Crystallography Open Database

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4071084 CIFC14 H8 Cl2 F12 Fe P2 PtP 1 21/c 19.661; 13.369; 17.265
90; 114.609; 90
2027.4Velazco, Euclides J.; Caffyn, Andrew J. M.; Le Goff, Xavier F.; Ricard, Louis
Synthesis, Structure, and Coordination Properties of 1,1′-Bis(bis(trifluoromethyl)phosphino)ferrocene, dfmpf
Organometallics, 2008, 27, 2402
4071085 CIFC18 H8 Cl2 F20 Fe P2 PtP 1 21/c 116.293; 18.822; 18.758
90; 112.877; 90
5300Velazco, Euclides J.; Caffyn, Andrew J. M.; Le Goff, Xavier F.; Ricard, Louis
Synthesis, Structure, and Coordination Properties of 1,1′-Bis(bis(trifluoromethyl)phosphino)ferrocene, dfmpf
Organometallics, 2008, 27, 2402
4071086 CIFC18 H24 F6 Fe N2 P PdP 1 21/c 116.188; 12.58; 21.091
90; 92.701; 90
4290.3Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4071087 CIFC18 H25 F6 Fe N2 P PdP 1 21/c 116.188; 12.58; 21.091
90; 92.701; 90
4290.3Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4071112 CIFC17 H12 Cl Mn O5P 1 21/c 112.2077; 12.2447; 12.4139
90; 114.101; 90
1693.9Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4071117 CIFC31 H48 Li Ni O7P 1 21/c 131.21; 11.851; 17.44
90; 98.85; 90
6374Buchalski, Piotr; Grabowska, Ilona; Kamińska, Elżbieta; Suwińska, Kinga
Synthesis and Structures of 9-Nickelafluorenyllithium Complexes
Organometallics, 2008, 27, 2346
4071118 CIFC21 H23 Li Ni O2P 1 21/c 116.5651; 14.5732; 17.3587
90; 116.77; 90
3741.37Buchalski, Piotr; Grabowska, Ilona; Kamińska, Elżbieta; Suwińska, Kinga
Synthesis and Structures of 9-Nickelafluorenyllithium Complexes
Organometallics, 2008, 27, 2346
4071119 CIFC16 H26 F6 N2 O2 P Rh SP 1 21/c 19.4642; 16.1506; 14.466
90; 106.127; 90
2124.15Schaub, Thomas; Radius, Udo; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium
Organometallics, 2008, 27, 1892
4071120 CIFC17 H29 B F4 Ir N3 O SP 1 21/c 110.722; 16.832; 11.867
90; 91.74; 90
2140.7Schaub, Thomas; Radius, Udo; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium
Organometallics, 2008, 27, 1892
4071128 CIFC59 H49 Fe N3 P2P 1 21/c 114.979; 16.927; 19.189
90; 101.118; 90
4774Montigny, Frédéric de; Argouarch, Gilles; Roisnel, Thierry; Toupet, Loic; Lapinte, Claude; Lam, Sally Chan-Fung; Tao, Chi-Hang; Yam, Vivian Wing-Wah
Syntheses, Structures, and Properties of Some Piano-Stool Iron Acetylides Bearing a Functional Anthracenyl Group
Organometallics, 2008, 27, 1912
4071133 CIFC30 H44 P Pt SiP 1 21/c 110.218; 13.957; 20.078
90; 93.089; 90
2859.2Tanabe, Makoto; Ito, Daisuke; Osakada, Kohtaro
Ligand Exchange of Diplatinum Complexes with Bridging Silyl Ligands Involving Si−H Bond Cleavage and Formation
Organometallics, 2008, 27, 2258
4071139 CIFC21 H10 Fe4 O9 S2P 1 21/c 113.6715; 7.1808; 24.949
90; 94.762; 90
2440.8Mathur, Pradeep; Singh, Amrendra K.; Mohanty, Jamini R.; Chatterjee, Saurav; Mobin, Shaikh M.
Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between TrimethylamineN-Oxide and Acetylenes on Fe3Te2(CO)9and Contrast with Reactions on Fe3E2(CO)9(E = S, Se)
Organometallics, 2008, 27, 5094
4071140 CIFC33 H20 Fe5 O9 S2P 1 21/c 110.1722; 12.7137; 25.4348
90; 101.025; 90
3228.7Mathur, Pradeep; Singh, Amrendra K.; Mohanty, Jamini R.; Chatterjee, Saurav; Mobin, Shaikh M.
Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between TrimethylamineN-Oxide and Acetylenes on Fe3Te2(CO)9and Contrast with Reactions on Fe3E2(CO)9(E = S, Se)
Organometallics, 2008, 27, 5094
4071162 CIFC42 H36 Br2 N4 NiP 1 21/c 15.8346; 18.133; 16.3959
90; 91.495; 90
1734.08Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071170 CIFC31 H55 I Si4 SnP 1 21/c 111.554; 38.173; 8.728
90; 108.207; 90
3657Kavara, Ajdin; Cousineau, Kandarpa D.; Rohr, Ahleah D.; Kampf, Jeff W.; Banaszak Holl, Mark M.
A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
Organometallics, 2008, 27, 1041
4071172 CIFC22 H49 Br Si4 SnP 1 21/c 18.6851; 11.7882; 29.04
90; 92.076; 90
2971.2Kavara, Ajdin; Cousineau, Kandarpa D.; Rohr, Ahleah D.; Kampf, Jeff W.; Banaszak Holl, Mark M.
A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
Organometallics, 2008, 27, 1041
4071177 CIFC65 H67 P3 Pt2 Si2P 1 21/c 116.777; 21.215; 16.82
90; 106.959; 90
5726.3Arii, Hidekazu; Takahashi, Makiko; Noda, Aki; Nanjo, Masato; Mochida, Kunio
Spectroscopic and Structural Studies of Thermally Unstable Intermediates Generated in the Reaction of [Pt(PPh3)2(η2-C2H4)] with Dihydrodisilanes
Organometallics, 2008, 27, 1929
4071180 CIFC16 H22 B0.2 F0.8 I1.8 N6 RuP 1 21/c 19.4985; 8.0984; 27.008
90; 90.21; 90
2077.5Poyatos, Macarena; McNamara, William; Incarvito, Chris; Clot, Eric; Peris, Eduardo; Crabtree, Robert H.
A Weak Donor, Planar Chelating Bitriazole N-Heterocyclic Carbene Ligand for Ruthenium(II), Palladium(II), and Rhodium
Organometallics, 2008, 27, 2128
4071185 CIFC40 H51 Cl6 F6 N4 O P RuP 1 21/c 123.998; 10.1734; 19.0161
90; 95.455; 90
4621.6Clavier, Hervé; Nolan, Steven P.; Mauduit, Marc
Ionic Liquid Anchored “Boomerang” Catalysts Bearing Saturated and Unsaturated NHCs: Recyclability in Biphasic Media for Cross-Metathesis
Organometallics, 2008, 27, 2287
4071188 CIFC36 H40 Os P2P 1 21/c 115.584; 15.643; 12.747
90; 101.54; 90
3044.7Dub, Pavel A.; Belkova, Natalia V.; Lyssenko, Konstantin A.; Silantyev, Gleb A.; Epstein, Lina M.; Shubina, Elena S.; Daran, Jean-Claude; Poli, Rinaldo
Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
Organometallics, 2008, 27, 3307
4071190 CIFC40 H59 N2 Ni O PP 1 21/c 110.2237; 21.053; 18.063
90; 96.135; 90
3865.6Azoulay, Jason D.; Itigaki, Koji; Wu, Guang; Bazan, Guillermo C.
Influence of Steric and Electronic Perturbations on the Polymerization Activities of α-Iminocarboxamide Nickel Complexes
Organometallics, 2008, 27, 2273
4071191 CIFC39 H57 N2 Ni O PP 1 21/c 19.716; 20.04; 19.496
90; 100.578; 90
3732Azoulay, Jason D.; Itigaki, Koji; Wu, Guang; Bazan, Guillermo C.
Influence of Steric and Electronic Perturbations on the Polymerization Activities of α-Iminocarboxamide Nickel Complexes
Organometallics, 2008, 27, 2273
4071194 CIFC31 H32 I P PdP 1 21/c 114.8326; 10.1125; 18.9106
90; 95.575; 90
2823.1Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071195 CIFC31 H33 I O3 P2 PdP 1 21/c 117.7153; 9.8948; 19.5425
90; 115.745; 90
3085.6Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071198 CIFC34 H30 I O2 P Pd SP 1 21/c 115.5188; 17.4313; 23.4898
90; 91.454; 90
6352.2Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071203 CIFC24 H25 Cl4 Fe N3P 1 21/c 110.414; 15.2465; 15.8488
90; 92.365; 90
2514.3Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4071205 CIFC36 H42 B Cl2 Fe N3 O2P 1 21/c 18.65; 23.25; 17.26
90; 90.99; 90
3471Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4071206 CIFC61 H74 B2 Cl6 Fe2 N6 O4P 1 21/c 131.466; 8.8961; 25.037
90; 111.985; 90
6498.8Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4071207 CIFC30 H36 B Cl2 Fe N3 O2P 1 21/c 114.116; 15.902; 14.105
90; 101.311; 90
3104.7Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4071208 CIFC29 H33 B Br Cl2 Fe N3 O2P 1 21/c 114.112; 15.854; 13.83
90; 100.75; 90
3040Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4071211 CIFC24 H47 P Si4 ZrP 1 21/c 117.927; 11.581; 17.288
90; 118.57; 90
3152.2Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071213 CIFC23 H43 P Si3 ZrP 1 21/c 118.106; 10.444; 15.295
90; 98.92; 90
2857.3Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071214 CIFC23 H43 Hf P Si3P 1 21/c 118.106; 10.445; 15.257
90; 99.06; 90
2849.4Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071218 CIFC32 H38 Si3 TiP 1 21/c 19.3013; 31; 11.056
90; 108.86; 90
3016.7Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071219 CIFC54 H66 Si6 ZrP 1 21/c 119.039; 9.6121; 30.102
90; 93.73; 90
5497.1Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071220 CIFC32 H38 Si3 ZrP 1 21/c 19.2332; 31.118; 11.252
90; 109.38; 90
3049.7Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071223 CIFC20 H22 Cl2 TiP 1 21/c 16.6105; 21.534; 12.248
90; 93.12; 90
1740.9Sassmannshausen, Jörg; Baumgartner, Judith
Synthesis, Reactivity, and Computational Studies of [η5-C5H5-(η5-C5H4CMe2C6H4Me)TiMe]+: Aromatic C−H Bond Activation at −50 °C§
Organometallics, 2008, 27, 1996
4071225 CIFC67 H58 Ge4P 1 21/c 112.6857; 18.4965; 23.2259
90; 98.34; 90
5392.1Amadoruge, Monika L.; Golen, James A.; Rheingold, Arnold L.; Weinert, Charles S.
Preparation, Structure, and Reactivity of Discrete Branched Oligogermanes⊥
Organometallics, 2008, 27, 1979
4071230 CIFC33 H52 O9 Os3 P2 Pt2P 1 21/c 115.303; 13.4145; 24.337
90; 95.975; 90
4968.8Adams, Richard D.; Boswell, Erin
Cleavage oftert-Butyl Groups from the Tri-tert-butylphosphine Ligand in Osmium−Platinum Carbonyl Cluster Complexes
Organometallics, 2008, 27, 2021
4071231 CIFC31 H50 O7 Os3 P2 PtP 1 21/c 113.7017; 10.4238; 26.7764
90; 96.779; 90
3797.6Adams, Richard D.; Boswell, Erin
Cleavage oftert-Butyl Groups from the Tri-tert-butylphosphine Ligand in Osmium−Platinum Carbonyl Cluster Complexes
Organometallics, 2008, 27, 2021
4071234 CIFC19 H25 N2 O4.5 PdP 1 21/c 113.41; 11.004; 27.454
90; 92.49; 90
4047.4Giri, Ramesh; Maugel, Nathan; Foxman, Bruce M.; Yu, Jin-Quan
Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
Organometallics, 2008, 27, 1667
4071240 CIFC24 H36 Ni O2 P2P 1 21/c 115.0464; 10.5122; 16.57
90; 112.802; 90
2416.07Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071241 CIFC26 H36 Ni O4 P2P 1 21/c 111.1191; 16.6497; 14.3339
90; 90.172; 90
2653.62Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071242 CIFC27 H36 Ni O5 P2P 1 21/c 114.9964; 9.3798; 19.6238
90; 102.52; 90
2694.71Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071253 CIFC30 H33 Mo3 O7 PP 1 21/c 110.0881; 15.58; 19.2306
90; 95.895; 90
3006.54Alvarez, M. Angeles; García-Vivó, Daniel; García, M. Esther; Martínez, M. Eugenia; Ramos, Alberto; Ruiz, Miguel A.
Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives
Organometallics, 2008, 27, 1973
4071254 CIFC69 H74 Fe4 Mo4 O16 P2P 1 21/c 113.3752; 11.7509; 25.3894
90; 119.262; 90
3481.26Alvarez, M. Angeles; García-Vivó, Daniel; García, M. Esther; Martínez, M. Eugenia; Ramos, Alberto; Ruiz, Miguel A.
Reactivity of the α-Agostic Methyl Bridge in the Unsaturated Complex [Mo2(η5-C5H5)2(μ-η1:η2-CH3)(μ-PCy2)(CO)2]: Migratory Behavior and Methylidyne Derivatives
Organometallics, 2008, 27, 1973
4071260 CIFC36 H30 Cl2 N O2 P RuP 1 21/c 117.8778; 9.6153; 18.4977
90; 107.393; 90
3034.4Mikhel, Igor S.; Rüegger, Heinz; Butti, Pietro; Camponovo, Francesco; Huber, Dominik; Mezzetti, Antonio
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes
Organometallics, 2008, 27, 2937
4071262 CIFC27 H45 La N2 SiP 1 21/c 111.505; 14.053; 17.978
90; 102.539; 90
2837.4Evans, William J.; Montalvo, Elizabeth; Champagne, Timothy M.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.
Diazomethane Insertion into Lanthanide− and Yttrium−C(allyl) Bonds To Form the η2-Hydrazonato Complexes (C5Me5)2Ln[η2(N,N′)-RNNCHSiMe3] (R = C3H5)
Organometallics, 2008, 27, 3582
4071263 CIFC27 H45 N2 Si YP 1 21/c 111.509; 13.9781; 18.573
90; 106.132; 90
2870.3Evans, William J.; Montalvo, Elizabeth; Champagne, Timothy M.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.
Diazomethane Insertion into Lanthanide− and Yttrium−C(allyl) Bonds To Form the η2-Hydrazonato Complexes (C5Me5)2Ln[η2(N,N′)-RNNCHSiMe3] (R = C3H5)
Organometallics, 2008, 27, 3582
4071269 CIFC30 H50 Br2 N4 O2 Zn2P 1 21/c 17.8297; 10.2172; 21.8335
90; 95.325; 90
1739.1Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071270 CIFC32 H52 Br2 N2 O4 Zn2P 1 21/c 111.7235; 9.287; 17.3462
90; 96.592; 90
1876.1Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071271 CIFC28 H40 Br2 N2 O4 Zn2P 1 21/c 18.123; 12.489; 16.18
90; 101.256; 90
1609.9Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071275 CIFC25 H17 Fe2 O6 P S2P 1 21/c 115.333; 10.876; 17.09
90; 112.554; 90
2632Song, Li-Cheng; Zeng, Guang-Huai; Lou, Shao-Xia; Zan, Hui-Ning; Ming, Jiang-Bo; Hu, Qing-Mei
Synthetic and Structural Studies of Butterfly Fe/S/P Cluster Complexes Related to the Active Site of [FeFe]-Hydrogenases. Proton Reduction to H2Catalyzed by (η1-Ph2PS-η1)2Fe2(CO)6
Organometallics, 2008, 27, 3714
4071284 CIFC66 H82 Cl10 N4 Pd2P 1 21/c 112.521; 10.182; 27.5197
90; 94.7006; 90
3496.65Chitanda, Jackson M.; Prokopchuk, Demyan E.; Quail, J. Wilson; Foley, Stephen R.
From Pyrroles to Isoindolines: Synthesis of a γ-Diimine Ligand for Applications in Palladium Coordination Chemistry and Catalysis
Organometallics, 2008, 27, 2337
4071289 CIFC54 H36 Al4 F36 O6P 1 21/c 117.285; 12.598; 30.701
90; 90.248; 90
6685Martínez, Gema; Pedrosa, Sergio; Tabernero, Vanessa; Mosquera, Marta E. G.; Cuenca, Tomás
Controlled Synthesis of Novel Aryloxide Polynuclear Aluminum Species. Study of Their Catalytic Properties in Polymerization Processes†
Organometallics, 2008, 27, 2300
4071290 CIFC7 H19 Fe0.5 P2P 1 21/c 18.762; 12.581; 12.814
90; 132.979; 90
1033.4Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4071295 CIFC70 H109 N8 Ni Sn4P 1 21/c 118.149; 12.499; 32.399
90; 101.773; 90
7195Zabula, Alexander V.; Pape, Tania; Hepp, Alexander; Hahn, F. Ekkehardt
Homoleptic Complexes of Bisstannylenes with Nickel(0): Synthesis, X-Ray Diffraction Studies, and119Sn NMR Investigations
Organometallics, 2008, 27, 2756
4071299 CIFC25 H34 Cl2 N O3 VP 1 21/c 17.5894; 13.7589; 24.542
90; 96.35; 90
2547Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071300 CIFC29 H42 Cl2 N O3 VP 1 21/c 110.7986; 21.683; 12.8415
90; 91.601; 90
3005.6Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071309 CIFC37 H43 Au Cl N2 P SP 1 21/c 112.0427; 14.638; 19.781
90; 103.936; 90
3384.4Nakabuchi, Takashi; Matano, Yoshihiro; Imahori, Hiroshi
Synthesis, Structures, and Coordinating Properties of Phosphole-Containing Hybrid Calixpyrroles
Organometallics, 2008, 27, 3142
4071310 CIFC37 H43 Au Cl N2 P SP 1 21/c 112.5038; 13.0739; 20.303
90; 99.716; 90
3271.4Nakabuchi, Takashi; Matano, Yoshihiro; Imahori, Hiroshi
Synthesis, Structures, and Coordinating Properties of Phosphole-Containing Hybrid Calixpyrroles
Organometallics, 2008, 27, 3142
4071312 CIFC74 H86 Cl2 N4 P2 Pt S2P 1 21/c 117.7327; 15.9055; 24.023
90; 90.823; 90
6774.9Nakabuchi, Takashi; Matano, Yoshihiro; Imahori, Hiroshi
Synthesis, Structures, and Coordinating Properties of Phosphole-Containing Hybrid Calixpyrroles
Organometallics, 2008, 27, 3142
4071319 CIFC24 H50 Cl2 N4 P2 Si2 Sn2P 1 21/c 113.704; 16.533; 16.125
90; 92.341; 90
3650.4Leung, Wing-Por; Chan, Ka-Po; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heteroleptic Tin(II) and Lead(II) Compounds from Pyrazyl-Linked Bisphosphoranoimine
Organometallics, 2008, 27, 2767
4071320 CIFC34 H60 N4 P2 Si2 Sn2P 1 21/c 117.645; 16.011; 15.407
90; 102.609; 90
4248Leung, Wing-Por; Chan, Ka-Po; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heteroleptic Tin(II) and Lead(II) Compounds from Pyrazyl-Linked Bisphosphoranoimine
Organometallics, 2008, 27, 2767
4071324 CIFC23 H26 Cl N2 RhP 1 21/c 115.6914; 8.8419; 14.6448
90; 95.747; 90
2021.63Song, Guoyong; Zhang, Yao; Li, Xingwei
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
Organometallics, 2008, 27, 1936
4071325 CIFC18 H13 Cl F3 Ir N2 O2P 1 21/c 114.2118; 8.7062; 15.8811
90; 110.789; 90
1837.05Song, Guoyong; Zhang, Yao; Li, Xingwei
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
Organometallics, 2008, 27, 1936
4071334 CIFC59 H71 I3 N4 O1.5 P2 RhP 1 21/c 120.4631; 17.5908; 17.3128
90; 113.3; 90
5723.7Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4071335 CIFC32 H48 N4 Ni O2P 1 21/c 111.1412; 18.133; 16.174
90; 103.358; 90
3179.1Scott, Natalie M.; Clavier, Hervé; Mahjoor, Parisa; Stevens, Edwin D.; Nolan, Steven P.
Synthetic, Structural, and Thermochemical Studies of N-Heterocyclic Carbene (NHC) and Tertiary Phosphine Ligands in the [(L)2Ni(CO)2] (L = PR3, NHC) System
Organometallics, 2008, 27, 3181
4071344 CIFC40.5 H48 N4 S TiP 1 21/c 111.1455; 12.2427; 25.737
90; 97.782; 90
3479.5Vujkovic, Nadia; Fillol, Julio Lloret; Ward, Benjamin D.; Wadepohl, Hubert; Mountford, Philip; Gade, Lutz H.
Insertions into Azatitanacyclobutenes: New Insights into Three-Component Coupling Reactions Involving Imidotitanium Intermediates
Organometallics, 2008, 27, 2518
4071345 CIFC40.5 H48 N4 Se TiP 1 21/c 111.2101; 12.1801; 25.94
90; 97.311; 90
3513.1Vujkovic, Nadia; Fillol, Julio Lloret; Ward, Benjamin D.; Wadepohl, Hubert; Mountford, Philip; Gade, Lutz H.
Insertions into Azatitanacyclobutenes: New Insights into Three-Component Coupling Reactions Involving Imidotitanium Intermediates
Organometallics, 2008, 27, 2518
4071347 CIFC25 H36 Cl2 N4 TiP 1 21/c 118.8864; 16.5995; 17.9096
90; 105.273; 90
5416.4Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071350 CIFC29 H34 Cl4 N4 TiP 1 21/c 19.2583; 40.714; 8.6018
90; 108.365; 90
3077.2Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071352 CIFC48 H51 Cl4 N5 TiP 1 21/c 113.2498; 14.9309; 23.7215
90; 89.522; 90
4692.7Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071355 CIFC19 H35 I P2 Pt SiP 1 21/c 116.982; 10.492; 15.289
90; 113.21; 90
2504Canty, Allan J.; Watson, Russell P.; Karpiniec, Samuel S.; Rodemann, Thomas; Gardiner, Michael G.; Jones, Roderick C.
Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
Organometallics, 2008, 27, 3203
4071362 CIFC20 H27 B F4 Ir N OP 1 21/c 18.626; 15.356; 16.209
90; 91.429; 90
2146.4Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071365 CIFC24 H18 Cl3 N9 O P RhP 1 21/c 19.3892; 16.7894; 21.7055
90; 109.176; 90
3231.78van Assema, Sander G. A.; Tazelaar, Cornelis G. J.; de Jong, G. Bas; van Maarseveen, Jan H.; Schakel, Marius; Lutz, Martin; Spek, Anthony L.; Slootweg, J. Chris; Lammertsma, Koop
Phospha-Scorpionate Complexes by Click Chemistry using Phenyl Azide and Ethynylphosphine Oxides
Organometallics, 2008, 27, 3210
4071367 CIFC36 H26 Mo N9 O9 P WP 1 21/c 110.87209; 17.3152; 29.607
90; 98.052; 90
5518.64van Assema, Sander G. A.; Tazelaar, Cornelis G. J.; de Jong, G. Bas; van Maarseveen, Jan H.; Schakel, Marius; Lutz, Martin; Spek, Anthony L.; Slootweg, J. Chris; Lammertsma, Koop
Phospha-Scorpionate Complexes by Click Chemistry using Phenyl Azide and Ethynylphosphine Oxides
Organometallics, 2008, 27, 3210
4071374 CIFC47 H57 N O2 TiP 1 21/c 19.67; 19.257; 21.95
90; 102.286; 90
3993.8Agapie, Theodor; Henling, Lawrence M.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Bercaw, John E.
Zirconium and Titanium Complexes Supported by Tridentate LX2Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization
Organometallics, 2008, 27, 6245
4071378 CIFC78 H72 Cl3 Cu3 P6P 1 21/c 126.08; 15.074; 19.347
90; 109.63; 90
7164Daly, Stephen; Haddow, Mairi F.; Orpen, A. Guy; Rolls, Giles T. A.; Wass, Duncan F.; Wingad, Richard L.
Copper(I) Diphosphine Catalysts for C−N Bond Formation: Synthesis, Structure, and Ligand Effects
Organometallics, 2008, 27, 3196
4071382 CIFC8 H13 Br N2P 1 21/c 16.7845; 10.725; 13.111
90; 101.54; 90
934.7Normand, Adrien T.; Yen, Swee Kuan; Huynh, Han Vinh; Hor, T. S. Andy; Cavell, Kingsley J.
Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple
Organometallics, 2008, 27, 3153
4071386 CIFC10 H17 O3 PP 1 21/c 18.176; 8.0969; 16.669
90; 94.144; 90
1100.6Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071387 CIFC10 H16 Cl O3 PP 1 21/c 19.656; 8.3144; 15.116
90; 100.463; 90
1193.4Downing, Joanne H.; Floure, Joëlle; Heslop, Katie; Haddow, Mairi F.; Hopewell, Jonathan; Lusi, Matteo; Phetmung, Hirahataya; Orpen, A. Guy; Pringle, Paul G.; Pugh, Robert I.; Zambrano-Williams, Damaris
General Routes to Alkyl Phosphatrioxaadamantane Ligands
Organometallics, 2008, 27, 3216
4071394 CIFC18 H30 Cl2 Cr N3 SiP 1 21/c 111.2546; 12.3589; 15.0347
90; 93.67; 90
2087Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4071395 CIFC22 H38 Cl2 Cr N3 SiP 1 21/c 117.1117; 8.9247; 16.6329
90; 96.069; 90
2525.9Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4071397 CIFC22 H32 Cl2 Cr N3 SiP 1 21/c 19.627; 27.1476; 18.3241
90; 91.22; 90
4787.9Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4071404 CIFC18 H28 Cl3 N Os2P 1 21/c 115.4555; 9.2944; 13.939
90; 100.518; 90
1968.7Esteruelas, Miguel A.; García-Yebra, Cristina; Oñate, Enrique
[H(EtOH)2][{OsCl(η4-COD)}2(μ-H)(μ-Cl)2] as an Intermediate for the Preparation of [OsCl2(COD)]xand Its Activity as an Ionic Hydrogenation and Etherification Catalyst
Organometallics, 2008, 27, 3029
4071406 CIFC41 H51 P Rh Si4P 1 21/c 19.5341; 38.073; 12.292
90; 110.462; 90
4180.4Sunada, Yusuke; Fujimura, Yoshiki; Nagashima, Hideo
“Synergistic Effects of Two Si−H Groups and a Metal Center” in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules: A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene
Organometallics, 2008, 27, 3502
4071409 CIFC59 H49 Cl2 Os P3P 1 21/c 111.8066; 23.7395; 17.4227
90; 90.885; 90
4882.7Gong, Lei; Lin, Yumei; Wen, Ting Bin; Zhang, Hong; Zeng, Birong; Xia, Haiping
Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
Organometallics, 2008, 27, 2584
4071410 CIFC59 H49 Cl2 O0 Os P3P 1 21/c 112.403; 18.544; 21.4896
90; 102.065; 90
4833.5Gong, Lei; Lin, Yumei; Wen, Ting Bin; Zhang, Hong; Zeng, Birong; Xia, Haiping
Formation of Four Conjugated Osmacyclic Species in a One-Pot Reaction
Organometallics, 2008, 27, 2584
4071413 CIFC20 H33 Mo N OP 1 21/c 113.1444; 9.1621; 16.758
90; 106.02; 90
1939.8Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071414 CIFC21 H33 Mo N OP 1 21/c 18.9342; 13.7757; 16.5414
90; 101.191; 90
1997.1Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071417 CIFC28 H42 Mo N2 OP 1 21/c 114.8524; 9.2086; 20.619
90; 110.106; 90
2648.2Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071422 CIFC43 H71 Lu O6 S2 SiP 1 21/c 113.4712; 27.631; 13.4928
90; 114.665; 90
4564.1Konkol, Marcin; Kondracka, Malgorzata; Voth, Peter; Spaniol, Thomas P.; Okuda, Jun
Rare-Earth Metal Alkyl and Hydrido Complexes Containing a Thioether-Functionalized Bis(phenolato) Ligand: Efficient Catalysts for Olefin Hydrosilylation
Organometallics, 2008, 27, 3774
4071427 CIFC68 H80 O2 P2 PtP 1 21/c 114.684; 22.008; 18.693
90; 107.72; 90
5754.3Hayashi, Kyohei; Nakatani, Mitsuharu; Hayashi, Akito; Takano, Masato; Okazaki, Masaaki; Toyota, Kozo; Yoshifuji, Masaaki; Ozawa, Fumiyuki
Synthesis and Structures of Platinum(0) Alkyne Complexes with Extended π-Conjugated Systems
Organometallics, 2008, 27, 1970
4071434 CIFC44 H59 B11 Ir N O P2 SnP 1 21/c 120.38; 18.465; 13.154
90; 97.689; 90
4906Kirchmann, Marius; Fleischhauer, Sebastian; Wesemann, Lars
Iridium Coordination Compounds of Stanna-closo-dodecaborate
Organometallics, 2008, 27, 2803
4071441 CIFC58 H90 O10 Si2 Y2P 1 21/c 113.3954; 13.4091; 17.5993
90; 106.135; 90
3036.7Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071442 CIFC58 H90 Dy2 O10 Si2P 1 21/c 113.403; 13.414; 17.451
90; 105.954; 90
3017Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071449 CIFC28 H17 Cl3 Cr2 O9 S TiP 1 21/c 111.26; 12.083; 23.804
90; 101.009; 90
3179Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071450 CIFC32 H18 Cr2 Fe O12 TiP 1 21/c 19.9813; 15.865; 20.1457
90; 101.723; 90
3123.6Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071457 CIFC31 H39 Cl2 N2 O VP 1 21/c 118.7923; 19.5289; 19.3387
90; 119.063; 90
6203.5Onishi, Yoshifumi; Katao, Shohei; Fujiki, Michiya; Nomura, Kotohiro
Synthesis and Structural Analysis of (Arylimido)vanadium(V) Complexes Containing Phenoxyimine Ligands: New, Efficient Catalyst Precursors for Ethylene Polymerization
Organometallics, 2008, 27, 2590
4071459 CIFC24 H28 N2 O4 S4P 1 21/c 124.396; 10.121; 10.18
90; 96.305; 90
2498.4Liu, Wei; Chen, Ya; Wang, Ru; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng
Rhenium(I) Tricarbonyl Complexes with New Pyridine Ligands Containing Crown Ether-Annelated or Anthracene-Functionalized 1,3-Dithiole-2-ylidene
Organometallics, 2008, 27, 2990
4071464 CIFC23 H32 N2 OP 1 21/c 18.3752; 22.935; 21.51
90; 96.43; 90
4105.8Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071473 CIFC21 H39 F3 N3 O3 Rh SP 1 21/c 19.533; 10.886; 23.252
90; 91.804; 90
2411.8Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071474 CIFC60 H117 F18 N9 Rh3 Sb3P 1 21/c 121.59; 23.061; 14.538
90; 98.05; 90
7167Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071475 CIFC20 H39 F6 Ir N3 SbP 1 21/c 19.532; 10.833; 23.082
90; 91.304; 90
2382.83Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071476 CIFC28 H51 Cl2 N3 Rh2P 1 21/c 18.575; 19.68; 19.295
90; 115.481; 90
2939.42Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071479 CIFC20 H48 Li N3 ZnP 1 21/c 110.0802; 14.9984; 16.8398
90; 94.22; 90
2539.05Clegg, William; García-Álvarez, Joaquín; García-Álvarez, Pablo; Graham, David V.; Harrington, Ross W.; Hevia, Eva; Kennedy, Alan R.; Mulvey, Robert E.; Russo, Luca
Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†
Organometallics, 2008, 27, 2654
4071480 CIFC58 H86 Li2 N6 Zn2P 1 21/c 112.9978; 16.615; 15.8875
90; 118.218; 90
3023.3Clegg, William; García-Álvarez, Joaquín; García-Álvarez, Pablo; Graham, David V.; Harrington, Ross W.; Hevia, Eva; Kennedy, Alan R.; Mulvey, Robert E.; Russo, Luca
Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†
Organometallics, 2008, 27, 2654
4071482 CIFC22 H26 N2 ZnP 1 21/c 111.6198; 9.6815; 18.3865
90; 107.61; 90
1971.5Clegg, William; García-Álvarez, Joaquín; García-Álvarez, Pablo; Graham, David V.; Harrington, Ross W.; Hevia, Eva; Kennedy, Alan R.; Mulvey, Robert E.; Russo, Luca
Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and Sodium DA-Zincate Bases (DA = diisopropylamide) with Phenylacetylene†
Organometallics, 2008, 27, 2654
4071486 CIFC38 H42 O5 P2 WP 1 21/c 111.5587; 24.323; 15.4742
90; 119.913; 90
3770.92Jansen, Helen; Rosenthal, Amos J.; Slootweg, J. Chris; Ehlers, Andreas W.; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop
Diastereoselective Formation of Complexed Methylenediphosphiranes
Organometallics, 2008, 27, 2868
4071492 CIFC28 H78 Al2 Si8P 1 21/c 112.3162; 42.191; 9.3853
90; 111.791; 90
4528.4Uhl, Werner; Er, Elif; Hepp, Alexander; Kösters, Jutta; Grunenberg, Jörg
Reactions of Terminal Alkynes with a Bulky Dialkylaluminum Hydride: Hydroalumination versus Deprotonation
Organometallics, 2008, 27, 3346
4071501 CIFC32 H27 B F10 Ir NP 1 21/c 110.2691; 19.219; 14.5208
90; 96.108; 90
2849.58Herrmann, Christoph; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Chemical Behavior of a Pair of (COD)CpRh and −Ir Complexes with Pendant Peripheral −B(C6F5)2Groups†
Organometallics, 2008, 27, 2328
4071506 CIFC20 H24 F6 N2 O6 S2 SnP 1 21/c 113.7458; 9.3395; 19.9533
90; 98.0965; 90
2536.05Kašná, Blanka; Dostál, Libor; Jirásko, Robert; Císařová, Ivana; Jambor, Roman
Role of Y,C,Y-Chelating Ligands in Control Hydrolysis of Diorganotin Compounds†
Organometallics, 2008, 27, 3743
4071514 CIFC38 H47 Cl4 F3 N3 O4 P Pd SP 1 21/c 117.7886; 13.7537; 35.728
90; 98.698; 90
8640.6Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4071520 CIFC21 H30 Cl N3 O5 PdP 1 21/c 113.912; 23.1974; 16.0669
90; 113.257; 90
4763.8Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4071522 CIFC29 H31 I2 N3 O PdP 1 21/c 19.8875; 19.6683; 16.0188
90; 102.863; 90
3037.01Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4071538 CIFC36 H70 Mn Na O6 S2 Si2P 1 21/c 123.1442; 17.4691; 23.2056
90; 104.506; 90
9083.1Kückmann, Theresa I.; Schödel, Frauke; Sänger, Inge; Bolte, Michael; Wagner, Matthias; Lerner, Hans-Wolfram
Mixed-Valence Manganese Carbonyl Complexes with Supersilyl Thiolate Ligands: [(OC)4Mn(μ-SSitBu3)2Mn(THF)X] (X = Br, SSitBu3) and Na(THF)6[(OC)3Mn(μ-SSitBu3)3MnSSitBu3]
Organometallics, 2008, 27, 3272
4071543 CIFC27 H36 Cl N2 O3 RhP 1 21/c 115.962; 10.6524; 17.215
90; 114.013; 90
2673.8Ito, Jun-ichi; Miyakawa, Takeshi; Nishiyama, Hisao
Amine-Assisted C−Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex
Organometallics, 2008, 27, 3312
4071547 CIFC63.5 H70 B Cl2 Ru2P 1 21/c 118.5122; 11.5818; 27.5397
90; 106.626; 90
5657.79Zhang, Li; Sung, Herman Ho-Yung; Williams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Reactions of Cp*RuCl(COD) with Alkynes: Isolation of Dinuclear Metallacyclopentatriene Complexes
Organometallics, 2008, 27, 5122
4071549 CIFC52 H24 Cl6 Fe8 O28 S4P 1 21/c 113.241; 26.387; 11.576
90; 115.037; 90
3664Song, Li-Cheng; Fang, Xiao-Niu; Li, Chang-Gong; Yan, Jing; Bao, Hai-Lin; Hu, Qing-Mei
Novel μ-CO-Containing Butterfly Fe/S Cluster Anions Generated from Tetrathiols, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles To Give Neutral Butterfly Fe/S Cluster Complexes
Organometallics, 2008, 27, 3225
4071553 CIFC36 H57 N6 Sb5P 1 21/c 110.312; 34.361; 13.847
90; 117.132; 90
4366.5Dostál, Libor; Jambor, Roman; Růžička, Aleš; Holeček, Jaroslav
Syntheses and Structures of Ar3Sb5and Ar4Sb4Compounds (Ar = C6H3-2,6-(CH2NMe2)2)
Organometallics, 2008, 27, 2169
4071555 CIFC24 H30 Cl2 N6 O2 PdP 1 21/c 110.646; 9.0631; 14.374
90; 105.509; 90
1336.4Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071556 CIFC18 H20 Cl2 N4 PdP 1 21/c 17.745; 12.647; 11.215
90; 120.353; 90
947.9Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071557 CIFC18 H20 Cl2 N4 PdP 1 21/c 110.5073; 13.1943; 14.06
90; 105.395; 90
1879.3Kawamura, Kenjiro; Haneda, Satoshi; Gan, Zhibin; Eda, Kazuo; Hayashi, Masahiko
2-Phenylimidazole−PdCl2and 2-Phenylimidazoline−PdCl2Complexes: Single-Crystal and Powder X-ray Diffractometry,1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions†
Organometallics, 2008, 27, 3748
4071570 CIFC23 H44 B9 Cl Na O4 ZrP 1 21/c 116.3272; 11.6787; 19.0496
90; 114.662; 90
3301.1Wang, Yaorong; Liu, Dongmei; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me2C(C5H4)(C2B9H10)]3−
Organometallics, 2008, 27, 2825
4071593 CIFC52 H51 B2 F6 N O2 P2 RuP 1 21/c 110.3401; 18.5289; 25.4882
90; 92.318; 90
4879.31Chou, Hsien-Hsin; Lin, Ying-Chih; Huang, Shou-Ling; Liu, Yi-Hong; Wang, Yu
Reactions of Ruthenium Acetylide and Vinylidene Complexes Containing a 2-Pyridyl Group
Organometallics, 2008, 27, 5212
4071596 CIFC29 H56 Cl3 N4 P2 RhP 1 21/c 114.1238; 13.6555; 18.8057
90; 97.296; 90
3597.6Grotjahn, Douglas B.; Zeng, Xi; Cooksy, Andrew L.; Kassel, W. Scott; DiPasquale, Antonio G.; Zakharov, Lev N.; Rheingold, Arnold L.
Experimental and Computational Study of the Transformation of Terminal Alkynes to Vinylidene Ligands ontrans-(Chloro)bis(phosphine)Rh Fragments and Effects of Phosphine Substituents
Organometallics, 2008, 27, 3626
4071609 CIFC29 H41 Ge N2 PP 1 21/c 114.138; 16.3244; 13.8086
90; 116.379; 90
2855.11Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071614 CIFC22 H32 F12 N8 P2 Pd2P 1 21/c 17.7026; 19.112; 11.4095
90; 104.382; 90
1627Ye, Jiansheng; Zhang, Xiaoming; Chen, Wanzhi; Shimada, Shigeru
Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling
Organometallics, 2008, 27, 4166
4071616 CIFC12 H19 Cl N4 O2P 1 21/c 15.0761; 14.6843; 21.131
90; 98.605; 90
1557.4Ye, Jiansheng; Zhang, Xiaoming; Chen, Wanzhi; Shimada, Shigeru
Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling
Organometallics, 2008, 27, 4166
4071617 CIFC36 H48 Ag4 Cl4 N12P 1 21/c 121.623; 6.6427; 15.8766
90; 100.017; 90
2245.7Ye, Jiansheng; Zhang, Xiaoming; Chen, Wanzhi; Shimada, Shigeru
Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling
Organometallics, 2008, 27, 4166
4071618 CIFC30 H48 P2P 1 21/c 19.4004; 13.1537; 10.8292
90; 97.526; 90
1327.5Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4071619 CIFC18 H32 P2P 1 21/c 110.2911; 8.0562; 23.5323
90; 99.591; 90
1923.73Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4071621 CIFC69 H98 Cl2 Mo2 O8 P4P 1 21/c 119.6088; 14.9522; 23.7674
90; 94.8711; 90
6943.3Brayton, Daniel F.; Heinekey, D. Michael
Synthesis and Structure of Molybdenum and Tungsten Bisphosphine Carbonyl Dimers
Organometallics, 2008, 27, 3901
4071622 CIFC26 H22 N O P SP 1 21/c 112.2827; 17.2457; 10.7969
90; 103.48; 90
2224Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4071624 CIFC25 H19 Cl N P Pd S2P 1 21/c 113.0603; 13.7939; 13.2593
90; 109.845; 90
2246.8Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4071638 CIFC23 H25 F3 N4 O5 Ru SP 1 21/c 116.616; 11.807; 15.049
90; 120.255; 90
2550Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071640 CIFC25 H28 Cl N3 RuP 1 21/c 111.117; 10.159; 19.476
90; 94.941; 90
2191Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071644 CIFC14 H9 B F4 N4 O4P 1 21/c 116.0959; 7.1079; 14.343
90; 109.097; 90
1550.65Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071645 CIFC21 H14 OP 1 21/c 18.8665; 16.4; 10.046
90; 103.966; 90
1417.6Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071646 CIFC22 H16 O2P 1 21/c 122.353; 4.2632; 16.519
90; 94.393; 90
1569.6Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071648 CIFC17 H14 Fe OP 1 21/c 110.105; 12.419; 20.819
90; 103.92; 90
2535.9Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071650 CIFC34 H26 Fe2P 1 21/c 16.311; 19.272; 20.099
90; 98.35; 90
2419Banide, Emilie V.; Ortin, Yannick; Chamiot, Bénédicte; Cassidy, Andrew; Niehaus, Jan; Moore, Angela; Seward, Corey M.; Müller-Bunz, Helge; McGlinchey, Michael J.
Syntheses, Structures, and Dimerizations of Ferrocenyl- and Fluorenylideneallenes: Push−Pull Multiple Bonds?
Organometallics, 2008, 27, 4173
4071653 CIFC37 H53 B Cl3 F4 N P2 RuP 1 21/c 116.659; 15.011; 16.473
90; 109.116; 90
3892.2Zhang, Jing; Gandelman, Mark; Shimon, Linda J. W.; Milstein, David
Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes
Organometallics, 2008, 27, 3526
4071655 CIFC23 H43 I2 N P2 RuP 1 21/c 114.88; 12.005; 16.352
90; 104.79; 90
2824.3Zhang, Jing; Gandelman, Mark; Shimon, Linda J. W.; Milstein, David
Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes
Organometallics, 2008, 27, 3526
4071658 CIFC20.6 H25 Br F6 N P RuP 1 21/c 18.2925; 15.354; 17.775
90; 94.66; 90
2255.7Gruber, Stefan; Zaitsev, Alexey B.; Wörle, Michael; Pregosin, Paul S.; Veiros, Luis F.
Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry
Organometallics, 2008, 27, 3796
4071660 CIFC48 H66 Ca N2 O2 P2 Si4P 1 21/c 111.894; 20.9365; 21.9023
90; 102.24; 90
5330.1Barrett, Anthony G. M.; Crimmin, Mark R.; Hill, Michael S.; Kociok-Köhn, Gabriele; MacDougall, Dugald J.; Mahon, Mary F.; Procopiou, Panayiotis A.
Synthesis, Characterization, and Solution Lability of N-Heterocyclic Carbene Adducts of the Heavier Group 2 Bis(trimethylsilyl)amides
Organometallics, 2008, 27, 3939
4071667 CIFC31 H46 Hf O SiP 1 21/c 115.9367; 11.7378; 16.5513
90; 114.011; 90
2828.2Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4071669 CIFC32 H44 Hf O2 SiP 1 21/c 110.2069; 17.1456; 17.6053
90; 105.079; 90
2974.9Beweries, Torsten; Burlakov, Vladimir V.; Peitz, Stephan; Arndt, Perdita; Baumann, Wolfgang; Spannenberg, Anke; Rosenthal, Uwe
Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and Carbon Dioxide†
Organometallics, 2008, 27, 3954
4071674 CIFC82 H31 Br Mo O3P 1 21/c 111.697; 19.067; 22.379
90; 96.709; 90
4956.9Matsuo, Yutaka; Iwashita, Akihiko; Nakamura, Eiichi
Group 6 Metal Complexes of the η5-Pentamethyl[60]fullerene
Organometallics, 2008, 27, 4611
4071677 CIFC69.5 H15 I Mo O3 S3P 1 21/c 116.872; 12.726; 20.054
90; 90.298; 90
4305.8Matsuo, Yutaka; Iwashita, Akihiko; Nakamura, Eiichi
Group 6 Metal Complexes of the η5-Pentamethyl[60]fullerene
Organometallics, 2008, 27, 4611
4071678 CIFC66 H16 S2P 1 21/c 19.996; 19.995; 18.673
90; 101; 90
3664Matsuo, Yutaka; Iwashita, Akihiko; Nakamura, Eiichi
Group 6 Metal Complexes of the η5-Pentamethyl[60]fullerene
Organometallics, 2008, 27, 4611
4071683 CIFC19 H19 N2 RhP 1 21/c 110.0544; 11.1105; 12.8356
90; 97.249; 90
1422.4Jiang, Huiling; Song, Datong
Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
Organometallics, 2008, 27, 3587
4071687 CIFC26 H29 N TiP 1 21/c 115.263; 9.5695; 16.15
90; 113.963; 90
2155.5Wu, Chun Ji; Lee, Sang Hoon; Yu, Seung Tack; Na, Sung Jae; Yun, Hoseop; Lee, Bun Yeoul
CO2-Mediatedortho-Lithiation ofN-Alkylanilines and Its Use for the Construction of Polymerization Catalysts
Organometallics, 2008, 27, 3907
4071689 CIFC16 H19 Cl2 N TiP 1 21/c 19.1152; 13.6101; 13.2743
90; 102.881; 90
1605.36Wu, Chun Ji; Lee, Sang Hoon; Yu, Seung Tack; Na, Sung Jae; Yun, Hoseop; Lee, Bun Yeoul
CO2-Mediatedortho-Lithiation ofN-Alkylanilines and Its Use for the Construction of Polymerization Catalysts
Organometallics, 2008, 27, 3907
4071701 CIFC18 H32 Br2 N4 O4 PtP 1 21/c 111.9689; 25.0784; 8.1507
90; 105.143; 90
2361.57Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4071709 CIFC38 H58 F6 Fe2 N2 O6 P4 S2 WP 1 21/c 116.9906; 14.3654; 19.478
90; 105.022; 90
4591.7Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki; Wakiji, Issei; Hidai, Masanobu
Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Organometallics, 2008, 27, 3947
4071713 CIFC22 H28 F3 N3 O5 Pd SP 1 21/c 114.0831; 11.5607; 16.9448
90; 112.467; 90
2549.4Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4071717 CIFC30 H29 Ni3P 1 21/c 112.505; 9.792; 19.219
90; 94.32; 90
2346.7Buchalski, Piotr; Jadach, Patryk; Pietrzykowski, Antoni; Suwińska, Kinga; Jerzykiewicz, Lucjan; Sadło, Jarosław
Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water
Organometallics, 2008, 27, 3618
4071719 CIFC19 H29 N2 VP 1 21/c 113.38; 11.0573; 13.949
90; 116.596; 90
1845.3Bouwkamp, Marco W.; Batinas, Aurora A.; Witte, Peter T.; Hubregtse, Ton; Dam, Jeroen; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Relative Reactivity of the Metal−Amido versus Metal−Imido Bond in Linked Cp-Amido and Half-Sandwich Complexes of Vanadium
Organometallics, 2008, 27, 4071
4071727 CIFC34 H30 Fe O3 P2P 1 21/c 122.552; 10.59; 12.22
90; 95.93; 90
2902.8Bar, Arun Kumar; Chakrabarty, Rajesh; Mukherjee, Partha Sarathi
Unusual Hydrogenation of Fumarate Anion Followed by Metal−Carbon Bond Formation: Synthesis and Characterization of Two Metallochelates
Organometallics, 2008, 27, 3806
4071729 CIFC11 H30 I2 In N Si3P 1 21/c 18.3419; 17.938; 16.57
90; 116.658; 90
2215.92Schachner, Jörg A.; Lund, Clinton L.; Burgess, Ian J.; Quail, J. Wilson; Schatte, Gabriele; Müller, Jens
The Dynamic Indium-Bridged [1.1]Ferrocenophane [(Me2Ntsi)In(C5H4)2Fe]2
Organometallics, 2008, 27, 4703
4071730 CIFC42 H76 Fe2 In2 N2 Si6P 1 21/c 117.1413; 9.5085; 16.7639
90; 112.153; 90
2530.62Schachner, Jörg A.; Lund, Clinton L.; Burgess, Ian J.; Quail, J. Wilson; Schatte, Gabriele; Müller, Jens
The Dynamic Indium-Bridged [1.1]Ferrocenophane [(Me2Ntsi)In(C5H4)2Fe]2
Organometallics, 2008, 27, 4703
4071734 CIFC9 H4 N O5 ReP 1 21/c 15.79; 10.7142; 16.4602
90; 93.551; 90
1019.15Mirebeau, Jean-Hugues; Le Bideau, Franck; Marrot, Jérôme; Jaouen, Gérard
Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands
Organometallics, 2008, 27, 2911
4071735 CIFC27 H21 N O4 P ReP 1 21/c 118.0665; 8.2603; 18.3269
90; 118.733; 90
2398.25Mirebeau, Jean-Hugues; Le Bideau, Franck; Marrot, Jérôme; Jaouen, Gérard
Synthesis of Rhenium Carbonyl Complexes Bearing Substituted Pyrrolyl Ligands
Organometallics, 2008, 27, 2911
4071737 CIFC54 H54 B O P3 S2 UP 1 21/c 113.33; 16.0507; 22.223
90; 97.554; 90
4713.5Arliguie, Thérèse; Blug, Matthias; Le Floch, Pascal; Mézailles, Nicolas; Thuéry, Pierre; Ephritikhine, Michel
Organouranium Complexes with Phosphinine-Based SPS Pincer Ligands. Variations with the Substituent at the Phosphorus Atom
Organometallics, 2008, 27, 4158
4071740 CIFC42 H42 O2 P2 S4 U2P 1 21/c 112.8051; 9.1321; 17.4375
90; 96.989; 90
2023.9Arliguie, Thérèse; Blug, Matthias; Le Floch, Pascal; Mézailles, Nicolas; Thuéry, Pierre; Ephritikhine, Michel
Organouranium Complexes with Phosphinine-Based SPS Pincer Ligands. Variations with the Substituent at the Phosphorus Atom
Organometallics, 2008, 27, 4158
4071747 CIFC31 H50 Ir N O P2P 1 21/c 115.554; 11.303; 18.303
90; 91.557; 90
3216.6Romero, Patricio E.; Whited, Matthew T.; Grubbs, Robert H.
Multiple C−H Activations of Methyltert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1
Organometallics, 2008, 27, 3422
4071751 CIFC54 H53 Cl6 Cr2 N3 O6 P4P 1 21/c 120.8878; 18.7658; 15.4625
90; 110.622; 90
5672.6Teo, Shihui; Weng, Zhiqiang; Hor, T. S. Andy
Unusual Ligand Transformation Mediated by Chromium(III): Hydrolytic Disintegration of a [PNP] Hybrid Ligand with CH3CN Insertion
Organometallics, 2008, 27, 4188
4071764 CIFC31 H38 Mo2 N2 S3P 1 21/c 18.3452; 22.6264; 16.2627
90; 98.299; 90
3038.6Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071767 CIFC50 H55 Br Cl4 Mo2 N4 S2P 1 21/c 115.2743; 18.2217; 19.7904
90; 107.814; 90
5244Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071769 CIFC35 H40 Mo4 O4 S6P 1 21/c 116.083; 10.1516; 13.2453
90; 110.9; 90
2020.3Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071770 CIFC15 H20 Cl2 Mo2 O3 S3P 1 21/c 110.8247; 12.9834; 16.0843
90; 113.652; 90
2070.6Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
C−C, C−S, and C−N Coupling versus Dealkylation Processes in the Cationic Tris(thiolato)dimolybdenum(III) Complexes [Mo2Cp2(μ-SMe)3L2]+(L = xylNC,t-BuNC, CO, MeCN)
Organometallics, 2008, 27, 4207
4071773 CIFC44.5 H36.25 F3 Mo O6.12 SP 1 21/c 110.096; 17.894; 22.843
90; 98.102; 90
4085.6Namorado, Sónia; Antunes, Maria Augusta; Veiros, Luis F.; Ascenso, José R.; Duarte, M. Teresa; Martins, Ana M.
Ionic Hydrogenation of Ketones with Molybdenum Pentabenzylcyclopentadienyl Hydride Catalysts
Organometallics, 2008, 27, 4589-4599
4071774 CIFC44.5 H36.25 F3 O6.12 S WP 1 21/c 110.071; 17.884; 22.796
90; 97.901; 90
4066.8Namorado, Sónia; Antunes, Maria Augusta; Veiros, Luis F.; Ascenso, José R.; Duarte, M. Teresa; Martins, Ana M.
Ionic Hydrogenation of Ketones with Molybdenum Pentabenzylcyclopentadienyl Hydride Catalysts
Organometallics, 2008, 27, 4589-4599
4071777 CIFC31 H41 Br0.18 Cl0.82 O3 P2 Ru SnP 1 21/c 19.6522; 16.4234; 21.222
90; 94.986; 90
3351.4Albertin, Gabriele; Antoniutti, Stefano; Bacchi, Alessia; Pelizzi, Giancarlo; Zanardo, Gianluigi
Synthesis and Reactivity of Trihydridostannyl Complexes of Ruthenium and Osmium
Organometallics, 2008, 27, 4407
4071781 CIFC30 H35 Cl4 O3 P PtP 1 21/c 113.348; 15.743; 15.33
90; 109.57; 90
3035.3Baber, Angharad; Fan, Cheng; Norman, David W.; Orpen, A. Guy; Pringle, Paul G.; Wingad, Richard L.
Oxidative Dehydrogenation of Tris(o-isopropylphenyl)phosphines by Platinum Complexes
Organometallics, 2008, 27, 5906
4071788 CIFC31.25 H39.5 Cl0.5 O7 P Pt Ru2 SnP 1 21/c 116.9915; 11.7343; 19.2385
90; 99.409; 90
3784.23Adams, Richard D.; Trufan, Eszter
Diruthenium−Tin Complexes from the Reaction of Ph2SnH2with Ru(CO)5and Their Reactions with Bis(tri-tert-butylphosphine)platinum
Organometallics, 2008, 27, 4108
4071790 CIFC54 H71 B Os3P 1 21/c 116.8668; 14.1879; 20.5803
90; 103.103; 90
4796.7Kameo, Hajime; Suzuki, Hiroharu
Synthesis of Trinuclear Osmium Polyhydrido Clusters [{(C5Me5)Os}3(μ-H)6]+and {(C5Me5)Os}3(μ-H)3(μ3-H)2and Comparison with the Ruthenium Analogues
Organometallics, 2008, 27, 4248
4071799 CIFC19 H11 Cl N O2 Rh SP 1 21/c 112.494; 11.358; 13.889
90; 116.917; 90
1757.4Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
Organometallics, 2008, 27, 4475
4071806 CIFC33 H36 Fe P2 SiP 1 21/c 112.3242; 12.3981; 19.511
90; 98.403; 90
2949.2Kumar, Mukesh; Cervantes-Lee, Francisco; Pannell, Keith H.; Shao, Jianguo
Synthesis and cyclic voltammetric studies of diiron complexes, ER(2)[(eta-C(5)H(4))Fe(L(2))Me](2) (E = C, Si, Ge, Sn; R = H, alkyl; L(2) = diphosphine] and (eta-C(5)H(5))Fe(L(2))ER(2)Fc [Fc = (eta-C(5)H(4))Fe(eta-C(5)H(5))].
Organometallics, 2008, 27, 4739-4748
4071812 CIFC30 H34 N4 O2 Pt SP 1 21/c 116.9605; 7.6043; 22.6425
90; 92.823; 90
2916.7Moret, Marc-Etienne; Chen, Peter
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands
Organometallics, 2008, 27, 4903
4071815 CIFC36 H37 K N4 PtP 1 21/c 112.5793; 9.2999; 28.4841
90; 92.192; 90
3329.8Moret, Marc-Etienne; Chen, Peter
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands
Organometallics, 2008, 27, 4903
4071818 CIFC78 H86 Cu2 N8 O3 Pt2P 1 21/c 119.7025; 13.3495; 28.314
90; 108.05; 90
7080.6Moret, Marc-Etienne; Chen, Peter
Mononuclear Organometallic Platinum(II) Complexes and Platinum(II)−Copper(I) Mixed Complexes from Symmetrical 3,5-Bis(iminoacetyl)pyrazolate Ligands
Organometallics, 2008, 27, 4903
4071826 CIFC18 H42 Fe O5 P4P 1 21/c 19.2623; 17.5775; 16.578
90; 103.317; 90
2626.5Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.
