#------------------------------------------------------------------------------
#$Date: 2016-03-26 15:37:28 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180346 $
#$URL: svn://www.crystallography.net/cod/cif/7/20/15/7201538.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7201538
loop_
_publ_author_name
'Chen, Zhen-Feng'
'Zhang, Zhi-Li'
'Tan, Yu-Hui'
'Tang, Yun-Zhi'
'Fun, Hoong-Kun'
'Zhou, Zhong-Yuan'
'Abrahams, Brendan F.'
'Liang, Hong'
_publ_section_title
;
 Coordination polymers constructed by linking metal ions with
 azodibenzoate anions
;
_journal_issue                   2
_journal_name_full               CrystEngComm
_journal_page_first              217
_journal_paper_doi               10.1039/b709587b
_journal_volume                  10
_journal_year                    2008
_chemical_formula_sum            'C24 H18 N4 O4 Zn'
_chemical_formula_weight         491.79
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.017(2)
_cell_angle_beta                 96.9130(10)
_cell_angle_gamma                93.6290(10)
_cell_formula_units_Z            2
_cell_length_a                   8.0104(8)
_cell_length_b                   8.3900(8)
_cell_length_c                   16.5826(17)
_cell_measurement_reflns_used    994
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      19.60
_cell_measurement_theta_min      2.53
_cell_volume                     1081.71(19)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0312
_diffrn_reflns_av_sigmaI/netI    0.0764
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            5535
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         2.48
_exptl_absorpt_coefficient_mu    1.175
_exptl_absorpt_correction_T_max  0.8816
_exptl_absorpt_correction_T_min  0.7989
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Sheldrick 1996'
_exptl_crystal_colour            Orange-red
_exptl_crystal_density_diffrn    1.510
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             504
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.341
_refine_diff_density_min         -0.425
_refine_diff_density_rms         0.072
_refine_ls_extinction_coef       0.0021(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.985
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     299
_refine_ls_number_reflns         3792
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.985
_refine_ls_R_factor_all          0.0833
_refine_ls_R_factor_gt           0.0532
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0670P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1164
_refine_ls_wR_factor_ref         0.1398
_reflns_number_gt                2620
_reflns_number_total             3792
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b709587b.txt
_cod_data_source_block           xb1122
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7201538
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.26685(6) 0.09874(6) 0.75375(3) 0.0425(2) Uani 1 1 d . . .
N1 N 1.0200(6) 0.4904(6) 0.5349(3) 0.0678(13) Uani 1 1 d . . .
N2 N 0.0457(5) 0.9669(5) 1.0244(3) 0.0508(10) Uani 1 1 d . . .
N3 N 0.0343(4) -0.0163(4) 0.6904(2) 0.0438(10) Uani 1 1 d . . .
N4 N 0.3474(4) -0.1059(5) 0.7906(3) 0.0440(10) Uani 1 1 d . . .
O1 O 0.3617(5) 0.1484(5) 0.6451(2) 0.0769(12) Uani 1 1 d . . .
O2 O 0.5301(5) 0.2062(4) 0.7605(2) 0.0681(11) Uani 1 1 d . . .
O3 O 0.1669(4) 0.2795(4) 0.8123(2) 0.0565(9) Uani 1 1 d . . .
O4 O 0.3273(5) 0.2658(4) 0.9291(2) 0.0707(11) Uani 1 1 d . . .
C1 C 0.5973(7) 0.3050(9) 0.5648(4) 0.096(2) Uani 1 1 d . . .
H1 H 0.4886 0.2778 0.5367 0.115 Uiso 1 1 calc R . .
C2 C 0.7212(8) 0.3740(9) 0.5266(4) 0.101(3) Uani 1 1 d . . .
H2 H 0.6953 0.3923 0.4731 0.121 Uiso 1 1 calc R . .
C3 C 0.8796(6) 0.4142(6) 0.5676(3) 0.0572(14) Uani 1 1 d . . .
C4 C 0.9174(7) 0.3855(7) 0.6457(4) 0.0666(16) Uani 1 1 d . . .
