#------------------------------------------------------------------------------
#$Date: 2016-03-26 19:44:10 +0100 (Sat 26 de Mar de 2016) $
#$Revision: 180446 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/15/7211551.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7211551
loop_
_publ_author_name
'Fan, Jun'
'Wang, Zhi-Hong'
'Yang, Ming'
'Yin, Xia'
'Zhang, Wei-Guang'
'Huang, Zhuo-Fen'
'Zeng, Rong-Hua'
_publ_section_title
;
 Controlled synthesis, structures and properties of one-, two-, and
 three-dimensional lanthanide coordination polymers based on
 (8-quinolyloxy)acetate
;
_journal_issue                   1
_journal_name_full               CrystEngComm
_journal_page_first              216
_journal_paper_doi               10.1039/b910219a
_journal_volume                  12
_journal_year                    2010
_chemical_formula_moiety         'C22 H20 Eu N2 O8, N O3, H2 O'
_chemical_formula_sum            'C22 H22 Eu N3 O12'
_chemical_formula_weight         672.39
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.97(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.724(4)
_cell_length_b                   15.086(3)
_cell_length_c                   8.6362(17)
_cell_measurement_reflns_used    4396
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.24
_cell_measurement_theta_min      1.09
_cell_volume                     2433.6(9)
_computing_cell_refinement       'SAINT (Bruker, 2004)'
_computing_data_collection       'APEX-II (Bruker, 2004)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL-XP (Bruker, 2004)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker Smart Apex II CCD area detector'
_diffrn_measurement_method       'φ and ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0419
_diffrn_reflns_av_sigmaI/netI    0.0376
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            21076
_diffrn_reflns_theta_full        25.24
_diffrn_reflns_theta_max         25.24
_diffrn_reflns_theta_min         1.09
_exptl_absorpt_coefficient_mu    2.649
_exptl_absorpt_correction_T_max  0.5962
_exptl_absorpt_correction_T_min  0.4575
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    1.835
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1336
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.760
_refine_diff_density_min         -0.602
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     344
_refine_ls_number_reflns         4396
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0461
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0650P)²+0.8000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0908
_refine_ls_wR_factor_ref         0.1028
_reflns_number_gt                3534
_reflns_number_total             4396
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b910219a.txt
_cod_data_source_block           hzf
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7211551
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.6057(4) 0.4620(4) 0.7411(7) 0.0542(16) Uani 1 1 d .
H1 H 0.6444 0.4240 0.7602 0.065 Uiso 1 1 calc R
C2 C 0.5409(4) 0.4386(5) 0.7974(9) 0.0618(19) Uani 1 1 d .
H2 H 0.5375 0.3861 0.8528 0.074 Uiso 1 1 calc R
C3 C 0.4822(4) 0.4906(5) 0.7734(8) 0.0626(19) Uani 1 1 d .
H3 H 0.4391 0.4752 0.8137 0.075 Uiso 1 1 calc R
C4 C 0.4881(3) 0.5681(4) 0.6865(7) 0.0486(16) Uani 1 1 d .
C5 C 0.4299(4) 0.6252(5) 0.6474(8) 0.0625(19) Uani 1 1 d .
H5 H 0.3851 0.6123 0.6820 0.075 Uiso 1 1 calc R
C6 C 0.4383(3) 0.6981(5) 0.5605(8) 0.0611(18) Uani 1 1 d .
H6 H 0.3990 0.7343 0.5356 0.073 Uiso 1 1 calc R
C7 C 0.5049(3) 0.7209(4) 0.5065(7) 0.0501(15) Uani 1 1 d .
H7 H 0.5095 0.7712 0.4458 0.060 Uiso 1 1 calc R
C8 C 0.5634(3) 0.6680(4) 0.5446(6) 0.0375(13) Uani 1 1 d .
C9 C 0.5563(3) 0.5892(3) 0.6327(6) 0.0365(13) Uani 1 1 d .
C10 C 0.6418(3) 0.7559(4) 0.4025(6) 0.0427(13) Uani 1 1 d .
H10A H 0.6242 0.8108 0.4441 0.051 Uiso 1 1 calc R
H10B H 0.6153 0.7442 0.3041 0.051 Uiso 1 1 calc R
C11 C 0.7208(3) 0.7642(4) 0.3784(6) 0.0402(13) Uani 1 1 d .
C12 C 0.8999(4) 0.6330(4) 0.7870(7) 0.0543(16) Uani 1 1 d .
