#------------------------------------------------------------------------------
#$Date: 2016-03-23 20:05:52 +0100 (Wed 23 de Mar de 2016) $
#$Revision: 179439 $
#$URL: svn://www.crystallography.net/cod/cif/4/33/36/4333601.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4333601
loop_
_publ_author_name
'M. Falmbigl'
'F. Kneidinger'
'M. Chen'
'A. Grytsiv'
'H. Michor'
'E. Royanian'
'E. Bauer'
'H. Effenberger'
'R. Podloucky'
'P. Rogl'
_publ_section_title
;
 Cage-Forming Compounds in the Ba-Rh-Ge System: From Thermoelectrics to
 Superconductivity
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              931
_journal_page_last               943
_journal_paper_doi               10.1021/ic302139r
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Ba6 Ge32 Rh8'
_chemical_formula_weight         3970.20
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           139
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   6.564(2)
_cell_length_b                   6.564(2)
_cell_length_c                   22.037(2)
_cell_measurement_temperature    293(2)
_cell_volume                     949.5(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0768
_diffrn_reflns_av_sigmaI/netI    0.0281
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            7402
_diffrn_reflns_theta_full        34.95
_diffrn_reflns_theta_max         34.95
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    34.330
_exptl_crystal_density_diffrn    6.943
_exptl_crystal_F_000             1720
_refine_diff_density_max         2.553
_refine_diff_density_min         -2.179
_refine_diff_density_rms         0.367
_refine_ls_extinction_coef       0.00000(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     26
_refine_ls_number_reflns         672
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.102
_refine_ls_R_factor_all          0.0511
_refine_ls_R_factor_gt           0.0301
_refine_ls_shift/su_max          0.040
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1153
_refine_ls_wR_factor_ref         0.1534
_reflns_number_gt                507
_reflns_number_total             672
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic302139r_si_002_4.cif
_cod_data_source_block           tau2
_cod_original_cell_volume        949.6(4)
_cod_database_code               4333601
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, -z'
'-x, -y, z'
'-x, y, -z'
'y, x, -z'
'y, -x, z'
'-y, x, z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'-x, y, z'
'x, y, -z'
'x, -y, z'
'-y, -x, z'
'-y, x, -z'
'y, -x, -z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'-x+1/2, y+1/2, z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'y+1/2, x+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.24346(12) 0.24346(12) 0.12892(6) 0.0138(3) Uani 1 2 d S
Ge2 Ge 0.2285(2) 0.5000 0.0000 0.0120(4) Uani 1 4 d S
Rh1 Rh 0.0000 0.5000 0.08876(5) 0.0091(3) Uani 1 4 d S
Ge3 Ge 0.0000 0.0000 0.19696(11) 0.0151(5) Uani 1 8 d S
Ge4 Ge 0.0000 0.0000 0.31061(11) 0.0166(5) Uani 1 8 d S
Ba2 Ba 0.0000 0.5000 0.2500 0.0115(3) Uani 1 8 d S
Ba1 Ba 0.0000 0.0000 0.0000 0.0133(4) Uani 1 16 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ba Ba -0.3244 2.2819 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Rh1 Ge1 Rh1 138.17(8) 21_655 .
Rh1 Ge1 Ge3 102.55(3) 21_655 .
Rh1 Ge1 Ge3 102.55(3) . .
Rh1 Ge1 Ge4 98.78(3) 21_655 25
Rh1 Ge1 Ge4 98.78(3) . 25
Ge3 Ge1 Ge4 117.21(8) . 25
Rh1 Ge1 Ba2 69.84(3) 21_655 25
Rh1 Ge1 Ba2 151.79(5) . 25
Ge3 Ge1 Ba2 66.25(4) . 25
Ge4 Ge1 Ba2 67.46(4) 25 25
Rh1 Ge1 Ba2 151.79(5) 21_655 .
Rh1 Ge1 Ba2 69.84(3) . .
Ge3 Ge1 Ba2 66.25(4) . .
Ge4 Ge1 Ba2 67.46(4) 25 .
Ba2 Ge1 Ba2 82.02(3) 25 .
Rh1 Ge1 Ba1 74.72(3) 21_655 .
