#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:15:30 +0100 (vie 25 de mar de 2016) $
#$Revision: 179887 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/83/7018356.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018356
loop_
_publ_author_name
'Merkens, Carina'
'Englert, Ulli'
_publ_section_title
;
 Ordered bimetallic coordination networks featuring rare earth and silver
 cations.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              4664
_journal_page_last               4673
_journal_paper_doi               10.1039/c2dt11772j
_journal_volume                  41
_journal_year                    2012
_chemical_formula_moiety         '4(C24 H24 Ag N4 O8 Yb), H2 O'
_chemical_formula_sum            'C96 H98 Ag4 N16 O33 Yb4'
_chemical_formula_weight         3127.55
_chemical_name_common            6c
_chemical_name_systematic
;
?
;
_space_group_IT_number           22
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'F 2 2'
_symmetry_space_group_name_H-M   'F 2 2 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     patt
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.1271(10)
_cell_length_b                   24.7427(14)
_cell_length_c                   30.1824(17)
_cell_measurement_reflns_used    3529
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      22.40
_cell_measurement_theta_min      2.38
_cell_volume                     12790.4(13)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  multilayer
_diffrn_radiation_source         microsource
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1468
_diffrn_reflns_av_sigmaI/netI    0.0909
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            44572
_diffrn_reflns_theta_full        26.42
_diffrn_reflns_theta_max         26.42
_diffrn_reflns_theta_min         2.13
_exptl_absorpt_coefficient_mu    3.565
_exptl_absorpt_correction_T_max  0.5215
_exptl_absorpt_correction_T_min  0.4045
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   MULABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.624
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             6072
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.21
_refine_diff_density_max         1.580
_refine_diff_density_min         -1.543
_refine_diff_density_rms         0.163
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.022(10)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     347
_refine_ls_number_reflns         6585
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0536
_refine_ls_R_factor_gt           0.0437
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0351P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1078
_refine_ls_wR_factor_ref         0.1118
_reflns_number_gt                5487
_reflns_number_total             6585
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt11772j.txt
_cod_data_source_block           6c
_cod_database_code               7018356
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'x, -y, -z'
'-x, y, -z'
'x, y+1/2, z+1/2'
'-x, -y+1/2, z+1/2'
'x, -y+1/2, -z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, y, z+1/2'
'-x+1/2, -y, z+1/2'
'x+1/2, -y, -z+1/2'
'-x+1/2, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Yb1 Yb 0.2500 0.511292(18) 0.7500 0.01671(15) Uani 1 2 d S .
Yb2 Yb 0.22865(3) 1.0000 0.5000 0.02484(15) Uani 1 2 d S .
Ag1 Ag 0.49599(7) 0.76180(2) 0.62314(2) 0.0286(3) Uani 1 1 d . .
O1 O 0.1541(4) 1.0224(2) 0.55870(19) 0.0257(15) Uani 1 1 d . .
O2 O 0.1617(4) 1.0775(2) 0.48171(19) 0.0283(16) Uani 1 1 d . .
C1 C 0.0951(8) 1.0607(4) 0.6226(3) 0.052(4) Uani 1 1 d . .
H1A H 0.1323 1.0403 0.6407 0.078 Uiso 1 1 calc R .
H1B H 0.0442 1.0426 0.6230 0.078 Uiso 1 1 calc R .
H1C H 0.0897 1.0973 0.6346 0.078 Uiso 1 1 calc R .
C2 C 0.1250(6) 1.0638(4) 0.5747(3) 0.027(2) Uani 1 1 d . .
C3 C 0.1160(6) 1.1127(4) 0.5495(3) 0.030(2) Uani 1 1 d . .
C4 C 0.1349(6) 1.1165(3) 0.5039(4) 0.029(2) Uani 1 1 d . .
C5 C 0.1209(8) 1.1689(4) 0.4780(4) 0.056(4) Uani 1 1 d . .
H5A H 0.1694 1.1801 0.4635 0.084 Uiso 1 1 calc R .
H5B H 0.1037 1.1973 0.4985 0.084 Uiso 1 1 calc R .
H5C H 0.0805 1.1628 0.4556 0.084 Uiso 1 1 calc R .
