#------------------------------------------------------------------------------
#$Date: 2016-02-14 05:40:26 +0100 (dom 14 de feb de 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/87/7108749.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7108749
loop_
_publ_author_name
'Jiehu Cui'
'Yizhi Li'
'Zijian Guo'
'Hegen Zheng'
_publ_section_title
;
 A porous metal-organic framework based on Zn6O2 clusters:: chemical
 stability, gas adsorption properties and solvatochromic behavior
;
_journal_name_full               Chem.Commun.
_journal_page_first              555
_journal_paper_doi               10.1039/c2cc36713k
_journal_volume                  49
_journal_year                    2013
_chemical_formula_sum            'C45 H38 O24 Zn5'
_chemical_formula_weight         1289.60
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.7110(10)
_cell_angle_beta                 99.7730(10)
_cell_angle_gamma                97.9730(10)
_cell_formula_units_Z            1
_cell_length_a                   6.3303(4)
_cell_length_b                   12.6819(8)
_cell_length_c                   15.6877(10)
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      0.994
_cell_volume                     1219.33(13)
_computing_cell_refinement       'SMART (Bruker, 2000)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SMART (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0678
_diffrn_reflns_av_sigmaI/netI    0.0621
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            6878
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    2.511
_exptl_absorpt_correction_T_max  0.605
_exptl_absorpt_correction_T_min  0.553
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.756
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             650
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         2.363
_refine_diff_density_min         -0.686
_refine_diff_density_rms         0.133
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     363
_refine_ls_number_reflns         4265
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.326
_refine_ls_R_factor_all          0.0519
_refine_ls_R_factor_gt           0.0462
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1098P)²+0.0200P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1486
_refine_ls_wR_factor_ref         0.1540
_reflns_number_gt                3631
_reflns_number_total             4265
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc36713k.txt
_cod_data_source_block           2
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_original_sg_symbol_H-M      'P -1 '
_cod_database_code               7108749
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3298(11) 0.8032(5) 0.2201(4) 0.0293(14) Uani 1 1 d . . .
C2 C 0.4019(10) 0.7201(5) 0.2751(4) 0.0266(13) Uani 1 1 d . . .
C3 C 0.3004(10) 0.6965(5) 0.3443(4) 0.0254(13) Uani 1 1 d . . .
H3 H 0.1882 0.7321 0.3565 0.031 Uiso 1 1 calc R . .
C4 C 0.3670(10) 0.6198(5) 0.3948(4) 0.0252(13) Uani 1 1 d . . .
C5 C 0.5351(11) 0.5660(5) 0.3781(4) 0.0290(14) Uani 1 1 d . . .
H5 H 0.5791 0.5141 0.4120 0.035 Uiso 1 1 calc R . .
C6 C 0.6358(10) 0.5921(5) 0.3091(4) 0.0282(14) Uani 1 1 d . . .
C7 C 0.5715(10) 0.6677(5) 0.2573(4) 0.0293(14) Uani 1 1 d . . .
H7 H 0.6405 0.6835 0.2113 0.035 Uiso 1 1 calc R . .
C8 C 0.7939(10) 0.4560(5) 0.2383(4) 0.0257(13) Uani 1 1 d . . .
C9 C 0.9847(10) 0.4215(5) 0.2243(4) 0.0337(15) Uani 1 1 d . . .
H9 H 1.1180 0.4597 0.2531 0.040 Uiso 1 1 calc R . .
C10 C 0.9760(10) 0.3304(5) 0.1674(4) 0.0292(14) Uani 1 1 d . . .
H10 H 1.1044 0.3072 0.1583 0.035 Uiso 1 1 calc R . .
C11 C 0.7788(9) 0.2727(4) 0.1234(4) 0.0209(12) Uani 1 1 d . . .
C12 C 0.5893(10) 0.3082(5) 0.1374(4) 0.0308(15) Uani 1 1 d . . .
H12 H 0.4559 0.2703 0.1083 0.037 Uiso 1 1 calc R . .
C13 C 0.5970(10) 0.4002(5) 0.1947(4) 0.0346(16) Uani 1 1 d . . .