H12 H 0.8673 0.6341 0.8636 0.065 Uiso 1 1 calc R
C13 C 0.9698(4) 0.6567(5) 0.8292(8) 0.0625(18) Uani 1 1 d .
H13 H 0.9829 0.6745 0.9303 0.075 Uiso 1 1 calc R
C14 C 1.0190(4) 0.6537(5) 0.7213(9) 0.0668(19) Uani 1 1 d .
H14 H 1.0667 0.6676 0.7485 0.080 Uiso 1 1 calc R
C15 C 0.9977(3) 0.6296(4) 0.5694(7) 0.0487(15) Uani 1 1 d .
C16 C 1.0455(4) 0.6259(5) 0.4467(9) 0.0624(19) Uani 1 1 d .
H16 H 1.0936 0.6400 0.4670 0.075 Uiso 1 1 calc R
C17 C 1.0212(4) 0.6025(5) 0.3038(9) 0.0602(18) Uani 1 1 d .
H17 H 1.0530 0.6006 0.2258 0.072 Uiso 1 1 calc R
C18 C 0.9498(4) 0.5809(4) 0.2680(8) 0.0558(18) Uani 1 1 d .
H18 H 0.9346 0.5649 0.1671 0.067 Uiso 1 1 calc R
C19 C 0.9015(3) 0.5831(3) 0.3810(6) 0.0383(13) Uani 1 1 d .
C20 C 0.9249(3) 0.6083(4) 0.5345(7) 0.0402(13) Uani 1 1 d .
C21 C 0.8011(3) 0.5617(4) 0.2014(6) 0.0477(15) Uani 1 1 d .
H21A H 0.8201 0.5118 0.1463 0.057 Uiso 1 1 calc R
H21B H 0.8143 0.6157 0.1497 0.057 Uiso 1 1 calc R
C22 C 0.7203(3) 0.5547(4) 0.1988(6) 0.0428(14) Uani 1 1 d .
Eu1 Eu 0.740989(14) 0.581314(16) 0.57730(3) 0.02887(12) Uani 1 1 d .
N1 N 0.6156(2) 0.5357(3) 0.6615(5) 0.0387(11) Uani 1 1 d .
N2 N 0.8758(3) 0.6089(3) 0.6457(5) 0.0414(11) Uani 1 1 d .
N3 N 0.7639(5) 0.2774(6) 0.2353(9) 0.092(2) Uani 1 1 d .
O1 O 0.63169(19) 0.6850(2) 0.5078(4) 0.0389(9) Uani 1 1 d .
O2 O 0.7647(2) 0.7188(3) 0.4565(4) 0.0461(10) Uani 1 1 d .
O3 O 0.7352(2) 0.8215(3) 0.2807(4) 0.0528(11) Uani 1 1 d .
O4 O 0.8309(2) 0.5621(3) 0.3587(4) 0.0415(9) Uani 1 1 d .
O5 O 0.6917(2) 0.5529(3) 0.3255(4) 0.0442(9) Uani 1 1 d .
O6 O 0.6883(2) 0.5482(3) 0.0680(4) 0.0594(12) Uani 1 1 d .
O7 O 0.7196(6) 0.2325(7) 0.280(2) 0.264(9) Uani 1 1 d .
O8 O 0.7739(6) 0.3517(5) 0.2481(9) 0.158(4) Uani 1 1 d .
O9 O 0.8099(5) 0.2299(6) 0.1808(12) 0.167(4) Uani 1 1 d .
O1W O 0.8484(4) 0.1302(6) 0.4471(9) 0.154(3) Uani 1 1 d .
H1W H 0.8222 0.1658 0.3892 0.230 Uiso 1 1 d R
H2W H 0.8636 0.1584 0.5283 0.230 Uiso 1 1 d R
O2W O 0.7553(3) 0.4243(2) 0.5343(5) 0.0554(12) Uani 1 1 d .
H4W H 0.7631 0.4075 0.4449 0.083 Uiso 1 1 d R
H3W H 0.7814 0.3959 0.5990 0.083 Uiso 1 1 d R
O3W O 0.7648(2) 0.5033(3) 0.8258(4) 0.0517(11) Uani 1 1 d .
H5W H 0.7501 0.5248 0.9089 0.078 Uiso 1 1 d R
H6W H 0.7901 0.4578 0.8504 0.078 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 123.6(7) . .