C6 C 0.0875(6) 1.1588(4) 0.5701(4) 0.031(3) Uani 1 1 d . .
N1 N 0.0652(6) 1.1982(4) 0.5872(3) 0.046(3) Uani 1 1 d . .
O3 O 0.3157(4) 0.5404(2) 0.68949(19) 0.0251(15) Uani 1 1 d . .
O4 O 0.3220(3) 0.5861(2) 0.77169(18) 0.0188(13) Uani 1 1 d . .
C7 C 0.3445(5) 0.5842(3) 0.6762(3) 0.018(2) Uani 1 1 d . .
C8 C 0.3626(6) 0.6274(3) 0.7051(3) 0.020(2) Uani 1 1 d . .
C9 C 0.3509(6) 0.6253(3) 0.7514(4) 0.026(2) Uani 1 1 d . .
C10 C 0.3732(8) 0.6742(4) 0.7802(4) 0.051(3) Uani 1 1 d . .
H10A H 0.4287 0.6721 0.7879 0.077 Uiso 1 1 calc R .
H10B H 0.3418 0.6741 0.8073 0.077 Uiso 1 1 calc R .
H10C H 0.3633 0.7076 0.7637 0.077 Uiso 1 1 calc R .
C11 C 0.3587(7) 0.5911(4) 0.6277(3) 0.038(3) Uani 1 1 d . .
H11A H 0.4148 0.5886 0.6217 0.057 Uiso 1 1 calc R .
H11B H 0.3395 0.6266 0.6182 0.057 Uiso 1 1 calc R .
H11C H 0.3311 0.5627 0.6113 0.057 Uiso 1 1 calc R .
C12 C 0.3961(7) 0.6740(4) 0.6854(3) 0.031(3) Uani 1 1 d . .
N2 N 0.4209(6) 0.7120(4) 0.6704(3) 0.046(3) Uani 1 1 d . .
O5 O 0.2982(4) 0.9705(3) 0.5589(2) 0.044(2) Uani 1 1 d . .
O6 O 0.3028(5) 0.9286(3) 0.4766(2) 0.051(2) Uani 1 1 d . .
C13 C 0.3525(10) 0.9185(7) 0.6187(4) 0.118(8) Uani 1 1 d . .
H13A H 0.3686 0.9525 0.6326 0.178 Uiso 1 1 calc R .
H13B H 0.3957 0.8926 0.6199 0.178 Uiso 1 1 calc R .
H13C H 0.3074 0.9037 0.6345 0.178 Uiso 1 1 calc R .
C14 C 0.3308(8) 0.9288(6) 0.5710(4) 0.069(5) Uani 1 1 d . .
C15 C 0.3471(8) 0.8856(6) 0.5417(5) 0.070(5) Uani 1 1 d . .
C16 C 0.3366(8) 0.8902(6) 0.4952(6) 0.069(4) Uani 1 1 d . .
C17 C 0.3640(10) 0.8426(5) 0.4668(5) 0.088(6) Uani 1 1 d . .
H17A H 0.3291 0.8118 0.4714 0.132 Uiso 1 1 calc R .
H17B H 0.4173 0.8326 0.4754 0.132 Uiso 1 1 calc R .
H17C H 0.3633 0.8530 0.4355 0.132 Uiso 1 1 calc R .
N3 N 0.4116(9) 0.8013(6) 0.5747(5) 0.112(6) Uani 1 1 d U .
C18 C 0.3841(11) 0.8409(7) 0.5599(5) 0.102(6) Uani 1 1 d U .