H4 H 1.0261 0.4119 0.6741 0.080 Uiso 1 1 calc R . .
C5 C 0.7922(6) 0.3168(6) 0.6819(3) 0.0604(14) Uani 1 1 d . . .
H5 H 0.8182 0.2971 0.7351 0.073 Uiso 1 1 calc R . .
C6 C 0.6340(6) 0.2773(6) 0.6428(3) 0.0510(13) Uani 1 1 d . . .
C7 C 0.5010(7) 0.2037(6) 0.6856(4) 0.0549(13) Uani 1 1 d . . .
C8 C 0.0486(6) 0.5690(6) 0.8817(3) 0.0491(12) Uani 1 1 d . . .
H8 H -0.0051 0.5114 0.8307 0.059 Uiso 1 1 calc R . .
C9 C 0.0035(6) 0.7210(6) 0.9120(3) 0.0492(12) Uani 1 1 d . . .
H9 H -0.0794 0.7665 0.8817 0.059 Uiso 1 1 calc R . .
C10 C 0.0820(6) 0.8065(6) 0.9883(3) 0.0448(12) Uani 1 1 d . . .
C11 C 0.2029(6) 0.7367(6) 1.0337(3) 0.0525(13) Uani 1 1 d . . .
H11 H 0.2537 0.7928 1.0856 0.063 Uiso 1 1 calc R . .
C12 C 0.2481(6) 0.5843(6) 1.0020(3) 0.0529(13) Uani 1 1 d . . .
H12 H 0.3302 0.5384 1.0326 0.063 Uiso 1 1 calc R . .
C13 C 0.1736(6) 0.4986(5) 0.9256(3) 0.0431(11) Uani 1 1 d . . .
C14 C 0.2267(6) 0.3353(6) 0.8885(3) 0.0487(12) Uani 1 1 d . . .
C15 C 0.3235(6) -0.2482(6) 0.7367(3) 0.0486(12) Uani 1 1 d . . .
H15 H 0.2567 -0.2535 0.6861 0.058 Uiso 1 1 calc R . .
C16 C 0.3922(6) -0.3869(6) 0.7520(4) 0.0589(14) Uani 1 1 d . . .
H16 H 0.3720 -0.4840 0.7131 0.071 Uiso 1 1 calc R . .
C17 C 0.4912(7) -0.3785(7) 0.8261(4) 0.0629(15) Uani 1 1 d . . .
H17 H 0.5418 -0.4698 0.8377 0.075 Uiso 1 1 calc R . .
C18 C 0.5152(7) -0.2360(7) 0.8827(4) 0.0622(15) Uani 1 1 d . . .
H18 H 0.5799 -0.2295 0.9339 0.075 Uiso 1 1 calc R . .
C19 C 0.4423(6) -0.1007(6) 0.8633(3) 0.0494(12) Uani 1 1 d . . .
H19 H 0.4598 -0.0030 0.9019 0.059 Uiso 1 1 calc R . .
C20 C -0.0800(6) -0.0485(6) 0.7387(3) 0.0536(13) Uani 1 1 d . . .
H20 H -0.0512 -0.0186 0.7959 0.064 Uiso 1 1 calc R . .
C21 C -0.2367(6) -0.1231(7) 0.7083(4) 0.0672(16) Uani 1 1 d . . .
H21 H -0.3121 -0.1452 0.7441 0.081 Uiso 1 1 calc R . .
C22 C -0.2813(7) -0.1646(8) 0.6252(4) 0.0785(19) Uani 1 1 d . . .
H22 H -0.3883 -0.2145 0.6031 0.094 Uiso 1 1 calc R . .
C23 C -0.1664(7) -0.1319(7) 0.5739(4) 0.0716(17) Uani 1 1 d . . .
H23 H -0.1937 -0.1599 0.5166 0.086 Uiso 1 1 calc R . .
C24 C -0.0111(6) -0.0572(6) 0.6092(3) 0.0573(14) Uani 1 1 d . . .
