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4070529 CIFC5 H5 Br3 ZrP -16.6064; 7.1808; 9.0424
100.621; 92.0073; 103.101
409.317Glöckner, Andreas; Arif, Atta M.; Ernst, Richard D.
Isolation and Characterization of Bromination Products of Zr(C5H5)2Br2
Organometallics, 2008, 27, 327
4070823 CIFC9 H13 GaP -17.02; 7.121; 10.309
72.703; 76.898; 65.767
445.43Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4071920 CIFC24 H26 CrP -17.372; 8.565; 8.586
69.977; 74.027; 73.589
478.9Meredith, M. Brett; Crisp, Jeffrey A.; Brady, Erik D.; Hanusa, Timothy P.; Yee, Gordon T.; Pink, Maren; Brennessel, William W.; Young, Victor G.
Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution
Organometallics, 2008, 27, 5464
4070677 CIFC13 H14 CoP 1 n 16.278; 7.28; 10.834
90; 101.286; 90
485.6Mayer, Ulrich F. J.; Charmant, Jonathan P. H.; Rae, James; Manners, Ian
Synthesis and Structures of Strained, Neutral [d7] and Cationic [d6] Hydrocarbon-Bridged [n]Cobaltocenophanes (n= 2, 3)
Organometallics, 2008, 27, 1524
4070543 CIFC16 H20 In2 N10P -16.8471; 8.6997; 9.0856
88.128; 82.9; 70.894
507.46Song, Yi-Hwa; Chiu, Yuan-Chieh; Chi, Yun; Chou, Pi-Tai; Cheng, Yi-Ming; Lin, Chun-Wei; Lee, Gene-Hsiang; Carty, Arthur J.
Synthesis, Characterization, and Photophysical Properties of Luminescent Gallium and Indium Complexes Constructed using Tridentate 6-Azolyl-2,2′-bipyridine Chelates
Organometallics, 2008, 27, 80
4070824 CIFC12 H19 GaP -16.628; 7.069; 12.689
87.743; 89.449; 82.605
589.11Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4071641 CIFC15 H13 N3P -17.7568; 8.2139; 11.3653
75.732; 78.83; 62.01
617.12Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071491 CIFC15 H18 Fe Li NP -17.4443; 9.2993; 9.9602
95.318; 108.51; 102.226
629.43Chen, Chao; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Structural Features of Lithio[3]ferrocenophane Systems Bearing Stabilizing Dimethylamino Substituents
Organometallics, 2008, 27, 3248
4072075 CIFC12 H20 B P SiP 1 21 16.3632; 7.6482; 13.6844
90; 97.056; 90
660.94Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4071488 CIFC16 H20 Fe Li NP -17.5675; 9.2846; 10.4913
106.946; 98.02; 102.853
670.75Chen, Chao; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Structural Features of Lithio[3]ferrocenophane Systems Bearing Stabilizing Dimethylamino Substituents
Organometallics, 2008, 27, 3248
4070708 CIFC8 H5 Fe2 N O6 S2P 1 21/m 16.8441; 13.6033; 7.7636
90; 108.98; 90
683.51Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4071712 CIFC13 H15 Cl N2 O PdP -18.2358; 8.817; 10.974
73.534; 87.561; 63.968
683.6Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4071454 CIFC24 H10 Bi2 F12 O8P -18.2529; 9.3214; 9.8706
91.121; 110.04; 100.932
697.46Dikarev, Evgeny V.; Li, Bo; Rogachev, Andrey Yu.; Zhang, Haitao; Petrukhina, Marina A.
Metal-Site-Controlled Arene Coordination in a Heterobimetallic Bi−Rh Complex with Pyrene
Organometallics, 2008, 27, 3728
4071268 CIFC16 H36 Br2 N2 O4 S2 Zn2P -18.0442; 9.6895; 9.9379
103.446; 99.177; 106.337
701.65Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071721 CIFC11 H16 N2 O2 Si WP -16.3928; 10.6551; 10.8766
100.632; 96.245; 93.51
721.32Fortman, George C.; Isrow, Derek; McDonough, James E.; Schleyer, Paul von Ragué; Schaefer, Henry F.; Scott, Brian; Kubas, Gregory J.; Kégl, Tamás; Ungváry, Ferenc; Hoff, Carl D.
Kinetic and Thermodynamic Studies of the Reactivity of (Trimethylsilyl)diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo−N2CH2SiMe3Bond Strength and Experimental Determination of the Enthalpy of Formation of (Trimethylsilyl)diazomethane
Organometallics, 2008, 27, 4873
4071183 CIFC6 H8 N6C 1 2/c 115.068; 6.881; 7.0171
90; 93.52; 90
726.2Poyatos, Macarena; McNamara, William; Incarvito, Chris; Clot, Eric; Peris, Eduardo; Crabtree, Robert H.
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
Organometallics, 2008, 27, 2128
4071975 CIFC28 H27 Br2 Cl2 N2 P PdP 18.0388; 8.1586; 12.571
91.974; 108.419; 109.78
726.797Schnitzler, Verena; Nonglaton, Guillaume; Roussière, Hélène; Maillet, Céline; Evain, Michel; Janvier, Pascal; Bujoli, Bruno; Petit, Marc
Nitrogen-Based Chirality Effects in Novel Mixed Phosphorus/Nitrogen Ligands Applied to Palladium-Catalyzed Allylic Substitutions
Organometallics, 2008, 27, 5997
4071771 CIFC14 H20 Co Si2P 1 21 18.2595; 10.3127; 8.5719
90; 90.38; 90
730.12Braunschweig, Holger; Breher, Frank; Kaupp, Martin; Gross, Manuela; Kupfer, Thomas; Nied, Dominik; Radacki, Krzysztof; Schinzel, Sandra
Synthesis, Crystal Structure, EPR and DFT Studies, and Redox Properties of [2]Tetramethyldisilacobaltocenophane
Organometallics, 2008, 27, 6427
4072031 CIFC18 H36 B20 Cu2P -17.036; 9.412; 11.529
92.363; 95.143; 105.407
731.4Ren, Shikuo; Xie, Zuowei
A Facile and Practical Synthetic Route to 1,1′-Bis(o-carborane)
Organometallics, 2008, 27, 5167
4070759 CIFC8 H3 B2 Br4 Mn O3P -16.7882; 10.6733; 11.313
100.226; 105.977; 105.209
732.3Eckensberger, U. David; Kunz, Kerstin; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Synthesis and Structural Characterization of the Diborylated Organometallics 1,3-Bis(dibromoboryl)-1′,2′,3′,4′,5′-(pentamethyl)ferrocene and 1,3-Bis(dibromoboryl)cymantrene
Organometallics, 2008, 27, 764
4072293 CIFC11 H12 Cl F3 N2 O2 Ru SP -17.015; 8.164; 14.067
75.68; 83.06; 70.01
733Ito, Masato; Endo, Yoshinori; Ikariya, Takao
Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones
Organometallics, 2008, 27, 6053
4070877 CIFC8 H12 Br2 N5 O ReP -18.1046; 9.4947; 10.0314
86.04; 82.6; 85.37
761.7Choualeb, A.; Maccaroni, E.; Blacque, O.; Schmalle, H. W.; Berke, H.
Rhenium Nitrosyl Complexes for Hydrogenations and Hydrosilylations
Organometallics, 2008, 27, 3474
4070640 CIFC38 H40 N4P -18.483; 9.652; 10.57
81.832; 66.426; 74.004
762Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4072265 CIFC13 H21 O2 P2 VP 1 21/m 17.024; 13.185; 8.438
90; 101.602; 90
765.5Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4071997 CIFC22 H18 B2P 1 21/c 13.9678; 10.318; 19.103
90; 91.268; 90
781.9Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4072363 CIFC14 H20 N6 Ni O4P 1 21/n 16.96; 12.4871; 9.3214
90; 104.732; 90
783.49Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071996 CIFC20 H12 B2 Br2P 1 21/c 13.9318; 19.055; 10.609
90; 92.275; 90
794.2Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4071795 CIFC38 H22 N2 O4 Ru2 S2P -18.805; 9.666; 10.32
105.377; 91.151; 109.159
794.4Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4071575 CIFC16 H21 I N2 PtP 1 21 111.311; 4.6196; 15.981
90; 98.687; 90
825.5Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071716 CIFC22 H20 NiP 1 21 15.7888; 13.1587; 11.1799
90; 103.979; 90
826.39Buchalski, Piotr; Jadach, Patryk; Pietrzykowski, Antoni; Suwińska, Kinga; Jerzykiewicz, Lucjan; Sadło, Jarosław
Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water
Organometallics, 2008, 27, 3618
4071990 CIFC14 H28 B2 N4P 1 21/c 16.7166; 12.7645; 9.7065
90; 93.278; 90
830.82Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071779 CIFC21 H20 O4P -18.0964; 8.8792; 12.731
86.206; 75.741; 71.116
839.2Barluenga, José; Fañanás-Mastral, Martín; Andina, Facundo; Aznar, Fernando; Valdés, Carlos
Cascade Reactions of Dialkynyl Fischer Carbene Complexes Involving Intramolecular Alkyne Insertions Oriented to the Synthesis of Functionalized Polycycles
Organometallics, 2008, 27, 3593
4070675 CIFC18 H23 N2 Ni0.5 OP -18.548; 9.595; 11.491
65.568; 82.827; 79.743
843Boardman, Brycelyn M.; Valderrama, Juan M.; Muñoz, Flor; Wu, Guang; Bazan, Guillermo C.; Rojas, Rene
Remote Activation of Nickel Complexes by Coordination of B(C6F5)3to an Exocyclic Carbonitrile Functionality
Organometallics, 2008, 27, 1671
4071989 CIFC14 H28 B2 N4P -18.024; 10.0761; 11.0822
88.784; 70.959; 84.598
843.2Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071918 CIFC22 H18 N4P 1 21 19.43; 9.3303; 9.6272
90; 90.282; 90
847.04Lowry, Roxy J.; Veige, Melanie K.; Clément, Olivier; Abboud, Khalil A.; Ghiviriga, Ion; Veige, Adam S.