Reductive Disproportionation of Carbon Dioxide at an Iron(II) Center
Organometallics, 2008, 27, 3328
4071828 CIFC23 H38 Cl5 P RuP 1 21/c 112.757; 15.4559; 13.4577
90; 92.309; 90
2651.31Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071830 CIFC29.4 H51.8 Cl6.3 P Ru2P 1 21/c 117.4584; 18.8627; 10.8896
90; 102.752; 90
3497.63Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071841 CIFC42 H65 Cl3 Li O2 Si2 U2P 1 21/c 115.052; 10.636; 28.982
90; 97.33; 90
4601.9Wang, Jiaxi; Gurevich, Ylia; Botoshansky, Mark; Eisen, Moris S.
Coordinative Unsaturation versus Oxophilicity:ansaDimethylsilyl Oxo-Bridged Uranium Metallocenes. Synthesis, Structures, and Unexpected Catalytic Activity with Alkynes and Silanes
Organometallics, 2008, 27, 4494
4071849 CIFC23 H25 N4 O2 SiP 1 21/c 110.356; 20.348; 11.087
90; 95.56; 90
2325.3Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071855 CIFC16 H26 N2 Si2 ZrP 1 21/c 18.7632; 27.233; 8.4558
90; 110.744; 90
1887.1Wang, Cun; Luo, He-Kuan; van Meurs, Martin; Stubbs, Ludger P.; Wong, Pui-Kwan
The New Tridentate Ligand CpSiNSiCp and Its Zirconium Complexes: Incorporation of Two Bridged Constrained-Geometry Units into One Molecule
Organometallics, 2008, 27, 2908
4071857 CIFC26 H39 B N9 O4 P WP 1 21/c 111.045; 13.584; 20.498
90; 98.111; 90
3044.7Kosturko, George W.; Graham, Peter M.; Myers, William H.; Smith, Timothy M.; Sabat, Michal; Harman, W. Dean
Tungsten-Promoted Diels−Alder Cycloaddition of Pyridines: Dearomatization of 2,6-Dimethoxypyridine Generates a Potent 2-Azadiene Synthon
Organometallics, 2008, 27, 4513
4071864 CIFC48 H62 Ge3 P4 Pd2P 1 21/c 116.2875; 16.1779; 18.868
90; 93.8134; 90
4960.7Tanabe, Makoto; Ishikawa, Naoko; Hanzawa, Masaya; Osakada, Kohtaro
Mono- and Dinuclear Germapalladacycles Obtained via the Ge−Ge Bond Forming Reactions Promoted by Palladium Complexes
Organometallics, 2008, 27, 5152
4071879 CIFC35 H49 B N2 O SiP 1 21/c 118.704; 17.323; 21.582
90; 94.347; 90
6972.65Kawachi, Atsushi; Zaima, Masatoshi; Yamamoto, Yohsuke
Intramolecular Reaction of Silanol and Triarylborane: Boron−Aryl Bond Cleavage and Formation of a Si−O−B Heterocyle
Organometallics, 2008, 27, 4691
4071881 CIFC35 H34 Fe2 N2 O4P 1 21/c 113.849; 13.765; 17.266
90; 112.71; 90
3036.3Busetto, Luigi; Marchetti, Fabio; Zacchini, Stefano; Zanotti, Valerio
Addition of Isocyanides at Diiron μ-Vinyliminium Complexes: Synthesis of Novel Ketenimine−Bis(alkylidene) Complexes
Organometallics, 2008, 27, 5058
4071883 CIFC29 H37 Fe2 N3 O4P 1 21/c 112.595; 16.987; 15.355
90; 112.73; 90
3030.1Busetto, Luigi; Marchetti, Fabio; Zacchini, Stefano; Zanotti, Valerio
Addition of Isocyanides at Diiron μ-Vinyliminium Complexes: Synthesis of Novel Ketenimine−Bis(alkylidene) Complexes
Organometallics, 2008, 27, 5058
4071885 CIFC34 H34 Fe2 N2 O2P 1 21/c 115.125; 12.884; 15.943
90; 106.24; 90
2982.9Busetto, Luigi; Marchetti, Fabio; Zacchini, Stefano; Zanotti, Valerio
Addition of Isocyanides at Diiron μ-Vinyliminium Complexes: Synthesis of Novel Ketenimine−Bis(alkylidene) Complexes
Organometallics, 2008, 27, 5058
4071886 CIFC58 H52 Cl5 P2 PdP 1 21/c 125.4012; 10.4782; 19.8507
90; 91.37; 90
5281.9Kaganovsky, Luba; Cho, Kyung-Bin; Gelman, Dmitri
New Trans-Chelating Ligands and Their Complexes and Catalytic Properties in the Mizoroki−Heck Arylation of Cyclohexene
Organometallics, 2008, 27, 5139
4071890 CIFC18 H35 B9 N2 ZrP 1 21/c 114.14; 10.683; 16.648
90; 111.59; 90
2338.4Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4071901 CIFC22 H34 Cl2 O2 Os2P 1 21/c 19.072; 16.049; 8.2477
90; 102.549; 90
1172.1Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4071902 CIFC20 H28 O8 OsP 1 21/c 112.114; 12.583; 14.151
90; 100.732; 90
2119.3Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4071905 CIFC51 H42 Cl4 P2 Pt SP 1 21/c 112.731; 10.829; 33.907
90; 92.26; 90
4670.9Kuniyasu, Hitoshi; Takekawa, Kazunobu; Yamashita, Fumikazu; Miyafuji, Kiyoshi; Asano, Shigehito; Takai, Yasutomo; Ohtaka, Atsushi; Tanaka, Aoi; Sugoh, Kunihiko; Kurosawa, Hideo; Kambe, Nobuaki
Insertion of Alkynes into an ArS−Pt Bond: Regio- and Stereoselective Thermal Reactions, Facilitation by “o-Halogen Effect” and Photoirradiation, Different Alkyne Preferences Depending on the Ancillary Ligand, and Application to a Catalytic Reaction
Organometallics, 2008, 27, 4788
4071914 CIFC42 H46 I2 N4 O Rh2P 1 21/c 112.8891; 14.6531; 22.462
90; 104.806; 90
4101.4Lowry, Roxy J.; Veige, Melanie K.; Clément, Olivier; Abboud, Khalil A.; Ghiviriga, Ion; Veige, Adam S.
New Constrained-Geometry C2-Symmetric Di-N-heterocyclic Carbene Ligands and Their Mono- and Dinuclear Rhodium(I) Complexes: Design, Synthesis, and Structural Analysis
Organometallics, 2008, 27, 5184-5195
4071916 CIFC41 H40 Cl2 I N4 RhP 1 21/c 110.7075; 30.42; 12.1504
90; 112.696; 90
3651.2Lowry, Roxy J.; Veige, Melanie K.; Clément, Olivier; Abboud, Khalil A.; Ghiviriga, Ion; Veige, Adam S.
New Constrained-Geometry C2-Symmetric Di-N-heterocyclic Carbene Ligands and Their Mono- and Dinuclear Rhodium(I) Complexes: Design, Synthesis, and Structural Analysis
Organometallics, 2008, 27, 5184-5195
4071921 CIFC24 H26 CrP 1 21/c 115.256; 9.663; 19.712
90; 96.277; 90
2888.5Meredith, M. Brett; Crisp, Jeffrey A.; Brady, Erik D.; Hanusa, Timothy P.; Yee, Gordon T.; Pink, Maren; Brennessel, William W.; Young, Victor G.
Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution
Organometallics, 2008, 27, 5464
4071922 CIFC24 H26 CrP 1 21/c 115.492; 9.721; 19.969
90; 96.296; 90
2989.1Meredith, M. Brett; Crisp, Jeffrey A.; Brady, Erik D.; Hanusa, Timothy P.; Yee, Gordon T.; Pink, Maren; Brennessel, William W.; Young, Victor G.
Tunable Spin-Crossover Behavior in Polymethylated Bis(indenyl)chromium(II) Complexes: The Significance of Benzo-Ring Substitution
Organometallics, 2008, 27, 5464
4071924 CIFC47 H50 B N8 O P RuP 1 21/c 19.7128; 22.7762; 19.922
90; 94.397; 90
4394.2Leung, Chung Wing; Zheng, Wenxu; Zhou, Zhongyuan; Lin, Zhenyang; Lau, Chak Po
Mechanism of Catalytic Hydration of Nitriles with Hydrotris(pyrazolyl)borato (Tp) Ruthenium Complexes
Organometallics, 2008, 27, 4957
4071926 CIFC48 H74 B2 Mo2 N14 O5P 1 21/c 18.053; 17.1793; 19.9944
90; 101.063; 90
2714.72Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Reactions of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes
Organometallics, 2008, 27, 4532
4071930 CIFC24 H39 B Mo N8 O3P 1 21/c 19.952; 16.9385; 15.9761
90; 92.829; 90
2689.84Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Reactions of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes
Organometallics, 2008, 27, 4532
4071936 CIFC36 H20 F8 P2 PdP 1 21/c 19.997; 12.2158; 12.7955
90; 105.055; 90
1508.97Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4071937 CIFC36 H20 F8 P2 PtP 1 21/c 110.0072; 12.2049; 12.7603
90; 104.943; 90
1505.8Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4071940 CIFC36 H20 F8 Ni P2P 1 21/c 112.471; 12.3859; 20.0281
90; 97.9282; 90
3064.06Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4071945 CIFC85 H127 Mg2 O8 S2P 1 21/c 115.5879; 19.53; 28.96
90; 102.972; 90
8591.3Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970
4071947 CIFC92 H128 Cl2 Mg2 O8 S2P 1 21/c 123.1133; 22.8161; 19.1247
90; 109.399; 90
9512.9Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970
4071958 CIFC23 H24 HfP 1 21/c 19.3987; 10.7366; 18.2206
90; 102.011; 90
1798.4Alonso-Moreno, Carlos; Lancaster, Simon J.; Wright, Joseph A.; Hughes, David L.; Zuccaccia, Cristiano; Correa, Andrea; Macchioni, Alceo; Cavallo, Luigi; Bochmann, Manfred
Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)
Organometallics, 2008, 27, 5474
4071959 CIFC22 H21 Cl ZrP 1 21/c 19.2398; 10.7676; 18.156
90; 102.353; 90
1764.5Alonso-Moreno, Carlos; Lancaster, Simon J.; Wright, Joseph A.; Hughes, David L.; Zuccaccia, Cristiano; Correa, Andrea; Macchioni, Alceo; Cavallo, Luigi; Bochmann, Manfred
Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)
Organometallics, 2008, 27, 5474
4071964 CIFC76 H76 Cl4 F12 N4 O20 Rh4 S4P 1 21/c 116.385; 18.966; 16.274
90; 92.407; 90
5053Han, Ying-Feng; Jia, Wei-Guo; Lin, Yue-Jian; Jin, Guo-Xin
Stepwise Formation of Molecular Rectangles of Half-Sandwich Rhodium and Ruthenium Complexes Containing Bridging Chloranilate Ligands
Organometallics, 2008, 27, 5002
4071966 CIFC80 H76 Cl4 F12 N4 O20 Ru4 S4P 1 21/c 119.72; 14.441; 20.72
90; 115.138; 90
5342Han, Ying-Feng; Jia, Wei-Guo; Lin, Yue-Jian; Jin, Guo-Xin
Stepwise Formation of Molecular Rectangles of Half-Sandwich Rhodium and Ruthenium Complexes Containing Bridging Chloranilate Ligands
Organometallics, 2008, 27, 5002
4071973 CIFC78 H88 B Cl N6 O P2 RuP 1 21/c 119.9209; 13.9488; 25.4091
90; 92.96; 90
7051.1Dabb, Serin L.; Messerle, Barbara A.; Wagler, Jörg
Formation of Metallacyclobutene Complexes via the Addition of Hydrazines to Ruthenium Vinylidene Complexes
Organometallics, 2008, 27, 4657
4071978 CIFC20 H29 Br O TiP 1 21/c 114.5885; 8.0976; 17.6573
90; 105.287; 90
2012.1Manz, Thomas A.; Sharma, Shalini; Phomphrai, Khamphee; Novstrup, Krista A.; Fenwick, Andrew E.; Fanwick, Phillip E.; Medvedev, Grigori A.; Abu-Omar, Mahdi M.; Delgass, W. Nicholas; Thomson, Kendall T.; Caruthers, James M.
Quantitative Effects of Ion Pairing and Sterics on Chain Propagation Kinetics for 1-Hexene Polymerization Catalyzed by Mixed Cp′/ArO Complexes
Organometallics, 2008, 27, 5504
4071979 CIFC41 H34 O TiP 1 21/c 111.056; 21.2786; 13.3141
90; 99.77; 90
3086.8Manz, Thomas A.; Sharma, Shalini; Phomphrai, Khamphee; Novstrup, Krista A.; Fenwick, Andrew E.; Fanwick, Phillip E.; Medvedev, Grigori A.; Abu-Omar, Mahdi M.; Delgass, W. Nicholas; Thomson, Kendall T.; Caruthers, James M.
Quantitative Effects of Ion Pairing and Sterics on Chain Propagation Kinetics for 1-Hexene Polymerization Catalyzed by Mixed Cp′/ArO Complexes
Organometallics, 2008, 27, 5504
4071982 CIFC70 H50 BaP 1 21/c 113.0103; 13.7274; 17.9609
90; 128.559; 90
2508.37Deacon, Glen B.; Forsyth, Craig M.; Jaroschik, Florian; Junk, Peter C.; Kay, Danielle L.; Maschmeyer, Thomas; Masters, Anthony F.; Wang, Jun; Field, Leslie D.
Accessing Decaphenylmetallocenes of Ytterbium, Calcium, and Barium by Desolvation of Solvent-Separated Ion Pairs: Overcoming Adverse Solubility Properties#
Organometallics, 2008, 27, 4772
4071985 CIFC40 H56 B4 N8P 1 21/c 111.585; 11.753; 14.228
90; 92.957; 90
1934.7Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071990 CIFC14 H28 B2 N4P 1 21/c 16.7166; 12.7645; 9.7065
90; 93.278; 90
830.82Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071996 CIFC20 H12 B2 Br2P 1 21/c 13.9318; 19.055; 10.609
90; 92.275; 90
794.2Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4071997 CIFC22 H18 B2P 1 21/c 13.9678; 10.318; 19.103
90; 91.268; 90
781.9Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4071998 CIFC22 H23 Al OP 1 21/c 19.5777; 12.781; 16.0315
90; 105.089; 90
1894.8Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4071999 CIFC22 H25 Al OP 1 21/c 112.126; 7.552; 21.1946
90; 100.231; 90
1910.05Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4072004 CIFC31 H56 O P2 RuP 1 21/c 114.1991; 13.1151; 16.3774
90; 95.543; 90
3035.58Bolton, Paul D.; Grellier, Mary; Vautravers, Nicolas; Vendier, Laure; Sabo-Etienne, Sylviane
Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols
Organometallics, 2008, 27, 5088
4072005 CIFC31 H54 O P2 RuP 1 21/c 115.835; 8.3164; 22.417
90; 98.27; 90
2921.4Bolton, Paul D.; Grellier, Mary; Vautravers, Nicolas; Vendier, Laure; Sabo-Etienne, Sylviane
Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols
Organometallics, 2008, 27, 5088
4072007 CIFC32 H56 O2 P2 RuP 1 21/c 19.682; 32.692; 9.7121
90; 93.996; 90
3066.6Bolton, Paul D.; Grellier, Mary; Vautravers, Nicolas; Vendier, Laure; Sabo-Etienne, Sylviane
Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols
Organometallics, 2008, 27, 5088
4072011 CIFC20 H19 I Pd S2P 1 21/c 112.8519; 13.564; 11.3059
90; 102.352; 90
1925.3Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4072013 CIFC37 H33 I O Pd S2P 1 21/c 110.3572; 15.159; 20.956
90; 101.254; 90
3226.9Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4072017 CIFC23 H26 Cl2 N2 O Pt SiP 1 21/c 112.6224; 9.555; 20.1223
90; 91.486; 90
2426.07West, Nathan M.; White, Peter S.; Templeton, Joseph L.
Alkyne Insertion into the Pt−H Bond of Pt(H)(1-pentene)(β-diiminate) Initiates a Reaction Cascade That Results in C−H Activation or C−C Coupling
Organometallics, 2008, 27, 5252
4072036 CIFC47.33 H69.66 B2 Cl0.66 F8 N3 Os P2P 1 21/c 121.522; 14.461; 19.434
90; 116.31; 90
5421.9Bolaño, Tamara; Castarlenas, Ricardo; Esteruelas, Miguel A.; Oñate, Enrique
Formation of an Asymmetric Acyclic Osmium−Dienylcarbene Complex
Organometallics, 2008, 27, 6367
4072037 CIFC30 H42 Fe2 O Si4P 1 21/c 18.52; 18.126; 10.723
90; 107.28; 90
1581.2Kumar, Mukesh; Metta-Magana, Alejandro J.; Pannell, Keith H.
Ferrocenylene- and Carbosiloxane-Bridged Bis(sila[1]ferrocenophanes) E[SiMe2-X-SiMeFC]2{E = (η5-C5H4)Fe(η5-C5H4) or O; X = (CH2)n(n= 2, 3, 6); CHCH;FC= (η5-C5H4)2Fe}
Organometallics, 2008, 27, 6457
4072045 CIFC18 H40 Ni P2P 1 21/c 114.2542; 13.7514; 10.5561
90; 95.091; 90
2060.99Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072062 CIFC38 H48 Fe N3 OP 1 21/c 18.3464; 18.493; 21.547
90; 92.38; 90
3322.9Trovitch, Ryan J.; Lobkovsky, Emil; Bouwkamp, Marco W.; Chirik, Paul J.
Carbon−Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C−O Bond Cleavage in Esters
Organometallics, 2008, 27, 6264
4072065 CIFC41 H78 Al3 Cr N4 P2P 1 21/c 118.9199; 14.762; 18.1352
90; 102.767; 90
4939.9Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Duchateau, Robbert; Koç, Ece; Burchell, Tara J.
Preparation and Characterization of a Switchable Single-Component Chromium Trimerization Catalyst
Organometallics, 2008, 27, 5708
4072072 CIFC22 H42 Cl O2 P PdP 1 21/c 116.081; 8.681; 17.306
90; 99.208; 90
2384.8Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072076 CIFC25 H34 Cl O P2 Rh Si2P 1 21/c 16.914; 6.698; 28.42
90; 95.71; 90
1309.6Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4072079 CIFC40 H58 N3 O Si2 YP 1 21/c 111.2166; 20.184; 20.545
90; 64.61; 90
4202Gao, Wei; Cui, Dongmei; Liu, Xiaoming; Zhang, Yu; Mu, Ying
Rare-Earth Metal Bis(alkyl)s Supported by a Quinolinyl Anilido-Imine Ligand: Synthesis and Catalysis on Living Polymerization of ε-Caprolactone
Organometallics, 2008, 27, 5889
4072095 CIFC38.5 H33 Cl2 N Ni P2P 1 21/c 114.647; 17.098; 15.666
90; 115.807; 90
3532Sun, Kai; Wang, Li; Wang, Zhong-Xia
Synthesis and Characterization of Amido Pincer Complexes of Lithium and Nickel and Catalysis of the Nickel Complexes in the Kumada Cross-Coupling
Organometallics, 2008, 27, 5649
4072096 CIFC52 H47 Cl N2 Ni P2P 1 21/c 115.2015; 18.635; 16.855
90; 113.301; 90
4385.3Sun, Kai; Wang, Li; Wang, Zhong-Xia
Synthesis and Characterization of Amido Pincer Complexes of Lithium and Nickel and Catalysis of the Nickel Complexes in the Kumada Cross-Coupling
Organometallics, 2008, 27, 5649
4072102 CIFC25 H24 O4P 1 21/c 114.7813; 7.3153; 17.9908
90; 93.613; 90
1941.47Yeh, Ming-Chang P.; Tsao, Wen-Cheng; Lee, Bo-Jen; Lin, Tzu-Ling
Facile Synthesis of Carbotetracycles via Gold(I)-Catalyzed Cyclization of Unactivated Cyclic 1-Aryl-6,8-dien-1-ynes
Organometallics, 2008, 27, 5326
4072109 CIFC24 H38 Si4P 1 21/c 115.9413; 10.0293; 17.9553
90; 115.261; 90
2596.2Lim, Young Mook; Lee, Myong Euy; Lee, Junseong; Do, Youngkyu
Reactivity of Bromodilithiosilane to Naphthalene and Anthracene
Organometallics, 2008, 27, 6375
4072120 CIFC28 H18 Au2 Fe N2P 1 21/c 19.0781; 24.9236; 13.4933
90; 128.191; 90
2399.5Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4072139 CIFC34 H26 N2 O6 Pd2P 1 21/c 115.0024; 23.9112; 19.8972
90; 104.317; 90
6915.95Chu, Jean-Ho; Chen, Chin-Chau; Wu, Ming-Jung
Palladium-Catalyzed Arylation and Alkylation of 3,5-Diphenylisoxazole with Boronic Acids via C−H Activation
Organometallics, 2008, 27, 5173
4072146 CIFC81 H88 Cl4 N10 O4 P2 Ru2P 1 21/c 118.0582; 22.6925; 18.8519
90; 92.771; 90
7716.2Kopf, Henning; Holzberger, Bastian; Pietraszuk, Cezary; Hübner, Eike; Burzlaff, Nicolai
Neutral Ruthenium Carbene Complexes bearing N,N,O Heteroscorpionate Ligands: Syntheses and Activity in Metathesis Reactions
Organometallics, 2008, 27, 5894
4072147 CIFC34.5 H49 Cl4 N4 O2 P RuP 1 21/c 115.35; 10.613; 25.671
90; 98.78; 90
4133Kopf, Henning; Holzberger, Bastian; Pietraszuk, Cezary; Hübner, Eike; Burzlaff, Nicolai
Neutral Ruthenium Carbene Complexes bearing N,N,O Heteroscorpionate Ligands: Syntheses and Activity in Metathesis Reactions
Organometallics, 2008, 27, 5894
4072161 CIFC24 H46 N6 O8 Rh2P 1 21/c 118.983; 18.6893; 8.7736
90; 95.933; 90
3096Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072162 CIFC32 H52 N8 O4 Rh2P 1 21/c 19.371; 15.8919; 23.994
90; 97.408; 90
3543.4Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072172 CIFC54 H96 B20 Cl4 Gd2 K2 O8P 1 21/c 115.9672; 10.634; 22.436
90; 103.323; 90
3707Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Constrained-Geometry Organolanthanide Chlorides and Alkyls Incorporating the Ligand [η5:σ-(C9H6)C2B10H10]2−
Organometallics, 2008, 27, 5309
4072173 CIFC28 H46 B10 N O3 YP 1 21/c 116.4219; 17.2152; 28.682
90; 120.51; 90
6985.9Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Constrained-Geometry Organolanthanide Chlorides and Alkyls Incorporating the Ligand [η5:σ-(C9H6)C2B10H10]2−
Organometallics, 2008, 27, 5309
4072179 CIFC33 H46 F12 Mo N2 O2P 1 21/c 117.949; 10.2839; 20.216
90; 102.473; 90
3643.5Lokare, Kapil S.; Staples, Richard J.; Odom, Aaron L.
Synthesis, Properties, and Structure of Tethered Molybdenum Alkylidenes
Organometallics, 2008, 27, 5130
4072190 CIFC34 H40 O2 P2P 1 21/c 110.9457; 12.8989; 11.2301
90; 104.899; 90
1532.2Long, Richard J.; Jones, David J.; Gibson, Vernon C.; White, Andrew J. P.
Zirconium Complexes Containing Tetradentate O,P,P,O Ligands: Ethylene and Propylene Polymerization Studies
Organometallics, 2008, 27, 5960
4072191 CIFC34 H38 Cl2 O2 P2 ZrP 1 21/c 18.3957; 17.8816; 23.1612
90; 99; 90
3434.35Long, Richard J.; Jones, David J.; Gibson, Vernon C.; White, Andrew J. P.
