#------------------------------------------------------------------------------
#$Date: 2021-02-05 00:05:02 +0100 (vie 05 de feb de 2021) $
#$Revision: 261632 $
#$URL: svn://www.crystallography.net/cod/cif/7/24/18/7241863.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7241863
loop_
_publ_author_name
'Dong, Lu'
'Lu, Ying-Bing'
'Zhu, Shui-Dong'
'Wu, Jun-Wei'
'Zhang, Xin-Ting'
'Liao, Yi'
'Liu, Cai-Ming'
'Liu, Sui-Jun'
'Xie, Yong-Rong'
'Zhang, Shi-Yong'
_publ_section_title
;
 A new family of dinuclear lanthanide complexes exhibiting luminescence,
 magnetic entropy changes and single molecule magnet behaviors
;
_journal_issue                   3
_journal_name_full               CrystEngComm
_journal_page_first              645
_journal_page_last               652
_journal_paper_doi               10.1039/D0CE01477J
_journal_volume                  23
_journal_year                    2021
_chemical_formula_moiety         '[Eu(C12N2H8)4(C3N4H3O2)2(Cl)2](ClO4)2'
_chemical_formula_sum            'C54 H38 Cl4 Eu2 N16 O12'
_chemical_formula_weight         1548.72
_chemical_melting_point          ?
_chemical_name_common            '[Eu(C12N2H8)4(C3N4H3O2)2(Cl)2](ClO4)2'
_chemical_name_systematic
; 
 '[Eu(C12N2H8)4(C3N4H3O2)2(Cl)2](ClO4)2' 
;
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2020-10-03 deposited with the CCDC.	2020-11-12 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 94.5420(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.0689(3)
_cell_length_b                   11.6727(3)
_cell_length_c                   21.7296(6)
_cell_measurement_temperature    293(2)
_cell_volume                     3051.58(14)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SMART'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0281
_diffrn_reflns_av_sigmaI/netI    0.0192
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            44951
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         3.40
_exptl_absorpt_coefficient_mu    2.285
_exptl_absorpt_correction_T_max  0.7459
_exptl_absorpt_correction_T_min  0.6328
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2008)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.685
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blcok
_exptl_crystal_F_000             1528
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.281
_refine_diff_density_min         -0.840
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         6951
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.065
_refine_ls_R_factor_all          0.0453
_refine_ls_R_factor_gt           0.0346
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0349P)²+13.2785P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0829
_refine_ls_wR_factor_ref         0.0922
_reflns_number_gt                5897
_reflns_number_total             6951
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d0ce01477j2.cif
_cod_data_source_block           14
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_chemical_melting_point' value 'not measured' was changed
to '?' -- the value is undefined or not given.

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_exptl_crystal_density_meas' value 'not measured' was
changed to '?' -- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 

 Adding full bibliography for 7241863--7241866.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7241863
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.605572(16) 0.872744(17) 0.492215(9) 0.02692(7) Uani 1 1 d . . .
Cl2 Cl 0.72227(11) 0.70591(13) 0.76878(6) 0.0498(3) Uani 1 1 d . . .
Cl1 Cl 0.37640(8) 0.89609(9) 0.47918(5) 0.0340(2) Uani 1 1 d . . .
C17 C 0.6714(5) 0.3841(4) 0.4622(3) 0.0572(15) Uani 1 1 d . . .
H17 H 0.6982 0.3112 0.4723 0.069 Uiso 1 1 calc R . .
C12 C 0.8904(4) 0.8671(4) 0.5274(2) 0.0359(9) Uani 1 1 d . . .
C25 C 0.4895(4) 0.9459(4) 0.6232(2) 0.0356(9) Uani 1 1 d . . .
C7 C 0.9769(4) 0.8087(5) 0.4336(3) 0.0479(12) Uani 1 1 d . . .
C1 C 0.8054(4) 0.9300(5) 0.6123(2) 0.0430(11) Uani 1 1 d . . .
H1 H 0.7414 0.9503 0.6308 0.052 Uiso 1 1 calc R . .
C11 C 0.8804(4) 0.8337(4) 0.4639(2) 0.0365(10) Uani 1 1 d . . .