N1 C1 H1 118.2 . .
C2 C1 H1 118.2 . .
C3 C2 C1 121.3(6) . .
C3 C2 H2 119.3 . .
C1 C2 H2 119.3 . .
C2 C3 C4 118.3(6) . .
C2 C3 H3 120.9 . .
C4 C3 H3 120.9 . .
C3 C4 C5 123.4(6) . .
C3 C4 C9 117.9(6) . .
C5 C4 C9 118.7(6) . .
C6 C5 C4 120.9(6) . .
C6 C5 H5 119.6 . .
C4 C5 H5 119.6 . .
C5 C6 C7 121.7(6) . .
C5 C6 H6 119.1 . .
C7 C6 H6 119.1 . .
C8 C7 C6 119.2(6) . .
C8 C7 H7 120.4 . .
C6 C7 H7 120.4 . .
O1 C8 C7 125.3(5) . .
O1 C8 C9 114.0(5) . .
C7 C8 C9 120.7(5) . .
N1 C9 C8 118.7(5) . .
N1 C9 C4 122.6(5) . .
C8 C9 C4 118.7(5) . .
O1 C10 C11 108.9(4) . .
O1 C10 H10A 109.9 . .
C11 C10 H10A 109.9 . .
O1 C10 H10B 109.9 . .
C11 C10 H10B 109.9 . .
H10A C10 H10B 108.3 . .
O2 C11 O3 125.8(6) . .
O2 C11 C10 120.0(5) . .
O3 C11 C10 114.1(5) . .
N2 C12 C13 124.8(6) . .
N2 C12 H12 117.6 . .
C13 C12 H12 117.6 . .
C14 C13 C12 119.1(6) . .
C14 C13 H13 120.4 . .
C12 C13 H13 120.4 . .
C13 C14 C15 119.4(6) . .
C13 C14 H14 120.3 . .
C15 C14 H14 120.3 . .
C14 C15 C20 118.1(6) . .
C14 C15 C16 123.5(6) . .
C20 C15 C16 118.5(6) . .
C17 C16 C15 120.2(6) . .
C17 C16 H16 119.9 . .
C15 C16 H16 119.9 . .
C16 C17 C18 121.9(6) . .
C16 C17 H17 119.0 . .
C18 C17 H17 119.0 . .
C19 C18 C17 120.4(7) . .
C19 C18 H18 119.8 . .
C17 C18 H18 119.8 . .
O4 C19 C18 125.1(6) . .
O4 C19 C20 115.4(5) . .
C18 C19 C20 119.5(6) . .
N2 C20 C15 122.1(5) . .
N2 C20 C19 118.5(5) . .
C15 C20 C19 119.4(5) . .
O4 C21 C22 109.7(4) . .
O4 C21 H21A 109.7 . .
C22 C21 H21A 109.7 . .
O4 C21 H21B 109.7 . .
C22 C21 H21B 109.7 . .
H21A C21 H21B 108.2 . .
O6 C22 O5 125.8(6) . .
O6 C22 C21 115.8(5) . .
O5 C22 C21 118.4(5) . .
O3 Eu1 O5 142.23(15) 4_576 .
O3 Eu1 O2 78.40(14) 4_576 .
O5 Eu1 O2 79.96(14) . .
O3 Eu1 O2W 139.07(15) 4_576 .
O5 Eu1 O2W 73.65(15) . .
O2 Eu1 O2W 139.64(15) . .
O3 Eu1 O3W 69.73(15) 4_576 .
O5 Eu1 O3W 139.29(14) . .
O2 Eu1 O3W 140.53(14) . .
O2W Eu1 O3W 69.51(14) . .
O3 Eu1 N2 79.61(15) 4_576 .
O5 Eu1 N2 123.86(14) . .
O2 Eu1 N2 75.58(14) . .
O2W Eu1 N2 94.36(16) . .
O3W Eu1 N2 76.29(15) . .
O3 Eu1 N1 82.14(15) 4_576 .
O5 Eu1 N1 84.61(14) . .
O2 Eu1 N1 123.61(14) . .
O2W Eu1 N1 84.00(16) . .
O3W Eu1 N1 75.03(14) . .
N2 Eu1 N1 149.91(14) . .
O3 Eu1 O1 73.48(14) 4_576 .
O5 Eu1 O1 69.16(13) . .
O2 Eu1 O1 62.87(12) . .
O2W Eu1 O1 130.18(14) . .