Zirconium Complexes Containing Tetradentate O,P,P,O Ligands: Ethylene and Propylene Polymerization Studies
Organometallics, 2008, 27, 5960
4072201 CIFC32 H35 Cl Hf SiP 1 21/c 117.2434; 10.037; 17.8692
90; 116.194; 90
2775.06Bryliakov, Konstantin P.; Talsi, Evgenii P.; Voskoboynikov, Alexander Z.; Lancaster, Simon J.; Bochmann, Manfred
Formation and Structures of Hafnocene Complexes in MAO- and AlBui3/CPh3[B(C6F5)4]-Activated Systems
Organometallics, 2008, 27, 6333
4072205 CIFC16 H19 Cl N2 O2 PdP 1 21/c 116.019; 9.903; 21.732
90; 105.974; 90
3314Kimura, Tsutomu; Uozumi, Yasuhiro
Synthesis of [2,6-Bis(2-oxazolinyl)phenyl]palladium Complexes via the Ligand Introduction Route
Organometallics, 2008, 27, 5159
4072222 CIFC42 H74 B Br2 Cl6 P2 PtP 1 21/c 112.7827; 24.4857; 16.2173
90; 90.412; 90
5075.8Braunschweig, Holger; Radacki, Krzysztof; Uttinger, Katharina
Syntheses and Structures of Mono- and Dinuclear Cationic Base-Stabilized Platinum Borylene Complexes
Organometallics, 2008, 27, 6005
4072225 CIFC34 H39 TiP 1 21/c 110.0271; 13.3244; 20.5151
90; 95.788; 90
2726.95Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072229 CIFC30 H47 Si2 TiP 1 21/c 113.781; 12.388; 18.374
90; 105.566; 90
3021.74Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072233 CIFC34 H53 Si TiP 1 21/c 129.3847; 11.9628; 18.7935
90; 108.441; 90
6267.11Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072240 CIFC25 H26 Cl F3 N O7 S TaP 1 21/c 18.9762; 14.6889; 20.673
90; 91.598; 90
2724.7Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodríguez, Ana
Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
Organometallics, 2008, 27, 6090
4072243 CIFC36 H56 Cl8 Ir2 N4 O8P 1 21/c 112.514; 11.847; 17.498
90; 108.541; 90
2459.5Jia, Wei-Guo; Han, Ying-Feng; Jin, Guo-Xin
Synthesis and Characterization of Binuclear Half-Sandwich Iridium and Rhodium Carbene Complexes Containing 1,2-Dichalcogenolato Carborane or Carbonato Ligands
Organometallics, 2008, 27, 6035
4072246 CIFC27 H22 N8 O RuP 1 21/c 19.0095; 16.9233; 16.3307
90; 100.047; 90
2451.8Singh, Amardeep; Pramanik, Avijit; Das, Gopal; Mondal, Biplab
Reduction of Coordinated Acetonitrile to Ethylamine in a Ruthenium Complex byp-Phenylenediamine or Hydroquinone
Organometallics, 2008, 27, 6403
4072260 CIFC23 H22 F12 N8 Ni2 O P2P 1 21/c 115.508; 7.7234; 32.033
90; 114.543; 90
3490.1Zhou, Yongbo; Xi, Zhenxing; Chen, Wanzhi; Wang, Daqi
Dinickel(II) Complexes of Bis(N-heterocyclic carbene) Ligands Containing [Ni2(μ-OH)] Cores as Highly Efficient Catalysts for the Coupling of Aryl Chlorides
Organometallics, 2008, 27, 5911
4072262 CIFC23 H32 P2 Si VP 1 21/c 110.1297; 8.8751; 26.927
90; 100.262; 90
2382.1Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4072268 CIFC20 H33 Cl2 Ir TiP 1 21/c 110.546; 14.0282; 15.4839
90; 106.382; 90
2197.71Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4072269 CIFC20 H33 Cl2 Ir ZrP 1 21/c 110.7052; 14.1183; 15.6994
90; 105.764; 90
2283.55Oishi, Masataka; Kato, Takeshi; Nakagawa, Mayuko; Suzuki, Hiroharu
Synthesis and Reactivity of Early−Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon−Hydrogen Bond Activation
Organometallics, 2008, 27, 6046
4072273 CIFC25 H34 Co N3P 1 21/c 112.706; 11.551; 15.914
90; 98.78; 90
2308.3Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072276 CIFC26 H35 N3P 1 21/c 19.247; 20.691; 12.481
90; 94.74; 90
2379.8Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072278 CIFC24 H31 Cl2 Co N3P 1 21/c 117.433; 9.802; 15.579
90; 115.26; 90
2407.6Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072279 CIFC25 H33 Cl2 Co N3P 1 21/c 117.509; 9.837; 15.598
90; 114.4; 90
2446.6Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072282 CIFC25 H33 Cl2 Fe N3P 1 21/c 117.316; 9.809; 15.391
90; 114.315; 90
2382.3Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072285 CIFC25 H33 Cl2 N3 RuP 1 21/c 115.651; 10.898; 30.092
90; 91.9; 90
5129.8Wallenhorst, Carolin; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Unsymmetrical Bis(iminoethyl)pyridine Metal Complexes with a Pendant Alkenyl Substituent. Part B: Internal Olefin Coordination to Ruthenium†
Organometallics, 2008, 27, 6557
4072288 CIFC29 H44 Cl2 N3 P RuP 1 21/c 115.031; 10.724; 19.3
90; 101.05; 90
3053.3Wallenhorst, Carolin; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Unsymmetrical Bis(iminoethyl)pyridine Metal Complexes with a Pendant Alkenyl Substituent. Part B: Internal Olefin Coordination to Ruthenium†
Organometallics, 2008, 27, 6557
4072289 CIFC30 H46 Cl2 N3 P RuP 1 21/c 115.6678; 10.4923; 19.886
90; 102.581; 90
3190.59Wallenhorst, Carolin; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Unsymmetrical Bis(iminoethyl)pyridine Metal Complexes with a Pendant Alkenyl Substituent. Part B: Internal Olefin Coordination to Ruthenium†
Organometallics, 2008, 27, 6557
4072292 CIFC23 H35 B Mo N6 O3 SeP 1 21/c 18.0591; 18.4282; 18.6374
90; 99.198; 90
2732.34Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Facile Generation of Lithiocarbyne Complexes: [M(CLi)(CO)2{HB(pzMe2)3}] (M = Mo, W; pz = Pyrazol-1-yl)
Organometallics, 2008, 27, 5177
4072294 CIFC12 H14 Cl F3 N2 O2 Ru SP 1 21/c 111.781; 9.656; 14.3
90; 105.102; 90
1571Ito, Masato; Endo, Yoshinori; Ikariya, Takao
Well-Defined Triflylamide-Tethered Arene−Ru(Tsdpen) Complexes for Catalytic Asymmetric Hydrogenation of Ketones
Organometallics, 2008, 27, 6053
4072297 CIFC52 H77 Ca N4 OP 1 21/c 111.7318; 18.3367; 23.4138
90; 94.186; 90
5023.4Barrett, Anthony G. M.; Crimmin, Mark R.; Hill, Michael S.; Hitchcock, Peter B.; Lomas, Sarah L.; Mahon, Mary F.; Procopiou, Panayiotis A.; Suntharalingam, Kogularamanan
β-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon−Carbon Bond Formation
Organometallics, 2008, 27, 6300
4072307 CIFC25 H43 Cl2 P Ru2 SP 1 21/c 117.0596; 8.9122; 18.6207
90; 93.9558; 90
2824.32Miyake, Yoshihiro; Endo, Satoshi; Yuki, Masahiro; Tanabe, Yoshiaki; Nishibayashi, Yoshiaki
Synthesis and Reactivity of Hybrid Phosphido- and Thiolato-Bridged Diruthenium Complexes
Organometallics, 2008, 27, 6039
4072313 CIFC24 H29 F6 I Ir N2 SbP 1 21/c 114.5088; 12.9346; 14.1699
90; 99.892; 90
2619.67Song, Guoyong; Zhang, Yao; Su, Yan; Deng, Weiqiao; Han, Keli; Li, Xingwei
Pyridine-Based N-Heterocyclic Carbene Hydride Complexes of Iridium via C−H Activation
Organometallics, 2008, 27, 6193
4072315 CIFC39 H49 Cl2 N5 TiP 1 21/c 122.2899; 17.6264; 19.8028
90; 91.9807; 90
7775.69Selby, Jonathan D.; Manley, Catherine D.; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study
Organometallics, 2008, 27, 6479
4072318 CIFC30 H48 N6 Si2 TiP 1 21/c 111.5182; 14.5639; 20.0751
90; 100.681; 90
3309.25Selby, Jonathan D.; Manley, Catherine D.; Schwarz, Andrew D.; Clot, Eric; Mountford, Philip
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study
Organometallics, 2008, 27, 6479
4072333 CIFC23 H24 F3 N3 O4 Ru SP 1 21/c 112.819; 12.076; 15.823
90; 105.74; 90
2357.6Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4072336 CIFC25 H27 F6 N6 O Os PP 1 21/c 117.261; 10.044; 16.238
90; 103.9; 90
2732.7Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4072340 CIFC104 H52 B2 F42 Zr2P 1 21/c 113.045; 12.697; 26.825
90; 91.183; 90
4442.1Wilson, Polly A.; Wright, Joseph A.; Oganesyan, Vasily S.; Lancaster, Simon J.; Bochmann, Manfred
Structural Characterization of a Cationic Zirconocene Dimethylaniline Complex and Related Catalytically Relevant Species
Organometallics, 2008, 27, 6371
4072342 CIFC64 H48 B F15 Zr2P 1 21/c 117.885; 13.8749; 21.482
90; 98.682; 90
5269.7Wilson, Polly A.; Wright, Joseph A.; Oganesyan, Vasily S.; Lancaster, Simon J.; Bochmann, Manfred
Structural Characterization of a Cationic Zirconocene Dimethylaniline Complex and Related Catalytically Relevant Species
Organometallics, 2008, 27, 6371
4072348 CIFC16 H44 Li2 N4 ZnP 1 21/c 113.205; 14.9516; 12.0045
90; 94.142; 90
2363.93Armstrong, David R.; Dougan, Christine; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Synthesis and Structural Elucidation of Alkyl, Amido, and Mixed Alkyl−Amido “Highly-Coordinated” Zincates
Organometallics, 2008, 27, 6063
4072354 CIFC26 H18 N2 O4 SiP 1 21/c 19.6245; 14.0115; 16.1647
90; 100.99; 90
2139.89Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072357 CIFC13 H15 N3 O2 SiP 1 21/c 17.2892; 9.8847; 18.3983
90; 98.578; 90
1310.8Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072359 CIFC15 H21 N3 O2 SiP 1 21/c 112.0673; 12.6067; 10.8886
90; 90.118; 90
1656.47Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072360 CIFC11 H11 N3 O2P 1 21/c 112.2364; 13.4662; 6.1023
90; 97.017; 90
997.99Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072362 CIFC26 H27.5 N6 Ni O3.75P 1 21/c 19.4184; 14.4888; 18.2332
90; 93.932; 90
2482.27Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072369 CIFC22 H17 B2 F4 FeP 1 21/c 19.7741; 7.6859; 25.183
90; 92.787; 90
1889.6Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4072372 CIFC13 H11 B OP 1 21/c 15.4887; 15.0318; 25.0114
90; 90.253; 90
2063.5Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4072373 CIFC18 H13 BP 1 21/c 120.523; 17.4242; 7.418
90; 95.576; 90
2640.1Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4072389 CIFC63 H58 B4 Cl2 N12P 1 21/c 110.4817; 30.2472; 16.7978
90; 98.561; 90
5266.3Cade, Ian A.; Hill, Anthony F.; Wagler, Jörg
Diels−Alder Dimerization of a Boracyclohexadiene
Organometallics, 2008, 27, 4844
4072399 CIFC22 H66 Si11P 1 21/c 117.892; 18.938; 25.108
90; 94.27; 90
8484Zirngast, Michaela; Baumgartner, Judith; Marschner, Christoph
Synthesis of Cyclic and Bicyclic Polysilanes of Variable Ring Sizes
Organometallics, 2008, 27, 6472
4072401 CIFC24 H72 Si12P 1 21/c 122.842; 16.013; 26.748
90; 109.36; 90
9230Zirngast, Michaela; Baumgartner, Judith; Marschner, Christoph
Synthesis of Cyclic and Bicyclic Polysilanes of Variable Ring Sizes
Organometallics, 2008, 27, 6472
4072413 CIFC13 H14 Br NP 1 21/c 110.7872; 9.4647; 12.7521
90; 110.547; 90
1219.13Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4072424 CIFC32 H56 Ir N3 P2P 1 21/c 117.0501; 22.666; 17.7204
90; 96.727; 90
6801Whited, Matthew T.; Grubbs, Robert H.
Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes
Organometallics, 2008, 27, 5737
4072428 CIFC45 H50 Cl2 Ir2 O5P 1 21/c 111.7231; 18.1973; 19.5353
90; 100.494; 90
4097.7Panichakul, Duanghathai; Su, Yan; Li, Yongxin; Deng, Weiqiao; Zhao, Jing; Li, Xingwei
A Rare η3Binding Mode of Aryloxides in Iridium, Rhodium, and Ruthenium Complexes
Organometallics, 2008, 27, 6390
4072432 CIFC41 H56 Br2 N4 Ni2P 1 21/c 117.3023; 23.345; 23.2655
90; 96.098; 90
9344.3Hahn, F. Ekkehardt; Radloff, Christian; Pape, Tania; Hepp, Alexander
A Nickel(II)-Cornered Molecular Rectangle with Biscarbene and 4,4′-Bipyridine Bridging Groups
Organometallics, 2008, 27, 6408
4083497 CIFC44 H100 Li2 O2 Si6P 1 21/c 115.048; 16.03; 23.183
90; 94.838; 90
5572.3Inoue, Shigeyoshi; Ichinohe, Masaaki; Sekiguchi, Akira
Isolable Alkali-Metal-Substituted Silyl Radicals (tBu2MeSi)2SiM (M = Li, Na, K): Electronically and Sterically Accessible Planar Silyl Radicals
Organometallics, 2008, 27, 1358
4083499 CIFC28 H34 Cl8 Ir2 O4P 1 21/c 111.189; 20.083; 8.224
90; 107.958; 90
1758Han, Ying-Feng; Lin, Yue-Jian; Jia, Wei-Guo; Jin, Guo-Xin
Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†
Organometallics, 2008, 27, 4088
4083506 CIFC26 H33 Cl2 N3 Ni O4P 1 21/c 19.984; 12.774; 22.118
90; 95.56; 90
2807.6Gao, Rong; Zhang, Min; Liang, Tongling; Wang, Fosong; Sun, Wen-Hua
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization
Organometallics, 2008, 27, 5641
4083508 CIFC21 H17 Br4 N3 Ni O2P 1 21/c 111.11; 15.427; 15.714
90; 121.36; 90
2299.8Gao, Rong; Zhang, Min; Liang, Tongling; Wang, Fosong; Sun, Wen-Hua
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization
Organometallics, 2008, 27, 5641
4083509 CIFC24 H23 F3 N4 O3 Pt SP 1 21/c 110.724; 24.2086; 9.2365
90; 99.893; 90
2362.26Zhao, Shu-Bin; Wu, Gang; Wang, Suning
Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes:fac-PtIVMe3Complexes of BAB and BAM
Organometallics, 2008, 27, 1030
4083513 CIFC52 H60 B F20 Si5P 1 21/c 110.881; 17.287; 31.322
90; 90.844; 90
5891Inoue, Shigeyoshi; Ichinohe, Masaaki; Yamaguchi, Torahiko; Sekiguchi, Akira
A Free Silylium Ion: A Cyclotetrasilenylium Ion with Allylic Character
Organometallics, 2008, 27, 6056
4070596 CIFC22 H35 B Cl2 N4 O S2 TaP 1 21/m 18.596; 14.522; 11.155
90; 94.99; 90
1387.2Hill, Anthony F.; Smith, Matthew K.; Wagler, Jörg
Near Linear Ta−H−B Geometry: [TaCl2(η-C5Me5){κ3-H,S,S′-H2B(methimazolyl)2}]
Organometallics, 2008, 27, 2137
4070670 CIFC41 H65 Br2 La N2 O3P 1 21/m 110.045; 20.093; 10.41
90; 91.951; 90
2099.9Bambirra, Sergio; Perazzolo, Francesca; Boot, Steven J.; Sciarone, Timo J. J.; Meetsma, Auke; Hessen, Bart
Strategies for the Synthesis of Lanthanum Dialkyl Complexes with Monoanionic Ancillary Ligands
Organometallics, 2008, 27, 704
4070708 CIFC8 H5 Fe2 N O6 S2P 1 21/m 16.8441; 13.6033; 7.7636
90; 108.98; 90
683.51Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4071200 CIFC65 H60 B F30 O3 P2 RhP 1 21/m 113.19; 19.765; 13.373
90; 97.16; 90
3459.2Salem, Hiyam; Shimon, Linda J. W.; Leitus, Gregory; Weiner, Lev; Milstein, David
B−C Bond Cleavage of BArFAnion Upon Oxidation of Rhodium(I) with AgBArF. Phosphinite Rhodium(I), Rhodium(II), and Rhodium(III) Pincer Complexes
Organometallics, 2008, 27, 2293
4071283 CIFC33 H42 Cl4 N2P 1 21/m 110.983; 14.196; 11.017
90; 106.04; 90
1650.8Chitanda, Jackson M.; Prokopchuk, Demyan E.; Quail, J. Wilson; Foley, Stephen R.
From Pyrroles to Isoindolines: Synthesis of a γ-Diimine Ligand for Applications in Palladium Coordination Chemistry and Catalysis
Organometallics, 2008, 27, 2337
4071354 CIFC18 H26 P2 PtP 1 21/m 18.624; 10.9514; 10.323
90; 106.99; 90
932.4Canty, Allan J.; Watson, Russell P.; Karpiniec, Samuel S.; Rodemann, Thomas; Gardiner, Michael G.; Jones, Roderick C.
Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
Organometallics, 2008, 27, 3203
4071446 CIFC16 H10 Cr O6 SP 1 21/m 19.2928; 7.633; 12.4413
90; 104.249; 90
855.34Bezuidenhout, Daniela I.; van der Watt, Elisia; Liles, David C.; Landman, Marilé; Lotz, Simon
Steric and Electronic Effects of Metal-Containing Substituents in Fischer Carbene Complexes of Chromium
Organometallics, 2008, 27, 2447
4071595 CIFC27 H28 Cl4 Ir PP 1 21/m 19.7472; 12.0024; 11.4226
90; 99.241; 90
1318.98Lebel, Hélène; Ladjel, Chehla
Iridium Complexes in Olefination Reactions
Organometallics, 2008, 27, 2676
4072119 CIFC30 H16 Au2 F6 Fe N2P 1 21/m 111.4667; 8.5646; 14.1478
90; 98.271; 90
1375Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4072129 CIFC15 H15 I N4 O4 WP 1 21/m 17.1875; 14.16; 9.0408
90; 97.959; 90
911.3Xie, Yun-Fu; Wen, Zhen-Kang; Tan, Run-Yu; Hong, Juan; Zhao, Shu-Bin; Tang, Liang-Fu
Bis(3,5-dimethylpyrazol-1-yl)acyl and Bis(3,5-dimethylpyrazol-1-yl)methide Carbonyl Tungsten Derivatives
Organometallics, 2008, 27, 5684
4072154 CIFC26 H48 N Si2 UP 1 21/m 18.753; 15.573; 11.017
90; 110.86; 90
1403.3Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4072265 CIFC13 H21 O2 P2 VP 1 21/m 17.024; 13.185; 8.438
90; 101.602; 90
765.5Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4070514 CIFC41 H32 O4 P2 Ru2 Te2P 1 21/n 111.015; 18.542; 19.843
90; 92.34; 90
4049Begum, Noorjahan; Hyder, Md. Iqbal; Hassan, Mohammad R.; Kabir, Shariff E.; Bennett, Dennis W.; Haworth, Daniel T.; Siddiquee, Tasneem A.; Rokhsana, Dalia; Sharmin, Ayesha; Rosenberg, Edward
Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenide and Capping Chalcogenido Ligands
Organometallics, 2008, 27, 1550
4070518 CIFC22 H35 B F4 Mo O7 P2P 1 21/n 110.5384; 13.0298; 20.266
90; 93.439; 90
2777.8Grime, Richard W.; Helliwell, Madeleine; Hussain, Zaffar I.; Lancashire, Hannah N.; Mason, Christopher R.; McDouall, Joseph J. W.; Mydlowski, Christopher M.; Whiteley, Mark W.
Metallacumulenylidene Complexes in the Cycloheptatrienyl Molybdenum Series [Mo{(C)nCR2}L2(η-C7H7)]+(n= 0−2; L2= P-Donor Ligand). X-ray Crystal Structures of [Mo{CC(H)Ph}{P(OMe)3}2(η-C7H7)][BF4] and [Mo(CCCPh2)(dppe)(η-C7H7)][PF6] and DFT Investigation of Cumulenylidene Ligand Orientations
Organometallics, 2008, 27, 857
4070520 CIFC26 H45 Fe2 S3P 1 21/n 110.3794; 17.0781; 15.4868
90; 92.412; 90
2742.8Chen, Yanhui; Zhou, Yuhan; Qu, Jingping
Synthesis and Reactions of Novel Triply Thiolate-Bridged Diiron Complexes [Cp*Fe(μ2-SR)3FeCp*] (Cp*= η5-C5Me5; R = Et, Ph)
Organometallics, 2008, 27, 666
4070521 CIFC19 H34 Cl2 Fe2 N S2P 1 21/n 18.9152; 16.2139; 17.5863
90; 103.271; 90
2474.22Chen, Yanhui; Zhou, Yuhan; Qu, Jingping
Synthesis and Reactions of Novel Triply Thiolate-Bridged Diiron Complexes [Cp*Fe(μ2-SR)3FeCp*] (Cp*= η5-C5Me5; R = Et, Ph)
Organometallics, 2008, 27, 666
4070524 CIFC31 H54 Fe2 N S3P 1 21/n 19.1039; 33.854; 11.6173
90; 105.452; 90
3451.1Chen, Yanhui; Zhou, Yuhan; Qu, Jingping
Synthesis and Reactions of Novel Triply Thiolate-Bridged Diiron Complexes [Cp*Fe(μ2-SR)3FeCp*] (Cp*= η5-C5Me5; R = Et, Ph)
Organometallics, 2008, 27, 666
4070530 CIFC10 H12 Br6 O Zr2P 1 21/n 110.5696; 16.7523; 11.6071
90; 116.499; 90
1839.3Glöckner, Andreas; Arif, Atta M.; Ernst, Richard D.
Isolation and Characterization of Bromination Products of Zr(C5H5)2Br2
Organometallics, 2008, 27, 327
4070544 CIFC62 H56 Cl5 F P4 RuP 1 21/n 114.0228; 17.5293; 23.478
90; 100.962; 90
5665.8Gauthier, Nicolas; Olivier, Céline; Rigaut, Stéphane; Touchard, Daniel; Roisnel, Thierry; Humphrey, Mark G.; Paul, Frédéric
Intramolecular Optical Electron Transfer in Mixed-Valent Dinuclear Iron−Ruthenium Complexes Featuring a 1,4-Diethynylaryl Spacer
Organometallics, 2008, 27, 1063
4070545 CIFC27 H44 K O PP 1 21/n 111.3181; 18.874; 13.5474
90; 113.76; 90
2648.7Brady, Erik D.; Chmely, Stephen C.; Jayaratne, Kumudini C.; Hanusa, Timothy P.; Young, Victor G.
s-Block Metal Complexes of the Bis(tetramethylcyclopentadienyl) Phosphonium Diylide [Me(t-Bu)P(C5Me4)2]−
Organometallics, 2008, 27, 1612
4070546 CIFC29 H54 Ca N P Si2P 1 21/n 115.615; 10.092; 21.098
90; 104.88; 90
3213.3Brady, Erik D.; Chmely, Stephen C.; Jayaratne, Kumudini C.; Hanusa, Timothy P.; Young, Victor G.
s-Block Metal Complexes of the Bis(tetramethylcyclopentadienyl) Phosphonium Diylide [Me(t-Bu)P(C5Me4)2]−
Organometallics, 2008, 27, 1612
4070549 CIFC52 H91 Fe2 K N4 O2 Sc Si4P 1 21/n 113.5186; 19.2906; 22.476
90; 99.559; 90
5780Carver, Colin T.; Monreal, Marisa J.; Diaconescu, Paula L.
Scandium Alkyl Complexes Supported by a Ferrocene Diamide Ligand
Organometallics, 2008, 27, 363
4070568 CIFC59 H51 Ir N4P 1 21/n 112.755; 22.544; 16.701
90; 100.692; 90
4719Cheung, Chi Wai; Chan, Kin Shing
Base-Promoted Selective Activation of Benzylic Carbon−Hydrogen Bonds of Toluenes by Iridium(III) Porphyrin
Organometallics, 2008, 27, 3043
4070577 CIFC51 H45 Au2 Cl2 N2 O2.5 P2 S4P 1 21/n 117.174; 14.14; 22.72
90; 93.788; 90
5505Liu, Wei; Wang, Ru; Zhou, Xin-Hui; Zuo, Jing-Lin; You, Xiao-Zeng
Syntheses, Structures, and Properties of Tricarbonyl Rhenium(I) Heteronuclear Complexes with a New Bridging Ligand Containing Coupled Bis(2-pyridyl) and 1,2-Dithiolene Units
Organometallics, 2008, 27, 126
4070594 CIFC29.5 H29.5 Cl2 F10 N2 O2 TiP 1 21/n 113.905; 16.987; 15.1935
90; 99.915; 90
3535.2Ye, Wei-Ping; Zhan, Jie; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis and Characterization of Titanium Complexes Bearing Two β-Enaminoketonato Ligands with Electron-Withdrawing Groups and Their Behavior in Ethylene Polymerization
Organometallics, 2008, 27, 3642
4070597 CIFC29 H46 B N6 O2 RhP 1 21/n 110.5252; 18.4639; 15.847
90; 92.326; 90
3077.1Blake, Alexander J.; George, Michael W.; Hall, Michael B.; McMaster, Jonathan; Portius, Peter; Sun, Xue Z.; Towrie, Michael; Webster, Charles Edwin; Wilson, Claire; Zarić, Snežana D.
Probing the Mechanism of Carbon−Hydrogen Bond Activation by Photochemically Generated Hydridotris(pyrazolyl)borato Carbonyl Rhodium Complexes: New Experimental and Theoretical Investigations
Organometallics, 2008, 27, 189
4070600 CIFC53 H51 B Co2 Mo N6 O6 P2P 1 21/n 114.093; 19.431; 20.15
90; 109.277; 90
5209Caldwell, Lorraine M.; Hill, Anthony F.; Rae, A. David; Willis, Anthony C.
Alkynylselenolatoalkylidynes: [Mo(CSeCCR)(CO)2{HB(pzMe2)3}] (R = CMe3, SiMe3; pzMe2= 3,5-Dimethylpyrazol-1-yl)
Organometallics, 2008, 27, 341
4070601 CIFC13.5 H18 B I2 N6 O0.5 Pt S3P 1 21/n 19.8899; 20.0454; 11.3937
90; 99.5623; 90
2227.38Crossley, Ian R.; Hill, Anthony F.; Willis, Anthony C.
Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10(mt = Methimazolyl)
Organometallics, 2008, 27, 312
4070604 CIFC31.5 H52 B7 Fe N2 O PP 1 21/n 113.04; 15.018; 18.379
90; 90.564; 90
3599.1Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4070619 CIFC14 H24 Cl2 N Ni O PP 1 21/n 18.877; 17.116; 12.018
90; 102.727; 90
1781.14Kermagoret, Anthony; Braunstein, Pierre
Mono- and Dinuclear Nickel Complexes with Phosphino-, Phosphinito-, and Phosphonitopyridine Ligands: Synthesis, Structures, and Catalytic Oligomerization of Ethylene
Organometallics, 2008, 27, 88
4070623 CIFC30 H48 N8 Zr2P 1 21/n 110.892; 16.012; 18.471
90; 100.392; 90
3168.6Majumder, Supriyo; Odom, Aaron L.
Group-4 Dipyrrolylmethane Complexes in Intramolecular Olefin Hydroamination
Organometallics, 2008, 27, 1174
4070626 CIFC20 H30 FeP 1 21/n 17.7101; 59.1719; 15.7478
90; 102.131; 90
7024.1Chong, Daesung; Geiger, William E.; Davis, Nathan A.; Weisbrich, Anke; Shi, Yifan; Arif, Atta M.; Ernst, Richard D.
Synthetic, Structural, and Electrochemical Studies of Edge-Bridged Open Ferrocenes
Organometallics, 2008, 27, 430
4070627 CIFC38 H8 F12 O18 Ru4P 1 21/n 110.3336; 11.8386; 18.0531
90; 106.042; 90
2122.53Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4070628 CIFC38 H8 F12 O18 Ru4P 1 21/n 110.2883; 15.4363; 14.0317
90; 110.34; 90
2089.47Sevryugina, Yulia; Weaver, Beth; Hansen, Jørn; Thompson, Janelle; Davies, Huw M. L.; Petrukhina, Marina A.
Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids
Organometallics, 2008, 27, 1750
4070645 CIFC20 H25 N O5 WP 1 21/n 18.3192; 14.2955; 17.0591
90; 92.92; 90
2026.16Jackson, Andrew B.; Khosla, Chetna; Gaskins, Helen E.; White, Peter S.; Templeton, Joseph L.
Reduction of π-Bound Nitriles to π-Bound Imines in a Tungsten(II) Bis(acetylacetonate) Coordination Sphere
Organometallics, 2008, 27, 1322
4070654 CIFC52 H80 Fe Li N5 O3P 1 21/n 111.5992; 21.2974; 20.5979
90; 93.886; 90
5076.7Fernández, Ignacio; Trovitch, Ryan J.; Lobkovsky, Emil; Chirik, Paul J.
Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3and FeCH2CMe3Derivatives
Organometallics, 2008, 27, 109
4070659 CIFC36 H40 F3 N2 O3 P Ru SP 1 21/n 118.3091; 19.9442; 19.2586
90; 91.1091; 90
7031.2Lundgren, Rylan J.; Rankin, Matthew A.; McDonald, Robert; Stradiotto, Mark
Neutral, Cationic, and Zwitterionic Ruthenium(II) Atom Transfer Radical Addition Catalysts Supported by P,N-Substituted Indene or Indenide Ligands
Organometallics, 2008, 27, 254
4070665 CIFC22 H34 Cl2 N4 O5 RuP 1 21/n 110.236; 10.781; 25.187
90; 92.132; 90
2777.57Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4070680 CIFC27 H29 B11 Cl6 Ir O PP 1 21/n 18.3919; 29.9794; 14.0388
90; 96.183; 90
3511.4Douvris, Christos; Reed, Christopher A.
Increasing the Reactivity of Vaska’s Compound. Oxidative Addition of Chlorobenzene at Ambient Temperature
Organometallics, 2008, 27, 807
4070681 CIFC39 H36 B11 Br6 Ir O2 P2P 1 21/n 19.1707; 23.557; 21.908
90; 93.6401; 90
4723.3Douvris, Christos; Reed, Christopher A.
Increasing the Reactivity of Vaska’s Compound. Oxidative Addition of Chlorobenzene at Ambient Temperature
Organometallics, 2008, 27, 807
4070695 CIFC43 H60 B D6 F4 Mo N7 OP 1 21/n 115.5178; 13.3193; 21.697
90; 95.982; 90
4460.1Petrovic, Dejan; Hrib, Cristian G.; Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands
Organometallics, 2008, 27, 778
4070696 CIFC32 H44 F6 Mo N7 PP 1 21/n 18.009; 27.588; 15.9818
90; 100.119; 90
3476.3Petrovic, Dejan; Hrib, Cristian G.; Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands
Organometallics, 2008, 27, 778
4070699 CIFC32 H55 F3 N6 O3 S Si2 ZrP 1 21/n 110.4937; 19.0633; 20.8233
90; 102.123; 90
4072.7Herrmann, Heike; Lloret Fillol, Julio; Wadepohl, Hubert; Gade, Lutz H.
A Zirconium (1-Pyridinio)imido Complex: Facile N−N Bond Cleavage and N−C Bond Formation
Organometallics, 2008, 27, 172
4070703 CIFC40 H35 Fe2 N O6 P2 S2P 1 21/n 19.3759; 19.56; 21.756
90; 94.719; 90
3976.4Song, Li-Cheng; Wang, Hu-Ting; Ge, Jian-Hua; Mei, Shu-Zhen; Gao, Jie; Wang, Liang-Xing; Gai, Bin; Zhao, Li-Qun; Yan, Jing; Wang, Yong-Zhen
Investigations on the Active Site Models of [FeFe]-Hydrogenases: Synthesis, Structure, and Properties of N-Functionalized Azadithiolatodiiron Complexes Containing Mono- and Diphosphine Ligands
Organometallics, 2008, 27, 1409
4070704 CIFC21 H18 Fe2 N O6 P S2P 1 21/n 112.519; 17.022; 12.706
90; 119.186; 90
2363.9Song, Li-Cheng; Wang, Hu-Ting; Ge, Jian-Hua; Mei, Shu-Zhen; Gao, Jie; Wang, Liang-Xing; Gai, Bin; Zhao, Li-Qun; Yan, Jing; Wang, Yong-Zhen
Investigations on the Active Site Models of [FeFe]-Hydrogenases: Synthesis, Structure, and Properties of N-Functionalized Azadithiolatodiiron Complexes Containing Mono- and Diphosphine Ligands
Organometallics, 2008, 27, 1409
4070706 CIFC10 H9 Fe2 N O6 S2P 1 21/n 19.964; 12.0864; 13.0405
90; 105.405; 90
1514Stanley, Jane L.; Heiden, Zachariah M.; Rauchfuss, Thomas B.; Wilson, Scott R.; De Gioia, Luca; Zampella, Guiseppe
Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.
