#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:59:31 +0100 (vie 25 de mar de 2016) $
#$Revision: 179946 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/41/7024126.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7024126
loop_
_publ_author_name
'Klosterman, Jeremy K.'
'Linden, Anthony'
'Frantz, Derik K.'
'Siegel, Jay S.'
_publ_section_title
;
 Manisyl-substituted polypyridine coordination compounds:
 Metallo-supramolecular networks of interdigitated double helices
 assembled via CH...pi and pi-pi interactions.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1519
_journal_page_last               1531
_journal_paper_doi               10.1039/b911272c
_journal_volume                  39
_journal_year                    2010
_chemical_formula_moiety         'C66 H62 N6 O4 Os 2+, 2(F6 P 1-), 6(C2 H3 N)'
_chemical_formula_sum            'C78 H80 F12 N12 O4 Os P2'
_chemical_formula_weight         1729.69
_chemical_name_systematic
;
bis[5,5"-bis-(4-methoxy-2,6-dimethylphenyl)-
[2,2':6,2"]terpyridine]osmium(II) hexafluorophosphate
hexa-acetonitrile solvate
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             05-09-14
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.9746(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   29.4529(4)
_cell_length_b                   11.8271(1)
_cell_length_c                   22.4142(2)
_cell_measurement_reflns_used    159774
_cell_measurement_temperature    160(1)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      2.0
_cell_volume                     7806.69(14)
_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Nonius, 2000)'
_computing_data_reduction
'DENZO-SMN and SCALEPACK (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL97 and PLATON (Spek, 2009)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altomare et al., 1994)'
_diffrn_ambient_temperature      160(1)
_diffrn_detector                 '65 mm CCD camera on \k goniostat'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type
'Nonius KappaCCD area-detector diffractometer'
_diffrn_measurement_method       'φ and ω scans with κ offsets'
_diffrn_radiation_monochromator  'horizontally mounted graphite crystal'
_diffrn_radiation_source         'Nonius FR590 sealed tube generator'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0566
_diffrn_reflns_av_sigmaI/netI    0.0291
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       -38
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            81476
_diffrn_reflns_theta_full        27.87
_diffrn_reflns_theta_max         27.87
_diffrn_reflns_theta_min         2.27
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.759
_exptl_absorpt_correction_T_max  0.773
_exptl_absorpt_correction_T_min  0.584
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Blessing, 1995)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.472
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       tablet
_exptl_crystal_F_000             3512
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.762
_refine_diff_density_min         -1.184
_refine_diff_density_rms         0.089
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     538
_refine_ls_number_reflns         9302
_refine_ls_number_restraints     415
_refine_ls_restrained_S_all      1.091
_refine_ls_R_factor_all          0.0385
_refine_ls_R_factor_gt           0.0313
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0375P)²+16.4115P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0729
_refine_ls_wR_factor_ref         0.0767
_reflns_number_gt                8424
_reflns_number_total             9306
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            b911272c.txt
_cod_data_source_block           9b
_cod_database_code               7024126
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os Os 0.5000 0.203090(11) 0.7500 0.02246(5) Uani 1 2 d S . .
O1 O 0.49301(8) 0.7495(2) 1.05120(9) 0.0400(5) Uani 1 1 d . . .
O2 O 0.27869(9) -0.3440(2) 0.65710(14) 0.0632(7) Uani 1 1 d . . .
N1 N 0.53811(7) 0.33011(18) 0.78868(10) 0.0248(4) Uani 1 1 d . . .
N2 N 0.55451(7) 0.20216(17) 0.69921(10) 0.0237(4) Uani 1 1 d . . .
N3 N 0.48332(7) 0.07573(17) 0.69073(9) 0.0230(4) Uani 1 1 d . . .
C1 C 0.44941(12) 0.7957(3) 1.05204(14) 0.0414(7) Uani 1 1 d . . .
H11 H 0.4455 0.8483 1.0186 0.062 Uiso 1 1 calc R . .