O3W Eu1 O1 125.31(13) . .
N2 Eu1 O1 133.87(13) . .
N1 Eu1 O1 60.92(13) . .
O3 Eu1 O4 133.28(14) 4_576 .
O5 Eu1 O4 62.89(13) . .
O2 Eu1 O4 68.45(13) . .
O2W Eu1 O4 72.46(15) . .
O3W Eu1 O4 119.15(13) . .
N2 Eu1 O4 61.23(13) . .
N1 Eu1 O4 143.84(13) . .
O1 Eu1 O4 115.54(11) . .
C1 N1 C9 116.3(5) . .
C1 N1 Eu1 121.9(4) . .
C9 N1 Eu1 121.7(3) . .
C12 N2 C20 116.4(5) . .
C12 N2 Eu1 121.3(4) . .
C20 N2 Eu1 121.9(4) . .
O8 N3 O7 131.3(10) . .
O8 N3 O9 119.4(10) . .
O7 N3 O9 108.7(10) . .
C8 O1 C10 117.3(4) . .
C8 O1 Eu1 124.5(3) . .
C10 O1 Eu1 117.3(3) . .
C11 O2 Eu1 125.9(4) . .
C11 O3 Eu1 168.9(4) . 4_575
C19 O4 C21 116.5(4) . .
C19 O4 Eu1 122.5(3) . .
C21 O4 Eu1 117.0(3) . .
C22 O5 Eu1 130.0(4) . .
H1W O1W H2W 108.1 . .
Eu1 O2W H4W 117.9 . .
Eu1 O2W H3W 117.8 . .
H4W O2W H3W 109.4 . .
Eu1 O3W H5W 120.3 . .
Eu1 O3W H6W 131.7 . .
H5W O3W H6W 107.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.327(7) .
C1 C2 1.384(9) .
C1 H1 0.9300 .
C2 C3 1.354(10) .
C2 H2 0.9300 .
C3 C4 1.398(9) .
C3 H3 0.9300 .
C4 C5 1.411(10) .
C4 C9 1.425(8) .
C5 C6 1.348(10) .
C5 H5 0.9300 .
C6 C7 1.404(9) .
C6 H6 0.9300 .
C7 C8 1.377(8) .
C7 H7 0.9300 .
C8 O1 1.363(6) .
C8 C9 1.422(7) .
C9 N1 1.382(7) .
C10 O1 1.426(6) .
C10 C11 1.512(8) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 O2 1.234(7) .
C11 O3 1.250(6) .
C12 N2 1.322(7) .
C12 C13 1.381(9) .
C12 H12 0.9300 .
C13 C14 1.357(10) .
C13 H13 0.9300 .
C14 C15 1.393(9) .
C14 H14 0.9300 .
C15 C20 1.412(8) .
C15 C16 1.435(9) .
C16 C17 1.332(10) .
C16 H16 0.9300 .
C17 C18 1.390(10) .
C17 H17 0.9300 .
C18 C19 1.376(8) .
C18 H18 0.9300 .
C19 O4 1.359(7) .
C19 C20 1.419(8) .
C20 N2 1.374(7) .
C21 O4 1.432(7) .
C21 C22 1.516(9) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C22 O6 1.245(7) .
C22 O5 1.251(7) .
Eu1 O3 2.297(4) 4_576
Eu1 O5 2.343(4) .
Eu1 O2 2.377(4) .
Eu1 O2W 2.415(4) .
Eu1 O3W 2.461(4) .
Eu1 N2 2.586(5) .
Eu1 N1 2.597(4) .
Eu1 O1 2.612(4) .
Eu1 O4 2.631(4) .
N3 O8 1.140(9) .
N3 O7 1.159(11) .
N3 O9 1.238(9) .
O3 Eu1 2.297(4) 4_575
O1W H1W 0.8632 .
O1W H2W 0.8530 .
O2W H4W 0.8353 .
O2W H3W 0.8346 .
O3W H5W 0.8506 .
O3W H6W 0.8529 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1W O9 0.86 2.04 2.800(14) 146.0 .
O1W H2W O9 0.85 2.40 3.042(13) 132.3 4_566
O1W H1W O7 0.86 2.31 3.129(17) 158.5 .
O2W H4W O8 0.84 1.92 2.748(8) 170.9 .