H24 H 0.0663 -0.0341 0.5745 0.069 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Zn1 N4 130.66(16) . . ?
O3 Zn1 N3 93.75(14) . . ?
N4 Zn1 N3 94.85(15) . . ?
O3 Zn1 O1 112.95(16) . . ?
N4 Zn1 O1 114.53(16) . . ?
N3 Zn1 O1 94.93(15) . . ?
O3 Zn1 O2 100.89(15) . . ?
N4 Zn1 O2 91.99(14) . . ?
N3 Zn1 O2 153.73(15) . . ?
O1 Zn1 O2 59.31(14) . . ?
N1 N1 C3 112.1(6) 2_766 . ?
N2 N2 C10 113.5(5) 2_577 . ?
C24 N3 C20 117.3(4) . . ?
C24 N3 Zn1 127.5(3) . . ?
C20 N3 Zn1 115.2(3) . . ?
C15 N4 C19 117.6(4) . . ?
C15 N4 Zn1 119.3(3) . . ?
C19 N4 Zn1 122.6(3) . . ?
C7 O1 Zn1 91.4(3) . . ?
C7 O2 Zn1 87.9(3) . . ?
C14 O3 Zn1 117.8(3) . . ?
C6 C1 C2 120.6(5) . . ?
C6 C1 H1 119.7 . . ?
C2 C1 H1 119.7 . . ?
C3 C2 C1 119.8(6) . . ?
C3 C2 H2 120.1 . . ?
C1 C2 H2 120.1 . . ?
C2 C3 C4 119.9(5) . . ?
C2 C3 N1 125.0(5) . . ?
C4 C3 N1 115.1(5) . . ?
C3 C4 C5 119.0(5) . . ?
C3 C4 H4 120.5 . . ?
C5 C4 H4 120.5 . . ?
C6 C5 C4 122.1(5) . . ?
C6 C5 H5 119.0 . . ?
C4 C5 H5 119.0 . . ?
C5 C6 C1 118.6(5) . . ?
C5 C6 C7 120.0(5) . . ?
C1 C6 C7 121.4(5) . . ?
O2 C7 O1 121.3(5) . . ?
O2 C7 C6 119.4(5) . . ?
O1 C7 C6 119.2(5) . . ?
C9 C8 C13 121.4(5) . . ?
C9 C8 H8 119.3 . . ?
C13 C8 H8 119.3 . . ?
C8 C9 C10 119.5(4) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 H9 120.3 . . ?
C11 C10 C9 119.9(4) . . ?
C11 C10 N2 116.6(4) . . ?
C9 C10 N2 123.6(4) . . ?
C12 C11 C10 120.0(5) . . ?
C12 C11 H11 120.0 . . ?
C10 C11 H11 120.0 . . ?
C11 C12 C13 121.0(5) . . ?
C11 C12 H12 119.5 . . ?
C13 C12 H12 119.5 . . ?
C12 C13 C8 118.3(4) . . ?
C12 C13 C14 121.6(4) . . ?
C8 C13 C14 120.0(5) . . ?
O4 C14 O3 123.6(5) . . ?
O4 C14 C13 120.7(5) . . ?
O3 C14 C13 115.6(4) . . ?
N4 C15 C16 123.3(5) . . ?
N4 C15 H15 118.3 . . ?
C16 C15 H15 118.3 . . ?
C17 C16 C15 118.3(5) . . ?
C17 C16 H16 120.9 . . ?
C15 C16 H16 120.9 . . ?
C18 C17 C16 119.6(5) . . ?
C18 C17 H17 120.2 . . ?
C16 C17 H17 120.2 . . ?
C17 C18 C19 119.2(5) . . ?
C17 C18 H18 120.4 . . ?
C19 C18 H18 120.4 . . ?
N4 C19 C18 122.0(5) . . ?
N4 C19 H19 119.0 . . ?
C18 C19 H19 119.0 . . ?
N3 C20 C21 123.1(5) . . ?
N3 C20 H20 118.4 . . ?
C21 C20 H20 118.4 . . ?
C22 C21 C20 119.0(5) . . ?