H12 H 0.4452 0.8362 1.0897 0.062 Uiso 1 1 calc R . .
H13 H 0.4269 0.7350 1.0485 0.062 Uiso 1 1 calc R . .
C2 C 0.50408(10) 0.6846(2) 1.00293(12) 0.0316(6) Uani 1 1 d . . .
C3 C 0.54749(10) 0.6388(2) 1.00377(13) 0.0345(6) Uani 1 1 d . . .
H3 H 0.5669 0.6518 1.0373 0.041 Uiso 1 1 calc R . .
C4 C 0.56300(10) 0.5745(2) 0.95651(13) 0.0327(6) Uani 1 1 d . . .
C5 C 0.60967(11) 0.5230(3) 0.96231(15) 0.0424(7) Uani 1 1 d . . .
H51 H 0.6314 0.5692 0.9404 0.064 Uiso 1 1 calc R . .
H52 H 0.6092 0.4463 0.9458 0.064 Uiso 1 1 calc R . .
H53 H 0.6188 0.5200 1.0045 0.064 Uiso 1 1 calc R . .
C6 C 0.53391(9) 0.5553(2) 0.90684(12) 0.0288(5) Uani 1 1 d . . .
C7 C 0.52610(9) 0.3937(2) 0.83569(11) 0.0257(5) Uani 1 1 d . . .
H7 H 0.4997 0.3729 0.8568 0.031 Uiso 1 1 calc R . .
C8 C 0.55032(9) 0.4883(2) 0.85496(12) 0.0288(5) Uani 1 1 d . . .
C9 C 0.58927(10) 0.5161(3) 0.82346(13) 0.0347(6) Uani 1 1 d . . .
H9 H 0.6067 0.5806 0.8347 0.042 Uiso 1 1 calc R . .
C10 C 0.60254(9) 0.4501(2) 0.77600(13) 0.0340(6) Uani 1 1 d . . .
H10 H 0.6293 0.4687 0.7551 0.041 Uiso 1 1 calc R . .
C11 C 0.57690(9) 0.3566(2) 0.75864(12) 0.0278(5) Uani 1 1 d . . .
C12 C 0.58744(9) 0.2810(2) 0.70865(12) 0.0280(5) Uani 1 1 d . . .
C13 C 0.62564(10) 0.2813(3) 0.67321(14) 0.0361(6) Uani 1 1 d . . .
H131 H 0.6488 0.3364 0.6789 0.043 Uiso 1 1 calc R . .
C14 C 0.62933(10) 0.1991(3) 0.62918(14) 0.0393(7) Uani 1 1 d . . .
H14 H 0.6552 0.1983 0.6045 0.047 Uiso 1 1 calc R . .
C15 C 0.59568(9) 0.1182(3) 0.62078(13) 0.0345(6) Uani 1 1 d . . .
H15 H 0.5987 0.0614 0.5912 0.041 Uiso 1 1 calc R . .
C16 C 0.55772(9) 0.1212(2) 0.65599(11) 0.0266(5) Uani 1 1 d . . .
C17 C 0.51791(9) 0.0467(2) 0.65303(11) 0.0262(5) Uani 1 1 d . . .
C18 C 0.51338(9) -0.0471(2) 0.61638(12) 0.0316(6) Uani 1 1 d . . .
H18 H 0.5375 -0.0682 0.5910 0.038 Uiso 1 1 calc R . .
C19 C 0.47389(10) -0.1098(2) 0.61673(12) 0.0326(6) Uani 1 1 d . . .
H19 H 0.4712 -0.1748 0.5920 0.039 Uiso 1 1 calc R . .
C20 C 0.43800(9) -0.0789(2) 0.65298(11) 0.0266(5) Uani 1 1 d . . .
C21 C 0.44459(9) 0.0150(2) 0.68924(11) 0.0245(5) Uani 1 1 d . . .
H21 H 0.4206 0.0376 0.7143 0.029 Uiso 1 1 calc R . .
C22 C 0.39453(9) -0.1439(2) 0.65394(12) 0.0290(5) Uani 1 1 d . . .
