#------------------------------------------------------------------------------
#$Date: 2016-02-16 02:10:39 +0100 (mar 16 de feb de 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/29/7212987.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_7212987
loop_
_publ_author_name
'Lebon, Florence'
'Ledecq, Marie'
'Benatallah, Zohra'
'Sicsic, Sames'
'Lapouyade, René'
'Kahn, Olivier'
'Garçon, Arnaud'
'Reboud-Ravaux, Michèle'
'Durant, François'
_publ_section_title
;
 Synthesis and structural analysis of copper(II) pyridine amide complexes
 as HIV-1 protease inhibitors
;
_journal_issue                   4
_journal_name_full
'Journal of the Chemical Society, Perkin Transactions 2'
_journal_page_first              795
_journal_paper_doi               10.1039/a809270b
_journal_year                    1999
_chemical_formula_sum            'C36 H52 Cl2 Cu N4 O20'
_chemical_formula_weight         995.26
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                114.180(4)
_cell_angle_beta                 93.573(5)
_cell_angle_gamma                116.809(6)
_cell_formula_units_Z            2
_cell_length_a                   10.9740(10)
_cell_length_b                   11.4210(10)
_cell_length_c                   11.6980(10)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      72.0
_cell_measurement_theta_min      2.1
_cell_volume                     1137.5(2)
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       Enraf-Nonius-cad-4
_diffrn_measurement_method       omega-2-theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuKa
_diffrn_radiation_wavelength     1.54179
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0091
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            4473
_diffrn_reflns_theta_max         72.06
_diffrn_reflns_theta_min         4.35
_diffrn_standards_decay_%        2
_diffrn_standards_interval_time  3600
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.461
_exptl_absorpt_correction_T_max  0.9983
_exptl_absorpt_correction_T_min  0.7130
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            Green
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_description       Cubic
_exptl_crystal_F_000             519
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         .453
_refine_diff_density_min         -.773
_refine_diff_density_rms         .072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.082
_refine_ls_goodness_of_fit_obs   1.100
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     326
_refine_ls_number_reflns         4472
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.099
_refine_ls_restrained_S_obs      1.100
_refine_ls_R_factor_all          0.0493
_refine_ls_R_factor_obs          0.0473
_refine_ls_shift/esd_max         0.088
_refine_ls_shift/esd_mean        0.006
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[s²(Fo²)+( 0.0847P)²+0.5721P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.1416
_refine_ls_wR_factor_obs         0.1375
_reflns_number_observed          4229
_reflns_number_total             4473
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            809270bsup1.cif
_cod_data_source_block           zb33
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc w=1/[s^2^(Fo^2^)+(
0.0847P)^2^+0.5721P] where P=(Fo^2^+2Fc^2^)/3' was changed to 'calc'.
New tag '_refine_ls_weighting_details' was created. The value of the
new tag was set to 'w=1/[s^2^(Fo^2^)+( 0.0847P)^2^+0.5721P] where
P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C36 H52 Cl2 Cu1 N4 O20'
_cod_database_code               7212987
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Cl26 Cl 0.70999(8) 0.92664(8) 1.18527(7) 0.0672(2) Uani 1 d . .
O30 O 0.6902(7) 0.8895(6) 1.0560(4) 0.169(2) Uani 1 d . .
O27 O 0.6131(14) 0.7773(8) 1.1598(11) 0.171(4) Uani 0.50 d PD 1
O28 O 0.8382(7) 0.9956(15) 1.2769(7) 0.163(5) Uani 0.50 d PD 1
O29 O 0.6343(12) 1.0002(10) 1.2368(15) 0.148(6) Uani 0.50 d PD 1
O27A O 0.7606(16) 0.8536(17) 1.2181(12) 0.156(4) Uani 0.50 d PD 2
O28A O 0.8344(9) 1.0718(7) 1.2090(11) 0.141(3) Uani 0.50 d PD 2
O29A O 0.6237(17) 0.9550(18) 1.2494(19) 0.177(7) Uani 0.50 d PD 2
C8 C 0.7385(3) 0.8996(3) 0.5275(3) 0.0606(7) Uani 1 d . .
H8A H 0.6910(20) 0.8663(17) 0.4389(3) 0.091 Uiso 1 calc R .
