#------------------------------------------------------------------------------
#$Date: 2017-04-05 11:40:13 +0200 (Wed 05 de Apr de 2017) $
#$Revision: 195052 $
#$URL: svn://www.crystallography.net/cod/cif/7/04/14/7041420.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7041420
loop_
_publ_author_name
'Zhou, Guo-Jun'
'Ding, You-Song'
'Zheng, Yan-Zhen'
_publ_section_title
;
 Dy(iii)-Carboxylate chain containing quasi-D5h sites exhibits enhanced
 energy barrier for magnetization reversal.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3100
_journal_page_last               3104
_journal_paper_doi               10.1039/c6dt04366f
_journal_volume                  46
_journal_year                    2017
_chemical_formula_moiety         '0.5(C64 H130 Dy6 O42), 2(C6 H5 N3)'
_chemical_formula_sum            'C44 H75 Dy3 N6 O21'
_chemical_formula_weight         1511.60
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2016-11-11
_audit_creation_method
;
Olex2 1.2
(compiled 2016.09.09 svn.r3337 for OlexSys, GUI svn.r5227)
;
_audit_update_record
;
2016-11-13 deposited with the CCDC.
2016-12-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 129.133(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   31.340(8)
_cell_length_b                   13.874(3)
_cell_length_c                   20.741(10)
_cell_measurement_reflns_used    5286
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.166
_cell_measurement_theta_min      2.462
_cell_volume                     6995(4)
_computing_cell_refinement       'SAINT v8.27A (Bruker, 2012)'
_computing_data_reduction        'SAINT v8.27A (Bruker, 2012)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_diffrn_ambient_temperature      296.15
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_unetI/netI     0.0562
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       39
_diffrn_reflns_limit_h_min       -40
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            23827
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.658
_diffrn_reflns_theta_min         1.675
_exptl_absorpt_coefficient_mu    3.234
_exptl_absorpt_correction_T_max  0.851
_exptl_absorpt_correction_T_min  0.610
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.435
_exptl_crystal_description       block
_exptl_crystal_F_000             2988
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.118
_refine_diff_density_min         -0.846
_refine_diff_density_rms         0.105
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.011
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     323
_refine_ls_number_reflns         8080
_refine_ls_number_restraints     400
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0700
_refine_ls_R_factor_gt           0.0378
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0447P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0874
_refine_ls_wR_factor_ref         0.0987
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5432
_reflns_number_total             8080
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt04366f2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7041419--7041420.cif.'
_cod_original_cell_volume        6996(4)
_cod_database_code               7041420
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups, All O(H) groups, All O(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Rigid bond restraints
 C2, C3
 with sigma for 1-2 distances of 0.02 and sigma for 1-3 distances of 0.02
3. Uiso/Uaniso restraints and constraints
Uanis(C6) \\sim Ueq, Uanis(C15) \\sim Ueq, Uanis(C3) \\sim Ueq, Uanis(C7) \\sim
Ueq, Uanis(C8) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of
0.005
Uanis(C14) = Uanis(C15)
Uanis(C2) = Uanis(C3)
4. Rigid body (RIGU) restrains
 All non-hydrogen atoms
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5. Others
 Fixed Sof: H2(0.5)
6.a Riding coordinates:
 O1(H1A,H1B), O2(H2), O9(H9A,H9B)
6.b Ternary CH refined with riding coordinates:
 C2(H2A), C6(H6), C10(H10), C14(H14)
6.c Me refined with riding coordinates:
 C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C11(H11A,
 H11B,H11C), C12(H12C,H12A,H12B), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C)
6.d Aromatic/amide H refined with riding coordinates:
 N2(H2B), C18(H18), C19(H19), C20(H20), C21(H21)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Dy1 Dy 1.0000 0.32361(3) 0.2500 0.04897(11) Uani 1 2 d S TU P
Dy2 Dy 0.82564(2) 0.25050(2) 0.12020(2) 0.03783(8) Uani 1 1 d . U .
O1 O 0.94225(14) 0.4608(3) 0.1838(2) 0.0782(13) Uani 1 1 d . U .
H1A H 0.9079 0.4700 0.1557 0.094 Uiso 1 1 d R . .
H1B H 0.9536 0.4952 0.1634 0.094 Uiso 1 1 d R . .