C23 C 0.36956(10) -0.1604(2) 0.60083(14) 0.0352(6) Uani 1 1 d . . .
C24 C 0.38297(12) -0.1085(3) 0.54236(14) 0.0446(7) Uani 1 1 d . . .
H241 H 0.3938 -0.0312 0.5492 0.067 Uiso 1 1 calc R . .
H242 H 0.3566 -0.1070 0.5151 0.067 Uiso 1 1 calc R . .
H243 H 0.4072 -0.1536 0.5247 0.067 Uiso 1 1 calc R . .
C25 C 0.33019(11) -0.2265(3) 0.60102(16) 0.0427(7) Uani 1 1 d . . .
H25 H 0.3135 -0.2385 0.5650 0.051 Uiso 1 1 calc R . .
C26 C 0.31564(11) -0.2742(3) 0.65338(18) 0.0451(8) Uani 1 1 d . . .
C27 C 0.25766(14) -0.3795(4) 0.6017(2) 0.0691(12) Uani 1 1 d . . .
H271 H 0.2444 -0.3137 0.5814 0.104 Uiso 1 1 calc R . .
H272 H 0.2338 -0.4348 0.6099 0.104 Uiso 1 1 calc R . .
H273 H 0.2806 -0.4140 0.5763 0.104 Uiso 1 1 calc R . .
C28 C 0.33900(11) -0.2544(3) 0.70664(16) 0.0433(7) Uani 1 1 d . . .
H28 H 0.3278 -0.2849 0.7428 0.052 Uiso 1 1 calc R . .
C29 C 0.37871(10) -0.1901(2) 0.70768(14) 0.0345(6) Uani 1 1 d . . .
C30 C 0.40419(13) -0.1761(3) 0.76609(15) 0.0486(8) Uani 1 1 d . . .
H301 H 0.3989 -0.1000 0.7818 0.073 Uiso 1 1 calc R . .
H302 H 0.4367 -0.1867 0.7597 0.073 Uiso 1 1 calc R . .
H303 H 0.3935 -0.2323 0.7947 0.073 Uiso 1 1 calc R . .
C31 C 0.45616(11) 0.5821(3) 0.85568(14) 0.0441(8) Uani 1 1 d . . .
H311 H 0.4417 0.5079 0.8596 0.066 Uiso 1 1 calc R . .
H312 H 0.4721 0.5859 0.8177 0.066 Uiso 1 1 calc R . .
H313 H 0.4329 0.6413 0.8567 0.066 Uiso 1 1 calc R . .
C32 C 0.48975(9) 0.5995(2) 0.90678(12) 0.0297(6) Uani 1 1 d . . .
C33 C 0.47494(10) 0.6637(2) 0.95486(12) 0.0312(6) Uani 1 1 d . . .
H33 H 0.4449 0.6931 0.9547 0.037 Uiso 1 1 calc R . .
C34 C 0.20615(15) 0.5159(5) 0.7405(2) 0.0801(14) Uani 1 1 d . . .
H341 H 0.2103 0.5939 0.7268 0.120 Uiso 1 1 calc R . .
H342 H 0.1859 0.5152 0.7748 0.120 Uiso 1 1 calc R . .
H343 H 0.1928 0.4706 0.7081 0.120 Uiso 1 1 calc R . .
C35 C 0.24942(16) 0.4691(5) 0.7578(2) 0.0791(14) Uani 1 1 d . . .
N36 N 0.28362(17) 0.4344(6) 0.7705(3) 0.140(3) Uani 1 1 d . . .
C37 C 0.19435(15) 0.8246(4) 0.8842(2) 0.0687(12) Uani 1 1 d . . .
H371 H 0.2255 0.8126 0.8710 0.103 Uiso 1 1 calc R . .
H372 H 0.1933 0.8172 0.9277 0.103 Uiso 1 1 calc R . .
H373 H 0.1843 0.9005 0.8725 0.103 Uiso 1 1 calc R . .