O7A O 0.2550(8) 0.4399(4) 0.7024(4) 0.027(3) Uiso 0.50 1 d P 1
O8A O 0.1251(6) 0.4847(4) 0.7376(4) 0.025(3) Uiso 0.50 1 d P 1
C19A C 0.2481(14) 0.3663(8) 0.6536(7) 0.053(6) Uiso 0.50 1 d P 1
H19A H 0.2844 0.3848 0.6337 0.079 Uiso 0.50 1 calc PR 1
H19B H 0.2085 0.3472 0.6362 0.079 Uiso 0.50 1 calc PR 1
H19C H 0.2769 0.3402 0.6718 0.079 Uiso 0.50 1 calc PR 1
C20A C 0.2086(10) 0.4075(7) 0.6836(6) 0.020(4) Uiso 0.50 1 d P 1
C21A C 0.1224(11) 0.4102(8) 0.6883(7) 0.019(4) Uiso 0.50 1 d P 1
C22A C 0.0912(11) 0.4488(7) 0.7162(6) 0.025(4) Uiso 0.50 1 d P 1
C23A C 0.001(2) 0.4474(9) 0.7221(7) 0.069(7) Uiso 0.50 1 d P 1
H23A H -0.0124 0.4277 0.7492 0.104 Uiso 0.50 1 calc PR 1
H23B H -0.0229 0.4292 0.6965 0.104 Uiso 0.50 1 calc PR 1
H23C H -0.0192 0.4844 0.7241 0.104 Uiso 0.50 1 calc PR 1
C24A C 0.0797(12) 0.3706(8) 0.6676(7) 0.026(5) Uiso 0.50 1 d P 1
N4A N 0.0418(11) 0.3391(7) 0.6478(6) 0.041(5) Uiso 0.50 1 d P 1
O7B O 0.3173(7) 0.4842(5) 0.8098(4) 0.026(3) Uiso 0.50 1 d P 2
O8B O 0.3248(8) 0.4389(5) 0.7287(4) 0.036(3) Uiso 0.50 1 d P 2
C19B C 0.3547(16) 0.4325(9) 0.8762(8) 0.053(7) Uiso 0.50 1 d P 2
H19D H 0.3486 0.4679 0.8904 0.079 Uiso 0.50 1 calc PR 2
H19E H 0.4054 0.4171 0.8843 0.079 Uiso 0.50 1 calc PR 2
H19F H 0.3129 0.4084 0.8862 0.079 Uiso 0.50 1 calc PR 2
C20B C 0.3501(12) 0.4392(8) 0.8249(7) 0.030(5) Uiso 0.50 1 d P 2
C21B C 0.3650(13) 0.3973(9) 0.7954(8) 0.031(5) Uiso 0.50 1 d P 2
C22B C 0.3589(14) 0.3974(8) 0.7482(10) 0.048(6) Uiso 0.50 1 d P 2
C23B C 0.389(2) 0.3450(12) 0.7210(12) 0.105(12) Uiso 0.50 1 d P 2
H23D H 0.3622 0.3127 0.7321 0.158 Uiso 0.50 1 calc PR 2
H23E H 0.4454 0.3408 0.7252 0.158 Uiso 0.50 1 calc PR 2
H23F H 0.3775 0.3497 0.6895 0.158 Uiso 0.50 1 calc PR 2
C24B C 0.3982(13) 0.3524(10) 0.8157(8) 0.036(6) Uiso 0.50 1 d P 2
N4B N 0.4246(12) 0.3117(8) 0.8323(7) 0.054(6) Uiso 0.50 1 d P 2
O10D O 0.5000 0.5000 0.0260(7) 0.080(7) Uiso 0.50 2 d SP .
H10D H 0.5000 0.5074 0.0000 0.096 Uiso 0.50 2 d SPR .
H10E H 0.5464 0.5043 0.0318 0.096 Uiso 0.25 1 d PR .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Yb Yb -0.3850 5.5486 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7B Yb1 O7B 145.2(6) 12_556 .
O7B Yb1 O3 119.3(3) 12_556 12_556
O7B Yb1 O3 72.6(3) . 12_556
O7B Yb1 O3 72.6(3) 12_556 .
O7B Yb1 O3 119.3(3) . .
O3 Yb1 O3 142.9(3) 12_556 .
O7B Yb1 O8A 122.0(4) 12_556 12_556
O7B Yb1 O8A 45.3(4) . 12_556
O3 Yb1 O8A 115.4(3) 12_556 12_556
O3 Yb1 O8A 75.9(3) . 12_556
O7B Yb1 O8A 45.3(4) 12_556 .
O7B Yb1 O8A 122.0(4) . .
O3 Yb1 O8A 75.9(3) 12_556 .
