#------------------------------------------------------------------------------
#$Date: 2016-03-26 11:46:26 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180215 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/01/7110164.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7110164
loop_
_publ_author_name
'Pengfei Ai'
'Andreas A. Danopoulos'
'Pierre Braunstein'
'Kirill Yu. Monakhovc'
_publ_section_title
;
 A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear
 complexes of d10 coinage metals
;
_journal_name_full               Chem.Commun.
_journal_page_first              103
_journal_paper_doi               10.1039/c3cc47370h
_journal_volume                  50
_journal_year                    2013
_chemical_formula_moiety         'C38 H76 Cu2 N4 P4, 2(C F3 O3 S)'
_chemical_formula_sum            'C40 H76 Cu2 F6 N4 O6 P4 S2'
_chemical_formula_weight         1138.13
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.3950(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.8473(5)
_cell_length_b                   13.1451(7)
_cell_length_c                   23.5989(13)
_cell_measurement_reflns_used    4917
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.25
_cell_measurement_theta_min      2.31
_cell_volume                     2736.4(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  triumph
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0486
_diffrn_reflns_av_sigmaI/netI    0.0617
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            22020
_diffrn_reflns_theta_full        29.02
_diffrn_reflns_theta_max         29.02
_diffrn_reflns_theta_min         1.77
_exptl_absorpt_coefficient_mu    1.034
_exptl_absorpt_correction_T_max  0.9501
_exptl_absorpt_correction_T_min  0.6824
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.381
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1192
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.454
_refine_diff_density_min         -1.336
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         7272
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.1190
_refine_ls_R_factor_gt           0.0742
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1155P)²+7.9422P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2009
_refine_ls_wR_factor_ref         0.2284
_reflns_number_gt                4812
_reflns_number_total             7272
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c3cc47370h.txt
_cod_data_source_block           pbad130416
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7110164
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.3877(4) 0.6554(3) -0.01337(16) 0.0168(8) Uani 1 1 d .
C2 C 0.3519(5) 0.7577(4) -0.08944(18) 0.0240(9) Uani 1 1 d .
H2 H 0.3531 0.7829 -0.1271 0.029 Uiso 1 1 calc R
C3 C 0.2986(5) 0.8063(4) -0.04571(18) 0.0247(9) Uani 1 1 d .
H3 H 0.2538 0.8720 -0.0465 0.030 Uiso 1 1 calc R
C4 C 0.3549(5) 0.5200(4) -0.15982(19) 0.0254(9) Uani 1 1 d .
C5 C 0.4357(7) 0.4459(5) -0.1975(2) 0.0430(14) Uani 1 1 d .
H5A H 0.3602 0.4053 -0.2200 0.064 Uiso 1 1 calc R
H5B H 0.5014 0.4007 -0.1735 0.064 Uiso 1 1 calc R
H5C H 0.4971 0.4843 -0.2229 0.064 Uiso 1 1 calc R
C6 C 0.2691(6) 0.6004(4) -0.1953(2) 0.0326(11) Uani 1 1 d .
H6A H 0.3409 0.6416 -0.2151 0.049 Uiso 1 1 calc R
H6B H 0.2136 0.6443 -0.1705 0.049 Uiso 1 1 calc R
H6C H 0.1974 0.5674 -0.2232 0.049 Uiso 1 1 calc R
C7 C 0.2421(6) 0.4608(5) -0.1255(2) 0.0406(13) Uani 1 1 d .
H7A H 0.1956 0.5074 -0.0995 0.061 Uiso 1 1 calc R
H7B H 0.2960 0.4068 -0.1036 0.061 Uiso 1 1 calc R
H7C H 0.1630 0.4306 -0.1516 0.061 Uiso 1 1 calc R
C8 C 0.6646(5) 0.6355(4) -0.1331(2) 0.0315(11) Uani 1 1 d .
C9 C 0.7285(7) 0.7060(6) -0.0848(3) 0.0510(16) Uani 1 1 d .
H9A H 0.7436 0.6670 -0.0494 0.077 Uiso 1 1 calc R
H9B H 0.6569 0.7616 -0.0797 0.077 Uiso 1 1 calc R
H9C H 0.8257 0.7343 -0.0945 0.077 Uiso 1 1 calc R
C10 C 0.7808(7) 0.5528(6) -0.1428(3) 0.0533(18) Uani 1 1 d .
