#------------------------------------------------------------------------------
#$Date: 2019-11-28 17:25:35 +0100 (jue 28 de nov de 2019) $
#$Revision: 244274 $
#$URL: svn://www.crystallography.net/cod/cif/7/23/86/7238656.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7238656
loop_
_publ_author_name
'Yang, Yanan'
'Gong, Jingjing'
'Zhang, Weisong'
'Zhang, Hengchao'
'Zhang, Lili'
'Liu, Yang'
'Huang, Hui'
'Hu, Hailiang'
'Kang, Zhenhui'
_publ_section_title
;
 High-connected strategy of polyoxometalates towards model of core--shell
 nanostructure
;
_journal_issue                   16
_journal_name_full               'RSC Advances'
_journal_page_first              6414
_journal_paper_doi               10.1039/c2ra20605f
_journal_volume                  2
_journal_year                    2012
_chemical_formula_moiety         '[Ag8(C2H3N4S)4][SiW12O40](H2O)2'
_chemical_formula_sum            'C8 H16 Ag8 N16 O42 S4 Si W12'
_chemical_formula_weight         4233.86
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.369(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.0393(12)
_cell_length_b                   13.9688(16)
_cell_length_c                   19.893(2)
_cell_measurement_reflns_used    3960
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.3795
_cell_measurement_theta_min      2.5105
_cell_volume                     2725.0(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0560
_diffrn_reflns_av_sigmaI/netI    0.0491
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            19690
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.80
_exptl_absorpt_coefficient_mu    28.293
_exptl_absorpt_correction_T_max  0.1324
_exptl_absorpt_correction_T_min  0.0703
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            'Light Yellow'
_exptl_crystal_density_diffrn    5.160
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             3708
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         3.163
_refine_diff_density_min         -3.087
_refine_diff_density_rms         0.499
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.305
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     432
_refine_ls_number_reflns         4739
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.305
_refine_ls_R_factor_all          0.0877
_refine_ls_R_factor_gt           0.0761
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+425.8493P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1474
_refine_ls_wR_factor_ref         0.1511
_reflns_number_gt                4106
_reflns_number_total             4739
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2ra20605f.txt
_cod_data_source_block           FUNSOM-4
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/RSC/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        2725.0(6)
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7238656
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Si1 Si 0.0000 0.0000 0.0000 0.016(2) Uani 1 2 d S
W1 W 0.31725(12) 0.11526(8) 0.05407(6) 0.0177(3) Uani 1 1 d .
W2 W 0.04297(16) 0.23589(9) -0.05336(7) 0.0291(3) Uani 1 1 d .
W3 W 0.20907(13) 0.04641(9) -0.11936(7) 0.0236(3) Uani 1 1 d .
W4 W 0.27281(13) -0.11927(10) 0.11056(6) 0.0243(3) Uani 1 1 d .
W5 W 0.10547(12) 0.07379(8) 0.17194(6) 0.0191(3) Uani 1 1 d .
W6 W -0.17052(14) 0.18897(10) 0.06308(8) 0.0318(4) Uani 1 1 d .
Ag1 Ag 0.0775(3) 0.1363(2) 0.36018(14) 0.0338(6) Uani 1 1 d .
Ag2 Ag -0.0224(3) -0.0423(3) 0.42840(16) 0.0468(8) Uani 1 1 d .
Ag3 Ag 0.6078(2) -0.02093(18) 0.45378(13) 0.0277(6) Uani 1 1 d .
Ag4 Ag 0.6080(3) -0.15429(17) 0.27445(12) 0.0266(5) Uani 1 1 d .
S1 S -0.2452(8) -0.0231(5) 0.3538(4) 0.0184(15) Uani 1 1 d .
S2 S 0.2194(7) 0.0098(6) 0.4369(4) 0.0234(17) Uani 1 1 d .
O1 O 0.463(3) 0.1755(19) 0.0784(15) 0.050(7) Uani 1 1 d .
O1W O 0.016(3) -0.1655(19) 0.5153(16) 0.053(8) Uani 1 1 d .
O2 O 0.062(3) 0.3489(19) -0.0770(13) 0.048(7) Uani 1 1 d .
O3 O 0.310(3) 0.066(2) -0.1777(14) 0.052(7) Uani 1 1 d .