C38 C 0.16465(13) 0.7408(4) 0.85658(19) 0.0554(9) Uani 1 1 d . . .
N39 N 0.14135(14) 0.6782(3) 0.8348(2) 0.0793(12) Uani 1 1 d . . .
C40 C 0.24534(18) 0.5343(4) 0.9215(3) 0.0832(14) Uani 1 1 d . . .
H401 H 0.2612 0.5854 0.8945 0.125 Uiso 1 1 calc R . .
H402 H 0.2370 0.5755 0.9577 0.125 Uiso 1 1 calc R . .
H403 H 0.2178 0.5054 0.9016 0.125 Uiso 1 1 calc R . .
C41 C 0.27465(15) 0.4412(4) 0.9374(2) 0.0697(12) Uani 1 1 d . . .
N42 N 0.29711(16) 0.3658(4) 0.9499(2) 0.0943(14) Uani 1 1 d . . .
P1 P 0.33567(2) 0.81553(7) 0.93519(3) 0.04143(19) Uani 1 1 d DU . .
F1 F 0.38552(5) 0.84072(15) 0.91356(7) 0.0708(7) Uani 1 1 d DU A .
F2 F 0.28587(5) 0.79045(15) 0.95691(8) 0.0787(8) Uani 1 1 d DU A .
F3A F 0.32198(9) 0.7736(6) 0.87039(10) 0.0779(17) Uani 0.550(12) 1 d PDU A 1
F4A F 0.34939(9) 0.8575(6) 1.00007(10) 0.0705(16) Uani 0.550(12) 1 d PDU A 1
F5A F 0.32102(8) 0.9400(2) 0.9178(3) 0.092(2) Uani 0.550(12) 1 d PDU A 1
F6A F 0.35038(8) 0.6911(2) 0.9527(3) 0.0751(17) Uani 0.550(12) 1 d PDU A 1
F3B F 0.31760(8) 0.8215(7) 0.86843(7) 0.084(2) Uani 0.450(12) 1 d PDU A 2
F4B F 0.35375(7) 0.8097(7) 1.00199(7) 0.076(2) Uani 0.450(12) 1 d PDU A 2
F5B F 0.32695(11) 0.94679(12) 0.9424(4) 0.0708(19) Uani 0.450(12) 1 d PDU A 2
F6B F 0.34443(12) 0.68438(12) 0.9280(4) 0.103(2) Uani 0.450(12) 1 d PDU A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 312 0.0033 0.0016
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
H H 320 0.0000 0.0000
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
F F 48 0.0171 0.0103
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
N N 48 0.0061 0.0033
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
O O 16 0.0106 0.0060
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Os Os 4 -1.2165 7.6030
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
P P 8 0.1023 0.0942
; International Tables for Crystallography (1992).
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N2 Os N2 179.37(12) 2_656
N2 Os N1 78.75(9) .
N2 Os N1 101.72(8) 2_656
N1 Os N1 86.23(12) 2_656
N2 Os N3 100.33(8) 2_656
N1 Os N3 98.02(8) 2_656
N2 Os N3 79.19(9) .
N1 Os N3 157.94(9) .
N3 Os N3 86.16(11) 2_656
C2 O1 C1 117.5(2) .
C26 O2 C27 117.0(3) .
C7 N1 C11 119.2(2) .
C7 N1 Os 126.07(17) .
C11 N1 Os 114.38(17) .
C12 N2 C16 122.2(2) .
C12 N2 Os 119.28(18) .
C16 N2 Os 118.50(17) .
C21 N3 C17 119.1(2) .
C21 N3 Os 126.69(17) .
C17 N3 Os 114.00(17) .
O1 C1 H11 109.5 .
O1 C1 H12 109.5 .
H11 C1 H12 109.5 .
O1 C1 H13 109.5 .
H11 C1 H13 109.5 .
H12 C1 H13 109.5 .
O1 C2 C3 116.0(3) .
O1 C2 C33 124.1(3) .