H10A H 0.7392 0.5060 -0.1724 0.080 Uiso 1 1 calc R
H10B H 0.8042 0.5151 -0.1074 0.080 Uiso 1 1 calc R
H10C H 0.8736 0.5841 -0.1549 0.080 Uiso 1 1 calc R
C11 C 0.6299(6) 0.6972(5) -0.1877(2) 0.0362(12) Uani 1 1 d .
H11A H 0.7211 0.7341 -0.1970 0.054 Uiso 1 1 calc R
H11B H 0.5485 0.7459 -0.1821 0.054 Uiso 1 1 calc R
H11C H 0.5979 0.6512 -0.2190 0.054 Uiso 1 1 calc R
C12 C 0.0836(5) 0.7853(4) 0.0715(2) 0.0342(11) Uani 1 1 d .
C13 C 0.0097(7) 0.6876(6) 0.0463(3) 0.0612(11) Uani 1 1 d .
H13A H 0.0434 0.6292 0.0698 0.092 Uiso 1 1 calc R
H13B H 0.0394 0.6779 0.0075 0.092 Uiso 1 1 calc R
H13C H -0.1009 0.6937 0.0456 0.092 Uiso 1 1 calc R
C14 C 0.0193(7) 0.8748(6) 0.0354(3) 0.0612(11) Uani 1 1 d .
H14A H -0.0914 0.8690 0.0302 0.092 Uiso 1 1 calc R
H14B H 0.0615 0.8735 -0.0018 0.092 Uiso 1 1 calc R
H14C H 0.0466 0.9390 0.0547 0.092 Uiso 1 1 calc R
C15 C 0.0436(7) 0.7962(6) 0.1326(3) 0.0612(11) Uani 1 1 d .
H15A H 0.0900 0.8583 0.1490 0.092 Uiso 1 1 calc R
H15B H 0.0818 0.7372 0.1546 0.092 Uiso 1 1 calc R
H15C H -0.0667 0.8003 0.1336 0.092 Uiso 1 1 calc R
C16 C 0.4135(6) 0.8698(4) 0.09349(19) 0.0293(10) Uani 1 1 d .
C17 C 0.5702(7) 0.8408(6) 0.0762(3) 0.0572(19) Uani 1 1 d .
H17A H 0.5691 0.8393 0.0347 0.086 Uiso 1 1 calc R
H17B H 0.5977 0.7734 0.0915 0.086 Uiso 1 1 calc R
H17C H 0.6445 0.8910 0.0914 0.086 Uiso 1 1 calc R
C18 C 0.4186(8) 0.8783(6) 0.1585(2) 0.0539(17) Uani 1 1 d .
H18A H 0.4487 0.8127 0.1756 0.081 Uiso 1 1 calc R
H18B H 0.3181 0.8971 0.1698 0.081 Uiso 1 1 calc R
H18C H 0.4923 0.9305 0.1715 0.081 Uiso 1 1 calc R
C19 C 0.3686(9) 0.9743(5) 0.0694(3) 0.0584(19) Uani 1 1 d .
H19A H 0.4455 1.0245 0.0825 0.088 Uiso 1 1 calc R
H19B H 0.2703 0.9941 0.0826 0.088 Uiso 1 1 calc R
H19C H 0.3611 0.9714 0.0278 0.088 Uiso 1 1 calc R
C20 C 0.9886(7) 0.1190(5) 0.2003(3) 0.0496(16) Uani 1 1 d .
O1 O 0.8447(7) -0.0440(4) 0.2215(2) 0.0749(17) Uani 1 1 d .
O2 O 0.7018(5) 0.1127(4) 0.2064(2) 0.0586(13) Uani 1 1 d .
O3 O 0.8112(6) 0.0297(3) 0.12762(18) 0.0520(11) Uani 1 1 d .
F1 F 1.1098(4) 0.0683(3) 0.1854(2) 0.0700(13) Uani 1 1 d .
F2 F 0.9789(4) 0.2055(3) 0.1706(2) 0.0717(13) Uani 1 1 d .
F3 F 1.0157(7) 0.1423(5) 0.2545(2) 0.120(2) Uani 1 1 d .
P1 P 0.50049(13) 0.56787(9) -0.10478(4) 0.0206(2) Uani 1 1 d .
P2 P 0.29021(13) 0.75739(9) 0.07441(5) 0.0207(2) Uani 1 1 d .