O4 O 0.399(3) -0.1778(18) 0.1615(13) 0.042(6) Uani 1 1 d .
O5 O 0.160(3) 0.1070(18) 0.2548(13) 0.039(6) Uani 1 1 d .
O6 O -0.248(2) 0.2814(16) 0.0895(12) 0.031(6) Uani 1 1 d .
O7 O 0.202(3) 0.219(2) 0.0145(14) 0.053(7) Uani 1 1 d .
O8 O 0.122(3) 0.165(2) -0.1161(14) 0.055(8) Uani 1 1 d .
O9 O -0.132(3) 0.209(2) -0.1106(14) 0.056(8) Uani 1 1 d .
O10 O -0.054(3) 0.262(2) 0.0154(15) 0.058(8) Uani 1 1 d .
O11 O 0.330(3) 0.079(2) -0.0353(14) 0.055(8) Uani 1 1 d .
O12 O 0.254(3) -0.086(2) -0.1010(16) 0.058(8) Uani 1 1 d .
O13 O -0.289(3) 0.170(2) -0.0241(14) 0.055(8) Uani 1 1 d .
O14 O -0.021(3) 0.171(2) 0.1317(15) 0.051(7) Uani 1 1 d .
O15 O -0.043(3) -0.0035(19) 0.1792(15) 0.050(7) Uani 1 1 d .
O16 O 0.236(3) 0.1331(18) 0.1292(14) 0.045(7) Uani 1 1 d .
O17 O 0.204(3) -0.0455(18) 0.1699(13) 0.041(6) Uani 1 1 d .
O18 O 0.364(3) -0.0082(19) 0.0859(14) 0.046(7) Uani 1 1 d .
O19 O 0.111(6) 0.074(4) -0.019(3) 0.049(14) Uani 0.50 1 d P
O20 O 0.079(5) -0.110(4) 0.024(3) 0.043(13) Uani 0.50 1 d P
O21 O -0.042(6) 0.039(4) 0.071(3) 0.045(13) Uani 0.50 1 d P
O22 O -0.127(5) -0.017(4) -0.061(3) 0.044(13) Uani 0.50 1 d P
N1 N -0.148(2) 0.1429(18) 0.3087(13) 0.023(6) Uani 1 1 d .
N2 N -0.198(3) 0.2168(19) 0.2681(14) 0.027(6) Uani 1 1 d .
N3 N -0.331(2) 0.2076(19) 0.2472(14) 0.025(6) Uani 1 1 d .
N4 N -0.361(2) 0.1226(17) 0.2730(12) 0.017(5) Uani 1 1 d .
N5 N 0.415(3) -0.0729(17) 0.3819(13) 0.022(6) Uani 1 1 d .
N6 N 0.425(3) -0.1333(17) 0.3297(14) 0.025(6) Uani 1 1 d .
N7 N 0.310(3) -0.1597(18) 0.2979(14) 0.025(6) Uani 1 1 d .
N8 N 0.220(2) -0.1243(17) 0.3317(13) 0.020(5) Uani 1 1 d .
C1 C -0.250(3) 0.086(2) 0.3113(17) 0.028(7) Uani 1 1 d .
C2 C -0.500(3) 0.091(2) 0.2603(18) 0.031(8) Uani 1 1 d .
H2A H -0.5033 0.0226 0.2545 0.046 Uiso 1 1 calc R
H2B H -0.5509 0.1207 0.2193 0.046 Uiso 1 1 calc R
H2C H -0.5395 0.1079 0.2986 0.046 Uiso 1 1 calc R
C3 C 0.285(3) -0.065(2) 0.3818(17) 0.027(7) Uani 1 1 d .
C4 C 0.075(3) -0.141(2) 0.3058(18) 0.031(8) Uani 1 1 d .
H4A H 0.0616 -0.1713 0.2614 0.046 Uiso 1 1 calc R
H4B H 0.0271 -0.0817 0.3019 0.046 Uiso 1 1 calc R
H4C H 0.0416 -0.1827 0.3370 0.046 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O22 Si1 O22 180(5) 3 .
O22 Si1 O19 114(3) 3 3
O22 Si1 O19 66(3) . 3
O22 Si1 O19 66(3) 3 .
O22 Si1 O19 114(3) . .
O19 Si1 O19 180(5) 3 .
