#------------------------------------------------------------------------------
#$Date: 2016-09-16 13:55:27 +0200 (vie 16 de sep de 2016) $
#$Revision: 186592 $
#$URL: svn://www.crystallography.net/cod/cif/1/53/74/1537456.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1537456
loop_
_publ_author_name
'Iusenko, K.V.'
'Romanenko, G.V.'
'Gromilov, S.A.'
'Korenev, S.V.'
'Baidina, I.A.'
'Korol'kov, I.V.'
_publ_section_title
;
 Double complex salts (Rh (N H3)5 Cl)2 (M Cl6) Cl2 (M= Re, Os): synthesis
 and crystal structure
;
_journal_name_full               'Zhurnal Neorganicheskoi Khimii'
_journal_page_first              568
_journal_page_last               573
_journal_volume                  49
_journal_year                    2004
_chemical_formula_sum            'Cl10 H30 N10 Os Rh2'
_chemical_name_systematic        '(Rh (N H3)5 Cl)2 (Os Cl6) Cl2'
_space_group_IT_number           12
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_cell_angle_alpha                90
_cell_angle_beta                 99.881
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.1946
_cell_length_b                   7.9203
_cell_length_c                   13.3954
_cell_volume                     1170.080
_citation_journal_id_ASTM        ZNOKAQ
_cod_data_source_file            Iusenko_ZNOKAQ_2004_557.cif
_cod_data_source_block           H30Cl10N10Os1Rh2
_cod_original_cell_volume        1170.08
_cod_original_formula_sum        'H30 Cl10 N10 Os1 Rh2'
_cod_database_code               1537456
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,y,-z
-x,-y,-z
x,-y,z
x+1/2,y+1/2,z
-x+1/2,y+1/2,-z
-x+1/2,-y+1/2,-z
x+1/2,-y+1/2,z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_attached_hydrogens
N3 N-3 -0.0027 0.5 0.2869 1 0.0 3
Cl2 Cl-1 -0.0093 0 0.3234 1 0.0 0
Rh1 Rh+3 -0.1719 0.5 0.1984 1 0.0 0
N2 N-3 -0.1158 -0.3154 0.1075 1 0.0 3
Cl3 Cl-1 0 -0.293 0.5 1 0.0 0
Os1 Os+4 0 0 0.5 1 0.0 0
N1 N-3 -0.2329 -0.318 0.2874 1 0.0 3
Cl1 Cl-1 0.2101 0 0.5228 1 0.0 0
Cl4 Cl-1 -0.3636 0.5 0.0969 1 0.0 0
Cl5 Cl-1 0.1765 0.5 0.1243 1 0.0 0