Rh1 Ge1 Ba1 74.72(3) . .
Ge3 Ge1 Ba1 85.06(5) . .
Ge4 Ge1 Ba1 157.73(6) 25 .
Ba2 Ge1 Ba1 126.95(2) 25 .
Ba2 Ge1 Ba1 126.95(2) . .
Rh1 Ge2 Rh1 105.03(6) 17_565 .
Rh1 Ge2 Ge2 115.49(2) 17_565 21_665
Rh1 Ge2 Ge2 115.49(2) . 21_665
Rh1 Ge2 Ge2 115.49(2) 17_565 5
Rh1 Ge2 Ge2 115.49(2) . 5
Ge2 Ge2 Ge2 90.0 21_665 5
Rh1 Ge2 Ba1 75.35(2) 17_565 .
Rh1 Ge2 Ba1 75.35(2) . .
Ge2 Ge2 Ba1 159.56(2) 21_665 .
Ge2 Ge2 Ba1 69.56(2) 5 .
Rh1 Ge2 Ba1 75.35(2) 17_565 1_565
Rh1 Ge2 Ba1 75.35(2) . 1_565
Ge2 Ge2 Ba1 69.56(2) 21_665 1_565
Ge2 Ge2 Ba1 159.56(2) 5 1_565
Ba1 Ge2 Ba1 130.87(4) . 1_565
Ge2 Rh1 Ge2 74.97(6) 17_565 .
Ge2 Rh1 Ge1 132.38(4) 17_565 20_565
Ge2 Rh1 Ge1 83.75(4) . 20_565
Ge2 Rh1 Ge1 132.38(4) 17_565 .
Ge2 Rh1 Ge1 83.75(4) . .
Ge1 Rh1 Ge1 85.34(5) 20_565 .
Ge2 Rh1 Ge1 83.75(4) 17_565 18
Ge2 Rh1 Ge1 132.38(4) . 18
Ge1 Rh1 Ge1 138.27(8) 20_565 18
Ge1 Rh1 Ge1 80.06(5) . 18
Ge2 Rh1 Ge1 83.75(4) 17_565 3_565
Ge2 Rh1 Ge1 132.38(4) . 3_565
Ge1 Rh1 Ge1 80.06(5) 20_565 3_565
Ge1 Rh1 Ge1 138.27(8) . 3_565
Ge1 Rh1 Ge1 85.34(5) 18 3_565
Ge2 Rh1 Ba2 142.51(3) 17_565 .
Ge2 Rh1 Ba2 142.51(3) . .
Ge1 Rh1 Ba2 69.13(4) 20_565 .
Ge1 Rh1 Ba2 69.13(4) . .
Ge1 Rh1 Ba2 69.13(4) 18 .
Ge1 Rh1 Ba2 69.13(4) 3_565 .
Ge2 Rh1 Ba1 66.03(2) 17_565 .
Ge2 Rh1 Ba1 66.03(2) . .
Ge1 Rh1 Ba1 139.87(3) 20_565 .
Ge1 Rh1 Ba1 66.43(3) . .
Ge1 Rh1 Ba1 66.43(3) 18 .
Ge1 Rh1 Ba1 139.87(3) 3_565 .
Ba2 Rh1 Ba1 120.793(17) . .
Ge2 Rh1 Ba1 66.03(2) 17_565 1_565
Ge2 Rh1 Ba1 66.03(2) . 1_565
Ge1 Rh1 Ba1 66.43(3) 20_565 1_565
Ge1 Rh1 Ba1 139.87(3) . 1_565
Ge1 Rh1 Ba1 139.87(3) 18 1_565
Ge1 Rh1 Ba1 66.43(3) 3_565 1_565
Ba2 Rh1 Ba1 120.793(17) . 1_565
Ba1 Rh1 Ba1 118.41(3) . 1_565
Ge4 Ge3 Ge1 123.56(5) . 3
Ge4 Ge3 Ge1 123.56(5) . 20
Ge1 Ge3 Ge1 72.20(5) 3 20
Ge4 Ge3 Ge1 123.56(5) . 18
Ge1 Ge3 Ge1 72.20(5) 3 18
Ge1 Ge3 Ge1 112.88(10) 20 18
Ge4 Ge3 Ge1 123.56(5) . .