O22 Si1 O21 67(3) 3 .
O22 Si1 O21 113(3) . .
O19 Si1 O21 73(3) 3 .
O19 Si1 O21 107(3) . .
O22 Si1 O21 113(3) 3 3
O22 Si1 O21 67(3) . 3
O19 Si1 O21 107(3) 3 3
O19 Si1 O21 73(3) . 3
O21 Si1 O21 180(3) . 3
O22 Si1 O20 71(3) 3 .
O22 Si1 O20 109(3) . .
O19 Si1 O20 71(3) 3 .
O19 Si1 O20 109(3) . .
O21 Si1 O20 104(3) . .
O21 Si1 O20 76(3) 3 .
O22 Si1 O20 109(3) 3 3
O22 Si1 O20 71(3) . 3
O19 Si1 O20 109(3) 3 3
O19 Si1 O20 71(3) . 3
O21 Si1 O20 76(3) . 3
O21 Si1 O20 104(3) 3 3
O20 Si1 O20 180(5) . 3
O1 W1 O18 103.2(13) . .
O1 W1 O16 102.0(13) . .
O18 W1 O16 88.4(11) . .
O1 W1 O11 100.4(14) . .
O18 W1 O11 90.5(12) . .
O16 W1 O11 157.2(13) . .
O1 W1 O7 98.9(14) . .
O18 W1 O7 157.7(13) . .
O16 W1 O7 84.2(12) . .
O11 W1 O7 88.4(12) . .
O1 W1 O19 155.9(17) . .
O18 W1 O19 96.2(16) . .
O16 W1 O19 92.7(16) . .
O11 W1 O19 64.8(16) . .
O7 W1 O19 63.3(16) . .
O1 W1 O22 159.9(16) . 3
O18 W1 O22 65.9(16) . 3
O16 W1 O22 62.2(15) . 3
O11 W1 O22 96.7(15) . 3
O7 W1 O22 92.1(16) . 3
O19 W1 O22 43.8(18) . 3
O2 W2 O7 101.1(13) . .
O2 W2 O10 97.5(14) . .
O7 W2 O10 89.8(13) . .
O2 W2 O8 102.6(13) . .
O7 W2 O8 89.8(12) . .
O10 W2 O8 159.6(13) . .
O2 W2 O9 99.6(13) . .
O7 W2 O9 159.2(13) . .
O10 W2 O9 85.3(12) . .
O8 W2 O9 87.9(12) . .
O2 W2 O20 153.8(16) . 3
O7 W2 O20 97.8(16) . 3
O10 W2 O20 64.5(16) . 3
O8 W2 O20 95.3(16) . 3
O9 W2 O20 61.9(16) . 3
O2 W2 O19 157.0(17) . .
O7 W2 O19 61.8(16) . .
O10 W2 O19 97.7(16) . .
O8 W2 O19 64.4(15) . .
O9 W2 O19 98.8(16) . .
O20 W2 O19 49.1(18) 3 .
O3 W3 O8 103.1(14) . .
O3 W3 O11 101.4(13) . .
O8 W3 O11 88.5(12) . .
O3 W3 O12 97.8(14) . .
O8 W3 O12 159.0(14) . .
O11 W3 O12 89.0(12) . .
O3 W3 O15 101.0(13) . 3
O8 W3 O15 87.0(12) . 3
O11 W3 O15 157.6(13) . 3
O12 W3 O15 87.4(12) . 3
O3 W3 O21 155.2(16) . 3
O8 W3 O21 93.1(16) . 3
O11 W3 O21 97.7(16) . 3
O12 W3 O21 66.6(16) . 3
O15 W3 O21 60.7(15) 3 3
O3 W3 O19 157.8(16) . .
O8 W3 O19 63.9(16) . .
O11 W3 O19 62.1(16) . .
O12 W3 O19 96.7(16) . .
O15 W3 O19 96.3(16) 3 .
O21 W3 O19 47.0(18) 3 .
O4 W4 O17 103.4(12) . .
O4 W4 O9 98.6(13) . 3
O17 W4 O9 89.1(12) . 3
O4 W4 O13 99.5(13) . 3
O17 W4 O13 157.1(13) . 3
O9 W4 O13 87.8(12) 3 3
O4 W4 O18 102.2(12) . .