O3 Yb1 O8A 115.4(3) . .
O8A Yb1 O8A 146.3(5) 12_556 .
O7B Yb1 O7A 44.0(4) 12_556 .
O7B Yb1 O7A 104.8(4) . .
O3 Yb1 O7A 140.7(3) 12_556 .
O3 Yb1 O7A 73.7(3) . .
O8A Yb1 O7A 81.0(4) 12_556 .
O8A Yb1 O7A 72.9(4) . .
O7B Yb1 O7A 104.8(4) 12_556 12_556
O7B Yb1 O7A 44.0(4) . 12_556
O3 Yb1 O7A 73.7(3) 12_556 12_556
O3 Yb1 O7A 140.7(3) . 12_556
O8A Yb1 O7A 72.9(4) 12_556 12_556
O8A Yb1 O7A 81.0(4) . 12_556
O7A Yb1 O7A 78.3(6) . 12_556
O7B Yb1 O8B 80.1(5) 12_556 .
O7B Yb1 O8B 72.8(4) . .
O3 Yb1 O8B 138.8(4) 12_556 .
O3 Yb1 O8B 75.2(4) . .
O8A Yb1 O8B 45.0(4) 12_556 .
O8A Yb1 O8B 104.7(4) . .
O7A Yb1 O8B 36.6(5) . .
O7A Yb1 O8B 65.9(4) 12_556 .
O7B Yb1 O8B 72.8(4) 12_556 12_556
O7B Yb1 O8B 80.1(5) . 12_556
O3 Yb1 O8B 75.2(4) 12_556 12_556
O3 Yb1 O8B 138.8(4) . 12_556
O8A Yb1 O8B 104.7(4) 12_556 12_556
O8A Yb1 O8B 45.0(4) . 12_556
O7A Yb1 O8B 65.9(4) . 12_556
O7A Yb1 O8B 36.6(5) 12_556 12_556
O8B Yb1 O8B 77.3(7) . 12_556
O7B Yb1 O4 137.6(3) 12_556 .
O7B Yb1 O4 74.8(3) . .
O3 Yb1 O4 77.4(2) 12_556 .
O3 Yb1 O4 73.1(2) . .
O8A Yb1 O4 71.6(3) 12_556 .
O8A Yb1 O4 141.2(3) . .
O7A Yb1 O4 141.0(4) . .
O7A Yb1 O4 117.5(3) 12_556 .
O8B Yb1 O4 113.9(4) . .
O8B Yb1 O4 147.3(4) 12_556 .
O7B Yb1 O4 74.8(3) 12_556 12_556
O7B Yb1 O4 137.6(3) . 12_556
O3 Yb1 O4 73.1(2) 12_556 12_556
O3 Yb1 O4 77.4(2) . 12_556
O8A Yb1 O4 141.2(3) 12_556 12_556
O8A Yb1 O4 71.6(3) . 12_556
O7A Yb1 O4 117.5(3) . 12_556
O7A Yb1 O4 141.0(4) 12_556 12_556
O8B Yb1 O4 147.3(4) . 12_556
O8B Yb1 O4 113.9(4) 12_556 12_556
O4 Yb1 O4 74.0(3) . 12_556
O1 Yb2 O1 110.9(3) 3_576 .
O1 Yb2 O5 76.1(2) 3_576 3_576
O1 Yb2 O5 146.9(2) . 3_576
O1 Yb2 O5 146.9(2) 3_576 .
O1 Yb2 O5 76.1(2) . .
O5 Yb2 O5 116.4(3) 3_576 .
O1 Yb2 O6 83.2(3) 3_576 .
O1 Yb2 O6 138.4(2) . .
O5 Yb2 O6 73.4(3) 3_576 .
O5 Yb2 O6 72.6(3) . .