O2W H3W O9 0.83 2.08 2.806(10) 145.0 4_566
O3W H5W O6 0.85 1.89 2.701(6) 159.2 1_556
O3W H6W O1W 0.85 1.88 2.716(8) 167.5 4_566
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 0.3(11) . .
C1 C2 C3 C4 1.6(11) . .
C2 C3 C4 C5 176.8(7) . .
C2 C3 C4 C9 -2.1(9) . .
C3 C4 C5 C6 -178.6(6) . .
C9 C4 C5 C6 0.2(9) . .
C4 C5 C6 C7 -0.6(10) . .
C5 C6 C7 C8 -0.7(10) . .
C6 C7 C8 O1 -176.0(5) . .
C6 C7 C8 C9 2.3(8) . .
O1 C8 C9 N1 -4.8(6) . .
C7 C8 C9 N1 176.8(5) . .
O1 C8 C9 C4 175.8(5) . .
C7 C8 C9 C4 -2.6(7) . .
C3 C4 C9 N1 0.9(8) . .
C5 C4 C9 N1 -178.0(5) . .
C3 C4 C9 C8 -179.8(5) . .
C5 C4 C9 C8 1.3(8) . .
O1 C10 C11 O2 -6.4(7) . .
O1 C10 C11 O3 176.1(4) . .
N2 C12 C13 C14 -1.7(11) . .
C12 C13 C14 C15 2.1(11) . .
C13 C14 C15 C20 -0.5(10) . .
C13 C14 C15 C16 178.9(7) . .
C14 C15 C16 C17 -179.8(7) . .
C20 C15 C16 C17 -0.4(10) . .
C15 C16 C17 C18 -0.1(11) . .
C16 C17 C18 C19 -0.1(10) . .
C17 C18 C19 O4 -179.1(5) . .
C17 C18 C19 C20 0.6(9) . .
C14 C15 C20 N2 -1.5(9) . .
C16 C15 C20 N2 179.0(6) . .
C14 C15 C20 C19 -179.7(6) . .
C16 C15 C20 C19 0.9(8) . .
O4 C19 C20 N2 0.5(7) . .
C18 C19 C20 N2 -179.2(5) . .
O4 C19 C20 C15 178.8(5) . .
C18 C19 C20 C15 -1.0(8) . .
O4 C21 C22 O6 -175.8(5) . .
O4 C21 C22 O5 1.9(8) . .
C2 C1 N1 C9 -1.5(9) . .
C2 C1 N1 Eu1 175.3(5) . .
C8 C9 N1 C1 -178.5(5) . .
C4 C9 N1 C1 0.9(7) . .
C8 C9 N1 Eu1 4.7(6) . .
C4 C9 N1 Eu1 -175.9(4) . .
O3 Eu1 N1 C1 -103.4(4) 4_576 .
O5 Eu1 N1 C1 112.0(4) . .
O2 Eu1 N1 C1 -173.8(4) . .
O2W Eu1 N1 C1 38.0(4) . .
O3W Eu1 N1 C1 -32.4(4) . .
N2 Eu1 N1 C1 -50.4(6) . .
O1 Eu1 N1 C1 -178.8(5) . .
O4 Eu1 N1 C1 86.9(5) . .
O3 Eu1 N1 C9 73.2(4) 4_576 .
O5 Eu1 N1 C9 -71.3(4) . .
O2 Eu1 N1 C9 2.8(4) . .
O2W Eu1 N1 C9 -145.4(4) . .
O3W Eu1 N1 C9 144.2(4) . .
N2 Eu1 N1 C9 126.3(4) . .
O1 Eu1 N1 C9 -2.2(3) . .
O4 Eu1 N1 C9 -96.5(4) . .
C13 C12 N2 C20 -0.3(9) . .
C13 C12 N2 Eu1 -173.8(5) . .
C15 C20 N2 C12 2.0(8) . .
C19 C20 N2 C12 -179.9(5) . .
C15 C20 N2 Eu1 175.4(4) . .
C19 C20 N2 Eu1 -6.4(7) . .
O3 Eu1 N2 C12 25.8(5) 4_576 .
O5 Eu1 N2 C12 173.4(4) . .
O2 Eu1 N2 C12 106.3(5) . .
O2W Eu1 N2 C12 -113.4(5) . .
O3W Eu1 N2 C12 -45.7(5) . .
N1 Eu1 N2 C12 -27.8(6) . .
O1 Eu1 N2 C12 80.5(5) . .
O4 Eu1 N2 C12 179.4(5) . .