O17 W4 O18 88.6(11) . .
O9 W4 O18 159.0(13) 3 .
O13 W4 O18 86.2(11) 3 .
O4 W4 O20 153.4(16) . .
O17 W4 O20 94.6(15) . .
O9 W4 O20 61.8(16) 3 .
O13 W4 O20 64.2(16) 3 .
O18 W4 O20 97.6(15) . .
O4 W4 O22 158.6(15) . 3
O17 W4 O22 62.9(14) . 3
O9 W4 O22 97.5(15) 3 3
O13 W4 O22 95.1(15) 3 3
O18 W4 O22 63.1(15) . 3
O20 W4 O22 48.0(17) . 3
O5 W5 O15 100.5(12) . .
O5 W5 O16 101.9(12) . .
O15 W5 O16 157.5(12) . .
O5 W5 O14 105.1(12) . .
O15 W5 O14 88.6(11) . .
O16 W5 O14 87.7(11) . .
O5 W5 O17 101.3(12) . .
O15 W5 O17 85.6(11) . .
O16 W5 O17 87.9(11) . .
O14 W5 O17 153.6(12) . .
O5 W5 O21 159.2(16) . .
O15 W5 O21 64.4(16) . .
O16 W5 O21 94.4(15) . .
O14 W5 O21 62.3(16) . .
O17 W5 O21 92.1(16) . .
O5 W5 O22 156.2(16) . 3
O15 W5 O22 96.4(16) . 3
O16 W5 O22 61.6(15) . 3
O14 W5 O22 91.8(16) . 3
O17 W5 O22 63.3(15) . 3
O21 W5 O22 44.6(18) . 3
O6 W6 O14 103.8(12) . .
O6 W6 O12 100.7(13) . 3
O14 W6 O12 87.9(12) . 3
O6 W6 O13 98.7(12) . .
O14 W6 O13 157.3(13) . .
O12 W6 O13 90.9(12) 3 .
O6 W6 O10 96.8(13) . .
O14 W6 O10 87.3(12) . .
O12 W6 O10 162.5(13) 3 .
O13 W6 O10 87.2(12) . .
O6 W6 O20 150.6(15) . 3
O14 W6 O20 95.5(16) . 3
O12 W6 O20 102.0(16) 3 3
O13 W6 O20 62.6(16) . 3
O10 W6 O20 61.8(16) . 3
O6 W6 O21 158.0(15) . .
O14 W6 O21 59.7(15) . .
O12 W6 O21 66.4(15) 3 .
O13 W6 O21 99.2(16) . .
O10 W6 O21 96.7(15) . .
O20 W6 O21 51.2(17) 3 .
N1 Ag1 O5 96.3(9) . .
N1 Ag1 S2 131.9(6) . .
O5 Ag1 S2 98.5(6) . .
N1 Ag1 Ag2 81.1(6) . .
O5 Ag1 Ag2 116.1(6) . .
S2 Ag1 Ag2 51.36(19) . .
O1W Ag2 S1 120.2(7) . .
O1W Ag2 S2 98.9(7) . .
S1 Ag2 S2 139.9(3) . .
O1W Ag2 Ag2 68.6(7) . 3_556
S1 Ag2 Ag2 117.7(2) . 3_556
S2 Ag2 Ag2 82.9(2) . 3_556
O1W Ag2 Ag1 150.4(6) . .
S1 Ag2 Ag1 89.2(2) . .
S2 Ag2 Ag1 52.9(2) . .
Ag2 Ag2 Ag1 95.78(16) 3_556 .
N5 Ag3 S2 156.5(7) . 3_656
N5 Ag3 O2 93.8(9) . 4_666
S2 Ag3 O2 102.2(6) 3_656 4_666
N5 Ag3 S1 93.3(6) . 1_655
S2 Ag3 S1 104.7(3) 3_656 1_655
O2 Ag3 S1 86.1(7) 4_666 1_655
N5 Ag3 Ag3 80.2(6) . 3_656
S2 Ag3 Ag3 85.2(2) 3_656 3_656
O2 Ag3 Ag3 81.5(7) 4_666 3_656
S1 Ag3 Ag3 165.6(2) 1_655 3_656
N2 Ag4 N6 133.6(9) 2_545 .