O1 Yb2 O6 138.4(2) 3_576 3_576
O1 Yb2 O6 83.2(3) . 3_576
O5 Yb2 O6 72.6(3) 3_576 3_576
O5 Yb2 O6 73.4(3) . 3_576
O6 Yb2 O6 112.6(4) . 3_576
O1 Yb2 O2 72.6(2) 3_576 3_576
O1 Yb2 O2 74.6(2) . 3_576
O5 Yb2 O2 136.1(3) 3_576 3_576
O5 Yb2 O2 78.8(2) . 3_576
O6 Yb2 O2 73.0(3) . 3_576
O6 Yb2 O2 147.8(2) 3_576 3_576
O1 Yb2 O2 74.6(2) 3_576 .
O1 Yb2 O2 72.6(2) . .
O5 Yb2 O2 78.8(2) 3_576 .
O5 Yb2 O2 136.1(3) . .
O6 Yb2 O2 147.8(2) . .
O6 Yb2 O2 73.0(3) 3_576 .
O2 Yb2 O2 120.2(3) 3_576 .
N4A Ag1 N1 125.7(5) 13 13_545
N4A Ag1 N3 94.1(6) 13 .
N1 Ag1 N3 109.0(4) 13_545 .
N4A Ag1 N4B 27.7(6) 13 8_656
N1 Ag1 N4B 110.4(6) 13_545 8_656
N3 Ag1 N4B 121.7(7) . 8_656
N4A Ag1 N2 117.4(5) 13 .
N1 Ag1 N2 102.7(3) 13_545 .
N3 Ag1 N2 106.0(5) . .
N4B Ag1 N2 105.1(6) 8_656 .
C2 O1 Yb2 137.6(6) . .
C4 O2 Yb2 133.8(7) . .
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O1 C2 C3 122.3(10) . .
O1 C2 C1 117.4(8) . .
C3 C2 C1 120.3(9) . .
C6 C3 C4 117.5(9) . .
C6 C3 C2 119.5(10) . .
C4 C3 C2 123.0(9) . .
O2 C4 C3 123.2(9) . .
O2 C4 C5 115.8(10) . .
C3 C4 C5 120.9(9) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
N1 C6 C3 178.4(13) . .
C6 N1 Ag1 166.0(10) . 13_455
C7 O3 Yb1 136.6(5) . .
C9 O4 Yb1 133.9(6) . .
O3 C7 C8 122.9(8) . .
O3 C7 C11 118.4(8) . .
C8 C7 C11 118.7(8) . .
C7 C8 C9 123.5(8) . .
C7 C8 C12 116.4(8) . .
C9 C8 C12 120.0(8) . .
O4 C9 C8 124.6(8) . .
O4 C9 C10 115.7(10) . .
C8 C9 C10 119.7(8) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C7 C11 H11A 109.5 . .
C7 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C7 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
N2 C12 C8 177.8(13) . .
C12 N2 Ag1 156.1(9) . .
C14 O5 Yb2 138.1(10) . .
C16 O6 Yb2 135.0(9) . .
C14 C13 H13A 109.5 . .
C14 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C14 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
O5 C14 C15 122.5(13) . .
O5 C14 C13 122.6(14) . .
C15 C14 C13 114.8(12) . .
C18 C15 C14 116.4(14) . .
C18 C15 C16 120.8(14) . .
C14 C15 C16 122.2(12) . .
O6 C16 C15 124.4(14) . .
O6 C16 C17 118.6(14) . .
C15 C16 C17 116.8(11) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C18 N3 Ag1 148.9(17) . .
N3 C18 C15 176(2) . .
C20A O7A Yb1 138.8(12) . .
C22A O8A Yb1 137.2(11) . .
O7A C20A C21A 123.5(16) . .
O7A C20A C19A 114.5(16) . .
C21A C20A C19A 122.0(17) . .
C24A C21A C22A 124.3(18) . .
C24A C21A C20A 117.0(17) . .
C22A C21A C20A 118.4(17) . .
O8A C22A C21A 129.0(18) . .
O8A C22A C23A 115.0(17) . .
C21A C22A C23A 116.0(18) . .
N4A C24A C21A 176(2) . .
C24A N4A Ag1 161.0(18) . 13_445
C20B O7B Yb1 138.1(12) . .
C22B O8B Yb1 137.0(16) . .
C20B C19B H19D 109.5 . .
C20B C19B H19E 109.5 . .
H19D C19B H19E 109.5 . .
C20B C19B H19F 109.5 . .