Organometallics, 2008, 27, 119-125
4070711 CIFC54 H69 N3 P Rh Si4 SnP 1 21/n 114.1402; 23.38; 15.953
90; 96.568; 90
5239.4Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
Triamidostannates(II) as Sterically Demanding Ligands for Rhodium and Iridium
Organometallics, 2008, 27, 524
4070719 CIFC16 H8 N2 O11 Ru3P 1 21/n 18.512; 22.951; 11.753
90; 110.2; 90
2155Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4070722 CIFC32 H24 N2 O11 Ru3P 1 21/n 113.6171; 15.1982; 16.7505
90; 90.604; 90
3466.41Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4070723 CIFC16 H8 N2 O11 Os3P 1 21/n 18.472; 22.858; 11.767
90; 110.195; 90
2138.6Cabeza, Javier A.; del Río, Ignacio; Miguel, Daniel; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela
Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
Organometallics, 2008, 27, 211
4070725 CIFC31 H46 B F2 Fe K O6 SnP 1 21/n 110.6477; 13.3122; 24.4814
90; 93.176; 90
3464.77Boshra, Ramez; Doshi, Ami; Jäkle, Frieder
Fluoride-Promoted Aryl and Allyl Migration from Boron to Tin in 1-Stannyl-2-borylferrocenes
Organometallics, 2008, 27, 1534
4070735 CIFC54 H110 Al2 Li2 N2 O4 Si4P 1 21/n 113.225; 17.355; 14.27
90; 95.577; 90
3259.7Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming
Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^
Organometallics, 2008, 27, 678-682
4070739 CIFC23 H46 Li N O Si2P 1 21/n 19.9324; 17.397; 16.0983
90; 101.203; 90
2728.7Cheng, Xiaoyan; Zhang, Jianying; Song, Haibin; Cui, Chunming
Synthesis and Characterization of the Monomeric Vicinal Dianion Li~2~(THF)~3~[ArNC(SiMe~3~)~2~] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe~3~)~2~]^-^
Organometallics, 2008, 27, 678-682
4070745 CIFC36 H45 B3 Bi F3 O6P 1 21/n 111.6453; 13.4108; 24.5109
90; 94.063; 90
3818.3Caires, Christopher C.; Guccione, Samira
Synthesis, Structure, and Reactivity of Borate Ester Coordinated Organobismuth Compounds
Organometallics, 2008, 27, 747
4070749 CIFC40 H48 Cl2 P2 Pd2P 1 21/n 19.2167; 12.9557; 16.6165
90; 95.89; 90
1973.68Yan, Xiaoyu; Xi, Chanjuan
Synthesis and Characterization of Novel Four-Membered Palladacycles
Organometallics, 2008, 27, 152
4070751 CIFC15 H23 B10 Co O4 S2P 1 21/n 19.936; 18.012; 13.344
90; 110.741; 90
2233.4Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4070753 CIFC15 H23 B10 Co O4 Se2P 1 21/n 110.0659; 18.0533; 13.4238
90; 110.922; 90
2278.6Xu, Bao-Hua; Tao, Jing-Cong; Li, Yi-Zhi; Li, Shu-Hua; Yan, Hong
Metal-Induced B−H Bond Activation: Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand
Organometallics, 2008, 27, 334
4070777 CIFC29 H36 Cl Ir N2 O2P 1 21/n 110.6033; 15.1588; 18.2189
90; 97.654; 90
2902.29Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4070778 CIFC35 H48 Cl Ir N2P 1 21/n 116.6208; 10.5366; 37.9569
90; 102.585; 90
6487.6Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4070784 CIFC35 H50 Cl Ir N2P 1 21/n 116.7211; 10.5462; 38.526
90; 102.481; 90
6633.3Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4070796 CIFC23 H26 N2 O4 SiP 1 21/n 17.584; 13.923; 20.265
90; 91.37; 90
2139.2Spiniello, Marisa; White, Jonathan M.
Structural Investigations into the β-Effect of Pentavalent Silicon
Organometallics, 2008, 27, 994
4070816 CIFC25 H46 B F3 O P2 PtP 1 21/n 19.8764; 21.34; 13.5382
90; 93.188; 90
2848.9Wu, Jianguo; Sharp, Paul R.
A Family of Platinaoxetanes
Organometallics, 2008, 27, 1234
4070819 CIFC28 H32 O6P 1 21/n 16.9725; 9.5826; 36.815
90; 91.424; 90
2459Melikyan, Gagik G.; Wild, Christopher; Toure, Pogban
Intramolecular Cyclizations of Co2(CO)6-Complexed Propargyl Radicals: Synthesis ofd,l- andmeso-1,5-Cyclodecadiynes
Organometallics, 2008, 27, 1569
4070821 CIFC71 H70 Ag F6 O6 P3 Pt2 S2P 1 21/n 111.194; 23.488; 26.19
90; 96.52; 90
6841Wachtler, Helmuth; Schuh, Walter; Augner, Sven; Hägele, Gerhard; Wurst, Klaus; Peringer, Paul
Syn−AntiIsomerization by Intramolecular Alkene Rotation: Study of the Dynamics of the Bicyclo[2.2.1]hept-2-ene Ligands in a Diplatinum(I) Complex and Its Lewis Acid Adducts
Organometallics, 2008, 27, 1797
4070831 CIFC78 H71 B F24 N3 PdP 1 21/n 112.8846; 15.727; 36.571
90; 91.951; 90
7406.3Li, Weidong; Zhang, Xiaochun; Meetsma, Auke; Hessen, Bart
Reactions of Cationic Palladium α-Diimine Complexes with Nitrogen-Containing Olefins: Branched Polyethylene with Carbazole Functionalities
Organometallics, 2008, 27, 2052
4070834 CIFC50 H33 Co O3 P2 PtP 1 21/n 112.745; 19.22; 18.529
90; 101.71; 90
4444Komine, Nobuyuki; Hirota, Takuma; Hirano, Masafumi; Komiya, Sanshiro
E-Selective Allyl Transfer Reaction in a μ-η1:η2-Crotylplatinum−Cobalt Complex
Organometallics, 2008, 27, 2145
4070835 CIFC39 H37 Co O3 P2 PtP 1 21/n 19.316; 18.188; 20.671
90; 91.18; 90
3501.7Komine, Nobuyuki; Hirota, Takuma; Hirano, Masafumi; Komiya, Sanshiro
E-Selective Allyl Transfer Reaction in a μ-η1:η2-Crotylplatinum−Cobalt Complex
Organometallics, 2008, 27, 2145
4070846 CIFC47 H54 B O Os PP 1 21/n 116.86; 10.1387; 23.855
90; 102.482; 90
3981.4Esteruelas, Miguel A.; Hernández, Yohar A.; López, Ana M.; Oliván, Montserrat; Rubio, Lucía
Reactions of a Dihydride−Osmium(IV) Complex with Aldehydes: Influence of the Substituent at the Carbonyl Group
Organometallics, 2008, 27, 799
4070850 CIFC19 H25 N3 O9 PdP 1 21/n 116.322; 8.2938; 18.474
90; 112.011; 90
2318.6Vicente, José; Arcas, Aurelia; Gálvez-López, María-Dolores; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Synthesis of Bis(2,6-dinitroaryl)palladium(II) and Mono(2,6-dinitroaryl)platinum(II) Complexes. A New Example of the Transphobia Effect and of Transmetalation from Pt to Hg
Organometallics, 2008, 27, 1582
4070858 CIFC60 H102 I3 N P6 Pt3P 1 21/n 116.944; 17.295; 25.961
90; 101.622; 90
7452Ghosh, Sushobhan; Mukherjee, Partha Sarathi
Self-Assembly of a Nanoscopic Prism via a New Organometallic Pt3Acceptor and Its Fluorescent Detection of Nitroaromatics
Organometallics, 2008, 27, 316
4070874 CIFC35 H32 Fe O3 Si2P 1 21/n 18.965; 19.433; 18.239
90; 95.184; 90
3164.5Zhang, Zhensheng; Gu, Jianli; Zhang, Chengxun; Sun, Huailin
Intramolecular Si−Si Bond Activation by the Iron Carbonyl Unit in an (η4-Silole)tricarbonyliron Complex
Organometallics, 2008, 27, 2149
4070886 CIFC22 H30 Br N2 RhP 1 21/n 110.3387; 13.433; 14.932
90; 96.477; 90
2060.5Türkmen, Hayati; Pape, Tania; Hahn, F. Ekkehardt; Çetinkaya, Bekir
Annulated N-Heterocyclic Carbene Ligands Derived from 2-Methylaminopiperidine: Their Complexes and Catalytic Applications
Organometallics, 2008, 27, 571
4070887 CIFC22 H30 Br Ir N2P 1 21/n 110.364; 13.438; 14.932
90; 96.208; 90
2067.4Türkmen, Hayati; Pape, Tania; Hahn, F. Ekkehardt; Çetinkaya, Bekir
Annulated N-Heterocyclic Carbene Ligands Derived from 2-Methylaminopiperidine: Their Complexes and Catalytic Applications
Organometallics, 2008, 27, 571
4070890 CIFC23.5 H29 Cl5 N P PdP 1 21/n 112.6691; 15.0351; 14.1201
90; 94.963; 90
2679.5Shaffer, Andrew R.; Schmidt, Joseph A. R.
Palladium(II) 3-Iminophosphine Complexes as Intermolecular Hydroamination Catalysts for the Formation of Imines and Enamines
Organometallics, 2008, 27, 1259
4070893 CIFC17 H36 B9 N3 ZrP 1 21/n 115.196; 9.917; 16.573
90; 107.43; 90
2382.9Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4070897 CIFC40 H76 B18 Hf2 N2 O6P 1 21/n 19.4478; 14.7429; 18.82
90; 97.712; 90
2597.7Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4070913 CIFC46 H86 N6 Sr2P 1 21/n 112.015; 12.68; 16.614
90; 102.513; 90
2471Cameron, Thomas M.; Xu, Chongying; Dipasquale, Antonio G.; Rheingold, Arnold L.
Synthesis and Structure of Strontium and Barium Guanidinates and Mixed-Ligand Guanidinate Pentamethylcyclopentadienyl Complexes
Organometallics, 2008, 27, 1596
4070933 CIFC35 H48 O2 Si2 ZrP 1 21/n 113.5735; 16.06; 15.706
90; 100.134; 90
3370.3Bazinet, Patrick; Tilley, T. Don
Octa- and Nonamethylfluorenyl Complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of Steric and Electronic Effects
Organometallics, 2008, 27, 1267
4070934 CIFC34 H46 O2 Si2 ZrP 1 21/n 111.8741; 15.1861; 18.4029
90; 103.33; 90
3229Bazinet, Patrick; Tilley, T. Don
Octa- and Nonamethylfluorenyl Complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of Steric and Electronic Effects
Organometallics, 2008, 27, 1267
4070940 CIFC58 H56 N2 Ni2 P6P 1 21/n 112.987; 14.438; 13.769
90; 92.25; 90
2579.8Acosta-Ramírez, Alberto; Flores-Álamo, Marcos; Jones, William D.; García, Juventino J.
P−C Bond Scission at the TRIPHOS Ligand and C−CN Bond Cleavage in 2-Methyl-3-butenenitrile with [Ni(COD)2]
Organometallics, 2008, 27, 1834
4070947 CIFC39 H31 N2 O4 P RuP 1 21/n 114.4; 10.748; 22.054
90; 103.395; 90
3320.5Armitt, David J.; Bruce, Michael I.; Skelton, Brian W.; White, Allan H.
Reactions of Alkynyl−Ruthenium Complexes with the Ketene Dithioacetal, (MeS)2CC(CN)2
Organometallics, 2008, 27, 3556
4070950 CIFC34 H34 Cl2 N4 Pd2P 1 21/n 17.4968; 9.9044; 21.6197
90; 97.241; 90
1592.49Hadzovic, Alen; Song, Datong
Synthesis, Characterization, and Reactivity of a Versatile Dinuclear Palladium β-Diiminate Complex
Organometallics, 2008, 27, 1290
4070953 CIFC38 H38 Cl2 N4 O4 Pd2P 1 21/n 117.8544; 11.2625; 18.3314
90; 90.086; 90
3686.17Hadzovic, Alen; Song, Datong
Synthesis, Characterization, and Reactivity of a Versatile Dinuclear Palladium β-Diiminate Complex
Organometallics, 2008, 27, 1290
4070955 CIFC61 H76 N2 O ThP 1 21/n 111.3511; 26.364; 36.2376
90; 98.736; 90
10718.7Cruz, Carlos A.; Emslie, David J. H.; Harrington, Laura E.; Britten, James F.
Single and Double Alkyl Abstraction from a Bis(anilido)xanthene Thorium(IV) Dibenzyl Complex: Isolation of an Organothorium Cation and a Thorium Dication
Organometallics, 2008, 27, 15
4070957 CIFC36 H61 Si2 SmP 1 21/n 116.4072; 11.7609; 18.791
90; 90.501; 90
3625.84Summerscales, Owen T.; Johnston, David R.; Cloke, F. Geoffrey N.; Hitchcock, Peter B.
Samarium(III) Pentalene Sandwich Compounds [Sm(η8-C8H4{SiiPr3-1,4}2)(Cp*)] and [Sm(η8-C8H4{SiiPr3-1,4}2)(η5-C8H5{SiiPr3-1,4}2)] and a Mixed-Valence Hexasamarium Cluster Derived from Sm(II)-Based Solvent Activation
Organometallics, 2008, 27, 5612
4070964 CIFC34 H48 Cl Fe N3 O5P 1 21/n 19.4467; 20.014; 18.161
90; 96.305; 90
3412.9Sciarone, Timo J. J.; Nijhuis, Christian A.; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Paramagnetic Amino-amidinate Iron(II) Complexes:19F NMR Evidence for Interactions with Weakly Coordinating Anions
Organometallics, 2008, 27, 2058
4070967 CIFC54 H78 Lu N5P 1 21/n 112.0911; 20.124; 21.253
90; 99.012; 90
5107.5Masuda, Jason D.; Jantunen, Kimberly C.; Scott, Brian L.; Kiplinger, Jaqueline L.
Synthesis, Characterization, and Reactivity of the Thermally Stable Lutetium Tris(alkyl) Complex (tBu2bpy)Lu(CH2SiMe3)3
Organometallics, 2008, 27, 1299
4070971 CIFC22 H21 F3 N2 O3 Pt S SiP 1 21/n 113.412; 13.1627; 14.2154
90; 113.369; 90
2303.7Sangtrirutnugul, Preeyanuch; Tilley, T. Don
Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Organometallics, 2008, 27, 2223
4070982 CIFC21 H25 I2 Ir N2P 1 21/n 19.5338; 11.0406; 21.147
90; 99.593; 90
2194.8Pontes da Costa, André; Viciano, Mónica; Sanaú, Mercedes; Merino, Sonia; Tejeda, Juan; Peris, Eduardo; Royo, Beatriz
First Cp*-Functionalized N-Heterocyclic Carbene and Its Coordination to Iridium. Study of the Catalytic Properties
Organometallics, 2008, 27, 1305
4070993 CIFC66 H126 Ca4 N2 O6 Si4P 1 21/n 114.9414; 13.7179; 18.2401
90; 90.379; 90
3738.49He, Xuyang; Hurley, Erin; Noll, Bruce C.; Henderson, Kenneth W.
Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Organometallics, 2008, 27, 3094
4071011 CIFC7 H4 Ag4 N4 O9P 1 21/n 17.2997; 16.0767; 11.7819
90; 92.056; 90
1381.8Zhao, Liang; Chen, Xu-Dong; Mak, Thomas C. W.
Silver(I)−Ethynide Supramolecular Synthons in the Assembly of π−π Stacked Infinite Columns⊥
Organometallics, 2008, 27, 2483
4071016 CIFC24 H24 Cl2 Co F I2 N3P 1 21/n 113.3251; 14.5228; 14.7832
90; 107.941; 90
2721.7Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Bobik Fones, Barbara; Fish, Brian M.; Schiffhauer, Matthew F.; Spence, Rupert E.; Xie, Tuyu
High-Temperature Catalysts for the Production of α-Olefins Based on Iron(II) and Cobalt(II) Tridentate Bis(imino)pyridine Complexes with a Double Pattern of Substitution:o-Methyl pluso-Fluorine in the Same Imino Arm†
Organometallics, 2008, 27, 1147
4071019 CIFC74.5 H66 Cl7 N P4 Ru2P 1 21/n 114.196; 33.708; 16.8163
90; 109.211; 90
7598.8Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071021 CIFC38 H35 Cl4 N P2 RuP 1 21/n 110.53; 13.425; 25.056
90; 95.832; 90
3524Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071022 CIFC40 H51 Cl8 N P2 RuP 1 21/n 112.5688; 20.003; 17.9037
90; 102.123; 90
4400.9Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071024 CIFC41 H45 Cl4 N P2 RuP 1 21/n 113.014; 16.287; 18.698
90; 96.651; 90
3937Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071032 CIFC20 H41 Li N4 O Si2P 1 21/n 110.708; 19.073; 13.227
90; 96.24; 90
2685.4Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071035 CIFC17 H37 Li N4 O Si2P 1 21/n 110.603; 13.144; 17.77
90; 91.05; 90
2476.1Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071036 CIFC18 H38 Li N5 Si2P 1 21/n 110.505; 17.673; 13.865
90; 100.61; 90
2530.1Aharonovich, Sinai; Kapon, Moshe; Botoshanski, Mark; Eisen, Moris S.
N,N′-Bis-Silylated Lithium Aryl Amidinates: Synthesis, Characterization, and the Gradual Transition of Coordination Mode from σ Toward π Originated by Crystal Packing Interactions
Organometallics, 2008, 27, 1869
4071038 CIFC22 H13 I2 Mo2 O6 PP 1 21/n 111.859; 18.165; 12.637
90; 111.89; 90
2526Ricci, Antonella; Angelucci, Francesco; Chiarini, Marco; Sterzo, Claudio Lo; Masi, Dante; Giambastiani, Giuliano; Bianchini, Claudio
Bis(cyclopentadienyl)phenylphosphine as Ligand Precursor for Assembling Heteropolymetal Complexes
Organometallics, 2008, 27, 1617
4071042 CIFC24 H43 F3 N3 O3 P2 Rh SP 1 21/n 18.4223; 15.6644; 22.9973
90; 93.5385; 90
3028.26Hanson, Susan Kloek; Heinekey, D. Michael; Goldberg, Karen I.
C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water
Organometallics, 2008, 27, 1454
4071045 CIFC35 H49 Cl11 O Os P4P 1 21/n 119.1611; 9.9137; 26.3
90; 105.754; 90
4808.2Gong, Lei; Lin, Yumei; He, Guomei; Zhang, Hong; Wang, Huijuan; Wen, Ting Bin; Xia, Haiping
Synthesis and Characterization of an Air-Stablep-Osmaphenol
Organometallics, 2008, 27, 309
4071049 CIFC47 H45 F6 N O3 P3 Ru S SbP 1 21/n 120.0192; 12.3803; 20.9031
90; 115.912; 90
4659.87Cadierno, Victorio; Díez, Josefina; García-Álvarez, Joaquín; Gimeno, José
(η6-Arene)−Ruthenium(II) Complexes Containing Methanide and Methandiide Anions of Ph2P(S)CH2P(NR)Ph2: Unprecedented Insertion of Isocyanide into a Ruthenium−Carbene Bond
Organometallics, 2008, 27, 1809
4071051 CIFC81 H80 Cl4 N6 P2 Ru SP 1 21/n 113.2605; 31.3082; 17.3833
90; 91.241; 90
7215.2Cadierno, Victorio; Díez, Josefina; García-Álvarez, Joaquín; Gimeno, José
(η6-Arene)−Ruthenium(II) Complexes Containing Methanide and Methandiide Anions of Ph2P(S)CH2P(NR)Ph2: Unprecedented Insertion of Isocyanide into a Ruthenium−Carbene Bond
Organometallics, 2008, 27, 1809
4071053 CIFC29.5 H18 Cl4 TiP 1 21/n 110.5761; 18.6258; 12.9464
90; 110.549; 90
2388Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071056 CIFC38 H28 Cl2 O TiP 1 21/n 110.3873; 18.6488; 14.7521
90; 96.188; 90
2841Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071057 CIFC41 H34 Cl2 O TiP 1 21/n 112.9695; 14.7973; 17.2211
90; 100.068; 90
3254.1Schröder, Kai; Haase, Detlev; Saak, Wolfgang; Beckhaus, Ruediger; Kretschmer, Winfried P.; Lützen, Arne
Tetrabenzo[a,c,g,i]fluorenyltitanium(III) and -(IV) Complexes: Syntheses, Reactions, and Catalytic Application
Organometallics, 2008, 27, 1859
4071063 CIFC34 H36 O6 SiP 1 21/n 17.3493; 22.774; 18.64
90; 91.177; 90
3119.2Pariya, Chandi; Marcos, Yoseph S.; Zhang, Yixun; Fronczek, Frank R.; Maverick, Andrew W.
Organosilicon-Based Multifunctional β-Diketones and their Rhodium and Iridium Complexes
Organometallics, 2008, 27, 4318
4071073 CIFC24 H42 N2 O WP 1 21/n 111.732; 13.594; 15.641
90; 104.161; 90
2418.7Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4071074 CIFC25 H44 N2 O WP 1 21/n 110.776; 18.681; 13.048
90; 98.56; 90
2597.4Tsang, Jenkins Y. K.; Buschhaus, Miriam S. A.; Fujita-Takayama, Chikako; Patrick, Brian O.; Legzdins, Peter
Different Modes of Reactivity of Cp*W(NO)(alkyl)(η3-allyl) Complexes with Cyclic Amines: The Influence of the Allyl Ligands
Organometallics, 2008, 27, 1634
4071091 CIFC9 H8 Fe0.5 O2 PP 1 21/n 16.796; 8.163; 16.939
90; 96.36; 90
933.9Escobar, Aholibama; Donnadieu, Bruno; Mathey, François
From Functional Phospholide Ions to Bifunctional 1,1′-Diphosphaferrocenes
Organometallics, 2008, 27, 1887
4071108 CIFC17 H37 Cl P4 TiP 1 21/n 19.996; 13.711; 17.241
90; 98.46; 90
2337.3You, Yujian; Girolami, Gregory S.
Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Dimerization and Trimerization Catalysis
Organometallics, 2008, 27, 3172
4071111 CIFC23 H52 B P3 Si TiP 1 21/n 116.279; 9.103; 20.746
90; 100.13; 90
3026.4You, Yujian; Girolami, Gregory S.
Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Dimerization and Trimerization Catalysis
Organometallics, 2008, 27, 3172
4071126 CIFC59 H47 Fe N5 P2P 1 21/n 112.113; 24.413; 16.942
90; 108.092; 90
4762.3Montigny, Frédéric de; Argouarch, Gilles; Roisnel, Thierry; Toupet, Loic; Lapinte, Claude; Lam, Sally Chan-Fung; Tao, Chi-Hang; Yam, Vivian Wing-Wah
Syntheses, Structures, and Properties of Some Piano-Stool Iron Acetylides Bearing a Functional Anthracenyl Group
Organometallics, 2008, 27, 1912
4071127 CIFC59 H47 Fe N5 P2P 1 21/n 112.2278; 24.5711; 17.097
90; 107.508; 90
4898.84Montigny, Frédéric de; Argouarch, Gilles; Roisnel, Thierry; Toupet, Loic; Lapinte, Claude; Lam, Sally Chan-Fung; Tao, Chi-Hang; Yam, Vivian Wing-Wah
Syntheses, Structures, and Properties of Some Piano-Stool Iron Acetylides Bearing a Functional Anthracenyl Group
Organometallics, 2008, 27, 1912
4071129 CIFC78 H114 O12 Si6P 1 21/n 118.2723; 11.9096; 18.6349
90; 90.3209; 90
4055.18Sase, Shohei; Cho, Yoen-Seok; Kawachi, Atsushi; Wakamiya, Atsushi; Yamaguchi, Shigehiro; Tsuji, Hayato; Tamao, Kohei
Synthesis and Electronic Spectra of Disilatriptycene Oligomers: Evidence for Electronic Delocalization along the One-Dimensional Arrangement of Bridge-Head Disilanes
Organometallics, 2008, 27, 5441
4071138 CIFC22 H20 Cl2 Fe3 N2 O8 Te2P 1 21/n 19.8877; 13.3922; 22.1362
90; 91.621; 90
2930.06Mathur, Pradeep; Singh, Amrendra K.; Mohanty, Jamini R.; Chatterjee, Saurav; Mobin, Shaikh M.
Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between TrimethylamineN-Oxide and Acetylenes on Fe3Te2(CO)9and Contrast with Reactions on Fe3E2(CO)9(E = S, Se)
Organometallics, 2008, 27, 5094
4071142 CIFC24 H37 N Ni P2P 1 21/n 19.051; 16.515; 16.53
90; 98.475; 90
2443.88Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071150 CIFC24 H25 O7 P WP 1 21/n 110.4536; 15.8144; 14.87
90; 99.6078; 90
2423.79Bode, Maren; Schnakenburg, Gregor; Jones, Peter G.; Streubel, Rainer
Synthesis of Novel O,P,C-Cage Complexes via Thermal C−O Ring Opening of an Oxaphosphirane W(CO)5Complex
Organometallics, 2008, 27, 2664
4071158 CIFC76 H106 N4 Ni O10 S2P 1 21/n 112.732; 15.4904; 36.9865
90; 98.778; 90
7209.2Li, Jianfeng; Tian, Dawei; Song, Haibin; Wang, Chunhua; Zhu, Xiaoqing; Cui, Chunming; Cheng, Jin-Pei
Synthesis, Structures, and Reactivity of Nickel Complexes Incorporating Sulfonamido-Imine Ligands
Organometallics, 2008, 27, 1605
4071164 CIFC66 H52 Br2 N4 NiP 1 21/n 110.8585; 15.3435; 15.6337
90; 90.693; 90
2604.5Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071166 CIFC34 H36 Br2 N4 NiP 1 21/n 110.993; 10.787; 13.442
90; 94.954; 90
1588Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071167 CIFC60 H58 Br2 N6 Ni O2P 1 21/n 110.5341; 17.8161; 14.2407
90; 94.987; 90
2662.5Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071169 CIFC28 H57 I Si4 SnP 1 21/n 120.028; 8.9373; 20.512
90; 106.195; 90
3525.9Kavara, Ajdin; Cousineau, Kandarpa D.; Rohr, Ahleah D.; Kampf, Jeff W.; Banaszak Holl, Mark M.
A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
Organometallics, 2008, 27, 1041
4071171 CIFC22 H51 I Si4 SnP 1 21/n 19.0768; 17.5676; 19.1346
90; 91.553; 90
3050Kavara, Ajdin; Cousineau, Kandarpa D.; Rohr, Ahleah D.; Kampf, Jeff W.; Banaszak Holl, Mark M.
A Stannylene/Aryl Iodide Reagent for Allylic CH Activation and Double Bond Addition Chemistry
Organometallics, 2008, 27, 1041
4071175 CIFC40 H44 P2 Pt Si2P 1 21/n 111.142; 15.245; 21.524
90; 91.594; 90
3654.6Arii, Hidekazu; Takahashi, Makiko; Noda, Aki; Nanjo, Masato; Mochida, Kunio
Spectroscopic and Structural Studies of Thermally Unstable Intermediates Generated in the Reaction of [Pt(PPh3)2(η2-C2H4)] with Dihydrodisilanes
Organometallics, 2008, 27, 1929
4071186 CIFC18 H27 Br OsP 1 21/n 18.7839; 13.3233; 14.1332
90; 97.17; 90
1641.08Dub, Pavel A.; Belkova, Natalia V.; Lyssenko, Konstantin A.; Silantyev, Gleb A.; Epstein, Lina M.; Shubina, Elena S.; Daran, Jean-Claude; Poli, Rinaldo
Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
Organometallics, 2008, 27, 3307
4071189 CIFC38 H55 N2 Ni O PP 1 21/n 110.1616; 36.813; 20.361
90; 92.918; 90
7606.7Azoulay, Jason D.; Itigaki, Koji; Wu, Guang; Bazan, Guillermo C.