S1 S 0.81547(17) 0.04533(11) 0.18811(6) 0.0407(3) Uani 1 1 d .
Cu1 Cu 0.56410(7) 0.45007(5) -0.04155(2) 0.02989(19) Uani 1 1 d .
N1 N 0.4064(4) 0.6623(3) -0.06989(14) 0.0199(7) Uani 1 1 d .
N2 N 0.3209(4) 0.7426(3) 0.00153(14) 0.0193(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 C1 N1 106.7(3) . .
N2 C1 Cu1 121.1(3) . 3_665
N1 C1 Cu1 132.2(3) . 3_665
C3 C2 N1 107.8(4) . .
C3 C2 H2 126.1 . .
N1 C2 H2 126.1 . .
C2 C3 N2 107.2(4) . .
C2 C3 H3 126.4 . .
N2 C3 H3 126.4 . .
C6 C4 C5 111.1(4) . .
C6 C4 C7 109.0(4) . .
C5 C4 C7 109.4(5) . .
C6 C4 P1 116.0(4) . .
C5 C4 P1 106.9(3) . .
C7 C4 P1 104.1(3) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C4 C6 H6A 109.5 . .
C4 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C4 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C4 C7 H7A 109.5 . .
C4 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C4 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C10 C8 C11 110.2(4) . .
C10 C8 C9 109.0(5) . .
C11 C8 C9 109.9(5) . .
C10 C8 P1 105.4(4) . .
C11 C8 P1 116.2(3) . .
C9 C8 P1 105.8(3) . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C8 C10 H10A 109.5 . .
C8 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C8 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C8 C11 H11A 109.5 . .
C8 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C8 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C15 C12 C14 110.6(5) . .
C15 C12 C13 108.9(5) . .
C14 C12 C13 107.2(5) . .
C15 C12 P2 106.5(4) . .
C14 C12 P2 119.5(4) . .
C13 C12 P2 103.7(4) . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C12 C14 H14A 109.5 . .
C12 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C12 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C12 C15 H15A 109.5 . .
C12 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C12 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C17 C16 C19 110.0(5) . .
C17 C16 C18 109.1(5) . .
C19 C16 C18 107.0(5) . .
C17 C16 P2 105.3(4) . .
C19 C16 P2 119.4(4) . .
C18 C16 P2 105.7(4) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C16 C18 H18A 109.5 . .
C16 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C16 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C16 C19 H19A 109.5 . .
C16 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C16 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
F3 C20 F1 106.4(5) . .
F3 C20 F2 108.1(6) . .
F1 C20 F2 107.9(6) . .
F3 C20 S1 111.4(6) . .
F1 C20 S1 112.2(5) . .
F2 C20 S1 110.6(4) . .
N1 P1 C4 103.92(19) . .
N1 P1 C8 104.1(2) . .
C4 P1 C8 115.1(2) . .
N1 P1 Cu1 106.81(12) . .
C4 P1 Cu1 111.27(16) . .
C8 P1 Cu1 114.40(16) . .
N2 P2 C12 102.1(2) . .
N2 P2 C16 100.97(19) . .
C12 P2 C16 114.0(2) . .
O1 S1 O2 116.4(3) . .
O1 S1 O3 114.8(3) . .
O2 S1 O3 114.9(3) . .
O1 S1 C20 103.7(4) . .
O2 S1 C20 103.1(3) . .
O3 S1 C20 101.0(3) . .
C1 Cu1 P1 177.81(13) 3_665 .
C1 Cu1 Cu1 86.81(12) 3_665 3_665
P1 Cu1 Cu1 92.93(4) . 3_665
C1 N1 C2 108.4(3) . .
C1 N1 P1 121.1(3) . .
C2 N1 P1 130.2(3) . .
C1 N2 C3 109.9(3) . .
C1 N2 P2 116.7(3) . .
C3 N2 P2 133.4(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N2 1.349(5) .
C1 N1 1.360(5) .
C1 Cu1 1.923(4) 3_665
C2 C3 1.330(6) .
C2 N1 1.409(6) .
C2 H2 0.9500 .
C3 N2 1.396(5) .
C3 H3 0.9500 .
C4 C6 1.516(7) .
C4 C5 1.531(7) .
C4 C7 1.544(7) .
C4 P1 1.867(5) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 C10 1.525(8) .
C8 C11 1.534(7) .
C8 C9 1.544(8) .
