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4070529 CIFC5 H5 Br3 ZrP -16.6064; 7.1808; 9.0424
100.621; 92.0073; 103.101
409.317Glöckner, Andreas; Arif, Atta M.; Ernst, Richard D.
Isolation and Characterization of Bromination Products of Zr(C5H5)2Br2
Organometallics, 2008, 27, 327
4070823 CIFC9 H13 GaP -17.02; 7.121; 10.309
72.703; 76.898; 65.767
445.43Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4071920 CIFC24 H26 CrP -17.372; 8.565; 8.586
69.977; 74.027; 73.589
478.9Meredith, M. Brett; Crisp, Jeffrey A.; Brady, Erik D.; Hanusa, Timothy P.; Yee, Gordon T.; Pink, Maren; Brennessel, William W.; Young, Victor G.
Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution
Organometallics, 2008, 27, 5464
4070677 CIFC13 H14 CoP 1 n 16.278; 7.28; 10.834
90; 101.286; 90
485.6Mayer, Ulrich F. J.; Charmant, Jonathan P. H.; Rae, James; Manners, Ian
Synthesis and Structures of Strained, Neutral [d7] and Cationic [d6] Hydrocarbon-Bridged [n]Cobaltocenophanes (n= 2, 3)
Organometallics, 2008, 27, 1524
4070543 CIFC16 H20 In2 N10P -16.8471; 8.6997; 9.0856
88.128; 82.9; 70.894
507.46Song, Yi-Hwa; Chiu, Yuan-Chieh; Chi, Yun; Chou, Pi-Tai; Cheng, Yi-Ming; Lin, Chun-Wei; Lee, Gene-Hsiang; Carty, Arthur J.
Synthesis, Characterization, and Photophysical Properties of Luminescent Gallium and Indium Complexes Constructed using Tridentate 6-Azolyl-2,2′-bipyridine Chelates
Organometallics, 2008, 27, 80
4070824 CIFC12 H19 GaP -16.628; 7.069; 12.689
87.743; 89.449; 82.605
589.11Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4071641 CIFC15 H13 N3P -17.7568; 8.2139; 11.3653
75.732; 78.83; 62.01
617.12Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071491 CIFC15 H18 Fe Li NP -17.4443; 9.2993; 9.9602
95.318; 108.51; 102.226
629.43Chen, Chao; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Structural Features of Lithio[3]ferrocenophane Systems Bearing Stabilizing Dimethylamino Substituents
Organometallics, 2008, 27, 3248
4072075 CIFC12 H20 B P SiP 1 21 16.3632; 7.6482; 13.6844
90; 97.056; 90
660.94Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4071488 CIFC16 H20 Fe Li NP -17.5675; 9.2846; 10.4913
106.946; 98.02; 102.853
670.75Chen, Chao; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Structural Features of Lithio[3]ferrocenophane Systems Bearing Stabilizing Dimethylamino Substituents
Organometallics, 2008, 27, 3248
4070708 CIFC8 H5 Fe2 N O6 S2P 1 21/m 16.8441; 13.6033; 7.7636
90; 108.98; 90
683.51Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4071712 CIFC13 H15 Cl N2 O PdP -18.2358; 8.817; 10.974
73.534; 87.561; 63.968
683.6Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4071454 CIFC24 H10 Bi2 F12 O8P -18.2529; 9.3214; 9.8706
91.121; 110.04; 100.932
697.46Dikarev, Evgeny V.; Li, Bo; Rogachev, Andrey Yu.; Zhang, Haitao; Petrukhina, Marina A.
Metal-Site-Controlled Arene Coordination in a Heterobimetallic Bi−Rh Complex with Pyrene
Organometallics, 2008, 27, 3728
4071268 CIFC16 H36 Br2 N2 O4 S2 Zn2P -18.0442; 9.6895; 9.9379
103.446; 99.177; 106.337
701.65Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071721 CIFC11 H16 N2 O2 Si WP -16.3928; 10.6551; 10.8766
100.632; 96.245; 93.51
721.32Fortman, George C.; Isrow, Derek; McDonough, James E.; Schleyer, Paul von Ragué; Schaefer, Henry F.; Scott, Brian; Kubas, Gregory J.; Kégl, Tamás; Ungváry, Ferenc; Hoff, Carl D.
Kinetic and Thermodynamic Studies of the Reactivity of (Trimethylsilyl)diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo−N2CH2SiMe3Bond Strength and Experimental Determination of the Enthalpy of Formation of (Trimethylsilyl)diazomethane
Organometallics, 2008, 27, 4873
4071183 CIFC6 H8 N6C 1 2/c 115.068; 6.881; 7.0171
90; 93.52; 90
726.2Poyatos, Macarena; McNamara, William; Incarvito, Chris; Clot, Eric; Peris, Eduardo; Crabtree, Robert H.
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
Organometallics, 2008, 27, 2128
4071975 CIFC28 H27 Br2 Cl2 N2 P PdP 18.0388; 8.1586; 12.571
91.974; 108.419; 109.78
726.797Schnitzler, Verena; Nonglaton, Guillaume; Roussière, Hélène; Maillet, Céline; Evain, Michel; Janvier, Pascal; Bujoli, Bruno; Petit, Marc
Nitrogen-Based Chirality Effects in Novel Mixed Phosphorus/Nitrogen Ligands Applied to Palladium-Catalyzed Allylic Substitutions
Organometallics, 2008, 27, 5997
4071771 CIFC14 H20 Co Si2P 1 21 18.2595; 10.3127; 8.5719
90; 90.38; 90
730.12Braunschweig, Holger; Breher, Frank; Kaupp, Martin; Gross, Manuela; Kupfer, Thomas; Nied, Dominik; Radacki, Krzysztof; Schinzel, Sandra
Synthesis, Crystal Structure, EPR and DFT Studies, and Redox Properties of [2]Tetramethyldisilacobaltocenophane
Organometallics, 2008, 27, 6427
4072031 CIFC18 H36 B20 Cu2P -17.036; 9.412; 11.529
92.363; 95.143; 105.407
731.4Ren, Shikuo; Xie, Zuowei
A Facile and Practical Synthetic Route to 1,1′-Bis(o-carborane)
Organometallics, 2008, 27, 5167
4070759 CIFC8 H3 B2 Br4 Mn O3P -16.7882; 10.6733; 11.313
100.226; 105.977; 105.209
732.3Eckensberger, U. David; Kunz, Kerstin; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Synthesis and Structural Characterization of the Diborylated Organometallics 1,3-Bis(dibromoboryl)-1′,2′,3′,4′,5′-(pentamethyl)ferrocene and 1,3-Bis(dibromoboryl)cymantrene
Organometallics, 2008, 27, 764
4072293 CIFC11 H12 Cl F3 N2 O2 Ru SP -17.015; 8.164; 14.067
75.68; 83.06; 70.01
733Ito, Masato; Endo, Yoshinori; Ikariya, Takao
Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones
Organometallics, 2008, 27, 6053
4070877 CIFC8 H12 Br2 N5 O ReP -18.1046; 9.4947; 10.0314
86.04; 82.6; 85.37
761.7Choualeb, A.; Maccaroni, E.; Blacque, O.; Schmalle, H. W.; Berke, H.
Rhenium Nitrosyl Complexes for Hydrogenations and Hydrosilylations
Organometallics, 2008, 27, 3474
4070640 CIFC38 H40 N4P -18.483; 9.652; 10.57
81.832; 66.426; 74.004
762Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4072265 CIFC13 H21 O2 P2 VP 1 21/m 17.024; 13.185; 8.438
90; 101.602; 90
765.5Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4071997 CIFC22 H18 B2P 1 21/c 13.9678; 10.318; 19.103
90; 91.268; 90
781.9Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4072363 CIFC14 H20 N6 Ni O4P 1 21/n 16.96; 12.4871; 9.3214
90; 104.732; 90
783.49Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071996 CIFC20 H12 B2 Br2P 1 21/c 13.9318; 19.055; 10.609
90; 92.275; 90
794.2Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4071795 CIFC38 H22 N2 O4 Ru2 S2P -18.805; 9.666; 10.32
105.377; 91.151; 109.159
794.4Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4071575 CIFC16 H21 I N2 PtP 1 21 111.311; 4.6196; 15.981
90; 98.687; 90
825.5Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071716 CIFC22 H20 NiP 1 21 15.7888; 13.1587; 11.1799
90; 103.979; 90
826.39Buchalski, Piotr; Jadach, Patryk; Pietrzykowski, Antoni; Suwińska, Kinga; Jerzykiewicz, Lucjan; Sadło, Jarosław
Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water
Organometallics, 2008, 27, 3618
4071990 CIFC14 H28 B2 N4P 1 21/c 16.7166; 12.7645; 9.7065
90; 93.278; 90
830.82Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071779 CIFC21 H20 O4P -18.0964; 8.8792; 12.731
86.206; 75.741; 71.116
839.2Barluenga, José; Fañanás-Mastral, Martín; Andina, Facundo; Aznar, Fernando; Valdés, Carlos
Cascade Reactions of Dialkynyl Fischer Carbene Complexes Involving Intramolecular Alkyne Insertions Oriented to the Synthesis of Functionalized Polycycles
Organometallics, 2008, 27, 3593
4070675 CIFC18 H23 N2 Ni0.5 OP -18.548; 9.595; 11.491
65.568; 82.827; 79.743
843Boardman, Brycelyn M.; Valderrama, Juan M.; Muñoz, Flor; Wu, Guang; Bazan, Guillermo C.; Rojas, Rene
Remote Activation of Nickel Complexes by Coordination of B(C6F5)3to an Exocyclic Carbonitrile Functionality
Organometallics, 2008, 27, 1671
4071989 CIFC14 H28 B2 N4P -18.024; 10.0761; 11.0822
88.784; 70.959; 84.598
843.2Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071918 CIFC22 H18 N4P 1 21 19.43; 9.3303; 9.6272
90; 90.282; 90
847.04Lowry, Roxy J.; Veige, Melanie K.; Clément, Olivier; Abboud, Khalil A.; Ghiviriga, Ion; Veige, Adam S.
New Constrained-Geometry C2-Symmetric Di-N-heterocyclic Carbene Ligands and Their Mono- and Dinuclear Rhodium(I) Complexes: Design, Synthesis, and Structural Analysis
Organometallics, 2008, 27, 5184-5195
4071446 CIFC16 H10 Cr O6 SP 1 21/m 19.2928; 7.633; 12.4413
90; 104.249; 90
855.34Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4072030 CIFC4 H22 B20P 1 21/n 17.0165; 9.8852; 12.375
90; 90.44; 90
858.3Ren, Shikuo; Xie, Zuowei
A Facile and Practical Synthetic Route to 1,1′-Bis(o-carborane)
Organometallics, 2008, 27, 5167
4071705 CIFC19 H17 P S3P -18.0053; 8.6885; 14.3922
103.068; 92.171; 114.772
875.37Huy, Ngoc Hoa Tran; Donnadieu, Bruno; Mathey, François
The Phosphaalkene-like Reactivity of Dithienophosphinines
Organometallics, 2008, 27, 4005
4070813 CIFC18 H54 Cl2 N4 P2 Si6P -18.762; 9.246; 12.34
77.45; 83.69; 63.81
875.5Schaffrath, Markus; Villinger, Alexander; Michalik, Dirk; Rosenthal, Uwe; Schulz, Axel
Titanocene-Mediated Formation of Phosphorus−Phosphorus Bonds
Organometallics, 2008, 27, 1393
4071561 CIFC30 H42 F10 O6 V2P -19.4241; 9.5143; 11.2825
75.416; 67.418; 78.047
897Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4072203 CIFC18 H23 Cl N2 O2 PdP 1 21 16.4305; 11.728; 12.283
90; 103.426; 90
901Kimura, Tsutomu; Uozumi, Yasuhiro
Synthesis of [2,6-Bis(2-oxazolinyl)phenyl]palladium Complexes via the Ligand Introduction Route
Organometallics, 2008, 27, 5159
4071714 CIFC20 H23 Cl N2 O PdP -17.956; 9.98; 12.514
97.255; 105.519; 103.746
910.6Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4072129 CIFC15 H15 I N4 O4 WP 1 21/m 17.1875; 14.16; 9.0408
90; 97.959; 90
911.3Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4071647 CIFC25 H18 Fe OP -19.5739; 10.447; 10.6029
102.072; 115.407; 96.572
911.4Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071388 CIFC32 H54 Cl2 O6 P2 PdP -18.375; 9.9901; 11.0436
87.13; 85.581; 84.121
915.6Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071000 CIFC40 H48 O4 Ru2 Si4P -110.3381; 10.4244; 10.4263
93.4825; 115.924; 109.649
922.64Okazaki, Masaaki; Yamahira, Nobukazu; Minglana, Jim Josephus Gabrillo; Komuro, Takashi; Ogino, Hiroshi; Tobita, Hiromi
[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
Organometallics, 2008, 27, 918
4071898 CIFC20 H28 N2P 1 21 18.196; 9.418; 12.004
90; 93.13; 90
925.2Grisi, Fabia; Costabile, Chiara; Gallo, Emanuela; Mariconda, Annaluisa; Tedesco, Consiglia; Longo, Pasquale
Ruthenium-Based Complexes Bearing Saturated Chiral N-Heterocyclic Carbene Ligands: Dynamic Behavior and Catalysis
Organometallics, 2008, 27, 4649
4071354 CIFC18 H26 P2 PtP 1 21/m 18.624; 10.9514; 10.323
90; 106.99; 90
932.4Canty, Allan J.; Watson, Russell P.; Karpiniec, Samuel S.; Rodemann, Thomas; Gardiner, Michael G.; Jones, Roderick C.
Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
Organometallics, 2008, 27, 3203
4071091 CIFC9 H8 Fe0.5 O2 PP 1 21/n 16.796; 8.163; 16.939
90; 96.36; 90
933.9Escobar, Aholibama; Donnadieu, Bruno; Mathey, François
From Functional Phospholide Ions to Bifunctional 1,1′-Diphosphaferrocenes
Organometallics, 2008, 27, 1887
4071382 CIFC8 H13 Br N2P 1 21/c 16.7845; 10.725; 13.111
90; 101.54; 90
934.7Normand, Adrien T.; Yen, Swee Kuan; Huynh, Han Vinh; Hor, T. S. Andy; Cavell, Kingsley J.
Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple
Organometallics, 2008, 27, 3153
4071854 CIFC19 H22 N4 O2 SiP -18.32; 9.969; 11.555
91.54; 99.44; 90.17
945Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071412 CIFC20 H33 Mo N OP -18.3346; 8.4671; 14.5068
84.83; 85.483; 68.227
945.7Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071556 CIFC18 H20 Cl2 N4 PdP 1 21/c 17.745; 12.647; 11.215
90; 120.353; 90
947.9Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071785 CIFC22 H31 N O WP -18.1917; 9.7406; 13.6903
73.624; 89.272; 65.724
948.71Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4070979 CIFC12 H35 N6 TaI m -3 m9.835; 9.835; 9.835
90; 90; 90
951.3Zhang, Xin-Hao; Chen, Shu-Jian; Cai, Hu; Im, Hee-Jung; Chen, Tianniu; Yu, Xianghua; Chen, Xuetai; Lin, Zhenyang; Wu, Yun-Dong; Xue, Zi-Ling
Unexpected Formation of (Dimethylaminomethylene)methylamide Complexes from the Reactions between Metal Chlorides and Lithium Dimethylamide
Organometallics, 2008, 27, 1338
4070978 CIFC12 H35 N6 NbI m -3 m9.852; 9.852; 9.852
90; 90; 90
956.25Zhang, Xin-Hao; Chen, Shu-Jian; Cai, Hu; Im, Hee-Jung; Chen, Tianniu; Yu, Xianghua; Chen, Xuetai; Lin, Zhenyang; Wu, Yun-Dong; Xue, Zi-Ling
Unexpected Formation of (Dimethylaminomethylene)methylamide Complexes from the Reactions between Metal Chlorides and Lithium Dimethylamide
Organometallics, 2008, 27, 1338
4070889 CIFC22 H26 N PP -19.6727; 10.3984; 10.748
114.074; 91.19; 102.036
958.5Shaffer, Andrew R.; Schmidt, Joseph A. R.
Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines
Organometallics, 2008, 27, 1259
4071598 CIFC25 H21 F O SiP -18.545; 9.429; 13.712
97.067; 97.216; 115.932
965.9Dorsey, Christopher L.; Gabbaï, François P.
R3C−H→SiFR3Agostic Interaction
Organometallics, 2008, 27, 3065
4072414 CIFC10 H5 Br F3 N OP 1 21/n 14.4543; 11.6713; 18.635
90; 94.179; 90
966.21Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4071134 CIFC18 H26 P2 Pt SiP -19.183; 11.193; 11.32
102.781; 112.877; 104.322
970.8Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4070808 CIFC21 H30 N4P -18.817; 10.72; 10.796
90.095; 103.026; 99.885
978.5Otero, Antonio; Fernández-Baeza, Juan; Antiñolo, Antonio; Lara-Sánchez, Agustín; Martínez-Caballero, Emilia; Tejeda, Juan; Sánchez-Barba, Luis F.; Alonso-Moreno, Carlos; López-Solera, Isabel
Scandium and Yttrium Complexes Supported by NNCp Heteroscorpionate Ligands: Synthesis, Structure, and Polymerization of ϵ-Caprolactone
Organometallics, 2008, 27, 976
4070612 CIFC9 H12 B N2 Na OP 1 21/c 15.1979; 19.9137; 9.6023
90; 99.177; 90
981.21Wagler, Jörg; Hill, Anthony F.
7-Azaindol-7-ylborate: A Novel Bidentate N^BH3Chelating Ligand
Organometallics, 2008, 27, 2350
4071222 CIFC22 H56 I2 Si8P -18.7389; 9.4834; 13.512
97.87; 92.04; 117.03
982Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4072063 CIFC12 H33 In Si3P -110.353; 10.358; 10.386
74.22; 77.787; 67.66
984Peckermann, Ilja; Robert, Dominique; Englert, Ulli; Spaniol, Thomas P.; Okuda, Jun
Neutral and Cationic Trimethylsilylmethyl Complexes of Indium
Organometallics, 2008, 27, 4817
4070857 CIFC20 H18 F4 Ir N O3P -18.2139; 9.175; 14.0581
73.448; 84.546; 75.868
984.45Ke Chan, Pek; Kee Leong, Weng
Reaction of Cp*Ir(CO)2with Activated Perfluoroaromatic Compounds: Formation of Metallocarboxylic Acids via Aromatic Nucleophilic Substitution
Organometallics, 2008, 27, 1247
4072360 CIFC11 H11 N3 O2P 1 21/c 112.2364; 13.4662; 6.1023
90; 97.017; 90
997.99Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071657 CIFC17 H25 F6 O2 P RuP 1 21 19.0768; 8.3752; 13.2634
90; 95.86; 90
1003.01Gruber, Stefan; Zaitsev, Alexey B.; Wörle, Michael; Pregosin, Paul S.; Veiros, Luis F.
Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry
Organometallics, 2008, 27, 3796
4071871 CIFC24 H19 Br N2 Ni O2P 21 21 213.167; 5.8235; 13.0951
90; 90; 90
1004.11Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4072259 CIFC30 H36 F12 N14 Ni2 P2P -17.775; 11.533; 12.12
75.005; 73.448; 84.909
1006.1Zhou, Yongbo; Xi, Zhenxing; Chen, Wanzhi; Wang, Daqi
Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni2(μ-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides
Organometallics, 2008, 27, 5911
4071114 CIFC23 H19 Mn O5P -18.9297; 10.794; 11.1264
72.273; 80.503; 88.397
1007.24Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4071095 CIFC21 H21 Cl2 O2 P RuP 1 21 19.7487; 9.9464; 10.4269
90; 91.709; 90
1010.59Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4071448 CIFC19 H10 Cr2 O9 SP -18.3523; 10.7547; 13.0118
109.519; 108.371; 95.519
1018.6Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071734 CIFC9 H4 N O5 ReP 1 21/c 15.79; 10.7142; 16.4602
90; 93.551; 90
1019.15Mirebeau, Jean-Hugues; Le Bideau, Franck; Marrot, Jérôme; Jaouen, Gérard
Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands
Organometallics, 2008, 27, 2911
4071778 CIFC23 H25 N O3 SiP -19.553; 10.856; 11.584
88.33; 69.67; 66.19
1022Barluenga, José; Fañanás-Mastral, Martín; Andina, Facundo; Aznar, Fernando; Valdés, Carlos
Cascade Reactions of Dialkynyl Fischer Carbene Complexes Involving Intramolecular Alkyne Insertions Oriented to the Synthesis of Functionalized Polycycles
Organometallics, 2008, 27, 3593
4083511 CIFC19 H21 F3 N4 O3 Pt SP -16.8821; 10.9123; 14.1919
92.657; 91.962; 104.942
1027.48Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4071850 CIFC17 H33 N4 O2 SiP -19.683; 11.351; 11.49
115.096; 110.27; 95.533
1027.9Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071290 CIFC7 H19 Fe0.5 P2P 1 21/c 18.762; 12.581; 12.814
90; 132.979; 90
1033.4Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4083507 CIFC22 H19 Br2 N3 Ni OP -19.2389; 9.817; 11.656
91.31; 98.99; 95.83
1038Gao, Rong; Zhang, Min; Liang, Tongling; Wang, Fosong; Sun, Wen-Hua
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization
Organometallics, 2008, 27, 5641
4070720 CIFC15 H5 N O12 Ru3P -18.332; 11.889; 11.904
84.78; 73.1; 70.62
1064.3Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4071297 CIFC21 H26 Cl2 N O3 VP -17.4606; 11.4975; 13.9387
109.77; 90.049; 107.679
1064.85Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4072008 CIFC22 H27 Cl N4 O PdP -18.9322; 11.5556; 11.6712
109.128; 107.747; 93.895
1064.97Luzyanin, Konstantin V.; Pombeiro, Armando J. L.; Haukka, Matti; Kukushkin, Vadim Yu.
Coupling between 3-Iminoisoindolin-1-ones and Complexed Isonitriles as a Metal-Mediated Route to a Novel Type of Palladium and Platinum Iminocarbene Species
Organometallics, 2008, 27, 5379
4070864 CIFC21 H26 F6 N O2 P RuP -16.872; 10.792; 14.599
97.798; 95.328; 91.472
1067.2Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4071699 CIFC32 H56 Br4 N8 O4 Pt2P -18.669; 11.457; 12.083
110.14; 91.04; 105.57
1077.2Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4070939 CIFC24 H28 Cl P RuP -17.942; 11.1756; 13.0715
77.024; 73.311; 82.677
1080.47Vergnaud, Jérôme; Grellier, Mary; Bouhadir, Ghenwa; Vendier, Laure; Sabo-Etienne, Sylviane; Bourissou, Didier
Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]
Organometallics, 2008, 27, 1140
4072274 CIFC24 H31 N3P -18.42; 11.852; 12.291
109.84; 108.27; 90.96
1085.1Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070678 CIFC12 H14 Cl Co OP 1 21/c 17.1957; 10.2972; 14.7117
90; 92.524; 90
1089.01Mayer, Ulrich F. J.; Charmant, Jonathan P. H.; Rae, James; Manners, Ian
Synthesis and Structures of Strained, Neutral [d7] and Cationic [d6] Hydrocarbon-Bridged [n]Cobaltocenophanes (n= 2, 3)
Organometallics, 2008, 27, 1524
4071178 CIFC20 H22 P Pt SiP -18.837; 9.838; 13.333
80.115; 73.335; 82.17
1089.32Arii, Hidekazu; Takahashi, Makiko; Noda, Aki; Nanjo, Masato; Mochida, Kunio
Spectroscopic and Structural Studies of Thermally Unstable Intermediates Generated in the Reaction of [Pt(PPh3)2(η2-C2H4)] with Dihydrodisilanes
Organometallics, 2008, 27, 1929
4070629 CIFC38 F20 O18 Ru4P -19.6158; 10.5643; 11.7591
112.876; 95.196; 91.192
1094Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4072021 CIFC30 H24P -16.4454; 11.125; 15.38
92.479; 92.629; 95.834
1094.7Chen, Jingjin; Li, Yuxue; Gao, Hongjun; Liu, Yuanhong
Carbon−Carbon Bond Formation of α-Alkynylzirconacyclopentenes via Cyclization or a Cu/Pd-Mediated Cyclization/Cross-Coupling Sequence with Aryl Iodides
Organometallics, 2008, 27, 5619
4072434 CIFC21 H32 Cl2 N O P PdP 1 21 17.2466; 19.5763; 7.9997
90; 104.296; 90
1099.71Rubina, Marina; Sherrill, William M.; Rubin, Michael
Dramatic Stereo- and Enantiodivergency in the Intermolecular Asymmetric Heck Reaction Catalyzed by Palladium Complexes with Cyclopropane-Based PHOX Ligands
Organometallics, 2008, 27, 6393
4071386 CIFC10 H17 O3 PP 1 21/c 18.176; 8.0969; 16.669
90; 94.144; 90
1100.6Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071597 CIFC25 H20 B F5 O SiP -19.812; 10.112; 13.009
110.373; 105.23; 101.512
1105.4Dorsey, Christopher L.; Gabbaï, François P.
R3C−H→SiFR3Agostic Interaction
Organometallics, 2008, 27, 3065
4070748 CIFC24 H25 B Bi F O2P -110.399; 10.701; 11.484
94.046; 95.697; 118.484
1107.5Caires, Christopher C.; Guccione, Samira
Synthesis, Structure, and Reactivity of Borate Ester Coordinated Organobismuth Compounds
Organometallics, 2008, 27, 747
4070825 CIFC13 H13 GaP 1 21/c 18.731; 11.977; 10.739
90; 99.202; 90
1108.5Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4070532 CIFC24 H31 Au Br PP -19.7079; 10.1259; 12.1991
110.563; 96.051; 93.479
1110.36Partyka, David V.; Robilotto, Thomas J.; Zeller, Matthias; Hunter, Allen D.; Gray, Thomas G.
Dialkylbiarylphosphine Complexes of Gold(I) Halides. Gold−Aryl π-Interactions in the Solid State
Organometallics, 2008, 27, 28
4070642 CIFC48 H52 N4 Ni2 O4P -17.651; 11.783; 13.848
114.862; 99.241; 90.263
1114.4Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4071419 CIFC48 H48 B2 Cl6 Fe2 N4P -19.9484; 10.4634; 11.6449
70.117; 78.568; 84.032
1116.41Pakkirisamy, Thilagar; Venkatasubbaiah, Krishnan; Kassel, W. Scott; Rheingold, Arnold L.; Jäkle, Frieder
Examination of the Pyridine Binding to the Bifunctional Lewis Acid B,B′-Diphenyldiboradiferrocene
Organometallics, 2008, 27, 3056
4070643 CIFC48 H52 Cu2 N4 O4P -17.688; 11.813; 13.804
114.828; 99.704; 90.174
1117.7Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4071149 CIFC22 H21 O6 P WP -19.488; 10.33; 13.083
101.576; 109.73; 103.089
1120.65Bode, Maren; Schnakenburg, Gregor; Jones, Peter G.; Streubel, Rainer
Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5Complex
Organometallics, 2008, 27, 2664
4072275 CIFC25 H33 N3P -18.459; 11.49; 12.48
100.34; 107.97; 95.02
1121.8Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071724 CIFC14 H16 FeP 1 21/n 19.8523; 7.6564; 15.4974
90; 106.337; 90
1121.82Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki
Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†
Organometallics, 2008, 27, 5279
4071383 CIFC24 H30 Br O3 PP -110.108; 10.339; 11.856
71.83; 88.97; 73.25
1123.8Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4070795 CIFC23 H25 N3 O6 SiP 1 n 19.341; 10.443; 11.71
90; 99.72; 90
1125.9Spiniello, Marisa; White, Jonathan M.
Structural Investigations into the β-Effect of Pentavalent Silicon
Organometallics, 2008, 27, 994
4070839 CIFC25 H30 N NbP 3 1 c11.2683; 11.2683; 10.2514
90; 90; 120
1127.3Arteaga-Müller, Rocío; Sánchez-Nieves, Javier; Ramos, Javier; Royo, Pascual; Mosquera, Marta E. G.
Isolobal Zwitterionic Niobium and Tantalum Imido and Zirconium Monocyclopentadienyl Complexes: Theoretical and Methyl Methacrylate Polymerization Studies
Organometallics, 2008, 27, 1417
4071061 CIFC24 H28 O4 SiP -18.016; 8.044; 17.791
87.401; 83.35; 81.92
1127.7Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
Organometallics, 2008, 27, 4318
4070904 CIFC22 H28 N4 Si ZnP -18.0286; 11.2735; 12.947
79.004; 80.062; 83.476
1129.1Chai, Zuo-Yun; Zhang, Cheng; Wang, Zhong-Xia
Synthesis, Characterization, and Catalysis in ϵ-Caprolactone Polymerization of Aluminum and Zinc Complexes Supported byN,N,N-Chelate Ligands
Organometallics, 2008, 27, 1626
4072186 CIFC19 H23 Al F12 N2 O2P -18.0836; 10.2938; 15.0534
102.211; 105.267; 100.619
1142.17Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4071528 CIFC40 H52 Cl8 N2 O4 Ru2P -19.7494; 10.9847; 11.4996
69.527; 83.3; 88.409
1145.8Mendoza-Ferri, Maria-Grazia; Hartinger, Christian G.; Eichinger, Rene E.; Stolyarova, Natalya; Severin, Kay; Jakupec, Michael A.; Nazarov, Alexey A.; Keppler, Bernhard K.
Influence of the Spacer Length on thein VitroAnticancer Activity of Dinuclear Ruthenium−Arene Compounds
Organometallics, 2008, 27, 2405
4071787 CIFC20 H10 O8 Ru2 SnP -18.2765; 9.317; 16.1426
87.377; 75.261; 72.544
1147.76Adams, Richard D.; Trufan, Eszter
Diruthenium−Tin Complexes from the Reaction of Ph2SnH2with Ru(CO)5and Their Reactions with Bis(tri-tert-butylphosphine)platinum
Organometallics, 2008, 27, 4108
4071782 CIFC26 H41 N O WP -19.7773; 11.3376; 11.7186
77.63; 65.729; 88.019
1154.6Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4071765 CIFC21 H25 Mo2 N S4P 1 21 19.8972; 12.5566; 9.3093
90; 90.261; 90
1156.9Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4072321 CIFC48 H72 Fe2 Li4 O7P -19.8205; 10.6036; 11.7149
74.735; 80.07; 84.505
1157.6Perucha, Alejandro Sánchez; Heilmann-Brohl, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Comparison of Doubly Lithiated, Magnesiated, and Zincated Ferrocenes: [Fe(η5-C5H4)2]2Zn2(tmeda)2, the First Example of a [1.1]Ferrocenophane with Bridging First-Row Transition Metal Atoms
Organometallics, 2008, 27, 6170
4071298 CIFC22 H25 Cl2 F3 N O3 VP -17.6147; 12.0671; 13.7396
67.631; 85.279; 86.104
1162.6Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4070755 CIFC15 H23 B10 Co O4 Se2P -19.5889; 9.6525; 13.9915
72.157; 75.856; 73.25
1163Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4071991 CIFC18 H39 B3 N6P -18.507; 10.052; 15.1233
85.667; 78.556; 66.589
1163.2Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4072174 CIFC4 H15 B10 N OP 21 21 218.8115; 10.4327; 12.6598
90; 90; 90
1163.8Mukhin, Sergey N.; Kabytaev, Kuanysh Z.; Zhigareva, Galina G.; Glukhov, Ivan V.; Starikova, Zoya A.; Bregadze, Vladimir I.; Beletskaya, Irina P.
Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom
Organometallics, 2008, 27, 5937
4070826 CIFC28 H27 N3 OP 1 21 18.8927; 14.556; 9.4158
90; 107.08; 90
1165Zi, Guofu; Xiang, Li; Song, Haibin
Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2′-(dimethylamino)-1,1′-binaphthyl
Organometallics, 2008, 27, 1242
4071130 CIFC22 H44 P Pt SiP -19.695; 9.826; 14.461
75.281; 82.659; 61.139
1166.9Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4071358 CIFC29 H30 Ir NP -17.87; 10.155; 15.749
73.934; 84.275; 74.846
1166.9Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071901 CIFC22 H34 Cl2 O2 Os2P 1 21/c 19.072; 16.049; 8.2477
90; 102.549; 90
1172.1Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4072067 CIFC22 H28 Cr O6P -19.3239; 10.351; 12.241
93.71; 94.57; 90.07
1175.2Wang, Qifeng; Zhang, Wen-Xiong; Xi, Zhenfeng
Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6(M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction
Organometallics, 2008, 27, 3627
4070909 CIFC23 H32 Cr O4 SiP 1 21 17.7412; 10.9198; 14.3413
90; 103.896; 90
1176.82Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A.
Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality
Organometallics, 2008, 27, 900
4070926 CIFC26 H10 F10 N2 ZnP -17.1098; 12.5886; 14.7792
68.372; 77.1; 76.065
1180.1Martin, Eddy; Spendley, Claire; Mountford, Andrew J.; Coles, Simon J.; Horton, Peter N.; Hughes, David L.; Hursthouse, Michael B.; Lancaster, Simon J.
Synthesis, Structure, and Supramolecular Architecture of Benzonitrile and Pyridine Adducts of Bis(pentafluorophenyl)zinc: Pentafluorophenyl‒Aryl Interactions versus Homoaromatic Pairing
Organometallics, 2008, 27, 1436
4072074 CIFC12 H17 P SiP 1 21/n 16.3438; 18.0866; 10.472
90; 100.732; 90
1180.52Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4071700 CIFC15 H25 Br2 Cl3 N4 O2 PtP -110.438; 10.449; 11.27
103.18; 93.43; 94.59
1189.1Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4070876 CIFC14 H10 Mn N O3P 1 21/c 114.5944; 5.7378; 15.4263
90; 112.656; 90
1192.11To, Tung T.; Duke III, Charles B.; Junker, Christopher S.; O’brien, Casey M.; Ross Ii, Charles R.; Barnes, Craig E.; Webster, Charles Edwin; Burkey, Theodore J.
Linkage Isomerization as a Mechanism for Photochromic Materials: Cyclopentadienylmanganese Tricarbonyl Derivatives with Chelatable Functional Groups
Organometallics, 2008, 27, 289
4071387 CIFC10 H16 Cl O3 PP 1 21/c 19.656; 8.3144; 15.116
90; 100.463; 90
1193.4Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4070923 CIFC17 H28 B10 Co N S3P -18.266; 10.433; 14.475
99.515; 96.993; 100.783
1194.3Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4071079 CIFC28 H29 Fe2 O3 PP -18.7611; 12.321; 12.427
105.131; 100.907; 106.022
1194.3Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Nucleophilic and Electrophilic Behavior of the Phosphinidene-Bridged Complex [Fe2(η5-C5H5)2(μ-PCy)(μ-CO)(CO)2]
Organometallics, 2008, 27, 1037
4071009 CIFC10 H4 Ag7 N5 O18P -17.236; 10.6353; 15.5849
87.661; 89.882; 86.547
1196.2Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4072073 CIFC22 H42 Cl O2 P PdP -18.592; 10.019; 15.068
100.372; 100.796; 104.467
1198.1Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072140 CIFC23 H27 N P2 Pt S2P -19.6108; 10.0711; 12.944
94.732; 105.693; 92.37
1199.4Lee, Kyung-Eun; Chang, Xiaohong; Kim, Yong-Joo; Huh, Hyun Sue; Lee, Soon W.
Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes,cis-[Pt(S2CNPh)L2] andcis-[Pt(S2SiPh2)L2] (L = PMe2Ph, PEt3; L-L = dppp)
Organometallics, 2008, 27, 5566
4071301 CIFC21 H24 Br2 Cl2 N O3 VP -17.7892; 11.996; 13.9022
106.917; 92.699; 103.18
1201.06Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071505 CIFC18 H20 F6 O9 S2 SnP -110.0999; 10.4971; 11.9202
73.1794; 86.1036; 85.105
1204.05Kašná, Blanka; Dostál, Libor; Jirásko, Robert; Císařová, Ivana; Jambor, Roman
Role of Y,C,Y-Chelating Ligands in Control Hydrolysis of Diorganotin Compounds†
Organometallics, 2008, 27, 3743
4071577 CIFC26 H25 I N P PtP 1 21 19.975; 8.3934; 14.854
90; 104.246; 90
1205.4Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071002 CIFC21 H31 F6 Ir N3 O2 PP 21 21 215.3775; 8.4994; 9.2423
90; 90; 90
1207.96Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4071228 CIFC17 H43 Cl Ir P3 SiP 1 21 19.3062; 10.7212; 12.1508
90; 94.122; 90
1209.19Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4071659 CIFC8 H12 O2P -110.5911; 11.79; 12.2848
66.034; 62.98; 67.991
1214.2Yada, Yukito; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Ruthenium-Catalyzed Intramolecular Cyclization of 3-Butyne-1,2-diols into Furans
Organometallics, 2008, 27, 3614
4070648 CIFC30 H22 Au N2 PP -110.0469; 10.6781; 13.1309
76.667; 68.524; 68.91
1215.14Vicente, José; Gil-Rubio, Juan; Barquero, Natalia; Jones, Peter G.; Bautista, Delia
Synthesis of Luminescent Alkynyl Gold Metalaligands Containing 2,2′-Bipyridine-5-yl and 2,2′:6′,2′′-Terpyridine-4-yl Donor Groups
Organometallics, 2008, 27, 646
4070716 CIFC24 H48 Cl8 O12 Si8P -110.02; 10.133; 12.855
79.93; 73.96; 78.09
1217.7Marciniec, Bogdan; Dutkiewicz, Michal; Maciejewski, Hieronim; Kubicki, Maciej
New, Effective Method of Synthesis and Structural Characterization of Octakis(3-chloropropyl)octasilsesquioxane
Organometallics, 2008, 27, 793
4072413 CIFC13 H14 Br NP 1 21/c 110.7872; 9.4647; 12.7521
90; 110.547; 90
1219.13Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4071436 CIFC40 H82 O2 Si4 Y2P -19.888; 11.153; 12.721
73.878; 85.735; 64.925
1219.2Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071068 CIFC35 H80 Cd5 N6 O6P -110.401; 11.508; 12.431
68.66; 66.65; 68.36
1227.8Jana, Surajit; Fröhlich, Roland; Hepp, Alexander; Mitzel, Norbert W.
An Organocadmium Hydroxylamide
Organometallics, 2008, 27, 1348
4083512 CIFC22 H29 F6 N4 O P PtP -19.2523; 11.2105; 13.4198
66.814; 73.859; 83.802
1229.1Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4072033 CIFC27 H32 Cl N4 RhP 1 21 18.6322; 16.3296; 9.2517
90; 109.21; 90
1231.51Ros, Abel; Alcarazo, Manuel; Iglesias-Sigüenza, Javier; Díez, Elena; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Stereoselective Synthesis of Rhodium(I) 4-(Dialkylamino)triazol-5-ylidene Complexes
Organometallics, 2008, 27, 4555
4072009 CIFC26 H21 Cl3 N4 O PtP -18.3009; 12.4324; 12.7236
74.722; 77.042; 85.816
1234.28Luzyanin, Konstantin V.; Pombeiro, Armando J. L.; Haukka, Matti; Kukushkin, Vadim Yu.
Coupling between 3-Iminoisoindolin-1-ones and Complexed Isonitriles as a Metal-Mediated Route to a Novel Type of Palladium and Platinum Iminocarbene Species
Organometallics, 2008, 27, 5379
4070570 CIFC19 H30 Cl4 N2 P2 PdP 1 21 17.9252; 15.1396; 10.4448
90; 99.015; 90
1237.73Das, Atanu Kumar; Bulak, Ece; Sarkar, Biprajit; Lissner, Falk; Schleid, Thomas; Niemeyer, Mark; Fiedler, Jan; Kaim, Wolfgang
Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate LigandR,R-QuinoxP
Organometallics, 2008, 27, 218
4071437 CIFC40 H82 Dy2 O2 Si4P -19.9249; 11.2281; 12.7924
73.973; 85.791; 64.861
1238.79Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071722 CIFC30 H35 Fe PP -17.4493; 12.5125; 14.4119
71.541; 85.738; 77.417
1243.59Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki
Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†
Organometallics, 2008, 27, 5279
4072408 CIFC34 H31 BP -18.567; 11.2119; 13.7498
98.642; 103.914; 98.317
1244.7Zhao, Shu-Bin; Wucher, Philipp; Hudson, Zachary M.; McCormick, Theresa M.; Liu, Xiang-Yang; Wang, Suning; Feng, Xiao-Dong; Lu, Zheng-Hong
Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes2Groups and the Peculiar Behavior of 1,6-(BMes2)2pyrene
Organometallics, 2008, 27, 6446
4072020 CIFC32 H30 N2P -17.961; 11.374; 14.41
80.274; 80.161; 78.185
1246.2Chen, Jingjin; Li, Yuxue; Gao, Hongjun; Liu, Yuanhong
Carbon−Carbon Bond Formation of α-Alkynylzirconacyclopentenes via Cyclization or a Cu/Pd-Mediated Cyclization/Cross-Coupling Sequence with Aryl Iodides
Organometallics, 2008, 27, 5619
4071004 CIFC20 H28 Cl F6 Ir N3 O2 PP 1 21 18.2524; 16.0006; 9.4409
90; 91.441; 90
1246.21Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4070569 CIFC19 H30 Cl4 N2 P2 PtP 1 21 17.9288; 15.1703; 10.52
90; 99.605; 90
1247.63Das, Atanu Kumar; Bulak, Ece; Sarkar, Biprajit; Lissner, Falk; Schleid, Thomas; Niemeyer, Mark; Fiedler, Jan; Kaim, Wolfgang
Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate LigandR,R-QuinoxP
Organometallics, 2008, 27, 218
4070922 CIFC17 H30 B10 N Rh S2P -110.429; 11.533; 11.584
81.027; 67.195; 77.123
1248.3Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4072305 CIFC28 H27 Ni O5 P SP -19.566; 9.877; 15.129
104.407; 95.245; 112.58
1250.1Zhou, Xiaoyuan; Bontemps, Sébastien; Jordan, Richard F.
Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes
Organometallics, 2008, 27, 4821
4071202 CIFC22 H40 Cl O2 P2 RhP -18.176; 12.184; 13.351
100.49; 95.71; 103.91
1255Salem, Hiyam; Shimon, Linda J. W.; Leitus, Gregory; Weiner, Lev; Milstein, David
B−C Bond Cleavage of BArFAnion Upon Oxidation of Rhodium(I) with AgBArF. Phosphinite Rhodium(I), Rhodium(II), and Rhodium(III) Pincer Complexes
Organometallics, 2008, 27, 2293
4072069 CIFC22 H28 O6 S WP -110.667; 11.59; 11.644
83.7; 66.19; 72.92
1258.9Wang, Qifeng; Zhang, Wen-Xiong; Xi, Zhenfeng
Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6(M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction
Organometallics, 2008, 27, 3627
4070607 CIFC18 H41 B7 Fe O2 P2P -18.7786; 9.8596; 15.0003
85.101; 79.204; 82.038
1260.69Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4071472 CIFC21 H41 Cl3 Ir N3P -19.465; 10.886; 14.286
70.589; 81.301; 65.269
1260.84Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4072183 CIFC22 H32 F12 N2 O2P 1 21/n 17.3782; 22.163; 7.7542
90; 91.228; 90
1267.7Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4071003 CIFC19 H27 F6 I2 Ir N3 O2 PP 1 21 17.7764; 17.402; 9.3814
90; 91.409; 90
1269.15Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4072376 CIFC27 H42 Cl P PdP -18.186; 10.01; 17.12
79.21; 86.43; 67.5
1273.1Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4071515 CIFC21 H31 I2 N3 O PdP -110.0442; 10.8695; 13.2366
111.027; 92.493; 106.846
1273.29Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4072123 CIFC5 H20 B9 N SP c a 2118.4915; 6.7105; 10.2849
90; 90; 90
1276.22Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4070793 CIFC25 H23 B N2 O3 P Re SP -18.486; 10.7559; 15.5117
94.743; 103.313; 109.504
1278.9Videira, Margarida; Maria, Leonor; Paulo, António; Santos, Isabel C.; Santos, Isabel; Vaz, Pedro D.; Calhorda, Maria José
Mixed-Ligand Rhenium Tricarbonyl Complexes Anchored on a (κ2-H,S) Trihydro(mercaptoimidazolyl)borate: A Missing Binding Motif for Soft Scorpionates
Organometallics, 2008, 27, 1334
4070903 CIFC18 H14 FeC m c 2115.06; 9.6563; 8.8505
90; 90; 90
1287.1Kirillov, Evgueni; Kahlal, Samia; Roisnel, Thierry; Georgelin, Thomas; Saillard, Jean-Yves; Carpentier, Jean-François
Haptotropic Rearrangements in Sandwich (Fluorenyl)(Cyclopentadienyl) Iron and Ruthenium Complexes
Organometallics, 2008, 27, 387
4071746 CIFC27 H37 Ir O P2P 1 21 18.2807; 14.1531; 11.5174
90; 106.646; 90
1293.24Romero, Patricio E.; Whited, Matthew T.; Grubbs, Robert H.
Multiple C−H Activations of Methyltert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1
Organometallics, 2008, 27, 3422
4072324 CIFC17 H18 FeP 1 21/n 15.8485; 17.0481; 12.987
90; 92.072; 90
1294.03Ogasawara, Masamichi; Watanabe, Susumu; Nakajima, Kiyohiko; Takahashi, Tamotsu
Preparation of [4]- and [5]Ferrocenophanes by Ruthenium-Catalyzed Ring-Closing Ene−Yne Metathesis
Organometallics, 2008, 27, 6565
4071247 CIFC11 H12 Ge O3 WP -16.822; 13.361; 14.685
82.509; 79.76; 81.872
1296.3Apodaca, Paula; Kumar, Mukesh; Cervantes-Lee, Francisco; Sharma, Hemant K.; Pannell, Keith H.
The Chloromethylgermyl Complexes (η5-C5H5)M(CO)nGeR2CH2Cl [M = Fe (n= 2), Mo, W (n= 3)]: Rearrangements, Transformations to 1-Germa-3-metallacyclobutanes (η5-C5H4)M(CO)nCH2GeR2, and their Ring-Opening Polymerizations
Organometallics, 2008, 27, 3136
4071141 CIFC30 H33 N P2P -18.4309; 12.8265; 13.2757
71; 74.009; 89.143
1300.46Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071246 CIFC11 H12 Ge Mo O3P -16.8366; 13.386; 14.6784
82.528; 79.887; 81.766
1301.2Apodaca, Paula; Kumar, Mukesh; Cervantes-Lee, Francisco; Sharma, Hemant K.; Pannell, Keith H.
The Chloromethylgermyl Complexes (η5-C5H5)M(CO)nGeR2CH2Cl [M = Fe (n= 2), Mo, W (n= 3)]: Rearrangements, Transformations to 1-Germa-3-metallacyclobutanes (η5-C5H4)M(CO)nCH2GeR2, and their Ring-Opening Polymerizations
Organometallics, 2008, 27, 3136
4071636 CIFC36 H30 Co Ni2P -19.256; 9.305; 17.278
96.93; 98.93; 114.74
1306.3Buchalski, Piotr; Grabowska, Ilona; Karaskiewicz, Anna; Suwińska, Kinga; Jerzykiewicz, Lucjan
Novel 9-Nickelafluorenyl Sandwich Complexes of Nickel(II) and Cobalt(II)
Organometallics, 2008, 27, 3316
4072076 CIFC25 H34 Cl O P2 Rh Si2P 1 21/c 16.914; 6.698; 28.42
90; 95.71; 90
1309.6Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4071094 CIFC26 H32 B F3 N2 O3 SP -18.2944; 10.4347; 16.1597
104.688; 96.856; 100.432
1310.3Chiu, Ching-Wen; Gabbaï, François P.
Diarylborenium Cations: Synthesis, Structure, and Electrochemistry
Organometallics, 2008, 27, 1657
4072357 CIFC13 H15 N3 O2 SiP 1 21/c 17.2892; 9.8847; 18.3983
90; 98.578; 90
1310.8Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071704 CIFC23 H30 Br2 Cl2 N4 O2 PtP -19.999; 10.9524; 13.0425
86.17; 67.837; 84.563
1316.09Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4070811 CIFC27 H35 Mo2 O4 PP -19.819; 11.145; 12.932
73.307; 76.161; 86.211
1316.2García, M. Esther; García-Vivó, Daniel; Ruiz, Miguel A.
Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 3. Formation and Cleavage of C−C and C−O Bonds in the Reactions of the Complexes [Mo2Cp2(µ-COMe)(µ-COR)(µ-PCy2)]BF4(R = Me, Et)
Organometallics, 2008, 27, 543
4071595 CIFC27 H28 Cl4 Ir PP 1 21/m 19.7472; 12.0024; 11.4226
90; 99.241; 90
1318.98Lebel, Hélène; Ladjel, Chehla
Iridium Complexes in Olefination Reactions
Organometallics, 2008, 27, 2676
4072330 CIFC40 H92 Al2 Cr2 N4 P2P -19.702; 10.454; 14.135
107.554; 95.139; 101.52
1322Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Koç, Ece; Duchateau, Robbert
Isolation of a Chromium Hydride Single-Component Ethylene Polymerization Catalyst
Organometallics, 2008, 27, 5943
4072280 CIFC26 H35 Cl2 Co N3P 1 21 19.451; 13.486; 10.434
90; 95.63; 90
1323.5Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070630 CIFC22 H6 F12 O8 Ru2P -19.6393; 11.3055; 14.1228
72.102; 73.861; 67.004
1326.11Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4071618 CIFC30 H48 P2P 1 21/c 19.4004; 13.1537; 10.8292
90; 97.526; 90
1327.5Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4071039 CIFC13 H18 B N SiP 1 21/c 110.0235; 15.6305; 8.5246
90; 96.184; 90
1327.8Pan, Jun; Kampf, Jeff W.; Ashe III, Arthur J.
The Preparation and Crystal Structures of η1-Derivatives of 2-Phenyl-1,2-azaboratabenzene
Organometallics, 2008, 27, 1345
4072283 CIFC26 H35 Cl2 Fe N3P 1 21 19.4994; 13.5202; 10.409
90; 95.779; 90
1330.07Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070937 CIFC36 H90 Br2 Si10P -110.6236; 12.1382; 12.6622
66.232; 85.365; 64.031
1334.33Ueba-Ohshima, Kiyomi; Iwamoto, Takeaki; Kira, Mitsuo
Synthesis, Structure, and Facile Ring Flipping of a Bicyclo[1.1.0]tetrasilane
Organometallics, 2008, 27, 320
4071447 CIFC25 H17 Cl3 Cr O6 S TiP -111.3041; 11.5751; 12.2429
66.52; 88.797; 67.038
1335.6Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071555 CIFC24 H30 Cl2 N6 O2 PdP 1 21/c 110.646; 9.0631; 14.374
90; 105.509; 90
1336.4Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071287 CIFC20 H18 Al2 F12 O2P 1 21/n 19.972; 7.6787; 17.488
90; 92.638; 90
1337.7Martínez, Gema; Pedrosa, Sergio; Tabernero, Vanessa; Mosquera, Marta E. G.; Cuenca, Tomás
Controlled Synthesis of Novel Aryloxide Polynuclear Aluminum Species. Study of Their Catalytic Properties in Polymerization Processes†
Organometallics, 2008, 27, 2300
4071179 CIFC22 H32 I2 N6 Rh2P -18.7286; 12.243; 13.855
103.63; 100.11; 105.71
1339.1Poyatos, Macarena; McNamara, William; Incarvito, Chris; Clot, Eric; Peris, Eduardo; Crabtree, Robert H.
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
Organometallics, 2008, 27, 2128
4071896 CIFC13 H23 Cl PdP 1 21/n 16.4359; 12.0616; 17.4155
90; 96.456; 90
1343.34Esposito, Oriana; Gois, Pedro M. P.; de K. Lewis, Alexandra K.; Caddick, Stephen; Cloke, F. Geoffrey N.; Hitchcock, Peter B.
Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties
Organometallics, 2008, 27, 6411
4072155 CIFC32 H44 N UP -19.2465; 10.885; 13.7791
86.5926; 80.0815; 80.0828
1345.1Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4072166 CIFC28 H34 N4 O4 Rh2P -18.2971; 11.5643; 14.67
78.139; 81.744; 79.456
1346Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072281 CIFC27 H37 Cl2 Co N3P 1 21 19.5883; 12.9838; 10.8393
90; 92.006; 90
1348.59Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071453 CIFC24 H10 Bi F12 O8 RhP -18.5229; 12.8739; 13.1035
81.988; 85.192; 71.631
1349.96Dikarev, Evgeny V.; Li, Bo; Rogachev, Andrey Yu.; Zhang, Haitao; Petrukhina, Marina A.
Metal-Site-Controlled Arene Coordination in a Heterobimetallic Bi−Rh Complex with Pyrene
Organometallics, 2008, 27, 3728
4070736 CIFC23 H46 Al N O Si2P 1 21 19.447; 12.565; 11.38
90; 91.994; 90
1350Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming
Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^
Organometallics, 2008, 27, 678-682
4071566 CIFC48 H54 B2 F20 O8 Zr2P -110.872; 11.866; 12.017
110.37; 105.386; 98.153
1353.4Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4070662 CIFC25 H40 N4 O3 RuP 1 21 110.634; 12.053; 11.28
90; 110.466; 90
1354.52Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4072421 CIFC56 H56 Cl8 N4 Pt2P -19.3132; 11.8742; 13.3219
67.5142; 85.269; 85.9551
1355.37Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4070762 CIFC24 H34 B F4 Ir N2 O3 SP 19.7323; 10.0866; 14.1647
91.517; 99.724; 97.879
1355.82Heiden, Zachariah M.; Gorecki, Bradford J.; Rauchfuss, Thomas B.
Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity
Organometallics, 2008, 27, 1542
4072126 CIFC6 H15 B9 Fe O2 SP 1 21/n 16.7953; 13.234; 15.1439
90; 94.436; 90
1357.8Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4072227 CIFC31 H43 Si TiP -18.6571; 11.5401; 14.2383
99.8037; 90.9041; 103.774
1359.02Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4070905 CIFC31 H31 N4 P ZnP -19.056; 11.133; 14.071
78.193; 82.371; 81.054
1364.2Chai, Zuo-Yun; Zhang, Cheng; Wang, Zhong-Xia
Synthesis, Characterization, and Catalysis in ϵ-Caprolactone Polymerization of Aluminum and Zinc Complexes Supported byN,N,N-Chelate Ligands
Organometallics, 2008, 27, 1626
4070875 CIFC15 H10 Mn N O4P 1 21/c 117.932; 10.443; 7.3797
90; 98.943; 90
1365.2To, Tung T.; Duke, III, Charles B.; Junker, Christopher S.; O'Brien, Casey M.; Ross, II, Charles R.; Barnes, Craig E.; Webster, Charles Edwin; Burkey, Theodore J.
Linkage Isomerization as a Mechanism for Photochromic Materials: Cyclopentadienylmanganese Tricarbonyl Derivatives with Chelatable Functional Groups
Organometallics, 2008, 27, 289
4070726 CIFC32 H38 Al N2 OP -111.4187; 11.5317; 12.1602
93.651; 106.249; 114.684
1366.6Yang, Ying; Schulz, Thomas; John, Michael; Yang, Zhi; Jiménez-Pérez, Victor Manuel; Roesky, Herbert W.; Gurubasavaraj, Prabhuodeyara M.; Stalke, Dietmar; Ye, Hongqi
Organoaluminum Hydroxides Supported by β-Diketiminato Ligands: Synthesis, Structural Characterization, and Reactions
Organometallics, 2008, 27, 769
4072136 CIFC30 H46 F2 TiP 4215.3556; 15.3556; 5.7986
90; 90; 90
1367.3Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070845 CIFC28 H38 Cl3 O3 RhP -19.6097; 11.3454; 14.8142
104.724; 96.667; 115.065
1368.05Bordoni, Silvia; Natanti, Paolo; Cerini, Stefano; Tarroni, Riccardo; Monari, Magda; Piccinelli, Fabio; Busetto, Luigi
Diastereoselective Synthesis of New Rhodium-Based Amphiphilic Polyol-Cp Systems
Organometallics, 2008, 27, 945
4070664 CIFC25 H40 N4 O5 RuP 1 21 110.602; 12.062; 11.393
90; 110.069; 90
1368.49Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4072404 CIFC25 H40 B Ir N6 O2P -18.0223; 13.1372; 13.2581
97.23; 94.549; 96.359
1371.46Paneque, Margarita; Poveda, Manuel L.; Santos, Laura L.; Carmona, Ernesto; Mereiter, Kurt
Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound
Organometallics, 2008, 27, 6353
4071151 CIFC29 H27 O7 P WP -18.8233; 10.726; 15.0798
92.218; 105.029; 93.583
1373.4Bode, Maren; Schnakenburg, Gregor; Jones, Peter G.; Streubel, Rainer
Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5Complex
Organometallics, 2008, 27, 2664
4070611 CIFC28 H20 Cl2 F6 N4 PdP -19.0014; 11.4002; 14.646
110.666; 93.013; 100.034
1374.07Wanniarachchi, Yoshitha A.; Slaughter, LeGrande M.
Reversible Chelate Ring Opening of a Sterically Crowded Palladium Bis(acyclic diaminocarbene) Complex
Organometallics, 2008, 27, 1055
4071096 CIFC27 H28 Cl F6 N O2 P2 RuP 1 21 19.364; 15.414; 9.544
90; 93.54; 90
1374.9Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4072119 CIFC30 H16 Au2 F6 Fe N2P 1 21/m 111.4667; 8.5646; 14.1478
90; 98.271; 90
1375Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4071293 CIFC22 H54 Fe P4P -17.593; 10.2012; 19.5659
77.903; 89.807; 68.634
1375.59Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4072291 CIFC15 H13 N2 P SP 1 21/n 16.0288; 18.5959; 12.3146
90; 93.68; 90
1377.75Oshovsky, Gennady V.; Ouali, Armelle; Xia, Ning; Zablocka, Maria; Boeré, René T.; Duhayon, Carine; Taillefer, Marc; Majoral, Jean Pierre
Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media
Organometallics, 2008, 27, 5733
4071682 CIFC60 H48 Cl6 N4 P2 Pd2P -19.9317; 11.7023; 13.2396
79.655; 87.484; 65.604
1377.8Jiang, Huiling; Song, Datong
Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
Organometallics, 2008, 27, 3587
4071267 CIFC20 H40 Br2 N2 O4 Zn2P 1 21/n 110.687; 8.8254; 14.8247
90; 99.537; 90
1378.9Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071029 CIFC21 H43 Li N4 Si2P -110.18; 10.636; 13.365
89.23; 72.67; 88.85
1381.1Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071011 CIFC7 H4 Ag4 N4 O9P 1 21/n 17.2997; 16.0767; 11.7819
90; 92.056; 90
1381.8Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4072332 CIFC29 H37 N3 O4 OsP -110.441; 11.3821; 13.4172
90.499; 108.143; 112.641
1383.35Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4072196 CIFC28 H42 N2 O2 ZnP 1 21 19.4749; 12.6708; 11.6753
90; 98.468; 90
1386.39Armstrong, David R.; Drummond, Allison M.; Balloch, Liam; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Metalation of 2,4,6-Trimethylacetophenone Using Organozinc Reagents: The Role of the Base in Determining Composition and Structure of the Developing Enolate
Organometallics, 2008, 27, 5860
4070865 CIFC22 H33 F12 N O P2 RuP 1 21 17.134; 12.2235; 15.9461
90; 94.372; 90
1386.49Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4071845 CIFC36 H34 N2 Ru2P 1 21 17.722; 13.556; 13.251
90; 91.012; 90
1386.89Pannetier, Nicolas; Sortais, Jean-Baptiste; Dieng, Pape Sylla; Barloy, Laurent; Sirlin, Claude; Pfeffer, Michel
Kinetics and Mechanism of Ruthenacycle-Catalyzed Asymmetric Hydrogen Transfer
Organometallics, 2008, 27, 5852
4070596 CIFC22 H35 B Cl2 N4 O S2 TaP 1 21/m 18.596; 14.522; 11.155
90; 94.99; 90
1387.2Hill, Anthony F.; Smith, Matthew K.; Wagler, Jörg
Near Linear Ta−H−B Geometry: [TaCl2(η-C5Me5){κ3-H,S,S′-H2B(methimazolyl)2}]
Organometallics, 2008, 27, 2137
4070849 CIFC25 H30 N3 O9.5 PdP -110.0026; 10.5211; 14.3597
107.407; 103.434; 91.7
1394.5Vicente, José; Arcas, Aurelia; Gálvez-López, María-Dolores; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Synthesis of Bis(2,6-dinitroaryl)palladium(II) and Mono(2,6-dinitroaryl)platinum(II) Complexes. A New Example of the Transphobia Effect and of Transmetalation from Pt to Hg
Organometallics, 2008, 27, 1582
4072121 CIFC61 H46 Au4 Cl2 Fe2 N4 O4P -18.4412; 11.8387; 14.197
87.29; 81.08; 84.569
1394.5Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4070707 CIFC27 H24 Fe2 N O5 P S2P -18.884; 10.484; 15.902
93.118; 98.856; 106.601
1394.9Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4071398 CIFC32 H31 Br P2 RuP 1 21 19.65602; 14.95694; 10.48788
90; 112.479; 90
1399.62Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071766 CIFC32 H34 Mo2 N2 S2P -18.4425; 11.7806; 14.4002
100.234; 95.882; 90.15
1401.7Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071136 CIFC14 H20 Mo S2P b c n13.271; 6.9263; 15.256
90; 90; 90
1402.3Kuo, Louis Y.; Adint, Tyler T.; Akagi, Allison E.; Zakharov, Lev
Degradation of a VX Analogue: First Organometallic Reagent To Promote Phosphonothioate Hydrolysis Through Selective P−S Bond Scission
Organometallics, 2008, 27, 2560
4072154 CIFC26 H48 N Si2 UP 1 21/m 18.753; 15.573; 11.017
90; 110.86; 90
1403.3Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4070702 CIFC27 H22 Fe2 N O7 P S2P -19.679; 12.785; 12.908
71.734; 68.835; 77.581
1405.1Song, Li-Cheng; Wang, Hu-Ting; Ge, Jian-Hua; Mei, Shu-Zhen; Gao, Jie; Wang, Liang-Xing; Gai, Bin; Zhao, Li-Qun; Yan, Jing; Wang, Yong-Zhen
Investigations on the Active Site Models of [FeFe]-Hydrogenases: Synthesis, Structure, and Properties of N-Functionalized Azadithiolatodiiron Complexes Containing Mono- and Diphosphine Ligands
Organometallics, 2008, 27, 1409
4072132 CIFC60 H92 Cl2 Ti2P 111.036; 11.7476; 11.8519
83.696; 67.575; 83.281
1407.05Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072137 CIFC30 H46 F2 HfP 4215.4892; 15.4892; 5.86566
90; 90; 90
1407.26Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072133 CIFC30 H46 F2 ZrP 4215.502; 15.502; 5.8576
90; 90; 90
1407.7Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070797 CIFC34 H28 Au Fe2 PP -17.9659; 12.0238; 15.14
100.165; 94.558; 96.371
1411.2Packheiser, Rico; Jakob, Alexander; Ecorchard, Petra; Walfort, Bernhard; Lang, Heinrich
Diphenylphosphinoferrocene Gold(I) Acetylides: Synthesis of Heterotri- and Heterotetrametallic Transition Metal Complexes
Organometallics, 2008, 27, 1214
4070646 CIFC13 H8 Cu2 N2 O5C 1 2/c 113.668; 8.401; 12.406
90; 96.961; 90
1414Takahashi, Yoshiteru; Tsutsumi, Ken; Nakagai, Yuzo; Morimoto, Tsumoru; Kakiuchi, Kiyomi; Ogoshi, Sensuke; Kurosawa, Hideo
Mono- and Dipalladium Movement on the π-Conjugated Five-Carbon Chain
Organometallics, 2008, 27, 276
4071399 CIFC32 H31 I P2 RuP 1 21 18.4821; 15.0654; 11.0948
90; 91.851; 90
1417Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071645 CIFC21 H14 OP 1 21/c 18.8665; 16.4; 10.046
90; 103.966; 90
1417.6Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4070855 CIFC22 H24 N4 O18 Pd2P -110.2492; 11.6858; 14.5201
66.848; 72.464; 64.161
1421.3Vicente, José; Arcas, Aurelia; Gálvez-López, María-Dolores; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Synthesis of Bis(2,6-dinitroaryl)palladium(II) and Mono(2,6-dinitroaryl)platinum(II) Complexes. A New Example of the Transphobia Effect and of Transmetalation from Pt to Hg
Organometallics, 2008, 27, 1582
4071683 CIFC19 H19 N2 RhP 1 21/c 110.0544; 11.1105; 12.8356
90; 97.249; 90
1422.4Jiang, Huiling; Song, Datong
Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
Organometallics, 2008, 27, 3587
4071666 CIFC31 H44 Hf SiP -19.7031; 10.366; 15.583
83.09; 72.17; 72.66
1423.6Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4071193 CIFC33 H34 I P PdP 1 21 18.6509; 19.449; 9.4379
90; 116.13; 90
1425.6Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071496 CIFC32 H28 B F10 N2 RhP -110.321; 10.501; 14.223
74.03; 74.6; 82.79
1426.5Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4070605 CIFC19 H26 B7 Co2 Fe O9 PP -17.5362; 8.3695; 23.0178
84.158; 83.378; 83.582
1427.28Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4071497 CIFC32 H28 B F10 Ir N2P -110.335; 10.481; 14.273
74.01; 74.64; 83.01
1431.2Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4071668 CIFC31 H46 O Si TiP -19.1336; 10.3287; 16.5723
93.569; 104.347; 107.04
1432.72Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4071848 CIFC11 H22 N4 O2 SiP 1 21/n 18.437; 12.084; 14.081
90; 90.94; 90
1435.4Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071612 CIFC58 H84 Ge2 N4 P2P -110.8175; 12.0783; 12.6434
91.55; 108.361; 111.339
1441.49Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071321 CIFC25 H41 Cl2 N2 P PtP -19.158; 10.9628; 16.0184
77.2924; 76.9733; 69.1103
1446.51Vuzman, Dana; Poverenov, Elena; Shimon, Linda J. W.; Diskin-Posner, Yael; Milstein, David
Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization
Organometallics, 2008, 27, 2627
4072051 CIFC34 H42 La NP -18.7176; 9.651; 18.4634
78.405; 87.337; 72.103
1447.86Quiroga Norambuena, Victor F.; Heeres, André; Heeres, Hero J.; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
Organometallics, 2008, 27, 5672
4072335 CIFC28 H34 F6 N3 O3 Os PP -19.2497; 10.955; 14.715
77.78; 87.82; 83.83
1448.7Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4071097 CIFC27.5 H29 Cl F7 N O2.5 P2 RuP 110.9667; 10.9759; 14.2777
76.588; 89.832; 60.962
1449.39Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4070798 CIFC34 H28 Au Fe P RuP -18.2561; 11.9946; 14.9913
99.395; 93.651; 96.474
1450.2Packheiser, Rico; Jakob, Alexander; Ecorchard, Petra; Walfort, Bernhard; Lang, Heinrich
Diphenylphosphinoferrocene Gold(I) Acetylides: Synthesis of Heterotri- and Heterotetrametallic Transition Metal Complexes
Organometallics, 2008, 27, 1214
4070552 CIFC24.5 H38 Cl Fe N2 Sc Si2P -19.913; 12.742; 12.952
70.982; 70.217; 87.775
1450.7Carver, Colin T.; Monreal, Marisa J.; Diaconescu, Paula L.
Scandium Alkyl Complexes Supported by a Ferrocene Diamide Ligand
Organometallics, 2008, 27, 363
4071273 CIFC28 H41 B2 N2 O Si YP -19.8641; 12.5338; 13.7462
102.128; 107.478; 108.072
1452.33Fang, Xiangdong; Deng, Yuanfu; Xie, Qinxing; Moingeon, Firmin
A Bis(1,2-Azaborolyl)yttrium Alkyl Complex: Synthesis, Structure, and Polymerization Study
Organometallics, 2008, 27, 2892
4072157 CIFC31 H49 Al N2P -18.4373; 9.7007; 19.346
82.033; 80.769; 69.565
1458.71Olson, Jeremy A.; Boyd, Ramon; Quail, J. Wilson; Foley, Stephen R.
Copper(II) Ethylene Polymerization Catalysts: Do They Really Exist?
Organometallics, 2008, 27, 5333
4071852 CIFC31 H40 N4 O2 SiP -19.691; 11.134; 14.777
80.57; 89.28; 68.48
1461.3Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4072245 CIFC36 H68 B20 Cl4 N4 Rh2 S4P -111.104; 11.219; 14.042
71.071; 78.586; 62.268
1462.3Jia, Wei-Guo; Han, Ying-Feng; Jin, Guo-Xin
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Containing 1,2-Dichalcogenolato Carborane or Carbonato Ligands
Organometallics, 2008, 27, 6035
4071895 CIFC17 H21 Fe N O2P 21 21 217.3992; 12.9482; 15.2689
90; 90; 90
1462.86Tebben, Ludger; Bussmann, Kathrin; Hegemann, Michael; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Ferrocene-Derived Bioorganometallic Chemistry: Preparation of a [3]Ferrocenophane γ-Amino Acid for Use in Peptide Synthesis
Organometallics, 2008, 27, 4269
4071332 CIFC20.5 H33.5 I3 N6 RhP -19.1548; 11.9397; 14.1549
95.23; 107.292; 93.65
1464.4Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4072228 CIFC32 H47 TiP -18.8959; 12.1869; 15.2672
92.443; 105.854; 111.242
1465.41Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4071012 CIFC12 H6 Ag8 N10 O21P -17.5346; 11.4637; 17.235
82.286; 88.016; 84.343
1467.7Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4071607 CIFC27 H28 Ge P PtP -18.638; 13.93; 14.177
109.661; 99.571; 107.007
1468.3Arii, Hidekazu; Nanjo, Masato; Mochida, Kunio
Characterization of Mononuclear and Dinuclear Germylplatinum Complexes and Ge−Ge Bond Formation at the Platinum Center
Organometallics, 2008, 27, 4147
4072244 CIFC17 H32 B10 Ir N2 Se2P -111.215; 11.238; 14.053
72.147; 80.786; 60.952
1473.7Jia, Wei-Guo; Han, Ying-Feng; Jin, Guo-Xin
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Containing 1,2-Dichalcogenolato Carborane or Carbonato Ligands
Organometallics, 2008, 27, 6035
4071005 CIFC20 H29 Cl3 F6 Ir N3 O3 P TlP 1 21 110.1512; 11.4196; 12.8731
90; 98.977; 90
1474Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4070929 CIFC34 H16 F10 N4 ZnP -18.0378; 14.0455; 14.551
114.357; 91.807; 97.603
1476.6Martin, Eddy; Spendley, Claire; Mountford, Andrew J.; Coles, Simon J.; Horton, Peter N.; Hughes, David L.; Hursthouse, Michael B.; Lancaster, Simon J.