H13 H 0.4690 0.4240 0.2037 0.041 Uiso 1 1 calc R . .
C14 C 0.7749(9) 0.1730(4) 0.0636(4) 0.0206(12) Uani 1 1 d . . .
C15 C 0.2443(11) 0.6708(5) 0.5246(4) 0.0264(13) Uani 1 1 d . . .
C16 C 0.0497(11) 0.6687(6) 0.5526(4) 0.0386(16) Uani 1 1 d . . .
H16 H -0.0675 0.6157 0.5278 0.046 Uiso 1 1 calc R . .
C17 C 0.0299(11) 0.7459(6) 0.6181(4) 0.0375(16) Uani 1 1 d . . .
H17 H -0.1027 0.7460 0.6361 0.045 Uiso 1 1 calc R . .
C18 C 0.2052(10) 0.8230(5) 0.6571(4) 0.0249(13) Uani 1 1 d . . .
C19 C 0.4010(11) 0.8230(6) 0.6296(5) 0.0390(17) Uani 1 1 d . . .
H19 H 0.5202 0.8740 0.6561 0.047 Uiso 1 1 calc R . .
C20 C 0.4203(11) 0.7468(6) 0.5624(4) 0.0387(17) Uani 1 1 d . . .
H20 H 0.5515 0.7473 0.5432 0.046 Uiso 1 1 calc R . .
C21 C 0.1852(10) 0.9066(5) 0.7289(4) 0.0265(13) Uani 1 1 d . . .
C24 C 0.836(4) 0.0222(17) 0.5371(11) 0.208(12) Uani 1 1 d . . .
H24A H 0.8819 0.0340 0.5993 0.311 Uiso 1 1 calc R . .
H24B H 0.7183 -0.0369 0.5218 0.311 Uiso 1 1 calc R . .
H24C H 0.7879 0.0856 0.5172 0.311 Uiso 1 1 calc R . .
C25 C 1.0000 0.0000 0.5000 0.087(6) Uani 1 2 d S . .
O1 O 0.2503(6) 1.0196(3) 0.1078(2) 0.0214(9) Uani 1 1 d . . .
H1A H 0.2890 1.0865 0.1240 0.026 Uiso 1 1 d R . .
O2 O -0.1870(6) 0.9179(3) 0.0870(2) 0.0224(9) Uani 1 1 d . . .
H2A H -0.2999 0.9446 0.0939 0.027 Uiso 1 1 d R . .
O3 O 0.4201(8) 0.8184(4) 0.1558(3) 0.0373(11) Uani 1 1 d . . .
O4 O 0.1816(9) 0.8515(4) 0.2430(3) 0.0447(13) Uani 1 1 d . . .
O5 O 0.8191(7) 0.5462(4) 0.2974(3) 0.0358(11) Uani 1 1 d . . .
O6 O 0.9528(6) 0.1512(3) 0.0479(3) 0.0276(10) Uani 1 1 d . . .
O7 O 0.5911(6) 0.1152(3) 0.0325(3) 0.0240(9) Uani 1 1 d . . .
O8 O 0.2614(8) 0.5890(3) 0.4611(3) 0.0335(11) Uani 1 1 d . . .
O9 O 0.3540(7) 0.9548(4) 0.7769(3) 0.0393(12) Uani 1 1 d . . .
O10 O -0.0080(7) 0.9223(4) 0.7343(3) 0.0364(11) Uani 1 1 d . . .
O12 O 1.178(3) 0.0923(13) 0.5621(10) 0.506(13) Uani 1 1 d U . .
H12A H 1.1403 0.1533 0.5562 0.759 Uiso 1 1 d R . .