C3 C2 C33 119.9(3) .
C2 C3 C4 121.2(3) .
C2 C3 H3 119.4 .
C4 C3 H3 119.4 .
C3 C4 C6 119.1(3) .
C3 C4 C5 117.9(3) .
C6 C4 C5 123.0(3) .
C4 C5 H51 109.5 .
C4 C5 H52 109.5 .
H51 C5 H52 109.5 .
C4 C5 H53 109.5 .
H51 C5 H53 109.5 .
H52 C5 H53 109.5 .
C32 C6 C4 119.5(3) .
C32 C6 C8 120.6(2) .
C4 C6 C8 119.9(3) .
N1 C7 C8 123.5(2) .
N1 C7 H7 118.2 .
C8 C7 H7 118.2 .
C7 C8 C9 117.0(3) .
C7 C8 C6 119.8(2) .
C9 C8 C6 123.2(2) .
C10 C9 C8 120.1(3) .
C10 C9 H9 119.9 .
C8 C9 H9 119.9 .
C9 C10 C11 120.4(3) .
C9 C10 H10 119.8 .
C11 C10 H10 119.8 .
N1 C11 C10 119.8(3) .
N1 C11 C12 115.0(2) .
C10 C11 C12 125.2(2) .
N2 C12 C13 119.7(3) .
N2 C12 C11 112.1(2) .
C13 C12 C11 128.2(3) .
C12 C13 C14 118.6(3) .
C12 C13 H131 120.7 .
C14 C13 H131 120.7 .
C15 C14 C13 120.9(3) .
C15 C14 H14 119.5 .
C13 C14 H14 119.5 .
C16 C15 C14 119.2(3) .
C16 C15 H15 120.4 .
C14 C15 H15 120.4 .
N2 C16 C15 119.4(3) .
N2 C16 C17 112.8(2) .
C15 C16 C17 127.8(3) .
N3 C17 C18 119.9(2) .
N3 C17 C16 114.9(2) .
C18 C17 C16 125.2(2) .
C19 C18 C17 120.0(2) .
C19 C18 H18 120.0 .
C17 C18 H18 120.0 .
C18 C19 C20 120.7(3) .
C18 C19 H19 119.7 .
C20 C19 H19 119.7 .
C21 C20 C19 116.8(2) .
C21 C20 C22 121.0(2) .
C19 C20 C22 122.2(2) .
N3 C21 C20 123.4(2) .
N3 C21 H21 118.3 .
C20 C21 H21 118.3 .
C23 C22 C29 119.7(3) .
C23 C22 C20 119.8(3) .
C29 C22 C20 120.5(2) .
C25 C23 C22 119.9(3) .
C25 C23 C24 117.4(3) .
C22 C23 C24 122.7(3) .
C23 C24 H241 109.5 .
C23 C24 H242 109.5 .
H241 C24 H242 109.5 .
C23 C24 H243 109.5 .
H241 C24 H243 109.5 .
H242 C24 H243 109.5 .
C26 C25 C23 120.1(3) .
C26 C25 H25 120.0 .
C23 C25 H25 120.0 .
O2 C26 C25 123.9(3) .
O2 C26 C28 115.6(3) .
C25 C26 C28 120.5(3) .
O2 C27 H271 109.5 .
O2 C27 H272 109.5 .
H271 C27 H272 109.5 .
O2 C27 H273 109.5 .
H271 C27 H273 109.5 .
H272 C27 H273 109.5 .
C26 C28 C29 120.7(3) .
C26 C28 H28 119.7 .
C29 C28 H28 119.7 .
C28 C29 C22 119.1(3) .
C28 C29 C30 118.7(3) .
C22 C29 C30 122.2(3) .
C29 C30 H301 109.5 .
C29 C30 H302 109.5 .
H301 C30 H302 109.5 .
C29 C30 H303 109.5 .
H301 C30 H303 109.5 .
H302 C30 H303 109.5 .
C32 C31 H311 109.5 .
C32 C31 H312 109.5 .
