#------------------------------------------------------------------------------
#$Date: 2022-10-03 16:40:12 +0200 (Mon 03 de Oct de 2022) $
#$Revision: 278324 $
#$URL: svn://www.crystallography.net/cod/cif/2/00/96/2009604.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2009604
loop_
_publ_author_name
'Cai, B.'
'Pan, Y.'
'Qiu, H.'
'Dewan, J. C.'
'Wink, D. J.'
'Murphy, R. B.'
'Schuster, D. I.'
_publ_section_title
;
 Diastereomeric octahydronaphthoquinolizines
;
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              609
_journal_page_last               613
_journal_paper_doi               10.1107/S0108270193009242
_journal_volume                  50
_journal_year                    1994
_chemical_formula_sum            'C16 H22 Cl N O4'
_chemical_formula_weight         327.81
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_type_scat_source           IntTabIV
_cell_angle_alpha                90.
_cell_angle_beta                 97.510(10)
_cell_angle_gamma                90.
_cell_formula_units_Z            4
_cell_length_a                   8.922(2)
_cell_length_b                   11.522(5)
_cell_length_c                   15.734(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    298
_cell_measurement_theta_max      17.4
_cell_measurement_theta_min      15.5
_cell_volume                     1603.6(8)
_diffrn_measurement_device       'Rigaku AFC-6R'
_diffrn_measurement_method       ω/θ
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            2655
_diffrn_reflns_theta_max         59.5
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 250
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.277
_exptl_absorpt_correction_T_max  1.26
_exptl_absorpt_correction_T_min  0.64
_exptl_absorpt_correction_type   'empirical (DIFABS)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.358
_exptl_crystal_description       block
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.23
_refine_diff_density_max         0.28
_refine_diff_density_min         -0.33
_refine_ls_goodness_of_fit_obs   2.59
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     199
_refine_ls_number_reflns         1833
_refine_ls_R_factor_obs          0.066
_refine_ls_shift/esd_max         0.001
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 4Fₒ²/σ²(Fₒ)²'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_obs         0.075
_reflns_number_observed          1833
_reflns_number_total             2477
_reflns_observed_criterion       I>2\s(I)
_cod_data_source_file            cr1066.cif
_cod_data_source_block           cr1066_structure_2_of_3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value '4F~o~^2^/\s^2^(F~o~)^2^' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to 'w =
4F~o~^2^/\s^2^(F~o~)^2^'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1603.5
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_original_formula_sum        'C16 H22 Cl N1 O4'
_cod_database_code               2009604
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x+1/2,y+1/2,-z+1/2
3 -x,-y,-z
4 x+1/2,-y+1/2,z+1/2
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
N4 -.1156(3) -.3311(3) .6225(2) 4.60(10)
C1 .0378(4) -.1069(4) .6407(3) 5.7(2)
C2 .1236(4) -.2199(4) .6308(3) 5.7(2)
C3 .0472(4) -.3220(4) .6651(3) 5.7(2)
C5 -.1894(5) -.4370(4) .6529(3) 5.9(2)
C6 -.3465(5) -.4512(4) .6070(3) 6.4(2)
C7 -.4398(4) -.3456(4) .6202(3) 5.7(2)
C7A -.3665(4) -.2343(3) .5931(2) 4.6(2)
C8 -.4544(4) -.1291(4) .6158(3) 5.3(2)
C8A -.3739(4) -.0140(3) .6105(2) 4.6(2)
C9 -.4576(4) .0872(4) .6121(3) 5.5(2)
C10 -.3905(6) .1939(4) .6116(3) 5.9(2)
C11 -.2377(6) .2008(4) .6088(3) 6.3(2)
C12 -.1524(5) .1019(4) .6062(3) 5.8(2)
C12A -.2197(4) -.0075(3) .6067(2) 4.6(2)
C12B -.1255(4) -.1181(3) .5999(2) 4.6(2)
C12C -.2015(4) -.2209(3) .6357(2) 4.2(2)
Cl11 .18430(10) .34780(10) .62595(7) 5.56(5)
O11 .1131(4) .3715(4) .6983(2) 8.9(2)
O12 .0810(4) .3779(4) .5525(2) 9.0(2)
O13 .2178(4) .2286(3) .6215(3) 10.1(3)
O14 .3192(4) .4081(4) .6278(3) 10.1(2)
H(1) -.1133 -.3396 .5626 ?