New Constrained-Geometry C2-Symmetric Di-N-heterocyclic Carbene Ligands and Their Mono- and Dinuclear Rhodium(I) Complexes: Design, Synthesis, and Structural Analysis
Organometallics, 2008, 27, 5184-5195
4071446 CIFC16 H10 Cr O6 SP 1 21/m 19.2928; 7.633; 12.4413
90; 104.249; 90
855.34Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4072030 CIFC4 H22 B20P 1 21/n 17.0165; 9.8852; 12.375
90; 90.44; 90
858.3Ren, Shikuo; Xie, Zuowei
A Facile and Practical Synthetic Route to 1,1′-Bis(o-carborane)
Organometallics, 2008, 27, 5167
4071705 CIFC19 H17 P S3P -18.0053; 8.6885; 14.3922
103.068; 92.171; 114.772
875.37Huy, Ngoc Hoa Tran; Donnadieu, Bruno; Mathey, François
The Phosphaalkene-like Reactivity of Dithienophosphinines
Organometallics, 2008, 27, 4005
4070813 CIFC18 H54 Cl2 N4 P2 Si6P -18.762; 9.246; 12.34
77.45; 83.69; 63.81
875.5Schaffrath, Markus; Villinger, Alexander; Michalik, Dirk; Rosenthal, Uwe; Schulz, Axel
Titanocene-Mediated Formation of Phosphorus−Phosphorus Bonds
Organometallics, 2008, 27, 1393
4071561 CIFC30 H42 F10 O6 V2P -19.4241; 9.5143; 11.2825
75.416; 67.418; 78.047
897Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4072203 CIFC18 H23 Cl N2 O2 PdP 1 21 16.4305; 11.728; 12.283
90; 103.426; 90
901Kimura, Tsutomu; Uozumi, Yasuhiro
Synthesis of [2,6-Bis(2-oxazolinyl)phenyl]palladium Complexes via the Ligand Introduction Route
Organometallics, 2008, 27, 5159
4071714 CIFC20 H23 Cl N2 O PdP -17.956; 9.98; 12.514
97.255; 105.519; 103.746
910.6Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4072129 CIFC15 H15 I N4 O4 WP 1 21/m 17.1875; 14.16; 9.0408
90; 97.959; 90
911.3Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4071647 CIFC25 H18 Fe OP -19.5739; 10.447; 10.6029
102.072; 115.407; 96.572
911.4Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071388 CIFC32 H54 Cl2 O6 P2 PdP -18.375; 9.9901; 11.0436
87.13; 85.581; 84.121
915.6Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071000 CIFC40 H48 O4 Ru2 Si4P -110.3381; 10.4244; 10.4263
93.4825; 115.924; 109.649
922.64Okazaki, Masaaki; Yamahira, Nobukazu; Minglana, Jim Josephus Gabrillo; Komuro, Takashi; Ogino, Hiroshi; Tobita, Hiromi
[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
Organometallics, 2008, 27, 918
4071898 CIFC20 H28 N2P 1 21 18.196; 9.418; 12.004
90; 93.13; 90
925.2Grisi, Fabia; Costabile, Chiara; Gallo, Emanuela; Mariconda, Annaluisa; Tedesco, Consiglia; Longo, Pasquale
Ruthenium-Based Complexes Bearing Saturated Chiral N-Heterocyclic Carbene Ligands: Dynamic Behavior and Catalysis
Organometallics, 2008, 27, 4649
4071354 CIFC18 H26 P2 PtP 1 21/m 18.624; 10.9514; 10.323
90; 106.99; 90
932.4Canty, Allan J.; Watson, Russell P.; Karpiniec, Samuel S.; Rodemann, Thomas; Gardiner, Michael G.; Jones, Roderick C.
Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
Organometallics, 2008, 27, 3203
4071091 CIFC9 H8 Fe0.5 O2 PP 1 21/n 16.796; 8.163; 16.939
90; 96.36; 90
933.9Escobar, Aholibama; Donnadieu, Bruno; Mathey, François
From Functional Phospholide Ions to Bifunctional 1,1′-Diphosphaferrocenes
Organometallics, 2008, 27, 1887
4071382 CIFC8 H13 Br N2P 1 21/c 16.7845; 10.725; 13.111
90; 101.54; 90
934.7Normand, Adrien T.; Yen, Swee Kuan; Huynh, Han Vinh; Hor, T. S. Andy; Cavell, Kingsley J.
Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple
Organometallics, 2008, 27, 3153
4071854 CIFC19 H22 N4 O2 SiP -18.32; 9.969; 11.555
91.54; 99.44; 90.17
945Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071412 CIFC20 H33 Mo N OP -18.3346; 8.4671; 14.5068
84.83; 85.483; 68.227
945.7Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071556 CIFC18 H20 Cl2 N4 PdP 1 21/c 17.745; 12.647; 11.215
90; 120.353; 90
947.9Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071785 CIFC22 H31 N O WP -18.1917; 9.7406; 13.6903
73.624; 89.272; 65.724
948.71Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4070979 CIFC12 H35 N6 TaI m -3 m9.835; 9.835; 9.835
90; 90; 90
951.3Zhang, Xin-Hao; Chen, Shu-Jian; Cai, Hu; Im, Hee-Jung; Chen, Tianniu; Yu, Xianghua; Chen, Xuetai; Lin, Zhenyang; Wu, Yun-Dong; Xue, Zi-Ling
Unexpected Formation of (Dimethylaminomethylene)methylamide Complexes from the Reactions between Metal Chlorides and Lithium Dimethylamide
Organometallics, 2008, 27, 1338
4070978 CIFC12 H35 N6 NbI m -3 m9.852; 9.852; 9.852
90; 90; 90
956.25Zhang, Xin-Hao; Chen, Shu-Jian; Cai, Hu; Im, Hee-Jung; Chen, Tianniu; Yu, Xianghua; Chen, Xuetai; Lin, Zhenyang; Wu, Yun-Dong; Xue, Zi-Ling
Unexpected Formation of (Dimethylaminomethylene)methylamide Complexes from the Reactions between Metal Chlorides and Lithium Dimethylamide
Organometallics, 2008, 27, 1338
4070889 CIFC22 H26 N PP -19.6727; 10.3984; 10.748
114.074; 91.19; 102.036
958.5Shaffer, Andrew R.; Schmidt, Joseph A. R.
Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines
Organometallics, 2008, 27, 1259
4071598 CIFC25 H21 F O SiP -18.545; 9.429; 13.712
97.067; 97.216; 115.932
965.9Dorsey, Christopher L.; Gabbaï, François P.
R3C−H→SiFR3Agostic Interaction
Organometallics, 2008, 27, 3065
4072414 CIFC10 H5 Br F3 N OP 1 21/n 14.4543; 11.6713; 18.635
90; 94.179; 90
966.21Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4071134 CIFC18 H26 P2 Pt SiP -19.183; 11.193; 11.32
102.781; 112.877; 104.322
970.8Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4070808 CIFC21 H30 N4P -18.817; 10.72; 10.796
90.095; 103.026; 99.885
978.5Otero, Antonio; Fernández-Baeza, Juan; Antiñolo, Antonio; Lara-Sánchez, Agustín; Martínez-Caballero, Emilia; Tejeda, Juan; Sánchez-Barba, Luis F.; Alonso-Moreno, Carlos; López-Solera, Isabel
Scandium and Yttrium Complexes Supported by NNCp Heteroscorpionate Ligands: Synthesis, Structure, and Polymerization of ϵ-Caprolactone
Organometallics, 2008, 27, 976
4070612 CIFC9 H12 B N2 Na OP 1 21/c 15.1979; 19.9137; 9.6023
90; 99.177; 90
981.21Wagler, Jörg; Hill, Anthony F.
7-Azaindol-7-ylborate: A Novel Bidentate N^BH3Chelating Ligand
Organometallics, 2008, 27, 2350
4071222 CIFC22 H56 I2 Si8P -18.7389; 9.4834; 13.512
97.87; 92.04; 117.03
982Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4072063 CIFC12 H33 In Si3P -110.353; 10.358; 10.386
74.22; 77.787; 67.66
984Peckermann, Ilja; Robert, Dominique; Englert, Ulli; Spaniol, Thomas P.; Okuda, Jun
Neutral and Cationic Trimethylsilylmethyl Complexes of Indium
Organometallics, 2008, 27, 4817
4070857 CIFC20 H18 F4 Ir N O3P -18.2139; 9.175; 14.0581
73.448; 84.546; 75.868
984.45Ke Chan, Pek; Kee Leong, Weng
Reaction of Cp*Ir(CO)2with Activated Perfluoroaromatic Compounds: Formation of Metallocarboxylic Acids via Aromatic Nucleophilic Substitution
Organometallics, 2008, 27, 1247
4072360 CIFC11 H11 N3 O2P 1 21/c 112.2364; 13.4662; 6.1023
90; 97.017; 90
997.99Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071657 CIFC17 H25 F6 O2 P RuP 1 21 19.0768; 8.3752; 13.2634
90; 95.86; 90
1003.01Gruber, Stefan; Zaitsev, Alexey B.; Wörle, Michael; Pregosin, Paul S.; Veiros, Luis F.
Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry
Organometallics, 2008, 27, 3796
4071871 CIFC24 H19 Br N2 Ni O2P 21 21 213.167; 5.8235; 13.0951
90; 90; 90
1004.11Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4072259 CIFC30 H36 F12 N14 Ni2 P2P -17.775; 11.533; 12.12
75.005; 73.448; 84.909
1006.1Zhou, Yongbo; Xi, Zhenxing; Chen, Wanzhi; Wang, Daqi
Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni2(μ-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides
Organometallics, 2008, 27, 5911
4071114 CIFC23 H19 Mn O5P -18.9297; 10.794; 11.1264
72.273; 80.503; 88.397
1007.24Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4071095 CIFC21 H21 Cl2 O2 P RuP 1 21 19.7487; 9.9464; 10.4269
90; 91.709; 90
1010.59Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4071448 CIFC19 H10 Cr2 O9 SP -18.3523; 10.7547; 13.0118
109.519; 108.371; 95.519
1018.6Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071734 CIFC9 H4 N O5 ReP 1 21/c 15.79; 10.7142; 16.4602
90; 93.551; 90
1019.15Mirebeau, Jean-Hugues; Le Bideau, Franck; Marrot, Jérôme; Jaouen, Gérard
Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands
Organometallics, 2008, 27, 2911
4071778 CIFC23 H25 N O3 SiP -19.553; 10.856; 11.584
88.33; 69.67; 66.19
1022Barluenga, José; Fañanás-Mastral, Martín; Andina, Facundo; Aznar, Fernando; Valdés, Carlos
Cascade Reactions of Dialkynyl Fischer Carbene Complexes Involving Intramolecular Alkyne Insertions Oriented to the Synthesis of Functionalized Polycycles
Organometallics, 2008, 27, 3593
4083511 CIFC19 H21 F3 N4 O3 Pt SP -16.8821; 10.9123; 14.1919
92.657; 91.962; 104.942
1027.48Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4071850 CIFC17 H33 N4 O2 SiP -19.683; 11.351; 11.49
115.096; 110.27; 95.533
1027.9Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071290 CIFC7 H19 Fe0.5 P2P 1 21/c 18.762; 12.581; 12.814
90; 132.979; 90
1033.4Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4083507 CIFC22 H19 Br2 N3 Ni OP -19.2389; 9.817; 11.656
91.31; 98.99; 95.83
1038Gao, Rong; Zhang, Min; Liang, Tongling; Wang, Fosong; Sun, Wen-Hua
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization
Organometallics, 2008, 27, 5641
4070720 CIFC15 H5 N O12 Ru3P -18.332; 11.889; 11.904
84.78; 73.1; 70.62
1064.3Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4071297 CIFC21 H26 Cl2 N O3 VP -17.4606; 11.4975; 13.9387
109.77; 90.049; 107.679
1064.85Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4072008 CIFC22 H27 Cl N4 O PdP -18.9322; 11.5556; 11.6712
109.128; 107.747; 93.895
1064.97Luzyanin, Konstantin V.; Pombeiro, Armando J. L.; Haukka, Matti; Kukushkin, Vadim Yu.
Coupling between 3-Iminoisoindolin-1-ones and Complexed Isonitriles as a Metal-Mediated Route to a Novel Type of Palladium and Platinum Iminocarbene Species
Organometallics, 2008, 27, 5379
4070864 CIFC21 H26 F6 N O2 P RuP -16.872; 10.792; 14.599
97.798; 95.328; 91.472
1067.2Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4071699 CIFC32 H56 Br4 N8 O4 Pt2P -18.669; 11.457; 12.083
110.14; 91.04; 105.57
1077.2Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4070939 CIFC24 H28 Cl P RuP -17.942; 11.1756; 13.0715
77.024; 73.311; 82.677
1080.47Vergnaud, Jérôme; Grellier, Mary; Bouhadir, Ghenwa; Vendier, Laure; Sabo-Etienne, Sylviane; Bourissou, Didier
Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]
Organometallics, 2008, 27, 1140
4072274 CIFC24 H31 N3P -18.42; 11.852; 12.291
109.84; 108.27; 90.96
1085.1Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070678 CIFC12 H14 Cl Co OP 1 21/c 17.1957; 10.2972; 14.7117
90; 92.524; 90
1089.01Mayer, Ulrich F. J.; Charmant, Jonathan P. H.; Rae, James; Manners, Ian
Synthesis and Structures of Strained, Neutral [d7] and Cationic [d6] Hydrocarbon-Bridged [n]Cobaltocenophanes (n= 2, 3)
Organometallics, 2008, 27, 1524
4071178 CIFC20 H22 P Pt SiP -18.837; 9.838; 13.333
80.115; 73.335; 82.17
1089.32Arii, Hidekazu; Takahashi, Makiko; Noda, Aki; Nanjo, Masato; Mochida, Kunio
Spectroscopic and Structural Studies of Thermally Unstable Intermediates Generated in the Reaction of [Pt(PPh3)2(η2-C2H4)] with Dihydrodisilanes
Organometallics, 2008, 27, 1929
4070629 CIFC38 F20 O18 Ru4P -19.6158; 10.5643; 11.7591
112.876; 95.196; 91.192
1094Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4072021 CIFC30 H24P -16.4454; 11.125; 15.38
92.479; 92.629; 95.834
1094.7Chen, Jingjin; Li, Yuxue; Gao, Hongjun; Liu, Yuanhong
Carbon−Carbon Bond Formation of α-Alkynylzirconacyclopentenes via Cyclization or a Cu/Pd-Mediated Cyclization/Cross-Coupling Sequence with Aryl Iodides
Organometallics, 2008, 27, 5619
4072434 CIFC21 H32 Cl2 N O P PdP 1 21 17.2466; 19.5763; 7.9997
90; 104.296; 90
1099.71Rubina, Marina; Sherrill, William M.; Rubin, Michael
Dramatic Stereo- and Enantiodivergency in the Intermolecular Asymmetric Heck Reaction Catalyzed by Palladium Complexes with Cyclopropane-Based PHOX Ligands
Organometallics, 2008, 27, 6393
4071386 CIFC10 H17 O3 PP 1 21/c 18.176; 8.0969; 16.669
90; 94.144; 90
1100.6Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071597 CIFC25 H20 B F5 O SiP -19.812; 10.112; 13.009
110.373; 105.23; 101.512
1105.4Dorsey, Christopher L.; Gabbaï, François P.
R3C−H→SiFR3Agostic Interaction
Organometallics, 2008, 27, 3065
4070748 CIFC24 H25 B Bi F O2P -110.399; 10.701; 11.484
94.046; 95.697; 118.484
1107.5Caires, Christopher C.; Guccione, Samira
Synthesis, Structure, and Reactivity of Borate Ester Coordinated Organobismuth Compounds
Organometallics, 2008, 27, 747
4070825 CIFC13 H13 GaP 1 21/c 18.731; 11.977; 10.739
90; 99.202; 90
1108.5Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg
Aryl(dimethyl)gallium Compounds and Methyl(diphenyl)gallium: Synthesis, Structure, and Redistribution Reactions
Organometallics, 2008, 27, 4565
4070532 CIFC24 H31 Au Br PP -19.7079; 10.1259; 12.1991
110.563; 96.051; 93.479
1110.36Partyka, David V.; Robilotto, Thomas J.; Zeller, Matthias; Hunter, Allen D.; Gray, Thomas G.
Dialkylbiarylphosphine Complexes of Gold(I) Halides. Gold−Aryl π-Interactions in the Solid State
Organometallics, 2008, 27, 28
4070642 CIFC48 H52 N4 Ni2 O4P -17.651; 11.783; 13.848
114.862; 99.241; 90.263
1114.4Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4071419 CIFC48 H48 B2 Cl6 Fe2 N4P -19.9484; 10.4634; 11.6449
70.117; 78.568; 84.032
1116.41Pakkirisamy, Thilagar; Venkatasubbaiah, Krishnan; Kassel, W. Scott; Rheingold, Arnold L.; Jäkle, Frieder
Examination of the Pyridine Binding to the Bifunctional Lewis Acid B,B′-Diphenyldiboradiferrocene
Organometallics, 2008, 27, 3056
4070643 CIFC48 H52 Cu2 N4 O4P -17.688; 11.813; 13.804
114.828; 99.704; 90.174
1117.7Huang, Yuan-Biao; Tang, Guang-Rong; Jin, Gui-Ying; Jin, Guo-Xin
Binuclear Nickel and Copper Complexes with Bridging 2,5-Diamino-1,4-benzoquinonediimines: Synthesis, Structures, and Catalytic Olefin Polymerization
Organometallics, 2008, 27, 259
4071149 CIFC22 H21 O6 P WP -19.488; 10.33; 13.083
101.576; 109.73; 103.089
1120.65Bode, Maren; Schnakenburg, Gregor; Jones, Peter G.; Streubel, Rainer
Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5Complex
Organometallics, 2008, 27, 2664
4072275 CIFC25 H33 N3P -18.459; 11.49; 12.48
100.34; 107.97; 95.02
1121.8Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071724 CIFC14 H16 FeP 1 21/n 19.8523; 7.6564; 15.4974
90; 106.337; 90
1121.82Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki
Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†
Organometallics, 2008, 27, 5279
4071383 CIFC24 H30 Br O3 PP -110.108; 10.339; 11.856
71.83; 88.97; 73.25
1123.8Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4070795 CIFC23 H25 N3 O6 SiP 1 n 19.341; 10.443; 11.71
90; 99.72; 90
1125.9Spiniello, Marisa; White, Jonathan M.
Structural Investigations into the β-Effect of Pentavalent Silicon
Organometallics, 2008, 27, 994
4070839 CIFC25 H30 N NbP 3 1 c11.2683; 11.2683; 10.2514
90; 90; 120
1127.3Arteaga-Müller, Rocío; Sánchez-Nieves, Javier; Ramos, Javier; Royo, Pascual; Mosquera, Marta E. G.
Isolobal Zwitterionic Niobium and Tantalum Imido and Zirconium Monocyclopentadienyl Complexes: Theoretical and Methyl Methacrylate Polymerization Studies
Organometallics, 2008, 27, 1417
4071061 CIFC24 H28 O4 SiP -18.016; 8.044; 17.791
87.401; 83.35; 81.92
1127.7Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
Organometallics, 2008, 27, 4318
4070904 CIFC22 H28 N4 Si ZnP -18.0286; 11.2735; 12.947
79.004; 80.062; 83.476
1129.1Chai, Zuo-Yun; Zhang, Cheng; Wang, Zhong-Xia
Synthesis, Characterization, and Catalysis in ϵ-Caprolactone Polymerization of Aluminum and Zinc Complexes Supported byN,N,N-Chelate Ligands
Organometallics, 2008, 27, 1626
4072186 CIFC19 H23 Al F12 N2 O2P -18.0836; 10.2938; 15.0534
102.211; 105.267; 100.619
1142.17Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4071528 CIFC40 H52 Cl8 N2 O4 Ru2P -19.7494; 10.9847; 11.4996
69.527; 83.3; 88.409
1145.8Mendoza-Ferri, Maria-Grazia; Hartinger, Christian G.; Eichinger, Rene E.; Stolyarova, Natalya; Severin, Kay; Jakupec, Michael A.; Nazarov, Alexey A.; Keppler, Bernhard K.