Synthesis, Structure, and Supramolecular Architecture of Benzonitrile and Pyridine Adducts of Bis(pentafluorophenyl)zinc: Pentafluorophenyl‒Aryl Interactions versus Homoaromatic Pairing
Organometallics, 2008, 27, 1436
4070504 CIFC22 H41 B8 N3 PtP -111.4393; 11.523; 12.9427
80.784; 81.299; 61.667
1476.71Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4071912 CIFC27 H29 O7 Os3 PP -19.0338; 10.632; 15.8388
79.472; 82.389; 84.241
1478Adams, Richard D.; Boswell, Erin M.; Hall, Michael B.; Yang, Xinzheng
Activation of Hydrogen and Related Small Molecules by the Unsaturated Cluster Complex PtOs3(CO)7(PBut3)(μ-PBut2)(μ4-CHCMeCH)
Organometallics, 2008, 27, 4938
4071894 CIFC25 H42 B9 O2 ZrP -19.8791; 11.4486; 13.9799
95.837; 108.744; 93.901
1480.99Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4071906 CIFC34 H30 O4 S2P 1 21 18.1156; 16.984; 11.5882
90; 111.984; 90
1481.12Kuniyasu, Hitoshi; Takekawa, Kazunobu; Yamashita, Fumikazu; Miyafuji, Kiyoshi; Asano, Shigehito; Takai, Yasutomo; Ohtaka, Atsushi; Tanaka, Aoi; Sugoh, Kunihiko; Kurosawa, Hideo; Kambe, Nobuaki
Insertion of Alkynes into an ArS−Pt Bond: Regio- and Stereoselective Thermal Reactions, Facilitation by “o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences Depending on the Ancillary Ligand, and Application to a Catalytic Reaction
Organometallics, 2008, 27, 4788
4072236 CIFC30 H49 Cl Si2 TiP -18.6384; 11.4893; 15.6002
78.9559; 77.8493; 86.9128
1485.44Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4070632 CIFC8 H4 F6 O10 Ru2P 1 21/c 112.6491; 8.7326; 13.626
90; 99.274; 90
1485.45Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4071583 CIFC39 H34 Fe2 N2 OP -111.231; 12.606; 12.79
114.55; 97.629; 108.532
1486.2Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4072167 CIFC32 H42 N4 O4 Rh2P 1 21/n 18.3492; 12.2916; 14.5016
90; 90.191; 90
1488.22Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072355 CIFC16 H14 N2 O4 SiP 21 21 217.3257; 13.6736; 14.8738
90; 90; 90
1489.89Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072231 CIFC30 H49 Si2 TiP -19.0306; 11.9583; 14.7172
89.3701; 82.0966; 71.3318
1490.48Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072261 CIFC23 H21 F12 N9 Ni2 O P2P -18.0204; 13.7196; 14.9468
109.605; 96.764; 101.033
1491Zhou, Yongbo; Xi, Zhenxing; Chen, Wanzhi; Wang, Daqi
Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni2(μ-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides
Organometallics, 2008, 27, 5911
4070526 CIFC28 H36 Co F6 O6 PP -19.746; 12.138; 14.577
114.113; 106.166; 91.635
1491.7Perekalin, Dmitry S.; Babak, Maria V.; Novikov, Valentin V.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Corsini, Maddalena; Zanello, Piero; Kudinov, Alexander R.
A New Approach to the Photochemically Controlled Crown Ethers: (Tetramethylcyclobutadiene)cobalt Complexes with Benzo-15-Crown-5 and Dibenzo-18-Crown-6†
Organometallics, 2008, 27, 3654
4071384 CIFC30 H57 O3 PP -18.6589; 10.335; 17.863
89.713; 77.73; 73.231
1492.9Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071030 CIFC23 H47 Li N4 Si2P -110.189; 11.171; 14.437
103.46; 108.24; 95.06
1494.6Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071791 CIFC30 H50 Os3P -111.0085; 11.0311; 15.1064
71.327; 73.298; 60.641
1495.67Kameo, Hajime; Suzuki, Hiroharu
Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(μ-H)6]+and {(C5Me5)Os}3(μ-H)3(μ3-H)2and Comparison with the Ruthenium Analogues
Organometallics, 2008, 27, 4248
4072371 CIFC70 H74 B2 Fe3 Li O8P -18.8567; 12.9851; 13.531
78.523; 80.93; 82.496
1498Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4072344 CIFC25 H33 Br2 Cl Co N3 O P2P -18.834; 9.4939; 18.3764
84.975; 78.725; 88.533
1505.6Wang, Aichen; Sun, Hongjian; Li, Xiaoyan
N-Assisted Carbon−Hydrogen Bond Activation by Cobalt(I) Complexes
Organometallics, 2008, 27, 5434
4071937 CIFC36 H20 F8 P2 PtP 1 21/c 110.0072; 12.2049; 12.7603
90; 104.943; 90
1505.8Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4082270 CIFC29 H32 Cl F6 N O2 P2 RuP 1 21 19.4734; 16.2505; 9.7948
90; 91.773; 90
1507.16Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4071936 CIFC36 H20 F8 P2 PdP 1 21/c 19.997; 12.2158; 12.7955
90; 105.055; 90
1508.97Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4070785 CIFC26 H52 O Si4P -110.0468; 10.3024; 17.0558
104.11; 94.399; 115.674
1509.15Naka, Akinobu; Motoike, Shingo; Senba, Norihito; Ohshita, Joji; Kunai, Atsutaka; Yoshizawa, Kazunari; Ishikawa, Mitsuo
Silicon−Carbon Unsaturated Compounds. 74. Thermal Behavior of 1-Silacyclobut-3-enes Generated from the Reaction of Acylpolysilanes withtert-Butylacetylene
Organometallics, 2008, 27, 2750
4070859 CIFC16 H21 Cl O RuC m c 219.0438; 13.2365; 12.6151
90; 90; 90
1510.13Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4072422 CIFC64 H72 Cl8 N4 Pt2P -110.0472; 12.0539; 13.355
70.392; 83.136; 86.422
1512.25Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4070706 CIFC10 H9 Fe2 N O6 S2P 1 21/n 19.964; 12.0864; 13.0405
90; 105.405; 90
1514Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4072302 CIFC33 H45 N P2 RuP -18.815; 10.673; 18.027
76.406; 75.879; 69.245
1517.25Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4072135 CIFC30 H46 Cl2 HfP 4215.3372; 15.3372; 6.4757
90; 90; 90
1523.28Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072272 CIFC32 H43 Ir N2 ZrP -111.1561; 11.174; 12.3671
89.535; 81.628; 88.713
1524.83Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4071495 CIFC19 H49 Al Si5P -110.554; 12.1864; 12.5117
97.449; 95.133; 105.461
1524.87Uhl, Werner; Er, Elif; Hepp, Alexander; Kösters, Jutta; Grunenberg, Jörg
Reactions of Terminal Alkynes with a Bulky Dialkylaluminum Hydride: Hydroalumination versus Deprotonation
Organometallics, 2008, 27, 3346
4072104 CIFC20 H20 O2P 1 21 110.6161; 6.8123; 21.2635
90; 96.907; 90
1526.62Yeh, Ming-Chang P.; Tsao, Wen-Cheng; Lee, Bo-Jen; Lin, Tzu-Ling
Facile Synthesis of Carbotetracycles via Gold(I)-Catalyzed Cyclization of Unactivated Cyclic 1-Aryl-6,8-dien-1-ynes
Organometallics, 2008, 27, 5326
4071276 CIFC30 H20 Fe2 O6 P2 S2P -19.991; 11.558; 14.893
71.732; 88.952; 70.292
1530.1Song, Li-Cheng; Zeng, Guang-Huai; Lou, Shao-Xia; Zan, Hui-Ning; Ming, Jiang-Bo; Hu, Qing-Mei
Synthetic and Structural Studies of Butterfly Fe/S/P Cluster Complexes Related to the Active Site of [FeFe]-Hydrogenases. Proton Reduction to H2Catalyzed by (η1-Ph2PS-η1)2Fe2(CO)6
Organometallics, 2008, 27, 3714
4070896 CIFC25 H46 B9 N O3 ZrP -19.4871; 13.1; 13.729
94.24; 105.41; 108.92
1531.9Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4072128 CIFC30 H32 N4 O4 Sn WP -18.607; 10.833; 17.866
93.782; 92.825; 112.388
1531.9Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4072190 CIFC34 H40 O2 P2P 1 21/c 110.9457; 12.8989; 11.2301
90; 104.899; 90
1532.2Long, Richard J.; Jones, David J.; Gibson, Vernon C.; White, Andrew J. P.
Zirconium Complexes Containing Tetradentate O,P,P,O Ligands: Ethylene and Propylene Polymerization Studies
Organometallics, 2008, 27, 5960
4071813 CIFC32 H38 N4 Pt SP -17.8393; 13.7453; 14.55
94.905; 97.696; 97.36
1532.5Moret, Marc-Etienne; Chen, Peter
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands
Organometallics, 2008, 27, 4903
4071210 CIFC27 H42 Si4 TiP 1 21 111.335; 10.597; 12.796
90; 94.356; 90
1532.6Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071054 CIFC39 H30 Cl2 O TiP -110.5863; 10.7139; 14.898
109.84; 97.97; 99.321
1534Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071670 CIFC18 H16 N P SP 1 21/n 112.4129; 7.3039; 17.1658
90; 99.485; 90
1535.02Kling, Christian; Ott, Holger; Schwab, Gerald; Stalke, Dietmar
Heteroaromatic Substituted Phosphoranes with Enhanced Hemilabile Character
Organometallics, 2008, 27, 5038
4072316 CIFC28 H44 N6 Si2 TiP -110.1794; 11.18; 13.8952
89.726; 77.178; 85.912
1537.9Selby, Jonathan D.; Manley, Catherine D.; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study
Organometallics, 2008, 27, 6479
4071753 CIFC34 H41 Cl2 Fe SiP -19.2204; 12.5311; 15.1144
70.815; 80.039; 69.2381
1539.09Sasamori, Takahiro; Yuasa, Akihiro; Hosoi, Yoshinobu; Furukawa, Yukio; Tokitoh, Norihiro
1,2-Bis(ferrocenyl)disilene: A Multistep Redox System with an SiSi Double Bond
Organometallics, 2008, 27, 3325
4070744 CIFC12 H15 B Bi Cl2 F O2P 21 21 219.1514; 11.6274; 14.5092
90; 90; 90
1543.9Caires, Christopher C.; Guccione, Samira
Synthesis, Structure, and Reactivity of Borate Ester Coordinated Organobismuth Compounds
Organometallics, 2008, 27, 747
4072300 CIFC34 H48 N3 P RuP -18.83; 10.96; 17.135
87.246; 83.675; 69.536
1544.08Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4070919 CIFC15 H19 Cl N Rh SP 1 21/c 112.712; 7.541; 16.181
90; 92.081; 90
1550.1Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4071644 CIFC14 H9 B F4 N4 O4P 1 21/c 116.0959; 7.1079; 14.343
90; 109.097; 90
1550.65Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071876 CIFC26 H53 B F4 O2 Os P2P m m n :213.041; 14.089; 8.462
90; 90; 90
1554.8Buil, María L.; Esteruelas, Miguel A.; Garcés, Karin; Oliván, Montserrat; Oñate, Enrique
Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands
Organometallics, 2008, 27, 4680
4071616 CIFC12 H19 Cl N4 O2P 1 21/c 15.0761; 14.6843; 21.131
90; 98.605; 90
1557.4Ye, Jiansheng; Zhang, Xiaoming; Chen, Wanzhi; Shimada, Shigeru
Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling
Organometallics, 2008, 27, 4166
4071908 CIFC36 H48 N O UP -110.635; 10.736; 15.299
82.214; 88.185; 64.197
1557.4Graves, Christopher R.; Scott, Brian L.; Morris, David E.; Kiplinger, Jaqueline L.
Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with CuCCPh
Organometallics, 2008, 27, 3335
4071131 CIFC30 H60 P Pt SiP -19.427; 13.635; 13.746
113.132; 90.197; 105.053
1558Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4071156 CIFC32 H41 Br N2 Ni O3 SP -18.277; 9.648; 20.574
77.699; 81.838; 77.803
1560.9Li, Jianfeng; Tian, Dawei; Song, Haibin; Wang, Chunhua; Zhu, Xiaoqing; Cui, Chunming; Cheng, Jin-Pei
Synthesis, Structures, and Reactivity of Nickel Complexes Incorporating Sulfonamido-Imine Ligands
Organometallics, 2008, 27, 1605
4070822 CIFC8 H11 GaP 1 2/c 116.863; 7.252; 12.828
90; 95.604; 90
1561.24Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4071754 CIFC28 H29 N7 O10 Sn2P -111.0753; 12.0391; 12.0906
90.121; 98.385; 101.599
1561.5Chandrasekhar, Vadapalli; Singh, Puja
Trapping a Discrete [R2Sn(μ-OH)SnR2] Motif. Synthesis and Structural Characterization of [{(Phen)(NO3)Me2Sn(μ-OH)SnMe2(NO3)(Phen)}{NO3}] (Phen = 1,10-Phenanthroline)
Organometallics, 2008, 27, 4083
4071428 CIFC18 H14 Ag8 N6 O21P -17.6273; 10.2369; 20.343
89.231; 79.744; 88.209
1562.2Zang, Shuang-Quan; Zhao, Liang; Mak, Thomas C. W.
Diverse Intermolecular Interactions in Metal−Organic Frameworks Constructed with the New Supramolecular Synthon Agn−L−Agn(n= 4, 5) (H2L = 2,2′-Bis(prop-2-ynyloxy)biphenyl)
Organometallics, 2008, 27, 2396
4071646 CIFC22 H16 O2P 1 21/c 122.353; 4.2632; 16.519
90; 94.393; 90
1569.6Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4072431 CIFC16 H19 Br N2 NiP 21 21 2110.2497; 10.7909; 14.198
90; 90; 90
1570.35Hahn, F. Ekkehardt; Radloff, Christian; Pape, Tania; Hepp, Alexander
A Nickel(II)-Cornered Molecular Rectangle with Biscarbene and 4,4′-Bipyridine Bridging Groups
Organometallics, 2008, 27, 6408
4072294 CIFC12 H14 Cl F3 N2 O2 Ru SP 1 21/c 111.781; 9.656; 14.3
90; 105.102; 90
1571Ito, Masato; Endo, Yoshinori; Ikariya, Takao
Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones
Organometallics, 2008, 27, 6053
4070942 CIFC37 H31 N2 P Ru S2P -110.345; 11.529; 13.657
88.342; 80.331; 78.733
1574.7Armitt, David J.; Bruce, Michael I.; Skelton, Brian W.; White, Allan H.
Reactions of Alkynyl−Ruthenium Complexes with the Ketene Dithioacetal, (MeS)2CC(CN)2
Organometallics, 2008, 27, 3556
4070658 CIFC33 H46 Fe N3 SiP -111.3974; 12.4327; 12.4651
96.722; 115.82; 90.816
1574.84Fernández, Ignacio; Trovitch, Ryan J.; Lobkovsky, Emil; Chirik, Paul J.
Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3and FeCH2CMe3Derivatives
Organometallics, 2008, 27, 109
4070564 CIFC32 H47 O Si2 YP -111.1359; 12.7246; 12.9267
76.003; 74.189; 64.557
1574.97Sun, Jianlong; Berg, David J.; Twamley, Brendan
Yttrium Complexes of a Phenanthrene-Fused Cyclopentadienyl: Synthetic, Structural, and Reactivity Studies
Organometallics, 2008, 27, 683
4071671 CIFC18 H16 N P SeP 1 21/n 112.6149; 7.2983; 17.4007
90; 100.102; 90
1577.2Kling, Christian; Ott, Holger; Schwab, Gerald; Stalke, Dietmar
Heteroaromatic Substituted Phosphoranes with Enhanced Hemilabile Character
Organometallics, 2008, 27, 5038
4070779 CIFC13 H20 Cl Ir N2 O2P n a 2110.7068; 10.3756; 14.2075
90; 90; 90
1578.3Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4071328 CIFC23 H37 I3 N7 RhP -19.8916; 11.2101; 15.4797
105.961; 95.541; 103.501
1580.8Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4072037 CIFC30 H42 Fe2 O Si4P 1 21/c 18.52; 18.126; 10.723
90; 107.28; 90
1581.2Kumar, Mukesh; Metta-Magana, Alejandro J.; Pannell, Keith H.
Ferrocenylene- and Carbosiloxane-Bridged Bis(sila[1]ferrocenophanes) E[SiMe2-X-SiMeFC]2{E = (η5-C5H4)Fe(η5-C5H4) or O; X = (CH2)n(n= 2, 3, 6); CHCH;FC= (η5-C5H4)2Fe}
Organometallics, 2008, 27, 6457
4071696 CIFC25 H45 B9 N3 O P ZrP -110.59; 11.642; 13.723
87.653; 70.193; 83.505
1581.6Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4070649 CIFC41 H29 Au N3 PP -18.6401; 9.4232; 19.5947
85.165; 86.406; 85.237
1581.69Vicente, José; Gil-Rubio, Juan; Barquero, Natalia; Jones, Peter G.; Bautista, Delia
Synthesis of Luminescent Alkynyl Gold Metalaligands Containing 2,2′-Bipyridine-5-yl and 2,2′:6′,2′′-Terpyridine-4-yl Donor Groups
Organometallics, 2008, 27, 646
4071166 CIFC34 H36 Br2 N4 NiP 1 21/n 110.993; 10.787; 13.442
90; 94.954; 90
1588Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071093 CIFC30 H43 B F3 N4 O3.5 SP -18.11; 13.043; 15.489
85.454; 78.149; 83.434
1590.3Chiu, Ching-Wen; Gabbaï, François P.
Diarylborenium Cations: Synthesis, Structure, and Electrochemistry
Organometallics, 2008, 27, 1657
4071726 CIFC38 H32 Fe O4 P2 PtP -110.562; 10.742; 15.34
84.819; 72.969; 73.107
1592.3Bar, Arun Kumar; Chakrabarty, Rajesh; Mukherjee, Partha Sarathi
Unusual Hydrogenation of Fumarate Anion Followed by Metal−Carbon Bond Formation: Synthesis and Characterization of Two Metallochelates
Organometallics, 2008, 27, 3806
4070950 CIFC34 H34 Cl2 N4 Pd2P 1 21/n 17.4968; 9.9044; 21.6197
90; 97.241; 90
1592.49Hadzovic, Alen; Song, Datong
Synthesis, Characterization, and Reactivity of a Versatile Dinuclear Palladium β-Diiminate Complex
Organometallics, 2008, 27, 1290
4071523 CIFC22 H14 FeP -111.814; 12.369; 12.749
71.211; 78.614; 64.992
1594Packheiser, Rico; Ecorchard, Petra; Rüffer, Tobias; Lohan, Manja; Bräuer, Björn; Justaud, Frédéric; Lapinte, Claude; Lang, Heinrich
Heterotrimetallic M−M′−M′′ Transition Metal Complexes Based on 1,3,5-Triethynylbenzene: Synthesis, Solid State Structure, and Electrochemical and UV−Vis Characterization. EPR Analysis of thein SituGenerated Associated Radical Cations
Organometallics, 2008, 27, 3444
4070799 CIFC35 H28 Au Cl2 Fe N2 PP -19.0155; 13.2674; 14.053
89.565; 85.665; 72.289
1596.5Packheiser, Rico; Jakob, Alexander; Ecorchard, Petra; Walfort, Bernhard; Lang, Heinrich
Diphenylphosphinoferrocene Gold(I) Acetylides: Synthesis of Heterotri- and Heterotetrametallic Transition Metal Complexes
Organometallics, 2008, 27, 1214
4071861 CIFC25 H36 B N8 O7 P WP -19.586; 11.53; 16.08
95.731; 104.202; 108.601
1602Kosturko, George W.; Graham, Peter M.; Myers, William H.; Smith, Timothy M.; Sabat, Michal; Harman, W. Dean
Tungsten-Promoted Diels−Alder Cycloaddition of Pyridines: Dearomatization of 2,6-Dimethoxypyridine Generates a Potent 2-Azadiene Synthon
Organometallics, 2008, 27, 4513
4072383 CIFC14 H25 Cl N2 PdP n a 2111.476; 10.767; 12.971
90; 90; 90
1602.72Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072295 CIFC32 H33 F3 N4 O4 Ru S2P 1 21 110.3427; 13.9319; 11.2884
90; 99.369; 90
1604.9Ito, Masato; Endo, Yoshinori; Ikariya, Takao
Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones
Organometallics, 2008, 27, 6053
4071689 CIFC16 H19 Cl2 N TiP 1 21/c 19.1152; 13.6101; 13.2743
90; 102.881; 90
1605.36Wu, Chun Ji; Lee, Sang Hoon; Yu, Seung Tack; Na, Sung Jae; Yun, Hoseop; Lee, Bun Yeoul
CO2-Mediatedortho-Lithiation ofN-Alkylanilines and Its Use for the Construction of Polymerization Catalysts
Organometallics, 2008, 27, 3907
4071934 CIFC6 H22 B9 Cl S SiP 1 21/n 18.9214; 14.2968; 13.1606
90; 106.972; 90
1605.49Meshcheryakov, Vladimir I.; Zheng, Chong; Kudinov, Alexander R.; Maguire, John A.; Hosmane, Narayan S.
Silicon(IV) and Germanium(IV) Moieties Stabilized by the Charge-Compensated Carborane Ligand [9-SMe2-7,8-C2B9H10]−: Synthetic and Structural Investigation
Organometallics, 2008, 27, 5033
4071935 CIFC6 H22 B9 Cl Ge SP 1 21/n 18.8368; 12.8117; 14.1838
90; 90.913; 90
1605.6Meshcheryakov, Vladimir I.; Zheng, Chong; Kudinov, Alexander R.; Maguire, John A.; Hosmane, Narayan S.
Silicon(IV) and Germanium(IV) Moieties Stabilized by the Charge-Compensated Carborane Ligand [9-SMe2-7,8-C2B9H10]−: Synthetic and Structural Investigation
Organometallics, 2008, 27, 5033
4071271 CIFC28 H40 Br2 N2 O4 Zn2P 1 21/c 18.123; 12.489; 16.18
90; 101.256; 90
1609.9Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4070946 CIFC39 H31 N2 P Ru S2P -19.72; 13.312; 13.636
97.32; 100.57; 108.64
1610.4Armitt, David J.; Bruce, Michael I.; Skelton, Brian W.; White, Allan H.
Reactions of Alkynyl−Ruthenium Complexes with the Ketene Dithioacetal, (MeS)2CC(CN)2
Organometallics, 2008, 27, 3556
4070901 CIFC25.5 H47 B9 N4 ZrP -110.1562; 10.8111; 16.456
78.112; 73.677; 69.557
1613.1Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4071574 CIFC16 H21 I N2 PtP 21 21 214.6146; 11.7364; 29.866
90; 90; 90
1617.51Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071725 CIFC38 H32 Fe O4 P2 PdP -110.647; 10.747; 15.536
85.044; 72.925; 72.852
1623.8Bar, Arun Kumar; Chakrabarty, Rajesh; Mukherjee, Partha Sarathi
Unusual Hydrogenation of Fumarate Anion Followed by Metal−Carbon Bond Formation: Synthesis and Characterization of Two Metallochelates
Organometallics, 2008, 27, 3806
4070542 CIFC16 H14 F3 Ga N4P 1 21/c 18.9197; 14.9354; 12.4181
90; 100.74; 90
1625.35Song, Yi-Hwa; Chiu, Yuan-Chieh; Chi, Yun; Chou, Pi-Tai; Cheng, Yi-Ming; Lin, Chun-Wei; Lee, Gene-Hsiang; Carty, Arthur J.
Synthesis, Characterization, and Photophysical Properties of Luminescent Gallium and Indium Complexes Constructed using Tridentate 6-Azolyl-2,2′-bipyridine Chelates
Organometallics, 2008, 27, 80
4071614 CIFC22 H32 F12 N8 P2 Pd2P 1 21/c 17.7026; 19.112; 11.4095
90; 104.382; 90
1627Ye, Jiansheng; Zhang, Xiaoming; Chen, Wanzhi; Shimada, Shigeru
Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling
Organometallics, 2008, 27, 4166
4071521 CIFC30 H31 Cl4 N3 O5 PdP -17.5612; 15.6521; 15.8294
113.26; 97.223; 103.022
1627.9Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4072040 CIFC37 H54 N3 O ScP -19.5975; 9.7793; 18.7475
100.653; 96.5794; 106.247
1634.2Ge, Shaozhong; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Rare Earth Metal Alkyl and Benzyl Compounds with the 1,4,6-Trimethyl-6-pyrrolidin-1-yl-1,4-diazepane Ligand and Their Performance in the Catalytic Hydroamination/Cyclization of Aminoalkenes
Organometallics, 2008, 27, 5339
4072423 CIFC53 H37 Cl11 F12 N4 O4 Pt2P -111.2692; 12.5803; 12.6285
69.421; 77.399; 84.709
1635.5Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4070861 CIFC17 H20 Cl N O RuC 1 c 117.5733; 8.3436; 13.953
90; 126.871; 90
1636.7Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4070581 CIFC31 H48 Br2 N4 Rh2P 21 21 213.5476; 14.3566; 8.4221
90; 90; 90
1638.1Wells, Kyle D.; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
Organometallics, 2008, 27, 691
4072271 CIFC28 H55 Hf Ir Si2P -111.1075; 11.5985; 12.909
87.188; 83.846; 82.685
1638.97Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4071173 CIFC27 H53 I Si4 SnP -18.8888; 9.563; 20.9269
91.915; 101.687; 108.692
1640.8Kavara, Ajdin; Cousineau, Kandarpa D.; Rohr, Ahleah D.; Kampf, Jeff W.; Banaszak Holl, Mark M.
A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
Organometallics, 2008, 27, 1041
4071186 CIFC18 H27 Br OsP 1 21/n 18.7839; 13.3233; 14.1332
90; 97.17; 90
1641.08Dub, Pavel A.; Belkova, Natalia V.; Lyssenko, Konstantin A.; Silantyev, Gleb A.; Epstein, Lina M.; Shubina, Elena S.; Daran, Jean-Claude; Poli, Rinaldo
Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
Organometallics, 2008, 27, 3307
4072058 CIFC34 H52 Mg N2 O3P -19.919; 10.934; 16.185
74.76; 76.25; 82.97
1641.7Liu, Yanyan; Yang, Peiju; Yu, Jie; Yang, Xiao-Juan; Zhang, Jun D.; Chen, Zhongfang; Schaefer, Henry F.; Wu, Biao
Sodium and Magnesium Complexes with Dianionic α-Diimine Ligands
Organometallics, 2008, 27, 5830
4071797 CIFC40 H26 N2 O4 Ru2 S2P -110.3493; 11.1995; 16.002
110.508; 90.724; 107.414
1643.2Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4070792 CIFC27 H53 N3 O2 Si2 YbP 1 21 19.981; 14.7544; 11.2266
90; 96.299; 90
1643.29Datta, Simmi; Gamer, Michael T.; Roesky, Peter W.
Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
Organometallics, 2008, 27, 1207
4071576 CIFC16 H19 F2 I N2 PtP 21 21 214.5846; 11.894; 30.144
90; 90; 90
1643.7Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4070729 CIFC32 H51 Al N2 O2 SiP 1 21 18.8703; 19.895; 10.231
90; 114.08; 90
1648.4Yang, Ying; Schulz, Thomas; John, Michael; Yang, Zhi; Jiménez-Pérez, Victor Manuel; Roesky, Herbert W.; Gurubasavaraj, Prabhuodeyara M.; Stalke, Dietmar; Ye, Hongqi
Organoaluminum Hydroxides Supported by β-Diketiminato Ligands: Synthesis, Structural Characterization, and Reactions
Organometallics, 2008, 27, 769
4071283 CIFC33 H42 Cl4 N2P 1 21/m 110.983; 14.196; 11.017
90; 106.04; 90
1650.8Chitanda, Jackson M.; Prokopchuk, Demyan E.; Quail, J. Wilson; Foley, Stephen R.
From Pyrroles to Isoindolines: Synthesis of a γ-Diimine Ligand for Applications in Palladium Coordination Chemistry and Catalysis
Organometallics, 2008, 27, 2337
4071508 CIFC33 H53 N O2 ZrP 1 21 19.9231; 17.3758; 9.9311
90; 105.171; 90
1652.66Gott, Andrew L.; Clarke, Adam J.; Clarkson, Guy J.; Munslow, Ian J.; Wade, Andrew R.; Scott, Peter
Single Diastereomer Half-Sandwich Salicyloxazoline Complexes of Titanium and Zirconium
Organometallics, 2008, 27, 2706
4070631 CIFC30 H14 F12 O9 Ru2P -111.5905; 11.9241; 13.0024
76.263; 73.727; 77.817
1655.44Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4072105 CIFC21 H22 O2P 1 21 110.6786; 6.8771; 22.698
90; 96.615; 90
1655.8Yeh, Ming-Chang P.; Tsao, Wen-Cheng; Lee, Bo-Jen; Lin, Tzu-Ling
Facile Synthesis of Carbotetracycles via Gold(I)-Catalyzed Cyclization of Unactivated Cyclic 1-Aryl-6,8-dien-1-ynes
Organometallics, 2008, 27, 5326
4072359 CIFC15 H21 N3 O2 SiP 1 21/c 112.0673; 12.6067; 10.8886
90; 90.118; 90
1656.47Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4070573 CIFC17 H14 F6 N P RuP 1 21/c 19.7862; 16.7367; 11.0019
90; 112.949; 90
1659.36Choi, Moon-Gun; Ho, Teh C.; Angelici, Robert J.
Arene Binding Affinities in [CpRu(η6-arene)]+Complexes: Models for the Adsorption of Arenes on Hydrodesulfurization Catalysts
Organometallics, 2008, 27, 1098
4071279 CIFC30 H54 Si4 TiP -19.0743; 11.6767; 16.9712
77.7294; 75.2076; 75.1488
1659.61Horáček, Michal; Pinkas, Jiří; Gyepes, Róbert; Kubišta, Jiří; Mach, Karel
Reactivity of SiMe2H Substituents in Permethylated Titanocene Complexes: Dehydrocoupling and Ethene Hydrosilylation
Organometallics, 2008, 27, 2635
4072426 CIFC33 H50 Ir N O3 P2P -110.64; 11.968; 14.554
85.152; 75.576; 67.644
1659.9Whited, Matthew T.; Grubbs, Robert H.
Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes
Organometallics, 2008, 27, 5737
4072308 CIFC32 H49 Cl2 O P Ru2 SP -110.5851; 12.3136; 13.1597
78.4177; 81.6515; 89.9665
1661.79Miyake, Yoshihiro; Endo, Satoshi; Yuki, Masahiro; Tanabe, Yoshiaki; Nishibayashi, Yoshiaki
Synthesis and Reactivity of Hybrid Phosphido- and Thiolato-Bridged Diruthenium Complexes
Organometallics, 2008, 27, 6039
4072248 CIFC24 H30 Fe N4P -16.5504; 16.014; 16.457
76.516; 82.67; 85.427
1662.8Tan, Weiqiang; Yu, Zhengkun; He, Wei; Wang, Liandi; Sun, Jie; Chen, Jinzhu
A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH2)2-Bridged Bis(pyrazole)
Organometallics, 2008, 27, 4833
4072356 CIFC40 H28 N4 O8 SiP -19.8419; 12.6734; 13.8628
85.201; 75.716; 87.212
1669.08Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072138 CIFC22 H15 N O2P -110.4372; 11.7904; 14.1541
76.651; 80.236; 87.845
1670.18Chu, Jean-Ho; Chen, Chin-Chau; Wu, Ming-Jung
Palladium-Catalyzed Arylation and Alkylation of 3,5-Diphenylisoxazole with Boronic Acids via C−H Activation
Organometallics, 2008, 27, 5173
4072266 CIFC15 H23 Cl Ge N2C 1 2/c 114.037; 11.109; 11.847
90; 115.2; 90
1671.6Nagendran, Selvarajan; Sen, Sakya S.; Roesky, Herbert W.; Koley, Debasis; Grubmüller, Helmut; Pal, Aritra; Herbst-Irmer, Regine
RGe(I)Ge(I)R Compound (R = PhC(NtBu)2) with a Ge−Ge Single Bond and a Comparison with the Gauche Conformation of Hydrazine†
Organometallics, 2008, 27, 5459
4072059 CIFC37 H49 Fe N3 O2P -110.6786; 10.6822; 16.6653
74.144; 81.909; 66.3
1673.44Trovitch, Ryan J.; Lobkovsky, Emil; Bouwkamp, Marco W.; Chirik, Paul J.
Carbon−Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C−O Bond Cleavage in Esters
Organometallics, 2008, 27, 6264
4070791 CIFC27 H53 Eu N3 O2 Si2P 1 21 110.0714; 14.8719; 11.2287
90; 95.272; 90
1674.7Datta, Simmi; Gamer, Michael T.; Roesky, Peter W.
Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
Organometallics, 2008, 27, 1207
4071235 CIFC17 H21 Cl N2 O2 PdP 1 21/n 111.4408; 9.9882; 14.8055
90; 97.645; 90
1676.83Giri, Ramesh; Maugel, Nathan; Foxman, Bruce M.; Yu, Jin-Quan
Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
Organometallics, 2008, 27, 1667
4070788 CIFC27 H53 N3 O2 Si2 SrP 1 21 110.0783; 14.8443; 11.2553
90; 95.166; 90
1677Datta, Simmi; Gamer, Michael T.; Roesky, Peter W.
Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
Organometallics, 2008, 27, 1207
4072319 CIFC32 H44 N6 Si2 TiP -110.1894; 10.3302; 17.9754
95.5849; 103.246; 111.583
1677.77Selby, Jonathan D.; Manley, Catherine D.; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study
Organometallics, 2008, 27, 6479
4071820 CIFC32.5 H37 Cl2 F6 Ir N3 PP -18.6792; 14.4528; 14.4654
110.965; 95.119; 92.42
1682.27Peng, Hong Mei; Webster, Richard D.; Li, Xingwei
Quinoline-Tethered N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Synthesis, Catalysis, and Electrochemical Properties
Organometallics, 2008, 27, 4484
4071308 CIFC37 H43 N2 P S2P -110.386; 10.593; 16.052
81.068; 79.756; 77.56
1684.5Nakabuchi, Takashi; Matano, Yoshihiro; Imahori, Hiroshi
Synthesis, Structures, and Coordinating Properties of Phosphole-Containing Hybrid Calixpyrroles
Organometallics, 2008, 27, 3142
4071603 CIFC36 H52 N O2 TaP -111.1983; 11.4259; 14.4511
88.758; 75.244; 70.959
1686.39Agapie, Theodor; Day, Michael W.; Bercaw, John E.
Synthesis and Reactivity of Tantalum Complexes Supported by Bidentate X2and Tridentate LX2Ligands with Two Phenolates Linked to Pyridine, Thiophene, Furan, and Benzene Connectors: Mechanistic Studies of the Formation of a Tantalum Benzylidene and Insertion Chemistry for Tantalum−Carbon Bonds
Organometallics, 2008, 27, 6123
4071780 CIFC29 H33 Cl8 P PtP -111.281; 12.104; 13.133
89.331; 76.72; 75.78
1689.9Baber, Angharad; Fan, Cheng; Norman, David W.; Orpen, A. Guy; Pringle, Paul G.; Wingad, Richard L.
Oxidative Dehydrogenation of Tris(o-isopropylphenyl)phosphines by Platinum Complexes
Organometallics, 2008, 27, 5906
4071112 CIFC17 H12 Cl Mn O5P 1 21/c 112.2077; 12.2447; 12.4139
90; 114.101; 90
1693.9Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4070595 CIFC30 H28 Cl2 F12 N2 O2 TiP 1 21/c 19.6966; 8.6009; 20.8763
90; 102.983; 90
1696.6Ye, Wei-Ping; Zhan, Jie; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis and Characterization of Titanium Complexes Bearing Two β-Enaminoketonato Ligands with Electron-Withdrawing Groups and Their Behavior in Ethylene Polymerization
Organometallics, 2008, 27, 3642
4070787 CIFC23 H56 O Si6P -19.33; 13.422; 14.544
82.699; 82.082; 71.186
1700.9Lim, Young Mook; Lee, Myong Euy
An Unexpected Ring Contraction: Phenylsilane to Silacyclopentane
Organometallics, 2008, 27, 1000
4071018 CIFC73 H62 Cl6 P4 Ru2P -110.793; 12.856; 13.174
96.96; 91.14; 109.87
1702.8Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071839 CIFC29 H29 B Cl2 N5 O3 P S2 WP -110.0313; 10.3673; 16.8936
95.5217; 90.9341; 102.745
1704.38Abernethy, Robyn J.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Tshabang, Never; Willis, Anthony C.; Young, Rowan D.
Poly(methimazolyl)borato Nitrosyl Complexes of Molybdenum and Tungsten
Organometallics, 2008, 27, 4455
4070786 CIFC23 H52 O Si6P -19.5333; 13.396; 14.371
82.678; 81.324; 70.564
1705Lim, Young Mook; Lee, Myong Euy
An Unexpected Ring Contraction: Phenylsilane to Silacyclopentane
Organometallics, 2008, 27, 1000
4070625 CIFC34 H62 Fe Si2P -19.9956; 11.2121; 17.1629
94.629; 95.3399; 115.613
1711.2Chong, Daesung; Geiger, William E.; Davis, Nathan A.; Weisbrich, Anke; Shi, Yifan; Arif, Atta M.; Ernst, Richard D.