Influence of Steric and Electronic Perturbations on the Polymerization Activities of α-Iminocarboxamide Nickel Complexes
Organometallics, 2008, 27, 2273
4071192 CIFC42 H55 N2 Ni O PP 1 21/n 19.9429; 25.4501; 15.2227
90; 93.662; 90
3844.2Azoulay, Jason D.; Itigaki, Koji; Wu, Guang; Bazan, Guillermo C.
Influence of Steric and Electronic Perturbations on the Polymerization Activities of α-Iminocarboxamide Nickel Complexes
Organometallics, 2008, 27, 2273
4071196 CIFC32 H35 I O3 P2 PdP 1 21/n 112.2084; 14.0521; 19.558
90; 105.207; 90
3237.8Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071197 CIFC33 H28 I O2 P Pd SP 1 21/n 19.8674; 17.5903; 17.8699
90; 98.806; 90
3065.1Bai, Tao; Xue, Liqin; Xue, Peng; Zhu, Jun; Sung, Herman Ho-Yung; Ma, Shengming; Wiliams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Insertion Reactions of Allenes with Palladium Aryl Complexes [PdI(Ph)(PPh3)]2and PdI(Ph)(dppe)
Organometallics, 2008, 27, 2614
4071204 CIFC37 H47 B2 Cl2 Fe N5 O4P 1 21/n 112.6115; 16.284; 19.867
90; 104.933; 90
3942.2Ionkin, Alex S.; Marshall, William J.; Adelman, Douglas J.; Fones, Barbara Bobik; Fish, Brian M.; Schiffhauer, Matthew F.
Modification of Iron(II) Tridentate Bis(imino)pyridine Complexes by a Boryl Group for the Production of α-Olefins at High Temperature†
Organometallics, 2008, 27, 1902
4071212 CIFC54 H84 Si8 Zr2P 1 21/n 116.088; 10.731; 17.823
90; 105.34; 90
2967.3Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071224 CIFC22 H28 TiP 1 21/n 16.9748; 12.204; 21.448
90; 94.9; 90
1819Sassmannshausen, Jörg; Baumgartner, Judith
Synthesis, Reactivity, and Computational Studies of [η5-C5H5-(η5-C5H4CMe2C6H4Me)TiMe]+: Aromatic C−H Bond Activation at −50 °C§
Organometallics, 2008, 27, 1996
4071226 CIFC18 H44 Ir P3P 1 21/n 115.2176; 9.3278; 17.7508
90; 114.744; 90
2288.33Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4071227 CIFC20 H49 Cl Ir O P3 SiP 1 21/n 19.3183; 18.2326; 17.2933
90; 104.074; 90
2849.9Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4071233 CIFC32 H50 O8 Os3 P2 PtP 1 21/n 19.1635; 25.1624; 17.6681
90; 101.637; 90
3990.1Adams, Richard D.; Boswell, Erin
Cleavage oftert-Butyl Groups from the Tri-tert-butylphosphine Ligand in Osmium−Platinum Carbonyl Cluster Complexes
Organometallics, 2008, 27, 2021
4071235 CIFC17 H21 Cl N2 O2 PdP 1 21/n 111.4408; 9.9882; 14.8055
90; 97.645; 90
1676.83Giri, Ramesh; Maugel, Nathan; Foxman, Bruce M.; Yu, Jin-Quan
Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
Organometallics, 2008, 27, 1667
4071238 CIFC78.57 H141.15 Cl4.94 N O7 P4 Ru4P 1 21/n 119.7118; 18.4691; 25.4987
90; 99.551; 90
9154.4Yi, Chae S.; Zeczycki, Tonya N.; Lindeman, Sergey V.
Kinetic, Spectroscopic, and X-Ray Crystallographic Evidence for the Cooperative Mechanism of the Hydration of Nitriles Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo Complex
Organometallics, 2008, 27, 2030
4071245 CIFC55 H43 Ag Cl2 F3 Fe3 O3 P3 SP 1 21/n 113.309; 24.399; 16.317
90; 106.752; 90
5073.69Mizuta, Tsutomu; Aotani, Tomoyuki; Imamura, Yuki; Kubo, Kazuyuki; Miyoshi, Katsuhiko
Structure and Properties of the Macrocyclic Tridentate Ferrocenylphosphine Ligand (−PhPC5H4FeC5H4−)3
Organometallics, 2008, 27, 2457
4071249 CIFC31 H27 Mn O2 SP 1 21/n 19.923; 21.7612; 12.017
90; 104.77; 90
2509.2Sentets, Stéphane; Serres, Rémi; Ortin, Yannick; Lugan, Noël; Lavigne, Guy
Directed Formation of Allene Complexes upon Reaction of Non-heteroatom-Substituted Manganese Alkynyl Carbene Complexes with Nucleophiles
Organometallics, 2008, 27, 2078
4071250 CIFC30 H29 Mn O3P 1 21/n 113.8542; 10.8128; 17.1782
90; 108.37; 90
2442.2Sentets, Stéphane; Serres, Rémi; Ortin, Yannick; Lugan, Noël; Lavigne, Guy
Directed Formation of Allene Complexes upon Reaction of Non-heteroatom-Substituted Manganese Alkynyl Carbene Complexes with Nucleophiles
Organometallics, 2008, 27, 2078
4071251 CIFC36 H42 Mn O2 PP 1 21/n 18.8673; 29.3918; 12.0901
90; 107.574; 90
3003.9Sentets, Stéphane; Serres, Rémi; Ortin, Yannick; Lugan, Noël; Lavigne, Guy
Directed Formation of Allene Complexes upon Reaction of Non-heteroatom-Substituted Manganese Alkynyl Carbene Complexes with Nucleophiles
Organometallics, 2008, 27, 2078
4071252 CIFC36 H42 Mn O2 PP 1 21/n 19.2247; 11.1454; 30.466
90; 97.174; 90
3107.8Sentets, Stéphane; Serres, Rémi; Ortin, Yannick; Lugan, Noël; Lavigne, Guy
Directed Formation of Allene Complexes upon Reaction of Non-heteroatom-Substituted Manganese Alkynyl Carbene Complexes with Nucleophiles
Organometallics, 2008, 27, 2078
4071259 CIFC150 H139 F12 N4 O14 P4 Rh2 Sb2P 1 21/n 125.143; 21.055; 26.124
90; 90.266; 90
13830Mikhel, Igor S.; Rüegger, Heinz; Butti, Pietro; Camponovo, Francesco; Huber, Dominik; Mezzetti, Antonio
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes
Organometallics, 2008, 27, 2937
4071264 CIFC31 H60 Ga2 SiP 1 21/n 112.1123; 18.898; 15.118
90; 97.756; 90
3428.8Uhl, Werner; Claesener, Michael; Hepp, Alexander
A Carbon-Bridged Digallium Compound as a Chelating Lewis Acid: Complexation of Thiophenolate and Benzoate Anions by H5C6−CH2−C(SiMe3)[Ga(CH2tBu)2]2
Organometallics, 2008, 27, 2118
4071265 CIFC56.5 H101 Ga2 N S SiP 1 21/n 114.202; 20.403; 21.021
90; 95.521; 90
6062.9Uhl, Werner; Claesener, Michael; Hepp, Alexander
A Carbon-Bridged Digallium Compound as a Chelating Lewis Acid: Complexation of Thiophenolate and Benzoate Anions by H5C6−CH2−C(SiMe3)[Ga(CH2tBu)2]2
Organometallics, 2008, 27, 2118
4071266 CIFC54 H101 Ga2 N O2 SiP 1 21/n 111.4755; 21.41; 23.672
90; 90.414; 90
5815.8Uhl, Werner; Claesener, Michael; Hepp, Alexander
A Carbon-Bridged Digallium Compound as a Chelating Lewis Acid: Complexation of Thiophenolate and Benzoate Anions by H5C6−CH2−C(SiMe3)[Ga(CH2tBu)2]2
Organometallics, 2008, 27, 2118
4071267 CIFC20 H40 Br2 N2 O4 Zn2P 1 21/n 110.687; 8.8254; 14.8247
90; 99.537; 90
1378.9Greco, Jeffrey F.; McNevin, Michael J.; Shoemaker, Richard K.; Hagadorn, John R.
Solid- and Solution-Phase Structures of Zinc Enolates of Amides and Ketones
Organometallics, 2008, 27, 1948
4071272 CIFC37 H34 N VP 1 21/n 19.5142; 30.774; 10.501
90; 116.33; 90
2755.6Liu, Guohua; Lu, Xiaoquan; Gagliardo, Marcella; Beetstra, Dirk J.; Meetsma, Auke; Hessen, Bart
Vanadium (β-(Dimethylamino)ethyl)cyclopentadienyl Complexes with Diphenylacetylene Ligands
Organometallics, 2008, 27, 2316
4071287 CIFC20 H18 Al2 F12 O2P 1 21/n 19.972; 7.6787; 17.488
90; 92.638; 90
1337.7Martínez, Gema; Pedrosa, Sergio; Tabernero, Vanessa; Mosquera, Marta E. G.; Cuenca, Tomás
Controlled Synthesis of Novel Aryloxide Polynuclear Aluminum Species. Study of Their Catalytic Properties in Polymerization Processes†
Organometallics, 2008, 27, 2300
4071303 CIFC32 H32 Cl N2 O3 VP 1 21/n 112.3342; 13.3442; 17.9276
90; 103.048; 90
2874.5Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071304 CIFC42 H52 Cl N2 O3 VP 1 21/n 111.6439; 22.3741; 14.8894
90; 93.753; 90
3870.7Wu, Ji-Qian; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis, Structural Characterization, and Ethylene Polymerization Behavior of the Vanadium(III) Complexes Bearing Salicylaldiminato Ligands
Organometallics, 2008, 27, 3840
4071318 CIFC24 H50 N4 P2 Si2 SnP 1 21/n 112.667; 21.268; 13.067
90; 111.222; 90
3281.5Leung, Wing-Por; Chan, Ka-Po; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heteroleptic Tin(II) and Lead(II) Compounds from Pyrazyl-Linked Bisphosphoranoimine
Organometallics, 2008, 27, 2767
4071322 CIFC25 H40 Cl N2 P PtP 1 21/n 112.6781; 10.0244; 20.893
90; 102.328; 90
2594.07Vuzman, Dana; Poverenov, Elena; Shimon, Linda J. W.; Diskin-Posner, Yael; Milstein, David
Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization
Organometallics, 2008, 27, 2627
4071323 CIFC15 H24 B Cl2 Hf NP 1 21/n 18.7643; 13.545; 15.1449
90; 105.048; 90
1736.2Fang, Xiangdong; Assoud, Jalil
Anionic Multisubstituted 1,2-Azaborolyl Ligands: Syntheses, Characterization, and Coordination Chemistry
Organometallics, 2008, 27, 2408
4071326 CIFC24 H25 Cl F3 N2 RhP 1 21/n 111.7872; 16.2148; 11.9178
90; 102.218; 90
2226.22Song, Guoyong; Zhang, Yao; Li, Xingwei
Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine
Organometallics, 2008, 27, 1936
4071327 CIFC59 H69 Cl15 I6 N8 Rh2P 1 21/n 121.4732; 18.5585; 21.8116
90; 94.105; 90
8669.8Yang, Liangru; Krüger, Anneke; Neels, Antonia; Albrecht, Martin
Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation
Organometallics, 2008, 27, 3161
4071348 CIFC44 H54 Cl2 N5 TiP 1 21/n 115.1103; 11.5282; 24.8172
90; 93.401; 90
4315.4Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071359 CIFC19 H26 Ir NP 1 21/n 18.612; 22.988; 9.451
90; 112.772; 90
1725Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071360 CIFC31 H34 Ir N O2P 1 21/n 110.922; 19.511; 12.677
90; 95.293; 90
2689.9Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071363 CIFC32 H60 O17 P3 Re SnP 1 21/n 110.7012; 22.898; 20.818
90; 93.557; 90
5091.3Albertin, Gabriele; Antoniutti, Stefano; Castro, Jesús; Fontán, Soledad García; Zanardo, Gianluigi
Preparation of Trivinylstannyl Complexes of Manganese and Rhenium
Organometallics, 2008, 27, 2789
4071368 CIFC22 H49 I Si4 SnP 1 21/n 111.6583; 16.829; 16.076
90; 105.156; 90
3044.4Kavara, Ajdin; Kampf, Jeff W.; Banaszak Holl, Mark M.
Direct Formation of Propargyltin Compounds via C−H Activation
Organometallics, 2008, 27, 2896
4071375 CIFC55 H77 N O4 ZrP 1 21/n 115.8272; 16.9637; 19.1982
90; 107.911; 90
4904.7Agapie, Theodor; Henling, Lawrence M.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Bercaw, John E.
Zirconium and Titanium Complexes Supported by Tridentate LX2Ligands Having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization
Organometallics, 2008, 27, 6245
4071379 CIFC30 H32 Cl Cu P2P 1 21/n 19.0865; 21.048; 14.503
90; 100.17; 90
2730.2Daly, Stephen; Haddow, Mairi F.; Orpen, A. Guy; Rolls, Giles T. A.; Wass, Duncan F.; Wingad, Richard L.
Copper(I) Diphosphine Catalysts for C−N Bond Formation: Synthesis, Structure, and Ligand Effects
Organometallics, 2008, 27, 3196
4071390 CIFC17 H26 N3 Rh SP 1 21/n 111.936; 8.874; 16.722
90; 97.1; 90
1757.6Gil, Wojciech; Trzeciak, Anna M.; Ziółkowski, Józef J.
Rhodium(I) N-Heterocyclic Carbene Complexes as Highly Selective Catalysts for 1-Hexene Hydroformylation
Organometallics, 2008, 27, 4131
4071396 CIFC44 H76 Cl4 Cr2 N6 Si2P 1 21/n 112.3769; 12.9565; 16.8703
90; 109.259; 90
2553.9Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Chromium Complexes with Me2Si-Bridged Cyclopentadienyl-imidazolin-2-imine Ligands: Synthesis, Structure, and Use in Ethylene Polymerization Catalysis
Organometallics, 2008, 27, 3232
4071405 CIFC46 H46 P2 Rh Si2P 1 21/n 110.7863; 17.5377; 21.737
90; 101.979; 90
4022.4Sunada, Yusuke; Fujimura, Yoshiki; Nagashima, Hideo
“Synergistic Effects of Two Si−H Groups and a Metal Center” in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules: A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene
Organometallics, 2008, 27, 3502
4071438 CIFC54 H90 O2 Si2 Y2P 1 21/n 113.2388; 10.2802; 20.5965
90; 91.044; 90
2802.7Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071439 CIFC54 H90 Dy2 O2 Si2P 1 21/n 113.211; 10.2343; 20.566
90; 91.11; 90
2780.1Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071440 CIFC54 H90 Lu2 O2 Si2P 1 21/n 113.0585; 10.1678; 20.55
90; 91.842; 90
2727.1Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071443 CIFC58 H90 Lu2 O10 Si2P 1 21/n 112.2388; 16.5089; 15.1412
90; 91.539; 90
3058.2Cui, Dongmei; Nishiura, Masayoshi; Tardif, Olivier; Hou, Zhaomin
Rare-Earth-Metal Mixed Hydride/Aryloxide Complexes Bearing Mono(cyclopentadienyl) Ligands. Synthesis, CO2Fixation, and Catalysis on Copolymerization of CO2with Cyclohexene Oxide
Organometallics, 2008, 27, 2428
4071445 CIFC34 H41 Cu N2 O2P 1 21/n 122.2579; 12.4609; 22.7399
90; 104.602; 90
6103.3Bhattacharyya, Koyel X.; Akana, Jennifer A.; Laitar, David S.; Berlin, Jacob M.; Sadighi, Joseph P.
Carbon−Carbon Bond Formation on Reaction of a Copper(I) Stannyl Complex with Carbon Dioxide
Organometallics, 2008, 27, 2682
4071466 CIFC23 H30 Ag Br N2P 1 21/n 18.4959; 19.0544; 13.9272
90; 104.775; 90
2180.05Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071468 CIFC27 H30 Ag Br N2P 1 21/n 19.902; 17.068; 15.94
90; 107.68; 90
2566.7Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071469 CIFC21 H19 F6 N2 PP 1 21/n 112.038; 12.986; 12.608
90; 97.311; 90
1954.9Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071477 CIFC28 H51 Cl2 Ir2 N3P 1 21/n 18.5172; 19.806; 17.3502
90; 90.554; 90
2926.7Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071485 CIFC37 H51 Cl N2 OsP 1 21/n 116.127; 12.312; 18.753
90; 114.684; 90
3383.3Castarlenas, Ricardo; Esteruelas, Miguel A.; Oñate, Enrique
Preparation, X-ray Structure, and Reactivity of an Osmium-Hydroxo Complex Stabilized by an N-Heterocyclic Carbene Ligand: A Base-Free Catalytic Precursor for Hydrogen Transfer from 2-Propanol to Aldehydes
Organometallics, 2008, 27, 3240
4071493 CIFC20 H49 Al Si4P 1 21/n 110.0479; 12.8181; 23.5244
90; 101.95; 90
2964.16Uhl, Werner; Er, Elif; Hepp, Alexander; Kösters, Jutta; Grunenberg, Jörg
Reactions of Terminal Alkynes with a Bulky Dialkylaluminum Hydride: Hydroalumination versus Deprotonation
Organometallics, 2008, 27, 3346
4071504 CIFC54 H56 B Cl2 F10 N2 O3 P3 RuP 1 21/n 112.046; 20.6031; 20.3481
90; 92.702; 90
5044.5Santoro, Francesco; Althaus, Martin; Bonaccorsi, Cristina; Gischig, Sebastian; Mezzetti, Antonio
Acidic Ruthenium PNNP Complexes of Non-enolized 1,3-Dicarbonyl Compounds as Catalysts for Asymmetric Michael Addition
Organometallics, 2008, 27, 3866
4071510 CIFC37 H35 Cl N5 O P Ru SP 1 21/n 116.3548; 11.1683; 19.8291
90; 107.635; 90
3451.7Zeng, Fanlong; Yu, Zhengkun
Exceptionally Efficient Unsymmetrical Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Based Pyrazolyl−Imidazolyl Ligand for Transfer Hydrogenation of Ketones
Organometallics, 2008, 27, 2898
4071517 CIFC49 H58 F6 N4 O10 Pd2 S2P 1 21/n 115.7388; 20.4783; 16.6344
90; 93.788; 90
5349.6Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4071524 CIFC43 H37 Fe N2 O3 ReP 1 21/n 116.0242; 12.0532; 19.8283
90; 101.457; 90
3753.4Packheiser, Rico; Ecorchard, Petra; Rüffer, Tobias; Lohan, Manja; Bräuer, Björn; Justaud, Frédéric; Lapinte, Claude; Lang, Heinrich
Heterotrimetallic M−M′−M′′ Transition Metal Complexes Based on 1,3,5-Triethynylbenzene: Synthesis, Solid State Structure, and Electrochemical and UV−Vis Characterization. EPR Analysis of thein SituGenerated Associated Radical Cations
Organometallics, 2008, 27, 3444
4071525 CIFC80 H67 Cl4 Fe N2 O3 P2 Pt ReP 1 21/n 123.2869; 12.9871; 24.1528
90; 93.857; 90
7288Packheiser, Rico; Ecorchard, Petra; Rüffer, Tobias; Lohan, Manja; Bräuer, Björn; Justaud, Frédéric; Lapinte, Claude; Lang, Heinrich
Heterotrimetallic M−M′−M′′ Transition Metal Complexes Based on 1,3,5-Triethynylbenzene: Synthesis, Solid State Structure, and Electrochemical and UV−Vis Characterization. EPR Analysis of thein SituGenerated Associated Radical Cations
Organometallics, 2008, 27, 3444
4071529 CIFC72 H74 B F24 Mo N2 O3.5P 1 21/n 118.4389; 21.1079; 18.8695
90; 95.313; 90
7312.6Jiang, Annie J.; Schrock, Richard R.; Müller, Peter
Cationic Molybdenum Imido Alkylidene Complexes
Organometallics, 2008, 27, 4428
4071530 CIFC67 H58 B F24 Mo N3P 1 21/n 124.9162; 18.826; 28.0325
90; 93.738; 90
13121.3Jiang, Annie J.; Schrock, Richard R.; Müller, Peter
Cationic Molybdenum Imido Alkylidene Complexes
Organometallics, 2008, 27, 4428
4071531 CIFC48 H57 Mo N3P 1 21/n 111.379; 19.8001; 18.8237
90; 99; 90
4188.9Jiang, Annie J.; Schrock, Richard R.; Müller, Peter
Cationic Molybdenum Imido Alkylidene Complexes
Organometallics, 2008, 27, 4428
4071532 CIFC70 H68 B F30 Mo N O4P 1 21/n 116.2; 22.5; 20.048
90; 96.045; 90
7266.9Jiang, Annie J.; Schrock, Richard R.; Müller, Peter
Cationic Molybdenum Imido Alkylidene Complexes
Organometallics, 2008, 27, 4428
4071540 CIFC32 H62 Br Mn2 O5 S2 Si2P 1 21/n 18.8106; 17.3613; 27.1951
90; 92.666; 90
4155.4Kückmann, Theresa I.; Schödel, Frauke; Sänger, Inge; Bolte, Michael; Wagner, Matthias; Lerner, Hans-Wolfram
Mixed-Valence Manganese Carbonyl Complexes with Supersilyl Thiolate Ligands: [(OC)4Mn(μ-SSitBu3)2Mn(THF)X] (X = Br, SSitBu3) and Na(THF)6[(OC)3Mn(μ-SSitBu3)3MnSSitBu3]
Organometallics, 2008, 27, 3272
4071541 CIFC28 H46 Cl2 N P2 Rh SiP 1 21/n 114.0161; 13.1551; 17.3099
90; 100.205; 90
3141.2Gatard, Sylvain; Chen, Chun-Hsing; Foxman, Bruce M.; Ozerov, Oleg V.
Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh Fragment
Organometallics, 2008, 27, 6257
4071545 CIFC30 H50 O Si4P 1 21/n 118.4637; 16.9235; 18.3509
90; 35.985; 90
3369.21Naka, Akinobu; Ueda, Shinsuke; Ohshita, Joji; Kunai, Atsutaka; Miura, Toshiko; Kobayashi, Hisayoshi; Ishikawa, Mitsuo
Silicon−Carbon Unsaturated Compounds. 75. Thermal Isomerization of 2-Alkyl- and 2-Aryl-2-trimethylsiloxy-1,1-bis(trimethylsilyl)-1-silacyclohex-4-enes
Organometallics, 2008, 27, 2922
4071548 CIFC58 H74.5 B Cl2 Ru2P 1 21/n 111.5277; 12.1013; 35.559
90; 95.199; 90
4940.1Zhang, Li; Sung, Herman Ho-Yung; Williams, Ian Duncan; Lin, Zhenyang; Jia, Guochen
Reactions of Cp*RuCl(COD) with Alkynes: Isolation of Dinuclear Metallacyclopentatriene Complexes
Organometallics, 2008, 27, 5122
4071560 CIFC30 H42 F10 O6 Ti2P 1 21/n 18.969; 16.822; 12.0463
90; 96.564; 90
1805.6Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4071563 CIFC22 H8 B F15 OP 1 21/n 114.2611; 11.2276; 14.7056
90; 115.967; 90
2116.9Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4071564 CIFC64 H136 N4 O14 Zr4P 1 21/n 114.1142; 15.6865; 18.9583
90; 103.676; 90
4078.4Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4071589 CIFC35.5 H53 B Cl2 N3 O4 ZrP 1 21/n 113.225; 10.845; 26.35
90; 97.86; 90
3744Dunne, James F.; Su, Jiachun; Ellern, Arkady; Sadow, Aaron D.
A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes
Organometallics, 2008, 27, 2399
4071590 CIFC21 H29.5 B N3 O3.25P 1 21/n 117.756; 14.0182; 19.789
90; 108.613; 90
4668Dunne, James F.; Su, Jiachun; Ellern, Arkady; Sadow, Aaron D.
A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes
Organometallics, 2008, 27, 2399
4071591 CIFC49 H41 N P2 RuP 1 21/n 18.835; 18.386; 24.034
90; 94.517; 90
3891.96Chou, Hsien-Hsin; Lin, Ying-Chih; Huang, Shou-Ling; Liu, Yi-Hong; Wang, Yu
Reactions of Ruthenium Acetylide and Vinylidene Complexes Containing a 2-Pyridyl Group
Organometallics, 2008, 27, 5212
4071602 CIFC44 H23 As2 B Cl4 F15 N PdP 1 21/n 114.085; 13.568; 25.932
90; 104.72; 90
4793.1Casares, Juan A.; Espinet, Pablo; Salas, Gorka
Palladium Catalysts for Norbornene Polymerization. A Study by NMR and Calorimetric Methods
Organometallics, 2008, 27, 3761
4071610 CIFC32 H51 Ge N2 P SiP 1 21/n 18.9098; 19.6084; 19.6505
90; 90.364; 90
3433Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071611 CIFC45 H79 Ge N2 P Si2P 1 21/n 111.5933; 22.8578; 18.3221
90; 93.233; 90
4847.6Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071613 CIFC30 H41 F3 Ge N2 O3 SP 1 21/n 112.087; 13.013; 24.046
90; 92.11; 90
3779.6Yao, Shenglai; Brym, Markus; Merz, Klaus; Driess, Matthias
Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2Group and Related PR2Derivatives
Organometallics, 2008, 27, 3601
4071630 CIFC34 H24 B FP 1 21/n 110.975; 9.582; 24.482
90; 97.028; 90
2555So, Cheuk-Wai; Watanabe, Daisuke; Wakamiya, Atsushi; Yamaguchi, Shigehiro
Synthesis and Structural Characterization of Pentaarylboroles and Their Dianions
Organometallics, 2008, 27, 3496
4071637 CIFC28 H36 Cl N3 O1.5 RuP 1 21/n 112.033; 15.396; 28.972
90; 91.024; 90
5366Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071639 CIFC24 H24 F6 N4 O7 Ru S2P 1 21/n 19.7732; 25.207; 11.618
90; 94.443; 90
2853.5Araki, Kenjirou; Kuwata, Shigeki; Ikariya, Takao
Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol
Organometallics, 2008, 27, 2176
4071670 CIFC18 H16 N P SP 1 21/n 112.4129; 7.3039; 17.1658
90; 99.485; 90
1535.02Kling, Christian; Ott, Holger; Schwab, Gerald; Stalke, Dietmar
Heteroaromatic Substituted Phosphoranes with Enhanced Hemilabile Character
Organometallics, 2008, 27, 5038
4071671 CIFC18 H16 N P SeP 1 21/n 112.6149; 7.2983; 17.4007
90; 100.102; 90
1577.2Kling, Christian; Ott, Holger; Schwab, Gerald; Stalke, Dietmar
Heteroaromatic Substituted Phosphoranes with Enhanced Hemilabile Character
Organometallics, 2008, 27, 5038
4071681 CIFC44 H30 N8 Na2P 1 21/n 114.418; 15.3044; 16.7139
90; 109.206; 90
3482.8Jiang, Huiling; Song, Datong
Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)
Organometallics, 2008, 27, 3587
4071693 CIFC21 H34 B10 N PP 1 21/n 111.2939; 11.0589; 20.992
90; 104.995; 90
2532.6Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4071694 CIFC21 H34 B10 N O PP 1 21/n 111.29; 10.9564; 21.1161
90; 105.089; 90
2522Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4071695 CIFC33 H60 B10 N3 O3 P ZrP 1 21/n 19.0355; 26.3259; 17.607
90; 95.732; 90
4167.2Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4071698 CIFC43 H44 B9 D18 K N3 O P TiP 1 21/n 110.5092; 26.7479; 17.1051
90; 100.61; 90
4726Wang, Hong; Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2−and [(C13H9)(iPr2N)P(O)(C2B9H10)]2−
Organometallics, 2008, 27, 3964
4071703 CIFC21 H25 Br2 Cl3 N4 O PtP 1 21/n 113.0583; 10.2477; 18.945
90; 103.107; 90
2469.13Kelly, Mairéad E.; Dietrich, Andrea; Gómez-Ruiz, Santiago; Kalinowski, Bernd; Kaluderović, Goran N.; Müller, Thomas; Paschke, Reinhard; Schmidt, Jürgen; Steinborn, Dirk; Wagner, Christoph; Schmidt, Harry
Platinum(IV) Metallacrown Ethers: Synthesis, Structures, Host Properties and Anticancer Evaluation
Organometallics, 2008, 27, 4917
4071718 CIFC30 H29 Ni3P 1 21/n 116.393; 9.319; 17.292
90; 109.71; 90
2487Buchalski, Piotr; Jadach, Patryk; Pietrzykowski, Antoni; Suwińska, Kinga; Jerzykiewicz, Lucjan; Sadło, Jarosław
Products of the Reaction of 9-Nickelafluorenyllithium Complexes with Water
Organometallics, 2008, 27, 3618
4071724 CIFC14 H16 FeP 1 21/n 19.8523; 7.6564; 15.4974
90; 106.337; 90
1121.82Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki
Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†
Organometallics, 2008, 27, 5279
4071732 CIFC22 H36 Cl3 P Ru2P 1 21/n 18.8726; 14.5203; 19.0631
90; 96.1559; 90
2441.79Miyake, Yoshihiro; Endo, Satoshi; Nomaguchi, Yohei; Yuki, Masahiro; Nishibayashi, Yoshiaki
Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Catalytic Activity toward Reactions of Propargylic Alcohols with Aromatic Compounds
Organometallics, 2008, 27, 4017
4071756 CIFC41 H51 O4.5 Ru2P 1 21/n 18.6409; 33.732; 13.1044
90; 103.598; 90
3712.54Takao, Toshiro; Akiyoshi, Kazunori; Suzuki, Hiroharu
Preparation and Properties of Diruthenium Hydrido Complexes Having a Bridging Benzoquinone Ligand: Formation of an Alcohol Adduct of a μ-η2:η2-Benzoquinone Complex through Hydrogen Bonding
Organometallics, 2008, 27, 4199
4071758 CIFC117 H178 N6 O2 Si Y3P 1 21/n 125.7685; 15.7564; 29.3881
90; 106.599; 90
11434.9Lyubov, Dmitrii M.; Döring, Christian; Fukin, Georgii K.; Cherkasov, Anton V.; Shavyrin, Andrei S.; Kempe, Rhett; Trifonov, Alexander A.