Influence of the Spacer Length on thein VitroAnticancer Activity of Dinuclear Ruthenium−Arene Compounds
Organometallics, 2008, 27, 2405
4071787 CIFC20 H10 O8 Ru2 SnP -18.2765; 9.317; 16.1426
87.377; 75.261; 72.544
1147.76Adams, Richard D.; Trufan, Eszter
Diruthenium−Tin Complexes from the Reaction of Ph2SnH2with Ru(CO)5and Their Reactions with Bis(tri-tert-butylphosphine)platinum
Organometallics, 2008, 27, 4108
4071782 CIFC26 H41 N O WP -19.7773; 11.3376; 11.7186
77.63; 65.729; 88.019
1154.6Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4071765 CIFC21 H25 Mo2 N S4P 1 21 19.8972; 12.5566; 9.3093
90; 90.261; 90
1156.9Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4072321 CIFC48 H72 Fe2 Li4 O7P -19.8205; 10.6036; 11.7149
74.735; 80.07; 84.505
1157.6Perucha, Alejandro Sánchez; Heilmann-Brohl, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Comparison of Doubly Lithiated, Magnesiated, and Zincated Ferrocenes: [Fe(η5-C5H4)2]2Zn2(tmeda)2, the First Example of a [1.1]Ferrocenophane with Bridging First-Row Transition Metal Atoms
Organometallics, 2008, 27, 6170
4071298 CIFC22 H25 Cl2 F3 N O3 VP -17.6147; 12.0671; 13.7396
67.631; 85.279; 86.104
1162.6Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4070755 CIFC15 H23 B10 Co O4 Se2P -19.5889; 9.6525; 13.9915
72.157; 75.856; 73.25
1163Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4071991 CIFC18 H39 B3 N6P -18.507; 10.052; 15.1233
85.667; 78.556; 66.589
1163.2Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4072174 CIFC4 H15 B10 N OP 21 21 218.8115; 10.4327; 12.6598
90; 90; 90
1163.8Mukhin, Sergey N.; Kabytaev, Kuanysh Z.; Zhigareva, Galina G.; Glukhov, Ivan V.; Starikova, Zoya A.; Bregadze, Vladimir I.; Beletskaya, Irina P.
Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom
Organometallics, 2008, 27, 5937
4070826 CIFC28 H27 N3 OP 1 21 18.8927; 14.556; 9.4158
90; 107.08; 90
1165Zi, Guofu; Xiang, Li; Song, Haibin
Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2′-(dimethylamino)-1,1′-binaphthyl
Organometallics, 2008, 27, 1242
4071130 CIFC22 H44 P Pt SiP -19.695; 9.826; 14.461
75.281; 82.659; 61.139
1166.9Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4071358 CIFC29 H30 Ir NP -17.87; 10.155; 15.749
73.934; 84.275; 74.846
1166.9Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071901 CIFC22 H34 Cl2 O2 Os2P 1 21/c 19.072; 16.049; 8.2477
90; 102.549; 90
1172.1Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4072067 CIFC22 H28 Cr O6P -19.3239; 10.351; 12.241
93.71; 94.57; 90.07
1175.2Wang, Qifeng; Zhang, Wen-Xiong; Xi, Zhenfeng
Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6(M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction
Organometallics, 2008, 27, 3627
4070909 CIFC23 H32 Cr O4 SiP 1 21 17.7412; 10.9198; 14.3413
90; 103.896; 90
1176.82Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A.
Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality
Organometallics, 2008, 27, 900
4070926 CIFC26 H10 F10 N2 ZnP -17.1098; 12.5886; 14.7792
68.372; 77.1; 76.065
1180.1Martin, Eddy; Spendley, Claire; Mountford, Andrew J.; Coles, Simon J.; Horton, Peter N.; Hughes, David L.; Hursthouse, Michael B.; Lancaster, Simon J.
Synthesis, Structure, and Supramolecular Architecture of Benzonitrile and Pyridine Adducts of Bis(pentafluorophenyl)zinc: Pentafluorophenyl‒Aryl Interactions versus Homoaromatic Pairing
Organometallics, 2008, 27, 1436
4072074 CIFC12 H17 P SiP 1 21/n 16.3438; 18.0866; 10.472
90; 100.732; 90
1180.52Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4071700 CIFC15 H25 Br2 Cl3 N4 O2 PtP -110.438; 10.449; 11.27
103.18; 93.43; 94.59
1189.1Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4070876 CIFC14 H10 Mn N O3P 1 21/c 114.5944; 5.7378; 15.4263
90; 112.656; 90
1192.11To, Tung T.; Duke III, Charles B.; Junker, Christopher S.; O’brien, Casey M.; Ross Ii, Charles R.; Barnes, Craig E.; Webster, Charles Edwin; Burkey, Theodore J.
Linkage Isomerization as a Mechanism for Photochromic Materials: Cyclopentadienylmanganese Tricarbonyl Derivatives with Chelatable Functional Groups
Organometallics, 2008, 27, 289
4071387 CIFC10 H16 Cl O3 PP 1 21/c 19.656; 8.3144; 15.116
90; 100.463; 90
1193.4Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4070923 CIFC17 H28 B10 Co N S3P -18.266; 10.433; 14.475
99.515; 96.993; 100.783
1194.3Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4071079 CIFC28 H29 Fe2 O3 PP -18.7611; 12.321; 12.427
105.131; 100.907; 106.022
1194.3Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Nucleophilic and Electrophilic Behavior of the Phosphinidene-Bridged Complex [Fe2(η5-C5H5)2(μ-PCy)(μ-CO)(CO)2]
Organometallics, 2008, 27, 1037
4071009 CIFC10 H4 Ag7 N5 O18P -17.236; 10.6353; 15.5849
87.661; 89.882; 86.547
1196.2Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4072073 CIFC22 H42 Cl O2 P PdP -18.592; 10.019; 15.068
100.372; 100.796; 104.467
1198.1Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072140 CIFC23 H27 N P2 Pt S2P -19.6108; 10.0711; 12.944
94.732; 105.693; 92.37
1199.4Lee, Kyung-Eun; Chang, Xiaohong; Kim, Yong-Joo; Huh, Hyun Sue; Lee, Soon W.
Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes,cis-[Pt(S2CNPh)L2] andcis-[Pt(S2SiPh2)L2] (L = PMe2Ph, PEt3; L-L = dppp)
Organometallics, 2008, 27, 5566
4071301 CIFC21 H24 Br2 Cl2 N O3 VP -17.7892; 11.996; 13.9022
106.917; 92.699; 103.18
1201.06Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071505 CIFC18 H20 F6 O9 S2 SnP -110.0999; 10.4971; 11.9202
73.1794; 86.1036; 85.105
1204.05Kašná, Blanka; Dostál, Libor; Jirásko, Robert; Císařová, Ivana; Jambor, Roman
Role of Y,C,Y-Chelating Ligands in Control Hydrolysis of Diorganotin Compounds†
Organometallics, 2008, 27, 3743
4071577 CIFC26 H25 I N P PtP 1 21 19.975; 8.3934; 14.854
90; 104.246; 90
1205.4Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071002 CIFC21 H31 F6 Ir N3 O2 PP 21 21 215.3775; 8.4994; 9.2423
90; 90; 90
1207.96Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4071228 CIFC17 H43 Cl Ir P3 SiP 1 21 19.3062; 10.7212; 12.1508
90; 94.122; 90
1209.19Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4071659 CIFC8 H12 O2P -110.5911; 11.79; 12.2848
66.034; 62.98; 67.991
1214.2Yada, Yukito; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Ruthenium-Catalyzed Intramolecular Cyclization of 3-Butyne-1,2-diols into Furans
Organometallics, 2008, 27, 3614
4070648 CIFC30 H22 Au N2 PP -110.0469; 10.6781; 13.1309
76.667; 68.524; 68.91
1215.14Vicente, José; Gil-Rubio, Juan; Barquero, Natalia; Jones, Peter G.; Bautista, Delia
Synthesis of Luminescent Alkynyl Gold Metalaligands Containing 2,2′-Bipyridine-5-yl and 2,2′:6′,2′′-Terpyridine-4-yl Donor Groups
Organometallics, 2008, 27, 646
4070716 CIFC24 H48 Cl8 O12 Si8P -110.02; 10.133; 12.855
79.93; 73.96; 78.09
1217.7Marciniec, Bogdan; Dutkiewicz, Michal; Maciejewski, Hieronim; Kubicki, Maciej
New, Effective Method of Synthesis and Structural Characterization of Octakis(3-chloropropyl)octasilsesquioxane
Organometallics, 2008, 27, 793
4072413 CIFC13 H14 Br NP 1 21/c 110.7872; 9.4647; 12.7521
90; 110.547; 90
1219.13Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4071436 CIFC40 H82 O2 Si4 Y2P -19.888; 11.153; 12.721
73.878; 85.735; 64.925
1219.2Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071068 CIFC35 H80 Cd5 N6 O6P -110.401; 11.508; 12.431
68.66; 66.65; 68.36
1227.8Jana, Surajit; Fröhlich, Roland; Hepp, Alexander; Mitzel, Norbert W.
An Organocadmium Hydroxylamide
Organometallics, 2008, 27, 1348
4083512 CIFC22 H29 F6 N4 O P PtP -19.2523; 11.2105; 13.4198
66.814; 73.859; 83.802
1229.1Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4072033 CIFC27 H32 Cl N4 RhP 1 21 18.6322; 16.3296; 9.2517
90; 109.21; 90
1231.51Ros, Abel; Alcarazo, Manuel; Iglesias-Sigüenza, Javier; Díez, Elena; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Stereoselective Synthesis of Rhodium(I) 4-(Dialkylamino)triazol-5-ylidene Complexes
Organometallics, 2008, 27, 4555
4072009 CIFC26 H21 Cl3 N4 O PtP -18.3009; 12.4324; 12.7236
74.722; 77.042; 85.816
1234.28Luzyanin, Konstantin V.; Pombeiro, Armando J. L.; Haukka, Matti; Kukushkin, Vadim Yu.