Ge1 Ge3 Ge1 112.88(10) 3 .
Ge1 Ge3 Ge1 72.20(5) 20 .
Ge1 Ge3 Ge1 72.20(5) 18 .
Ge4 Ge3 Ba2 70.40(4) . 25
Ge1 Ge3 Ba2 137.78(2) 3 25
Ge1 Ge3 Ba2 68.31(2) 20 25
Ge1 Ge3 Ba2 137.78(2) 18 25
Ge1 Ge3 Ba2 68.31(2) . 25
Ge4 Ge3 Ba2 70.40(4) . .
Ge1 Ge3 Ba2 137.78(2) 3 .
Ge1 Ge3 Ba2 137.78(2) 20 .
Ge1 Ge3 Ba2 68.31(2) 18 .
Ge1 Ge3 Ba2 68.31(2) . .
Ba2 Ge3 Ba2 83.54(2) 25 .
Ge4 Ge3 Ba2 70.40(4) . 1_545
Ge1 Ge3 Ba2 68.31(2) 3 1_545
Ge1 Ge3 Ba2 68.31(2) 20 1_545
Ge1 Ge3 Ba2 137.78(2) 18 1_545
Ge1 Ge3 Ba2 137.78(2) . 1_545
Ba2 Ge3 Ba2 83.54(2) 25 1_545
Ba2 Ge3 Ba2 140.80(7) . 1_545
Ge4 Ge3 Ba2 70.40(4) . 25_455
Ge1 Ge3 Ba2 68.31(2) 3 25_455
Ge1 Ge3 Ba2 137.78(2) 20 25_455
Ge1 Ge3 Ba2 68.31(2) 18 25_455
Ge1 Ge3 Ba2 137.78(2) . 25_455
Ba2 Ge3 Ba2 140.80(7) 25 25_455
Ba2 Ge3 Ba2 83.54(2) . 25_455
Ba2 Ge3 Ba2 83.54(2) 1_545 25_455
Ge3 Ge4 Ge1 119.23(5) . 25
Ge3 Ge4 Ge1 119.23(5) . 27_445
Ge1 Ge4 Ge1 121.54(10) 25 27_445
Ge3 Ge4 Ge1 119.23(5) . 12_545
Ge1 Ge4 Ge1 76.21(5) 25 12_545
Ge1 Ge4 Ge1 76.21(5) 27_445 12_545
Ge3 Ge4 Ge1 119.23(5) . 10_455
Ge1 Ge4 Ge1 76.21(5) 25 10_455
Ge1 Ge4 Ge1 76.21(5) 27_445 10_455
Ge1 Ge4 Ge1 121.54(10) 12_545 10_455
Ge3 Ge4 Ba2 67.86(4) . 25_455
Ge1 Ge4 Ba2 139.079(12) 25 25_455
Ge1 Ge4 Ba2 67.20(2) 27_445 25_455
Ge1 Ge4 Ba2 139.079(12) 12_545 25_455
Ge1 Ge4 Ba2 67.20(2) 10_455 25_455
Ge3 Ge4 Ba2 67.86(4) . 1_545
Ge1 Ge4 Ba2 139.079(12) 25 1_545
Ge1 Ge4 Ba2 67.20(2) 27_445 1_545
Ge1 Ge4 Ba2 67.20(2) 12_545 1_545
Ge1 Ge4 Ba2 139.079(12) 10_455 1_545
Ba2 Ge4 Ba2 81.83(3) 25_455 1_545
Ge3 Ge4 Ba2 67.86(4) . 25
Ge1 Ge4 Ba2 67.20(2) 25 25
Ge1 Ge4 Ba2 139.079(12) 27_445 25
Ge1 Ge4 Ba2 67.20(2) 12_545 25
Ge1 Ge4 Ba2 139.079(12) 10_455 25
Ba2 Ge4 Ba2 135.71(7) 25_455 25
Ba2 Ge4 Ba2 81.83(3) 1_545 25
Ge3 Ge4 Ba2 67.86(4) . .