Selective Assembly of Trinuclear Rare-Earth Alkyl Hydrido Clusters Supported by Amidopyridinate Ligands
Organometallics, 2008, 27, 2905
4071792 CIFC43 H42 Cl Fe N P2P 1 21/n 111.9115; 19.3856; 15.7925
90; 92.116; 90
3644.18Justaud, Frédéric; Argouarch, Gilles; Ghazala, Safaa Ibn; Toupet, Loic; Paul, Frédéric; Lapinte, Claude
Novel Straightforward Access to a 2,2′-Bipyridine Ligand Bearing Two “(η2-dppe)(η5-C5Me5)FeCC−” Redox-Active Substituents by Homocoupling of Mononuclear Organoiron(II) 2-Bromopyridyl Synthons
Organometallics, 2008, 27, 4260
4071793 CIFC43 H42 Br Fe N P2P 1 21/n 112.0166; 19.3821; 16.1491
90; 92.543; 90
3757.5Justaud, Frédéric; Argouarch, Gilles; Ghazala, Safaa Ibn; Toupet, Loic; Paul, Frédéric; Lapinte, Claude
Novel Straightforward Access to a 2,2′-Bipyridine Ligand Bearing Two “(η2-dppe)(η5-C5Me5)FeCC−” Redox-Active Substituents by Homocoupling of Mononuclear Organoiron(II) 2-Bromopyridyl Synthons
Organometallics, 2008, 27, 4260
4071801 CIFC55 H49 Cl2 N4 RhP 1 21/n 115.5087; 18.651; 16.2663
90; 106.993; 90
4499.7Chan, Yun Wai; Chan, Kin Shing
Base-Promoted Carbon−Hydrogen Bond Activation of Alkanes with Rhodium(III) Porphyrin Complexes
Organometallics, 2008, 27, 4625
4071802 CIFC55 H51 N4 O RhP 1 21/n 115.579; 18.482; 16.155
90; 107.516; 90
4435.8Chan, Yun Wai; Chan, Kin Shing
Base-Promoted Carbon−Hydrogen Bond Activation of Alkanes with Rhodium(III) Porphyrin Complexes
Organometallics, 2008, 27, 4625
4071807 CIFC64 H40 B F24 Mo O2 PP 1 21/n 115.371; 24.095; 17.319
90; 106.67; 90
6144.8Cheng, Tan-Yun; Szalda, David J.; Hanson, Jonathan C.; Muckerman, James T.; Bullock, R. Morris
Four-Electron-Donor Hemilabile η3-PPh3Ligand that Binds through a CC Bond Rather than an Agostic C−H Interaction, and Displacement of the CC by Methyl Iodide or Water
Organometallics, 2008, 27, 3785
4071810 CIFC21 H36 Ir O2 PP 1 21/n 113.16; 8.4206; 19.586
90; 105.452; 90
2092Jiménez, M. Victoria; Rangel-Salas, I. Idalia; Lahoz, Fernando J.; Oro, Luis A.
C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds§
Organometallics, 2008, 27, 4229
4071811 CIFC24 H36 Ir O2 PP 1 21/n 17.9252; 29.893; 9.7153
90; 102.441; 90
2247.6Jiménez, M. Victoria; Rangel-Salas, I. Idalia; Lahoz, Fernando J.; Oro, Luis A.
C−C Formation and C−O Cleavage Reactions on Hemilabile Arene−Phosphine Ligands in Route to η5-Cyclohexadienyl Iridium Compounds§
Organometallics, 2008, 27, 4229
4071819 CIFC52 H54 F6 N6 P RhP 1 21/n 117.9389; 15.8145; 18.7496
90; 117.49; 90
4718.6Peng, Hong Mei; Webster, Richard D.; Li, Xingwei
Quinoline-Tethered N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Synthesis, Catalysis, and Electrochemical Properties
Organometallics, 2008, 27, 4484
4071821 CIFC34 H43 F6 N3 O P RhP 1 21/n 111.2937; 27.1335; 11.4634
90; 105.052; 90
3392.29Peng, Hong Mei; Webster, Richard D.; Li, Xingwei
Quinoline-Tethered N-Heterocyclic Carbene Complexes of Rhodium and Iridium: Synthesis, Catalysis, and Electrochemical Properties
Organometallics, 2008, 27, 4484
4071822 CIFC72 H106 K2 N4 O4 Zn2P 1 21/n 113.4672; 20.206; 14.0769
90; 91.367; 90
3829.5Yu, Jie; Yang, Xiao-Juan; Liu, Yanyan; Pu, Zhifeng; Li, Qian-Shu; Xie, Yaoming; Schaefer, Henry F.; Wu, Biao
Dinuclear versus Mononuclear Zinc Compounds from Reduction of LZnCl2(L = α-Diimine Ligands): Effects of the Ligand Substituent, Reducing Agent, and Solvent
Organometallics, 2008, 27, 5800
4071823 CIFC48 H68 N4 Na2 O2 ZnP 1 21/n 111.5189; 23.1977; 18.0425
90; 96.279; 90
4792.3Yu, Jie; Yang, Xiao-Juan; Liu, Yanyan; Pu, Zhifeng; Li, Qian-Shu; Xie, Yaoming; Schaefer, Henry F.; Wu, Biao
Dinuclear versus Mononuclear Zinc Compounds from Reduction of LZnCl2(L = α-Diimine Ligands): Effects of the Ligand Substituent, Reducing Agent, and Solvent
Organometallics, 2008, 27, 5800
4071827 CIFC30.33 H33.67 Cl4.67 P Ru2P 1 21/n 19.5465; 19.3372; 17.5203
90; 104.265; 90
3134.57Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071831 CIFC25 H41 Cl2 P RuP 1 21/n 110.2138; 18.8352; 13.6626
90; 111.811; 90
2440.24Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071832 CIFC29 H30 Cl8 P Ru2P 1 21/n 119.7274; 9.6194; 20.4425
90; 118.446; 90
3410.9Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071834 CIFC24 H38 Cl5 Ir2 N3P 1 21/n 112.5314; 15.3256; 16.6218
90; 106.641; 90
3058.5Zanardi, Alessandro; Corberán, Rosa; Mata, José A.; Peris, Eduardo
Homo- and Heterodinuclear Complexes with Triazolyl-diylidene. An Easy Approach to Tandem Catalysts⊥
Organometallics, 2008, 27, 3570
4071835 CIFC24 H38 Cl5 Ir N3 RhP 1 21/n 112.5908; 15.2228; 16.6788
90; 106.813; 90
3060.13Zanardi, Alessandro; Corberán, Rosa; Mata, José A.; Peris, Eduardo
Homo- and Heterodinuclear Complexes with Triazolyl-diylidene. An Easy Approach to Tandem Catalysts⊥
Organometallics, 2008, 27, 3570
4071847 CIFC23 H43 Cl2 Fe N P2P 1 21/n 112.0831; 15.5084; 14.5049
90; 91.093; 90
2717.6Pelczar, Elizabeth M.; Emge, Thomas J.; Krogh-Jespersen, Karsten; Goldman, Alan S.
Unusual Structural and Spectroscopic Features of Some PNP-Pincer Complexes of Iron
Organometallics, 2008, 27, 5759
4071848 CIFC11 H22 N4 O2 SiP 1 21/n 18.437; 12.084; 14.081
90; 90.94; 90
1435.4Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071851 CIFC25 H28 N4 O2 SiP 1 21/n 19.0893; 20.272; 12.872
90; 103.255; 90
2308.6Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071853 CIFC25 H30 N4 O2 SiP 1 21/n 114.293; 10.3528; 15.528
90; 99.007; 90
2269.4Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
Organometallics, 2008, 27, 5285
4071859 CIFC25 H39 B N8 O5.5 P WP 1 21/n 120.548; 13.322; 22.697
90; 94.58; 90
6193Kosturko, George W.; Graham, Peter M.; Myers, William H.; Smith, Timothy M.; Sabat, Michal; Harman, W. Dean
Tungsten-Promoted Diels−Alder Cycloaddition of Pyridines: Dearomatization of 2,6-Dimethoxypyridine Generates a Potent 2-Azadiene Synthon
Organometallics, 2008, 27, 4513
4071860 CIFC26 H37 B Cl3 N8 O7 P WP 1 21/n 111.5691; 13.0081; 23.9368
90; 102.98; 90
3510.3Kosturko, George W.; Graham, Peter M.; Myers, William H.; Smith, Timothy M.; Sabat, Michal; Harman, W. Dean
Tungsten-Promoted Diels−Alder Cycloaddition of Pyridines: Dearomatization of 2,6-Dimethoxypyridine Generates a Potent 2-Azadiene Synthon
Organometallics, 2008, 27, 4513
4071863 CIFC30 H38 Ge2 P2 PdP 1 21/n 112.063; 19.635; 13.47
90; 105.616; 90
3072.7Tanabe, Makoto; Ishikawa, Naoko; Hanzawa, Masaya; Osakada, Kohtaro
Mono- and Dinuclear Germapalladacycles Obtained via the Ge−Ge Bond Forming Reactions Promoted by Palladium Complexes
Organometallics, 2008, 27, 5152
4071880 CIFC14 H30 Cl N Pt Si2P 1 21/n 18.513; 9.243; 25.006
90; 97.385; 90
1951.29Arunachalampillai, Athimoolam; Johnson, Magnus T.; Wendt, Ola F.
Synthesis of a Platinum(II) Bis(trimethylsilyl)amido Complex: A Better Starting Material for the Cyclometalation of Pincer Ligands
Organometallics, 2008, 27, 4541
4071887 CIFC56.5 H45.5 Cl5.5 O P2 RhP 1 21/n 110.5211; 21.0544; 23.1205
90; 97.247; 90
5080.6Kaganovsky, Luba; Cho, Kyung-Bin; Gelman, Dmitri
New Trans-Chelating Ligands and Their Complexes and Catalytic Properties in the Mizoroki−Heck Arylation of Cyclohexene
Organometallics, 2008, 27, 5139
4071888 CIFC61 H51 B Cl9 F4 P2 RhP 1 21/n 111.0563; 26.6545; 20.6206
90; 104.7; 90
5878Kaganovsky, Luba; Cho, Kyung-Bin; Gelman, Dmitri
New Trans-Chelating Ligands and Their Complexes and Catalytic Properties in the Mizoroki−Heck Arylation of Cyclohexene
Organometallics, 2008, 27, 5139
4071896 CIFC13 H23 Cl PdP 1 21/n 16.4359; 12.0616; 17.4155
90; 96.456; 90
1343.34Esposito, Oriana; Gois, Pedro M. P.; de K. Lewis, Alexandra K.; Caddick, Stephen; Cloke, F. Geoffrey N.; Hitchcock, Peter B.
Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties
Organometallics, 2008, 27, 6411
4071909 CIFC40 H45 N UP 1 21/n 19.7134; 21.99; 16.212
90; 104.659; 90
3350.1Graves, Christopher R.; Scott, Brian L.; Morris, David E.; Kiplinger, Jaqueline L.
Tetravalent and Pentavalent Uranium Acetylide Complexes Prepared by Oxidative Functionalization with CuCCPh
Organometallics, 2008, 27, 3335
4071911 CIFC61 H78 Ge O7 Os3 P2 PtP 1 21/n 117.5041; 19.0187; 19.5406
90; 102.623; 90
6347.9Adams, Richard D.; Boswell, Erin M.; Hall, Michael B.; Yang, Xinzheng
Activation of Hydrogen and Related Small Molecules by the Unsaturated Cluster Complex PtOs3(CO)7(PBut3)(μ-PBut2)(μ4-CHCMeCH)
Organometallics, 2008, 27, 4938
4071913 CIFC32 H26 N4P 1 21/n 110.5224; 38.633; 11.9173
90; 102.497; 90
4729.7Lowry, Roxy J.; Veige, Melanie K.; Clément, Olivier; Abboud, Khalil A.; Ghiviriga, Ion; Veige, Adam S.
New Constrained-Geometry C2-Symmetric Di-N-heterocyclic Carbene Ligands and Their Mono- and Dinuclear Rhodium(I) Complexes: Design, Synthesis, and Structural Analysis
Organometallics, 2008, 27, 5184-5195
4071915 CIFC50 H54 Cl6 N4 Rh2P 1 21/n 112.4529; 22.822; 17.3074
90; 101.42; 90
4821.4Lowry, Roxy J.; Veige, Melanie K.; Clément, Olivier; Abboud, Khalil A.; Ghiviriga, Ion; Veige, Adam S.
New Constrained-Geometry C2-Symmetric Di-N-heterocyclic Carbene Ligands and Their Mono- and Dinuclear Rhodium(I) Complexes: Design, Synthesis, and Structural Analysis
Organometallics, 2008, 27, 5184-5195
4071925 CIFC34 H33 B N7 O2 P RuP 1 21/n 114.216; 13.421; 17.806
90; 102.204; 90
3320.5Leung, Chung Wing; Zheng, Wenxu; Zhou, Zhongyuan; Lin, Zhenyang; Lau, Chak Po
Mechanism of Catalytic Hydration of Nitriles with Hydrotris(pyrazolyl)borato (Tp) Ruthenium Complexes
Organometallics, 2008, 27, 4957
4071934 CIFC6 H22 B9 Cl S SiP 1 21/n 18.9214; 14.2968; 13.1606
90; 106.972; 90
1605.49Meshcheryakov, Vladimir I.; Zheng, Chong; Kudinov, Alexander R.; Maguire, John A.; Hosmane, Narayan S.
Silicon(IV) and Germanium(IV) Moieties Stabilized by the Charge-Compensated Carborane Ligand [9-SMe2-7,8-C2B9H10]−: Synthetic and Structural Investigation
Organometallics, 2008, 27, 5033
4071935 CIFC6 H22 B9 Cl Ge SP 1 21/n 18.8368; 12.8117; 14.1838
90; 90.913; 90
1605.6Meshcheryakov, Vladimir I.; Zheng, Chong; Kudinov, Alexander R.; Maguire, John A.; Hosmane, Narayan S.
Silicon(IV) and Germanium(IV) Moieties Stabilized by the Charge-Compensated Carborane Ligand [9-SMe2-7,8-C2B9H10]−: Synthetic and Structural Investigation
Organometallics, 2008, 27, 5033
4071942 CIFC46 H28 F8 N2 Ni P2P 1 21/n 114.8947; 16.9283; 15.86
90; 101.692; 90
3916Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4071944 CIFC37 H21.144 F8 O3.572 P2P 1 21/n 19.6431; 12.5819; 26.2617
90; 98.1043; 90
3154.47Bennett, Martin A.; Bhargava, Suresh K.; Keniry, Max A.; Privér, Steven H.; Simmonds, Peta M.; Wagler, Jörg; Willis, Anthony C.
A Triad of Bis(orthometalated) d8-Complexes Containing Four-Membered Rings
Organometallics, 2008, 27, 5361
4071953 CIFC51 H63 F Mg O7 SP 1 21/n 114.8665; 22.4247; 15.9899
90; 100.39; 90
5243.3Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970
4071963 CIFC54 H72 N4 NiP 1 21/n 112.734; 26.979; 14.039
90; 92.5494; 90
4818.3Matsubara, Kouki; Miyazaki, Satoshi; Koga, Yuji; Nibu, Yoshinori; Hashimura, Takaaki; Matsumoto, Taisuke
An Unsaturated Nickel(0) NHC Catalyst: Facile Preparation and Structure of Ni(0)(NHC)2, Featuring a Reduction Process from Ni(II)(NHC)(acac)2
Organometallics, 2008, 27, 6020
4071965 CIFC90 H96 Cl4 F12 N4 O24 Ru4 S4P 1 21/n 121.293; 10.919; 23.103
90; 91.099; 90
5370Han, Ying-Feng; Jia, Wei-Guo; Lin, Yue-Jian; Jin, Guo-Xin
Stepwise Formation of Molecular Rectangles of Half-Sandwich Rhodium and Ruthenium Complexes Containing Bridging Chloranilate Ligands
Organometallics, 2008, 27, 5002
4071968 CIFC41 H71 F5 P4 Pt2P 1 21/n 19.0267; 36.3908; 14.5404
90; 96.838; 90
4742.4de Quadras, Laura; Shelton, Abigail H.; Kuhn, Helene; Hampel, Frank; Schanze, Kirk S.; Gladysz, John A.
Syntheses, Structures, and Electronic and Photophysical Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C6F5)(R3P)2Pt, (p-tol)(R3P)2Pt, and (Ph3P)Au End-Groups
Organometallics, 2008, 27, 4979
4071971 CIFC43 H67 F5 P4 Pt2P 1 21/n 113.5959; 11.4504; 30.672
90; 90.788; 90
4774.52de Quadras, Laura; Shelton, Abigail H.; Kuhn, Helene; Hampel, Frank; Schanze, Kirk S.; Gladysz, John A.
Syntheses, Structures, and Electronic and Photophysical Properties of Unsymmetrically Substituted Butadiynediyl and Hexatriynediyl Complexes Derived from (C6F5)(R3P)2Pt, (p-tol)(R3P)2Pt, and (Ph3P)Au End-Groups
Organometallics, 2008, 27, 4979
4071983 CIFC70 H50 YbP 1 21/n 110.346; 13.4649; 18.1324
90; 95.586; 90
2513.99Deacon, Glen B.; Forsyth, Craig M.; Jaroschik, Florian; Junk, Peter C.; Kay, Danielle L.; Maschmeyer, Thomas; Masters, Anthony F.; Wang, Jun; Field, Leslie D.
Accessing Decaphenylmetallocenes of Ytterbium, Calcium, and Barium by Desolvation of Solvent-Separated Ion Pairs: Overcoming Adverse Solubility Properties#
Organometallics, 2008, 27, 4772
4071986 CIFC38 H38 K2 Mn4 N12 O14P 1 21/n 110.3347; 16.2699; 29.092
90; 91.446; 90
4890.1Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071987 CIFC46 H58 B2 Li2 N8 O8P 1 21/n 18.6293; 15.113; 18.731
90; 101.906; 90
2390.2Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071992 CIFC31 H24 B2 Cl2 Mn2 N12 O6P 1 21/n 115.5531; 14.6474; 16.5291
90; 103.423; 90
3662.7Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4072001 CIFC52 H80 Al2 Ca O6P 1 21/n 112.8483; 15.8241; 12.9309
90; 90; 90
2629.02Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4072002 CIFC56 H92 Al2 Ca O6P 1 21/n 112.5891; 16.7864; 13.8631
90; 93.245; 90
2924.93Krieck, Sven; Görls, Helmar; Westerhausen, Matthias
Synthesis and Properties of Calcium Tetraorganylalanates with [Me4−nAlPhn]−Anions
Organometallics, 2008, 27, 5052
4072003 CIFC31 H50 O P2 RuP 1 21/n 19.9048; 16.2576; 17.4663
90; 98.693; 90
2780.26Bolton, Paul D.; Grellier, Mary; Vautravers, Nicolas; Vendier, Laure; Sabo-Etienne, Sylviane
Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols
Organometallics, 2008, 27, 5088
4072015 CIFC36 H30 F N P2P 1 21/n 19.2235; 20.7854; 15.0618
90; 92.457; 90
2884.9Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4072019 CIFC20 H25 Cl3 Cr N5 OP 1 21/n 110.053; 16.831; 13.9668
90; 103.847; 90
2294.5Zhang, Jun; Braunstein, Pierre; Hor, T. S. Andy
Highly Selective Chromium(III) Ethylene Trimerization Catalysts with [NON] and [NSN] Heteroscorpionate Ligands
Organometallics, 2008, 27, 4277
4072028 CIFC25 H B Cu F21 N6 OP 1 21/n 19.415; 11.6353; 28.0159
90; 94; 90
3061.6Despagnet-Ayoub, Emmanuelle; Jacob, Kane; Vendier, Laure; Etienne, Michel; Álvarez, Eleuterio; Caballero, Ana; Díaz-Requejo, M. Mar; Pérez, Pedro J.
A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)
Organometallics, 2008, 27, 4779
4072029 CIFC25 H Ag B F21 N6 OP 1 21/n 19.311; 11.5542; 27.9217
90; 94.789; 90
2993.4Despagnet-Ayoub, Emmanuelle; Jacob, Kane; Vendier, Laure; Etienne, Michel; Álvarez, Eleuterio; Caballero, Ana; Díaz-Requejo, M. Mar; Pérez, Pedro J.
A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag)
Organometallics, 2008, 27, 4779
4072030 CIFC4 H22 B20P 1 21/n 17.0165; 9.8852; 12.375
90; 90.44; 90
858.3Ren, Shikuo; Xie, Zuowei
A Facile and Practical Synthetic Route to 1,1′-Bis(o-carborane)
Organometallics, 2008, 27, 5167
4072044 CIFC17 H37 Br Ni P2P 1 21/n 18.4858; 11.859; 20.8903
90; 90.796; 90
2102.05Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072046 CIFC23 H42 Ni P2P 1 21/n 110.1898; 12.5298; 19.3011
90; 97.936; 90
2440.7Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072047 CIFC20 H40 Ni P2P 1 21/n 110.8603; 14.5551; 14.1473
90; 92.175; 90
2234.7Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072053 CIFC17 H27 Cl2 N P Si TaP 1 21/n 111.3952; 14.8865; 13.2074
90; 106.379; 90
2149.51Ignatov, Stanislav K.; Rees, Nicholas H.; Merkoulov, Alexei A.; Dubberley, Stuart R.; Razuvaev, Alexei G.; Mountford, Philip; Nikonov, Georgii I.
Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies
Organometallics, 2008, 27, 5968
4072054 CIFC64 H100 N4 Na4 O2P 1 21/n 117.0908; 11.0256; 18.646
90; 113.231; 90
3228.7Liu, Yanyan; Yang, Peiju; Yu, Jie; Yang, Xiao-Juan; Zhang, Jun D.; Chen, Zhongfang; Schaefer, Henry F.; Wu, Biao
Sodium and Magnesium Complexes with Dianionic α-Diimine Ligands
Organometallics, 2008, 27, 5830
4072055 CIFC60 H96 N4 Na4 O4P 1 21/n 113.7512; 11.157; 21.709
90; 106.525; 90
3193.1Liu, Yanyan; Yang, Peiju; Yu, Jie; Yang, Xiao-Juan; Zhang, Jun D.; Chen, Zhongfang; Schaefer, Henry F.; Wu, Biao
Sodium and Magnesium Complexes with Dianionic α-Diimine Ligands
Organometallics, 2008, 27, 5830
4072056 CIFC30 H44 N2 Na2 O2P 1 21/n 110.4148; 20.699; 14.609
90; 107.828; 90
2998.1Liu, Yanyan; Yang, Peiju; Yu, Jie; Yang, Xiao-Juan; Zhang, Jun D.; Chen, Zhongfang; Schaefer, Henry F.; Wu, Biao
Sodium and Magnesium Complexes with Dianionic α-Diimine Ligands
Organometallics, 2008, 27, 5830
4072060 CIFC36 H48 Fe N3P 1 21/n 110.8956; 23.3911; 12.5814
90; 91.122; 90
3205.88Trovitch, Ryan J.; Lobkovsky, Emil; Bouwkamp, Marco W.; Chirik, Paul J.
Carbon−Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C−O Bond Cleavage in Esters
Organometallics, 2008, 27, 6264
4072066 CIFC32 H52 Cr N4 P2P 1 21/n 19.201; 21.91; 9.597
90; 113.947; 90
1768Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Duchateau, Robbert; Koç, Ece; Burchell, Tara J.
Preparation and Characterization of a Switchable Single-Component Chromium Trimerization Catalyst
Organometallics, 2008, 27, 5708
4072068 CIFC22 H28 O6 WP 1 21/n 19.816; 21.264; 11.675
90; 94.04; 90
2430.8Wang, Qifeng; Zhang, Wen-Xiong; Xi, Zhenfeng
Pyranylidene Carbene Complexes from 1-Lithio 1,3-Dienes and M(CO)6(M = Cr, Mo, W): Novel Synthesis and Demetalation Reaction
Organometallics, 2008, 27, 3627
4072070 CIFC22 H42 Cl O2 P PdP 1 21/n 113.573; 14.203; 14.125
90; 116.313; 90
2440.8Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072071 CIFC23 H44 Cl3 O2 P PdP 1 21/n 112.052; 10.073; 22.418
90; 104.159; 90
2639Takamiya, Ikuko; Yamashita, Makoto; Nozaki, Kyoko
Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated withtBu3P: Studies on the Insertion ofexo- andendo-Monomers in the Ester-Substituted Norbornene Polymerization
Organometallics, 2008, 27, 5347
4072074 CIFC12 H17 P SiP 1 21/n 16.3438; 18.0866; 10.472
90; 100.732; 90
1180.52Ochida, Atsuko; Hamasaka, Go; Yamauchi, Yoshihiro; Kawamorita, Soichiro; Oshima, Naoya; Hara, Kenji; Ohmiya, Hirohisa; Sawamura, Masaya
Synthesis, Properties, and Catalytic Applications of Caged, Compact Trialkylphosphine 4-Phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Organometallics, 2008, 27, 5494
4072084 CIFC52.4 H52.8 Cl0.8 N4 O10 Os4P 1 21/n 110.272; 22.8096; 24.0937
90; 94.131; 90
5630.5Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4072086 CIFC27 H14 N2 O14 Os5P 1 21/n 117.845; 10.7365; 19.3626
90; 116.698; 90
3314.2Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4072087 CIFC37 H28 N2 O15 Os6P 1 21/n 110.4402; 24.0703; 17.0669
90; 104.113; 90
4159.44Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4072100 CIFC91 H54 Cl2 F36 N4 O13 P2 Pt Yb2P 1 21/n 120.594; 18.854; 27.594
90; 92.108; 90
10707Xu, Hai-Bing; Ni, Jun; Chen, Kun-Jiao; Zhang, Li-Yi; Chen, Zhong-Ning
Preparation, Characterization, and Photophysical Properties ofcis- ortrans-PtLn2(Ln = Nd, Eu, Yb) Arrays with 5-Ethynyl-2,2′-bipyridine
Organometallics, 2008, 27, 5665
4072101 CIFC45 H25 F18 N2 O6 P Pt0.5 YbP 1 21/n 111.779; 27.718; 15.891
90; 94.628; 90
5171Xu, Hai-Bing; Ni, Jun; Chen, Kun-Jiao; Zhang, Li-Yi; Chen, Zhong-Ning
Preparation, Characterization, and Photophysical Properties ofcis- ortrans-PtLn2(Ln = Nd, Eu, Yb) Arrays with 5-Ethynyl-2,2′-bipyridine
Organometallics, 2008, 27, 5665
4072106 CIFC33 H45 F12 N5 O2 P2 RuP 1 21/n 110.237; 16.822; 22.528
90; 97.73; 90
3844.2Wong, Chun-Yuen; Lai, Lo-Ming; Lam, Chi-Yeung; Zhu, Nianyong
Ruthenium Carbene and Allenylidene Complexes Supported by the Tertiary Amine−Aromatic Diimine Ligand Set: Structural, Spectroscopic, and Theoretical Studies
Organometallics, 2008, 27, 5806
4072113 CIFC58 H94 N6 Si4 Zn2P 1 21/n 118.469; 21.213; 19.522
90; 117.927; 90
6758Piesik, Dirk F.-J.; Range, Sven; Harder, Sjoerd
Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization
Organometallics, 2008, 27, 6178
4072114 CIFC52 H88 N6 Si4 Zn2P 1 21/n 110.9191; 35.169; 18.4217
90; 95.451; 90
7042.2Piesik, Dirk F.-J.; Range, Sven; Harder, Sjoerd
Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization
Organometallics, 2008, 27, 6178
4072116 CIFC43 H61 N5 O4 S2 Zn2P 1 21/n 111.2229; 28.1674; 15.3663
90; 108.547; 90
4605.3Piesik, Dirk F.-J.; Range, Sven; Harder, Sjoerd
Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization
Organometallics, 2008, 27, 6178
4072117 CIFC22 H56 B2 P2 Pb Si2P 1 21/n 111.4175; 17.6207; 16.6197
90; 106.796; 90
3201Izod, Keith; McFarlane, William; Wills, Corinne; Clegg, William; Harrington, Ross W.