H8B H 0.8113(5) 1.0045(4) 0.5692(20) 0.091 Uiso 1 calc R .
H8C H 0.6700(18) 0.8851(20) 0.5754(19) 0.091 Uiso 1 calc R .
Cu1 Cu 1.0000 0.5000 0.5000 0.03434(15) Uani 1 d S .
O11 O 0.9906(2) 0.5286(2) 0.67516(14) 0.0391(3) Uani 1 d . .
O22 O 0.7908(2) 0.2728(2) 0.7064(2) 0.0453(4) Uani 1 d . .
N9 N 0.8329(2) 0.6085(2) 0.6906(2) 0.0375(4) Uani 1 d . .
H9 H 0.7650(2) 0.6067(2) 0.7242(2) 0.053(8) Uiso 1 calc R .
N2 N 0.9312(2) 0.6420(2) 0.5235(2) 0.0351(4) Uani 1 d . .
O18 O 0.9782(2) 0.7929(2) 0.9704(2) 0.0576(5) Uani 1 d . .
O20 O 0.7331(2) 0.2199(2) 0.9067(2) 0.0627(5) Uani 1 d . .
O24 O 0.7497(2) 0.3007(2) 0.4070(2) 0.0712(6) Uani 1 d . .
H24 H 0.7446(45) 0.2350(46) 0.3711(41) 0.080 Uiso 1 d . .
O31 O 0.6312(2) 0.6437(3) 0.8170(2) 0.0689(6) Uani 1 d . .
H31 H 0.6535(45) 0.7126(48) 0.8860(42) 0.090 Uiso 1 d . .
C3 C 0.9512(3) 0.7082(2) 0.4472(2) 0.0429(5) Uani 1 d . .
H3 H 1.0081(3) 0.6969(2) 0.3930(2) 0.052 Uiso 1 calc R .
C4 C 0.8920(3) 0.7907(3) 0.4460(2) 0.0472(5) Uani 1 d . .
H4 H 0.9091(3) 0.8338(3) 0.3919(2) 0.057 Uiso 1 calc R .
C5 C 0.8060(3) 0.8102(3) 0.5261(2) 0.0435(5) Uani 1 d . .
C6 C 0.7874(2) 0.7457(2) 0.6055(2) 0.0402(4) Uani 1 d . .
H6 H 0.7309(2) 0.7559(2) 0.6605(2) 0.048 Uiso 1 calc R .
C7 C 0.8527(2) 0.6655(2) 0.6037(2) 0.0341(4) Uani 1 d . .
C10 C 0.9056(2) 0.5561(2) 0.7286(2) 0.0340(4) Uani 1 d . .
C12 C 0.8792(2) 0.5331(2) 0.8425(2) 0.0364(4) Uani 1 d . .
C13 C 0.9149(3) 0.6562(3) 0.9655(2) 0.0437(5) Uani 1 d . .
C14 C 0.8868(3) 0.6314(3) 1.0693(2) 0.0545(6) Uani 1 d . .
H14 H 0.9098(3) 0.7119(3) 1.1512(2) 0.065 Uiso 1 calc R .
C15 C 0.8247(3) 0.4877(3) 1.0524(2) 0.0559(6) Uani 1 d . .
H15 H 0.8054(3) 0.4728(3) 1.1232(2) 0.067 Uiso 1 calc R .
C16 C 0.7904(2) 0.3650(3) 0.9323(2) 0.0475(5) Uani 1 d . .
C17 C 0.8184(2) 0.3892(2) 0.8266(2) 0.0386(4) Uani 1 d . .
C19 C 1.0554(3) 0.9252(3) 1.0954(3) 0.0663(7) Uani 1 d . .
H19A H 0.9895(4) 0.9388(16) 1.1417(10) 0.099 Uiso 1 calc R .
H19B H 1.1093(21) 1.0108(5) 1.0837(3) 0.099 Uiso 1 calc R .
H19C H 1.1197(19) 0.9156(12) 1.1453(10) 0.099 Uiso 1 calc R .
C21 C 0.6887(4) 0.1865(4) 1.0070(4) 0.0790(10) Uani 1 d . .