O2 O 1.0000 0.1556(4) 0.2500 0.0804(19) Uani 1 2 d S TU P
H2 H 0.9702 0.1250 0.2155 0.097 Uiso 0.5 1 d R . .
O3 O 0.96989(15) 0.3251(3) 0.3222(2) 0.0757(12) Uani 1 1 d . U .
O4 O 0.88039(14) 0.3309(3) 0.2441(2) 0.0642(10) Uani 1 1 d . U .
O5 O 0.91402(13) 0.2743(3) 0.1303(2) 0.0498(9) Uani 1 1 d . U .
O6 O 0.83899(13) 0.2060(3) 0.0231(2) 0.0534(9) Uani 1 1 d . U .
O7 O 0.88952(15) 0.1180(3) 0.1924(2) 0.0665(10) Uani 1 1 d . U .
O8 O 0.83187(15) 0.1372(3) 0.2155(2) 0.0631(10) Uani 1 1 d . U .
O9 O 0.76068(12) 0.3154(2) 0.12968(19) 0.0487(8) Uani 1 1 d . U .
H9A H 0.7606 0.3677 0.1510 0.058 Uiso 1 1 d R . .
H9B H 0.7295 0.3091 0.0819 0.058 Uiso 1 1 d R . .
O10 O 0.74861(13) 0.1558(2) 0.0231(2) 0.0460(8) Uani 1 1 d . U .
O11 O 0.67150(12) 0.0881(2) -0.0784(2) 0.0494(8) Uani 1 1 d . U .
N1 N 0.7608(2) 0.4855(4) 0.1994(3) 0.0744(14) Uani 1 1 d . U .
N2 N 0.7250(2) 0.5896(4) 0.2291(3) 0.0684(13) Uani 1 1 d . U .
H2B H 0.7049 0.6135 0.2400 0.082 Uiso 1 1 calc R . .
N3 N 0.7267(2) 0.4958(4) 0.2156(4) 0.0797(15) Uani 1 1 d . U .
C1 C 0.8870(2) 0.2358(4) 0.0585(3) 0.0494(13) Uani 1 1 d . U .
C2 C 0.9115(4) 0.2307(6) 0.0153(5) 0.1028(18) Uani 1 1 d . U .
H2A H 0.9517 0.2289 0.0570 0.123 Uiso 1 1 calc R . .
C3 C 0.8930(3) 0.1492(6) -0.0398(5) 0.1028(18) Uani 1 1 d . U .
H3A H 0.9102 0.1505 -0.0651 0.154 Uiso 1 1 calc R . .
H3B H 0.9027 0.0906 -0.0087 0.154 Uiso 1 1 calc R . .
H3C H 0.8538 0.1522 -0.0822 0.154 Uiso 1 1 calc R . .
C4 C 0.8933(4) 0.3290(7) -0.0350(6) 0.142(3) Uani 1 1 d . U .
H4A H 0.9059 0.3822 0.0027 0.212 Uiso 1 1 calc R . .
H4B H 0.9089 0.3331 -0.0624 0.212 Uiso 1 1 calc R . .
H4C H 0.8539 0.3312 -0.0756 0.212 Uiso 1 1 calc R . .
C5 C 0.9268(2) 0.3424(4) 0.3112(3) 0.0557(14) Uani 1 1 d . U .
C6 C 0.9330(4) 0.3725(7) 0.3867(5) 0.117(3) Uani 1 1 d . U .
H6 H 0.9651 0.3409 0.4365 0.141 Uiso 1 1 calc R . .
C7 C 0.9428(6) 0.4769(10) 0.3906(8) 0.221(5) Uani 1 1 d . U .
H7A H 0.9744 0.4880 0.3940 0.332 Uiso 1 1 calc R . .
H7B H 0.9112 0.5073 0.3416 0.332 Uiso 1 1 calc R . .
H7C H 0.9493 0.5034 0.4389 0.332 Uiso 1 1 calc R . .
C8 C 0.8859(5) 0.3581(9) 0.3818(7) 0.181(4) Uani 1 1 d . U .
H8A H 0.8788 0.2903 0.3792 0.271 Uiso 1 1 calc R . .
H8B H 0.8926 0.3852 0.4301 0.271 Uiso 1 1 calc R . .
H8C H 0.8546 0.3891 0.3328 0.271 Uiso 1 1 calc R . .