Coupling between 3-Iminoisoindolin-1-ones and Complexed Isonitriles as a Metal-Mediated Route to a Novel Type of Palladium and Platinum Iminocarbene Species
Organometallics, 2008, 27, 5379
4070570 CIFC19 H30 Cl4 N2 P2 PdP 1 21 17.9252; 15.1396; 10.4448
90; 99.015; 90
1237.73Das, Atanu Kumar; Bulak, Ece; Sarkar, Biprajit; Lissner, Falk; Schleid, Thomas; Niemeyer, Mark; Fiedler, Jan; Kaim, Wolfgang
Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate LigandR,R-QuinoxP
Organometallics, 2008, 27, 218
4071437 CIFC40 H82 Dy2 O2 Si4P -19.9249; 11.2281; 12.7924
73.973; 85.791; 64.861
1238.79Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071722 CIFC30 H35 Fe PP -17.4493; 12.5125; 14.4119
71.541; 85.738; 77.417
1243.59Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki
Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†
Organometallics, 2008, 27, 5279
4072408 CIFC34 H31 BP -18.567; 11.2119; 13.7498
98.642; 103.914; 98.317
1244.7Zhao, Shu-Bin; Wucher, Philipp; Hudson, Zachary M.; McCormick, Theresa M.; Liu, Xiang-Yang; Wang, Suning; Feng, Xiao-Dong; Lu, Zheng-Hong
Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes2Groups and the Peculiar Behavior of 1,6-(BMes2)2pyrene
Organometallics, 2008, 27, 6446
4072020 CIFC32 H30 N2P -17.961; 11.374; 14.41
80.274; 80.161; 78.185
1246.2Chen, Jingjin; Li, Yuxue; Gao, Hongjun; Liu, Yuanhong
Carbon−Carbon Bond Formation of α-Alkynylzirconacyclopentenes via Cyclization or a Cu/Pd-Mediated Cyclization/Cross-Coupling Sequence with Aryl Iodides
Organometallics, 2008, 27, 5619
4071004 CIFC20 H28 Cl F6 Ir N3 O2 PP 1 21 18.2524; 16.0006; 9.4409
90; 91.441; 90
1246.21Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4070569 CIFC19 H30 Cl4 N2 P2 PtP 1 21 17.9288; 15.1703; 10.52
90; 99.605; 90
1247.63Das, Atanu Kumar; Bulak, Ece; Sarkar, Biprajit; Lissner, Falk; Schleid, Thomas; Niemeyer, Mark; Fiedler, Jan; Kaim, Wolfgang
Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate LigandR,R-QuinoxP
Organometallics, 2008, 27, 218
4070922 CIFC17 H30 B10 N Rh S2P -110.429; 11.533; 11.584
81.027; 67.195; 77.123
1248.3Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4072305 CIFC28 H27 Ni O5 P SP -19.566; 9.877; 15.129
104.407; 95.245; 112.58
1250.1Zhou, Xiaoyuan; Bontemps, Sébastien; Jordan, Richard F.
Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes
Organometallics, 2008, 27, 4821
4071202 CIFC22 H40 Cl O2 P2 RhP -18.176; 12.184; 13.351
100.49; 95.71; 103.91
1255Salem, Hiyam; Shimon, Linda J. W.; Leitus, Gregory; Weiner, Lev; Milstein, David
B−C Bond Cleavage of BArFAnion Upon Oxidation of Rhodium(I) with AgBArF. Phosphinite Rhodium(I), Rhodium(II), and Rhodium(III) Pincer Complexes
Organometallics, 2008, 27, 2293
4072069 CIFC22 H28 O6 S WP -110.667; 11.59; 11.644
83.7; 66.19; 72.92
1258.9Wang, Qifeng; Zhang, Wen-Xiong; Xi, Zhenfeng
Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6(M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction
Organometallics, 2008, 27, 3627
4070607 CIFC18 H41 B7 Fe O2 P2P -18.7786; 9.8596; 15.0003
85.101; 79.204; 82.038
1260.69Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4071472 CIFC21 H41 Cl3 Ir N3P -19.465; 10.886; 14.286
70.589; 81.301; 65.269
1260.84Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4072183 CIFC22 H32 F12 N2 O2P 1 21/n 17.3782; 22.163; 7.7542
90; 91.228; 90
1267.7Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4071003 CIFC19 H27 F6 I2 Ir N3 O2 PP 1 21 17.7764; 17.402; 9.3814
90; 91.409; 90
1269.15Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4072376 CIFC27 H42 Cl P PdP -18.186; 10.01; 17.12
79.21; 86.43; 67.5
1273.1Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4071515 CIFC21 H31 I2 N3 O PdP -110.0442; 10.8695; 13.2366
111.027; 92.493; 106.846
1273.29Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4072123 CIFC5 H20 B9 N SP c a 2118.4915; 6.7105; 10.2849
90; 90; 90
1276.22Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4070793 CIFC25 H23 B N2 O3 P Re SP -18.486; 10.7559; 15.5117
94.743; 103.313; 109.504
1278.9Videira, Margarida; Maria, Leonor; Paulo, António; Santos, Isabel C.; Santos, Isabel; Vaz, Pedro D.; Calhorda, Maria José
Mixed-Ligand Rhenium Tricarbonyl Complexes Anchored on a (κ2-H,S) Trihydro(mercaptoimidazolyl)borate: A Missing Binding Motif for Soft Scorpionates
Organometallics, 2008, 27, 1334
4070903 CIFC18 H14 FeC m c 2115.06; 9.6563; 8.8505
90; 90; 90
1287.1Kirillov, Evgueni; Kahlal, Samia; Roisnel, Thierry; Georgelin, Thomas; Saillard, Jean-Yves; Carpentier, Jean-François
Haptotropic Rearrangements in Sandwich (Fluorenyl)(Cyclopentadienyl) Iron and Ruthenium Complexes
Organometallics, 2008, 27, 387
4071746 CIFC27 H37 Ir O P2P 1 21 18.2807; 14.1531; 11.5174
90; 106.646; 90
1293.24Romero, Patricio E.; Whited, Matthew T.; Grubbs, Robert H.
Multiple C−H Activations of Methyltert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1
Organometallics, 2008, 27, 3422
4072324 CIFC17 H18 FeP 1 21/n 15.8485; 17.0481; 12.987
90; 92.072; 90
1294.03Ogasawara, Masamichi; Watanabe, Susumu; Nakajima, Kiyohiko; Takahashi, Tamotsu
Preparation of [4]- and [5]Ferrocenophanes by Ruthenium-Catalyzed Ring-Closing Ene−Yne Metathesis
Organometallics, 2008, 27, 6565
4071247 CIFC11 H12 Ge O3 WP -16.822; 13.361; 14.685
82.509; 79.76; 81.872
1296.3Apodaca, Paula; Kumar, Mukesh; Cervantes-Lee, Francisco; Sharma, Hemant K.; Pannell, Keith H.
The Chloromethylgermyl Complexes (η5-C5H5)M(CO)nGeR2CH2Cl [M = Fe (n= 2), Mo, W (n= 3)]: Rearrangements, Transformations to 1-Germa-3-metallacyclobutanes (η5-C5H4)M(CO)nCH2GeR2, and their Ring-Opening Polymerizations
Organometallics, 2008, 27, 3136
4071141 CIFC30 H33 N P2P -18.4309; 12.8265; 13.2757
71; 74.009; 89.143
1300.46Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071246 CIFC11 H12 Ge Mo O3P -16.8366; 13.386; 14.6784
82.528; 79.887; 81.766
1301.2Apodaca, Paula; Kumar, Mukesh; Cervantes-Lee, Francisco; Sharma, Hemant K.; Pannell, Keith H.
The Chloromethylgermyl Complexes (η5-C5H5)M(CO)nGeR2CH2Cl [M = Fe (n= 2), Mo, W (n= 3)]: Rearrangements, Transformations to 1-Germa-3-metallacyclobutanes (η5-C5H4)M(CO)nCH2GeR2, and their Ring-Opening Polymerizations
Organometallics, 2008, 27, 3136
4071636 CIFC36 H30 Co Ni2P -19.256; 9.305; 17.278
96.93; 98.93; 114.74
1306.3Buchalski, Piotr; Grabowska, Ilona; Karaskiewicz, Anna; Suwińska, Kinga; Jerzykiewicz, Lucjan
Novel 9-Nickelafluorenyl Sandwich Complexes of Nickel(II) and Cobalt(II)
Organometallics, 2008, 27, 3316
4072076 CIFC25 H34 Cl O P2 Rh Si2P 1 21/c 16.914; 6.698; 28.42
90; 95.71; 90
1309.6Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4071094 CIFC26 H32 B F3 N2 O3 SP -18.2944; 10.4347; 16.1597
104.688; 96.856; 100.432
1310.3Chiu, Ching-Wen; Gabbaï, François P.
Diarylborenium Cations: Synthesis, Structure, and Electrochemistry
Organometallics, 2008, 27, 1657
4072357 CIFC13 H15 N3 O2 SiP 1 21/c 17.2892; 9.8847; 18.3983
90; 98.578; 90
1310.8Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4071704 CIFC23 H30 Br2 Cl2 N4 O2 PtP -19.999; 10.9524; 13.0425
86.17; 67.837; 84.563
1316.09Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4070811 CIFC27 H35 Mo2 O4 PP -19.819; 11.145; 12.932
73.307; 76.161; 86.211
1316.2García, M. Esther; García-Vivó, Daniel; Ruiz, Miguel A.
Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 3. Formation and Cleavage of C−C and C−O Bonds in the Reactions of the Complexes [Mo2Cp2(µ-COMe)(µ-COR)(µ-PCy2)]BF4(R = Me, Et)
Organometallics, 2008, 27, 543
4071595 CIFC27 H28 Cl4 Ir PP 1 21/m 19.7472; 12.0024; 11.4226
90; 99.241; 90
1318.98Lebel, Hélène; Ladjel, Chehla
Iridium Complexes in Olefination Reactions
Organometallics, 2008, 27, 2676
4072330 CIFC40 H92 Al2 Cr2 N4 P2P -19.702; 10.454; 14.135
107.554; 95.139; 101.52
1322Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Koç, Ece; Duchateau, Robbert
Isolation of a Chromium Hydride Single-Component Ethylene Polymerization Catalyst
Organometallics, 2008, 27, 5943
4072280 CIFC26 H35 Cl2 Co N3P 1 21 19.451; 13.486; 10.434
90; 95.63; 90
1323.5Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070630 CIFC22 H6 F12 O8 Ru2P -19.6393; 11.3055; 14.1228
72.102; 73.861; 67.004
1326.11Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4071618 CIFC30 H48 P2P 1 21/c 19.4004; 13.1537; 10.8292
90; 97.526; 90
1327.5Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4071039 CIFC13 H18 B N SiP 1 21/c 110.0235; 15.6305; 8.5246
90; 96.184; 90
1327.8Pan, Jun; Kampf, Jeff W.; Ashe III, Arthur J.