C8 P1 1.869(5) .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 C15 1.516(9) .
C12 C14 1.537(9) .
C12 C13 1.540(10) .
C12 P2 1.860(5) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 C17 1.523(8) .
C16 C19 1.528(8) .
C16 C18 1.535(7) .
C16 P2 1.871(5) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 F3 1.321(8) .
C20 F1 1.332(7) .
C20 F2 1.335(8) .
C20 S1 1.816(7) .
O1 S1 1.427(5) .
O2 S1 1.431(5) .
O3 S1 1.440(4) .
P1 N1 1.736(4) .
P1 Cu1 2.1936(13) .
P2 N2 1.772(3) .
Cu1 C1 1.923(4) 3_665
Cu1 Cu1 2.6827(12) 3_665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C2 C3 N2 0.8(5) . .
C6 C4 P1 N1 48.3(4) . .
C5 C4 P1 N1 172.8(3) . .
C7 C4 P1 N1 -71.4(4) . .
C6 C4 P1 C8 -64.9(4) . .
C5 C4 P1 C8 59.6(4) . .
C7 C4 P1 C8 175.4(3) . .
C6 C4 P1 Cu1 162.9(3) . .
C5 C4 P1 Cu1 -72.6(4) . .
C7 C4 P1 Cu1 43.2(4) . .
C10 C8 P1 N1 158.3(4) . .
C11 C8 P1 N1 -79.4(4) . .
C9 C8 P1 N1 42.9(4) . .
C10 C8 P1 C4 -88.7(4) . .
C11 C8 P1 C4 33.7(5) . .
C9 C8 P1 C4 155.9(4) . .
C10 C8 P1 Cu1 42.1(4) . .
C11 C8 P1 Cu1 164.4(4) . .
C9 C8 P1 Cu1 -73.4(4) . .
C15 C12 P2 N2 178.3(4) . .
C14 C12 P2 N2 -55.7(5) . .
C13 C12 P2 N2 63.5(4) . .
C15 C12 P2 C16 -73.8(5) . .
C14 C12 P2 C16 52.3(6) . .
C13 C12 P2 C16 171.4(4) . .
C17 C16 P2 N2 -54.7(4) . .
C19 C16 P2 N2 69.4(5) . .
C18 C16 P2 N2 -170.1(4) . .
C17 C16 P2 C12 -163.3(4) . .
C19 C16 P2 C12 -39.2(5) . .
C18 C16 P2 C12 81.2(5) . .
F3 C20 S1 O1 -60.7(5) . .
F1 C20 S1 O1 58.4(6) . .
F2 C20 S1 O1 179.0(5) . .
F3 C20 S1 O2 61.0(5) . .
F1 C20 S1 O2 -179.8(5) . .
F2 C20 S1 O2 -59.2(5) . .
F3 C20 S1 O3 -179.9(5) . .
F1 C20 S1 O3 -60.7(5) . .
F2 C20 S1 O3 59.9(5) . .
N1 P1 Cu1 Cu1 0.87(14) . 3_665
C4 P1 Cu1 Cu1 -111.91(16) . 3_665
C8 P1 Cu1 Cu1 115.50(19) . 3_665
N2 C1 N1 C2 1.3(5) . .
Cu1 C1 N1 C2 -179.5(3) 3_665 .
N2 C1 N1 P1 175.8(3) . .
Cu1 C1 N1 P1 -5.0(6) 3_665 .
C3 C2 N1 C1 -1.3(5) . .
C3 C2 N1 P1 -175.1(3) . .
C4 P1 N1 C1 119.3(3) . .
C8 P1 N1 C1 -119.8(3) . .
Cu1 P1 N1 C1 1.6(4) . .
C4 P1 N1 C2 -67.6(4) . .
C8 P1 N1 C2 53.3(4) . .
Cu1 P1 N1 C2 174.7(4) . .
N1 C1 N2 C3 -0.8(5) . .
Cu1 C1 N2 C3 179.8(3) 3_665 .
N1 C1 N2 P2 -177.2(3) . .
Cu1 C1 N2 P2 3.4(4) 3_665 .
C2 C3 N2 C1 0.0(5) . .
C2 C3 N2 P2 175.6(3) . .
C12 P2 N2 C1 -126.0(3) . .
C16 P2 N2 C1 116.4(3) . .
C12 P2 N2 C3 58.7(5) . .
C16 P2 N2 C3 -59.0(5) . .