C22 C21 H21 120.5 . . ?
C20 C21 H21 120.5 . . ?
C21 C22 C23 119.1(5) . . ?
C21 C22 H22 120.4 . . ?
C23 C22 H22 120.4 . . ?
C24 C23 C22 118.5(5) . . ?
C24 C23 H23 120.8 . . ?
C22 C23 H23 120.8 . . ?
N3 C24 C23 123.0(5) . . ?
N3 C24 H24 118.5 . . ?
C23 C24 H24 118.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O3 1.914(3) . ?
Zn1 N4 2.046(4) . ?
Zn1 N3 2.102(4) . ?
Zn1 O1 2.138(4) . ?
Zn1 O2 2.221(4) . ?
N1 N1 1.207(8) 2_766 ?
N1 C3 1.468(6) . ?
N2 N2 1.258(7) 2_577 ?
N2 C10 1.427(6) . ?
N3 C24 1.325(6) . ?
N3 C20 1.335(6) . ?
N4 C15 1.335(6) . ?
N4 C19 1.337(6) . ?
O1 C7 1.244(6) . ?
O2 C7 1.232(6) . ?
O3 C14 1.281(6) . ?
O4 C14 1.234(6) . ?
C1 C6 1.358(7) . ?
C1 C2 1.393(7) . ?
C1 H1 0.9300 . ?
C2 C3 1.355(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.364(7) . ?
C4 C5 1.380(7) . ?
C4 H4 0.9300 . ?
C5 C6 1.343(6) . ?
C5 H5 0.9300 . ?
C6 C7 1.513(7) . ?
C8 C9 1.366(6) . ?
C8 C13 1.395(6) . ?
C8 H8 0.9300 . ?
C9 C10 1.384(6) . ?
C9 H9 0.9300 . ?
C10 C11 1.383(6) . ?
C11 C12 1.375(6) . ?
C11 H11 0.9300 . ?
C12 C13 1.375(6) . ?
C12 H12 0.9300 . ?
C13 C14 1.501(6) . ?
C15 C16 1.373(6) . ?
C15 H15 0.9300 . ?
C16 C17 1.366(7) . ?
C16 H16 0.9300 . ?
C17 C18 1.359(7) . ?
C17 H17 0.9300 . ?
C18 C19 1.383(6) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C21 1.360(7) . ?
C20 H20 0.9300 . ?
C21 C22 1.352(8) . ?
C21 H21 0.9300 . ?
C22 C23 1.375(7) . ?
C22 H22 0.9300 . ?
C23 C24 1.367(7) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Zn1 N3 C24 121.7(4) . . . . ?
N4 Zn1 N3 C24 -107.0(4) . . . . ?
O1 Zn1 N3 C24 8.2(4) . . . . ?
O2 Zn1 N3 C24 -2.5(6) . . . . ?
O3 Zn1 N3 C20 -57.2(3) . . . . ?
N4 Zn1 N3 C20 74.2(3) . . . . ?
O1 Zn1 N3 C20 -170.7(3) . . . . ?
O2 Zn1 N3 C20 178.7(3) . . . . ?
O3 Zn1 N4 C15 142.2(3) . . . . ?
N3 Zn1 N4 C15 43.0(4) . . . . ?
O1 Zn1 N4 C15 -54.6(4) . . . . ?
O2 Zn1 N4 C15 -111.6(3) . . . . ?
O3 Zn1 N4 C19 -46.5(4) . . . . ?
N3 Zn1 N4 C19 -145.6(4) . . . . ?
O1 Zn1 N4 C19 116.7(4) . . . . ?
O2 Zn1 N4 C19 59.7(4) . . . . ?
O3 Zn1 O1 C7 88.5(3) . . . . ?
N4 Zn1 O1 C7 -77.7(3) . . . . ?
N3 Zn1 O1 C7 -175.3(3) . . . . ?
O2 Zn1 O1 C7 -0.7(3) . . . . ?
O3 Zn1 O2 C7 -109.6(3) . . . . ?