The Preparation and Crystal Structures of η1-Derivatives of 2-Phenyl-1,2-azaboratabenzene
Organometallics, 2008, 27, 1345
4072283 CIFC26 H35 Cl2 Fe N3P 1 21 19.4994; 13.5202; 10.409
90; 95.779; 90
1330.07Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4070937 CIFC36 H90 Br2 Si10P -110.6236; 12.1382; 12.6622
66.232; 85.365; 64.031
1334.33Ueba-Ohshima, Kiyomi; Iwamoto, Takeaki; Kira, Mitsuo
Synthesis, Structure, and Facile Ring Flipping of a Bicyclo[1.1.0]tetrasilane
Organometallics, 2008, 27, 320
4071447 CIFC25 H17 Cl3 Cr O6 S TiP -111.3041; 11.5751; 12.2429
66.52; 88.797; 67.038
1335.6Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071555 CIFC24 H30 Cl2 N6 O2 PdP 1 21/c 110.646; 9.0631; 14.374
90; 105.509; 90
1336.4Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071287 CIFC20 H18 Al2 F12 O2P 1 21/n 19.972; 7.6787; 17.488
90; 92.638; 90
1337.7Martínez, Gema; Pedrosa, Sergio; Tabernero, Vanessa; Mosquera, Marta E. G.; Cuenca, Tomás
Controlled Synthesis of Novel Aryloxide Polynuclear Aluminum Species. Study of Their Catalytic Properties in Polymerization Processes†
Organometallics, 2008, 27, 2300
4071179 CIFC22 H32 I2 N6 Rh2P -18.7286; 12.243; 13.855
103.63; 100.11; 105.71
1339.1Poyatos, Macarena; McNamara, William; Incarvito, Chris; Clot, Eric; Peris, Eduardo; Crabtree, Robert H.
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
Organometallics, 2008, 27, 2128
4071896 CIFC13 H23 Cl PdP 1 21/n 16.4359; 12.0616; 17.4155
90; 96.456; 90
1343.34Esposito, Oriana; Gois, Pedro M. P.; de K. Lewis, Alexandra K.; Caddick, Stephen; Cloke, F. Geoffrey N.; Hitchcock, Peter B.
Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties
Organometallics, 2008, 27, 6411
4072155 CIFC32 H44 N UP -19.2465; 10.885; 13.7791
86.5926; 80.0815; 80.0828
1345.1Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4072166 CIFC28 H34 N4 O4 Rh2P -18.2971; 11.5643; 14.67
78.139; 81.744; 79.456
1346Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072281 CIFC27 H37 Cl2 Co N3P 1 21 19.5883; 12.9838; 10.8393
90; 92.006; 90
1348.59Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4071453 CIFC24 H10 Bi F12 O8 RhP -18.5229; 12.8739; 13.1035
81.988; 85.192; 71.631
1349.96Dikarev, Evgeny V.; Li, Bo; Rogachev, Andrey Yu.; Zhang, Haitao; Petrukhina, Marina A.
Metal-Site-Controlled Arene Coordination in a Heterobimetallic Bi−Rh Complex with Pyrene
Organometallics, 2008, 27, 3728
4070736 CIFC23 H46 Al N O Si2P 1 21 19.447; 12.565; 11.38
90; 91.994; 90
1350Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming
Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^
Organometallics, 2008, 27, 678-682
4071566 CIFC48 H54 B2 F20 O8 Zr2P -110.872; 11.866; 12.017
110.37; 105.386; 98.153
1353.4Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4070662 CIFC25 H40 N4 O3 RuP 1 21 110.634; 12.053; 11.28
90; 110.466; 90
1354.52Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4072421 CIFC56 H56 Cl8 N4 Pt2P -19.3132; 11.8742; 13.3219
67.5142; 85.269; 85.9551
1355.37Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4070762 CIFC24 H34 B F4 Ir N2 O3 SP 19.7323; 10.0866; 14.1647
91.517; 99.724; 97.879
1355.82Heiden, Zachariah M.; Gorecki, Bradford J.; Rauchfuss, Thomas B.
Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity
Organometallics, 2008, 27, 1542
4072126 CIFC6 H15 B9 Fe O2 SP 1 21/n 16.7953; 13.234; 15.1439
90; 94.436; 90
1357.8Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4072227 CIFC31 H43 Si TiP -18.6571; 11.5401; 14.2383
99.8037; 90.9041; 103.774
1359.02Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4070905 CIFC31 H31 N4 P ZnP -19.056; 11.133; 14.071
78.193; 82.371; 81.054
1364.2Chai, Zuo-Yun; Zhang, Cheng; Wang, Zhong-Xia
Synthesis, Characterization, and Catalysis in ϵ-Caprolactone Polymerization of Aluminum and Zinc Complexes Supported byN,N,N-Chelate Ligands
Organometallics, 2008, 27, 1626
4070875 CIFC15 H10 Mn N O4P 1 21/c 117.932; 10.443; 7.3797
90; 98.943; 90
1365.2To, Tung T.; Duke, III, Charles B.; Junker, Christopher S.; O'Brien, Casey M.; Ross, II, Charles R.; Barnes, Craig E.; Webster, Charles Edwin; Burkey, Theodore J.
Linkage Isomerization as a Mechanism for Photochromic Materials: Cyclopentadienylmanganese Tricarbonyl Derivatives with Chelatable Functional Groups
Organometallics, 2008, 27, 289
4070726 CIFC32 H38 Al N2 OP -111.4187; 11.5317; 12.1602
93.651; 106.249; 114.684
1366.6Yang, Ying; Schulz, Thomas; John, Michael; Yang, Zhi; Jiménez-Pérez, Victor Manuel; Roesky, Herbert W.; Gurubasavaraj, Prabhuodeyara M.; Stalke, Dietmar; Ye, Hongqi
Organoaluminum Hydroxides Supported by β-Diketiminato Ligands: Synthesis, Structural Characterization, and Reactions
Organometallics, 2008, 27, 769
4072136 CIFC30 H46 F2 TiP 4215.3556; 15.3556; 5.7986
90; 90; 90
1367.3Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070845 CIFC28 H38 Cl3 O3 RhP -19.6097; 11.3454; 14.8142
104.724; 96.667; 115.065
1368.05Bordoni, Silvia; Natanti, Paolo; Cerini, Stefano; Tarroni, Riccardo; Monari, Magda; Piccinelli, Fabio; Busetto, Luigi
Diastereoselective Synthesis of New Rhodium-Based Amphiphilic Polyol-Cp Systems
Organometallics, 2008, 27, 945
4070664 CIFC25 H40 N4 O5 RuP 1 21 110.602; 12.062; 11.393
90; 110.069; 90
1368.49Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4072404 CIFC25 H40 B Ir N6 O2P -18.0223; 13.1372; 13.2581
97.23; 94.549; 96.359
1371.46Paneque, Margarita; Poveda, Manuel L.; Santos, Laura L.; Carmona, Ernesto; Mereiter, Kurt
Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound
Organometallics, 2008, 27, 6353
4071151 CIFC29 H27 O7 P WP -18.8233; 10.726; 15.0798
92.218; 105.029; 93.583
1373.4Bode, Maren; Schnakenburg, Gregor; Jones, Peter G.; Streubel, Rainer
Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5Complex
Organometallics, 2008, 27, 2664
4070611 CIFC28 H20 Cl2 F6 N4 PdP -19.0014; 11.4002; 14.646
110.666; 93.013; 100.034
1374.07Wanniarachchi, Yoshitha A.; Slaughter, LeGrande M.