C9 C 0.8726(2) 0.0951(4) 0.2322(3) 0.0621(15) Uani 1 1 d . U .
C10 C 0.9019(3) 0.0186(6) 0.2993(5) 0.101(2) Uani 1 1 d . U .
H10 H 0.8741 -0.0130 0.2996 0.121 Uiso 1 1 calc R . .
C11 C 0.9415(4) 0.0659(8) 0.3814(5) 0.161(4) Uani 1 1 d . U .
H11A H 0.9227 0.1134 0.3888 0.242 Uiso 1 1 calc R . .
H11B H 0.9575 0.0184 0.4246 0.242 Uiso 1 1 calc R . .
H11C H 0.9700 0.0964 0.3839 0.242 Uiso 1 1 calc R . .
C12 C 0.9266(4) -0.0578(7) 0.2804(7) 0.160(4) Uani 1 1 d . U .
H12C H 0.8985 -0.0848 0.2265 0.239 Uiso 1 1 calc R . .
H12A H 0.9548 -0.0298 0.2809 0.239 Uiso 1 1 calc R . .
H12B H 0.9423 -0.1077 0.3216 0.239 Uiso 1 1 calc R . .
C13 C 0.71671(19) 0.0832(4) -0.0065(3) 0.0418(11) Uani 1 1 d . U .
C14 C 0.7349(3) -0.0073(5) 0.0444(5) 0.0960(16) Uani 1 1 d . U .
H14 H 0.7537 0.0102 0.1025 0.115 Uiso 1 1 calc R . .
C15 C 0.6899(3) -0.0757(5) 0.0167(4) 0.0960(16) Uani 1 1 d . U .
H15A H 0.7048 -0.1313 0.0521 0.144 Uiso 1 1 calc R . .
H15B H 0.6637 -0.0449 0.0194 0.144 Uiso 1 1 calc R . .
H15C H 0.6721 -0.0951 -0.0395 0.144 Uiso 1 1 calc R . .
C16 C 0.7768(4) -0.0581(6) 0.0387(5) 0.126(3) Uani 1 1 d . U .
H16A H 0.8062 -0.0145 0.0566 0.188 Uiso 1 1 calc R . .
H16B H 0.7915 -0.1141 0.0738 0.188 Uiso 1 1 calc R . .
H16C H 0.7585 -0.0772 -0.0177 0.188 Uiso 1 1 calc R . .
C17 C 0.7820(2) 0.5752(5) 0.2051(3) 0.0623(14) Uani 1 1 d . U .
C18 C 0.8208(3) 0.6033(5) 0.1959(4) 0.086(2) Uani 1 1 d . U .
H18 H 0.8370 0.5586 0.1839 0.103 Uiso 1 1 calc R . .
C19 C 0.8337(3) 0.6976(6) 0.2051(5) 0.100(2) Uani 1 1 d . U .
H19 H 0.8595 0.7182 0.1997 0.120 Uiso 1 1 calc R . .
C20 C 0.8094(4) 0.7649(5) 0.2228(5) 0.094(2) Uani 1 1 d . U .
H20 H 0.8191 0.8294 0.2280 0.112 Uiso 1 1 calc R . .
C21 C 0.7721(3) 0.7398(5) 0.2325(4) 0.0768(18) Uani 1 1 d . U .
H21 H 0.7563 0.7852 0.2446 0.092 Uiso 1 1 calc R . .
C22 C 0.7584(2) 0.6411(4) 0.2234(3) 0.0583(14) Uani 1 1 d . U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O1 73.57(18) 2_755 .
O2 Dy1 O1 143.22(9) . 2_755
O2 Dy1 O1 143.22(9) . .
O2 Dy1 O5 72.95(9) . .
O2 Dy1 O5 72.95(9) . 2_755
O3 Dy1 O1 83.65(15) . .
O3 Dy1 O1 95.48(16) 2_755 .
O3 Dy1 O1 83.65(15) 2_755 2_755
O3 Dy1 O1 95.48(16) . 2_755
O3 Dy1 O2 90.54(12) 2_755 .
O3 Dy1 O2 90.54(12) . .
O3 Dy1 O3 178.9(2) . 2_755
O3 Dy1 O5 91.33(13) . .
O3 Dy1 O5 88.99(13) 2_755 .
O3 Dy1 O5 88.99(13) . 2_755
O3 Dy1 O5 91.32(13) 2_755 2_755
O5 Dy1 O1 70.92(13) . .