O11 O 0.200(3) 0.5248(13) 1.0250(10) 0.039(6) Uani 0.250(13) 1 d PR A 1
H11A H 0.2173 0.5915 1.0437 0.058 Uiso 0.250(13) 1 d PR A 1
H11B H 0.0693 0.4966 1.0251 0.058 Uiso 0.250(13) 1 d PR A 1
O13 O 0.062(4) 0.357(2) 0.9505(15) 0.057(8) Uani 0.250(13) 1 d P A 1
H13B H 0.0760 0.4202 0.9769 0.085 Uiso 0.250(13) 1 d PR A 1
H13C H -0.0696 0.3266 0.9440 0.085 Uiso 0.250(13) 1 d PR A 1
O11' O 0.050(3) 0.4541(15) 0.9873(11) 0.028(6) Uani 0.250(13) 1 d P . 2
H11H H 0.0848 0.4505 0.9371 0.034 Uiso 0.250(13) 1 d PR A 2
H11E H 0.0687 0.5196 1.0097 0.042 Uiso 0.250(13) 1 d PR A 2
O13' O 0.167(4) 0.307(2) 0.9365(15) 0.048(7) Uani 0.250(13) 1 d P A 2
H13D H 0.2547 0.2718 0.9640 0.058 Uiso 0.250(13) 1 d PR A 2
H13E H 0.0382 0.2737 0.9317 0.058 Uiso 0.250(13) 1 d PR A 2
Zn1 Zn 0.0000 1.0000 0.0000 0.0228(3) Uani 1 2 d S . .
Zn2 Zn 0.51997(10) 0.95383(6) 0.10046(4) 0.0217(3) Uani 1 1 d . . .
Zn3 Zn 0.05860(11) 0.96181(6) 0.18612(4) 0.0249(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 C1 O4 126.2(6) . .
O3 C1 C2 117.4(5) . .
O4 C1 C2 116.4(5) . .
C3 C2 C7 120.2(6) . .
C3 C2 C1 119.8(5) . .
C7 C2 C1 120.0(6) . .
C4 C3 C2 119.7(5) . .
C4 C3 H3 120.2 . .
C2 C3 H3 120.2 . .
C3 C4 O8 121.5(5) . .
C3 C4 C5 121.2(6) . .
O8 C4 C5 117.2(5) . .
C4 C5 C6 118.0(6) . .
C4 C5 H5 121.0 . .
C6 C5 H5 121.0 . .
C7 C6 C5 122.0(6) . .
C7 C6 O5 119.6(6) . .
C5 C6 O5 118.2(6) . .
C6 C7 C2 118.9(6) . .
C6 C7 H7 120.5 . .
C2 C7 H7 120.5 . .
O5 C8 C13 124.6(5) . .
O5 C8 C9 115.3(5) . .
C13 C8 C9 120.1(5) . .
C10 C9 C8 119.6(6) . .
C10 C9 H9 120.2 . .
C8 C9 H9 120.2 . .
C9 C10 C11 121.1(5) . .
C9 C10 H10 119.5 . .
C11 C10 H10 119.5 . .
C12 C11 C10 118.9(5) . .
C12 C11 C14 121.4(5) . .
C10 C11 C14 119.7(5) . .
C11 C12 C13 120.3(6) . .
C11 C12 H12 119.8 . .
C13 C12 H12 119.8 . .
C8 C13 C12 120.0(5) . .
C8 C13 H13 120.0 . .
C12 C13 H13 120.0 . .
O6 C14 O7 124.5(5) . .
O6 C14 C11 117.7(5) . .
O7 C14 C11 117.8(5) . .
C20 C15 C16 120.8(6) . .
C20 C15 O8 121.2(6) . .
C16 C15 O8 117.9(6) . .
C15 C16 C17 119.4(6) . .
C15 C16 H16 120.3 . .
C17 C16 H16 120.3 . .
C16 C17 C18 120.7(6) . .
C16 C17 H17 119.7 . .
C18 C17 H17 119.7 . .
C19 C18 C17 119.4(6) . .
C19 C18 C21 119.7(6) . .
C17 C18 C21 120.9(6) . .
C18 C19 C20 120.1(6) . .
C18 C19 H19 119.9 . .
C20 C19 H19 119.9 . .
C15 C20 C19 119.6(6) . .
C15 C20 H20 120.2 . .
C19 C20 H20 120.2 . .
O9 C21 O10 125.7(5) . .
O9 C21 C18 118.1(5) . .
O10 C21 C18 116.2(5) . .