N4 Zn1 O2 C7 118.3(3) . . . . ?
N3 Zn1 O2 C7 13.1(5) . . . . ?
O1 Zn1 O2 C7 0.7(3) . . . . ?
N4 Zn1 O3 C14 40.8(4) . . . . ?
N3 Zn1 O3 C14 140.4(4) . . . . ?
O1 Zn1 O3 C14 -122.6(4) . . . . ?
O2 Zn1 O3 C14 -61.5(4) . . . . ?
C6 C1 C2 C3 -0.2(12) . . . . ?
C1 C2 C3 C4 0.6(11) . . . . ?
C1 C2 C3 N1 -178.7(6) . . . . ?
N1 N1 C3 C2 -2.2(10) 2_766 . . . ?
N1 N1 C3 C4 178.5(6) 2_766 . . . ?
C2 C3 C4 C5 -0.5(9) . . . . ?
N1 C3 C4 C5 178.9(5) . . . . ?
C3 C4 C5 C6 -0.1(9) . . . . ?
C4 C5 C6 C1 0.6(9) . . . . ?
C4 C5 C6 C7 -179.4(5) . . . . ?
C2 C1 C6 C5 -0.4(10) . . . . ?
C2 C1 C6 C7 179.6(6) . . . . ?
Zn1 O2 C7 O1 -1.3(5) . . . . ?
Zn1 O2 C7 C6 175.5(4) . . . . ?
Zn1 O1 C7 O2 1.3(5) . . . . ?
Zn1 O1 C7 C6 -175.4(4) . . . . ?
C5 C6 C7 O2 12.4(8) . . . . ?
C1 C6 C7 O2 -167.5(6) . . . . ?
C5 C6 C7 O1 -170.7(5) . . . . ?
C1 C6 C7 O1 9.3(8) . . . . ?
C13 C8 C9 C10 -0.6(7) . . . . ?
C8 C9 C10 C11 -1.1(7) . . . . ?
C8 C9 C10 N2 178.8(4) . . . . ?
N2 N2 C10 C11 170.1(5) 2_577 . . . ?
N2 N2 C10 C9 -9.8(8) 2_577 . . . ?
C9 C10 C11 C12 1.7(7) . . . . ?
N2 C10 C11 C12 -178.2(4) . . . . ?
C10 C11 C12 C13 -0.6(7) . . . . ?
C11 C12 C13 C8 -1.1(7) . . . . ?
C11 C12 C13 C14 177.3(4) . . . . ?
C9 C8 C13 C12 1.7(7) . . . . ?
C9 C8 C13 C14 -176.7(4) . . . . ?
Zn1 O3 C14 O4 -10.7(7) . . . . ?
Zn1 O3 C14 C13 166.2(3) . . . . ?
C12 C13 C14 O4 7.3(7) . . . . ?
C8 C13 C14 O4 -174.3(4) . . . . ?
C12 C13 C14 O3 -169.7(4) . . . . ?
C8 C13 C14 O3 8.7(6) . . . . ?
C19 N4 C15 C16 -0.6(7) . . . . ?
Zn1 N4 C15 C16 171.2(4) . . . . ?
N4 C15 C16 C17 -0.5(8) . . . . ?
C15 C16 C17 C18 1.6(8) . . . . ?
C16 C17 C18 C19 -1.7(8) . . . . ?
C15 N4 C19 C18 0.5(7) . . . . ?
Zn1 N4 C19 C18 -170.9(4) . . . . ?
C17 C18 C19 N4 0.6(8) . . . . ?
C24 N3 C20 C21 1.3(7) . . . . ?
Zn1 N3 C20 C21 -179.7(4) . . . . ?
N3 C20 C21 C22 -1.2(9) . . . . ?
C20 C21 C22 C23 0.7(9) . . . . ?
C21 C22 C23 C24 -0.5(10) . . . . ?
C20 N3 C24 C23 -1.0(8) . . . . ?
Zn1 N3 C24 C23 -179.9(4) . . . . ?
C22 C23 C24 N3 0.6(9) . . . . ?