Reversible Chelate Ring Opening of a Sterically Crowded Palladium Bis(acyclic diaminocarbene) Complex
Organometallics, 2008, 27, 1055
4071096 CIFC27 H28 Cl F6 N O2 P2 RuP 1 21 19.364; 15.414; 9.544
90; 93.54; 90
1374.9Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4072119 CIFC30 H16 Au2 F6 Fe N2P 1 21/m 111.4667; 8.5646; 14.1478
90; 98.271; 90
1375Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4071293 CIFC22 H54 Fe P4P -17.593; 10.2012; 19.5659
77.903; 89.807; 68.634
1375.59Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4072291 CIFC15 H13 N2 P SP 1 21/n 16.0288; 18.5959; 12.3146
90; 93.68; 90
1377.75Oshovsky, Gennady V.; Ouali, Armelle; Xia, Ning; Zablocka, Maria; Boeré, René T.; Duhayon, Carine; Taillefer, Marc; Majoral, Jean Pierre
Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media
Organometallics, 2008, 27, 5733
4071682 CIFC60 H48 Cl6 N4 P2 Pd2P -19.9317; 11.7023; 13.2396
79.655; 87.484; 65.604
1377.8Jiang, Huiling; Song, Datong
Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
Organometallics, 2008, 27, 3587
4071267 CIFC20 H40 Br2 N2 O4 Zn2P 1 21/n 110.687; 8.8254; 14.8247
90; 99.537; 90
1378.9Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071029 CIFC21 H43 Li N4 Si2P -110.18; 10.636; 13.365
89.23; 72.67; 88.85
1381.1Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071011 CIFC7 H4 Ag4 N4 O9P 1 21/n 17.2997; 16.0767; 11.7819
90; 92.056; 90
1381.8Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4072332 CIFC29 H37 N3 O4 OsP -110.441; 11.3821; 13.4172
90.499; 108.143; 112.641
1383.35Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4072196 CIFC28 H42 N2 O2 ZnP 1 21 19.4749; 12.6708; 11.6753
90; 98.468; 90
1386.39Armstrong, David R.; Drummond, Allison M.; Balloch, Liam; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Metalation of 2,4,6-Trimethylacetophenone Using Organozinc Reagents: The Role of the Base in Determining Composition and Structure of the Developing Enolate
Organometallics, 2008, 27, 5860
4070865 CIFC22 H33 F12 N O P2 RuP 1 21 17.134; 12.2235; 15.9461
90; 94.372; 90
1386.49Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4071845 CIFC36 H34 N2 Ru2P 1 21 17.722; 13.556; 13.251
90; 91.012; 90
1386.89Pannetier, Nicolas; Sortais, Jean-Baptiste; Dieng, Pape Sylla; Barloy, Laurent; Sirlin, Claude; Pfeffer, Michel
Kinetics and Mechanism of Ruthenacycle-Catalyzed Asymmetric Hydrogen Transfer
Organometallics, 2008, 27, 5852
4070596 CIFC22 H35 B Cl2 N4 O S2 TaP 1 21/m 18.596; 14.522; 11.155
90; 94.99; 90
1387.2Hill, Anthony F.; Smith, Matthew K.; Wagler, Jörg
Near Linear Ta−H−B Geometry: [TaCl2(η-C5Me5){κ3-H,S,S′-H2B(methimazolyl)2}]
Organometallics, 2008, 27, 2137
4070849 CIFC25 H30 N3 O9.5 PdP -110.0026; 10.5211; 14.3597
107.407; 103.434; 91.7
1394.5Vicente, José; Arcas, Aurelia; Gálvez-López, María-Dolores; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Synthesis of Bis(2,6-dinitroaryl)palladium(II) and Mono(2,6-dinitroaryl)platinum(II) Complexes. A New Example of the Transphobia Effect and of Transmetalation from Pt to Hg
Organometallics, 2008, 27, 1582
4072121 CIFC61 H46 Au4 Cl2 Fe2 N4 O4P -18.4412; 11.8387; 14.197
87.29; 81.08; 84.569
1394.5Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4070707 CIFC27 H24 Fe2 N O5 P S2P -18.884; 10.484; 15.902
93.118; 98.856; 106.601
1394.9Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4071398 CIFC32 H31 Br P2 RuP 1 21 19.65602; 14.95694; 10.48788
90; 112.479; 90
1399.62Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071766 CIFC32 H34 Mo2 N2 S2P -18.4425; 11.7806; 14.4002
100.234; 95.882; 90.15
1401.7Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071136 CIFC14 H20 Mo S2P b c n13.271; 6.9263; 15.256
90; 90; 90
1402.3Kuo, Louis Y.; Adint, Tyler T.; Akagi, Allison E.; Zakharov, Lev
Degradation of a VX Analogue: First Organometallic Reagent To Promote Phosphonothioate Hydrolysis Through Selective P−S Bond Scission
Organometallics, 2008, 27, 2560
4072154 CIFC26 H48 N Si2 UP 1 21/m 18.753; 15.573; 11.017
90; 110.86; 90
1403.3Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4070702 CIFC27 H22 Fe2 N O7 P S2P -19.679; 12.785; 12.908
71.734; 68.835; 77.581
1405.1Song, Li-Cheng; Wang, Hu-Ting; Ge, Jian-Hua; Mei, Shu-Zhen; Gao, Jie; Wang, Liang-Xing; Gai, Bin; Zhao, Li-Qun; Yan, Jing; Wang, Yong-Zhen
Investigations on the Active Site Models of [FeFe]-Hydrogenases: Synthesis, Structure, and Properties of N-Functionalized Azadithiolatodiiron Complexes Containing Mono- and Diphosphine Ligands
Organometallics, 2008, 27, 1409
4072132 CIFC60 H92 Cl2 Ti2P 111.036; 11.7476; 11.8519
83.696; 67.575; 83.281
1407.05Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072137 CIFC30 H46 F2 HfP 4215.4892; 15.4892; 5.86566
90; 90; 90
1407.26Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072133 CIFC30 H46 F2 ZrP 4215.502; 15.502; 5.8576
90; 90; 90
1407.7Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070797 CIFC34 H28 Au Fe2 PP -17.9659; 12.0238; 15.14
100.165; 94.558; 96.371
1411.2Packheiser, Rico; Jakob, Alexander; Ecorchard, Petra; Walfort, Bernhard; Lang, Heinrich
Diphenylphosphinoferrocene Gold(I) Acetylides: Synthesis of Heterotri- and Heterotetrametallic Transition Metal Complexes
Organometallics, 2008, 27, 1214
4070646 CIFC13 H8 Cu2 N2 O5C 1 2/c 113.668; 8.401; 12.406
90; 96.961; 90
1414Takahashi, Yoshiteru; Tsutsumi, Ken; Nakagai, Yuzo; Morimoto, Tsumoru; Kakiuchi, Kiyomi; Ogoshi, Sensuke; Kurosawa, Hideo
Mono- and Dipalladium Movement on the π-Conjugated Five-Carbon Chain
Organometallics, 2008, 27, 276
4071399 CIFC32 H31 I P2 RuP 1 21 18.4821; 15.0654; 11.0948
90; 91.851; 90
1417Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071645 CIFC21 H14 OP 1 21/c 18.8665; 16.4; 10.046
90; 103.966; 90
1417.6Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4070855 CIFC22 H24 N4 O18 Pd2P -110.2492; 11.6858; 14.5201
66.848; 72.464; 64.161
1421.3Vicente, José; Arcas, Aurelia; Gálvez-López, María-Dolores; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Synthesis of Bis(2,6-dinitroaryl)palladium(II) and Mono(2,6-dinitroaryl)platinum(II) Complexes. A New Example of the Transphobia Effect and of Transmetalation from Pt to Hg
Organometallics, 2008, 27, 1582
4071683 CIFC19 H19 N2 RhP 1 21/c 110.0544; 11.1105; 12.8356
90; 97.249; 90
1422.4Jiang, Huiling; Song, Datong
Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
Organometallics, 2008, 27, 3587
4071666 CIFC31 H44 Hf SiP -19.7031; 10.366; 15.583
83.09; 72.17; 72.66
1423.6Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4071193 CIFC33 H34 I P PdP 1 21 18.6509; 19.449; 9.4379
90; 116.13; 90
1425.6Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071496 CIFC32 H28 B F10 N2 RhP -110.321; 10.501; 14.223
74.03; 74.6; 82.79
1426.5Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4070605 CIFC19 H26 B7 Co2 Fe O9 PP -17.5362; 8.3695; 23.0178
84.158; 83.378; 83.582
1427.28Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4071497 CIFC32 H28 B F10 Ir N2P -110.335; 10.481; 14.273
74.01; 74.64; 83.01
1431.2Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4071668 CIFC31 H46 O Si TiP -19.1336; 10.3287; 16.5723
93.569; 104.347; 107.04
1432.72Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4071848 CIFC11 H22 N4 O2 SiP 1 21/n 18.437; 12.084; 14.081
90; 90.94; 90
1435.4Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071612 CIFC58 H84 Ge2 N4 P2P -110.8175; 12.0783; 12.6434
91.55; 108.361; 111.339
1441.49Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071321 CIFC25 H41 Cl2 N2 P PtP -19.158; 10.9628; 16.0184
77.2924; 76.9733; 69.1103
1446.51Vuzman, Dana; Poverenov, Elena; Shimon, Linda J. W.; Diskin-Posner, Yael; Milstein, David
Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization
Organometallics, 2008, 27, 2627
4072051 CIFC34 H42 La NP -18.7176; 9.651; 18.4634
78.405; 87.337; 72.103
1447.86Quiroga Norambuena, Victor F.; Heeres, André; Heeres, Hero J.; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
Organometallics, 2008, 27, 5672
4072335 CIFC28 H34 F6 N3 O3 Os PP -19.2497; 10.955; 14.715
77.78; 87.82; 83.83
1448.7Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4071097 CIFC27.5 H29 Cl F7 N O2.5 P2 RuP 110.9667; 10.9759; 14.2777
76.588; 89.832; 60.962
1449.39Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4070798 CIFC34 H28 Au Fe P RuP -18.2561; 11.9946; 14.9913
99.395; 93.651; 96.474
1450.2Packheiser, Rico; Jakob, Alexander; Ecorchard, Petra; Walfort, Bernhard; Lang, Heinrich
Diphenylphosphinoferrocene Gold(I) Acetylides: Synthesis of Heterotri- and Heterotetrametallic Transition Metal Complexes
Organometallics, 2008, 27, 1214
4070552 CIFC24.5 H38 Cl Fe N2 Sc Si2P -19.913; 12.742; 12.952
70.982; 70.217; 87.775
1450.7Carver, Colin T.; Monreal, Marisa J.; Diaconescu, Paula L.
Scandium Alkyl Complexes Supported by a Ferrocene Diamide Ligand
Organometallics, 2008, 27, 363
4071273 CIFC28 H41 B2 N2 O Si YP -19.8641; 12.5338; 13.7462
102.128; 107.478; 108.072
1452.33Fang, Xiangdong; Deng, Yuanfu; Xie, Qinxing; Moingeon, Firmin
A Bis(1,2-Azaborolyl)yttrium Alkyl Complex: Synthesis, Structure, and Polymerization Study
Organometallics, 2008, 27, 2892
4072157 CIFC31 H49 Al N2P -18.4373; 9.7007; 19.346
82.033; 80.769; 69.565
1458.71Olson, Jeremy A.; Boyd, Ramon; Quail, J. Wilson; Foley, Stephen R.
Copper(II) Ethylene Polymerization Catalysts: Do They Really Exist?
Organometallics, 2008, 27, 5333
4071852 CIFC31 H40 N4 O2 SiP -19.691; 11.134; 14.777
80.57; 89.28; 68.48
1461.3Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4072245 CIFC36 H68 B20 Cl4 N4 Rh2 S4P -111.104; 11.219; 14.042
71.071; 78.586; 62.268
1462.3Jia, Wei-Guo; Han, Ying-Feng; Jin, Guo-Xin
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Containing 1,2-Dichalcogenolato Carborane or Carbonato Ligands
Organometallics, 2008, 27, 6035
4071895 CIFC17 H21 Fe N O2P 21 21 217.3992; 12.9482; 15.2689
90; 90; 90
1462.86Tebben, Ludger; Bussmann, Kathrin; Hegemann, Michael; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Ferrocene-Derived Bioorganometallic Chemistry: Preparation of a [3]Ferrocenophane γ-Amino Acid for Use in Peptide Synthesis
Organometallics, 2008, 27, 4269
4071332 CIFC20.5 H33.5 I3 N6 RhP -19.1548; 11.9397; 14.1549
95.23; 107.292; 93.65
1464.4Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4072228 CIFC32 H47 TiP -18.8959; 12.1869; 15.2672
92.443; 105.854; 111.242
1465.41Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4071012 CIFC12 H6 Ag8 N10 O21P -17.5346; 11.4637; 17.235
82.286; 88.016; 84.343
1467.7Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4071607 CIFC27 H28 Ge P PtP -18.638; 13.93; 14.177
109.661; 99.571; 107.007
1468.3Arii, Hidekazu; Nanjo, Masato; Mochida, Kunio
Characterization of Mononuclear and Dinuclear Germylplatinum Complexes and Ge−Ge Bond Formation at the Platinum Center
Organometallics, 2008, 27, 4147
4072244 CIFC17 H32 B10 Ir N2 Se2P -111.215; 11.238; 14.053
72.147; 80.786; 60.952
1473.7Jia, Wei-Guo; Han, Ying-Feng; Jin, Guo-Xin
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Containing 1,2-Dichalcogenolato Carborane or Carbonato Ligands
Organometallics, 2008, 27, 6035
4071005 CIFC20 H29 Cl3 F6 Ir N3 O3 P TlP 1 21 110.1512; 11.4196; 12.8731
90; 98.977; 90
1474Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4070929 CIFC34 H16 F10 N4 ZnP -18.0378; 14.0455; 14.551
114.357; 91.807; 97.603
1476.6Martin, Eddy; Spendley, Claire; Mountford, Andrew J.; Coles, Simon J.; Horton, Peter N.; Hughes, David L.; Hursthouse, Michael B.; Lancaster, Simon J.