N2 Ag4 O3 83.2(10) 2_545 3_655
N6 Ag4 O3 134.3(9) . 3_655
N2 Ag4 S1 123.9(7) 2_545 1_655
N6 Ag4 S1 91.5(7) . 1_655
O3 Ag4 S1 83.7(7) 3_655 1_655
C1 S1 Ag2 108.7(11) . .
C1 S1 Ag4 111.2(12) . 1_455
Ag2 S1 Ag4 127.7(3) . 1_455
C1 S1 Ag3 112.8(11) . 1_455
Ag2 S1 Ag3 97.4(3) . 1_455
Ag4 S1 Ag3 97.1(2) 1_455 1_455
C3 S2 Ag3 107.5(11) . 3_656
C3 S2 Ag2 106.2(11) . .
Ag3 S2 Ag2 124.3(3) 3_656 .
C3 S2 Ag1 106.0(11) . .
Ag3 S2 Ag1 132.5(4) 3_656 .
Ag2 S2 Ag1 75.7(2) . .
W2 O2 Ag3 150.1(14) . 4_565
W3 O3 Ag4 156.2(16) . 3_655
W5 O5 Ag1 141.5(14) . .
W2 O7 W1 137.9(16) . .
W3 O8 W2 138.2(16) . .
W4 O9 W2 136.3(17) 3 .
W2 O10 W6 135.4(17) . .
W1 O11 W3 137.7(17) . .
W6 O12 W3 134.3(17) 3 .
W6 O13 W4 136.0(17) . 3
W6 O14 W5 141.0(16) . .
W5 O15 W3 136.9(16) . 3
W1 O16 W5 139.7(15) . .
W4 O17 W5 140.2(15) . .
W1 O18 W4 137.7(15) . .
Si1 O19 O22 56(2) . 3
Si1 O19 W1 125(3) . .
O22 O19 W1 70(3) 3 .
Si1 O19 W2 120(3) . .
O22 O19 W2 130(3) 3 .
W1 O19 W2 96(2) . .
Si1 O19 W3 120(3) . .
O22 O19 W3 134(3) 3 .
W1 O19 W3 95(2) . .
W2 O19 W3 93.1(19) . .
Si1 O20 W2 120(3) . 3
Si1 O20 W4 121(3) . .
W2 O20 W4 100(2) 3 .
Si1 O20 W6 116(3) . 3
W2 O20 W6 98.2(19) 3 3
W4 O20 W6 97.2(19) . 3
Si1 O21 O22 55(2) . 3
Si1 O21 W5 126(3) . .
O22 O21 W5 71(2) 3 .
Si1 O21 W3 120(3) . 3
O22 O21 W3 136(3) 3 3
W5 O21 W3 97.4(19) . 3
Si1 O21 W6 117(3) . .
O22 O21 W6 130(3) 3 .
W5 O21 W6 96.3(19) . .
W3 O21 W6 92.7(18) 3 .
Si1 O22 O19 58(3) . 3
Si1 O22 O21 59(2) . 3
O19 O22 O21 97(4) 3 3
Si1 O22 W1 125(3) . 3
O19 O22 W1 67(2) 3 3
O21 O22 W1 135(3) 3 3
Si1 O22 W5 123(3) . 3
O19 O22 W5 133(3) 3 3
O21 O22 W5 64(2) 3 3
W1 O22 W5 95.6(18) 3 3
Si1 O22 W4 120(3) . 3
O19 O22 W4 130(3) 3 3
O21 O22 W4 126(3) 3 3
W1 O22 W4 93.1(18) 3 3
W5 O22 W4 93.0(18) 3 3
C1 N1 N2 108(3) . .
C1 N1 Ag1 132(2) . .
N2 N1 Ag1 120.6(18) . .
N3 N2 N1 110(2) . .
N3 N2 Ag4 114.9(18) . 2
N1 N2 Ag4 135.4(19) . 2
N2 N3 N4 105(2) . .
C1 N4 N3 110(2) . .
C1 N4 C2 131(3) . .
N3 N4 C2 119(2) . .
C3 N5 N6 107(3) . .
C3 N5 Ag3 133(2) . .
N6 N5 Ag3 119.4(19) . .
N7 N6 N5 111(2) . .
N7 N6 Ag4 117(2) . .
N5 N6 Ag4 128.8(19) . .