C22 C 0.4925(4) 0.7251(5) 0.3638(2) 0.0443(11) Uani 1 1 d . . .
H22 H 0.4580 0.7953 0.3558 0.053 Uiso 1 1 calc R . .
C24 C 0.6394(4) 0.5828(4) 0.4926(2) 0.0322(9) Uani 1 1 d . . .
C23 C 0.5899(4) 0.6033(4) 0.4314(2) 0.0329(9) Uani 1 1 d . . .
C20 C 0.5337(5) 0.5390(5) 0.3286(3) 0.0539(14) Uani 1 1 d . . .
H20 H 0.5325 0.4841 0.2976 0.065 Uiso 1 1 calc R . .
C21 C 0.4857(5) 0.6432(5) 0.3173(3) 0.0531(14) Uani 1 1 d . . .
H21 H 0.4488 0.6593 0.2790 0.064 Uiso 1 1 calc R . .
C19 C 0.5853(4) 0.5150(4) 0.3876(2) 0.0429(11) Uani 1 1 d . . .
C10 C 0.7704(5) 0.8054(5) 0.3736(2) 0.0514(13) Uani 1 1 d . . .
H10 H 0.7006 0.8054 0.3522 0.062 Uiso 1 1 calc R . .
C4 C 0.9958(4) 0.8752(4) 0.5589(3) 0.0458(12) Uani 1 1 d . . .
C2 C 0.9083(5) 0.9403(5) 0.6468(3) 0.0508(13) Uani 1 1 d . . .
H2 H 0.9116 0.9666 0.6873 0.061 Uiso 1 1 calc R . .
C13 C 0.6840(5) 0.6491(5) 0.5910(2) 0.0455(12) Uani 1 1 d . . .
H13 H 0.6888 0.7093 0.6191 0.055 Uiso 1 1 calc R . .
C15 C 0.7161(5) 0.4524(5) 0.5698(3) 0.0550(14) Uani 1 1 d . . .
H15 H 0.7410 0.3800 0.5823 0.066 Uiso 1 1 calc R . .
C14 C 0.7186(5) 0.5407(5) 0.6115(3) 0.0555(14) Uani 1 1 d . . .
H14 H 0.7430 0.5286 0.6527 0.067 Uiso 1 1 calc R . .
C26 C 0.4924(6) 0.9158(6) 0.6913(2) 0.0598(16) Uani 1 1 d . . .
H26A H 0.4776 0.8345 0.6951 0.072 Uiso 1 1 calc R . .
H26B H 0.5667 0.9301 0.7101 0.072 Uiso 1 1 calc R . .
C16 C 0.6761(4) 0.4715(4) 0.5088(2) 0.0431(11) Uani 1 1 d . . .
N5 N 0.4147(5) 0.9778(6) 0.7250(2) 0.0759(18) Uani 1 1 d . . .
C3 C 1.0018(5) 0.9119(5) 0.6208(3) 0.0560(14) Uani 1 1 d . . .
H3 H 1.0703 0.9165 0.6435 0.067 Uiso 1 1 calc R . .
C18 C 0.6292(5) 0.4051(5) 0.4045(3) 0.0581(15) Uani 1 1 d . . .
H18 H 0.6286 0.3473 0.3751 0.070 Uiso 1 1 calc R . .
C8 C 0.9641(5) 0.7789(6) 0.3714(3) 0.0602(16) Uani 1 1 d . . .
H8 H 1.0260 0.7599 0.3505 0.072 Uiso 1 1 calc R . .
C9 C 0.8621(5) 0.7779(6) 0.3415(3) 0.0617(16) Uani 1 1 d . . .
H9 H 0.8530 0.7589 0.2998 0.074 Uiso 1 1 calc R . .
C5 C 1.0923(4) 0.8508(5) 0.5266(3) 0.0600(16) Uani 1 1 d . . .
H5 H 1.1626 0.8576 0.5471 0.072 Uiso 1 1 calc R . .
C6 C 1.0829(4) 0.8186(6) 0.4674(3) 0.0602(16) Uani 1 1 d . . .
H6 H 1.1468 0.8022 0.4478 0.072 Uiso 1 1 calc R . .