Ge1 Ge4 Ba2 67.20(2) 25 .
Ge1 Ge4 Ba2 139.079(12) 27_445 .
Ge1 Ge4 Ba2 139.079(12) 12_545 .
Ge1 Ge4 Ba2 67.20(2) 10_455 .
Ba2 Ge4 Ba2 81.83(3) 25_455 .
Ba2 Ge4 Ba2 135.71(7) 1_545 .
Ba2 Ge4 Ba2 81.83(3) 25 .
Ge3 Ba2 Ge3 96.46(2) 25 .
Ge3 Ba2 Ge3 140.80(7) 25 25_455
Ge3 Ba2 Ge3 96.46(2) . 25_455
Ge3 Ba2 Ge3 96.46(2) 25 1_565
Ge3 Ba2 Ge3 140.80(7) . 1_565
Ge3 Ba2 Ge3 96.46(2) 25_455 1_565
Ge3 Ba2 Ge1 45.44(3) 25 12
Ge3 Ba2 Ge1 132.75(3) . 12
Ge3 Ba2 Ge1 101.27(4) 25_455 12
Ge3 Ba2 Ge1 80.06(4) 1_565 12
Ge3 Ba2 Ge1 132.75(3) 25 18
Ge3 Ba2 Ge1 45.44(3) . 18
Ge3 Ba2 Ge1 80.06(4) 25_455 18
Ge3 Ba2 Ge1 101.27(4) 1_565 18
Ge1 Ba2 Ge1 178.03(4) 12 18
Ge3 Ba2 Ge1 45.44(3) 25 25
Ge3 Ba2 Ge1 80.06(4) . 25
Ge3 Ba2 Ge1 101.27(4) 25_455 25
Ge3 Ba2 Ge1 132.75(3) 1_565 25
Ge1 Ba2 Ge1 53.72(3) 12 25
Ge1 Ba2 Ge1 124.69(2) 18 25
Ge3 Ba2 Ge1 101.27(4) 25 27_455
Ge3 Ba2 Ge1 132.75(3) . 27_455
Ge3 Ba2 Ge1 45.44(3) 25_455 27_455
Ge3 Ba2 Ge1 80.06(4) 1_565 27_455
Ge1 Ba2 Ge1 56.87(4) 12 27_455
Ge1 Ba2 Ge1 124.69(2) 18 27_455
Ge1 Ba2 Ge1 82.05(3) 25 27_455
Ge3 Ba2 Ge1 132.75(3) 25 3_565
Ge3 Ba2 Ge1 101.27(4) . 3_565
Ge3 Ba2 Ge1 80.06(4) 25_455 3_565
Ge3 Ba2 Ge1 45.44(3) 1_565 3_565
Ge1 Ba2 Ge1 124.69(2) 12 3_565
Ge1 Ba2 Ge1 56.87(4) 18 3_565
Ge1 Ba2 Ge1 178.03(4) 25 3_565
Ge1 Ba2 Ge1 97.98(3) 27_455 3_565
Ge3 Ba2 Ge1 80.06(4) 25 20_565
Ge3 Ba2 Ge1 101.27(4) . 20_565
Ge3 Ba2 Ge1 132.75(3) 25_455 20_565
Ge3 Ba2 Ge1 45.44(3) 1_565 20_565
Ge1 Ba2 Ge1 97.98(3) 12 20_565
Ge1 Ba2 Ge1 82.05(3) 18 20_565
Ge1 Ba2 Ge1 124.69(2) 25 20_565
Ge1 Ba2 Ge1 124.69(2) 27_455 20_565
Ge1 Ba2 Ge1 53.72(3) 3_565 20_565
Ge3 Ba2 Ge1 101.27(4) 25 10_455
Ge3 Ba2 Ge1 80.06(4) . 10_455
Ge3 Ba2 Ge1 45.44(3) 25_455 10_455
Ge3 Ba2 Ge1 132.75(3) 1_565 10_455
Ge1 Ba2 Ge1 82.05(3) 12 10_455
Ge1 Ba2 Ge1 97.98(3) 18 10_455
Ge1 Ba2 Ge1 56.87(4) 25 10_455
Ge1 Ba2 Ge1 53.72(3) 27_455 10_455
Ge1 Ba2 Ge1 124.69(2) 3_565 10_455
Ge1 Ba2 Ge1 178.03(4) 20_565 10_455
Ge3 Ba2 Ge1 80.06(4) 25 .