H19D C19B H19F 109.5 . .
H19E C19B H19F 109.5 . .
O7B C20B C21B 118.9(18) . .
O7B C20B C19B 116.9(17) . .
C21B C20B C19B 123.2(19) . .
C24B C21B C20B 113(2) . .
C24B C21B C22B 118(2) . .
C20B C21B C22B 129(2) . .
O8B C22B C21B 119(2) . .
O8B C22B C23B 123(3) . .
C21B C22B C23B 119(2) . .
C22B C23B H23D 109.5 . .
C22B C23B H23E 109.5 . .
H23D C23B H23E 109.5 . .
C22B C23B H23F 109.5 . .
H23D C23B H23F 109.5 . .
H23E C23B H23F 109.5 . .
N4B C24B C21B 177(3) . .
C24B N4B Ag1 157(2) . 8_646
H10D O10D H10E 100.4 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Yb1 O7B 2.245(11) 12_556
Yb1 O7B 2.245(11) .
Yb1 O3 2.263(6) 12_556
Yb1 O3 2.263(6) .
Yb1 O8A 2.269(11) 12_556
Yb1 O8A 2.269(11) .
Yb1 O7A 2.278(11) .
Yb1 O7A 2.278(11) 12_556
Yb1 O8B 2.293(13) .
Yb1 O8B 2.293(13) 12_556
Yb1 O4 2.319(6) .
Yb1 O4 2.319(5) 12_556
Yb2 O1 2.254(6) 3_576
Yb2 O1 2.254(6) .
Yb2 O5 2.262(6) 3_576
Yb2 O5 2.262(6) .
Yb2 O6 2.287(7) .
Yb2 O6 2.287(7) 3_576
Yb2 O2 2.301(6) 3_576
Yb2 O2 2.301(6) .
Ag1 N4A 2.197(18) 13
Ag1 N1 2.248(10) 13_545
Ag1 N3 2.276(11) .
Ag1 N4B 2.28(2) 8_656
Ag1 N2 2.282(8) .
O1 C2 1.236(10) .
O2 C4 1.261(11) .
C1 C2 1.536(14) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
C2 C3 1.438(12) .
C3 C6 1.387(13) .
C3 C4 1.417(15) .
C4 C5 1.532(13) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 N1 1.168(12) .
N1 Ag1 2.248(10) 13_455
O3 C7 1.256(10) .
O4 C9 1.249(10) .
C7 C8 1.413(11) .
C7 C11 1.496(12) .
C8 C9 1.415(14) .
C8 C12 1.418(12) .
C9 C10 1.537(12) .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 N2 1.126(12) .
O5 C14 1.229(14) .
O6 C16 1.246(13) .
C13 C14 1.507(17) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C15 1.41(2) .
C15 C18 1.387(17) .
C15 C16 1.42(2) .
C16 C17 1.529(18) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
N3 C18 1.175(16) .
O7A C20A 1.26(2) .
O8A C22A 1.24(2) .
C19A C20A 1.52(3) .
C19A H19A 0.9800 .
C19A H19B 0.9800 .
C19A H19C 0.9800 .
C20A C21A 1.48(3) .
C21A C24A 1.37(3) .
C21A C22A 1.38(3) .
C22A C23A 1.56(4) .
C23A H23A 0.9800 .
C23A H23B 0.9800 .
C23A H23C 0.9800 .
C24A N4A 1.18(2) .
N4A Ag1 2.197(18) 13_445
O7B C20B 1.33(2) .
O8B C22B 1.32(2) .
C19B C20B 1.56(3) .
C19B H19D 0.9800 .
C19B H19E 0.9800 .
C19B H19F 0.9800 .
C20B C21B 1.39(3) .
C21B C24B 1.39(3) .
C21B C22B 1.43(4) .
C22B C23B 1.62(4) .
C23B H23D 0.9800 .
C23B H23E 0.9800 .
C23B H23F 0.9800 .
C24B N4B 1.21(3) .
N4B Ag1 2.28(2) 8_646
O10D O10D 1.57(4) 3_565
O10D H10D 0.8055 .
O10D H10E 0.8203 .