N3 N 0.6447(3) 0.6709(3) 0.53350(17) 0.0355(8) Uani 1 1 d . . .
N1 N 0.7951(3) 0.8926(3) 0.55428(17) 0.0340(8) Uani 1 1 d . . .
N4 N 0.5457(3) 0.7089(3) 0.41914(17) 0.0352(8) Uani 1 1 d . . .
N2 N 0.7772(3) 0.8316(4) 0.43340(18) 0.0385(9) Uani 1 1 d . . .
N6 N 0.3059(8) 0.9530(9) 0.7229(4) 0.120(3) Uani 1 1 d U . .
N8 N 0.3460(12) 1.1077(11) 0.7812(5) 0.153(4) Uani 1 1 d U . .
N7 N 0.2707(8) 1.0361(9) 0.7618(4) 0.116(3) Uani 1 1 d U . .
C27 C 0.4324(13) 1.0677(11) 0.7603(4) 0.140(5) Uani 1 1 d . . .
H27A H 0.5026 1.0994 0.7691 0.168 Uiso 1 1 calc R . .
O1 O 0.5503(3) 0.8844(3) 0.59318(14) 0.0369(7) Uani 1 1 d . . .
O2 O 0.4311(3) 1.0291(3) 0.60393(14) 0.0368(7) Uani 1 1 d . . .
O4 O 0.7213(6) 0.7461(8) 0.8264(3) 0.144(3) Uani 1 1 d U . .
O6 O 0.7688(7) 0.7715(8) 0.7263(3) 0.155(3) Uani 1 1 d U . .
O5 O 0.7971(8) 0.6158(9) 0.7767(6) 0.185(4) Uani 1 1 d U . .
O3 O 0.6175(4) 0.6635(5) 0.7451(2) 0.0731(13) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O2 137.88(10) . 3_676 ?
O1 Eu1 N3 77.49(11) . . ?
O2 Eu1 N3 139.91(12) 3_676 . ?
O1 Eu1 N4 122.52(12) . . ?
O2 Eu1 N4 77.98(12) 3_676 . ?
N3 Eu1 N4 64.05(12) . . ?
O1 Eu1 N2 141.02(12) . . ?
O2 Eu1 N2 75.83(12) 3_676 . ?
N3 Eu1 N2 82.43(13) . . ?
N4 Eu1 N2 75.51(13) . . ?
O1 Eu1 N1 79.12(12) . . ?
O2 Eu1 N1 120.66(12) 3_676 . ?
N3 Eu1 N1 76.53(12) . . ?
N4 Eu1 N1 126.15(12) . . ?
N2 Eu1 N1 63.79(12) . . ?
O1 Eu1 Cl1 74.62(8) . . ?
O2 Eu1 Cl1 75.50(8) 3_676 . ?
N3 Eu1 Cl1 106.38(9) . . ?
N4 Eu1 Cl1 77.24(9) . . ?
N2 Eu1 Cl1 143.77(9) . . ?
N1 Eu1 Cl1 152.07(9) . . ?
O1 Eu1 Cl1 75.94(8) . 3_676 ?
O2 Eu1 Cl1 74.68(8) 3_676 3_676 ?
N3 Eu1 Cl1 144.14(9) . 3_676 ?
N4 Eu1 Cl1 151.80(9) . 3_676 ?
N2 Eu1 Cl1 103.98(10) . 3_676 ?
N1 Eu1 Cl1 75.16(9) . 3_676 ?
Cl1 Eu1 Cl1 89.26(3) . 3_676 ?
O1 Eu1 Eu1 69.08(7) . 3_676 ?
O2 Eu1 Eu1 68.80(7) 3_676 3_676 ?
N3 Eu1 Eu1 140.15(9) . 3_676 ?
N4 Eu1 Eu1 117.67(8) . 3_676 ?
N2 Eu1 Eu1 137.42(10) . 3_676 ?
N1 Eu1 Eu1 116.14(8) . 3_676 ?
Cl1 Eu1 Eu1 44.66(2) . 3_676 ?
Cl1 Eu1 Eu1 44.61(2) 3_676 3_676 ?
O4 Cl2 O6 118.3(5) . . ?