H21A H 0.6460(29) 0.0805(7) 0.9754(11) 0.119 Uiso 1 calc R .
H21B H 0.6200(24) 0.2148(31) 1.0303(21) 0.119 Uiso 1 calc R .
H21C H 0.7703(6) 0.2417(26) 1.0830(11) 0.119 Uiso 1 calc R .
C23 C 0.6435(3) 0.1748(3) 0.6316(3) 0.0640(7) Uani 1 d . .
H23A H 0.6338(4) 0.1025(17) 0.5463(9) 0.096 Uiso 1 calc R .
H23B H 0.6054(7) 0.2324(5) 0.6222(20) 0.096 Uiso 1 calc R .
H23C H 0.5919(5) 0.1232(20) 0.6759(12) 0.096 Uiso 1 calc R .
C25 C 0.6264(4) 0.2914(5) 0.3498(4) 0.0868(10) Uani 1 d . .
H25A H 0.5855(20) 0.3260(34) 0.4168(6) 0.130 Uiso 1 calc R .
H25B H 0.5577(15) 0.1888(7) 0.2850(23) 0.130 Uiso 1 calc R .
H25C H 0.6522(7) 0.3532(29) 0.3088(28) 0.130 Uiso 1 calc R .
C32 C 0.5257(4) 0.5132(5) 0.8161(5) 0.1009(13) Uani 1 d . .
H32A H 0.4873(28) 0.4286(9) 0.7290(9) 0.151 Uiso 1 calc R .
H32B H 0.4502(19) 0.5275(16) 0.8425(35) 0.151 Uiso 1 calc R .
H32C H 0.5680(10) 0.4947(24) 0.8761(27) 0.151 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0181 .0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0311 .0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O .0492 .0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl .3639 .7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu -1.9646 .5888 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O29A Cl26 O27A 114.9(8) . .
O29A Cl26 O30 122.4(9) . .
O27A Cl26 O30 112.9(5) . .
O30 Cl26 O28 125.8(5) . .
O30 Cl26 O27 95.3(5) . .
O28 Cl26 O27 112.8(7) . .
O30 Cl26 O29 108.2(7) . .
O28 Cl26 O29 109.7(7) . .
O27 Cl26 O29 101.8(7) . .
O29A Cl26 O28A 108.8(8) . .
O27A Cl26 O28A 108.3(7) . .
O30 Cl26 O28A 84.0(5) . .
C5 C8 H8A 109.47(14) . .
C5 C8 H8B 109.47(15) . .
H8A C8 H8B 109.5 . .
C5 C8 H8C 109.47(14) . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
O11 Cu1 O11 180.0 . 2_766
O11 Cu1 N2 90.82(6) . 2_766
O11 Cu1 N2 89.18(6) 2_766 2_766
O11 Cu1 N2 89.17(6) . .
O11 Cu1 N2 90.83(6) 2_766 .
N2 Cu1 N2 179.999(2) 2_766 .
O11 Cu1 O24 89.91(8) . .
O11 Cu1 O24 90.09(8) 2_766 .
N2 Cu1 O24 93.45(8) 2_766 .
N2 Cu1 O24 86.55(8) . .
O11 Cu1 O24 90.09(8) . 2_766
O11 Cu1 O24 89.91(8) 2_766 2_766
N2 Cu1 O24 86.55(8) 2_766 2_766
N2 Cu1 O24 93.45(8) . 2_766
O24 Cu1 O24 180.0 . 2_766
C10 O11 Cu1 125.49(13) . .
C17 O22 C23 114.4(2) . .
C10 N9 C7 128.6(2) . .
C10 N9 H9 115.72(11) . .
C7 N9 H9 115.71(10) . .
C7 N2 C3 116.4(2) . .
C7 N2 Cu1 123.02(13) . .
C3 N2 Cu1 120.25(14) . .
C13 O18 C19 118.5(2) . .
C16 O20 C21 117.6(3) . .
C25 O24 Cu1 132.1(2) . .
C25 O24 H24 107.7(37) . .
Cu1 O24 H24 109.2(37) . .
C32 O31 H31 107.6(32) . .
N2 C3 C4 123.5(2) . .
N2 C3 H3 118.27(12) . .