Synthesis, Structure, and Supramolecular Architecture of Benzonitrile and Pyridine Adducts of Bis(pentafluorophenyl)zinc: Pentafluorophenyl‒Aryl Interactions versus Homoaromatic Pairing
Organometallics, 2008, 27, 1436
4070504 CIFC22 H41 B8 N3 PtP -111.4393; 11.523; 12.9427
80.784; 81.299; 61.667
1476.71Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4071912 CIFC27 H29 O7 Os3 PP -19.0338; 10.632; 15.8388
79.472; 82.389; 84.241
1478Adams, Richard D.; Boswell, Erin M.; Hall, Michael B.; Yang, Xinzheng
Activation of Hydrogen and Related Small Molecules by the Unsaturated Cluster Complex PtOs3(CO)7(PBut3)(μ-PBut2)(μ4-CHCMeCH)
Organometallics, 2008, 27, 4938
4071894 CIFC25 H42 B9 O2 ZrP -19.8791; 11.4486; 13.9799
95.837; 108.744; 93.901
1480.99Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4071906 CIFC34 H30 O4 S2P 1 21 18.1156; 16.984; 11.5882
90; 111.984; 90
1481.12Kuniyasu, Hitoshi; Takekawa, Kazunobu; Yamashita, Fumikazu; Miyafuji, Kiyoshi; Asano, Shigehito; Takai, Yasutomo; Ohtaka, Atsushi; Tanaka, Aoi; Sugoh, Kunihiko; Kurosawa, Hideo; Kambe, Nobuaki
Insertion of Alkynes into an ArS−Pt Bond: Regio- and Stereoselective Thermal Reactions, Facilitation by “o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences Depending on the Ancillary Ligand, and Application to a Catalytic Reaction
Organometallics, 2008, 27, 4788
4072236 CIFC30 H49 Cl Si2 TiP -18.6384; 11.4893; 15.6002
78.9559; 77.8493; 86.9128
1485.44Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4070632 CIFC8 H4 F6 O10 Ru2P 1 21/c 112.6491; 8.7326; 13.626
90; 99.274; 90
1485.45Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4071583 CIFC39 H34 Fe2 N2 OP -111.231; 12.606; 12.79
114.55; 97.629; 108.532
1486.2Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4072167 CIFC32 H42 N4 O4 Rh2P 1 21/n 18.3492; 12.2916; 14.5016
90; 90.191; 90
1488.22Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072355 CIFC16 H14 N2 O4 SiP 21 21 217.3257; 13.6736; 14.8738
90; 90; 90
1489.89Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072231 CIFC30 H49 Si2 TiP -19.0306; 11.9583; 14.7172
89.3701; 82.0966; 71.3318
1490.48Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072261 CIFC23 H21 F12 N9 Ni2 O P2P -18.0204; 13.7196; 14.9468
109.605; 96.764; 101.033
1491Zhou, Yongbo; Xi, Zhenxing; Chen, Wanzhi; Wang, Daqi
Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni2(μ-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides
Organometallics, 2008, 27, 5911
4070526 CIFC28 H36 Co F6 O6 PP -19.746; 12.138; 14.577
114.113; 106.166; 91.635
1491.7Perekalin, Dmitry S.; Babak, Maria V.; Novikov, Valentin V.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Corsini, Maddalena; Zanello, Piero; Kudinov, Alexander R.
A New Approach to the Photochemically Controlled Crown Ethers: (Tetramethylcyclobutadiene)cobalt Complexes with Benzo-15-Crown-5 and Dibenzo-18-Crown-6†
Organometallics, 2008, 27, 3654
4071384 CIFC30 H57 O3 PP -18.6589; 10.335; 17.863
89.713; 77.73; 73.231
1492.9Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071030 CIFC23 H47 Li N4 Si2P -110.189; 11.171; 14.437
103.46; 108.24; 95.06
1494.6Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071791 CIFC30 H50 Os3P -111.0085; 11.0311; 15.1064
71.327; 73.298; 60.641
1495.67Kameo, Hajime; Suzuki, Hiroharu
Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(μ-H)6]+and {(C5Me5)Os}3(μ-H)3(μ3-H)2and Comparison with the Ruthenium Analogues
Organometallics, 2008, 27, 4248
4072371 CIFC70 H74 B2 Fe3 Li O8P -18.8567; 12.9851; 13.531
78.523; 80.93; 82.496
1498Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4072344 CIFC25 H33 Br2 Cl Co N3 O P2P -18.834; 9.4939; 18.3764
84.975; 78.725; 88.533
1505.6Wang, Aichen; Sun, Hongjian; Li, Xiaoyan
N-Assisted Carbon−Hydrogen Bond Activation by Cobalt(I) Complexes
Organometallics, 2008, 27, 5434
4071937 CIFC36 H20 F8 P2 PtP 1 21/c 110.0072; 12.2049; 12.7603
90; 104.943; 90
1505.8Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4082270 CIFC29 H32 Cl F6 N O2 P2 RuP 1 21 19.4734; 16.2505; 9.7948
90; 91.773; 90
1507.16Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4071936 CIFC36 H20 F8 P2 PdP 1 21/c 19.997; 12.2158; 12.7955
90; 105.055; 90
1508.97Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4070785 CIFC26 H52 O Si4P -110.0468; 10.3024; 17.0558
104.11; 94.399; 115.674
1509.15Naka, Akinobu; Motoike, Shingo; Senba, Norihito; Ohshita, Joji; Kunai, Atsutaka; Yoshizawa, Kazunari; Ishikawa, Mitsuo
Silicon−Carbon Unsaturated Compounds. 74. Thermal Behavior of 1-Silacyclobut-3-enes Generated from the Reaction of Acylpolysilanes withtert-Butylacetylene
Organometallics, 2008, 27, 2750
4070859 CIFC16 H21 Cl O RuC m c 219.0438; 13.2365; 12.6151
90; 90; 90
1510.13Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4072422 CIFC64 H72 Cl8 N4 Pt2P -110.0472; 12.0539; 13.355
70.392; 83.136; 86.422
1512.25Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4070706 CIFC10 H9 Fe2 N O6 S2P 1 21/n 19.964; 12.0864; 13.0405
90; 105.405; 90
1514Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4072302 CIFC33 H45 N P2 RuP -18.815; 10.673; 18.027
76.406; 75.879; 69.245
1517.25Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4072135 CIFC30 H46 Cl2 HfP 4215.3372; 15.3372; 6.4757
90; 90; 90
1523.28Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072272 CIFC32 H43 Ir N2 ZrP -111.1561; 11.174; 12.3671
89.535; 81.628; 88.713
1524.83Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4071495 CIFC19 H49 Al Si5P -110.554; 12.1864; 12.5117
97.449; 95.133; 105.461
1524.87Uhl, Werner; Er, Elif; Hepp, Alexander; Kösters, Jutta; Grunenberg, Jörg
Reactions of Terminal Alkynes with a Bulky Dialkylaluminum Hydride: Hydroalumination versus Deprotonation
Organometallics, 2008, 27, 3346
4072104 CIFC20 H20 O2P 1 21 110.6161; 6.8123; 21.2635
90; 96.907; 90
1526.62Yeh, Ming-Chang P.; Tsao, Wen-Cheng; Lee, Bo-Jen; Lin, Tzu-Ling
Facile Synthesis of Carbotetracycles via Gold(I)-Catalyzed Cyclization of Unactivated Cyclic 1-Aryl-6,8-dien-1-ynes
Organometallics, 2008, 27, 5326
4071276 CIFC30 H20 Fe2 O6 P2 S2P -19.991; 11.558; 14.893
71.732; 88.952; 70.292
1530.1Song, Li-Cheng; Zeng, Guang-Huai; Lou, Shao-Xia; Zan, Hui-Ning; Ming, Jiang-Bo; Hu, Qing-Mei
Synthetic and Structural Studies of Butterfly Fe/S/P Cluster Complexes Related to the Active Site of [FeFe]-Hydrogenases. Proton Reduction to H2Catalyzed by (η1-Ph2PS-η1)2Fe2(CO)6
Organometallics, 2008, 27, 3714
4070896 CIFC25 H46 B9 N O3 ZrP -19.4871; 13.1; 13.729
94.24; 105.41; 108.92
1531.9Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4072128 CIFC30 H32 N4 O4 Sn WP -18.607; 10.833; 17.866
93.782; 92.825; 112.388
1531.9Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4072190 CIFC34 H40 O2 P2P 1 21/c 110.9457; 12.8989; 11.2301
90; 104.899; 90
1532.2Long, Richard J.; Jones, David J.; Gibson, Vernon C.; White, Andrew J. P.
Zirconium Complexes Containing Tetradentate O,P,P,O Ligands: Ethylene and Propylene Polymerization Studies
Organometallics, 2008, 27, 5960
4071813 CIFC32 H38 N4 Pt SP -17.8393; 13.7453; 14.55
94.905; 97.696; 97.36
1532.5Moret, Marc-Etienne; Chen, Peter
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands
Organometallics, 2008, 27, 4903

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