Synthetic, Structural, and Electrochemical Studies of Edge-Bridged Open Ferrocenes
Organometallics, 2008, 27, 430
4071048 CIFC37 H32 N O2 P3 S2P -19.7483; 13.3566; 13.8758
87.933; 82.946; 72.76
1712.5Cadierno, Victorio; Díez, Josefina; García-Álvarez, Joaquín; Gimeno, José
(η6-Arene)−Ruthenium(II) Complexes Containing Methanide and Methandiide Anions of Ph2P(S)CH2P(NR)Ph2: Unprecedented Insertion of Isocyanide into a Ruthenium−Carbene Bond
Organometallics, 2008, 27, 1809
4070952 CIFC18 H17 Cl N2 O PdP -19.3629; 10.1302; 20.1619
97.107; 93.707; 114.448
1713.21Hadzovic, Alen; Song, Datong
Synthesis, Characterization, and Reactivity of a Versatile Dinuclear Palladium β-Diiminate Complex
Organometallics, 2008, 27, 1290
4070556 CIFC16 H27 Cl N3 RhP 1 21/c 110.3428; 13.0938; 12.7756
90; 97.251; 90
1716.3Jiménez, M. Victoria; Pérez-Torrente, Jesús J.; Bartolomé, M. Isabel; Gierz, Verena; Lahoz, Fernando J.; Oro, Luis A.
Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts
Organometallics, 2008, 27, 224
4072290 CIFC18 H18 N3 P SP 1 21/n 113.7417; 8.8007; 15.3125
90; 111.659; 90
1721.1Oshovsky, Gennady V.; Ouali, Armelle; Xia, Ning; Zablocka, Maria; Boeré, René T.; Duhayon, Carine; Taillefer, Marc; Majoral, Jean Pierre
Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media
Organometallics, 2008, 27, 5733
4071359 CIFC19 H26 Ir NP 1 21/n 18.612; 22.988; 9.451
90; 112.772; 90
1725Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071649 CIFC50 H34 Fe2P -110.7366; 11.7389; 14.6319
100.457; 95.144; 105.829
1725.8Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4070867 CIFC34 H58 B Ni P3P -110.4003; 11.84; 15.52
76.509; 88.116; 68.598
1727.4Fischbach, Andreas; Bazinet, Patrick R.; Waterman, Rory; Tilley, T. Don
β-Phosphinoethylboranes as Ambiphilic Ligands in Nickel−Methyl Complexes
Organometallics, 2008, 27, 1135
4072317 CIFC30 H50 N6 Si3 TiP -110.3113; 11.9118; 14.0949
92.133; 90.7564; 90.655
1729.75Selby, Jonathan D.; Manley, Catherine D.; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study
Organometallics, 2008, 27, 6479
4070988 CIFC33 H55 Ca N O4 Si2P 1 21 18.5176; 19.9843; 10.2846
90; 98.502; 90
1731.39He, Xuyang; Hurley, Erin; Noll, Bruce C.; Henderson, Kenneth W.
Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Organometallics, 2008, 27, 3094
4072299 CIFC39 H50 N P Ru SiP -19.487; 11.844; 16.851
98.505; 101.4; 107.029
1731.4Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4070814 CIFC18 H54 N4 P2 Si6P -18.724; 9.467; 23.224
84.51; 80.24; 66.53
1733.1Schaffrath, Markus; Villinger, Alexander; Michalik, Dirk; Rosenthal, Uwe; Schulz, Axel
Titanocene-Mediated Formation of Phosphorus−Phosphorus Bonds
Organometallics, 2008, 27, 1393
4071162 CIFC42 H36 Br2 N4 NiP 1 21/c 15.8346; 18.133; 16.3959
90; 91.495; 90
1734.08Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4072016 CIFC37 H32 Cl2 N2 Pt SiP -110.2345; 11.6447; 14.6854
97.484; 90.52; 91.588
1734.45West, Nathan M.; White, Peter S.; Templeton, Joseph L.
Alkyne Insertion into the Pt−H Bond of Pt(H)(1-pentene)(β-diiminate) Initiates a Reaction Cascade That Results in C−H Activation or C−C Coupling
Organometallics, 2008, 27, 5252
4083510 CIFC18 H20 N4 PtP 1 21 18.092; 20.908; 10.379
90; 98.975; 90
1734.5Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4070738 CIFC31 H59 Li2 N O3 Si2P 1 21 110.134; 17.794; 10.376
90; 112.011; 90
1734.7Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming
Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^
Organometallics, 2008, 27, 678-682
4071697 CIFC27 H48 B9 N4 O P TiP -110.1719; 10.4903; 18.1888
104.137; 91.393; 111.625
1735.48Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4071323 CIFC15 H24 B Cl2 Hf NP 1 21/n 18.7643; 13.545; 15.1449
90; 105.048; 90
1736.2Fang, Xiangdong; Assoud, Jalil
Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry
Organometallics, 2008, 27, 2408
4070870 CIFC29 H56 Lu N3 Si2P -19.613; 10.999; 17.249
87.576; 74.846; 80.946
1738.4Xu, Xin; Xu, Xiaoyan; Chen, Yaofeng; Sun, Jie
Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors
Organometallics, 2008, 27, 758
4071269 CIFC30 H50 Br2 N4 O2 Zn2P 1 21/c 17.8297; 10.2172; 21.8335
90; 95.325; 90
1739.1Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4070761 CIFC33 H39 F6 Ir N3 O2 P SP -110.363; 11.7165; 16.5434
72.085; 77.22; 66.401
1740.32Heiden, Zachariah M.; Gorecki, Bradford J.; Rauchfuss, Thomas B.
Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity
Organometallics, 2008, 27, 1542
4072091 CIFC33.5 H29 Cl N2 O9 Os3P -18.3651; 10.8743; 20.4975
80.968; 81.369; 71.935
1740.42Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4071223 CIFC20 H22 Cl2 TiP 1 21/c 16.6105; 21.534; 12.248
90; 93.12; 90
1740.9Sassmannshausen, Jörg; Baumgartner, Judith
Synthesis, Reactivity, and Computational Studies of [η5-C5H5-(η5-C5H4CMe2C6H4Me)TiMe]+: Aromatic C−H Bond Activation at −50 °C§
Organometallics, 2008, 27, 1996
4072131 CIFC14 H15 Cl N4 O3 WP -19.196; 14.033; 14.305
81.941; 81.338; 73.698
1742.2Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4071083 CIFC14 H8 F12 Fe P2C 1 2/c 117.536; 9.85; 12.428
90; 125.65; 90
1744.4Velazco, Euclides J.; Caffyn, Andrew J. M.; Le Goff, Xavier F.; Ricard, Louis
Synthesis, Structure, and Coordination Properties of 1,1′-Bis(bis(trifluoromethyl)phosphino)ferrocene, dfmpf
Organometallics, 2008, 27, 2402
4071460 CIFC28 H29 Cl4 N2 O7 Re S4P -18.684; 13.561; 16.668
112.251; 104.201; 91.12
1747.3Liu, Wei; Chen, Ya; Wang, Ru; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng
Rhenium(I) Tricarbonyl Complexes with New Pyridine Ligands Containing Crown Ether-Annelated or Anthracene-Functionalized 1,3-Dithiole-2-ylidene
Organometallics, 2008, 27, 2990
4071632 CIFC42 H41 B K2 O2P -112.98; 13.155; 13.21
106.095; 112.617; 108.978
1747.4So, Cheuk-Wai; Watanabe, Daisuke; Wakamiya, Atsushi; Yamaguchi, Shigehiro
Synthesis and Structural Characterization of Pentaarylboroles and Their Dianions
Organometallics, 2008, 27, 3496
4070765 CIFC33 H42 B F4 Ir N4 O2 SP -110.73; 10.8762; 15.795
94.397; 97.846; 105.071
1751.08Heiden, Zachariah M.; Gorecki, Bradford J.; Rauchfuss, Thomas B.
Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity
Organometallics, 2008, 27, 1542
4071274 CIFC15 H25 Cl2 P RuP 21 21 217.467; 13.096; 17.923
90; 90; 90
1752.7Aznar, Rosario; Muller, Guillermo; Sainz, Daniel; Font-Bardia, Mercè; Solans, Xavier
Synthesis and Reactivity of P-Chiral Tethered (η1:η6-phosphinoarene)ruthenium Complexes
Organometallics, 2008, 27, 1967
4070705 CIFC33 H26 Fe3 N O8 P S2P -111.09; 12.673; 14.953
89.762; 69.865; 64.38
1752.9Song, Li-Cheng; Wang, Hu-Ting; Ge, Jian-Hua; Mei, Shu-Zhen; Gao, Jie; Wang, Liang-Xing; Gai, Bin; Zhao, Li-Qun; Yan, Jing; Wang, Yong-Zhen
Investigations on the Active Site Models of [FeFe]-Hydrogenases: Synthesis, Structure, and Properties of N-Functionalized Azadithiolatodiiron Complexes Containing Mono- and Diphosphine Ligands
Organometallics, 2008, 27, 1409
4070694 CIFC27 H41 F12 Mo N8 P2P -111.5973; 12.5314; 14.8528
65.387; 70.003; 66.079
1754.5Petrovic, Dejan; Hrib, Cristian G.; Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands
Organometallics, 2008, 27, 778
4070871 CIFC29 H56 N3 Si2 SmP -19.5972; 11.0827; 17.2952
88.29; 75.119; 81.251
1757.1Xu, Xin; Xu, Xiaoyan; Chen, Yaofeng; Sun, Jie
Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors
Organometallics, 2008, 27, 758
4072195 CIFC34 H58 Li2 N4 O2P n n 216.4657; 12.1496; 8.7833
90; 90; 90
1757.11Armstrong, David R.; Drummond, Allison M.; Balloch, Liam; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Metalation of 2,4,6-Trimethylacetophenone Using Organozinc Reagents: The Role of the Base in Determining Composition and Structure of the Developing Enolate
Organometallics, 2008, 27, 5860
4071799 CIFC19 H11 Cl N O2 Rh SP 1 21/c 112.494; 11.358; 13.889
90; 116.917; 90
1757.4Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4071390 CIFC17 H26 N3 Rh SP 1 21/n 111.936; 8.874; 16.722
90; 97.1; 90
1757.6Gil, Wojciech; Trzeciak, Anna M.; Ziółkowski, Józef J.
Rhodium(I) N-Heterocyclic Carbene Complexes as Highly Selective Catalysts for 1-Hexene Hydroformylation
Organometallics, 2008, 27, 4131
4083499 CIFC28 H34 Cl8 Ir2 O4P 1 21/c 111.189; 20.083; 8.224
90; 107.958; 90
1758Han, Ying-Feng; Lin, Yue-Jian; Jia, Wei-Guo; Jin, Guo-Xin
Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†
Organometallics, 2008, 27, 4088
4072061 CIFC40 H48 Fe N3 O2P -111.8995; 12.17; 14.3484
70.793; 89.882; 65.349
1761.1Trovitch, Ryan J.; Lobkovsky, Emil; Bouwkamp, Marco W.; Chirik, Paul J.
Carbon−Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C−O Bond Cleavage in Esters
Organometallics, 2008, 27, 6264
4071499 CIFC39.5 H34 B F10 Ir N2P -19.378; 11.921; 17.189
70.04; 79.63; 79.52
1761.6Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4071601 CIFC34 H29 As2 B F9 N PdP -110.91; 11.633; 16.125
98.501; 97.285; 116.804
1763Casares, Juan A.; Espinet, Pablo; Salas, Gorka
Palladium Catalysts for Norbornene Polymerization. A Study by NMR and Calorimetric Methods
Organometallics, 2008, 27, 3761
4071059 CIFC41.5 H39 Cl2 N O TiP -110.2441; 14.2527; 14.5183
62.46; 75.719; 70.775
1763.42Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071959 CIFC22 H21 Cl ZrP 1 21/c 19.2398; 10.7676; 18.156
90; 102.353; 90
1764.5Alonso-Moreno, Carlos; Lancaster, Simon J.; Wright, Joseph A.; Hughes, David L.; Zuccaccia, Cristiano; Correa, Andrea; Macchioni, Alceo; Cavallo, Luigi; Bochmann, Manfred
Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)
Organometallics, 2008, 27, 5474
4071122 CIFC16 H25 Ir N2 O2 SP -110.2477; 10.89; 15.8653
89.3335; 85.4925; 88.7271
1764.53Schaub, Thomas; Radius, Udo; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium
Organometallics, 2008, 27, 1892
4071121 CIFC16 H25 N2 O2 Rh SP -110.2627; 10.8734; 15.8663
89.5308; 85.4696; 88.7646
1764.55Schaub, Thomas; Radius, Udo; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium
Organometallics, 2008, 27, 1892
4072018 CIFC13 H20 Cl3 Cr N4 SP 21 21 219.233; 12.9405; 14.769
90; 90; 90
1764.6Zhang, Jun; Braunstein, Pierre; Hor, T. S. Andy
Highly Selective Chromium(III) Ethylene Trimerization Catalysts with [NON] and [NSN] Heteroscorpionate Ligands
Organometallics, 2008, 27, 4277
4070872 CIFC29 H56 N3 Nd Si2P -19.6033; 11.1048; 17.3163
88.372; 75.294; 81.282
1765.4Xu, Xin; Xu, Xiaoyan; Chen, Yaofeng; Sun, Jie
Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors
Organometallics, 2008, 27, 758
4071900 CIFC34 H36 Cl6 N O2 Os PP 111.3914; 12.7982; 13.092
90.109; 107.61; 103.228
1765.7Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4071838 CIFC11 H15 B Mo N5 O3.5 S2P n n m17.4413; 6.7479; 15.0143
90; 90; 90
1767.07Abernethy, Robyn J.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Tshabang, Never; Willis, Anthony C.; Young, Rowan D.
Poly(methimazolyl)borato Nitrosyl Complexes of Molybdenum and Tungsten
Organometallics, 2008, 27, 4455
4072066 CIFC32 H52 Cr N4 P2P 1 21/n 19.201; 21.91; 9.597
90; 113.947; 90
1768Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Duchateau, Robbert; Koç, Ece; Burchell, Tara J.
Preparation and Characterization of a Switchable Single-Component Chromium Trimerization Catalyst
Organometallics, 2008, 27, 5708
4071498 CIFC37 H32 B Cl2 F10 N2 RhP -19.319; 11.981; 17.343
109.96; 94.35; 100.45
1769.9Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4072163 CIFC30.7 H35.4 B Cl1.4 F4 N6 O4 Rh2P 1 21 18.1512; 15.89; 13.803
90; 97.983; 90
1770.5Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4071642 CIFC25 H18 Fe OP -111.1696; 12.1768; 14.8291
70.257; 76.117; 70.514
1771.11Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4070869 CIFC29 H56 N3 Si2 YP -19.6359; 11.092; 17.373
87.918; 75.102; 81.202
1773.3Xu, Xin; Xu, Xiaoyan; Chen, Yaofeng; Sun, Jie
Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors
Organometallics, 2008, 27, 758
4071569 CIFC22 H49 B9 Cl2 Li O6 ZrP -18.8238; 13.7493; 15.3256
74.175; 89.627; 82.88
1774.3Wang, Yaorong; Liu, Dongmei; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me2C(C5H4)(C2B9H10)]3−
Organometallics, 2008, 27, 2825
4071006 CIFC69 H86 Cl6 Mn2 Mo4 O10 P2P -19.1962; 12.467; 15.803
101.45; 91.795; 90.698
1774.6García-Vivó, Daniel; García, M. Esther; Ruiz, Miguel A.
Multisite Reactivity of the Unsaturated Methoxycarbyne Complex [Mo2(η5-C5H5)2(µ-COMe)(µ-PCy2)(µ-CO)]
Organometallics, 2008, 27, 169
4070619 CIFC14 H24 Cl2 N Ni O PP 1 21/n 18.877; 17.116; 12.018
90; 102.727; 90
1781.14Kermagoret, Anthony; Braunstein, Pierre
Mono- and Dinuclear Nickel Complexes with Phosphino-, Phosphinito-, and Phosphonitopyridine Ligands: Synthesis, Structures, and Catalytic Oligomerization of Ethylene
Organometallics, 2008, 27, 88
4071353 CIFC35 H38 Cl5 N5 TiP 1 21 112.117; 10.836; 14.5802
90; 111.287; 90
1783.8Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071988 CIFC28 H38 Br Li Mn2 N4 O10P 19.8143; 13.4117; 14.9784
88.404; 75.817; 69.459
1786.3Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4070943 CIFC39 H33 Cl2 N2 O P Ru S2P -111.017; 12.958; 13.858
113.835; 91.729; 96.604
1791.2Armitt, David J.; Bruce, Michael I.; Skelton, Brian W.; White, Allan H.
Reactions of Alkynyl−Ruthenium Complexes with the Ketene Dithioacetal, (MeS)2CC(CN)2
Organometallics, 2008, 27, 3556
4071958 CIFC23 H24 HfP 1 21/c 19.3987; 10.7366; 18.2206
90; 102.011; 90
1798.4Alonso-Moreno, Carlos; Lancaster, Simon J.; Wright, Joseph A.; Hughes, David L.; Zuccaccia, Cristiano; Correa, Andrea; Macchioni, Alceo; Cavallo, Luigi; Bochmann, Manfred
Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)
Organometallics, 2008, 27, 5474
4071463 CIFC21 N2P 110.143; 11.374; 16.292
87.179; 86.37; 73.739
1799.77Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4072098 CIFC18 H19 O5 PP n a 2119.555; 12.571; 7.3292
90; 90; 90
1801.7Duan, Zheng; Zhang, Jianzhen; Tian, Rongqiang; Bai, Liuying; Mathey, Francois
Reinvestigation of the Reactions of 1-Phenyl-3,4-dimethylphosphole with Dimethyl Acetylenedicarboxylate
Organometallics, 2008, 27, 5169
4072081 CIFC31 H24 Ag Cl N2 O10 Os3P -18.1388; 12.5307; 18.048
93.746; 97.217; 97.567
1803.9Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4071560 CIFC30 H42 F10 O6 Ti2P 1 21/n 18.969; 16.822; 12.0463
90; 96.564; 90
1805.6Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4072251 CIFC82 H92 Fe2 N8 Ni4P -110.9417; 11.8878; 14.2357
79.239; 83.872; 89.668
1808.5Tan, Weiqiang; Yu, Zhengkun; He, Wei; Wang, Liandi; Sun, Jie; Chen, Jinzhu
A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH2)2-Bridged Bis(pyrazole)
Organometallics, 2008, 27, 4833
4083498 CIFC28 H62 Na O5 Si3P -111.268; 11.625; 15.315
71.941; 78.913; 72.57
1808.75Inoue, Shigeyoshi; Ichinohe, Masaaki; Sekiguchi, Akira
Isolable Alkali-Metal-Substituted Silyl Radicals (tBu2MeSi)2SiM (M = Li, Na, K): Electronically and Sterically Accessible Planar Silyl Radicals
Organometallics, 2008, 27, 1358
4072078 CIFC36 H50 N3 Sc Si2P -110.0455; 10.5478; 18.0428
84.01; 82.35; 73.292
1810.4Gao, Wei; Cui, Dongmei; Liu, Xiaoming; Zhang, Yu; Mu, Ying
Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of ε-Caprolactone
Organometallics, 2008, 27, 5889
4071980 CIFC45 H45 O ZrP -111.3794; 12.5637; 14.6962
70.816; 67.903; 74.723
1815Manz, Thomas A.; Sharma, Shalini; Phomphrai, Khamphee; Novstrup, Krista A.; Fenwick, Andrew E.; Fanwick, Phillip E.; Medvedev, Grigori A.; Abu-Omar, Mahdi M.; Delgass, W. Nicholas; Thomson, Kendall T.; Caruthers, James M.
Quantitative Effects of Ion Pairing and Sterics on Chain Propagation Kinetics for 1-Hexene Polymerization Catalyzed by Mixed Cp′/ArO Complexes
Organometallics, 2008, 27, 5504
4071224 CIFC22 H28 TiP 1 21/n 16.9748; 12.204; 21.448
90; 94.9; 90
1819Sassmannshausen, Jörg; Baumgartner, Judith
Synthesis, Reactivity, and Computational Studies of [η5-C5H5-(η5-C5H4CMe2C6H4Me)TiMe]+: Aromatic C−H Bond Activation at −50 °C§
Organometallics, 2008, 27, 1996
4071877 CIFC28.5 H57.8 B Cl2 F4 O2 Os P2P -17.89; 15.363; 16.115
71.071; 82.244; 82.111
1821.7Buil, María L.; Esteruelas, Miguel A.; Garcés, Karin; Oliván, Montserrat; Oñate, Enrique
Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands
Organometallics, 2008, 27, 4680
4072080 CIFC36 H50 Lu N3 Si2P -110.102; 10.6056; 17.9299
84.109; 81.755; 74.098
1824.3Gao, Wei; Cui, Dongmei; Liu, Xiaoming; Zhang, Yu; Mu, Ying
Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of ε-Caprolactone
Organometallics, 2008, 27, 5889
4071651 CIFC50 H34 Cl2 Fe2P -18.5593; 12.884; 17.537
74.723; 79.113; 84.303
1829.5Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4070998 CIFC38 H57 O2 P Ru Si2P -110.1305; 10.3795; 19.2411
98.116; 92.896; 112.966
1831.8Okazaki, Masaaki; Yamahira, Nobukazu; Minglana, Jim Josephus Gabrillo; Komuro, Takashi; Ogino, Hiroshi; Tobita, Hiromi
[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
Organometallics, 2008, 27, 918
4072103 CIFC24 H22 O2P -17.6847; 9.6434; 25.397
84.277; 78.835; 89.807
1837Yeh, Ming-Chang P.; Tsao, Wen-Cheng; Lee, Bo-Jen; Lin, Tzu-Ling
Facile Synthesis of Carbotetracycles via Gold(I)-Catalyzed Cyclization of Unactivated Cyclic 1-Aryl-6,8-dien-1-ynes
Organometallics, 2008, 27, 5326
4071325 CIFC18 H13 Cl F3 Ir N2 O2P 1 21/c 114.2118; 8.7062; 15.8811
90; 110.789; 90
1837.05Song, Guoyong; Zhang, Yao; Li, Xingwei
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
Organometallics, 2008, 27, 1936
4071072 CIFC18 H31 N O WP 1 21/c 110.651; 11.5052; 15.1007
90; 96.778; 90
1837.54Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4070530 CIFC10 H12 Br6 O Zr2P 1 21/n 110.5696; 16.7523; 11.6071
90; 116.499; 90
1839.3Glöckner, Andreas; Arif, Atta M.; Ernst, Richard D.
Isolation and Characterization of Bromination Products of Zr(C5H5)2Br2
Organometallics, 2008, 27, 327
4071910 CIFC31 H52 O7 Os3 P2 PtP -18.8502; 13.7431; 15.6238
95.218; 95.758; 101.06
1843.8Adams, Richard D.; Boswell, Erin M.; Hall, Michael B.; Yang, Xinzheng
Activation of Hydrogen and Related Small Molecules by the Unsaturated Cluster Complex PtOs3(CO)7(PBut3)(μ-PBut2)(μ4-CHCMeCH)
Organometallics, 2008, 27, 4938
4071719 CIFC19 H29 N2 VP 1 21/c 113.38; 11.0573; 13.949
90; 116.596; 90
1845.3Bouwkamp, Marco W.; Batinas, Aurora A.; Witte, Peter T.; Hubregtse, Ton; Dam, Jeroen; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Relative Reactivity of the Metal−Amido versus Metal−Imido Bond in Linked Cp-Amido and Half-Sandwich Complexes of Vanadium
Organometallics, 2008, 27, 4071
4072390 CIFC40.5 H58 Mo N4P -19.468; 10.102; 20.072
92.682; 102.986; 97.859
1847.1Marinescu, Smaranda C.; Singh, Rojendra; Hock, Adam S.; Wampler, Keith M.; Schrock, Richard R.; Müller, Peter
Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes
Organometallics, 2008, 27, 6570
4071882 CIFC38.5 H40 Cl3 Fe2 N3 O4P -111.013; 11.506; 14.818
94.56; 93.89; 95.94
1856.2Busetto, Luigi; Marchetti, Fabio; Zacchini, Stefano; Zanotti, Valerio
Addition of Isocyanides at Diiron μ-Vinyliminium Complexes: Synthesis of Novel Ketenimine−Bis(alkylidene) Complexes
Organometallics, 2008, 27, 5058
4083496 CIFC34.5 H61 Cl N6 O P2 RuP -110.1217; 11.7586; 15.8825
94.871; 90.261; 99.551
1857.02Dutta, Barnali; Scolaro, Claudine; Scopelliti, Rosario; Dyson, Paul J.; Severin, Kay
Importance of the π-Ligand: Remarkable Effect of the Cyclopentadienyl Ring on the Cytotoxicity of Ruthenium PTA Compounds
Organometallics, 2008, 27, 1355
4071470 CIFC22 H28 N2P n m a9.87; 22.911; 8.2427
90; 90; 90
1863.9Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4070856 CIFC19 H16 F4 Ir N O3C 1 2/m 113.3143; 8.8432; 16.7447
90; 108.601; 90
1868.6Ke Chan, Pek; Kee Leong, Weng
Reaction of Cp*Ir(CO)2with Activated Perfluoroaromatic Compounds: Formation of Metallocarboxylic Acids via Aromatic Nucleophilic Substitution
Organometallics, 2008, 27, 1247
4070512 CIFC31 H42 B8 I2 O P2 PtP -110.086; 11.493; 17.784
77.85; 74.33; 71.97
1869.2Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4071058 CIFC50.5 H34 Cl2 O TiP -19.5715; 12.8182; 16.3538
92.982; 95.251; 109.988
1870.2Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4072394 CIFC45 H49 Mo N3P -19.6278; 11.405; 17.323
86.603; 81.86; 84.473
1872.23Marinescu, Smaranda C.; Singh, Rojendra; Hock, Adam S.; Wampler, Keith M.; Schrock, Richard R.; Müller, Peter
Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes
Organometallics, 2008, 27, 6570
4071147 CIFC43 H49 N Ni P2P -111.1581; 13.0512; 13.3333
78.43; 81.972; 83.135
1875.19Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071270 CIFC32 H52 Br2 N2 O4 Zn2P 1 21/c 111.7235; 9.287; 17.3462
90; 96.592; 90
1876.1Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071557 CIFC18 H20 Cl2 N4 PdP 1 21/c 110.5073; 13.1943; 14.06
90; 105.395; 90
1879.3Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071155 CIFC46 H48 N2 Ni O2 P SP -19.381; 10.605; 19.553
76.759; 88.739; 83.266
1880Li, Jianfeng; Tian, Dawei; Song, Haibin; Wang, Chunhua; Zhu, Xiaoqing; Cui, Chunming; Cheng, Jin-Pei
Synthesis, Structures, and Reactivity of Nickel Complexes Incorporating Sulfonamido-Imine Ligands
Organometallics, 2008, 27, 1605
4072185 CIFC14 H15 Al F12 N2 O3P 1 21/n 111.0304; 13.3518; 13.8804
90; 112.863; 90
1883.6Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4071392 CIFC36 H60 Al2 N2 TiP -19.772; 10.029; 20.808
87.45; 87.38; 67.78
1885Nikiforov, Grigory B.; Roesky, Herbert W.; Heisen, Burkhard C.; Oswald, Rainer B.
Formation of a Titanium Complex with a TiCHAl2Structural Unit from LTiMe3and Trimethylaluminum§
Organometallics, 2008, 27, 2544
4070754 CIFC11 H19 B10 Co O2 Se2P 1 21/c 16.6368; 21.23; 13.4715
90; 96.437; 90
1886.2Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4071855 CIFC16 H26 N2 Si2 ZrP 1 21/c 18.7632; 27.233; 8.4558
90; 110.744; 90
1887.1Wang, Cun; Luo, He-Kuan; van Meurs, Martin; Stubbs, Ludger P.; Wong, Pui-Kwan
The New Tridentate Ligand CpSiNSiCp and Its Zirconium Complexes: Incorporation of Two Bridged Constrained-Geometry Units into One Molecule
Organometallics, 2008, 27, 2908
4072369 CIFC22 H17 B2 F4 FeP 1 21/c 19.7741; 7.6859; 25.183
90; 92.787; 90
1889.6Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4070613 CIFC44 H38 B N2 O P2 RhP -111.6962; 11.7252; 14.5351
95.812; 94.505; 106.179
1892.63Wagler, Jörg; Hill, Anthony F.
7-Azaindol-7-ylborate: A Novel Bidentate N^BH3Chelating Ligand
Organometallics, 2008, 27, 2350
4071998 CIFC22 H23 Al OP 1 21/c 19.5777; 12.781; 16.0315
90; 105.089; 90
1894.8Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4071707 CIFC36 H56 Fe2 N4 P4 WP -110.3251; 12.9548; 16.0045
68.5308; 75.0976; 75.3906
1895.23Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki; Wakiji, Issei; Hidai, Masanobu
Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Organometallics, 2008, 27, 3947
4070945 CIFC20 H16 N2 O Ru S2P 1 21/c 110.481; 17.294; 10.778
90; 103.73; 90
1897.8Armitt, David J.; Bruce, Michael I.; Skelton, Brian W.; White, Allan H.
Reactions of Alkynyl−Ruthenium Complexes with the Ketene Dithioacetal, (MeS)2CC(CN)2
Organometallics, 2008, 27, 3556
4071490 CIFC42 H50 Fe2 Li2 N2 OP -110.9229; 12.9582; 13.9885
75.41; 84.683; 83.606
1899.88Chen, Chao; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Structural Features of Lithio[3]ferrocenophane Systems Bearing Stabilizing Dimethylamino Substituents
Organometallics, 2008, 27, 3248
4070873 CIFC32 H60 N3 Si2 YP -110.989; 11.935; 14.662
89.934; 84.979; 82.763
1900.2Xu, Xin; Xu, Xiaoyan; Chen, Yaofeng; Sun, Jie
Dialkyllanthanide Complexes Containing New Tridentate Monoanionic Ligands with Nitrogen Donors
Organometallics, 2008, 27, 758
4071708 CIFC36 H56 Fe2 Mo N4 P4P -110.3341; 12.9756; 16.0505
68.4688; 75.0902; 75.3883
1904.58Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki; Wakiji, Issei; Hidai, Masanobu
Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Organometallics, 2008, 27, 3947
4071403 CIFC47 H41 P2 RhP -110.2753; 11.0726; 17.1524
90.769; 99.159; 98.058
1906.3Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071999 CIFC22 H25 Al OP 1 21/c 112.126; 7.552; 21.1946
90; 100.231; 90
1910.05Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4072392 CIFC42 H61 Mo N3P -19.8591; 12.2228; 17.486
90.304; 102.933; 110.709
1912.8Marinescu, Smaranda C.; Singh, Rojendra; Hock, Adam S.; Wampler, Keith M.; Schrock, Richard R.; Müller, Peter
Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes
Organometallics, 2008, 27, 6570
4070944 CIFC20 H16 N2 O Ru S2P 1 21/c 111.2373; 14.751; 11.6038
90; 95.161; 90
1915.66Armitt, David J.; Bruce, Michael I.; Skelton, Brian W.; White, Allan H.
Reactions of Alkynyl−Ruthenium Complexes with the Ketene Dithioacetal, (MeS)2CC(CN)2
Organometallics, 2008, 27, 3556
4071020 CIFC39 H38 Cl4 N2 P2 RuP -111.61; 12.953; 13.189
78.39; 80.52; 86.84
1915.8Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071408 CIFC33 H50 Cl4 O Os P4P -111.1653; 12.7631; 13.6141
87.747; 85.366; 83.153
1919.06Gong, Lei; Lin, Yumei; Wen, Ting Bin; Zhang, Hong; Zeng, Birong; Xia, Haiping
Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
Organometallics, 2008, 27, 2584
4070907 CIFC38 H47 N3 P2 Si2 ZnP -111.924; 12.2017; 14.1673
87.485; 69.713; 83.888
1922.3Chai, Zuo-Yun; Zhang, Cheng; Wang, Zhong-Xia
Synthesis, Characterization, and Catalysis in ϵ-Caprolactone Polymerization of Aluminum and Zinc Complexes Supported byN,N,N-Chelate Ligands
Organometallics, 2008, 27, 1626
4071619 CIFC18 H32 P2P 1 21/c 110.2911; 8.0562; 23.5323
90; 99.591; 90
1923.73Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4071665 CIFC16 H38 Ni P2C 1 2/c 112.837; 8.514; 17.74
90; 96.954; 90
1924.6Dubinina, Galyna G.; Brennessel, William W.; Miller, Jennifer L.; Vicic, David A.
Exploring Trifluoromethylation Reactions at Nickel: A Structural and Reactivity Study
Organometallics, 2008, 27, 3933
4072011 CIFC20 H19 I Pd S2P 1 21/c 112.8519; 13.564; 11.3059
90; 102.352; 90
1925.3Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4071585 CIFC51 H44 Fe2 O2P -110.14; 15.103; 15.293
117.633; 91.536; 108.432
1926.1Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4072012 CIFC16 H27 I Pd S2P n a 2117.195; 11.49; 9.75
90; 90; 90
1926.3Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4071720 CIFC46 H54 B N2 O VP -19.2873; 12.827; 16.83
93.63; 94.974; 104.1
1929.8Bouwkamp, Marco W.; Batinas, Aurora A.; Witte, Peter T.; Hubregtse, Ton; Dam, Jeroen; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Relative Reactivity of the Metal−Amido versus Metal−Imido Bond in Linked Cp-Amido and Half-Sandwich Complexes of Vanadium
Organometallics, 2008, 27, 4071
4071985 CIFC40 H56 B4 N8P 1 21/c 111.585; 11.753; 14.228
90; 92.957; 90
1934.7Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071483 CIFC18 H30 N2 ZnP -110.4058; 14.1317; 14.986
61.934; 85.505; 89.357
1937.8Clegg, William; García-Álvarez, Joaquín; García-Álvarez, Pablo; Graham, David V.; Harrington, Ross W.; Hevia, Eva; Kennedy, Alan R.; Mulvey, Robert E.; Russo, Luca
Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†
Organometallics, 2008, 27, 2654
4071413 CIFC20 H33 Mo N OP 1 21/c 113.1444; 9.1621; 16.758
90; 106.02; 90
1939.8Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071069 CIFC19 H33 N O WP 1 21/c 19.0412; 14.243; 15.6092
90; 105.103; 90
1940.63Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4072102 CIFC25 H24 O4P 1 21/c 114.7813; 7.3153; 17.9908
90; 93.613; 90
1941.47Yeh, Ming-Chang P.; Tsao, Wen-Cheng; Lee, Bo-Jen; Lin, Tzu-Ling
Facile Synthesis of Carbotetracycles via Gold(I)-Catalyzed Cyclization of Unactivated Cyclic 1-Aryl-6,8-dien-1-ynes
Organometallics, 2008, 27, 5326
4071462 CIFC23 H30 N2P 21 21 218.3994; 10.519; 22.0339
90; 90; 90
1946.8Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4070727 CIFC43 H63 Al N2 O3P -19.0526; 12.0803; 18.727
73.667; 82.399; 86.187
1947.1Yang, Ying; Schulz, Thomas; John, Michael; Yang, Zhi; Jiménez-Pérez, Victor Manuel; Roesky, Herbert W.; Gurubasavaraj, Prabhuodeyara M.; Stalke, Dietmar; Ye, Hongqi
Organoaluminum Hydroxides Supported by β-Diketiminato Ligands: Synthesis, Structural Characterization, and Reactions
Organometallics, 2008, 27, 769
4072181 CIFC38.5 H66 Mo N2P -19.82; 14.543; 15.017
94.018; 105.146; 107.555
1947.7Lokare, Kapil S.; Staples, Richard J.; Odom, Aaron L.
Synthesis, Properties, and Structure of Tethered Molybdenum Alkylidenes
Organometallics, 2008, 27, 5130
4071961 CIFC70 H86 Ag4 F12 N12 O4 P2P -112.5681; 12.9967; 14.3012
63.361; 68.893; 80.629
1947.95Scheele, Ulrich J.; Georgiou, Maria; John, Michael; Dechert, Sebastian; Meyer, Franc
Combining Pyrazolate and N-Heterocyclic Carbene Coordination Motifs: Synthesis and Characterization of a Double-Crowned Silver Complex
Organometallics, 2008, 27, 5146
4071880 CIFC14 H30 Cl N Pt Si2P 1 21/n 18.513; 9.243; 25.006
90; 97.385; 90
1951.29Arunachalampillai, Athimoolam; Johnson, Magnus T.; Wendt, Ola F.