H311 C31 H312 109.5 .
C32 C31 H313 109.5 .
H311 C31 H313 109.5 .
H312 C31 H313 109.5 .
C33 C32 C6 120.3(2) .
C33 C32 C31 116.7(3) .
C6 C32 C31 123.0(3) .
C2 C33 C32 120.0(3) .
C2 C33 H33 120.0 .
C32 C33 H33 120.0 .
C35 C34 H341 109.5 .
C35 C34 H342 109.5 .
H341 C34 H342 109.5 .
C35 C34 H343 109.5 .
H341 C34 H343 109.5 .
H342 C34 H343 109.5 .
N36 C35 C34 178.4(6) .
C38 C37 H371 109.5 .
C38 C37 H372 109.5 .
H371 C37 H372 109.5 .
C38 C37 H373 109.5 .
H371 C37 H373 109.5 .
H372 C37 H373 109.5 .
N39 C38 C37 178.5(5) .
C41 C40 H401 109.5 .
C41 C40 H402 109.5 .
H401 C40 H402 109.5 .
C41 C40 H403 109.5 .
H401 C40 H403 109.5 .
H402 C40 H403 109.5 .
N42 C41 C40 178.5(5) .
F6B P1 F3B 90.05(4) .
F3A P1 F2 90.04(4) .
F6B P1 F2 90.06(4) .
F3B P1 F2 90.05(4) .
F3A P1 F5A 90.06(4) .
F2 P1 F5A 90.01(4) .
F3A P1 F6A 90.05(4) .
F2 P1 F6A 90.04(4) .
F5A P1 F6A 179.87(6) .
F6B P1 F5B 179.94(7) .
F3B P1 F5B 89.99(4) .
F2 P1 F5B 89.98(4) .
F6B P1 F4B 90.01(4) .
F3B P1 F4B 179.93(7) .
F2 P1 F4B 89.98(4) .
F5B P1 F4B 89.95(4) .
F3A P1 F1 90.05(4) .
F6B P1 F1 89.99(4) .
F3B P1 F1 90.04(4) .
F2 P1 F1 179.90(5) .
F5A P1 F1 89.97(4) .
F6A P1 F1 89.97(4) .
F5B P1 F1 89.97(4) .
F4B P1 F1 89.94(4) .
F3A P1 F4A 179.97(7) .
F2 P1 F4A 89.98(4) .
F5A P1 F4A 89.96(4) .
F6A P1 F4A 89.93(4) .
F1 P1 F4A 89.93(4) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Os N2 1.984(2)
Os N1 2.058(2)
Os N3 2.062(2)
O1 C2 1.371(4)
O1 C1 1.396(4)
O2 C26 1.370(4)
O2 C27 1.440(5)
N1 C7 1.347(3)
N1 C11 1.372(3)
N2 C12 1.360(3)
N2 C16 1.366(3)
N3 C21 1.348(3)
N3 C17 1.378(3)
C1 H11 0.9800
C1 H12 0.9800
C1 H13 0.9800
C2 C3 1.388(4)
C2 C33 1.388(4)
C3 C4 1.388(4)
C3 H3 0.9500
C4 C6 1.411(4)
C4 C5 1.507(4)
C5 H51 0.9800
C5 H52 0.9800
C5 H53 0.9800
C6 C32 1.401(4)
C6 C8 1.494(4)
C7 C8 1.391(4)
C7 H7 0.9500
C8 C9 1.397(4)
C9 C10 1.381(4)
C9 H9 0.9500
C10 C11 1.391(4)
C10 H10 0.9500
C11 C12 1.471(4)
C12 C13 1.388(4)
C13 C14 1.391(4)
C13 H131 0.9500
C14 C15 1.388(4)
C14 H14 0.9500
C15 C16 1.380(4)
C15 H15 0.9500
C16 C17 1.468(4)
C17 C18 1.385(4)
C18 C19 1.380(4)
C18 H18 0.9500
C19 C20 1.393(4)