C25 C24 H24A 109.5 . .
C25 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C25 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C24 C25 C24 179.998(9) 2_756 .
C24 C25 O12 94.9(12) 2_756 2_756
C24 C25 O12 85.1(12) . 2_756
C24 C25 O12 85.1(12) 2_756 .
C24 C25 O12 94.9(12) . .
O12 C25 O12 179.998(2) 2_756 .
Zn3 O1 Zn2 117.51(19) . .
Zn3 O1 Zn1 93.96(16) . .
Zn2 O1 Zn1 120.22(18) . .
Zn3 O1 H1A 108.0 . .
Zn2 O1 H1A 108.0 . .
Zn1 O1 H1A 108.0 . .
Zn3 O2 Zn2 118.65(18) . 1_455
Zn3 O2 Zn1 90.73(16) . .
Zn2 O2 Zn1 120.58(19) 1_455 .
Zn3 O2 H2A 113.5 . .
Zn2 O2 H2A 10.2 1_455 .
Zn1 O2 H2A 113.5 . .
C1 O3 Zn2 133.6(4) . .
C1 O4 Zn3 125.8(4) . .
C8 O5 C6 118.8(5) . .
C14 O6 Zn1 124.0(4) . 1_645
C14 O7 Zn2 125.8(4) . 2_665
C14 O7 Zn2 114.5(4) . 1_545
Zn2 O7 Zn2 98.14(15) 2_665 1_545
C4 O8 C15 116.3(5) . .
C21 O9 Zn2 143.9(4) . 2_676
C21 O10 Zn3 121.0(4) . 2_576
C25 O12 H12A 109.5 . .
H11A O11 H11B 109.4 . .
H11A O11 H11E 94.4 . .
H11B O11 H11E 27.4 . .
H13B O13 H13C 109.4 . .
H13B O13 H11H 38.8 . .
H13C O13 H11H 114.5 . .
H13B O13 H13E 167.0 . .
H13C O13 H13E 66.0 . .
H11H O13 H13E 154.1 . .
O11' O11' H11B 43.8 2_567 .
O11' O11' H13B 173.4 2_567 .
H11B O11' H13B 141.6 . .
O11' O11' H11H 116.4 2_567 .
H11B O11' H11H 134.2 . .
H13B O11' H11H 63.4 . .
O11' O11' H11E 32.8 2_567 .
H11B O11' H11E 27.7 . .
H13B O11' H11E 153.7 . .
H11H O11' H11E 109.5 . .
H13D O13' H13E 108.3 . .
O6 Zn1 O6 180.0(2) 2_665 1_465
O6 Zn1 O1 95.40(15) 2_665 .
O6 Zn1 O1 84.60(15) 1_465 .
O6 Zn1 O1 84.60(15) 2_665 2_575
O6 Zn1 O1 95.40(15) 1_465 2_575
O1 Zn1 O1 180.00(16) . 2_575
O6 Zn1 O2 86.11(16) 2_665 .
O6 Zn1 O2 93.89(16) 1_465 .
O1 Zn1 O2 83.02(15) . .
O1 Zn1 O2 96.98(15) 2_575 .
O6 Zn1 O2 93.89(16) 2_665 2_575
O6 Zn1 O2 86.11(16) 1_465 2_575
O1 Zn1 O2 96.98(15) . 2_575
O1 Zn1 O2 83.02(15) 2_575 2_575
O2 Zn1 O2 180.00(13) . 2_575
O6 Zn1 Zn3 84.28(12) 2_665 2_575
O6 Zn1 Zn3 95.72(12) 1_465 2_575
O1 Zn1 Zn3 138.17(11) . 2_575
O1 Zn1 Zn3 41.83(11) 2_575 2_575
O2 Zn1 Zn3 138.37(10) . 2_575
O2 Zn1 Zn3 41.63(10) 2_575 2_575
O2 Zn2 O1 168.20(16) 1_655 .
O2 Zn2 O3 96.41(17) 1_655 .
O1 Zn2 O3 95.18(17) . .