C4 C3 H3 118.27(13) . .
C3 C4 C5 119.9(2) . .
C3 C4 H4 120.04(13) . .
C5 C4 H4 120.04(13) . .
C6 C5 C4 117.0(2) . .
C6 C5 C8 121.3(2) . .
C4 C5 C8 121.7(2) . .
C5 C6 C7 120.2(2) . .
C5 C6 H6 119.90(13) . .
C7 C6 H6 119.90(12) . .
N2 C7 C6 122.9(2) . .
N2 C7 N9 120.4(2) . .
C6 C7 N9 116.6(2) . .
O11 C10 N9 124.0(2) . .
O11 C10 C12 120.6(2) . .
N9 C10 C12 115.3(2) . .
C17 C12 C13 120.4(2) . .
C17 C12 C10 119.5(2) . .
C13 C12 C10 120.1(2) . .
O18 C13 C14 125.8(2) . .
O18 C13 C12 115.2(2) . .
C14 C13 C12 119.0(2) . .
C13 C14 C15 120.3(2) . .
C13 C14 H14 119.84(15) . .
C15 C14 H14 119.84(14) . .
C14 C15 C16 121.6(2) . .
C14 C15 H15 119.20(13) . .
C16 C15 H15 119.20(14) . .
O20 C16 C15 126.1(2) . .
O20 C16 C17 115.5(2) . .
C15 C16 C17 118.4(2) . .
O22 C17 C12 118.6(2) . .
O22 C17 C16 121.1(2) . .
C12 C17 C16 120.3(2) . .
O18 C19 H19A 109.5(2) . .
O18 C19 H19B 109.5(2) . .
H19A C19 H19B 109.5 . .
O18 C19 H19C 109.5(2) . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
O20 C21 H21A 109.5(2) . .
O20 C21 H21B 109.5(2) . .
H21A C21 H21B 109.47(6) . .
O20 C21 H21C 109.5(2) . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
O22 C23 H23A 109.47(14) . .
O22 C23 H23B 109.47(14) . .
H23A C23 H23B 109.5 . .
O22 C23 H23C 109.5(2) . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O24 C25 H25A 109.5(2) . .
O24 C25 H25B 109.5(2) . .
H25A C25 H25B 109.5 . .
O24 C25 H25C 109.5(2) . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
O31 C32 H32A 109.5(2) . .
O31 C32 H32B 109.5(2) . .
H32A C32 H32B 109.47(5) . .
O31 C32 H32C 109.5(2) . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cl26 O29A 1.315(11) .
Cl26 O27A 1.344(6) .
Cl26 O30 1.365(4) .
Cl26 O28 1.367(7) .
Cl26 O27 1.427(8) .
Cl26 O29 1.427(10) .
Cl26 O28A 1.491(7) .
C8 C5 1.504(3) .
C8 H8A 0.96 .
C8 H8B 0.96 .
C8 H8C 0.96 .
Cu1 O11 1.9553(14) .
Cu1 O11 1.9553(14) 2_766
Cu1 N2 2.011(2) 2_766
Cu1 N2 2.011(2) .
Cu1 O24 2.423(2) .
Cu1 O24 2.423(2) 2_766
O11 C10 1.239(2) .
O22 C17 1.374(3) .
O22 C23 1.421(3) .
N9 C10 1.340(3) .
N9 C7 1.395(3) .
N9 H9 0.86 .
N2 C7 1.340(3) .
N2 C3 1.357(3) .
O18 C13 1.366(3) .
O18 C19 1.421(3) .
O20 C16 1.364(3) .
O20 C21 1.425(3) .
O24 C25 1.410(4) .
O24 H24 0.67(4) .
O31 C32 1.411(5) .
O31 H31 0.78(4) .
C3 C4 1.368(3) .
C3 H3 0.93 .
C4 C5 1.395(3) .
C4 H4 0.93 .
C5 C6 1.376(3) .
C6 C7 1.391(3) .
C6 H6 0.93 .
C10 C12 1.482(3) .
C12 C17 1.388(3) .
C12 C13 1.405(3) .
C13 C14 1.379(3) .
C14 C15 1.380(4) .
C14 H14 0.93 .
C15 C16 1.387(4) .