C19 H19 0.9500
C20 C21 1.388(3)
C20 C22 1.493(4)
C21 H21 0.9500
C22 C23 1.402(4)
C22 C29 1.409(4)
C23 C25 1.399(4)
C23 C24 1.506(5)
C24 H241 0.9800
C24 H242 0.9800
C24 H243 0.9800
C25 C26 1.377(5)
C25 H25 0.9500
C26 C28 1.388(5)
C27 H271 0.9800
C27 H272 0.9800
C27 H273 0.9800
C28 C29 1.395(4)
C28 H28 0.9500
C29 C30 1.507(5)
C30 H301 0.9800
C30 H302 0.9800
C30 H303 0.9800
C31 C32 1.515(4)
C31 H311 0.9800
C31 H312 0.9800
C31 H313 0.9800
C32 C33 1.395(4)
C33 H33 0.9500
C34 C35 1.437(6)
C34 H341 0.9800
C34 H342 0.9800
C34 H343 0.9800
C35 N36 1.120(6)
C37 C38 1.453(6)
C37 H371 0.9800
C37 H372 0.9800
C37 H373 0.9800
C38 N39 1.117(5)
C40 C41 1.440(7)
C40 H401 0.9800
C40 H402 0.9800
C40 H403 0.9800
C41 N42 1.142(6)
P1 F3A 1.5806(12)
P1 F6B 1.5810(12)
P1 F3B 1.5811(12)
P1 F2 1.5813(12)
P1 F5A 1.5816(12)
P1 F6A 1.5816(12)
P1 F5B 1.5822(12)
P1 F4B 1.5822(12)
P1 F1 1.5825(12)
P1 F4A 1.5827(12)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N2 Os N1 C7 -1.2(2) 2_656
N2 Os N1 C7 179.3(2) .
N1 Os N1 C7 76.5(2) 2_656
N3 Os N1 C7 -81.7(2) 2_656
N3 Os N1 C7 178.6(2) .
N2 Os N1 C11 -174.39(18) 2_656
N2 Os N1 C11 6.04(18) .
N1 Os N1 C11 -96.71(19) 2_656
N3 Os N1 C11 105.05(18) 2_656
N3 Os N1 C11 5.4(3) .
N2 Os N2 C12 -142.0(2) 2_656
N1 Os N2 C12 -3.94(19) .
N1 Os N2 C12 79.8(2) 2_656
N3 Os N2 C12 -100.16(19) 2_656
N3 Os N2 C12 175.8(2) .
N2 Os N2 C16 37.56(19) 2_656
N1 Os N2 C16 175.6(2) .
N1 Os N2 C16 -100.68(19) 2_656
N3 Os N2 C16 79.40(19) 2_656
N3 Os N2 C16 -4.63(18) .
N2 Os N3 C21 1.6(2) 2_656
N2 Os N3 C21 -178.9(2) .
N1 Os N3 C21 -178.2(2) .
N1 Os N3 C21 -78.4(2) 2_656
N3 Os N3 C21 79.8(2) 2_656
N2 Os N3 C17 -172.66(17) 2_656
N2 Os N3 C17 6.91(17) .
N1 Os N3 C17 7.5(3) .
N1 Os N3 C17 107.40(18) 2_656
N3 Os N3 C17 -94.38(18) 2_656
C1 O1 C2 C3 -179.3(3) .
C1 O1 C2 C33 1.0(4) .
O1 C2 C3 C4 -178.0(3) .
C33 C2 C3 C4 1.7(4) .
C2 C3 C4 C6 -0.1(4) .
C2 C3 C4 C5 -177.0(3) .
C3 C4 C6 C32 -1.4(4) .
C5 C4 C6 C32 175.3(3) .
C3 C4 C6 C8 178.7(2) .
C5 C4 C6 C8 -4.6(4) .
C11 N1 C7 C8 2.0(4) .
Os N1 C7 C8 -170.98(19) .
N1 C7 C8 C9 -0.7(4) .
N1 C7 C8 C6 178.7(2) .