O2 Zn2 O9 92.25(16) 1_655 2_676
O1 Zn2 O9 84.92(16) . 2_676
O3 Zn2 O9 92.8(2) . 2_676
O2 Zn2 O7 86.88(15) 1_655 2_665
O1 Zn2 O7 94.04(15) . 2_665
O3 Zn2 O7 96.59(18) . 2_665
O9 Zn2 O7 170.58(18) 2_676 2_665
O2 Zn2 O7 90.28(15) 1_655 1_565
O1 Zn2 O7 78.22(15) . 1_565
O3 Zn2 O7 173.05(16) . 1_565
O9 Zn2 O7 88.76(18) 2_676 1_565
O7 Zn2 O7 81.87(15) 2_665 1_565
O4 Zn3 O10 113.7(2) . 2_576
O4 Zn3 O2 118.1(2) . .
O10 Zn3 O2 111.97(18) 2_576 .
O4 Zn3 O1 109.58(18) . .
O10 Zn3 O1 109.74(19) 2_576 .
O2 Zn3 O1 91.33(16) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O3 1.260(8) .
C1 O4 1.270(7) .
C1 C2 1.498(8) .
C2 C3 1.388(8) .
C2 C7 1.391(8) .
C3 C4 1.380(8) .
C3 H3 0.9300 .
C4 O8 1.388(7) .
C4 C5 1.388(8) .
C5 C6 1.391(9) .
C5 H5 0.9300 .
C6 C7 1.377(9) .
C6 O5 1.399(7) .
C7 H7 0.9300 .
C8 O5 1.371(7) .
C8 C13 1.375(9) .
C8 C9 1.384(9) .
C9 C10 1.376(8) .
C9 H9 0.9300 .
C10 C11 1.387(8) .
C10 H10 0.9300 .
C11 C12 1.382(8) .
C11 C14 1.493(7) .
C12 C13 1.390(8) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 O6 1.254(7) .
C14 O7 1.276(7) .
C15 C20 1.373(9) .
C15 C16 1.374(10) .
C15 O8 1.394(7) .
C16 C17 1.381(9) .
C16 H16 0.9300 .
C17 C18 1.383(9) .
C17 H17 0.9300 .
C18 C19 1.380(9) .
C18 C21 1.502(8) .
C19 C20 1.391(9) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 O9 1.239(8) .
C21 O10 1.281(8) .
C24 C25 1.32(2) .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 C24 1.32(2) 2_756
C25 O12 1.619(17) 2_756
C25 O12 1.619(17) .
O1 Zn3 1.990(4) .
O1 Zn2 2.016(4) .
O1 Zn1 2.081(4) .
O1 H1A 0.8500 .
O2 Zn3 1.978(4) .
O2 Zn2 2.010(4) 1_455
O2 Zn1 2.200(4) .
O2 H2A 0.8501 .
O3 Zn2 2.070(5) .
O4 Zn3 1.917(4) .
O6 Zn1 2.068(4) 1_645
O7 Zn2 2.141(4) 2_665
O7 Zn2 2.422(4) 1_545
O9 Zn2 2.112(4) 2_676
O10 Zn3 1.929(4) 2_576
O12 H12A 0.8500 .
O11 H11A 0.8529 .
O11 H11B 0.8520 .
O11 H11E 0.8137 .
O13 H13B 0.8529 .
O13 H13C 0.8521 .
O13 H11H 1.2214 .
O13 H13E 1.0487 .
O11' O11' 1.45(3) 2_567
O11' H11B 0.7412 .
O11' H13B 0.5034 .
O11' H11H 0.8527 .
O11' H11E 0.8530 .
O13' H13D 0.8539 .
O13' H13E 0.8520 .
Zn1 O6 2.068(4) 2_665
Zn1 O6 2.068(4) 1_465
Zn1 O1 2.081(4) 2_575
Zn1 O2 2.200(4) 2_575
Zn1 Zn3 2.9767(7) 2_575
Zn2 O2 2.010(4) 1_655
Zn2 O9 2.112(4) 2_676
Zn2 O7 2.140(4) 2_665
Zn2 O7 2.422(4) 1_565
Zn3 O10 1.929(4) 2_576
