(3) no . . .
C16 P3 O20 Eu1 -124.0(4) no . . .
O20 P3 C30 C31 84.1(2) no . . .
O20 P3 C30 C32 -90.6(2) no . . .
C30 P3 O20 Eu1 -5.0(4) no . . .
C8 P3 C16 Ru2 50.0(2) no . . .
C8 P3 C16 C15 -40.6(3) no . . .
C8 P3 C16 C17 137.2(2) no . . .
C16 P3 C8 C7 -119.4(2) no . . .
C16 P3 C8 C9 59.6(3) no . . .
C8 P3 C30 C31 -37.1(3) no . . .
C8 P3 C30 C32 148.2(2) no . . .
C30 P3 C8 C7 123.9(2) no . . .
C30 P3 C8 C9 -57.1(2) no . . .
C16 P3 C30 C31 -155.7(2) no . . .
C16 P3 C30 C32 29.6(3) no . . .
C30 P3 C16 Ru2 166.56(17) no . . .
C30 P3 C16 C15 76.0(3) no . . .
C30 P3 C16 C17 -106.2(2) no . . .
Eu1 O21 C25 C24 -7.0(6) no . . .
Eu1 O21 C25 C41 172.59(17) no . . .
Eu1 O22 C23 C24 2.7(5) no . . .
Eu1 O22 C23 C26 -177.38(15) no . . .
Eu1 O46 C36 C37 170.52(16) no . . .
Eu1 O46 C36 C45 -8.4(5) no . . .
C5 C4 C9 C8 -0.8(5) no . . .
C9 C4 C5 C6 -0.1(6) no . . .
C4 C5 C6 C7 0.8(6) no . . .
C5 C6 C7 C8 -0.7(5) no . . .
C6 C7 C8 P3 178.9(3) no . . .
C6 C7 C8 C9 -0.2(4) no . . .
P3 C8 C9 C4 -178.1(2) no . . .
C7 C8 C9 C4 0.9(5) no . . .
Ru2 C10 C11 Ru2 0.0 no . . .
Ru2 C10 C11 C12 61.4(2) no . . .
Ru2 C10 C14 Ru2 0.0 no . . .
Ru2 C10 C14 C13 -61.4(2) no . . .
C11 C10 C14 Ru2 61.3(3) no . . .
C11 C10 C14 C13 -0.1(4) no . . .
C14 C10 C11 Ru2 -61.1(3) no . . .
C14 C10 C11 C12 0.4(4) no . . .
Ru2 C11 C12 Ru2 -0.000(10) no . . .
Ru2 C11 C12 C13 61.1(2) no . . .
C10 C11 C12 Ru2 -61.6(3) no . . .
C10 C11 C12 C13 -0.5(4) no . . .
Ru2 C12 C13 Ru2 -0.000(11) no . . .
Ru2 C12 C13 C14 62.1(2) no . . .
C11 C12 C13 Ru2 -61.6(3) no . . .
C11 C12 C13 C14 0.5(4) no . . .
Ru2 C13 C14 Ru2 0.0 no . . .
Ru2 C13 C14 C10 61.8(2) no . . .
C12 C13 C14 Ru2 -62.0(3) no . . .
C12 C13 C14 C10 -0.2(4) no . . .
Ru2 C15 C16 Ru2 0.000(10) no . . .
Ru2 C15 C16 P3 115.4(3) no . . .
Ru2 C15 C16 C17 -62.61(17) no . . .
Ru2 C15 C19 Ru2 0.000(10) no . . .
Ru2 C15 C19 C18 61.2(2) no . . .
C16 C15 C19 Ru2 -61.5(2) no . . .
C16 C15 C19 C18 -0.3(4) no . . .
C19 C15 C16 Ru2 63.0(2) no . . .
C19 C15 C16 P3 178.5(3) no . . .
C19 C15 C16 C17 0.4(3) no . . .
Ru2 C16 C17 Ru2 0.000(11) no . . .
Ru2 C16 C17 C18 -62.38(18) no . . .
P3 C16 C17 Ru2 -116.3(2) no . . .
P3 C16 C17 C18 -178.64(18) no . . .
C15 C16 C17 Ru2 62.0(2) no . . .
C15 C16 C17 C18 -0.4(3) no . . .
Ru2 C17 C18 Ru2 0.000(11) no . . .
Ru2 C17 C18 C19 -60.5(2) no . . .
C16 C17 C18 Ru2 60.8(2) no . . .
C16 C17 C18 C19 0.2(4) no . . .
Ru2 C18 C19 Ru2 -0.0 no . . .
Ru2 C18 C19 C15 -59.9(2) no . . .
C17 C18 C19 Ru2 59.9(3) no . . .
C17 C18 C19 C15 0.0(4) no . . .
O22 C23 C24 C25 0.5(6) no . . .
O22 C23 C26 F27 55.7(4) no . . .
O22 C23 C26 F28 -64.9(4) no . . .
O22 C23 C26 F29 175.0(3) no . . .
C24 C23 C26 F27 -124.4(3) no . . .
C24 C23 C26 F28 115.1(3) no . . .
C24 C23 C26 F29 -5.0(5) no . . .
C26 C23 C24 C25 -179.4(3) no . . .
C23 C24 C25 O21 1.6(7) no . . .
C23 C24 C25 C41 -178.0(3) no . . .
O21 C25 C41 F42 -80.0(5) no . . .
O21 C25 C41 F43 38.1(6) no . . .
O21 C25 C41 F44 155.8(4) no . . .
C24 C25 C41 F42 99.7(5) no . . .
C24 C25 C41 F43 -142.3(4) no . . .
C24 C25 C41 F44 -24.5(7) no . . .
P3 C30 C31 C35 -173.1(2) no . . .
P3 C30 C32 C33 173.1(2) no . . .
C31 C30 C32 C33 -1.7(5) no . . .
C32 C30 C31 C35 1.6(5) no . . .
C30 C31 C35 C34 -0.3(6) no . . .
C30 C32 C33 C34 0.3(6) no . . .
C32 C33 C34 C35 1.1(7) no . . .
C33 C34 C35 C31 -1.1(6) no . . .
O46 C36 C37 F38 48.2(4) no . . .
O46 C36 C37 F39 171.8(3) no . . .
O46 C36 C37 F40 -68.8(4) no . . .
O46 C36 C45 C36 4.2(4) no . . 2_655
C37 C36 C45 C36 -174.7(2) no . . 2_655
C45 C36 C37 F38 -132.7(3) no . . .
C45 C36 C37 F39 -9.1(4) no . . .
C45 C36 C37 F40 110.3(3) no . . .