O4 Cl2 O5 101.8(6) . . ?
O6 Cl2 O5 102.3(7) . . ?
O4 Cl2 O3 112.9(4) . . ?
O6 Cl2 O3 110.8(4) . . ?
O5 Cl2 O3 109.5(5) . . ?
Eu1 Cl1 Eu1 90.74(3) . 3_676 ?
C18 C17 C16 121.4(5) . . ?
C18 C17 H17 119.3 . . ?
C16 C17 H17 119.3 . . ?
N1 C12 C4 122.7(5) . . ?
N1 C12 C11 117.6(4) . . ?
C4 C12 C11 119.7(4) . . ?
O1 C25 O2 127.6(4) . . ?
O1 C25 C26 114.1(4) . . ?
O2 C25 C26 118.3(4) . . ?
C8 C7 C11 118.1(5) . . ?
C8 C7 C6 123.1(5) . . ?
C11 C7 C6 118.7(5) . . ?
N1 C1 C2 123.2(5) . . ?
N1 C1 H1 118.4 . . ?
C2 C1 H1 118.4 . . ?
N2 C11 C7 121.7(5) . . ?
N2 C11 C12 118.5(4) . . ?
C7 C11 C12 119.8(4) . . ?
N4 C22 C21 123.8(5) . . ?
N4 C22 H22 118.1 . . ?
C21 C22 H22 118.1 . . ?
N3 C24 C16 122.5(4) . . ?
N3 C24 C23 118.4(4) . . ?
C16 C24 C23 119.0(4) . . ?
N4 C23 C19 122.6(4) . . ?
N4 C23 C24 117.4(4) . . ?
C19 C23 C24 120.0(4) . . ?
C21 C20 C19 119.6(5) . . ?
C21 C20 H20 120.2 . . ?
C19 C20 H20 120.2 . . ?
C20 C21 C22 118.9(5) . . ?
C20 C21 H21 120.6 . . ?
C22 C21 H21 120.6 . . ?
C23 C19 C20 117.6(5) . . ?
C23 C19 C18 119.5(5) . . ?
C20 C19 C18 122.9(5) . . ?
N2 C10 C9 123.5(5) . . ?
N2 C10 H10 118.2 . . ?
C9 C10 H10 118.2 . . ?
C12 C4 C3 117.6(5) . . ?
C12 C4 C5 119.2(5) . . ?
C3 C4 C5 123.1(5) . . ?
C3 C2 C1 119.3(5) . . ?
C3 C2 H2 120.3 . . ?
C1 C2 H2 120.3 . . ?
N3 C13 C14 123.4(5) . . ?
N3 C13 H13 118.3 . . ?
C14 C13 H13 118.3 . . ?
C14 C15 C16 119.8(5) . . ?
C14 C15 H15 120.1 . . ?
C16 C15 H15 120.1 . . ?
C15 C14 C13 118.7(5) . . ?
C15 C14 H14 120.6 . . ?
C13 C14 H14 120.6 . . ?
N5 C26 C25 114.7(4) . . ?
N5 C26 H26A 108.6 . . ?
C25 C26 H26A 108.6 . . ?
N5 C26 H26B 108.6 . . ?
C25 C26 H26B 108.6 . . ?
H26A C26 H26B 107.6 . . ?
C15 C16 C24 117.6(5) . . ?
C15 C16 C17 123.3(5) . . ?
C24 C16 C17 119.0(5) . . ?
N6 N5 C27 107.9(8) . . ?
N6 N5 C26 123.5(8) . . ?
C27 N5 C26 128.5(9) . . ?
C2 C3 C4 119.8(5) . . ?
C2 C3 H3 120.1 . . ?
C4 C3 H3 120.1 . . ?
C17 C18 C19 120.9(5) . . ?
C17 C18 H18 119.5 . . ?
C19 C18 H18 119.5 . . ?
C9 C8 C7 119.8(5) . . ?
C9 C8 H8 120.1 . . ?
C7 C8 H8 120.1 . . ?
C8 C9 C10 119.3(6) . . ?
C8 C9 H9 120.4 . . ?
C10 C9 H9 120.4 . . ?
C6 C5 C4 121.1(5) . . ?