Synthesis of a Platinum(II) Bis(trimethylsilyl)amido Complex: A Better Starting Material for the Cyclometalation of Pincer Ligands
Organometallics, 2008, 27, 4541
4071373 CIFC47 H57 N O2 TiP -111.2513; 13.1612; 13.7639
76.075; 81.769; 84.868
1954.68Agapie, Theodor; Henling, Lawrence M.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Bercaw, John E.
Zirconium and Titanium Complexes Supported by Tridentate LX2Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization
Organometallics, 2008, 27, 6245
4071469 CIFC21 H19 F6 N2 PP 1 21/n 112.038; 12.986; 12.608
90; 97.311; 90
1954.9Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4070503 CIFC11 H30 B8 N2 PtP n m a11.6161; 17.703; 9.5129
90; 90; 90
1956.2Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4070862 CIFC36 H46 F12 O4 P2 Ru2P 1 21 17.362; 12.5244; 21.2886
90; 92.984; 90
1960.25Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4072089 CIFC40 H33 N2 O10 Os4P -112.3074; 12.6819; 14.7598
74.792; 87.235; 62.317
1961.26Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4070614 CIFC47 H46 B N2 O P2 RhP -110.5388; 12.5141; 15.3891
95.952; 95.274; 101.739
1963.05Wagler, Jörg; Hill, Anthony F.
7-Azaindol-7-ylborate: A Novel Bidentate N^BH3Chelating Ligand
Organometallics, 2008, 27, 2350
4071404 CIFC18 H28 Cl3 N Os2P 1 21/c 115.4555; 9.2944; 13.939
90; 100.518; 90
1968.7Esteruelas, Miguel A.; García-Yebra, Cristina; Oñate, Enrique
[H(EtOH)2][{OsCl(η4-COD)}2(μ-H)(μ-Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]xand Its Activity as an Ionic Hydrogenation and Etherification Catalyst
Organometallics, 2008, 27, 3029
4071376 CIFC46 H56 O3 TiP -19.566; 14.1; 15.1
85.053; 76.411; 85.591
1968.9Agapie, Theodor; Henling, Lawrence M.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Bercaw, John E.
Zirconium and Titanium Complexes Supported by Tridentate LX2Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization
Organometallics, 2008, 27, 6245
4071487 CIFC43 H44 O5 P2 WP -111.3216; 13.2755; 14.5331
70.009; 78.96; 75.101
1970.75Jansen, Helen; Rosenthal, Amos J.; Slootweg, J. Chris; Ehlers, Andreas W.; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop
Diastereoselective Formation of Complexed Methylenediphosphiranes
Organometallics, 2008, 27, 2868
4071482 CIFC22 H26 N2 ZnP 1 21/c 111.6198; 9.6815; 18.3865
90; 107.61; 90
1971.5Clegg, William; García-Álvarez, Joaquín; García-Álvarez, Pablo; Graham, David V.; Harrington, Ross W.; Hevia, Eva; Kennedy, Alan R.; Mulvey, Robert E.; Russo, Luca
Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†
Organometallics, 2008, 27, 2654
4070749 CIFC40 H48 Cl2 P2 Pd2P 1 21/n 19.2167; 12.9557; 16.6165
90; 95.89; 90
1973.68Yan, Xiaoyu; Xi, Chanjuan
Synthesis and Characterization of Novel Four-Membered Palladacycles
Organometallics, 2008, 27, 152
4072238 CIFC22 H33 Cl TiP -415.3776; 15.3776; 8.3838
90; 90; 90
1982.52Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4071043 CIFC41 H60 N O3 P2 RhP -110.3991; 11.5735; 18.0621
101.4; 91.9941; 110.495
1983.22Hanson, Susan Kloek; Heinekey, D. Michael; Goldberg, Karen I.
C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water
Organometallics, 2008, 27, 1454
4071571 CIFC29 H57 B9 Cl Na O6 ZrP -110.5338; 13.4462; 15.1478
105.486; 105.523; 90.742
1983.97Wang, Yaorong; Liu, Dongmei; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me2C(C5H4)(C2B9H10)]3−
Organometallics, 2008, 27, 2825
4070602 CIFC32 H35 B Cl5 N6 P Pt S3P -19.7438; 12.9979; 17.1896
109.965; 101.305; 93.5646
1986.73Crossley, Ian R.; Hill, Anthony F.; Willis, Anthony C.
Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10(mt = Methimazolyl)
Organometallics, 2008, 27, 312
4071153 CIFC23 H18 Cl N2 Ni PP n a 2118.787; 8.8927; 11.8928
90; 90; 90
1986.9Han, Fu-Bin; Zhang, Yu-Liang; Sun, Xiu-Li; Li, Bao-Guo; Guo, Yang-Hui; Tang, Yong
Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization
Organometallics, 2008, 27, 1924
4071955 CIFC50 H43 N3 O4P 1 21 111.699; 10.6226; 16.698
90; 106.573; 90
1988.9Matsuzawa, Hiroshi; Tanabe, Yoshiaki; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Synthesis of Optically ActiveN,N,N′,N′-Tetraphenyl-1,1′-binaphthyl-2,2′-diamine Derivatives as Analogues of BINAP
Organometallics, 2008, 27, 4021
4071286 CIFC45 H44 Cl3 N O2 P RhP 1 21 111.234; 11.493; 15.8389
90; 103.231; 90
1990.7Filipuzzi, Serena; Männel, Elisabeth; Pregosin, Paul S.; Albinati, Alberto; Rizzato, Silvia; Veiros, Luis F.
Multinuclear NMR, X-ray, and DFT Studies on RhCl(diene)(phosphoramidite) Complexes
Organometallics, 2008, 27, 4580
4071414 CIFC21 H33 Mo N OP 1 21/c 18.9342; 13.7757; 16.5414
90; 101.191; 90
1997.1Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071071 CIFC18 H33 N O Si WP 1 21/c 19.4739; 13.991; 15.631
90; 105.378; 90
1997.7Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4071152 CIFC23 H18 Br N2 Ni PP n a 2118.8941; 8.8776; 11.9195
90; 90; 90
1999.3Han, Fu-Bin; Zhang, Yu-Liang; Sun, Xiu-Li; Li, Bao-Guo; Guo, Yang-Hui; Tang, Yong
Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization
Organometallics, 2008, 27, 1924
4070766 CIFC27 H22 N2 PtP n m a19.8057; 18.9645; 5.3313
90; 90; 90
2002.46De Crisci, Antonio G.; Lough, Alan J.; Multani, Kanwarpal; Fekl, Ulrich
9,10-Dihydroplatinaanthracenes with Aromatic Diimine Ligands: Syntheses and Spectroscopic and Computational Studies of New Luminescent Materials
Organometallics, 2008, 27, 1765
4071331 CIFC34 H41.5 I3 N8.5 RhP -111.2799; 12.3517; 15.2258
102.957; 101.685; 94.4
2007.85Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4072130 CIFC32 H48 Cl4 N4 O3 Sn2 WP -110.6878; 12.4245; 17.41
74.486; 75.947; 65.769
2008Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4071145 CIFC48 H51 N Ni O P2P -110.852; 12.986; 15.941
108.973; 95.631; 105.171
2008.66Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071691 CIFC50 H44 O P2 RuP -113.898; 15.542; 10.008
96.38; 110.6; 88.54
2010.8Hirano, Masafumi; Kuga, Toshinori; Kitamura, Mariko; Kanaya, Susumu; Komine, Nobuyuki; Komiya, Sanshiro
Acid-Promoted Hydrogen Migration in (2-Allylphenoxo)ruthenium(II) To Form an η3-Allyl Complex
Organometallics, 2008, 27, 3635
4071978 CIFC20 H29 Br O TiP 1 21/c 114.5885; 8.0976; 17.6573
90; 105.287; 90
2012.1Manz, Thomas A.; Sharma, Shalini; Phomphrai, Khamphee; Novstrup, Krista A.; Fenwick, Andrew E.; Fanwick, Phillip E.; Medvedev, Grigori A.; Abu-Omar, Mahdi M.; Delgass, W. Nicholas; Thomson, Kendall T.; Caruthers, James M.
Quantitative Effects of Ion Pairing and Sterics on Chain Propagation Kinetics for 1-Hexene Polymerization Catalyzed by Mixed Cp′/ArO Complexes
Organometallics, 2008, 27, 5504
4072090 CIFC38.5 H29 Cl N2 O10 Os4P -112.3075; 12.7131; 15.1134
73.738; 86.774; 62.89
2013.66Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4072388 CIFC20 H29 Cl N2 PdP 1 21/n 110.854; 15.446; 12.618
90; 107.6; 90
2016.4Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4070617 CIFC16 H12 N4 O8 Re2P c c n12.0644; 14.0753; 11.8832
90; 90; 90
2017.89Wu, Jing-Yun; Thanasekaran, P.; Cheng, Yi-Wei; Lee, Chung-Chou; Manimaran, B.; Rajendran, T.; Liao, Rong-Tang; Lee, Gene-Hsiang; Peng, Shie-Ming; Lu, Kuang-Lieh
Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles
Organometallics, 2008, 27, 2141
4071769 CIFC35 H40 Mo4 O4 S6P 1 21/c 116.083; 10.1516; 13.2453
90; 110.9; 90
2020.3Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071324 CIFC23 H26 Cl N2 RhP 1 21/c 115.6914; 8.8419; 14.6448
90; 95.747; 90
2021.63Song, Guoyong; Zhang, Yao; Li, Xingwei
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
Organometallics, 2008, 27, 1936
4071740 CIFC42 H42 O2 P2 S4 U2P 1 21/c 112.8051; 9.1321; 17.4375
90; 96.989; 90
2023.9Arliguie, Thérèse; Blug, Matthias; Le Floch, Pascal; Mézailles, Nicolas; Thuéry, Pierre; Ephritikhine, Michel
Organouranium Complexes with Phosphinine-Based SPS Pincer Ligands. Variations with the Substituent at the Phosphorus Atom
Organometallics, 2008, 27, 4158
4071904 CIFC42 H34 Br Cl P2 Pt SP -19.1621; 11.634; 20.201
83.907; 77.3; 74.767
2024.1Kuniyasu, Hitoshi; Takekawa, Kazunobu; Yamashita, Fumikazu; Miyafuji, Kiyoshi; Asano, Shigehito; Takai, Yasutomo; Ohtaka, Atsushi; Tanaka, Aoi; Sugoh, Kunihiko; Kurosawa, Hideo; Kambe, Nobuaki
Insertion of Alkynes into an ArS−Pt Bond: Regio- and Stereoselective Thermal Reactions, Facilitation by “o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences Depending on the Ancillary Ligand, and Application to a Catalytic Reaction
Organometallics, 2008, 27, 4788
4070645 CIFC20 H25 N O5 WP 1 21/n 18.3192; 14.2955; 17.0591
90; 92.92; 90
2026.16Jackson, Andrew B.; Khosla, Chetna; Gaskins, Helen E.; White, Peter S.; Templeton, Joseph L.
Reduction of π-Bound Nitriles to π-Bound Imines in a Tungsten(II) Bis(acetylacetonate) Coordination Sphere
Organometallics, 2008, 27, 1322
4071676 CIFC68.5 H20 Cr N O2 S3P -110.006; 11.455; 19.938
80.38; 75.29; 66.89
2027.14Matsuo, Yutaka; Iwashita, Akihiko; Nakamura, Eiichi
Group 6 Metal Complexes of the η5-Pentamethyl[60]fullerene
Organometallics, 2008, 27, 4611
4071084 CIFC14 H8 Cl2 F12 Fe P2 PtP 1 21/c 19.661; 13.369; 17.265
90; 114.609; 90
2027.4Velazco, Euclides J.; Caffyn, Andrew J. M.; Le Goff, Xavier F.; Ricard, Louis
Synthesis, Structure, and Coordination Properties of 1,1′-Bis(bis(trifluoromethyl)phosphino)ferrocene, dfmpf
Organometallics, 2008, 27, 2402
4071652 CIFC40 H61 Cl2 N O P2 RuP -112.274; 12.697; 13.241
85.74; 81.89; 83.86
2027.5Zhang, Jing; Gandelman, Mark; Shimon, Linda J. W.; Milstein, David
Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes
Organometallics, 2008, 27, 3526
4072125 CIFC13 H31 B9 Co N SP 1 21/n 19.3712; 16.954; 12.8825
90; 97.711; 90
2028.3Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4071154 CIFC23 H18 Cl N2 P PdP n a 2118.8885; 8.9493; 11.9998
90; 90; 90
2028.4Han, Fu-Bin; Zhang, Yu-Liang; Sun, Xiu-Li; Li, Bao-Guo; Guo, Yang-Hui; Tang, Yong
Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization
Organometallics, 2008, 27, 1924
4070879 CIFC44 H45 Br2 N2 O P2 ReP -110.834; 12.5413; 15.6724
79.551; 86.688; 76.017
2031.9Choualeb, A.; Maccaroni, E.; Blacque, O.; Schmalle, H. W.; Berke, H.
Rhenium Nitrosyl Complexes for Hydrogenations and Hydrosilylations
Organometallics, 2008, 27, 3474
4071892 CIFC31 H57 B9 Cl Na O6 ZrP -111.494; 12.777; 14.431
83.71; 74.74; 88.56
2032.3Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4070882 CIFC43 H37 Cl5 Fe P2 PdP 1 21 111.566; 11.258; 15.813
90; 98.68; 90
2035.4Wang, Yaping; Sturm, Thomas; Steurer, Marianne; Arion, Vladimir B.; Mereiter, Kurt; Spindler, Felix; Weissensteiner, Walter
Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Organometallics, 2008, 27, 1119
4070902 CIFC39 H56 B9 N O4 ZrP -19.627; 11.5096; 18.6693
86.478; 86.608; 81.024
2036.8Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4071361 CIFC22 H32 Ir N OP -19.092; 9.101; 25.409
90.061; 90.049; 104.137
2038.8Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071784 CIFC24 H31 N O WP n a 2116.821; 12.6397; 9.6412
90; 90; 90
2049.84Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4071728 CIFC22 H60 Cl4 In2 N2 Si6P -111.0773; 12.7834; 14.8553
83.17; 89.9; 79.024
2049.99Schachner, Jörg A.; Lund, Clinton L.; Burgess, Ian J.; Quail, J. Wilson; Schatte, Gabriele; Müller, Jens
The Dynamic Indium-Bridged [1.1]Ferrocenophane [(Me2Ntsi)In(C5H4)2Fe]2
Organometallics, 2008, 27, 4703
4070580 CIFC38 H39 Cl N5 O4 Pt Re S4P -18.9503; 13.158; 17.986
100.325; 94.305; 98.211
2051.5Liu, Wei; Wang, Ru; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng
Syntheses, Structures, and Properties of Tricarbonyl Rhenium(I) Heteronuclear Complexes with a New Bridging Ligand Containing Coupled Bis(2-pyridyl) and 1,2-Dithiolene Units
Organometallics, 2008, 27, 126
4070575 CIFC20 H16 N4 S4P 1 21 15.195; 9.58; 41.29
90; 90; 90
2055Liu, Wei; Wang, Ru; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng
Syntheses, Structures, and Properties of Tricarbonyl Rhenium(I) Heteronuclear Complexes with a New Bridging Ligand Containing Coupled Bis(2-pyridyl) and 1,2-Dithiolene Units
Organometallics, 2008, 27, 126
4070583 CIFC14 H14 Br2 N4 O4 Rh2P 1 21/c 112.8695; 13.727; 11.6622
90; 93.176; 90
2057.1Wells, Kyle D.; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
Organometallics, 2008, 27, 691
4071077 CIFC47.5 H54.74 B2 Cl0.25 F2 N2P -18.3878; 10.8845; 23.6171
96.175; 93.566; 105.236
2059.1Huh, Jung Oh; Do, Youngkyu; Lee, Min Hyung
A BODIPY−Borane Dyad for the Selective Complexation of Cyanide Ion
Organometallics, 2008, 27, 1022
4070886 CIFC22 H30 Br N2 RhP 1 21/n 110.3387; 13.433; 14.932
90; 96.477; 90
2060.5Türkmen, Hayati; Pape, Tania; Hahn, F. Ekkehardt; Çetinkaya, Bekir
Annulated N-Heterocyclic Carbene Ligands Derived from 2-Methylaminopiperidine: Their Complexes and Catalytic Applications
Organometallics, 2008, 27, 571
4072045 CIFC18 H40 Ni P2P 1 21/c 114.2542; 13.7514; 10.5561
90; 95.091; 90
2060.99Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072372 CIFC13 H11 B OP 1 21/c 15.4887; 15.0318; 25.0114
90; 90.253; 90
2063.5Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4070887 CIFC22 H30 Br Ir N2P 1 21/n 110.364; 13.438; 14.932
90; 96.208; 90
2067.4Türkmen, Hayati; Pape, Tania; Hahn, F. Ekkehardt; Çetinkaya, Bekir
Annulated N-Heterocyclic Carbene Ligands Derived from 2-Methylaminopiperidine: Their Complexes and Catalytic Applications
Organometallics, 2008, 27, 571
4070885 CIFC20 H23 Br Fe I NP 21 21 219.433; 12.543; 17.474
90; 90; 90
2067.5Wang, Yaping; Sturm, Thomas; Steurer, Marianne; Arion, Vladimir B.; Mereiter, Kurt; Spindler, Felix; Weissensteiner, Walter
Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Organometallics, 2008, 27, 1119
4071770 CIFC15 H20 Cl2 Mo2 O3 S3P 1 21/c 110.8247; 12.9834; 16.0843
90; 113.652; 90
2070.6Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071870 CIFC18 H25 Cl N2 Ni O7P 21 21 216.1341; 11.6353; 29.016
90; 90; 90
2070.9Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4072252 CIFC49.5 H54 Fe N4 Ni2P -110.5506; 11.7665; 18.0307
72.868; 81.398; 76.811
2074.5Tan, Weiqiang; Yu, Zhengkun; He, Wei; Wang, Liandi; Sun, Jie; Chen, Jinzhu
A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH2)2-Bridged Bis(pyrazole)
Organometallics, 2008, 27, 4833
4071878 CIFC40 H64 B F4 N O Os P2P -110.258; 14.422; 14.825
92.738; 94.386; 107.905
2075Buil, María L.; Esteruelas, Miguel A.; Garcés, Karin; Oliván, Montserrat; Oñate, Enrique
Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands
Organometallics, 2008, 27, 4680
4071180 CIFC16 H22 B0.2 F0.8 I1.8 N6 RuP 1 21/c 19.4985; 8.0984; 27.008
90; 90.21; 90
2077.5Poyatos, Macarena; McNamara, William; Incarvito, Chris; Clot, Eric; Peris, Eduardo; Crabtree, Robert H.
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
Organometallics, 2008, 27, 2128
4083495 CIFC40 H70 Cl2 O2 Ru2P -19.6933; 12.9082; 17.281
101.758; 99.882; 92.274
2079.2Dutta, Barnali; Scolaro, Claudine; Scopelliti, Rosario; Dyson, Paul J.; Severin, Kay
Importance of the π-Ligand: Remarkable Effect of the Cyclopentadienyl Ring on the Cytotoxicity of Ruthenium PTA Compounds
Organometallics, 2008, 27, 1355
4071586 CIFC H Cl0.96 Fe N OP -110.438; 14.746; 14.994
83.396; 71.005; 73.007
2086.4Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4071394 CIFC18 H30 Cl2 Cr N3 SiP 1 21/c 111.2546; 12.3589; 15.0347
90; 93.67; 90
2087Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4070881 CIFC43 H37 Cl5 Fe P2 PdP 1 21 111.278; 14.443; 13.142
90; 102.8; 90
2087.5Wang, Yaping; Sturm, Thomas; Steurer, Marianne; Arion, Vladimir B.; Mereiter, Kurt; Spindler, Felix; Weissensteiner, Walter
Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Organometallics, 2008, 27, 1119
4070628 CIFC38 H8 F12 O18 Ru4P 1 21/n 110.2883; 15.4363; 14.0317
90; 110.34; 90
2089.47Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4071582 CIFC50 H46 B2 N4 YbP -110.8679; 13.486; 14.778
100.474; 97.923; 95.89
2091.3Cui, Peng; Chen, Yaofeng; Wang, Guoping; Li, Guangyu; Xia, Wei
Divalent Ytterbium Boratabenzene Complex (C5H5BNPh2)2Yb(THF)2: Synthesis, Structure, and Solvent-Mediated Redox Transformation
Organometallics, 2008, 27, 4013
4071810 CIFC21 H36 Ir O2 PP 1 21/n 113.16; 8.4206; 19.586
90; 105.452; 90
2092Jiménez, M. Victoria; Rangel-Salas, I. Idalia; Lahoz, Fernando J.; Oro, Luis A.
C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds§
Organometallics, 2008, 27, 4229
4072180 CIFC37 H56 F12 Mo N2 O3P -110.55; 13.514; 15.842
102.763; 90.02; 107.753
2092.4Lokare, Kapil S.; Staples, Richard J.; Odom, Aaron L.
Synthesis, Properties, and Structure of Tethered Molybdenum Alkylidenes
Organometallics, 2008, 27, 5130
4071239 CIFC44 H60 Ni O3 P2P 21 21 213.9217; 14.4359; 10.4167
90; 90; 90
2093.5Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071816 CIFC44 H49 Cu N8 PtP -112.5439; 12.631; 14.1299
69.921; 85.038; 89.992
2093.8Moret, Marc-Etienne; Chen, Peter
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands
Organometallics, 2008, 27, 4903
4072370 CIFC27 H22 B Fe N OP 1 21/n 112.4839; 11.3114; 15.0039
90; 97.82; 90
2099Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4070930 CIFC22 H10 F10 N2 ZnP 1 21/c 116.1446; 10.2398; 13.2794
90; 106.979; 90
2099.6Martin, Eddy; Spendley, Claire; Mountford, Andrew J.; Coles, Simon J.; Horton, Peter N.; Hughes, David L.; Hursthouse, Michael B.; Lancaster, Simon J.
Synthesis, Structure, and Supramolecular Architecture of Benzonitrile and Pyridine Adducts of Bis(pentafluorophenyl)zinc: Pentafluorophenyl‒Aryl Interactions versus Homoaromatic Pairing
Organometallics, 2008, 27, 1436
4072168 CIFC54 H44 P2 PtP 1 21/n 113.6022; 8.5341; 18.0885
90; 90.447; 90
2099.7Sadowy, Amber L.; Ferguson, Michael J.; McDonald, Robert; Tykwinski, Rik R.
Chiralcis-Platinum Acetylide Complexes via Diphosphine Ligand Exchange: Effect of the Ligand
Organometallics, 2008, 27, 6321
4070670 CIFC41 H65 Br2 La N2 O3P 1 21/m 110.045; 20.093; 10.41
90; 91.951; 90
2099.9Bambirra, Sergio; Perazzolo, Francesca; Boot, Steven J.; Sciarone, Timo J. J.; Meetsma, Auke; Hessen, Bart
Strategies for the Synthesis of Lanthanum Dialkyl Complexes with Monoanionic Ancillary Ligands
Organometallics, 2008, 27, 704
4072115 CIFC43 H61 N5 Zn2P -111.6831; 14.2544; 14.5619
67.162; 79.572; 70.257
2100.1Piesik, Dirk F.-J.; Range, Sven; Harder, Sjoerd
Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization
Organometallics, 2008, 27, 6178
4070994 CIFC36 H68 Cl2 Ir2 N2 P4P 1 21/c 112.1403; 13.0878; 16.6594
90; 127.475; 90
2100.71Hoover, Jessica M.; Freudenthal, John; Michael, Forrest E.; Mayer, James M.
Reactivity of Low-Valent Iridium, Rhodium, and Platinum Complexes with Di- and Tetrasubstituted Hydrazines
Organometallics, 2008, 27, 2238
4072044 CIFC17 H37 Br Ni P2P 1 21/n 18.4858; 11.859; 20.8903
90; 90.796; 90
2102.05Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4071467 CIFC21 H26 Ag I N2P n a 2116.288; 15.495; 8.3719
90; 90; 90
2112.9Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4070972 CIFC45 H21 B F20 N2 Pt SiP -112.5123; 12.6603; 15.4852
108.625; 103.534; 104.601
2113.01Sangtrirutnugul, Preeyanuch; Tilley, T. Don
Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Organometallics, 2008, 27, 2223
4071563 CIFC22 H8 B F15 OP 1 21/n 114.2611; 11.2276; 14.7056
90; 115.967; 90
2116.9Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4071875 CIFC46 H138 Si22P -19.2052; 9.6344; 27.109
94.89; 95.07; 116.65
2119.2Wallner, Andreas; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Rohm, Henning W.; Köckerling, Martin; Krempner, Clemens
Structure, Conformation, and UV Absorption Behavior of Partially Trimethylsilylated Oligosilane Chains
Organometallics, 2008, 27, 5221
4071902 CIFC20 H28 O8 OsP 1 21/c 112.114; 12.583; 14.151
90; 100.732; 90
2119.3Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4071243 CIFC49 H40 Cl3 Fe3 P3P -112.62; 13.013; 14.979
94.816; 95.71; 118.712
2122.14Mizuta, Tsutomu; Aotani, Tomoyuki; Imamura, Yuki; Kubo, Kazuyuki; Miyoshi, Katsuhiko
Structure and Properties of the Macrocyclic Tridentate Ferrocenylphosphine Ligand (−PhPC5H4FeC5H4−)3
Organometallics, 2008, 27, 2457
4070627 CIFC38 H8 F12 O18 Ru4P 1 21/n 110.3336; 11.8386; 18.0531
90; 106.042; 90
2122.53Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4071119 CIFC16 H26 F6 N2 O2 P Rh SP 1 21/c 19.4642; 16.1506; 14.466
90; 106.127; 90
2124.15Schaub, Thomas; Radius, Udo; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium
Organometallics, 2008, 27, 1892
4070622 CIFC33 H32 B Cl6 N6 P Ru S4P -111.9019; 13.3665; 14.9119
68.943; 74.221; 81.936
2128.1Crossley, Ian R.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Owen, Gareth R.; White, Andrew J. P.; Williams, David J.; Willis, Anthony C.
Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru\ρightarrow B)8and [Ru(CO)(CNR){B(mt)3}](Ru→B)8(mt = methimazolyl, R =tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)
Organometallics, 2008, 27, 381
4071663 CIFC33 H60 Ba N4 Si4P -111.6902; 11.6877; 15.7698
91.931; 91.114; 96.964
2136.94Barrett, Anthony G. M.; Crimmin, Mark R.; Hill, Michael S.; Kociok-Köhn, Gabriele; MacDougall, Dugald J.; Mahon, Mary F.; Procopiou, Panayiotis A.
Synthesis, Characterization, and Solution Lability of N-Heterocyclic Carbene Adducts of the Heavier Group 2 Bis(trimethylsilyl)amides
Organometallics, 2008, 27, 3939
4070723 CIFC16 H8 N2 O11 Os3P 1 21/n 18.472; 22.858; 11.767
90; 110.195; 90
2138.6Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4070796 CIFC23 H26 N2 O4 SiP 1 21/n 17.584; 13.923; 20.265
90; 91.37; 90
2139.2Spiniello, Marisa; White, Jonathan M.
Structural Investigations into the β-Effect of Pentavalent Silicon
Organometallics, 2008, 27, 994
4072354 CIFC26 H18 N2 O4 SiP 1 21/c 19.6245; 14.0115; 16.1647
90; 100.99; 90
2139.89Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072353 CIFC10 H13 N O2 SiP b c a12.1828; 9.7269; 18.0635
90; 90; 90
2140.54Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071120 CIFC17 H29 B F4 Ir N3 O SP 1 21/c 110.722; 16.832; 11.867
90; 91.74; 90
2140.7Schaub, Thomas; Radius, Udo; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium
Organometallics, 2008, 27, 1892
4071891 CIFC33 H59 B9 Cl Na O6 ZrP -112.265; 13.11; 13.761
78.22; 83.36; 84.01
2144.1Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4071899 CIFC21 H27 B F4 N2P 41 21 27.4997; 7.4997; 38.126
90; 90; 90
2144.4Grisi, Fabia; Costabile, Chiara; Gallo, Emanuela; Mariconda, Annaluisa; Tedesco, Consiglia; Longo, Pasquale
Ruthenium-Based Complexes Bearing Saturated Chiral N-Heterocyclic Carbene Ligands: Dynamic Behavior and Catalysis
Organometallics, 2008, 27, 4649
4072171 CIFC54 H96 B20 Cl4 K2 O8 Y2P -110.3117; 15.4772; 16.0368
61.719; 76.49; 73.435
2145.6Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Constrained-Geometry Organolanthanide Chlorides and Alkyls Incorporating the Ligand [η5:σ-(C9H6)C2B10H10]2−
Organometallics, 2008, 27, 5309
4071362 CIFC20 H27 B F4 Ir N OP 1 21/c 18.626; 15.356; 16.209
90; 91.429; 90
2146.4Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071907 CIFC46 H44 O6 P2 Pt SP -112.631; 17.188; 11.455
90.219; 114.082; 107.153
2147.4Kuniyasu, Hitoshi; Takekawa, Kazunobu; Yamashita, Fumikazu; Miyafuji, Kiyoshi; Asano, Shigehito; Takai, Yasutomo; Ohtaka, Atsushi; Tanaka, Aoi; Sugoh, Kunihiko; Kurosawa, Hideo; Kambe, Nobuaki
Insertion of Alkynes into an ArS−Pt Bond: Regio- and Stereoselective Thermal Reactions, Facilitation by “o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences Depending on the Ancillary Ligand, and Application to a Catalytic Reaction
Organometallics, 2008, 27, 4788
4072053 CIFC17 H27 Cl2 N P Si TaP 1 21/n 111.3952; 14.8865; 13.2074
90; 106.379; 90
2149.51Ignatov, Stanislav K.; Rees, Nicholas H.; Merkoulov, Alexei A.; Dubberley, Stuart R.; Razuvaev, Alexei G.; Mountford, Philip; Nikonov, Georgii I.
Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies
Organometallics, 2008, 27, 5968
4070615 CIFC36 H32 N12 O12 Re4P 1 21/c 19.4514; 13.0932; 17.4539
90; 95.338; 90
2150.54Wu, Jing-Yun; Thanasekaran, P.; Cheng, Yi-Wei; Lee, Chung-Chou; Manimaran, B.; Rajendran, T.; Liao, Rong-Tang; Lee, Gene-Hsiang; Peng, Shie-Ming; Lu, Kuang-Lieh
Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles
Organometallics, 2008, 27, 2141
4070719 CIFC16 H8 N2 O11 Ru3P 1 21/n 18.512; 22.951; 11.753
90; 110.2; 90
2155Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4071687 CIFC26 H29 N TiP 1 21/c 115.263; 9.5695; 16.15
90; 113.963; 90
2155.5Wu, Chun Ji; Lee, Sang Hoon; Yu, Seung Tack; Na, Sung Jae; Yun, Hoseop; Lee, Bun Yeoul
CO2-Mediatedortho-Lithiation ofN-Alkylanilines and Its Use for the Construction of Polymerization Catalysts
Organometallics, 2008, 27, 3907
4071923 CIFC28 H34 CrC 1 2/c 111.101; 13.664; 14.302
90; 93.237; 90
2165.9Meredith, M. Brett; Crisp, Jeffrey A.; Brady, Erik D.; Hanusa, Timothy P.; Yee, Gordon T.; Pink, Maren; Brennessel, William W.; Young, Victor G.
Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution
Organometallics, 2008, 27, 5464
4071805 CIFC51 H51 Fe2 P2 SiP -110.1001; 14.4739; 15.7609
77.574; 80.248; 76.378
2169.6Kumar, Mukesh; Cervantes-Lee, Francisco; Pannell, Keith H.; Shao, Jianguo
Synthesis and cyclic voltammetric studies of diiron complexes, ER(2)[(eta-C(5)H(4))Fe(L(2))Me](2) (E = C, Si, Ge, Sn; R = H, alkyl; L(2) = diphosphine] and (eta-C(5)H(5))Fe(L(2))ER(2)Fc [Fc = (eta-C(5)H(4))Fe(eta-C(5)H(5))].
Organometallics, 2008, 27, 4739-4748
4071160 CIFC20 H34 Cl2 SnP 21 21 216.9891; 15.683; 19.816
90; 90; 90
2172Beckmann, Jens; Duthie, Andrew; Grassmann, Marian; Semisch, Annetta
Optically Active Organotin Compounds Derived from β-Pinene. The Quest for Chiral Polystannanes†
Organometallics, 2008, 27, 1495
4072151 CIFC20 H30 I2 UP 1 21/n 18.5406; 16.293; 15.827
90; 98.717; 90
2176.9Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4071466 CIFC23 H30 Ag Br N2P 1 21/n 18.4959; 19.0544; 13.9272
90; 104.775; 90
2180.05Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4072134 CIFC42 H54 Cl2 ZrP 21 21 213.362; 25.112; 6.5155
90; 90; 90
2186.3Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070809 CIFC43 H65 N4 Sc Si2P -112.093; 12.191; 17.037
83.874; 70.672; 67.402
2187.6Otero, Antonio; Fernández-Baeza, Juan; Antiñolo, Antonio; Lara-Sánchez, Agustín; Martínez-Caballero, Emilia; Tejeda, Juan; Sánchez-Barba, Luis F.; Alonso-Moreno, Carlos; López-Solera, Isabel
Scandium and Yttrium Complexes Supported by NNCp Heteroscorpionate Ligands: Synthesis, Structure, and Polymerization of ϵ-Caprolactone
Organometallics, 2008, 27, 976
4070525 CIFC39 H54 Co2 F12 O7 P2P -112.584; 14.088; 15.533
114.865; 93.39; 114.21
2187.7Perekalin, Dmitry S.; Babak, Maria V.; Novikov, Valentin V.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Corsini, Maddalena; Zanello, Piero; Kudinov, Alexander R.
A New Approach to the Photochemically Controlled Crown Ethers: (Tetramethylcyclobutadiene)cobalt Complexes with Benzo-15-Crown-5 and Dibenzo-18-Crown-6†
Organometallics, 2008, 27, 3654
4071640 CIFC25 H28 Cl N3 RuP 1 21/c 111.117; 10.159; 19.476
90; 94.941; 90
2191Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4070982 CIFC21 H25 I2 Ir N2P 1 21/n 19.5338; 11.0406; 21.147
90; 99.593; 90
2194.8Pontes da Costa, André; Viciano, Mónica; Sanaú, Mercedes; Merino, Sonia; Tejeda, Juan; Peris, Eduardo; Royo, Beatriz
First Cp*-Functionalized N-Heterocyclic Carbene and Its Coordination to Iridium. Study of the Catalytic Properties
Organometallics, 2008, 27, 1305
4072268 CIFC20 H33 Cl2 Ir TiP 1 21/c 110.546; 14.0282; 15.4839
90; 106.382; 90
2197.71Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4072241 CIFC37 H42 Cl6 N2 O10 Ta2P -111.089; 12.084; 17.119
102.968; 99.251; 92.625
2198.3Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodríguez, Ana
Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
Organometallics, 2008, 27, 6090
4070641 CIFC44 H48 N4 Ni2 O6C 1 2/m 123.63; 7.308; 16.31
90; 128.656; 90
2199Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4070794 CIFC23 H26 N2 O4 SiP 1 21/c 17.5985; 41.416; 7.2772
90; 106.158; 90
2199.7Spiniello, Marisa; White, Jonathan M.