O3 Eu1 N2 C20 -147.3(4) 4_576 .
O5 Eu1 N2 C20 0.3(5) . .
O2 Eu1 N2 C20 -66.8(4) . .
O2W Eu1 N2 C20 73.5(4) . .
O3W Eu1 N2 C20 141.2(4) . .
N1 Eu1 N2 C20 159.1(4) . .
O1 Eu1 N2 C20 -92.6(4) . .
O4 Eu1 N2 C20 6.3(4) . .
C7 C8 O1 C10 -9.8(7) . .
C9 C8 O1 C10 171.8(4) . .
C7 C8 O1 Eu1 -178.7(4) . .
C9 C8 O1 Eu1 2.9(6) . .
C11 C10 O1 C8 179.5(4) . .
C11 C10 O1 Eu1 -10.8(5) . .
O3 Eu1 O1 C8 -90.6(4) 4_576 .
O5 Eu1 O1 C8 95.0(4) . .
O2 Eu1 O1 C8 -175.8(4) . .
O2W Eu1 O1 C8 50.7(4) . .
O3W Eu1 O1 C8 -41.4(4) . .
N2 Eu1 O1 C8 -147.5(3) . .
N1 Eu1 O1 C8 -0.5(3) . .
O4 Eu1 O1 C8 138.8(3) . .
O3 Eu1 O1 C10 100.5(4) 4_576 .
O5 Eu1 O1 C10 -73.9(3) . .
O2 Eu1 O1 C10 15.3(3) . .
O2W Eu1 O1 C10 -118.2(3) . .
O3W Eu1 O1 C10 149.7(3) . .
N2 Eu1 O1 C10 43.6(4) . .
N1 Eu1 O1 C10 -169.4(4) . .
O4 Eu1 O1 C10 -30.1(4) . .
O3 C11 O2 Eu1 -158.6(4) . .
C10 C11 O2 Eu1 24.3(7) . .
O3 Eu1 O2 C11 -98.4(5) 4_576 .
O5 Eu1 O2 C11 50.4(4) . .
O2W Eu1 O2 C11 99.9(5) . .
O3W Eu1 O2 C11 -134.7(4) . .
N2 Eu1 O2 C11 179.5(5) . .
N1 Eu1 O2 C11 -26.1(5) . .
O1 Eu1 O2 C11 -21.2(4) . .
O4 Eu1 O2 C11 115.1(5) . .
O2 C11 O3 Eu1 148.5(17) . 4_575
C10 C11 O3 Eu1 -34(2) . 4_575
C18 C19 O4 C21 -17.9(8) . .
C20 C19 O4 C21 162.4(5) . .
C18 C19 O4 Eu1 -174.8(4) . .
C20 C19 O4 Eu1 5.5(6) . .
C22 C21 O4 C19 -169.2(5) . .
C22 C21 O4 Eu1 -11.1(6) . .
O3 Eu1 O4 C19 30.8(4) 4_576 .
O5 Eu1 O4 C19 168.3(4) . .
O2 Eu1 O4 C19 78.8(4) . .
O2W Eu1 O4 C19 -111.5(4) . .
O3W Eu1 O4 C19 -58.1(4) . .
N2 Eu1 O4 C19 -6.1(3) . .
N1 Eu1 O4 C19 -163.3(3) . .
O1 Eu1 O4 C19 121.8(4) . .
O3 Eu1 O4 C21 -126.0(4) 4_576 .
O5 Eu1 O4 C21 11.5(4) . .
O2 Eu1 O4 C21 -78.0(4) . .
O2W Eu1 O4 C21 91.8(4) . .
O3W Eu1 O4 C21 145.1(4) . .
N2 Eu1 O4 C21 -162.9(4) . .
N1 Eu1 O4 C21 40.0(5) . .
O1 Eu1 O4 C21 -35.0(4) . .
O6 C22 O5 Eu1 -171.5(5) . .
C21 C22 O5 Eu1 11.0(8) . .
O3 Eu1 O5 C22 114.2(5) 4_576 .
O2 Eu1 O5 C22 58.4(5) . .
O2W Eu1 O5 C22 -90.7(5) . .
O3W Eu1 O5 C22 -116.5(5) . .
N2 Eu1 O5 C22 -6.5(6) . .
N1 Eu1 O5 C22 -176.0(5) . .
O1 Eu1 O5 C22 123.1(5) . .
O4 Eu1 O5 C22 -12.4(5) . .