O5 Dy1 O1 70.92(13) 2_755 2_755
O5 Dy1 O1 142.80(13) 2_755 .
O5 Dy1 O1 142.80(13) . 2_755
O5 Dy1 O5 145.91(18) . 2_755
O4 Dy2 O5 81.09(12) . .
O4 Dy2 O6 131.98(12) . .
O4 Dy2 O7 86.22(14) . .
O4 Dy2 O8 77.53(14) . .
O4 Dy2 O9 78.11(12) . .
O4 Dy2 O10 121.27(13) . 7_655
O4 Dy2 O10 151.22(13) . .
O4 Dy2 O11 77.30(13) . 7_655
O4 Dy2 C1 107.01(14) . .
O4 Dy2 C9 79.35(15) . .
O4 Dy2 C13 99.02(14) . 7_655
O5 Dy2 O10 99.16(10) . 7_655
O5 Dy2 C1 25.98(12) . .
O5 Dy2 C9 93.10(15) . .
O5 Dy2 C13 83.50(12) . 7_655
O6 Dy2 O5 50.95(10) . .
O6 Dy2 O7 78.95(13) . .
O6 Dy2 O8 123.51(13) . .
O6 Dy2 O10 71.44(12) . 7_655
O6 Dy2 O11 82.59(13) . 7_655
O6 Dy2 C1 24.98(12) . .
O6 Dy2 C9 102.74(16) . .
O6 Dy2 C13 75.93(13) . 7_655
O7 Dy2 O5 68.41(12) . .
O7 Dy2 O8 52.80(13) . .
O7 Dy2 O10 148.69(12) . 7_655
O7 Dy2 O11 136.15(12) . 7_655
O7 Dy2 C1 72.59(14) . .
O7 Dy2 C9 26.83(14) . .
O7 Dy2 C13 150.35(13) . 7_655
O8 Dy2 O5 118.00(12) . .
O8 Dy2 O10 141.31(11) . 7_655
O8 Dy2 C1 125.07(14) . .
O8 Dy2 C9 26.06(14) . .
O8 Dy2 C13 156.83(13) . 7_655
O9 Dy2 O5 149.38(11) . .
O9 Dy2 O6 142.68(11) . .
O9 Dy2 O7 131.54(13) . .
O9 Dy2 O8 78.98(12) . .
O9 Dy2 O10 73.44(11) . 7_655
O9 Dy2 O11 84.57(12) . 7_655
O9 Dy2 C1 155.86(13) . .
O9 Dy2 C9 104.75(16) . .
O9 Dy2 C13 77.90(12) . 7_655
O10 Dy2 O5 126.47(11) . .
O10 Dy2 O6 76.30(12) . .
O10 Dy2 O7 96.16(13) . .
O10 Dy2 O8 81.17(13) . .
O10 Dy2 O9 79.00(11) . .
O10 Dy2 O10 67.45(13) . 7_655
O10 Dy2 O11 117.52(11) . 7_655
O10 Dy2 C1 84.20(13) 7_655 .
O10 Dy2 C1 101.02(13) . .
O10 Dy2 C9 157.30(14) 7_655 .
O10 Dy2 C9 89.90(14) . .
O10 Dy2 C13 25.52(10) 7_655 7_655
O10 Dy2 C13 92.97(13) . 7_655
O11 Dy2 O5 69.03(11) 7_655 .
O11 Dy2 O8 152.25(12) 7_655 .
O11 Dy2 O10 50.09(10) 7_655 7_655
O11 Dy2 C1 73.96(13) 7_655 .
O11 Dy2 C9 152.44(14) 7_655 .
O11 Dy2 C13 24.56(11) 7_655 7_655
C1 Dy2 C13 78.00(14) . 7_655
C9 Dy2 C1 99.39(17) . .
C9 Dy2 C13 176.44(15) . 7_655
C5 O3 Dy1 139.0(4) . .
C5 O4 Dy2 147.7(4) . .
Dy1 O5 Dy2 124.44(14) . .
C1 O5 Dy1 146.5(3) . .
C1 O5 Dy2 88.1(3) . .
C1 O6 Dy2 101.9(3) . .
C9 O7 Dy2 94.0(3) . .
C9 O8 Dy2 94.1(3) . .