Ge3 Ba2 Ge1 45.44(3) . .
Ge3 Ba2 Ge1 132.75(3) 25_455 .
Ge3 Ba2 Ge1 101.27(4) 1_565 .
Ge1 Ba2 Ge1 124.69(2) 12 .
Ge1 Ba2 Ge1 53.72(3) 18 .
Ge1 Ba2 Ge1 97.98(3) 25 .
Ge1 Ba2 Ge1 178.03(4) 27_455 .
Ge1 Ba2 Ge1 82.05(3) 3_565 .
Ge1 Ba2 Ge1 56.87(4) 20_565 .
Ge1 Ba2 Ge1 124.69(2) 10_455 .
Ge2 Ba1 Ge2 139.13(4) . 21
Ge2 Ba1 Ge2 40.87(4) . 5
Ge2 Ba1 Ge2 180.00(4) 21 5
Ge2 Ba1 Ge2 180.00(4) . 17
Ge2 Ba1 Ge2 40.87(4) 21 17
Ge2 Ba1 Ge2 139.13(4) 5 17
Ge2 Ba1 Ge2 90.0 . 21_655
Ge2 Ba1 Ge2 130.87(4) 21 21_655
Ge2 Ba1 Ge2 49.13(4) 5 21_655
Ge2 Ba1 Ge2 90.0 17 21_655
Ge2 Ba1 Ge2 90.0 . 5_455
Ge2 Ba1 Ge2 49.13(4) 21 5_455
Ge2 Ba1 Ge2 130.87(4) 5 5_455
Ge2 Ba1 Ge2 90.0 17 5_455
Ge2 Ba1 Ge2 180.0 21_655 5_455
Ge2 Ba1 Ge2 49.13(4) . 17_565
Ge2 Ba1 Ge2 90.0 21 17_565
Ge2 Ba1 Ge2 90.0 5 17_565
Ge2 Ba1 Ge2 130.87(4) 17 17_565
Ge2 Ba1 Ge2 139.13(4) 21_655 17_565
Ge2 Ba1 Ge2 40.87(4) 5_455 17_565
Ge2 Ba1 Ge2 130.87(4) . 1_545
Ge2 Ba1 Ge2 90.0 21 1_545
Ge2 Ba1 Ge2 90.0 5 1_545
Ge2 Ba1 Ge2 49.13(4) 17 1_545
Ge2 Ba1 Ge2 40.87(4) 21_655 1_545
Ge2 Ba1 Ge2 139.13(4) 5_455 1_545
Ge2 Ba1 Ge2 180.00(4) 17_565 1_545
Ge2 Ba1 Ge1 125.688(19) . 17
Ge2 Ba1 Ge1 54.312(19) 21 17
Ge2 Ba1 Ge1 125.688(19) 5 17
Ge2 Ba1 Ge1 54.312(19) 17 17
Ge2 Ba1 Ge1 102.555(14) 21_655 17
Ge2 Ba1 Ge1 77.445(14) 5_455 17
Ge2 Ba1 Ge1 102.555(14) 17_565 17
Ge2 Ba1 Ge1 77.445(14) 1_545 17
Ge2 Ba1 Ge1 54.312(19) . .
Ge2 Ba1 Ge1 125.688(19) 21 .
Ge2 Ba1 Ge1 54.312(19) 5 .
Ge2 Ba1 Ge1 125.688(19) 17 .
Ge2 Ba1 Ge1 77.445(14) 21_655 .
Ge2 Ba1 Ge1 102.555(14) 5_455 .
Ge2 Ba1 Ge1 77.445(14) 17_565 .
Ge2 Ba1 Ge1 102.555(14) 1_545 .
Ge1 Ba1 Ge1 180.00(3) 17 .