C6 C5 H5 119.5 . . ?
C4 C5 H5 119.5 . . ?
C5 C6 C7 121.5(5) . . ?
C5 C6 H6 119.2 . . ?
C7 C6 H6 119.2 . . ?
C13 N3 C24 117.9(4) . . ?
C13 N3 Eu1 123.4(3) . . ?
C24 N3 Eu1 118.1(3) . . ?
C1 N1 C12 117.3(4) . . ?
C1 N1 Eu1 122.6(3) . . ?
C12 N1 Eu1 120.0(3) . . ?
C22 N4 C23 117.3(4) . . ?
C22 N4 Eu1 123.2(3) . . ?
C23 N4 Eu1 118.0(3) . . ?
C10 N2 C11 117.5(4) . . ?
C10 N2 Eu1 122.7(3) . . ?
C11 N2 Eu1 119.8(3) . . ?
N7 N6 N5 100.1(9) . . ?
N7 N8 C27 103.0(13) . . ?
N6 N7 N8 114.6(10) . . ?
N5 C27 N8 114.1(15) . . ?
N5 C27 H27A 123.0 . . ?
N8 C27 H27A 123.0 . . ?
C25 O1 Eu1 138.2(3) . . ?
C25 O2 Eu1 136.3(3) . 3_676 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.347(3) . ?
Eu1 O2 2.393(3) 3_676 ?
Eu1 N3 2.552(4) . ?
Eu1 N4 2.553(4) . ?
Eu1 N2 2.564(4) . ?
Eu1 N1 2.572(4) . ?
Eu1 Cl1 2.7713(10) . ?
Eu1 Cl1 2.7736(11) 3_676 ?
Eu1 Eu1 3.9460(4) 3_676 ?
Cl2 O4 1.338(6) . ?
Cl2 O6 1.355(6) . ?
Cl2 O5 1.388(9) . ?
Cl2 O3 1.417(4) . ?
Cl1 Eu1 2.7736(11) 3_676 ?
C17 C18 1.337(9) . ?
C17 C16 1.435(8) . ?
C17 H17 0.9300 . ?
C12 N1 1.364(6) . ?
C12 C4 1.400(6) . ?
C12 C11 1.430(7) . ?
C25 O1 1.247(5) . ?
C25 O2 1.254(5) . ?
C25 C26 1.518(7) . ?
C7 C8 1.392(8) . ?
C7 C11 1.413(6) . ?
C7 C6 1.429(8) . ?
C1 N1 1.330(6) . ?
C1 C2 1.405(7) . ?
C1 H1 0.9300 . ?
C11 N2 1.364(6) . ?
C22 N4 1.331(6) . ?
C22 C21 1.388(7) . ?
C22 H22 0.9300 . ?
C24 N3 1.357(6) . ?
C24 C16 1.409(6) . ?
C24 C23 1.434(6) . ?
C23 N4 1.361(6) . ?
C23 C19 1.401(6) . ?
C20 C21 1.361(8) . ?
C20 C19 1.407(8) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C19 C18 1.425(7) . ?
C10 N2 1.331(6) . ?
C10 C9 1.393(7) . ?
C10 H10 0.9300 . ?
C4 C3 1.407(8) . ?
C4 C5 1.435(8) . ?
C2 C3 1.344(8) . ?
C2 H2 0.9300 . ?
C13 N3 1.326(6) . ?
C13 C14 1.394(7) . ?
C13 H13 0.9300 . ?
C15 C14 1.371(8) . ?
C15 C16 1.393(8) . ?
C15 H15 0.9300 . ?
C14 H14 0.9300 . ?
C26 N5 1.431(8) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
N5 N6 1.343(11) . ?
N5 C27 1.307(14) . ?
C3 H3 0.9300 . ?
C18 H18 0.9300 . ?
C8 C9 1.346(9) . ?
C8 H8 0.9300 . ?
C9 H9 0.9300 . ?
C5 C6 1.336(9) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
N6 N7 1.376(12) . ?
N8 N7 1.281(14) . ?
N8 C27 1.260(14) . ?
C27 H27A 0.9300 . ?
O2 Eu1 2.393(3) 3_676 ?