Dy2 O10 Dy2 112.55(13) . 7_655
C13 O10 Dy2 88.9(3) . 7_655
C13 O10 Dy2 158.5(3) . .
C13 O11 Dy2 101.9(3) . 7_655
N3 N1 C17 107.8(5) . .
C22 N2 N3 111.4(5) . .
N1 N3 N2 107.8(5) . .
O5 C1 Dy2 66.0(3) . .
O5 C1 C2 120.2(5) . .
O6 C1 Dy2 53.1(2) . .
O6 C1 O5 119.0(5) . .
O6 C1 C2 120.7(5) . .
C2 C1 Dy2 172.3(5) . .
C1 C2 C4 104.0(6) . .
C3 C2 C1 114.0(7) . .
C3 C2 C4 110.8(8) . .
O3 C5 C6 116.7(5) . .
O4 C5 O3 123.6(5) . .
O4 C5 C6 119.5(5) . .
C7 C6 C5 102.4(9) . .
C8 C6 C5 115.9(8) . .
C8 C6 C7 108.2(10) . .
O7 C9 Dy2 59.1(3) . .
O7 C9 C10 120.8(6) . .
O8 C9 Dy2 59.8(3) . .
O8 C9 O7 118.7(5) . .
O8 C9 C10 120.5(6) . .
C10 C9 Dy2 174.3(5) . .
C11 C10 C9 109.1(7) . .
C11 C10 C12 114.5(7) . .
C12 C10 C9 111.6(7) . .
O10 C13 Dy2 65.5(2) . 7_655
O10 C13 C14 119.3(5) . .
O11 C13 Dy2 53.5(2) . 7_655
O11 C13 O10 119.0(4) . .
O11 C13 C14 121.7(5) . .
C14 C13 Dy2 174.7(4) . 7_655
C13 C14 C16 106.9(6) . .
C15 C14 C13 114.6(5) . .
C15 C14 C16 108.7(7) . .
N1 C17 C18 130.7(6) . .
C22 C17 N1 108.1(5) . .
C22 C17 C18 121.1(6) . .
C19 C18 C17 117.5(7) . .
C18 C19 C20 121.4(8) . .
C21 C20 C19 122.4(7) . .
C20 C21 C22 116.7(7) . .
N2 C22 C17 104.8(5) . .
N2 C22 C21 134.3(6) . .
C17 C22 C21 120.9(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.376(4) 2_755
Dy1 O1 2.376(4) .
Dy1 O2 2.330(6) .
Dy1 O3 2.218(4) 2_755
Dy1 O3 2.218(4) .
Dy1 O5 2.334(3) 2_755
Dy1 O5 2.334(3) .
Dy2 O4 2.286(4) .
Dy2 O5 2.663(3) .
Dy2 O6 2.382(3) .
Dy2 O7 2.418(4) .
Dy2 O8 2.435(4) .
Dy2 O9 2.345(3) .
Dy2 O10 2.685(3) 7_655
Dy2 O10 2.340(3) .
Dy2 O11 2.423(3) 7_655
Dy2 C1 2.914(5) .
Dy2 C9 2.810(6) .
Dy2 C13 2.949(5) 7_655
O3 C5 1.242(6) .
O4 C5 1.235(6) .
O5 C1 1.277(6) .
O6 C1 1.258(6) .
O7 C9 1.271(6) .
O8 C9 1.237(6) .
O10 Dy2 2.685(3) 7_655
O10 C13 1.271(5) .
O11 Dy2 2.423(3) 7_655
O11 C13 1.253(5) .
N1 N3 1.313(6) .
N1 C17 1.379(7) .
N2 N3 1.339(6) .
N2 C22 1.335(7) .
C1 C2 1.503(8) .
C2 C3 1.444(10) .
C2 C4 1.588(12) .
C5 C6 1.511(9) .
C6 C7 1.472(14) .
C6 C8 1.428(12) .
C9 C10 1.515(8) .
C10 C11 1.485(11) .
C10 C12 1.504(11) .
C13 Dy2 2.949(5) 7_655
C13 C14 1.502(8) .
C14 C15 1.482(8) .
C14 C16 1.558(10) .
C17 C18 1.400(8) .
C17 C22 1.371(7) .
C18 C19 1.347(10) .
C19 C20 1.394(10) .
C20 C21 1.349(10) .
C21 C22 1.410(8) .