C15 H15 0.93 .
C16 C17 1.397(3) .
C19 H19A 0.96 .
C19 H19B 0.96 .
C19 H19C 0.96 .
C21 H21A 0.96 .
C21 H21B 0.96 .
C21 H21C 0.96 .
C23 H23A 0.96 .
C23 H23B 0.96 .
C23 H23C 0.96 .
C25 H25A 0.96 .
C25 H25B 0.96 .
C25 H25C 0.96 .
C32 H32A 0.96 .
C32 H32B 0.96 .
C32 H32C 0.96 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
O11 Cu1 O11 C10 90.3(288) 2_766
N2 Cu1 O11 C10 -149.5(2) 2_766
N2 Cu1 O11 C10 30.5(2) .
O24 Cu1 O11 C10 -56.1(2) .
O24 Cu1 O11 C10 123.9(2) 2_766
O11 Cu1 N2 C7 -25.5(2) .
O11 Cu1 N2 C7 154.5(2) 2_766
N2 Cu1 N2 C7 -6.9(191) 2_766
O24 Cu1 N2 C7 64.4(2) .
O24 Cu1 N2 C7 -115.6(2) 2_766
O11 Cu1 N2 C3 161.0(2) .
O11 Cu1 N2 C3 -19.0(2) 2_766
N2 Cu1 N2 C3 179.6(191) 2_766
O24 Cu1 N2 C3 -109.0(2) .
O24 Cu1 N2 C3 71.0(2) 2_766
O11 Cu1 O24 C25 110.8(3) .
O11 Cu1 O24 C25 -69.2(3) 2_766
N2 Cu1 O24 C25 -158.4(3) 2_766
N2 Cu1 O24 C25 21.6(3) .
O24 Cu1 O24 C25 -174.8(52) 2_766
C7 N2 C3 C4 -2.3(3) .
Cu1 N2 C3 C4 171.6(2) .
N2 C3 C4 C5 0.0(4) .
C3 C4 C5 C6 1.2(4) .
C3 C4 C5 C8 -179.8(2) .
C4 C5 C6 C7 0.0(3) .
C8 C5 C6 C7 -179.0(2) .
C3 N2 C7 C6 3.5(3) .
Cu1 N2 C7 C6 -170.2(2) .
C3 N2 C7 N9 -176.6(2) .
Cu1 N2 C7 N9 9.7(3) .
C5 C6 C7 N2 -2.4(3) .
C5 C6 C7 N9 177.7(2) .
C10 N9 C7 N2 15.4(3) .
C10 N9 C7 C6 -164.7(2) .
Cu1 O11 C10 N9 -18.1(3) .
Cu1 O11 C10 C12 162.46(14) .
C7 N9 C10 O11 -11.7(3) .
C7 N9 C10 C12 167.8(2) .
O11 C10 C12 C17 -63.3(3) .
N9 C10 C12 C17 117.2(2) .
O11 C10 C12 C13 117.0(2) .
N9 C10 C12 C13 -62.5(3) .
C19 O18 C13 C14 17.4(4) .
C19 O18 C13 C12 -161.4(2) .
C17 C12 C13 O18 178.0(2) .
C10 C12 C13 O18 -2.3(3) .
C17 C12 C13 C14 -0.9(3) .
C10 C12 C13 C14 178.8(2) .
O18 C13 C14 C15 -178.7(2) .
C12 C13 C14 C15 0.1(4) .
C13 C14 C15 C16 0.8(4) .
C21 O20 C16 C15 7.6(4) .
C21 O20 C16 C17 -173.6(2) .
C14 C15 C16 O20 177.9(2) .
C14 C15 C16 C17 -0.9(4) .
C23 O22 C17 C12 -105.7(2) .
C23 O22 C17 C16 76.3(3) .
C13 C12 C17 O22 -177.2(2) .
C10 C12 C17 O22 3.1(3) .
C13 C12 C17 C16 0.9(3) .
C10 C12 C17 C16 -178.9(2) .
O20 C16 C17 O22 -0.9(3) .
C15 C16 C17 O22 178.0(2) .
O20 C16 C17 C12 -178.9(2) .
C15 C16 C17 C12 0.0(3) .