Structural Investigations into the β-Effect of Pentavalent Silicon
Organometallics, 2008, 27, 994
4071329 CIFC37 H47 I3 N9 RhP -112.2798; 14.1168; 15.6034
62.889; 66.075; 79.759
2200.7Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4070961 CIFC46 H64 Cl2 Fe2 N6P 1 21/c 114.889; 9.889; 16.661
90; 116.03; 90
2204.3Sciarone, Timo J. J.; Nijhuis, Christian A.; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Paramagnetic Amino-amidinate Iron(II) Complexes:19F NMR Evidence for Interactions with Weakly Coordinating Anions
Organometallics, 2008, 27, 2058
4071702 CIFC38 H44 Br4 Cl4 N8 Pt2P -113.2372; 14.0095; 14.3908
66.918; 65.29; 87.68
2205.83Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4072184 CIFC18 H22 F12 N2 O2P -112.0774; 12.4309; 16.7774
74.731; 89.694; 66.091
2206.68Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4071050 CIFC39 H45 F6 N O2 P3 Ru S2 SbP -111.3019; 12.332; 16.0514
97.042; 95.058; 90.731
2211.01Cadierno, Victorio; Díez, Josefina; García-Álvarez, Joaquín; Gimeno, José
(η6-Arene)−Ruthenium(II) Complexes Containing Methanide and Methandiide Anions of Ph2P(S)CH2P(NR)Ph2: Unprecedented Insertion of Isocyanide into a Ruthenium−Carbene Bond
Organometallics, 2008, 27, 1809
4071729 CIFC11 H30 I2 In N Si3P 1 21/c 18.3419; 17.938; 16.57
90; 116.658; 90
2215.92Schachner, Jörg A.; Lund, Clinton L.; Burgess, Ian J.; Quail, J. Wilson; Schatte, Gabriele; Müller, Jens
The Dynamic Indium-Bridged [1.1]Ferrocenophane [(Me2Ntsi)In(C5H4)2Fe]2
Organometallics, 2008, 27, 4703
4071076 CIFC21 H37 N3 O WP -18.0022; 16.383; 17.082
84.451; 89.925; 84.088
2217Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4071008 CIFC43 H49 Mo2 O2 P SiP -111.313; 12.471; 17.09
68.836; 84.285; 81.815
2222.6García-Vivó, Daniel; García, M. Esther; Ruiz, Miguel A.
Multisite Reactivity of the Unsaturated Methoxycarbyne Complex [Mo2(η5-C5H5)2(µ-COMe)(µ-PCy2)(µ-CO)]
Organometallics, 2008, 27, 169
4071070 CIFC24 H35 N O WP 1 21/c 112.7252; 11.7231; 15.2438
90; 102.146; 90
2223.15Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4071622 CIFC26 H22 N O P SP 1 21/c 112.2827; 17.2457; 10.7969
90; 103.48; 90
2224Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4071803 CIFC56 H51 N4 RhP -110.578; 14.574; 16.226
65.745; 77.764; 82.348
2225.9Chan, Yun Wai; Chan, Kin Shing
Base-Promoted Carbon−Hydrogen Bond Activation of Alkanes with Rhodium(III) Porphyrin Complexes
Organometallics, 2008, 27, 4625
4071326 CIFC24 H25 Cl F3 N2 RhP 1 21/n 111.7872; 16.2148; 11.9178
90; 102.218; 90
2226.22Song, Guoyong; Zhang, Yao; Li, Xingwei
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
Organometallics, 2008, 27, 1936
4070601 CIFC13.5 H18 B I2 N6 O0.5 Pt S3P 1 21/n 19.8899; 20.0454; 11.3937
90; 99.5623; 90
2227.38Crossley, Ian R.; Hill, Anthony F.; Willis, Anthony C.
Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10(mt = Methimazolyl)
Organometallics, 2008, 27, 312
4071715 CIFC11 H17 Cl O PdP b c a8.2836; 13.7315; 19.6036
90; 90; 90
2229.8Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4070700 CIFC38.5 H58 F3 N5 O4 S Si2 ZrP -19.9979; 13.3201; 18.538
92.16; 103.483; 110.444
2230.2Herrmann, Heike; Lloret Fillol, Julio; Wadepohl, Hubert; Gade, Lutz H.
A Zirconium (1-Pyridinio)imido Complex: Facile N−N Bond Cleavage and N−C Bond Formation
Organometallics, 2008, 27, 172
4071750 CIFC26 H25 N O2 P2C 1 2/c 120.424; 8.974; 12.342
90; 99.544; 90
2231Teo, Shihui; Weng, Zhiqiang; Hor, T. S. Andy
Unusual Ligand Transformation Mediated by Chromium(III): Hydrolytic Disintegration of a [PNP] Hybrid Ligand with CH3CN Insertion
Organometallics, 2008, 27, 4188
4070751 CIFC15 H23 B10 Co O4 S2P 1 21/n 19.936; 18.012; 13.344
90; 110.741; 90
2233.4Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4072047 CIFC20 H40 Ni P2P 1 21/n 110.8603; 14.5551; 14.1473
90; 92.175; 90
2234.7Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4071176 CIFC55 H50 P2 Pt SiP -19.5937; 11.1677; 21.3492
97.04; 94.1; 98.436
2236.19Arii, Hidekazu; Takahashi, Makiko; Noda, Aki; Nanjo, Masato; Mochida, Kunio
Spectroscopic and Structural Studies of Thermally Unstable Intermediates Generated in the Reaction of [Pt(PPh3)2(η2-C2H4)] with Dihydrodisilanes
Organometallics, 2008, 27, 1929
4072341 CIFC104 H52 B2 Cl2 F40 Zr2P -110.2127; 13.5318; 16.5965
81.864; 83.95; 81.446
2236.9Wilson, Polly A.; Wright, Joseph A.; Oganesyan, Vasily S.; Lancaster, Simon J.; Bochmann, Manfred
Structural Characterization of a Cationic Zirconocene Dimethylaniline Complex and Related Catalytically Relevant Species
Organometallics, 2008, 27, 6371
4070655 CIFC38 H48 Cl Fe N4P -18.9994; 14.7098; 17.5144
87.111; 83.529; 76.58
2240.2Fernández, Ignacio; Trovitch, Ryan J.; Lobkovsky, Emil; Chirik, Paul J.
Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3and FeCH2CMe3Derivatives
Organometallics, 2008, 27, 109
4071804 CIFC15 H17 Cl7 Cr N5C 1 2/c 114.649; 14.395; 11.144
90; 107.51; 90
2241.1McGuinness, David S.; Suttil, James A.; Gardiner, Michael G.; Davies, Noel W.
Ethylene Oligomerization with Cr−NHC Catalysts: Further Insights into the Extended Metallacycle Mechanism of Chain Growth
Organometallics, 2008, 27, 4238
4071346 CIFC53 H61 N5 TiP -111.434; 14.483; 14.939
95.761; 103.409; 108.459
2241.8Vujkovic, Nadia; Fillol, Julio Lloret; Ward, Benjamin D.; Wadepohl, Hubert; Mountford, Philip; Gade, Lutz H.
Insertions into Azatitanacyclobutenes: New Insights into Three-Component Coupling Reactions Involving Imidotitanium Intermediates
Organometallics, 2008, 27, 2518
4070709 CIFC35 H58 Li N3 O Si4 SnP -112.5582; 13.3633; 16.1012
71.821; 67.989; 65.683
2242.8Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
Triamidostannates(II) as Sterically Demanding Ligands for Rhodium and Iridium
Organometallics, 2008, 27, 524
4071088 CIFC19 H27 F6 Fe N2 P PdP 21 21 219.717; 14.296; 16.165
90; 90; 90
2245.5Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4071617 CIFC36 H48 Ag4 Cl4 N12P 1 21/c 121.623; 6.6427; 15.8766
90; 100.017; 90
2245.7Ye, Jiansheng; Zhang, Xiaoming; Chen, Wanzhi; Shimada, Shigeru
Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling
Organometallics, 2008, 27, 4166
4071624 CIFC25 H19 Cl N P Pd S2P 1 21/c 113.0603; 13.7939; 13.2593
90; 109.845; 90
2246.8Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4071811 CIFC24 H36 Ir O2 PP 1 21/n 17.9252; 29.893; 9.7153
90; 102.441; 90
2247.6Jiménez, M. Victoria; Rangel-Salas, I. Idalia; Lahoz, Fernando J.; Oro, Luis A.
C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds§
Organometallics, 2008, 27, 4229
4072107 CIFC40 H49 F12 N5 O2 P2 RuP -110.664; 13.418; 16.109
96.96; 93.22; 99.66
2248.7Wong, Chun-Yuen; Lai, Lo-Ming; Lam, Chi-Yeung; Zhu, Nianyong
Ruthenium Carbene and Allenylidene Complexes Supported by the Tertiary Amine−Aromatic Diimine Ligand Set: Structural, Spectroscopic, and Theoretical Studies
Organometallics, 2008, 27, 5806
4071116 CIFC25 H33 Li Ni O2P 21 21 219.8482; 14.5816; 15.6829
90; 90; 90
2252.1Buchalski, Piotr; Grabowska, Ilona; Kamińska, Elżbieta; Suwińska, Kinga
Synthesis and Structures of 9-Nickelafluorenyllithium Complexes
Organometallics, 2008, 27, 2346
4071800 CIFC45 H30 Cl4 N2 O4 Rh4 S2P -110.4989; 15.479; 15.746
77.245; 70.566; 70.183
2253.3Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4072014 CIFC18 H29 I N6 P2 PdC 1 2/c 119.064; 11.8607; 10.9238
90; 114.054; 90
2255.5Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4071658 CIFC20.6 H25 Br F6 N P RuP 1 21/c 18.2925; 15.354; 17.775
90; 94.66; 90
2255.7Gruber, Stefan; Zaitsev, Alexey B.; Wörle, Michael; Pregosin, Paul S.; Veiros, Luis F.
Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry
Organometallics, 2008, 27, 3796
4072210 CIFC59 H76 B Ni P SP -111.3711; 13.09; 16.842
106.206; 97.013; 106.216
2256.5Emslie, David J. H.; Harrington, Laura E.; Jenkins, Hilary A.; Robertson, Craig M.; Britten, James F.
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η3(BCC)-Triarylborane Coordination
Organometallics, 2008, 27, 5317
4070638 CIFC37 H74 Si7P -111.384; 13.277; 15.422
79.505; 80.473; 87.062
2259.8Kajiwara, Takashi; Takeda, Nobuhiro; Sasamori, Takahiro; Tokitoh, Norihiro
Synthesis of Alkali Metal Salts of Borylsilyl Anions Utilizing Highly Crowded Silylboranes and Their Properties#
Organometallics, 2008, 27, 880
4070698 CIFC39 H59 F3 N6 O3 S Si2 ZrP -110.8684; 13.9752; 15.6286
82.742; 81.84; 75.184
2261.6Herrmann, Heike; Lloret Fillol, Julio; Wadepohl, Hubert; Gade, Lutz H.
A Zirconium (1-Pyridinio)imido Complex: Facile N−N Bond Cleavage and N−C Bond Formation
Organometallics, 2008, 27, 172
4071853 CIFC25 H30 N4 O2 SiP 1 21/n 114.293; 10.3528; 15.528
90; 99.007; 90
2269.4Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071513 CIFC18 H28 F3 N3 O4 Pd SP 21 21 2112.8466; 12.9925; 13.6154
90; 90; 90
2272.5Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4072381 CIFC21 H38 I P PdP 1 21/n 113.609; 11.773; 15.122
90; 110.004; 90
2276.66Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4070753 CIFC15 H23 B10 Co O4 Se2P 1 21/n 110.0659; 18.0533; 13.4238
90; 110.922; 90
2278.6Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4072255 CIFC42 H39 B F20 N6 TiP -111.6237; 12.7345; 17.5683
110.764; 100.462; 102.264
2280.25Bolton, Paul D.; Feliz, Marta; Cowley, Andrew R.; Clot, Eric; Mountford, Philip
TiNR vs Ti−R′ Functional Group Selectivity in Titanium Imido Alkyl Cations from an Experimental Perspective
Organometallics, 2008, 27, 6096
4072269 CIFC20 H33 Cl2 Ir ZrP 1 21/c 110.7052; 14.1183; 15.6994
90; 105.764; 90
2283.55Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4071868 CIFC22 H31 I N2 O2P 1 21 19.478; 21.389; 11.315
90; 95.246; 90
2284Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4071226 CIFC18 H44 Ir P3P 1 21/n 115.2176; 9.3278; 17.7508
90; 114.744; 90
2288.33Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4072019 CIFC20 H25 Cl3 Cr N5 OP 1 21/n 110.053; 16.831; 13.9668
90; 103.847; 90
2294.5Zhang, Jun; Braunstein, Pierre; Hor, T. S. Andy
Highly Selective Chromium(III) Ethylene Trimerization Catalysts with [NON] and [NSN] Heteroscorpionate Ligands
Organometallics, 2008, 27, 4277
4071587 CIFC53 H46 Cl4 Fe2 N2 O2P m n 2128.871; 7.5729; 10.514
90; 90; 90
2298.8Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4083508 CIFC21 H17 Br4 N3 Ni O2P 1 21/c 111.11; 15.427; 15.714
90; 121.36; 90
2299.8Gao, Rong; Zhang, Min; Liang, Tongling; Wang, Fosong; Sun, Wen-Hua
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization
Organometallics, 2008, 27, 5641
4071512 CIFC50.12 H49.34 Cl1.77 I N O1.55 P2 PdP -112.1163; 13.7556; 15.558
87.638; 80.44; 64.323
2303.11Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4070971 CIFC22 H21 F3 N2 O3 Pt S SiP 1 21/n 113.412; 13.1627; 14.2154
90; 113.369; 90
2303.7Sangtrirutnugul, Preeyanuch; Tilley, T. Don
Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Organometallics, 2008, 27, 2223
4072273 CIFC25 H34 Co N3P 1 21/c 112.706; 11.551; 15.914
90; 98.78; 90
2308.3Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071851 CIFC25 H28 N4 O2 SiP 1 21/n 19.0893; 20.272; 12.872
90; 103.255; 90
2308.6Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071291 CIFC16 H38 Fe O4 P4P 41 21 28.99; 8.99; 28.589
90; 90; 90
2310.6Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4071280 CIFC22 H36 Cl Si2 TiC 1 2/c 114.8534; 9.8688; 16.7163
90; 109.387; 90
2311.42Horáček, Michal; Pinkas, Jiří; Gyepes, Róbert; Kubišta, Jiří; Mach, Karel
Reactivity of SiMe2H Substituents in Permethylated Titanocene Complexes: Dehydrocoupling and Ethene Hydrosilylation
Organometallics, 2008, 27, 2635
4071761 CIFC42.5 H52 Cl8 N3 P RuP -111.2488; 15.0628; 15.3236
66.061; 78.15; 89.338
2315Galan, Brandon R.; Pitak, Mateusz; Keister, Jerome B.; Diver, Steven T.
Isocyanide-Promoted Ylidene Transfer to Phosphorus: Rearrangement in the First-Generation Grubbs Complex
Organometallics, 2008, 27, 3630
4071081 CIFC22 H31 Fe2 N2 O2 P SiP 1 21/c 118.5613; 10.1935; 12.5422
90; 102.496; 90
2316.83Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Nucleophilic and Electrophilic Behavior of the Phosphinidene-Bridged Complex [Fe2(η5-C5H5)2(μ-PCy)(μ-CO)(CO)2]
Organometallics, 2008, 27, 1037
4072277 CIFC25 H35 N3P 1 21/n 112.387; 16.007; 12.911
90; 115.16; 90
2317.1Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070850 CIFC19 H25 N3 O9 PdP 1 21/n 116.322; 8.2938; 18.474
90; 112.011; 90
2318.6Vicente, José; Arcas, Aurelia; Gálvez-López, María-Dolores; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Synthesis of Bis(2,6-dinitroaryl)palladium(II) and Mono(2,6-dinitroaryl)platinum(II) Complexes. A New Example of the Transphobia Effect and of Transmetalation from Pt to Hg
Organometallics, 2008, 27, 1582
4070878 CIFC88 H162 Br4 N4 O5 P4 Re2P -19.9073; 14.117; 17.523
106.501; 93.603; 96.888
2320.8Choualeb, A.; Maccaroni, E.; Blacque, O.; Schmalle, H. W.; Berke, H.
Rhenium Nitrosyl Complexes for Hydrogenations and Hydrosilylations
Organometallics, 2008, 27, 3474
4072301 CIFC54 H64 N P2 RuP -112.903; 12.922; 15.899
74.415; 71.476; 70.052
2324.2Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4071849 CIFC23 H25 N4 O2 SiP 1 21/c 110.356; 20.348; 11.087
90; 95.56; 90
2325.3Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071760 CIFC40 H59 Cl2 Li0 N2 O2 YP -112.828; 13.41; 15.715
71.15; 84.948; 65.743
2329.4Lyubov, Dmitrii M.; Döring, Christian; Fukin, Georgii K.; Cherkasov, Anton V.; Shavyrin, Andrei S.; Kempe, Rhett; Trifonov, Alexander A.
Selective Assembly of Trinuclear Rare-Earth Alkyl Hydrido Clusters Supported by Amidopyridinate Ligands
Organometallics, 2008, 27, 2905
4071952 CIFC46 H62 Br Mg O5 SP -113.406; 13.949; 14.944
99.659; 110.113; 109.958
2334.2Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970
4070895 CIFC17 H32 B9 N O2 TiP 1 21/c 19.7861; 13.9424; 17.7544
90; 105.438; 90
2335Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4071108 CIFC17 H37 Cl P4 TiP 1 21/n 19.996; 13.711; 17.241
90; 98.46; 90
2337.3You, Yujian; Girolami, Gregory S.
Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Dimerization and Trimerization Catalysis
Organometallics, 2008, 27, 3172
4071890 CIFC18 H35 B9 N2 ZrP 1 21/c 114.14; 10.683; 16.648
90; 111.59; 90
2338.4Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4070506 CIFC17 H34 B8 P2 PtP 1 21/c 112.0336; 11.1519; 19.2314
90; 114.892; 90
2341.06Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4072374 CIFC22 H40 Cl P PdP 1 21/n 19.921; 13.999; 17.112
90; 99.4; 90
2344.7Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4070732 CIFC21 H34 Cl Ir2 N O2 SP 1 21/c 114.283; 11.501; 14.714
90; 103.945; 90
2345.8Arita, Hiroko; Ishiwata, Koji; Kuwata, Shigeki; Ikariya, Takao
Acid‒Base Bifunction and Umpolung of the Bridging Hydride in a Coordinatively Unsaturated Mesylimido- and Hydrido-Bridged Diiridium Complex
Organometallics, 2008, 27, 493
4071717 CIFC30 H29 Ni3P 1 21/c 112.505; 9.792; 19.219
90; 94.32; 90
2346.7Buchalski, Piotr; Jadach, Patryk; Pietrzykowski, Antoni; Suwińska, Kinga; Jerzykiewicz, Lucjan; Sadło, Jarosław
Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water
Organometallics, 2008, 27, 3618
4071075 CIFC23 H40 N2 O WP 1 21/c 112.6452; 8.1081; 22.9995
90; 95.311; 90
2347.98Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4070742 CIFC50 H74 B Br2 P2 PtP -18.6839; 16.0549; 17.787
78.295; 81.914; 76.596
2350.69Braunschweig, Holger; Leech, Ralph; Rais, Daniela; Radacki, Krzysztof; Uttinger, Katharina
Conversion oftrans-Bromoboryl Platinum Complexes into theircis-Analogues upon Treatment with Chelating Bisphosphines
Organometallics, 2008, 27, 418
4070911 CIFC36 H80 N12 Sr2P -19.891; 11.804; 21.654
90.608; 93.615; 111.042
2353.4Cameron, Thomas M.; Xu, Chongying; Dipasquale, Antonio G.; Rheingold, Arnold L.
Synthesis and Structure of Strontium and Barium Guanidinates and Mixed-Ligand Guanidinate Pentamethylcyclopentadienyl Complexes
Organometallics, 2008, 27, 1596
4072333 CIFC23 H24 F3 N3 O4 Ru SP 1 21/c 112.819; 12.076; 15.823
90; 105.74; 90
2357.6Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4071393 CIFC22 H39 N3 SiP -112.9556; 14.538; 15.1015
97.509; 106.363; 115.41
2359Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4072365 CIFC44 H41 Br2 N4 O3 ScP -112.4102; 13.6661; 15.9836
95.656; 108.915; 109.094
2359Lv, Kui; Cui, Dongmei
Tridentate CCC-Pincer Bis(carbene)-Ligated Rare-Earth Metal Dibromides. Synthesis and Characterization
Organometallics, 2008, 27, 5438
4071701 CIFC18 H32 Br2 N4 O4 PtP 1 21/c 111.9689; 25.0784; 8.1507
90; 105.143; 90
2361.57Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4083509 CIFC24 H23 F3 N4 O3 Pt SP 1 21/c 110.724; 24.2086; 9.2365
90; 99.893; 90
2362.26Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4071608 CIFC54 H45 Ge2 P2 PtP -112.229; 13.241; 16.754
81.668; 73.344; 65.413
2362.4Arii, Hidekazu; Nanjo, Masato; Mochida, Kunio
Characterization of Mononuclear and Dinuclear Germylplatinum Complexes and Ge−Ge Bond Formation at the Platinum Center
Organometallics, 2008, 27, 4147
4071866 CIFC22 H31 I N2 O2 PdP 1 21 16.0186; 32.173; 12.237
90; 94.131; 90
2363.4Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4070704 CIFC21 H18 Fe2 N O6 P S2P 1 21/n 112.519; 17.022; 12.706
90; 119.186; 90
2363.9Song, Li-Cheng; Wang, Hu-Ting; Ge, Jian-Hua; Mei, Shu-Zhen; Gao, Jie; Wang, Liang-Xing; Gai, Bin; Zhao, Li-Qun; Yan, Jing; Wang, Yong-Zhen
Investigations on the Active Site Models of [FeFe]-Hydrogenases: Synthesis, Structure, and Properties of N-Functionalized Azadithiolatodiiron Complexes Containing Mono- and Diphosphine Ligands
Organometallics, 2008, 27, 1409
4072348 CIFC16 H44 Li2 N4 ZnP 1 21/c 113.205; 14.9516; 12.0045
90; 94.142; 90
2363.93Armstrong, David R.; Dougan, Christine; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Synthesis and Structural Elucidation of Alkyl, Amido, and Mixed Alkyl−Amido “Highly-Coordinated” Zincates
Organometallics, 2008, 27, 6063
4071600 CIFC52 H52 Cl2 N2 O2 P4 PdP -112.819; 13.213; 14.508
89.216; 76.579; 81.903
2365.9Buchard, Antoine; Komly, Bruno; Auffrant, Audrey; Le Goff, Xavier F.; Floch, Pascal Le
A Mixed Phosphine−Iminophosphorane Tetradentate Ligand: Synthesis, Coordination to Group 10 Metal Centers, and Use as Catalyst in Suzuki−Miyaura Coupling
Organometallics, 2008, 27, 4380
4070992 CIFC77 H150 Ca6 N2 O12 Si4P -112.9348; 13.58; 15.0286
76.942; 87.619; 67.419
2371.4He, Xuyang; Hurley, Erin; Noll, Bruce C.; Henderson, Kenneth W.
Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Organometallics, 2008, 27, 3094
4070651 CIFC54 H47 Au2 N4 O0.5 P2P -113.552; 14.052; 15.189
69.737; 66.133; 66.901
2371.8Vicente, José; Gil-Rubio, Juan; Barquero, Natalia; Jones, Peter G.; Bautista, Delia
Synthesis of Luminescent Alkynyl Gold Metalaligands Containing 2,2′-Bipyridine-5-yl and 2,2′:6′,2′′-Terpyridine-4-yl Donor Groups
Organometallics, 2008, 27, 646
4072377 CIFC10 H17 Cl N2 PdC 1 2/c 120.107; 8.448; 14.16
90; 99.575; 90
2371.8Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072276 CIFC26 H35 N3P 1 21/c 19.247; 20.691; 12.481
90; 94.74; 90
2379.8Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072352 CIFC44 H52 Cu2 F6 N4P 1 2/c 112.23; 8.46; 23.49
90; 101.43; 90
2382Dubinina, Galyna G.; Ogikubo, Junichi; Vicic, David A.
Structure of Bis(trifluoromethyl)cuprate and Its Role in Trifluoromethylation Reactions
Organometallics, 2008, 27, 6233
4072262 CIFC23 H32 P2 Si VP 1 21/c 110.1297; 8.8751; 26.927
90; 100.262; 90
2382.1Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4072282 CIFC25 H33 Cl2 Fe N3P 1 21/c 117.316; 9.809; 15.391
90; 114.315; 90
2382.3Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071475 CIFC20 H39 F6 Ir N3 SbP 1 21/c 19.532; 10.833; 23.082
90; 91.304; 90
2382.83Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4070893 CIFC17 H36 B9 N3 ZrP 1 21/n 115.196; 9.917; 16.573
90; 107.43; 90
2382.9Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4072072 CIFC22 H42 Cl O2 P PdP 1 21/c 116.081; 8.681; 17.306
90; 99.208; 90
2384.8Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072361 CIFC11 H13 N4 Ni O2.5C 1 2/c 117.4537; 16.9011; 9.6894
90; 123.441; 90
2385.07Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071053 CIFC29.5 H18 Cl4 TiP 1 21/n 110.5761; 18.6258; 12.9464
90; 110.549; 90
2388Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071987 CIFC46 H58 B2 Li2 N8 O8P 1 21/n 18.6293; 15.113; 18.731
90; 101.906; 90
2390.2Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4072000 CIFC48 H68 Al Ca I O6P -19.5544; 14.2629; 19.1425
108.701; 102.449; 92.823
2392.96Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4071783 CIFC26 H41 N O WP 1 21/a 114.605; 8.6048; 20.1135
90; 108.781; 90
2393.14Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4072366 CIFC44 H41 Br2 Lu N4 O3P -112.5889; 13.6491; 15.9722
95.998; 108.746; 108.725
2394.4Lv, Kui; Cui, Dongmei
Tridentate CCC-Pincer Bis(carbene)-Ligated Rare-Earth Metal Dibromides. Synthesis and Characterization
Organometallics, 2008, 27, 5438
4071735 CIFC27 H21 N O4 P ReP 1 21/c 118.0665; 8.2603; 18.3269
90; 118.733; 90
2398.25Mirebeau, Jean-Hugues; Le Bideau, Franck; Marrot, Jérôme; Jaouen, Gérard
Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands
Organometallics, 2008, 27, 2911
4072239 CIFC24 H26 Cl2 N O4 TaP 1 21/n 18.9484; 10.9534; 24.7479
90; 98.5; 90
2399Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodríguez, Ana
Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
Organometallics, 2008, 27, 6090
4072120 CIFC28 H18 Au2 Fe N2P 1 21/c 19.0781; 24.9236; 13.4933
90; 128.191; 90
2399.5Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4072099 CIFC60 H44 N4 P2 PtP -111.1503; 15.0906; 15.5381
74.182; 83.504; 72.694
2400.17Xu, Hai-Bing; Ni, Jun; Chen, Kun-Jiao; Zhang, Li-Yi; Chen, Zhong-Ning
Preparation, Characterization, and Photophysical Properties ofcis- ortrans-PtLn2(Ln = Nd, Eu, Yb) Arrays with 5-Ethynyl-2,2′-bipyridine
Organometallics, 2008, 27, 5665
4070891 CIFC25 H31 Cl N P PdP 1 21/c 19.9685; 13.7786; 17.6498
90; 97.424; 90
2403.9Shaffer, Andrew R.; Schmidt, Joseph A. R.
Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines
Organometallics, 2008, 27, 1259
4071369 CIFC41 H72 O2 Si7P -110.1725; 11.8167; 20.9701
84.6454; 92.711; 73.972
2405.1Ozaki, Shuhei; Sasamori, Takahiro; Tokitoh, Norihiro
Synthesis of a 1-Hydrosilene Stable in Solution and Its Unique Properties#
Organometallics, 2008, 27, 2163
4072278 CIFC24 H31 Cl2 Co N3P 1 21/c 117.433; 9.802; 15.579
90; 115.26; 90
2407.6Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071115 CIFC25 H29 Mn N2 O4P 21 21 2110.5344; 13.924; 16.439
90; 90; 90
2411.3Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4071473 CIFC21 H39 F3 N3 O3 Rh SP 1 21/c 19.533; 10.886; 23.252
90; 91.804; 90
2411.8Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071240 CIFC24 H36 Ni O2 P2P 1 21/c 115.0464; 10.5122; 16.57
90; 112.802; 90
2416.07Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071073 CIFC24 H42 N2 O WP 1 21/n 111.732; 13.594; 15.641
90; 104.161; 90
2418.7Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4071650 CIFC34 H26 Fe2P 1 21/c 16.311; 19.272; 20.099
90; 98.35; 90
2419Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4070980 CIFC25 H21 Cl N5 O3 ReP 1 21/c 114.4025; 12.6203; 14.9129
90; 116.677; 90
2422.1Salassa, Luca; Garino, Claudio; Albertino, Andrea; Volpi, Giorgio; Nervi, Carlo; Gobetto, Roberto; Hardcastle, Kenneth I.
Computational and Spectroscopic Studies of New Rhenium(I) Complexes Containing Pyridylimidazo[1,5-a]pyridine Ligands: Charge Transfer and Dual Emission by Fine-Tuning of Excited States
Organometallics, 2008, 27, 1427
4071150 CIFC24 H25 O7 P WP 1 21/n 110.4536; 15.8144; 14.87
90; 99.6078; 90
2423.79Bode, Maren; Schnakenburg, Gregor; Jones, Peter G.; Streubel, Rainer
Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5Complex
Organometallics, 2008, 27, 2664
4072017 CIFC23 H26 Cl2 N2 O Pt SiP 1 21/c 112.6224; 9.555; 20.1223
90; 91.486; 90
2426.07West, Nathan M.; White, Peter S.; Templeton, Joseph L.
Alkyne Insertion into the Pt−H Bond of Pt(H)(1-pentene)(β-diiminate) Initiates a Reaction Cascade That Results in C−H Activation or C−C Coupling
Organometallics, 2008, 27, 5252
4071786 CIFC20 H12 O8 Ru2 SnP -19.6227; 15.1915; 17.7393
75.2; 75.721; 89.312
2426.1Adams, Richard D.; Trufan, Eszter
Diruthenium−Tin Complexes from the Reaction of Ph2SnH2with Ru(CO)5and Their Reactions with Bis(tri-tert-butylphosphine)platinum
Organometallics, 2008, 27, 4108
4072160 CIFC40 H66 N12 O11 Rh4P 1 21/n 116.4293; 8.8025; 17.288
90; 103.974; 90
2426.2Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072068 CIFC22 H28 O6 WP 1 21/n 19.816; 21.264; 11.675
90; 94.04; 90
2430.8Wang, Qifeng; Zhang, Wen-Xiong; Xi, Zhenfeng
Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6(M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction
Organometallics, 2008, 27, 3627
4071627 CIFC42 H42 B F20 O S3 Sc Si2P -110.7691; 12.7989; 17.9114
81.1573; 86.3644; 86.733
2431.73Tredget, Cara S.; Clot, Eric; Mountford, Philip
Synthesis, DFT Studies, and Reactions of Scandium and Yttrium Dialkyl Cations Containing Neutralfac-N3andfac-S3Donor Ligands
Organometallics, 2008, 27, 3458
4071872 CIFC112 H108 Br4 N8 Ni4 O8P 21 21 216.2679; 10.9501; 35.488
90; 90; 90
2435.7Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4070509 CIFC15 H41 B8 N3 PtC 1 2 120.4041; 9.719; 13.7472
90; 116.543; 90
2438.83Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4071500 CIFC28 H22 B F10 IrP -111.8637; 13.7856; 16.3812
105.611; 90.657; 108.065
2439.88Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4071831 CIFC25 H41 Cl2 P RuP 1 21/n 110.2138; 18.8352; 13.6626
90; 111.811; 90
2440.24Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4072046 CIFC23 H42 Ni P2P 1 21/n 110.1898; 12.5298; 19.3011
90; 97.936; 90
2440.7Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4071139 CIFC21 H10 Fe4 O9 S2P 1 21/c 113.6715; 7.1808; 24.949
90; 94.762; 90
2440.8Mathur, Pradeep; Singh, Amrendra K.; Mohanty, Jamini R.; Chatterjee, Saurav; Mobin, Shaikh M.
Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between TrimethylamineN-Oxide and Acetylenes on Fe3Te2(CO)9and Contrast with Reactions on Fe3E2(CO)9(E = S, Se)
Organometallics, 2008, 27, 5094
4072070 CIFC22 H42 Cl O2 P PdP 1 21/n 113.573; 14.203; 14.125
90; 116.313; 90
2440.8Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072367 CIFC44 H41 Br2 N4 O3 SmP -112.7112; 13.6559; 16.0694
96.391; 108.324; 108.478
2441.5Lv, Kui; Cui, Dongmei
Tridentate CCC-Pincer Bis(carbene)-Ligated Rare-Earth Metal Dibromides. Synthesis and Characterization
Organometallics, 2008, 27, 5438
4071732 CIFC22 H36 Cl3 P Ru2P 1 21/n 18.8726; 14.5203; 19.0631
90; 96.1559; 90
2441.79Miyake, Yoshihiro; Endo, Satoshi; Nomaguchi, Yohei; Yuki, Masahiro; Nishibayashi, Yoshiaki
Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Catalytic Activity toward Reactions of Propargylic Alcohols with Aromatic Compounds
Organometallics, 2008, 27, 4017
4071250 CIFC30 H29 Mn O3P 1 21/n 113.8542; 10.8128; 17.1782
90; 108.37; 90
2442.2Sentets, Stéphane; Serres, Rémi; Ortin, Yannick; Lugan, Noël; Lavigne, Guy
Directed Formation of Allene Complexes upon Reaction of Non-heteroatom-Substituted Manganese Alkynyl Carbene Complexes with Nucleophiles
Organometallics, 2008, 27, 2078
4071142 CIFC24 H37 N Ni P2P 1 21/n 19.051; 16.515; 16.53
90; 98.475; 90
2443.88Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071278 CIFC22 H38 Cl2 Si2 TiC 1 2/c 118.3852; 8.1284; 16.4522
90; 96.183; 90
2444.4Horáček, Michal; Pinkas, Jiří; Gyepes, Róbert; Kubišta, Jiří; Mach, Karel
Reactivity of SiMe2H Substituents in Permethylated Titanocene Complexes: Dehydrocoupling and Ethene Hydrosilylation
Organometallics, 2008, 27, 2635
4072279 CIFC25 H33 Cl2 Co N3P 1 21/c 117.509; 9.837; 15.598
90; 114.4; 90
2446.6Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072150 CIFC21 H27 I2 N5 O RuC 1 c 114.925; 17.76; 9.3659
90; 99.702; 90
2447.1Zeng, Fanlong; Yu, Zhengkun
Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl−N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in the Transfer Hydrogenation of Ketones
Organometallics, 2008, 27, 6025
4070910 CIFC24 H32 Cr O6 SiP 1 21 19.0373; 10.5947; 25.708
90; 96.084; 90
2447.6Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A.
Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality
Organometallics, 2008, 27, 900
4072246 CIFC27 H22 N8 O RuP 1 21/c 19.0095; 16.9233; 16.3307
90; 100.047; 90
2451.8Singh, Amardeep; Pramanik, Avijit; Das, Gopal; Mondal, Biplab
Reduction of Coordinated Acetonitrile to Ethylamine in a Ruthenium Complex byp-Phenylenediamine or Hydroquinone
Organometallics, 2008, 27, 6403
4071739 CIFC55 H56 B O1.5 P3 S2 UP -112.596; 13.3444; 17.325
68.359; 88.154; 66.305
2455.5Arliguie, Thérèse; Blug, Matthias; Le Floch, Pascal; Mézailles, Nicolas; Thuéry, Pierre; Ephritikhine, Michel
Organouranium Complexes with Phosphinine-Based SPS Pincer Ligands. Variations with the Substituent at the Phosphorus Atom
Organometallics, 2008, 27, 4158
4070819 CIFC28 H32 O6P 1 21/n 16.9725; 9.5826; 36.815
90; 91.424; 90
2459Melikyan, Gagik G.; Wild, Christopher; Toure, Pogban
Intramolecular Cyclizations of Co2(CO)6-Complexed Propargyl Radicals: Synthesis ofd,l- andmeso-1,5-Cyclodecadiynes
Organometallics, 2008, 27, 1569
4071592 CIFC53 H50 Br Cl2 N O3 P2 RuP -111.483; 11.914; 20.403
95.104; 103.517; 112.414
2459.22Chou, Hsien-Hsin; Lin, Ying-Chih; Huang, Shou-Ling; Liu, Yi-Hong; Wang, Yu
Reactions of Ruthenium Acetylide and Vinylidene Complexes Containing a 2-Pyridyl Group
Organometallics, 2008, 27, 5212
4072243 CIFC36 H56 Cl8 Ir2 N4 O8P 1 21/c 112.514; 11.847; 17.498
90; 108.541; 90
2459.5Jia, Wei-Guo; Han, Ying-Feng; Jin, Guo-Xin
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Containing 1,2-Dichalcogenolato Carborane or Carbonato Ligands
Organometallics, 2008, 27, 6035
4072256 CIFC43 H41 B Cl2 F20 N6 TiP -112.3574; 14.2186; 14.5834
86.511; 85.619; 74.544
2460.3Bolton, Paul D.; Feliz, Marta; Cowley, Andrew R.; Clot, Eric; Mountford, Philip
TiNR vs Ti−R′ Functional Group Selectivity in Titanium Imido Alkyl Cations from an Experimental Perspective
Organometallics, 2008, 27, 6096
4072176 CIFC6 H17 B10 N OP c a 2116.7029; 7.4094; 19.8847
90; 90; 90
2460.9Mukhin, Sergey N.; Kabytaev, Kuanysh Z.; Zhigareva, Galina G.; Glukhov, Ivan V.; Starikova, Zoya A.; Bregadze, Vladimir I.; Beletskaya, Irina P.
Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom
Organometallics, 2008, 27, 5937
4072050 CIFC29 H37 LaP n a 2120.064; 10.051; 12.233
90; 90; 90
2466.9Quiroga Norambuena, Victor F.; Heeres, André; Heeres, Hero J.; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
Organometallics, 2008, 27, 5672
4072418 CIFC48 H26 Cl4 F12 N4 O4P -111.0134; 12.9399; 17.9995
91.364; 97.888; 103.432
2467.2Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4072409 CIFC60 H62 B2 SiP -113.0386; 14.1669; 14.6777
67.266; 87.495; 80.888
2468.6Zhao, Shu-Bin; Wucher, Philipp; Hudson, Zachary M.; McCormick, Theresa M.; Liu, Xiang-Yang; Wang, Suning; Feng, Xiao-Dong; Lu, Zheng-Hong
Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes2Groups and the Peculiar Behavior of 1,6-(BMes2)2pyrene
Organometallics, 2008, 27, 6446
4071703 CIFC21 H25 Br2 Cl3 N4 O PtP 1 21/n 113.0583; 10.2477; 18.945
90; 103.107; 90
2469.13Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4071635 CIFC34 H26 Ni3P n a 2118.3002; 9.116; 14.8054
90; 90; 90
2469.91Buchalski, Piotr; Grabowska, Ilona; Karaskiewicz, Anna; Suwińska, Kinga; Jerzykiewicz, Lucjan
Novel 9-Nickelafluorenyl Sandwich Complexes of Nickel(II) and Cobalt(II)
Organometallics, 2008, 27, 3316
4071040 CIFC30 H28 B2 N2 ZrP 1 21/c 114.7537; 11.6042; 15.1993
90; 108.281; 90
2470.9Pan, Jun; Kampf, Jeff W.; Ashe III, Arthur J.
The Preparation and Crystal Structures of η1-Derivatives of 2-Phenyl-1,2-azaboratabenzene
Organometallics, 2008, 27, 1345
4070913 CIFC46 H86 N6 Sr2P 1 21/n 112.015; 12.68; 16.614
90; 102.513; 90
2471Cameron, Thomas M.; Xu, Chongying; Dipasquale, Antonio G.; Rheingold, Arnold L.
Synthesis and Structure of Strontium and Barium Guanidinates and Mixed-Ligand Guanidinate Pentamethylcyclopentadienyl Complexes
Organometallics, 2008, 27, 1596
4071625 CIFC26 H21 Cl N P Pd S2P 21 21 2112.7414; 12.7768; 15.1936
90; 90; 90
2473.43Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4070521 CIFC19 H34 Cl2 Fe2 N S2P 1 21/n 18.9152; 16.2139; 17.5863
90; 103.271; 90
2474.22Chen, Yanhui; Zhou, Yuhan; Qu, Jingping
Synthesis and Reactions of Novel Triply Thiolate-Bridged Diiron Complexes [Cp*Fe(μ2-SR)3FeCp*] (Cp*= η5-C5Me5; R = Et, Ph)
Organometallics, 2008, 27, 666
4071080 CIFC28 H29 Fe2 O3 PP 1 21/c 113.158; 13.171; 14.28
90; 91.119; 90
2474.3Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Nucleophilic and Electrophilic Behavior of the Phosphinidene-Bridged Complex [Fe2(η5-C5H5)2(μ-PCy)(μ-CO)(CO)2]
Organometallics, 2008, 27, 1037
4072304 CIFC55 H76.5 N4.5 P RuP -110.951; 14.3673; 16.7877
84.2967; 77.9902; 73.5579
2475.5Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4071035 CIFC17 H37 Li N4 O Si2P 1 21/n 110.603; 13.144; 17.77
90; 91.05; 90
2476.1Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4070888 CIFC27 H40 Br Ir N2P 1 21/c 117.867; 8.7314; 15.9881
90; 96.694; 90
2477.2Türkmen, Hayati; Pape, Tania; Hahn, F. Ekkehardt; Çetinkaya, Bekir
Annulated N-Heterocyclic Carbene Ligands Derived from 2-Methylaminopiperidine: Their Complexes and Catalytic Applications
Organometallics, 2008, 27, 571
4071113 CIFC25 H28 Cl Mn N2 O4P 21 21 219.4528; 12.0818; 21.7123
90; 90; 90
2479.7Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4072329 CIFC40 H90 Al2 Cr N4 P2P 1 21/n 112.604; 13.74; 14.445
90; 97.494; 90
2480.2Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Koç, Ece; Duchateau, Robbert
Isolation of a Chromium Hydride Single-Component Ethylene Polymerization Catalyst
Organometallics, 2008, 27, 5943
4072362 CIFC26 H27.5 N6 Ni O3.75P 1 21/c 19.4184; 14.4888; 18.2332
90; 93.932; 90
2482.27Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071718 CIFC30 H29 Ni3P 1 21/n 116.393; 9.319; 17.292
90; 109.71; 90
2487Buchalski, Piotr; Jadach, Patryk; Pietrzykowski, Antoni; Suwińska, Kinga; Jerzykiewicz, Lucjan; Sadło, Jarosław
Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water
Organometallics, 2008, 27, 3618
4070620 CIFC18 H24 B N7 O Ru S3P 1 21/c 114.3067; 13.3228; 13.0886
90; 91.665; 90
2493.7Crossley, Ian R.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Owen, Gareth R.; White, Andrew J. P.; Williams, David J.; Willis, Anthony C.
Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru\ρightarrow B)8and [Ru(CO)(CNR){B(mt)3}](Ru→B)8(mt = methimazolyl, R =tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)
Organometallics, 2008, 27, 381
4071679 CIFC57 H54 Fe2 Ga O6 P3P -111.3945; 14.6164; 17.6617
108.559; 99.294; 110.135
2493.7Muraoka, Takako; Motohashi, Hideaki; Hirotsu, Masakazu; Ueno, Keiji
Reactions of a Gallium-Bridged Diiron Complex with Alkyl Lithium, HCl, and Phosphines
Organometallics, 2008, 27, 3918
4071459 CIFC24 H28 N2 O4 S4P 1 21/c 124.396; 10.121; 10.18
90; 96.305; 90
2498.4Liu, Wei; Chen, Ya; Wang, Ru; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng
Rhenium(I) Tricarbonyl Complexes with New Pyridine Ligands Containing Crown Ether-Annelated or Anthracene-Functionalized 1,3-Dithiole-2-ylidene
Organometallics, 2008, 27, 2990
4071662 CIFC85 H152 Ca2 N8 Si8P -111.5618; 12.276; 18.7309
104.199; 90.16; 103.675
2499.03Barrett, Anthony G. M.; Crimmin, Mark R.; Hill, Michael S.; Kociok-Köhn, Gabriele; MacDougall, Dugald J.; Mahon, Mary F.; Procopiou, Panayiotis A.
Synthesis, Characterization, and Solution Lability of N-Heterocyclic Carbene Adducts of the Heavier Group 2 Bis(trimethylsilyl)amides
Organometallics, 2008, 27, 3939
4072234 CIFC26 H41 Cl Si TiP 21 21 2110.4972; 11.3834; 20.923
90; 90; 90
2500.17Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4070948 CIFC54 H51 Ir N4 O3 SiP -111.743; 12.886; 16.755
83.32; 84.748; 85.872
2503Li, Baozhu; Chan, Kin Shing
Base-Promoted Silicon−Hydrogen Bond Activation of Silanes by Iridium(III) Porphyrin Complexes
Organometallics, 2008, 27, 4034
4071355 CIFC19 H35 I P2 Pt SiP 1 21/c 116.982; 10.492; 15.289
90; 113.21; 90
2504Canty, Allan J.; Watson, Russell P.; Karpiniec, Samuel S.; Rodemann, Thomas; Gardiner, Michael G.; Jones, Roderick C.
Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
Organometallics, 2008, 27, 3203
4071982 CIFC70 H50 BaP 1 21/c 113.0103; 13.7274; 17.9609
90; 128.559; 90
2508.37Deacon, Glen B.; Forsyth, Craig M.; Jaroschik, Florian; Junk, Peter C.; Kay, Danielle L.; Maschmeyer, Thomas; Masters, Anthony F.; Wang, Jun; Field, Leslie D.
Accessing Decaphenylmetallocenes of Ytterbium, Calcium, and Barium by Desolvation of Solvent-Separated Ion Pairs: Overcoming Adverse Solubility Properties#
Organometallics, 2008, 27, 4772
4071249 CIFC31 H27 Mn O2 SP 1 21/n 19.923; 21.7612; 12.017
90; 104.77; 90
2509.2Sentets, Stéphane; Serres, Rémi; Ortin, Yannick; Lugan, Noël; Lavigne, Guy
Directed Formation of Allene Complexes upon Reaction of Non-heteroatom-Substituted Manganese Alkynyl Carbene Complexes with Nucleophiles
Organometallics, 2008, 27, 2078
4071983 CIFC70 H50 YbP 1 21/n 110.346; 13.4649; 18.1324
90; 95.586; 90
2513.99Deacon, Glen B.; Forsyth, Craig M.; Jaroschik, Florian; Junk, Peter C.; Kay, Danielle L.; Maschmeyer, Thomas; Masters, Anthony F.; Wang, Jun; Field, Leslie D.
Accessing Decaphenylmetallocenes of Ytterbium, Calcium, and Barium by Desolvation of Solvent-Separated Ion Pairs: Overcoming Adverse Solubility Properties#
Organometallics, 2008, 27, 4772
4071013 CIFC24 H25 Cl4 Fe N3P 1 21/c 110.414; 15.2465; 15.8488
90; 92.365; 90
2514.3Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Bobik Fones, Barbara; Fish, Brian M.; Schiffhauer, Matthew F.; Spence, Rupert E.; Xie, Tuyu
High-Temperature Catalysts for the Production of α-Olefins Based on Iron(II) and Cobalt(II) Tridentate Bis(imino)pyridine Complexes with a Double Pattern of Substitution:o-Methyl pluso-Fluorine in the Same Imino Arm†
Organometallics, 2008, 27, 1147
4071203 CIFC24 H25 Cl4 Fe N3P 1 21/c 110.414; 15.2465; 15.8488
90; 92.365; 90
2514.3Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4072159 CIFC25 H33 As Cl N PdP 21 21 219.9468; 13.537; 18.6809
90; 90; 90
2515.38Coote, Michelle L.; Krenske, Elizabeth H.; Porter, Keith A.; Weir, Michelle L.; Willis, Anthony C.; Zhou, Xiangting; Wild, S. Bruce
Asymmetric Synthesis of a Tertiary Arsine by Nucleophilic Addition to a Chiral Phosphine-Stabilized Arsenium Salt
Organometallics, 2008, 27, 5099
4071132 CIFC25 H42 P Pt SiP 1 21/a 110.053; 18.213; 13.751
90; 91.15; 90
2517.2Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4072412 CIFC16 H39 B F4 P4 RuP 21 21 219.8335; 15.5702; 16.4684
90; 90; 90
2521.5Field, Leslie D.; Magill, Alison M.; Jensen, Paul
Butenynyl and Vinylidene Complexes of Ruthenium
Organometallics, 2008, 27, 6539
4071694 CIFC21 H34 B10 N O PP 1 21/n 111.29; 10.9564; 21.1161
90; 105.089; 90
2522Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4071432 CIFC46 H61 B11 Ir N O2 P2 SnP 1 21 112.381; 14.88; 13.831
90; 98.11; 90
2522.6Kirchmann, Marius; Fleischhauer, Sebastian; Wesemann, Lars
Iridium Coordination Compounds of Stanna-closo-dodecaborate
Organometallics, 2008, 27, 2803
4070634 CIFC39 H80 Si8P -19.708; 14.996; 17.847
79.35; 87.704; 81.536
2525.4Kajiwara, Takashi; Takeda, Nobuhiro; Sasamori, Takahiro; Tokitoh, Norihiro
Synthesis of Alkali Metal Salts of Borylsilyl Anions Utilizing Highly Crowded Silylboranes and Their Properties#
Organometallics, 2008, 27, 880
4071395 CIFC22 H38 Cl2 Cr N3 SiP 1 21/c 117.1117; 8.9247; 16.6329
90; 96.069; 90
2525.9Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4071038 CIFC22 H13 I2 Mo2 O6 PP 1 21/n 111.859; 18.165; 12.637
90; 111.89; 90
2526Ricci, Antonella; Angelucci, Francesco; Chiarini, Marco; Sterzo, Claudio Lo; Masi, Dante; Giambastiani, Giuliano; Bianchini, Claudio
Bis(cyclopentadienyl)phenylphosphine as Ligand Precursor for Assembling Heteropolymetal Complexes
Organometallics, 2008, 27, 1617
4071036 CIFC18 H38 Li N5 Si2P 1 21/n 110.505; 17.673; 13.865
90; 100.61; 90
2530.1Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071730 CIFC42 H76 Fe2 In2 N2 Si6P 1 21/c 117.1413; 9.5085; 16.7639
90; 112.153; 90
2530.62Schachner, Jörg A.; Lund, Clinton L.; Burgess, Ian J.; Quail, J. Wilson; Schatte, Gabriele; Müller, Jens
The Dynamic Indium-Bridged [1.1]Ferrocenophane [(Me2Ntsi)In(C5H4)2Fe]2
Organometallics, 2008, 27, 4703
4071693 CIFC21 H34 B10 N PP 1 21/n 111.2939; 11.0589; 20.992
90; 104.995; 90
2532.6Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4070734 CIFC23 H33 Ir2 N O4 SP 1 21/c 18.504; 17.302; 17.943
90; 106.364; 90
2533Arita, Hiroko; Ishiwata, Koji; Kuwata, Shigeki; Ikariya, Takao
Acid‒Base Bifunction and Umpolung of the Bridging Hydride in a Coordinatively Unsaturated Mesylimido- and Hydrido-Bridged Diiridium Complex
Organometallics, 2008, 27, 493
4070820 CIFC29 H23 Mn O5P 1 21/c 112.864; 11.6069; 17.1408
90; 98.163; 90
2533.4Jacques, Béatrice; Chanaewa, Alina; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène
A Combined Experimental−Theoretical Study on the Lithiation/Electrophilic Quench Sequence of (η5-Cyclohexadienyl)Mn(CO)3Complexes
Organometallics, 2008, 27, 626
4072197 CIFC48.5 H66 Lu N2 O P S Si2P -112.0645; 14.3557; 15.3451
99.231; 96.813; 102.039
2533.5Wang, Dun; Li, Shihui; Liu, Xinli; Gao, Wei; Cui, Dongmei
Thiophene-NPN Ligand Supported Rare-Earth Metal Bis(alkyl) Complexes. Synthesis and Catalysis toward Highlytrans-1,4 Selective Polymerization of Butadiene
Organometallics, 2008, 27, 6531
4071648 CIFC17 H14 Fe OP 1 21/c 110.105; 12.419; 20.819
90; 103.92; 90
2535.9Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071506 CIFC20 H24 F6 N2 O6 S2 SnP 1 21/c 113.7458; 9.3395; 19.9533
90; 98.0965; 90
2536.05Kašná, Blanka; Dostál, Libor; Jirásko, Robert; Císařová, Ivana; Jambor, Roman
Role of Y,C,Y-Chelating Ligands in Control Hydrolysis of Diorganotin Compounds†
Organometallics, 2008, 27, 3743
4071479 CIFC20 H48 Li N3 ZnP 1 21/c 110.0802; 14.9984; 16.8398
90; 94.22; 90
2539.05Clegg, William; García-Álvarez, Joaquín; García-Álvarez, Pablo; Graham, David V.; Harrington, Ross W.; Hevia, Eva; Kennedy, Alan R.; Mulvey, Robert E.; Russo, Luca
Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†
Organometallics, 2008, 27, 2654
4072298 CIFC27 H38 N P RuP -18.3256; 15.1105; 21.0117
84.0995; 79.32; 78.8049
2542Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4071299 CIFC25 H34 Cl2 N O3 VP 1 21/c 17.5894; 13.7589; 24.542
90; 96.35; 90
2547Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4072052 CIFC29 H37 YP c a 2116.4646; 10.5009; 14.7315
90; 90; 90
2547Quiroga Norambuena, Victor F.; Heeres, André; Heeres, Hero J.; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
Organometallics, 2008, 27, 5672
4070990 CIFC40 H86 Ca2 N2 O4 Si4P 1 21/c 19.857; 19.686; 13.933
90; 109.45; 90
2549.3He, Xuyang; Hurley, Erin; Noll, Bruce C.; Henderson, Kenneth W.
Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Organometallics, 2008, 27, 3094
4071713 CIFC22 H28 F3 N3 O5 Pd SP 1 21/c 114.0831; 11.5607; 16.9448
90; 112.467; 90
2549.4Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4071638 CIFC23 H25 F3 N4 O5 Ru SP 1 21/c 116.616; 11.807; 15.049
90; 120.255; 90
2550Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071338 CIFC58 H44 Cl6 P2 PdP 1 21 114.0682; 12.4225; 14.9801
90; 102.862; 90
2552.3Doherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William
Biaryl-Like CATPHOS Diphosphines via Double Diels‒Alder Cycloaddition between 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne and Anthracenes: Efficient Ligands for the Palladium-Catalyzed Amination of Aromatic Bromides and α-Arylation of Ketones
Organometallics, 2008, 27, 1679
4071339 CIFC58 H44 Cl6 P2 PtP 1 21 114.0757; 12.4304; 14.9485
90; 102.585; 90
2552.6Doherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William
Biaryl-Like CATPHOS Diphosphines via Double Diels‒Alder Cycloaddition between 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne and Anthracenes: Efficient Ligands for the Palladium-Catalyzed Amination of Aromatic Bromides and α-Arylation of Ketones
Organometallics, 2008, 27, 1679
4071798 CIFC24.5 H17.5 Cl2.5 F3 N O3 Ru S2P -113.923; 14.058; 15.425
106.098; 95.814; 114.678
2553Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4070838 CIFC61 H73 B Ru3P -111.3369; 13.8483; 17.3975
70.706; 86.346; 82.148
2553.3Takao, Toshiro; Moriya, Makoto; Suzuki, Hiroharu
Insertion of Acetylene and Nitriles into a Ru‒C Bond of a Dicationic Triruthenium Complex Having a μ~3~-η^3^-C~3~ Ring: Formation of Six-Membered Ruthenacycles on a Triruthenium Core
Organometallics, 2008, 27, 1044-1054
4071396 CIFC44 H76 Cl4 Cr2 N6 Si2P 1 21/n 112.3769; 12.9565; 16.8703
90; 109.259; 90
2553.9Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4070647 CIFC49 H51 Cl P2 Pd2 SiP -19.161; 15.238; 18.554
94.636; 97.931; 91.766
2555Takahashi, Yoshiteru; Tsutsumi, Ken; Nakagai, Yuzo; Morimoto, Tsumoru; Kakiuchi, Kiyomi; Ogoshi, Sensuke; Kurosawa, Hideo
Mono- and Dipalladium Movement on the π-Conjugated Five-Carbon Chain
Organometallics, 2008, 27, 276
4071630 CIFC34 H24 B FP 1 21/n 110.975; 9.582; 24.482
90; 97.028; 90
2555So, Cheuk-Wai; Watanabe, Daisuke; Wakamiya, Atsushi; Yamaguchi, Shigehiro
Synthesis and Structural Characterization of Pentaarylboroles and Their Dianions
Organometallics, 2008, 27, 3496
4070756 CIFC61.5 H65 Fe Lu N2 O2 SiP -112.447; 15.072; 15.12
69.439; 76.291; 78.331
2558Eppinger, Jörg; Nikolaides, Katharina R.; Zhang-Presse, Mei; Riederer, Florian A.; Rabe, Gerd W.; Rheingold, Arnold L.
Alkyl Complexes of Rare-Earth Metal Centers Supported by Chelating 1,1′-Diamidoferrocene Ligands: Synthesis, Structure, and Application in Methacrylate Polymerization
Organometallics, 2008, 27, 736
4070894 CIFC17 H36 B9 Hf N3P 1 21/c 115.551; 10.17; 19.253
90; 122.79; 90
2559.8Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4070908 CIFC28 H34 Cr O4 SiP 21 21 2110.7012; 10.8019; 22.171
90; 90; 90
2562.8Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A.
Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality
Organometallics, 2008, 27, 900
4070731 CIFC21 H35 Cl2 Ir2 N O2 SP -112.244; 14.843; 15.51
114.224; 91.944; 92.901
2563Arita, Hiroko; Ishiwata, Koji; Kuwata, Shigeki; Ikariya, Takao
Acid‒Base Bifunction and Umpolung of the Bridging Hydride in a Coordinatively Unsaturated Mesylimido- and Hydrido-Bridged Diiridium Complex
Organometallics, 2008, 27, 493
4071929 CIFC24 H27 B Mo N6 O2 SP -110.7556; 14.796; 17.6052
108.689; 90.741; 103.944
2563.34Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Reactions of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes
Organometallics, 2008, 27, 4532
4071628 CIFC35 H27 BP 41 21 210.099; 10.099; 25.157
90; 90; 90
2566So, Cheuk-Wai; Watanabe, Daisuke; Wakamiya, Atsushi; Yamaguchi, Shigehiro
Synthesis and Structural Characterization of Pentaarylboroles and Their Dianions
Organometallics, 2008, 27, 3496
4071468 CIFC27 H30 Ag Br N2P 1 21/n 19.902; 17.068; 15.94
90; 107.68; 90
2566.7Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071317 CIFC40 H82 Li2 N4 O4 P2 Si2P -110.186; 15.616; 18.308
105.08; 99.53; 108.25
2571.7Leung, Wing-Por; Chan, Ka-Po; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heteroleptic Tin(II) and Lead(II) Compounds from Pyrazyl-Linked Bisphosphoranoimine
Organometallics, 2008, 27, 2767
4072212 CIFC48.74 H51.48 Cl3.48 I2 P2 Pt SP -19.8451; 15.2773; 17.2635
84.936; 84.033; 89.179
2572.4Emslie, David J. H.; Harrington, Laura E.; Jenkins, Hilary A.; Robertson, Craig M.; Britten, James F.
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η3(BCC)-Triarylborane Coordination
Organometallics, 2008, 27, 5317
4072387 CIFC21 H42 B F4 N2 P PdP 21 21 218.1831; 16.9422; 18.5709
90; 90; 90
2574.66Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072406 CIFC24 H36 Cl P3 PdP 1 21/n 114.31; 11.988; 15.352
90; 102.12; 90
2574.9Mazzeo, Mina; Lamberti, Marina; Massa, Antonio; Scettri, Arrigo; Pellecchia, Claudio; Peters, Jonas C.
Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes
Organometallics, 2008, 27, 5741
4071092 CIFC12 H16 O4 PC 1 2/c 120.816; 10.489; 12.513
90; 109.335; 90
2578Escobar, Aholibama; Donnadieu, Bruno; Mathey, François
From Functional Phospholide Ions to Bifunctional 1,1′-Diphosphaferrocenes
Organometallics, 2008, 27, 1887
4070940 CIFC58 H56 N2 Ni2 P6P 1 21/n 112.987; 14.438; 13.769
90; 92.25; 90
2579.8Acosta-Ramírez, Alberto; Flores-Álamo, Marcos; Jones, William D.; García, Juventino J.
P−C Bond Scission at the TRIPHOS Ligand and C−CN Bond Cleavage in 2-Methyl-3-butenenitrile with [Ni(COD)2]
Organometallics, 2008, 27, 1834
4071184 CIFC41 H55 Cl8 F6 N4 O P RuP -110.3228; 12.5344; 22.0194
83.698; 77.671; 68.189
2582.7Clavier, Hervé; Nolan, Steven P.; Mauduit, Marc
Ionic Liquid Anchored “Boomerang” Catalysts Bearing Saturated and Unsaturated NHCs: Recyclability in Biphasic Media for Cross-Metathesis
Organometallics, 2008, 27, 2287
4071588 CIFC63 H54 Cl2 Fe3 N2 OP -112.865; 14.584; 14.693
78.951; 72.719; 87.21
2583.4Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4070609 CIFC19 H43 B7 Fe O2 P2P 1 21/c 17.8468; 20.1965; 16.5178
90; 98.123; 90
2591.4Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4071623 CIFC51.5 H41 Cl5 N2 P2 Pd2 S4P -111.9887; 14.6611; 14.8385
89.829; 84.196; 87.873
2592.97Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4071745 CIFC27 H38 I Ir P2P 21 21 217.4979; 16.7508; 20.6495
90; 90; 90
2593.5Romero, Patricio E.; Whited, Matthew T.; Grubbs, Robert H.
Multiple C−H Activations of Methyltert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1
Organometallics, 2008, 27, 3422
4070843 CIFC55 H83 B N2 Os P2P 1 21 113.467; 13.713; 14.322
90; 101.286; 90
2593.7Eguillor, Beatriz; Esteruelas, Miguel A.; Oliván, Montserrat; Puerta, Marta
Abnormal and Normal N-Heterocyclic Carbene Osmium Polyhydride Complexes Obtained by Direct Metalation of Imidazolium Salts
Organometallics, 2008, 27, 445
4071322 CIFC25 H40 Cl N2 P PtP 1 21/n 112.6781; 10.0244; 20.893
90; 102.328; 90
2594.07Vuzman, Dana; Poverenov, Elena; Shimon, Linda J. W.; Diskin-Posner, Yael; Milstein, David
Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization
Organometallics, 2008, 27, 2627
4072187 CIFC21 H27 Al F12 N2 O3P 110.5749; 15.88; 16.688
70.161; 79.861; 85.599
2594.5Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4072109 CIFC24 H38 Si4P 1 21/c 115.9413; 10.0293; 17.9553
90; 115.261; 90
2596.2Lim, Young Mook; Lee, Myong Euy; Lee, Junseong; Do, Youngkyu
Reactivity of Bromodilithiosilane to Naphthalene and Anthracene
Organometallics, 2008, 27, 6375
4071074 CIFC25 H44 N2 O WP 1 21/n 110.776; 18.681; 13.048
90; 98.56; 90
2597.4Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4070897 CIFC40 H76 B18 Hf2 N2 O6P 1 21/n 19.4478; 14.7429; 18.82
90; 97.712; 90
2597.7Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4072311 CIFC23 H31 F6 I Ir N2 PP 1 21/n 111.3177; 12.8037; 17.9585
90; 91.143; 90
2601.82Song, Guoyong; Zhang, Yao; Su, Yan; Deng, Weiqiao; Han, Keli; Li, Xingwei
Pyridine-Based N-Heterocyclic Carbene Hydride Complexes of Iridium via C−H Activation
Organometallics, 2008, 27, 6193
4071164 CIFC66 H52 Br2 N4 NiP 1 21/n 110.8585; 15.3435; 15.6337
90; 90.693; 90
2604.5Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071062 CIFC28 H36 O4 SiP -19.845; 16.663; 17.247
68.294; 89.725; 83.072
2607.1Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
Organometallics, 2008, 27, 4318
4072314 CIFC27 H25 Cl2 N5 TiC 1 2/c 114.011; 19.8007; 9.4425
90; 93.9572; 90
2613.36Selby, Jonathan D.; Manley, Catherine D.; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study
Organometallics, 2008, 27, 6479
4070984 CIFC28 H23 Cr N O7P 21 21 2112.693; 13.031; 15.808
90; 90; 90
2614.68Meca, Luděk; Císařová, Ivana; Drahoňovský, Dušan; Dvořák, Dalimil
Enantiomerically Pure Axially Chiral Aminocarbene Complexes of Chromium
Organometallics, 2008, 27, 1850
4071941 CIFC62 H44 F8 Ni P4P -112.6153; 12.735; 17.2316
81.818; 79.226; 75.125
2615.42Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4071943 CIFC62 H44 F8 P4 PtP -112.6153; 12.735; 17.2316
81.818; 79.226; 75.125
2615.42Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4072405 CIFC27 H36 B Ir N6 OP 1 21/n 18.0575; 20.3891; 16.4221
90; 104.086; 90
2616.8Paneque, Margarita; Poveda, Manuel L.; Santos, Laura L.; Carmona, Ernesto; Mereiter, Kurt
Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound
Organometallics, 2008, 27, 6353
4070782 CIFC29 H38 Cl Ir N2P 1 21/c 115.4063; 11.8278; 15.0331
90; 107.026; 90
2619.3Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4072313 CIFC24 H29 F6 I Ir N2 SbP 1 21/c 114.5088; 12.9346; 14.1699
90; 99.892; 90
2619.67Song, Guoyong; Zhang, Yao; Su, Yan; Deng, Weiqiao; Han, Keli; Li, Xingwei
Pyridine-Based N-Heterocyclic Carbene Hydride Complexes of Iridium via C−H Activation
Organometallics, 2008, 27, 6193
4072258 CIFC48 H55 B F20 N6 Si TiP -111.9619; 12.7619; 17.984
75.5723; 80.1952; 86.9238
2619.78Bolton, Paul D.; Feliz, Marta; Cowley, Andrew R.; Clot, Eric; Mountford, Philip
TiNR vs Ti−R′ Functional Group Selectivity in Titanium Imido Alkyl Cations from an Experimental Perspective
Organometallics, 2008, 27, 6096
4070637 CIFC43 H85 B O2 Si7P -19.22; 12.874; 23.73
100.332; 92.284; 108.119
2620Kajiwara, Takashi; Takeda, Nobuhiro; Sasamori, Takahiro; Tokitoh, Norihiro
Synthesis of Alkali Metal Salts of Borylsilyl Anions Utilizing Highly Crowded Silylboranes and Their Properties#
Organometallics, 2008, 27, 880
4071041 CIFC24 H46 N P2 RhP 21 21 2113.052; 13.841; 14.526
90; 90; 90
2624.16Hanson, Susan Kloek; Heinekey, D. Michael; Goldberg, Karen I.
C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water
Organometallics, 2008, 27, 1454
4071826 CIFC18 H42 Fe O5 P4P 1 21/c 19.2623; 17.5775; 16.578
90; 103.317; 90
2626.5Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.
Reductive Disproportionation of Carbon Dioxide at an Iron(II) Center
Organometallics, 2008, 27, 3328
4071846 CIFC25 H43 Fe N O2 P2P 21 21 2111.7404; 14.5944; 15.3327
90; 90; 90
2627.2Pelczar, Elizabeth M.; Emge, Thomas J.; Krogh-Jespersen, Karsten; Goldman, Alan S.
Unusual Structural and Spectroscopic Features of Some PNP-Pincer Complexes of Iron
Organometallics, 2008, 27, 5759
4072001 CIFC52 H80 Al2 Ca O6P 1 21/n 112.8483; 15.8241; 12.9309
90; 90; 90
2629.02Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4071275 CIFC25 H17 Fe2 O6 P S2P 1 21/c 115.333; 10.876; 17.09
90; 112.554; 90
2632Song, Li-Cheng; Zeng, Guang-Huai; Lou, Shao-Xia; Zan, Hui-Ning; Ming, Jiang-Bo; Hu, Qing-Mei
Synthetic and Structural Studies of Butterfly Fe/S/P Cluster Complexes Related to the Active Site of [FeFe]-Hydrogenases. Proton Reduction to H2Catalyzed by (η1-Ph2PS-η1)2Fe2(CO)6
Organometallics, 2008, 27, 3714
4071060 CIFC33 H26 Cl2 O TiP 1 21/c 113.3823; 10.8547; 18.1479
90; 92.797; 90
2633.04Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4072071 CIFC23 H44 Cl3 O2 P PdP 1 21/n 112.052; 10.073; 22.418
90; 104.159; 90
2639Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072373 CIFC18 H13 BP 1 21/c 120.523; 17.4242; 7.418
90; 95.576; 90
2640.1Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4070750 CIFC55 H48 Cl5 Ir N2 O4 P2P -114.039; 14.109; 16.251
87.69; 65.47; 66
2643Di Salvo, Florencia; Estrin, Darío A.; Leitus, Gregory; Doctorovich, Fabio
Synthesis, Structure, and Reactivity of Aliphatic Primary Nitrosamines Stabilized by Coordination to [IrCl5]2−
Organometallics, 2008, 27, 1985
4070892 CIFC26 H31 F3 N O3 P Pd SP 1 21/c 111.2833; 8.8106; 26.981
90; 99.783; 90
2643.25Shaffer, Andrew R.; Schmidt, Joseph A. R.
Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines
Organometallics, 2008, 27, 1259
4071455 CIFC27 H31 Cl2 N2 O VC 1 c 119.4008; 9.8601; 16.1374
90; 121.044; 90
2644.8Onishi, Yoshifumi; Katao, Shohei; Fujiki, Michiya; Nomura, Kotohiro
Synthesis and Structural Analysis of (Arylimido)vanadium(V) Complexes Containing Phenoxyimine Ligands: New, Efficient Catalyst Precursors for Ethylene Polymerization
Organometallics, 2008, 27, 2590
4070513 CIFC55 H42 O6 P2 Ru3 S4P -113.243; 13.758; 16.578
97.57; 91.79; 117.29
2646.4Begum, Noorjahan; Hyder, Md. Iqbal; Hassan, Mohammad R.; Kabir, Shariff E.; Bennett, Dennis W.; Haworth, Daniel T.; Siddiquee, Tasneem A.; Rokhsana, Dalia; Sharmin, Ayesha; Rosenberg, Edward
Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenide and Capping Chalcogenido Ligands
Organometallics, 2008, 27, 1550
4071949 CIFC54.5 H58 Mg O5 SP -114.1759; 14.8279; 15.2796
104.389; 116.698; 98.781
2646.5Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970
4071417 CIFC28 H42 Mo N2 OP 1 21/c 114.8524; 9.2086; 20.619
90; 110.106; 90
2648.2Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4070545 CIFC27 H44 K O PP 1 21/n 111.3181; 18.874; 13.5474
90; 113.76; 90
2648.7Brady, Erik D.; Chmely, Stephen C.; Jayaratne, Kumudini C.; Hanusa, Timothy P.; Young, Victor G.
s-Block Metal Complexes of the Bis(tetramethylcyclopentadienyl) Phosphonium Diylide [Me(t-Bu)P(C5Me4)2]−
Organometallics, 2008, 27, 1612
4071552 CIFC8.5 H4 Fe2 O6 S2I b a 211.825; 17.627; 12.708
90; 90; 90
2649Song, Li-Cheng; Fang, Xiao-Niu; Li, Chang-Gong; Yan, Jing; Bao, Hai-Lin; Hu, Qing-Mei
Novel μ-CO-Containing Butterfly Fe/S Cluster Anions Generated from Tetrathiols, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles To Give Neutral Butterfly Fe/S Cluster Complexes
Organometallics, 2008, 27, 3225
4070616 CIFC48 H40 N12 O12 Re4P 1 21/c 19.9044; 15.6627; 17.5653
90; 103.424; 90
2650.5Wu, Jing-Yun; Thanasekaran, P.; Cheng, Yi-Wei; Lee, Chung-Chou; Manimaran, B.; Rajendran, T.; Liao, Rong-Tang; Lee, Gene-Hsiang; Peng, Shie-Ming; Lu, Kuang-Lieh
Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles
Organometallics, 2008, 27, 2141
4071828 CIFC23 H38 Cl5 P RuP 1 21/c 112.757; 15.4559; 13.4577
90; 92.309; 90
2651.31Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071241 CIFC26 H36 Ni O4 P2P 1 21/c 111.1191; 16.6497; 14.3339
90; 90.172; 90
2653.62Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071599 CIFC54 H52 Br2 Cl4 N2 Ni P4P -112.498; 13.157; 16.541
86.688; 86.511; 78.482
2657.3Buchard, Antoine; Komly, Bruno; Auffrant, Audrey; Le Goff, Xavier F.; Floch, Pascal Le
A Mixed Phosphine−Iminophosphorane Tetradentate Ligand: Synthesis, Coordination to Group 10 Metal Centers, and Use as Catalyst in Suzuki−Miyaura Coupling
Organometallics, 2008, 27, 4380
4071951 CIFC52.5 H58.5 Cl Mg O5 SP -113.9706; 14.9301; 15.4703
103.167; 116.353; 100.663
2659.8Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970
4071167 CIFC60 H58 Br2 N6 Ni O2P 1 21/n 110.5341; 17.8161; 14.2407
90; 94.987; 90
2662.5Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071543 CIFC27 H36 Cl N2 O3 RhP 1 21/c 115.962; 10.6524; 17.215
90; 114.013; 90
2673.8Ito, Jun-ichi; Miyakawa, Takeshi; Nishiyama, Hisao
Amine-Assisted C−Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
Organometallics, 2008, 27, 3312
4071869 CIFC30 H31 Br N2 O2 PdP 21 21 216.6808; 19.625; 20.422
90; 90; 90
2677.5Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4070890 CIFC23.5 H29 Cl5 N P PdP 1 21/n 112.6691; 15.0351; 14.1201
90; 94.963; 90
2679.5Shaffer, Andrew R.; Schmidt, Joseph A. R.
Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines
Organometallics, 2008, 27, 1259
4071090 CIFC25 H31 F6 Fe N2 P PdP 21 c n11.248; 12.039; 19.803
90; 90; 90
2682Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4071685 CIFC64 H63 Mo N O4P -112.194; 12.241; 20.29
88.751; 76.586; 66.079
2684Schrock, Richard R.; Tonzetich, Zachary J.; Lichtscheidl, Alejandro G.; Müller, Peter; Schattenmann, Florian J.
Carboxylate-Based Molybdenum Alkylidene Catalysts: Synthesis, Characterization, and Use as Initiators for 1,6-Heptadiyne Cyclopolymerizations
Organometallics, 2008, 27, 3986
4071032 CIFC20 H41 Li N4 O Si2P 1 21/n 110.708; 19.073; 13.227
90; 96.24; 90
2685.4Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071930 CIFC24 H39 B Mo N8 O3P 1 21/c 19.952; 16.9385; 15.9761
90; 92.829; 90
2689.84Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Reactions of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes
Organometallics, 2008, 27, 4532
4071360 CIFC31 H34 Ir N O2P 1 21/n 110.922; 19.511; 12.677
90; 95.293; 90
2689.9Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4070714 CIFC55 H66 N3 P Rh Si4 SnP -111.87; 11.947; 19.451
85.419; 81.054; 81.686
2691.5Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
Triamidostannates(II) as Sterically Demanding Ligands for Rhodium and Iridium
Organometallics, 2008, 27, 524
4070924 CIFC26 H32 Cl F6 Ir N2 P2P 1 21/c 112.5058; 7.2918; 29.657
90; 95.284; 90
2692.92Song, Guoyong; Wang, Xinjiao; Li, Yongxin; Li, Xingwei
Iridium Abnormal N-Heterocyclic Carbene Hydrides via Highly Selective C−H Activation
Organometallics, 2008, 27, 1187
4071242 CIFC27 H36 Ni O5 P2P 1 21/c 114.9964; 9.3798; 19.6238
90; 102.52; 90
2694.71Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071967 CIFC20 H30 Cl4 O3 Si2 Ti2C 1 2/c 115.4858; 8.3884; 21.9165
90; 108.691; 90
2696.82Postigo, Lorena; Vázquez, Ana B.; Sánchez-Nieves, Javier; Royo, Pascual; Herdtweck, Eberhardt
Mono- and Dinuclear Cyclopentadienylsiloxo Titanium Complexes: Synthesis, Reactivity, and Catalytic Polymerization Applications
Organometallics, 2008, 27, 5588
4070517 CIFC55 H42 O6 P2 Ru3 S0 Se4P -113.103; 13.604; 17.044
95.79; 93.41; 115.75
2704.3Begum, Noorjahan; Hyder, Md. Iqbal; Hassan, Mohammad R.; Kabir, Shariff E.; Bennett, Dennis W.; Haworth, Daniel T.; Siddiquee, Tasneem A.; Rokhsana, Dalia; Sharmin, Ayesha; Rosenberg, Edward
Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenide and Capping Chalcogenido Ligands
Organometallics, 2008, 27, 1550
4072417 CIFC60 H62 Cl4 N4P -112.7286; 15.2208; 15.4805
104.52; 105.413; 99.82
2707.06Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4071456 CIFC28 H33 Cl2 N2 O VP 21 21 2111.2178; 14.2133; 16.9951
90; 90; 90
2709.73Onishi, Yoshifumi; Katao, Shohei; Fujiki, Michiya; Nomura, Kotohiro
Synthesis and Structural Analysis of (Arylimido)vanadium(V) Complexes Containing Phenoxyimine Ligands: New, Efficient Catalyst Precursors for Ethylene Polymerization
Organometallics, 2008, 27, 2590
4072253 CIFC24 H51 N Os P2P 1 21/n 19.053; 23.341; 12.827
90; 90.305; 90
2710.4Esteruelas, Miguel A.; Forcén, Elena; Oliván, Montserrat; Oñate, Enrique
Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative
Organometallics, 2008, 27, 6188
4071451 CIFC26 H18 Cr2 Fe O12C 1 2/c 112.391; 14.6211; 14.9681
90; 90.047; 90
2711.8Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4070599 CIFC53 H53 B Co2 Mo N6 O6 P2 SeP -19.1891; 12.9671; 23.1494
87.108; 81.2931; 84.9957
2714.26Caldwell, Lorraine M.; Hill, Anthony F.; Rae, A. David; Willis, Anthony C.
Alkynylselenolatoalkylidynes: [Mo(CSeCCR)(CO)2{HB(pzMe2)3}] (R = CMe3, SiMe3; pzMe2= 3,5-Dimethylpyrazol-1-yl)
Organometallics, 2008, 27, 341
4071926 CIFC48 H74 B2 Mo2 N14 O5P 1 21/c 18.053; 17.1793; 19.9944
90; 101.063; 90
2714.72Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Reactions of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes
Organometallics, 2008, 27, 4532
4071847 CIFC23 H43 Cl2 Fe N P2P 1 21/n 112.0831; 15.5084; 14.5049
90; 91.093; 90
2717.6Pelczar, Elizabeth M.; Emge, Thomas J.; Krogh-Jespersen, Karsten; Goldman, Alan S.
Unusual Structural and Spectroscopic Features of Some PNP-Pincer Complexes of Iron
Organometallics, 2008, 27, 5759
4070574 CIFC27 H37 F36 Ir2 N3 O12 P6P -111.982; 12.206; 21.559
80.422; 79.953; 61.608
2718.6Esswein, Arthur J.; Veige, Adam S.; Piccoli, Paula M. B.; Schultz, Arthur J.; Nocera, Daniel G.
Intramolecular C−H Bond Activation and Redox Isomerization across Two-Electron Mixed Valence Diiridium Cores
Organometallics, 2008, 27, 1073
4072164 CIFC20 H36 B F4 N4 O6 Rh2C 1 2/c 112.4694; 17.4131; 13.4049
90; 110.823; 90
2720.5Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4071201 CIFC22 H39 F2 O4 P3 RhP -18.404; 16.6; 20.931
102.71; 95.99; 104.26
2721.6Salem, Hiyam; Shimon, Linda J. W.; Leitus, Gregory; Weiner, Lev; Milstein, David
B−C Bond Cleavage of BArFAnion Upon Oxidation of Rhodium(I) with AgBArF. Phosphinite Rhodium(I), Rhodium(II), and Rhodium(III) Pincer Complexes
Organometallics, 2008, 27, 2293
4071016 CIFC24 H24 Cl2 Co F I2 N3P 1 21/n 113.3251; 14.5228; 14.7832
90; 107.941; 90
2721.7Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Bobik Fones, Barbara; Fish, Brian M.; Schiffhauer, Matthew F.; Spence, Rupert E.; Xie, Tuyu
High-Temperature Catalysts for the Production of α-Olefins Based on Iron(II) and Cobalt(II) Tridentate Bis(imino)pyridine Complexes with a Double Pattern of Substitution:o-Methyl pluso-Fluorine in the Same Imino Arm†
Organometallics, 2008, 27, 1147
4071711 CIFC45 H73 F6 Fe2 Mo N2 O7 P4 S2P -110.8177; 11.2497; 23.4127
77.5875; 78.6013; 84.5651
2723.7Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki; Wakiji, Issei; Hidai, Masanobu
Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Organometallics, 2008, 27, 3947
4072240 CIFC25 H26 Cl F3 N O7 S TaP 1 21/c 18.9762; 14.6889; 20.673
90; 91.598; 90
2724.7Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodríguez, Ana
Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
Organometallics, 2008, 27, 6090
4071034 CIFC20 H41 Li N4 O Si2P 1 21 110.458; 26.418; 10.945
90; 115.69; 90
2725Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4072225 CIFC34 H39 TiP 1 21/c 110.0271; 13.3244; 20.5151
90; 95.788; 90
2726.95Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4071440 CIFC54 H90 Lu2 O2 Si2P 1 21/n 113.0585; 10.1678; 20.55
90; 91.842; 90
2727.1Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4070739 CIFC23 H46 Li N O Si2P 1 21/n 19.9324; 17.397; 16.0983
90; 101.203; 90
2728.7Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming
Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^
Organometallics, 2008, 27, 678-682
4072379 CIFC28 H32 B F4 N2 P PdP 1 21/n 116.804; 8.897; 18.902
90; 105.072; 90
2728.73Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4071379 CIFC30 H32 Cl Cu P2P 1 21/n 19.0865; 21.048; 14.503
90; 100.17; 90
2730.2Daly, Stephen; Haddow, Mairi F.; Orpen, A. Guy; Rolls, Giles T. A.; Wass, Duncan F.; Wingad, Richard L.
Copper(I) Diphosphine Catalysts for C−N Bond Formation: Synthesis, Structure, and Ligand Effects
Organometallics, 2008, 27, 3196
4071144 CIFC30 H33 N Ni P2P 1 21/a 117.922; 8.081; 20.62
90; 113.842; 90
2731.5Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4072292 CIFC23 H35 B Mo N6 O3 SeP 1 21/c 18.0591; 18.4282; 18.6374
90; 99.198; 90
2732.34Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Facile Generation of Lithiocarbyne Complexes: [M(CLi)(CO)2{HB(pzMe2)3}] (M = Mo, W; pz = Pyrazol-1-yl)
Organometallics, 2008, 27, 5177
4072336 CIFC25 H27 F6 N6 O Os PP 1 21/c 117.261; 10.044; 16.238
90; 103.9; 90
2732.7Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4070608 CIFC18.5 H42 B7 Cl Fe O2 P2P -112.2721; 14.7948; 17.112
106.637; 107.82; 98.8
2733.7Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4070682 CIFC44 H36 B11 Cl12 Ir O P2P -112.3768; 13.7609; 17.074
75.545; 82.197; 77.793
2741.7Douvris, Christos; Reed, Christopher A.
Increasing the Reactivity of Vaska’s Compound. Oxidative Addition of Chlorobenzene at Ambient Temperature
Organometallics, 2008, 27, 807
4070520 CIFC26 H45 Fe2 S3P 1 21/n 110.3794; 17.0781; 15.4868
90; 92.412; 90
2742.8Chen, Yanhui; Zhou, Yuhan; Qu, Jingping
Synthesis and Reactions of Novel Triply Thiolate-Bridged Diiron Complexes [Cp*Fe(μ2-SR)3FeCp*] (Cp*= η5-C5Me5; R = Et, Ph)
Organometallics, 2008, 27, 666
4070510 CIFC17 H34 B8 I2 N2 PtP 1 21/c 114.3012; 10.3809; 22.6397
90; 125.297; 90
2743.2Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4071710 CIFC45 H73 F6 Fe2 N2 O7 P4 S2 WP -110.9423; 11.2199; 23.4042
77.6402; 78.933; 83.6774
2747.42Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki; Wakiji, Issei; Hidai, Masanobu
Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Organometallics, 2008, 27, 3947
4072156 CIFC54 H76 Cl2 Cu2 N2 O2P -112.7591; 14.5248; 17.2981
111.594; 100.07; 104.797
2750Olson, Jeremy A.; Boyd, Ramon; Quail, J. Wilson; Foley, Stephen R.
Copper(II) Ethylene Polymerization Catalysts: Do They Really Exist?
Organometallics, 2008, 27, 5333
4072338 CIFC25.75 H38.5 Cl2 N3 O0.25 Os PP -19.2152; 16.7244; 18.191
91.582; 99.521; 95.268
2750.7Esteruelas, Miguel A.; Fernández-Alvarez, Francisco J.; Oñate, Enrique
NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism
Organometallics, 2008, 27, 6236
4070571 CIFC21 H28 Cl N2 O3 P2 ReC 1 2 122.692; 11.993; 10.439
90; 104.375; 90
2752Das, Atanu Kumar; Bulak, Ece; Sarkar, Biprajit; Lissner, Falk; Schleid, Thomas; Niemeyer, Mark; Fiedler, Jan; Kaim, Wolfgang
Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate LigandR,R-QuinoxP
Organometallics, 2008, 27, 218
4071407 CIFC32 H37 Mn O3P n a 2126.234; 16.479; 6.3671
90; 90; 90
2752.6Price, Craig J.; Zeits, Paul D.; Reibenspies, Joseph H.; Miller, Stephen A.
Octamethyloctahydrodibenzofluorenyl: Electronic Comparisons between a Sterically Expanded Ligand and Its Cyclopentadienyl Analogues
Organometallics, 2008, 27, 3722
4072306 CIFC59 H78 Ni2 O6 P2 S2P -110.524; 14.941; 17.791
87.493; 85.024; 81.311
2753.6Zhou, Xiaoyuan; Bontemps, Sébastien; Jordan, Richard F.
Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes
Organometallics, 2008, 27, 4821
4071272 CIFC37 H34 N VP 1 21/n 19.5142; 30.774; 10.501
90; 116.33; 90
2755.6Liu, Guohua; Lu, Xiaoquan; Gagliardo, Marcella; Beetstra, Dirk J.; Meetsma, Auke; Hessen, Bart
Vanadium (β-(Dimethylamino)ethyl)cyclopentadienyl Complexes with Diphenylacetylene Ligands
Organometallics, 2008, 27, 2316
4072026 CIFC24 H B F21 N6 TlP -19.6514; 18.1834; 18.2284
64.197; 89.612; 74.763
2757.4Despagnet-Ayoub, Emmanuelle; Jacob, Kane; Vendier, Laure; Etienne, Michel; Álvarez, Eleuterio; Caballero, Ana; Díaz-Requejo, M. Mar; Pérez, Pedro J.
A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)
Organometallics, 2008, 27, 4779
4070633 CIFC24 H84 La2 N6 Si12P -110.967; 11.242; 26.084
85.594; 78.046; 61.295
2758.6Yuen, Holming F.; Marks, Tobin J.
Synthesis and Catalytic Properties of Phenylene-Bridged Binuclear Organolanthanide Complexes
Organometallics, 2008, 27, 155
4071429 CIFC17 H10 Ag5 F12 O11P 1 2/c 111.6074; 12.2988; 22.4969
90; 120.287; 90
2773.2Zang, Shuang-Quan; Zhao, Liang; Mak, Thomas C. W.
Diverse Intermolecular Interactions in Metal−Organic Frameworks Constructed with the New Supramolecular Synthon Agn−L−Agn(n= 4, 5) (H2L = 2,2′-Bis(prop-2-ynyloxy)biphenyl)
Organometallics, 2008, 27, 2396
4072254 CIFC24 H50 Cl N Os P2P 1 21/n 110.867; 15.319; 17.315
90; 105.762; 90
2774Esteruelas, Miguel A.; Forcén, Elena; Oliván, Montserrat; Oñate, Enrique
Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative
Organometallics, 2008, 27, 6188
4072201 CIFC32 H35 Cl Hf SiP 1 21/c 117.2434; 10.037; 17.8692
90; 116.194; 90
2775.06Bryliakov, Konstantin P.; Talsi, Evgenii P.; Voskoboynikov, Alexander Z.; Lancaster, Simon J.; Bochmann, Manfred
Formation and Structures of Hafnocene Complexes in MAO- and AlBui3/CPh3[B(C6F5)4]-Activated Systems
Organometallics, 2008, 27, 6333
4070665 CIFC22 H34 Cl2 N4 O5 RuP 1 21/n 110.236; 10.781; 25.187
90; 92.132; 90
2777.57Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4070518 CIFC22 H35 B F4 Mo O7 P2P 1 21/n 110.5384; 13.0298; 20.266
90; 93.439; 90
2777.8Grime, Richard W.; Helliwell, Madeleine; Hussain, Zaffar I.; Lancashire, Hannah N.; Mason, Christopher R.; McDouall, Joseph J. W.; Mydlowski, Christopher M.; Whiteley, Mark W.
Metallacumulenylidene Complexes in the Cycloheptatrienyl Molybdenum Series [Mo{(C)nCR2}L2(η-C7H7)]+(n= 0−2; L2= P-Donor Ligand). X-ray Crystal Structures of [Mo{CC(H)Ph}{P(OMe)3}2(η-C7H7)][BF4] and [Mo(CCCPh2)(dppe)(η-C7H7)][PF6] and DFT Investigation of Cumulenylidene Ligand Orientations
Organometallics, 2008, 27, 857
4071439 CIFC54 H90 Dy2 O2 Si2P 1 21/n 113.211; 10.2343; 20.566
90; 91.11; 90
2780.1Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4070718 CIFC23 H36 B Cl3 F4 N2 Pd RuP 1 21/c 19.77336; 19.3029; 14.73985
90; 91.055; 90
2780.26Bonnet, Sylvestre; Lutz, Martin; Spek, Anthony L.; Koten, Gerard van; Klein Gebbink, Robertus J. M.
η6-Coordination of a Ruthenium(II) Organometallic Fragment to the Arene Ring of N,C,N-Pincer Metal Complexes
Organometallics, 2008, 27, 159
4072003 CIFC31 H50 O P2 RuP 1 21/n 19.9048; 16.2576; 17.4663
90; 98.693; 90
2780.26Bolton, Paul D.; Grellier, Mary; Vautravers, Nicolas; Vendier, Laure; Sabo-Etienne, Sylviane
Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols
Organometallics, 2008, 27, 5088
4070717 CIFC23 H36 B Cl3 F4 N2 Pt RuP 1 21/c 19.7601; 19.3294; 14.7733
90; 91.19; 90
2786.5Bonnet, Sylvestre; Lutz, Martin; Spek, Anthony L.; Koten, Gerard van; Klein Gebbink, Robertus J. M.
η6-Coordination of a Ruthenium(II) Organometallic Fragment to the Arene Ring of N,C,N-Pincer Metal Complexes
Organometallics, 2008, 27, 159
4072097 CIFC16 H22 O2 PtC 1 2/c 120.776; 13.85; 11.4466
90; 122.207; 90
2786.9Wu, Jianguo; Sharp, Paul R.
CO, Isocyanide, Alkene, and Alkyne Insertions into Platinaoxetane Pt−O Bonds
Organometallics, 2008, 27, 4810
4072325 CIFC31 H34 Fe N4P 1 21/a 19.0356; 27.0393; 11.4976
90; 97.113; 90
2787.43Ogasawara, Masamichi; Watanabe, Susumu; Nakajima, Kiyohiko; Takahashi, Tamotsu
Preparation of [4]- and [5]Ferrocenophanes by Ruthenium-Catalyzed Ring-Closing Ene−Yne Metathesis
Organometallics, 2008, 27, 6565
4070567 CIFC55 H42 Ir N5 O2P 1 21/c 17.6573; 16.574; 21.973
90; 90.18; 90
2788.6Cheung, Chi Wai; Chan, Kin Shing
Base-Promoted Selective Activation of Benzylic Carbon−Hydrogen Bonds of Toluenes by Iridium(III) Porphyrin
Organometallics, 2008, 27, 3043
4071055 CIFC37 H26 Cl2 O TiP 1 21/c 114.6198; 10.0172; 19.524
90; 102.673; 90
2789.6Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071993 CIFC30 H22 B2 Mn2 N12 O6R -3 :H11.6044; 11.6044; 23.935
90; 90; 120
2791.3Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071620 CIFC51 H80 O8 P4 W2P -114.3209; 15.2303; 15.9883
110.816; 108.949; 105.043
2791.99Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4070560 CIFC51 H67 K N3 O8 S6 UP -111.5158; 12.3498; 21.6525
90.184; 93.485; 114.484
2795.9Roger, Mathieu; Belkhiri, Lotfi; Arliguie, Thérèse; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
Uranium and Lanthanide Complexes with the 2-Mercapto Benzothiazolate Ligand: Evidence for a Specific Covalent Binding Site in the Differentiation of Isostructural Lanthanide(III) and Actinide(III) Compounds
Organometallics, 2008, 27, 33
4071356 CIFC30 H33 Cl3 Ir NP 21 21 2111.557; 11.913; 20.31
90; 90; 90
2796.3Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4070661 CIFC25 H40 N4 O4 RuP 1 21/a 116.519; 10.743; 17.38
90; 114.699; 90
2802.15Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4071316 CIFC36 H86 N6 P2 Pb2 Si6P -112.4223; 15.818; 16.737
66.813; 75.262; 69.288
2802.2Leung, Wing-Por; Chan, Ka-Po; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heteroleptic Tin(II) and Lead(II) Compounds from Pyrazyl-Linked Bisphosphoranoimine
Organometallics, 2008, 27, 2767
4071438 CIFC54 H90 O2 Si2 Y2P 1 21/n 113.2388; 10.2802; 20.5965
90; 91.044; 90
2802.7Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4083503 CIFC80 H80 Cl4 F12 Ir4 N4 O20 S4P -18.43; 16.397; 21.769
103.33; 101.033; 99.267
2807Han, Ying-Feng; Lin, Yue-Jian; Jia, Wei-Guo; Jin, Guo-Xin
Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†
Organometallics, 2008, 27, 4088
4072339 CIFC68 H48 B F20 N ZrP -113.368; 14.468; 17.283
113.805; 91.394; 110.625
2807.6Wilson, Polly A.; Wright, Joseph A.; Oganesyan, Vasily S.; Lancaster, Simon J.; Bochmann, Manfred
Structural Characterization of a Cationic Zirconocene Dimethylaniline Complex and Related Catalytically Relevant Species
Organometallics, 2008, 27, 6371
4083506 CIFC26 H33 Cl2 N3 Ni O4P 1 21/c 19.984; 12.774; 22.118
90; 95.56; 90
2807.6Gao, Rong; Zhang, Min; Liang, Tongling; Wang, Fosong; Sun, Wen-Hua
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization
Organometallics, 2008, 27, 5641
4070983 CIFC30 H27 Cr N O7P 1 21 17.8806; 11.5719; 30.8273
90; 92.077; 90
2809.4Meca, Luděk; Císařová, Ivana; Drahoňovský, Dušan; Dvořák, Dalimil
Enantiomerically Pure Axially Chiral Aminocarbene Complexes of Chromium
Organometallics, 2008, 27, 1850
4070586 CIFC45 H50 Br Cl6 I N6 O2 P2 Rh2P -114.2878; 14.4048; 15.9943
105.019; 113.443; 97.7086
2810.5Wells, Kyle D.; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
Organometallics, 2008, 27, 691
4071315 CIFC36 H86 N6 P2 Si6 Sn2P -112.192; 15.576; 15.974
83.363; 69.356; 89.615
2817.8Leung, Wing-Por; Chan, Ka-Po; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heteroleptic Tin(II) and Lead(II) Compounds from Pyrazyl-Linked Bisphosphoranoimine
Organometallics, 2008, 27, 2767
4071194 CIFC31 H32 I P PdP 1 21/c 114.8326; 10.1125; 18.9106
90; 95.575; 90
2823.1Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071028 CIFC21 H43 Li N4 Si2P 1 21/c 110.203; 29.221; 10.481
90; 115.36; 90
2823.7Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071655 CIFC23 H43 I2 N P2 RuP 1 21/c 114.88; 12.005; 16.352
90; 104.79; 90
2824.3Zhang, Jing; Gandelman, Mark; Shimon, Linda J. W.; Milstein, David
Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes
Organometallics, 2008, 27, 3526
4072307 CIFC25 H43 Cl2 P Ru2 SP 1 21/c 117.0596; 8.9122; 18.6207
90; 93.9558; 90
2824.32Miyake, Yoshihiro; Endo, Satoshi; Yuki, Masahiro; Tanabe, Yoshiaki; Nishibayashi, Yoshiaki
Synthesis and Reactivity of Hybrid Phosphido- and Thiolato-Bridged Diruthenium Complexes
Organometallics, 2008, 27, 6039
4072143 CIFC24 H34 P2 Pt S2 SiP n m a17.707; 13.5049; 11.8162
90; 90; 90
2825.6Lee, Kyung-Eun; Chang, Xiaohong; Kim, Yong-Joo; Huh, Hyun Sue; Lee, Soon W.
Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes,cis-[Pt(S2CNPh)L2] andcis-[Pt(S2SiPh2)L2] (L = PMe2Ph, PEt3; L-L = dppp)
Organometallics, 2008, 27, 5566
4071137 CIFC24 H17 Fe4 N O9 Te2P 21 21 219.325; 15.1222; 20.0419
90; 90; 90
2826.2Mathur, Pradeep; Singh, Amrendra K.; Mohanty, Jamini R.; Chatterjee, Saurav; Mobin, Shaikh M.
Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between TrimethylamineN-Oxide and Acetylenes on Fe3Te2(CO)9and Contrast with Reactions on Fe3E2(CO)9(E = S, Se)
Organometallics, 2008, 27, 5094
4071667 CIFC31 H46 Hf O SiP 1 21/c 115.9367; 11.7378; 16.5513
90; 114.011; 90
2828.2Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4070693 CIFC25 H38 B F4 Mo N7P 1 21/c 114.507; 8.2464; 23.934
90; 98.753; 90
2829.9Petrovic, Dejan; Hrib, Cristian G.; Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands
Organometallics, 2008, 27, 778
4071163 CIFC26 H36 Br2 N4 NiP b c a17.0371; 9.4576; 17.5727
90; 90; 90
2831.5Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4072346 CIFC19 H53 Li2 N7 ZnP c a 2117.316; 9.1221; 17.9321
90; 90; 90
2832.52Armstrong, David R.; Dougan, Christine; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Synthesis and Structural Elucidation of Alkyl, Amido, and Mixed Alkyl−Amido “Highly-Coordinated” Zincates
Organometallics, 2008, 27, 6063
4072177 CIFC56 H44 F12 Fe2 O2 P2P -113.2117; 14.6163; 15.5367
92.319; 109.009; 89.863
2834.1Ba, Fatou; Cabon, Nolwenn; Robin-Le Guen, Françoise; Le Poul, Pascal; Le Poul, Nicolas; Le Mest, Yves; Golhen, Stéphane; Caro, Bertrand
Diferrocenylbispyrylium Salts and Electron-Rich Diferrocenylbispyran from Oxidative Coupling of Ferrocenylpyran. Induced Electron Transfer C−C Bond Making/Breaking Involving a Metallocenyl Radical Intermediate
Organometallics, 2008, 27, 6396
4071262 CIFC27 H45 La N2 SiP 1 21/c 111.505; 14.053; 17.978
90; 102.539; 90
2837.4Evans, William J.; Montalvo, Elizabeth; Champagne, Timothy M.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.
Diazomethane Insertion into Lanthanide− and Yttrium−C(allyl) Bonds To Form the η2-Hydrazonato Complexes (C5Me5)2Ln[η2(N,N′)-RNNCHSiMe3] (R = C3H5)
Organometallics, 2008, 27, 3582
4072042 CIFC58.5 H87 B N3 O Sc Si2P -113.108; 14.586; 15.371
78.892; 83.362; 81.16
2838.3Ge, Shaozhong; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Rare Earth Metal Alkyl and Benzyl Compounds with the 1,4,6-Trimethyl-6-pyrrolidin-1-yl-1,4-diazepane Ligand and Their Performance in the Catalytic Hydroamination/Cyclization of Aminoalkenes
Organometallics, 2008, 27, 5339
4071056 CIFC38 H28 Cl2 O TiP 1 21/n 110.3873; 18.6488; 14.7521
90; 96.188; 90
2841Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071873 CIFC30 H90 Si14P -19.5206; 14.645; 20.701
81.88; 89.2; 84.67
2845Wallner, Andreas; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Rohm, Henning W.; Köckerling, Martin; Krempner, Clemens
Structure, Conformation, and UV Absorption Behavior of Partially Trimethylsilylated Oligosilane Chains
Organometallics, 2008, 27, 5221
4072337 CIFC24 H51 Cl2 N Os P2P 1 21/n 18.75; 18.705; 17.512
90; 96.759; 90
2846.2Esteruelas, Miguel A.; Fernández-Alvarez, Francisco J.; Oñate, Enrique
NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism
Organometallics, 2008, 27, 6236
4070816 CIFC25 H46 B F3 O P2 PtP 1 21/n 19.8764; 21.34; 13.5382
90; 93.188; 90
2848.9Wu, Jianguo; Sharp, Paul R.
A Family of Platinaoxetanes
Organometallics, 2008, 27, 1234
4071411 CIFC59.75 H52.5 Cl3.5 O1.5 Os P3P -112.249; 12.959; 20.138
98.431; 95.354; 113.906
2849.3Gong, Lei; Lin, Yumei; Wen, Ting Bin; Zhang, Hong; Zeng, Birong; Xia, Haiping
Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
Organometallics, 2008, 27, 2584
4071214 CIFC23 H43 Hf P Si3P 1 21/c 118.106; 10.445; 15.257
90; 99.06; 90
2849.4Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071501 CIFC32 H27 B F10 Ir NP 1 21/c 110.2691; 19.219; 14.5208
90; 96.108; 90
2849.58Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4071227 CIFC20 H49 Cl Ir O P3 SiP 1 21/n 19.3183; 18.2326; 17.2933
90; 104.074; 90
2849.9Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4071430 CIFC38 H23 Ag9 F21 N3 O17P -111.789; 15.211; 18.017
70.96; 73.919; 72.171
2850.6Zang, Shuang-Quan; Zhao, Liang; Mak, Thomas C. W.
Diverse Intermolecular Interactions in Metal−Organic Frameworks Constructed with the New Supramolecular Synthon Agn−L−Agn(n= 4, 5) (H2L = 2,2′-Bis(prop-2-ynyloxy)biphenyl)
Organometallics, 2008, 27, 2396
4071639 CIFC24 H24 F6 N4 O7 Ru S2P 1 21/n 19.7732; 25.207; 11.618
90; 94.443; 90
2853.5Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071609 CIFC29 H41 Ge N2 PP 1 21/c 114.138; 16.3244; 13.8086
90; 116.379; 90
2855.11Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071213 CIFC23 H43 P Si3 ZrP 1 21/c 118.106; 10.444; 15.295
90; 98.92; 90
2857.3Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071133 CIFC30 H44 P Pt SiP 1 21/c 110.218; 13.957; 20.078
90; 93.089; 90
2859.2Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4072142 CIFC28 H32 P2 Pt S2 SiC 1 2/c 114.898; 11.8386; 16.944
90; 106.882; 90
2859.7Lee, Kyung-Eun; Chang, Xiaohong; Kim, Yong-Joo; Huh, Hyun Sue; Lee, Soon W.
Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes,cis-[Pt(S2CNPh)L2] andcis-[Pt(S2SiPh2)L2] (L = PMe2Ph, PEt3; L-L = dppp)
Organometallics, 2008, 27, 5566
4071341 CIFC56 H76 Cl4 O4 P2 RuP -114.556; 14.86; 15.45
81.08; 64.64; 71.75
2867Hayashi, Akito; Yoshitomi, Takahiko; Umeda, Kazutoshi; Okazaki, Masaaki; Ozawa, Fumiyuki
Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes
Organometallics, 2008, 27, 2321
4071263 CIFC27 H45 N2 Si YP 1 21/c 111.509; 13.9781; 18.573
90; 106.132; 90
2870.3Evans, William J.; Montalvo, Elizabeth; Champagne, Timothy M.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.
Diazomethane Insertion into Lanthanide− and Yttrium−C(allyl) Bonds To Form the η2-Hydrazonato Complexes (C5Me5)2Ln[η2(N,N′)-RNNCHSiMe3] (R = C3H5)
Organometallics, 2008, 27, 3582
4071303 CIFC32 H32 Cl N2 O3 VP 1 21/n 112.3342; 13.3442; 17.9276
90; 103.048; 90
2874.5Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071168 CIFC34 H30 Cl N5 PdC 1 2/c 116.337; 9.571; 18.747
90; 100.79; 90
2879.5Wei, Wei; Qin, Yuancheng; Luo, Meiming; Xia, Pingfang; Wong, Man Shing
Synthesis, Structure, and Catalytic Activity of Palladium(II) Complexes of New CNC Pincer-Type N-Heterocyclic Carbene Ligands
Organometallics, 2008, 27, 2268
4072015 CIFC36 H30 F N P2P 1 21/n 19.2235; 20.7854; 15.0618
90; 92.457; 90
2884.9Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4083504 CIFC27 H44 Cl2 Si2 ZrP 21 21 218.7249; 11.4772; 28.8269
90; 90; 90
2886.65Min, Endy Y.-J.; Byers, Jeffery A.; Bercaw, John E.
Catalyst Site Epimerization during the Kinetic Resolution of Chiral α-Olefins by Polymerization
Organometallics, 2008, 27, 2179
4071594 CIFC58 H57 F12 N O3 P4 RuP -112.0479; 15.3359; 16.6007
72.371; 81.136; 86.12
2887.56Chou, Hsien-Hsin; Lin, Ying-Chih; Huang, Shou-Ling; Liu, Yi-Hong; Wang, Yu
Reactions of Ruthenium Acetylide and Vinylidene Complexes Containing a 2-Pyridyl Group
Organometallics, 2008, 27, 5212
4071921 CIFC24 H26 CrP 1 21/c 115.256; 9.663; 19.712
90; 96.277; 90
2888.5Meredith, M. Brett; Crisp, Jeffrey A.; Brady, Erik D.; Hanusa, Timothy P.; Yee, Gordon T.; Pink, Maren; Brennessel, William W.; Young, Victor G.
Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution
Organometallics, 2008, 27, 5464
4071174 CIFC67 H60 P2 Pt Si2P -112.644; 14.132; 17.016
73.49; 86.09; 83.673
2895.2Arii, Hidekazu; Takahashi, Makiko; Noda, Aki; Nanjo, Masato; Mochida, Kunio
Spectroscopic and Structural Studies of Thermally Unstable Intermediates Generated in the Reaction of [Pt(PPh3)2(η2-C2H4)] with Dihydrodisilanes
Organometallics, 2008, 27, 1929
4070777 CIFC29 H36 Cl Ir N2 O2P 1 21/n 110.6033; 15.1588; 18.2189
90; 97.654; 90
2902.29Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4071727 CIFC34 H30 Fe O3 P2P 1 21/c 122.552; 10.59; 12.22
90; 95.93; 90
2902.8Bar, Arun Kumar; Chakrabarty, Rajesh; Mukherjee, Partha Sarathi
Unusual Hydrogenation of Fumarate Anion Followed by Metal−Carbon Bond Formation: Synthesis and Characterization of Two Metallochelates
Organometallics, 2008, 27, 3806
4072027 CIFC26 H4 B Cu F21 N7C 1 c 117.9262; 17.6733; 9.2157
90; 95.485; 90
2906.3Despagnet-Ayoub, Emmanuelle; Jacob, Kane; Vendier, Laure; Etienne, Michel; Álvarez, Eleuterio; Caballero, Ana; Díaz-Requejo, M. Mar; Pérez, Pedro J.
A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)
Organometallics, 2008, 27, 4779
4071066 CIFC65 H77 O6 Rh3 SiP -16.8596; 16.044; 27.2
98.156; 96.646; 97.498
2910.3Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
Organometallics, 2008, 27, 4318

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