N6 N7 N8 107(2) . .
N7 N8 C3 109(2) . .
N7 N8 C4 120(2) . .
C3 N8 C4 131(3) . .
N1 C1 N4 108(3) . .
N1 C1 S1 128(2) . .
N4 C1 S1 124(2) . .
N5 C3 N8 106(3) . .
N5 C3 S2 124(3) . .
N8 C3 S2 130(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Si1 O22 1.58(5) 3
Si1 O22 1.58(5) .
Si1 O19 1.62(6) 3
Si1 O19 1.62(6) .
Si1 O21 1.65(5) .
Si1 O21 1.65(5) 3
Si1 O20 1.75(5) .
Si1 O20 1.75(5) 3
W1 O1 1.67(2) .
W1 O18 1.86(3) .
W1 O16 1.87(3) .
W1 O11 1.88(3) .
W1 O7 1.91(3) .
W1 O19 2.33(6) .
W1 O22 2.38(5) 3
W2 O2 1.67(3) .
W2 O7 1.87(3) .
W2 O10 1.88(3) .
W2 O8 1.89(3) .
W2 O9 1.91(3) .
W2 O20 2.29(5) 3
W2 O19 2.42(5) .
W3 O3 1.72(3) .
W3 O8 1.88(3) .
W3 O11 1.90(3) .
W3 O12 1.92(3) .
W3 O15 1.92(3) 3
W3 O21 2.42(5) 3
W3 O19 2.44(5) .
W4 O4 1.66(2) .
W4 O17 1.81(3) .
W4 O9 1.89(3) 3
W4 O13 1.90(3) 3
W4 O18 1.92(3) .
W4 O20 2.31(5) .
W4 O22 2.47(5) 3
W5 O5 1.69(2) .
W5 O15 1.87(3) .
W5 O16 1.90(3) .
W5 O14 1.92(3) .
W5 O17 1.94(3) .
W5 O21 2.28(5) .
W5 O22 2.39(5) 3
W6 O6 1.65(2) .
W6 O14 1.82(3) .
W6 O12 1.90(3) 3
W6 O13 1.90(3) .
W6 O10 1.94(3) .
W6 O20 2.39(5) 3
W6 O21 2.45(5) .
Ag1 N1 2.28(2) .
Ag1 O5 2.45(2) .
Ag1 S2 2.559(8) .
Ag1 Ag2 3.107(4) .
Ag2 O1W 2.41(3) .
Ag2 S1 2.419(8) .
Ag2 S2 2.505(8) .
Ag2 Ag2 3.027(6) 3_556
Ag3 N5 2.26(3) .
Ag3 S2 2.479(7) 3_656
Ag3 O2 2.50(3) 4_666
Ag3 S1 2.718(8) 1_655
Ag3 Ag3 3.180(5) 3_656
Ag4 N2 2.26(3) 2_545
Ag4 N6 2.35(3) .
Ag4 O3 2.56(3) 3_655
Ag4 S1 2.651(7) 1_655
S1 C1 1.73(3) .
S1 Ag4 2.651(7) 1_455
S1 Ag3 2.718(8) 1_455
S2 C3 1.74(3) .
S2 Ag3 2.479(7) 3_656
O2 Ag3 2.50(3) 4_565
O3 Ag4 2.56(3) 3_655
O9 W4 1.89(3) 3
O12 W6 1.90(3) 3
O13 W4 1.90(3) 3
O15 W3 1.92(3) 3
O19 O22 1.75(7) 3
O20 W2 2.29(5) 3
O20 W6 2.39(5) 3
O21 O22 1.78(8) 3
O21 W3 2.42(5) 3
O22 O19 1.75(7) 3
O22 O21 1.78(8) 3
O22 W1 2.38(5) 3
O22 W5 2.39(5) 3
O22 W4 2.47(5) 3
N1 C1 1.30(4) .
N1 N2 1.34(3) .
N2 N3 1.32(3) .
N2 Ag4 2.26(3) 2
N3 N4 1.35(3) .
N4 C1 1.32(4) .
N4 C2 1.44(4) .
N5 C3 1.31(4) .
N5 N6 1.36(3) .
N6 N7 1.25(4) .
N7 N8 1.33(3) .
N8 C3 1.36(4) .
N8 C4 1.45(4) .