C32 C6 C8 C7 -55.3(4) .
C4 C6 C8 C7 124.6(3) .
C32 C6 C8 C9 124.1(3) .
C4 C6 C8 C9 -56.1(4) .
C7 C8 C9 C10 -0.8(4) .
C6 C8 C9 C10 179.8(3) .
C8 C9 C10 C11 1.0(4) .
C7 N1 C11 C10 -1.7(4) .
Os N1 C11 C10 172.0(2) .
C7 N1 C11 C12 179.0(2) .
Os N1 C11 C12 -7.2(3) .
C9 C10 C11 N1 0.3(4) .
C9 C10 C11 C12 179.4(3) .
C16 N2 C12 C13 0.7(4) .
Os N2 C12 C13 -179.8(2) .
C16 N2 C12 C11 -178.3(2) .
Os N2 C12 C11 1.2(3) .
N1 C11 C12 N2 4.1(3) .
C10 C11 C12 N2 -175.2(3) .
N1 C11 C12 C13 -174.8(3) .
C10 C11 C12 C13 6.0(5) .
N2 C12 C13 C14 -0.8(4) .
C11 C12 C13 C14 178.0(3) .
C12 C13 C14 C15 -0.2(5) .
C13 C14 C15 C16 1.3(5) .
C12 N2 C16 C15 0.5(4) .
Os N2 C16 C15 -179.1(2) .
C12 N2 C16 C17 -178.8(2) .
Os N2 C16 C17 1.6(3) .
C14 C15 C16 N2 -1.5(4) .
C14 C15 C16 C17 177.8(3) .
C21 N3 C17 C18 -3.1(4) .
Os N3 C17 C18 171.6(2) .
C21 N3 C17 C16 177.2(2) .
Os N3 C17 C16 -8.1(3) .
N2 C16 C17 N3 4.5(3) .
C15 C16 C17 N3 -174.8(3) .
N2 C16 C17 C18 -175.3(2) .
C15 C16 C17 C18 5.4(4) .
N3 C17 C18 C19 1.4(4) .
C16 C17 C18 C19 -178.9(3) .
C17 C18 C19 C20 1.0(4) .
C18 C19 C20 C21 -1.7(4) .
C18 C19 C20 C22 179.2(3) .
C17 N3 C21 C20 2.4(4) .
Os N3 C21 C20 -171.54(19) .
C19 C20 C21 N3 0.0(4) .
C22 C20 C21 N3 179.1(2) .
C21 C20 C22 C23 124.3(3) .
C19 C20 C22 C23 -56.6(4) .
C21 C20 C22 C29 -56.6(4) .
C19 C20 C22 C29 122.5(3) .
C29 C22 C23 C25 -2.6(4) .
C20 C22 C23 C25 176.4(3) .
C29 C22 C23 C24 176.7(3) .
C20 C22 C23 C24 -4.3(4) .
C22 C23 C25 C26 0.8(5) .
C24 C23 C25 C26 -178.6(3) .
C27 O2 C26 C25 7.8(5) .
C27 O2 C26 C28 -171.3(3) .
C23 C25 C26 O2 -177.0(3) .
C23 C25 C26 C28 2.0(5) .
O2 C26 C28 C29 176.2(3) .
C25 C26 C28 C29 -2.9(5) .
C26 C28 C29 C22 1.0(4) .
C26 C28 C29 C30 -176.8(3) .
C23 C22 C29 C28 1.8(4) .
C20 C22 C29 C28 -177.3(3) .
C23 C22 C29 C30 179.5(3) .
C20 C22 C29 C30 0.4(4) .
C4 C6 C32 C33 1.3(4) .
C8 C6 C32 C33 -178.8(2) .
C4 C6 C32 C31 -179.4(3) .
C8 C6 C32 C31 0.5(4) .
O1 C2 C33 C32 177.9(3) .
C3 C2 C33 C32 -1.8(4) .
C6 C32 C33 C2 0.3(4) .
C31 C32 C33 C2 -179.0(3) .