Ge2 Ba1 Ge1 102.555(14) . 2
Ge2 Ba1 Ge1 102.555(14) 21 2
Ge2 Ba1 Ge1 77.445(14) 5 2
Ge2 Ba1 Ge1 77.445(14) 17 2
Ge2 Ba1 Ge1 54.312(19) 21_655 2
Ge2 Ba1 Ge1 125.688(19) 5_455 2
Ge2 Ba1 Ge1 125.688(19) 17_565 2
Ge2 Ba1 Ge1 54.312(19) 1_545 2
Ge1 Ba1 Ge1 52.24(3) 17 2
Ge1 Ba1 Ge1 127.76(3) . 2
Ge2 Ba1 Ge1 77.445(14) . 4
Ge2 Ba1 Ge1 77.445(14) 21 4
Ge2 Ba1 Ge1 102.555(14) 5 4
Ge2 Ba1 Ge1 102.555(14) 17 4
Ge2 Ba1 Ge1 125.688(19) 21_655 4
Ge2 Ba1 Ge1 54.312(19) 5_455 4
Ge2 Ba1 Ge1 54.312(19) 17_565 4
Ge2 Ba1 Ge1 125.688(19) 1_545 4
Ge1 Ba1 Ge1 52.24(3) 17 4
Ge1 Ba1 Ge1 127.76(3) . 4
Ge1 Ba1 Ge1 77.01(4) 2 4
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 Rh1 2.4846(9) 21_655
Ge1 Rh1 2.4846(9) .
Ge1 Ge3 2.7122(18) .
Ge1 Ge4 2.7290(18) 25
Ge1 Ba2 3.5368(11) 25
Ge1 Ba2 3.5368(11) .
Ge1 Ba1 3.6303(13) .
Ge2 Rh1 2.4651(13) 17_565
Ge2 Rh1 2.4651(13) .
Ge2 Ge2 2.520(2) 21_665
Ge2 Ge2 2.520(2) 5
Ge2 Ba1 3.6087(12) .
Ge2 Ba1 3.6087(12) 1_565
Rh1 Ge2 2.4651(13) 17_565
Rh1 Ge1 2.4846(9) 20_565
Rh1 Ge1 2.4846(9) 18
Rh1 Ge1 2.4846(9) 3_565
Rh1 Ba2 3.5531(12) .
Rh1 Ba1 3.8208(11) .
Rh1 Ba1 3.8208(11) 1_565
Ge3 Ge4 2.504(4) .
Ge3 Ge1 2.7122(18) 3
Ge3 Ge1 2.7122(18) 20
Ge3 Ge1 2.7122(18) 18
Ge3 Ba2 3.4841(12) 25
Ge3 Ba2 3.4841(12) .
Ge3 Ba2 3.4841(12) 1_545
Ge3 Ba2 3.4841(12) 25_455
Ge4 Ge1 2.7290(18) 25
Ge4 Ge1 2.7290(18) 27_445
Ge4 Ge1 2.7290(18) 12_545
Ge4 Ge1 2.7290(18) 10_455
Ge4 Ba2 3.5435(13) 25_455
Ge4 Ba2 3.5435(13) 1_545
Ge4 Ba2 3.5435(13) 25
Ge4 Ba2 3.5435(13) .
Ba2 Ge3 3.4841(12) 25
Ba2 Ge3 3.4841(12) 25_455
Ba2 Ge3 3.4841(12) 1_565
Ba2 Ge1 3.5368(11) 12
Ba2 Ge1 3.5368(11) 18
Ba2 Ge1 3.5368(11) 25
Ba2 Ge1 3.5368(11) 27_455
Ba2 Ge1 3.5368(11) 3_565
Ba2 Ge1 3.5368(11) 20_565
Ba2 Ge1 3.5368(11) 10_455
Ba1 Ge2 3.6087(12) 21
Ba1 Ge2 3.6087(12) 5
Ba1 Ge2 3.6087(12) 17
Ba1 Ge2 3.6087(12) 21_655
Ba1 Ge2 3.6087(12) 5_455
Ba1 Ge2 3.6087(12) 17_565
Ba1 Ge2 3.6087(12) 1_545
Ba1 Ge1 3.6303(13) 17
Ba1 Ge1 3.6303(13) 2
Ba1 Ge1 3.6303(13) 4