H(2) .0401 -.0898 .6999 ?
H(3) .0849 -.0458 .6135 ?
H(4) .1300 -.2323 .5717 ?
H(5) .2225 -.2130 .6611 ?
H(6) .0482 -.3131 .7252 ?
H(7) .1000 -.3907 .6539 ?
H(8) -.1312 -.5033 .6425 ?
H(9) -.1940 -.4302 .7127 ?
H(10) -.3420 -.4612 .5475 ?
H(11) -.3921 -.5175 .6288 ?
H(12) -.5363 -.3538 .5872 ?
H(13) -.4515 -.3401 .6792 ?
H(14) -.3671 -.2359 .5327 ?
H(15) -.5462 -.1262 .5777 ?
H(16) -.4765 -.1384 .6729 ?
H(17) -.5635 .0823 .6136 ?
H(18) -.4492 .2625 .6131 ?
H(19) -.1905 .2747 .6087 ?
H(20) -.0468 .1080 .6041 ?
H(21) -.1239 -.1326 .5406 ?
H(22) -.2017 -.2094 .6955 ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C3 N4 C5 110.5(3) yes
C3 N4 C12C 110.7(3) yes
C5 N4 C12C 112.9(3) yes
C7 C7A C8 110.7(3) yes
C7 C7A C12C 112.5(3) yes
C8 C7A C12C 108.2(3) yes
C7A C8 C8A 115.1(3) yes
C8 C8A C12A 122.0(3) yes
C8A C12A C12B 120.8(3) yes
C1 C12B C12A 113.8(3) yes
C1 C12B C12C 111.2(3) yes
C12A C12B C12C 110.4(3) yes
N4 C12C C7A 109.2(3) yes
N4 C12C C12B 110.3(3) yes
C7A C12C C12B 111.5(3) yes
O11 Cl11 O12 107.3(2) no
O11 Cl11 O13 110.6(2) no
O11 Cl11 O14 111.7(3) no
O12 Cl11 O13 108.4(2) no
O12 Cl11 O14 111.3(3) no
O13 Cl11 O14 107.5(2) no
C2 C1 C12B 110.5(3) no
C1 C2 C3 112.1(4) no
N4 C3 C2 110.5(3) no
N4 C5 C6 110.9(3) no
C5 C6 C7 110.2(4) no
C6 C7 C7A 112.1(3) no
C8 C8A C9 118.3(3) no
C9 C8A C12A 119.7(4) no
C8A C9 C10 121.3(4) no
C9 C10 C11 119.3(4) no
C10 C11 C12 120.6(4) no
C11 C12 C12A 120.6(4) no
C8A C12A C12 118.6(4) no
C12 C12A C12B 120.5(3) no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
N4 C3 1.522(5) yes
N4 C5 1.496(5) yes
N4 C12C 1.511(4) yes
C7A C12C 1.542(5) yes
C12B C12C 1.510(5) yes
C7A C8 1.512(5) yes
C8A C12A 1.386(5) yes
C10 C11 1.372(7) yes
Cl11 O11 1.401(3) no
Cl11 O12 1.423(3) no
Cl11 O13 1.409(4) no
Cl11 O14 1.386(4) no
C1 C2 1.529(6) no
C1 C12B 1.519(5) no
C2 C3 1.495(6) no
C5 C6 1.499(6) no
C6 C7 1.503(6) no
C7 C7A 1.526(5) no
C8 C8A 1.516(5) no
C8A C9 1.386(5) no
C9 C10 1.368(6) no
C11 C12 1.374(6) no
C12 C12A 1.397(6) no
C12A C12B 1.537(5) no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N4 C3 C2 C1 55.6(5)
N4 C5 C6 C7 -58.0(5)
N4 C12C C7A C7 50.9(4)
N4 C12C C7A C8 173.6(3)
N4 C12C C12B C1 -57.3(4)
N4 C12C C12B C12A 175.4(3)
C2 C1 C12B C12A -179.7(3)
C3 C2 C1 C12B -54.5(5)
C7 C7A C8 C8A 166.8(3)