Agostic-Type B−H···Pb Interactions Stabilize a Dialkylplumbylene. Structure of and Bonding in [{nPr2P(BH3)}(Me3Si)C(CH2)]2Pb
Organometallics, 2008, 27, 4386
4072125 CIFC13 H31 B9 Co N SP 1 21/n 19.3712; 16.954; 12.8825
90; 97.711; 90
2028.3Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4072126 CIFC6 H15 B9 Fe O2 SP 1 21/n 16.7953; 13.234; 15.1439
90; 94.436; 90
1357.8Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4072127 CIFC39 H67 N3 O3 ZrP 1 21/n 118.4222; 23.949; 18.8965
90; 101.982; 90
8155.4Ning, Yalan; Zhang, Yuetao; Rodriguez-Delgado, Antonio; Chen, Eugene Y.-X.
Neutral Metallocene Ester Enolate and Non-Metallocene Alkoxy Complexes of Zirconium for Catalytic Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5632
4072149 CIFC39 H40 Cl5 N4 O2 P RuP 1 21/n 114.278; 18.997; 16.217
90; 115.07; 90
3984.3Kopf, Henning; Holzberger, Bastian; Pietraszuk, Cezary; Hübner, Eike; Burzlaff, Nicolai
Neutral Ruthenium Carbene Complexes bearing N,N,O Heteroscorpionate Ligands: Syntheses and Activity in Metathesis Reactions
Organometallics, 2008, 27, 5894
4072151 CIFC20 H30 I2 UP 1 21/n 18.5406; 16.293; 15.827
90; 98.717; 90
2176.9Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4072160 CIFC40 H66 N12 O11 Rh4P 1 21/n 116.4293; 8.8025; 17.288
90; 103.974; 90
2426.2Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072167 CIFC32 H42 N4 O4 Rh2P 1 21/n 18.3492; 12.2916; 14.5016
90; 90.191; 90
1488.22Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4072168 CIFC54 H44 P2 PtP 1 21/n 113.6022; 8.5341; 18.0885
90; 90.447; 90
2099.7Sadowy, Amber L.; Ferguson, Michael J.; McDonald, Robert; Tykwinski, Rik R.
Chiralcis-Platinum Acetylide Complexes via Diphosphine Ligand Exchange: Effect of the Ligand
Organometallics, 2008, 27, 6321
4072183 CIFC22 H32 F12 N2 O2P 1 21/n 17.3782; 22.163; 7.7542
90; 91.228; 90
1267.7Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4072185 CIFC14 H15 Al F12 N2 O3P 1 21/n 111.0304; 13.3518; 13.8804
90; 112.863; 90
1883.6Bouyahyi, Miloud; Grunova, Ekaterina; Marquet, Nicolas; Kirillov, Evgueni; Thomas, Christophe M.; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated Dialkoxy-Diimino Salen-like Ligands: Syntheses, Structures, and Use in Ring-Opening Polymerization of Cyclic Esters
Organometallics, 2008, 27, 5815
4072198 CIFC46 H64 N2 O P S Sc Si2P 1 21/n 112.2694; 26.4988; 14.3383
90; 93.135; 90
4654.8Wang, Dun; Li, Shihui; Liu, Xinli; Gao, Wei; Cui, Dongmei
Thiophene-NPN Ligand Supported Rare-Earth Metal Bis(alkyl) Complexes. Synthesis and Catalysis toward Highlytrans-1,4 Selective Polymerization of Butadiene
Organometallics, 2008, 27, 6531
4072200 CIFC50.5 H68 N2 O P Sc Si2P 1 21/n 113.1455; 25.6245; 14.6598
90; 91.278; 90
4936.9Wang, Dun; Li, Shihui; Liu, Xinli; Gao, Wei; Cui, Dongmei
Thiophene-NPN Ligand Supported Rare-Earth Metal Bis(alkyl) Complexes. Synthesis and Catalysis toward Highlytrans-1,4 Selective Polymerization of Butadiene
Organometallics, 2008, 27, 6531
4072202 CIFC48 H47 Br O6 P2 Pd S2P 1 21/n 113.392; 18.203; 19.051
90; 95.945; 90
4619.2Kimura, Tsutomu; Uozumi, Yasuhiro
Synthesis of [2,6-Bis(2-oxazolinyl)phenyl]palladium Complexes via the Ligand Introduction Route
Organometallics, 2008, 27, 5159
4072207 CIFC42 H54 Cl3 N3 PdP 1 21/n 110.3012; 20.3145; 19.4043
90; 98.103; 90
4020.1Broggi, Julie; Clavier, Hervé; Nolan, Steven P.
N-Heterocyclic Carbenes (NHCs) ContainingN-C-Palladacycle Complexes: Synthesis and Reactivity in Aryl Amination Reactions
Organometallics, 2008, 27, 5525
4072208 CIFC54 H56 B P Pd SP 1 21/n 115.9022; 12.5955; 23.306
90; 102.427; 90
4558.7Emslie, David J. H.; Harrington, Laura E.; Jenkins, Hilary A.; Robertson, Craig M.; Britten, James F.
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η3(BCC)-Triarylborane Coordination
Organometallics, 2008, 27, 5317
4072211 CIFC67 H94 B O P Pd S Si2P 1 21/n 117.16; 9.849; 36.227
90; 96.351; 90
6085Emslie, David J. H.; Harrington, Laura E.; Jenkins, Hilary A.; Robertson, Craig M.; Britten, James F.
Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η3(BCC)-Triarylborane Coordination
Organometallics, 2008, 27, 5317
4072215 CIFC89 H58 Cl7 O3 Rh3P 1 21/n 111.6158; 24.7527; 24.7806
90; 91.395; 90
7122.9Rechavi, Dalit; Scopelliti, Rosario; Severin, Kay
The Enigmatic Nature of RhICl(cyclopentadienone) Complexes: Dimers, Trimers, and Tetramers
Organometallics, 2008, 27, 5978
4072216 CIFC46 H46 Cl2 N2 O2 Rh2P 1 21/n 118.823; 9.3966; 23.578
90; 95.544; 90
4150.8Rechavi, Dalit; Scopelliti, Rosario; Severin, Kay
The Enigmatic Nature of RhICl(cyclopentadienone) Complexes: Dimers, Trimers, and Tetramers
Organometallics, 2008, 27, 5978
4072221 CIFC82 H101 B2 Br F24 N2 P2 PtP 1 21/n 115.5886; 14.4814; 38.158
90; 92.916; 90
8602.8Braunschweig, Holger; Radacki, Krzysztof; Uttinger, Katharina
Syntheses and Structures of Mono- and Dinuclear Cationic Base-Stabilized Platinum Borylene Complexes
Organometallics, 2008, 27, 6005
4072223 CIFC78 H125 B2 Br4 P3 PtP 1 21/n 114.9389; 24.4311; 21.7945
90; 90.988; 90
7953.2Braunschweig, Holger; Radacki, Krzysztof; Uttinger, Katharina
Syntheses and Structures of Mono- and Dinuclear Cationic Base-Stabilized Platinum Borylene Complexes
Organometallics, 2008, 27, 6005
4072239 CIFC24 H26 Cl2 N O4 TaP 1 21/n 18.9484; 10.9534; 24.7479
90; 98.5; 90
2399Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodríguez, Ana
Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
Organometallics, 2008, 27, 6090
4072242 CIFC43 H55 F3 N2 O16 S Ta2P 1 21/n 116.414; 13.115; 22.553
90; 106.737; 90
4649.3Conde, Ana; Fandos, Rosa; Otero, Antonio; Rodríguez, Ana
Oxo and Hydroxo Organometallic Complexes of Tantalum: Soluble Molecular Models of Tantalum Oxide
Organometallics, 2008, 27, 6090
4072250 CIFC88 H79 Cl6 Fe2 N8 Ni4P 1 21/n 112.7273; 18.5978; 17.265
90; 90.644; 90
4086.4Tan, Weiqiang; Yu, Zhengkun; He, Wei; Wang, Liandi; Sun, Jie; Chen, Jinzhu
A Toluene Guest in a Poly(heteronuclear) Complex Host of Ferrocenyl−(CH2)2-Bridged Bis(pyrazole)
Organometallics, 2008, 27, 4833
4072253 CIFC24 H51 N Os P2P 1 21/n 19.053; 23.341; 12.827
90; 90.305; 90
2710.4Esteruelas, Miguel A.; Forcén, Elena; Oliván, Montserrat; Oñate, Enrique
Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative
Organometallics, 2008, 27, 6188
4072254 CIFC24 H50 Cl N Os P2P 1 21/n 110.867; 15.319; 17.315
90; 105.762; 90
2774Esteruelas, Miguel A.; Forcén, Elena; Oliván, Montserrat; Oñate, Enrique
Aromatic C−H Bond Activation of 2-Methylpyridine Promoted by an Osmium(VI) Complex: Formation of an η2(N,C)-Pyridyl Derivative
Organometallics, 2008, 27, 6188
4072257 CIFC45 H47 B F20 N6 TiP 1 21/n 119.107; 13.2045; 20.4267
90; 113.494; 90
4726.4Bolton, Paul D.; Feliz, Marta; Cowley, Andrew R.; Clot, Eric; Mountford, Philip
TiNR vs Ti−R′ Functional Group Selectivity in Titanium Imido Alkyl Cations from an Experimental Perspective
Organometallics, 2008, 27, 6096
4072277 CIFC25 H35 N3P 1 21/n 112.387; 16.007; 12.911
90; 115.16; 90
2317.1Wallenhorst, Carolin; Kehr, Gerald; Luftmann, Heinrich; Fröhlich, Roland; Erker, Gerhard
Bis(iminoethyl)pyridine Systems with a Pendant Alkenyl Group. Part A: Cobalt and Iron Complexes and Their Catalytic Behavior†
Organometallics, 2008, 27, 6547
4072284 CIFC43 H48 Cl4 N3 P RuP 1 21/n 19.688; 11.853; 36.224
90; 93.24; 90
4153Wallenhorst, Carolin; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Unsymmetrical Bis(iminoethyl)pyridine Metal Complexes with a Pendant Alkenyl Substituent. Part B: Internal Olefin Coordination to Ruthenium†
Organometallics, 2008, 27, 6557
4072290 CIFC18 H18 N3 P SP 1 21/n 113.7417; 8.8007; 15.3125
90; 111.659; 90
1721.1Oshovsky, Gennady V.; Ouali, Armelle; Xia, Ning; Zablocka, Maria; Boeré, René T.; Duhayon, Carine; Taillefer, Marc; Majoral, Jean Pierre
Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media
Organometallics, 2008, 27, 5733
4072291 CIFC15 H13 N2 P SP 1 21/n 16.0288; 18.5959; 12.3146
90; 93.68; 90
1377.75Oshovsky, Gennady V.; Ouali, Armelle; Xia, Ning; Zablocka, Maria; Boeré, René T.; Duhayon, Carine; Taillefer, Marc; Majoral, Jean Pierre
Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media
Organometallics, 2008, 27, 5733
4072309 CIFC38 H34 O2 P2P 1 21/n 112.7759; 15.4131; 16.196
90; 112.371; 90
2949.2Doherty, Simon; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William
Highly Enantioselective Synthesis of Pseudo-C2-Symmetric Axially Chiral Biaryl Diphosphines via Rhodium-Catalyzed Double [2 + 2 + 2] Cycloaddition
Organometallics, 2008, 27, 4837
4072311 CIFC23 H31 F6 I Ir N2 PP 1 21/n 111.3177; 12.8037; 17.9585
90; 91.143; 90
2601.82Song, Guoyong; Zhang, Yao; Su, Yan; Deng, Weiqiao; Han, Keli; Li, Xingwei
Pyridine-Based N-Heterocyclic Carbene Hydride Complexes of Iridium via C−H Activation
Organometallics, 2008, 27, 6193
4072324 CIFC17 H18 FeP 1 21/n 15.8485; 17.0481; 12.987
90; 92.072; 90
1294.03Ogasawara, Masamichi; Watanabe, Susumu; Nakajima, Kiyohiko; Takahashi, Tamotsu
Preparation of [4]- and [5]Ferrocenophanes by Ruthenium-Catalyzed Ring-Closing Ene−Yne Metathesis
Organometallics, 2008, 27, 6565
4072329 CIFC40 H90 Al2 Cr N4 P2P 1 21/n 112.604; 13.74; 14.445
90; 97.494; 90
2480.2Albahily, Khalid; Al-Baldawi, Danya; Gambarotta, Sandro; Koç, Ece; Duchateau, Robbert
Isolation of a Chromium Hydride Single-Component Ethylene Polymerization Catalyst
Organometallics, 2008, 27, 5943
4072331 CIFC28 H28 Cl2 F3 N3 O4 Ru SP 1 21/n 113.531; 11.219; 20.357
90; 106.48; 90
2963.3Schuecker, Raffael; John, Roland O.; Jakupec, Michael A.; Arion, Vladimir B.; Keppler, Bernhard K.
Water-Soluble Mixed-Ligand Ruthenium(II) and Osmium(II) Arene Complexes with High Antiproliferative Activity
Organometallics, 2008, 27, 6587
4072337 CIFC24 H51 Cl2 N Os P2P 1 21/n 18.75; 18.705; 17.512
90; 96.759; 90
2846.2Esteruelas, Miguel A.; Fernández-Alvarez, Francisco J.; Oñate, Enrique
NH-Tautomerization of 2-Substituted Pyridines and Quinolines on Osmium and Ruthenium: Determining Factors and Mechanism
Organometallics, 2008, 27, 6236
4072345 CIFC26 H50 Co2 N2 O2 P4P 1 21/n 111.1122; 23.9375; 13.2156
90; 104.732; 90
3399.8Wang, Aichen; Sun, Hongjian; Li, Xiaoyan
N-Assisted Carbon−Hydrogen Bond Activation by Cobalt(I) Complexes
Organometallics, 2008, 27, 5434
4072350 CIFC68 H87 B F20 N O P TiP 1 21/n 123.554; 13.974; 24.053
90; 118.863; 90
6933Friesen, Dawn M.; Piers, Warren E.; Parvez, Masood
Selective Catalytic Dimerization of Neohexene by [Cp*Ti(NPtBu3)Me][B(C6F5)4]
Organometallics, 2008, 27, 6596
4072363 CIFC14 H20 N6 Ni O4P 1 21/n 16.96; 12.4871; 9.3214
90; 104.732; 90
783.49Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072364 CIFC24 H21 N3 O2 SiP 1 21/n 115.0974; 11.6399; 23.4817
90; 103.043; 90
4020.03Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072370 CIFC27 H22 B Fe N OP 1 21/n 112.4839; 11.3114; 15.0039
90; 97.82; 90
2099Kaufmann, Linda; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
9-Ferrocenyl-9-borafluoreneA Redox-Switchable Main Group Lewis Acid
Organometallics, 2008, 27, 6215
4072374 CIFC22 H40 Cl P PdP 1 21/n 19.921; 13.999; 17.112
90; 99.4; 90
2344.7Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072379 CIFC28 H32 B F4 N2 P PdP 1 21/n 116.804; 8.897; 18.902
90; 105.072; 90
2728.73Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072380 CIFC31 H38 B F4 N2 P PdP 1 21/n 111.019; 17.662; 15.607
90; 101.556; 90
2975.83Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072381 CIFC21 H38 I P PdP 1 21/n 113.609; 11.773; 15.122
90; 110.004; 90
2276.66Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072384 CIFC24 H42.67 B0.67 F2.67 N1.33 O0.67 P0.67 Pd0.67P 1 21/n 110.9411; 19.7725; 17.8474
90; 93.8024; 90
3852.48Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072388 CIFC20 H29 Cl N2 PdP 1 21/n 110.854; 15.446; 12.618
90; 107.6; 90
2016.4Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072391 CIFC38 H53 Mo N3P 1 21/n 114.0969; 17.7008; 14.2302
90; 106.634; 90
3402.2Marinescu, Smaranda C.; Singh, Rojendra; Hock, Adam S.; Wampler, Keith M.; Schrock, Richard R.; Müller, Peter
Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes
Organometallics, 2008, 27, 6570
4072393 CIFC49 H51 Mo N3P 1 21/n 110.4441; 21.2061; 18.0345
90; 101.269; 90
3917.2Marinescu, Smaranda C.; Singh, Rojendra; Hock, Adam S.; Wampler, Keith M.; Schrock, Richard R.; Müller, Peter
Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes
Organometallics, 2008, 27, 6570
4072402 CIFC18 H54 Si10P 1 21/n 118.509; 21.689; 19.166
90; 114.73; 90
6988Zirngast, Michaela; Baumgartner, Judith; Marschner, Christoph
Synthesis of Cyclic and Bicyclic Polysilanes of Variable Ring Sizes
Organometallics, 2008, 27, 6472
4072403 CIFC29 H42 B Ir N6 O2P 1 21/n 111.201; 17.6163; 16.7825
90; 94.928; 90
3299.3Paneque, Margarita; Poveda, Manuel L.; Santos, Laura L.; Carmona, Ernesto; Mereiter, Kurt
Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound
Organometallics, 2008, 27, 6353
4072405 CIFC27 H36 B Ir N6 OP 1 21/n 18.0575; 20.3891; 16.4221
90; 104.086; 90
2616.8Paneque, Margarita; Poveda, Manuel L.; Santos, Laura L.; Carmona, Ernesto; Mereiter, Kurt
Generation of Metallacyclic Structures from the Reactions of Vinyl Ethers with a TpMe2IrIIICompound
Organometallics, 2008, 27, 6353
4072406 CIFC24 H36 Cl P3 PdP 1 21/n 114.31; 11.988; 15.352
90; 102.12; 90
2574.9Mazzeo, Mina; Lamberti, Marina; Massa, Antonio; Scettri, Arrigo; Pellecchia, Claudio; Peters, Jonas C.
Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes
Organometallics, 2008, 27, 5741
4072411 CIFC27 H61 B F4 O P4 RuP 1 21/n 110.139; 19.718; 18.652
90; 92.459; 90
3725.5Field, Leslie D.; Magill, Alison M.; Jensen, Paul
Butenynyl and Vinylidene Complexes of Ruthenium
Organometallics, 2008, 27, 6539
4072414 CIFC10 H5 Br F3 N OP 1 21/n 14.4543; 11.6713; 18.635
90; 94.179; 90
966.21Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4072416 CIFC52 H46 Cl4 N4P 1 21/n 112.5079; 21.9598; 19.328
90; 91.434; 90
5307.2Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4072420 CIFC62 H70 N4 Pt2P 1 21/n 116.0011; 11.9023; 17.194
90; 101.73; 90
3206.2Tan, Runyu; Jia, Peng; Rao, Yingli; Jia, Wenli; Hadzovic, Alen; Yu, Qing; Li, Xia; Song, Datong
Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization
Organometallics, 2008, 27, 6614
4072425 CIFC35 H65 Ir N3 P3P 1 21/n 110.5431; 16.3967; 21.8123
90; 94.963; 90
3756.6Whited, Matthew T.; Grubbs, Robert H.
Synthesis and Reactivity of Iridium(III) Dihydrido Aminocarbenes
Organometallics, 2008, 27, 5737
4072430 CIFC94 H124 B4 F16 N12 Ni4 O2P 1 21/n 116.368; 16.892; 18.687
90; 100.086; 90
5086.9Hahn, F. Ekkehardt; Radloff, Christian; Pape, Tania; Hepp, Alexander
A Nickel(II)-Cornered Molecular Rectangle with Biscarbene and 4,4′-Bipyridine Bridging Groups
Organometallics, 2008, 27, 6408
4072433 CIFC46 H56 F12 N6 Ni2 O P2P 1 21/n 118.765; 10.511; 25.588
90; 104.416; 90
4888Hahn, F. Ekkehardt; Radloff, Christian; Pape, Tania; Hepp, Alexander
A Nickel(II)-Cornered Molecular Rectangle with Biscarbene and 4,4′-Bipyridine Bridging Groups
Organometallics, 2008, 27, 6408
4083500 CIFC51 H48 Br2 Cl4 F6 Ir2 N2 O10 S2P 1 21/n 112.952; 35.774; 14.664
90; 112.652; 90
6270Han, Ying-Feng; Lin, Yue-Jian; Jia, Wei-Guo; Jin, Guo-Xin
Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†
Organometallics, 2008, 27, 4088
4070667 CIFC62 H100 La2 N8 Si2P 1 c 117.277; 9.771; 18.618
90; 94.561; 90
3133Bambirra, Sergio; Perazzolo, Francesca; Boot, Steven J.; Sciarone, Timo J. J.; Meetsma, Auke; Hessen, Bart
Strategies for the Synthesis of Lanthanum Dialkyl Complexes with Monoanionic Ancillary Ligands
Organometallics, 2008, 27, 704
4072093 CIFC25 H20 N PP 1 c 115.108; 13.258; 20.346
90; 98.395; 90
4031.7Sun, Kai; Wang, Li; Wang, Zhong-Xia
Synthesis and Characterization of Amido Pincer Complexes of Lithium and Nickel and Catalysis of the Nickel Complexes in the Kumada Cross-Coupling
Organometallics, 2008, 27, 5649
4070677 CIFC13 H14 CoP 1 n 16.278; 7.28; 10.834
90; 101.286; 90
485.6Mayer, Ulrich F. J.; Charmant, Jonathan P. H.; Rae, James; Manners, Ian
Synthesis and Structures of Strained, Neutral [d7] and Cationic [d6] Hydrocarbon-Bridged [n]Cobaltocenophanes (n= 2, 3)
Organometallics, 2008, 27, 1524
4070795 CIFC23 H25 N3 O6 SiP 1 n 19.341; 10.443; 11.71
90; 99.72; 90
1125.9Spiniello, Marisa; White, Jonathan M.
Structural Investigations into the β-Effect of Pentavalent Silicon
Organometallics, 2008, 27, 994
4072327 CIFC75 H68 B4 Cl2 N4 Y2P 1 n 111.8415; 11.8468; 24.244
90; 101.164; 90
3336.7Yuan, Yuanyuan; Chen, Yaofeng; Li, Guangyu; Xia, Wei
Reactions of Boratabenzene Yttrium Complexes with KN(SiMe3)2: Salt Elimination and π-Ligand Displacement
Organometallics, 2008, 27, 6307
4070581 CIFC31 H48 Br2 N4 Rh2P 21 21 213.5476; 14.3566; 8.4221
90; 90; 90
1638.1Wells, Kyle D.; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
Organometallics, 2008, 27, 691
4070773 CIFC17 H24 Cl Ir N2 O2P 21 21 214.3072; 23.352; 12.2214
90; 90; 90
4083.2Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4071002 CIFC21 H31 F6 Ir N3 O2 PP 21 21 215.3775; 8.4994; 9.2423
90; 90; 90
1207.96Paredes, Paloma; Díez, Josefina; Gamasa, M. Pilar
Synthesis of Enantiopure Iridium(I) and Iridium(III) Pybox Complexes and Their Application in the Asymmetric Transfer Hydrogenation of Ketones†
Organometallics, 2008, 27, 2597
4071103 CIFC46.4 H52.5 Br0.67 Cl0.33 N2 O3.35 PdP 21 21 217.0116; 23.8755; 9.9206
90; 90; 90
4029.36Gosiewska, Silvia; Martinez Herreras, Sara; Lutz, Martin; Spek, Anthony L.; Havenith, Remco W. A.; van Klink, Gerard P. M.; van Koten, Gerard; Gebbink, Robertus J. M. Klein
Synthesis, Structure, and Catalytic Performance of Diastereopure Five-Coordinated NCN-Pincer Palladium(II) Complexes Bearing Bulky Amino Acid Substituents
Organometallics, 2008, 27, 2549
4071239 CIFC44 H60 Ni O3 P2P 21 21 213.9217; 14.4359; 10.4167
90; 90; 90
2093.5Ruhland, Klaus; Obenhuber, Andreas; Hoffmann, Stephan D.
Cleavage of Unstrained C(sp2)—C(sp2) Single Bonds with Ni0Complexes Using Chelating Assistance
Organometallics, 2008, 27, 3482
4071871 CIFC24 H19 Br N2 Ni O2P 21 21 213.167; 5.8235; 13.0951
90; 90; 90
1004.11Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4071932 CIFC54 H72 N6 O3 Sn3P 21 21 212.624; 35.226; 12.908
90; 90; 90
5740.1Padělková, Zdeňka; Nechaev, Mikhail S.; Černošek, Zdeněk; Brus, Jiří; Růžička, Aleš
Solvent-Controlled Ring Size in Double C,N-Chelated Stannoxanes⊥
Organometallics, 2008, 27, 5303
4072134 CIFC42 H54 Cl2 ZrP 21 21 213.362; 25.112; 6.5155
90; 90; 90
2186.3Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070528 CIFC62 H48 I P3 RuP 21 21 2111.1598; 14.9046; 29.3635
90; 90; 90
4884.1Zhao, Xiaoxi; Ivanova, Nina; Hadzovic, Alen; Zimmer-De Iuliis, Marco; Lough, Alan J.; Morris, Robert H.
Use of an Iodide-Modified Merrifield Resin in the Synthesis of Ruthenium Hydride Complexes. The Structure of RuHI((R)-binap)(PPh3)
Organometallics, 2008, 27, 503
4070550 CIFC51 H84 Fe2 K N4 Sc Si4P 21 21 2113.554; 19.352; 20.878
90; 90; 90
5476Carver, Colin T.; Monreal, Marisa J.; Diaconescu, Paula L.
Scandium Alkyl Complexes Supported by a Ferrocene Diamide Ligand
Organometallics, 2008, 27, 363
4070689 CIFC84 H106 Br2 N6 O3 Pd2P 21 21 2114.5583; 20.1309; 26.9433
90; 90; 90
7896.3Dyson, Gavin; Frison, Jean-Cédric; Simonovic, Stevan; Whitwood, Adrian C.; Douthwaite, Richard E.
Synthesis and Structural Variation of Iron, Rhodium, Palladium, and Silver Complexes of a Chiral N-Heterocyclic Carbene−Phenoxyimine Hybrid Ligand
Organometallics, 2008, 27, 281
4070690 CIFC41 H57 Cl N3 O RhP 21 21 2112.786; 16.419; 18.434
90; 90; 90
3869.9Dyson, Gavin; Frison, Jean-Cédric; Simonovic, Stevan; Whitwood, Adrian C.; Douthwaite, Richard E.
Synthesis and Structural Variation of Iron, Rhodium, Palladium, and Silver Complexes of a Chiral N-Heterocyclic Carbene−Phenoxyimine Hybrid Ligand
Organometallics, 2008, 27, 281
4070691 CIFC73 H96 Ag2 Br2 Fe N6 O2P 21 21 2116.8959; 18.3946; 23.265
90; 90; 90
7230.6Dyson, Gavin; Frison, Jean-Cédric; Simonovic, Stevan; Whitwood, Adrian C.; Douthwaite, Richard E.
Synthesis and Structural Variation of Iron, Rhodium, Palladium, and Silver Complexes of a Chiral N-Heterocyclic Carbene−Phenoxyimine Hybrid Ligand
Organometallics, 2008, 27, 281
4070744 CIFC12 H15 B Bi Cl2 F O2P 21 21 219.1514; 11.6274; 14.5092
90; 90; 90
1543.9Caires, Christopher C.; Guccione, Samira
Synthesis, Structure, and Reactivity of Borate Ester Coordinated Organobismuth Compounds
Organometallics, 2008, 27, 747
4070746 CIFC24 H25 B Bi Cl2 F O2P 21 21 219.4733; 13.9288; 37.941
90; 90; 90
5006.4Caires, Christopher C.; Guccione, Samira
Synthesis, Structure, and Reactivity of Borate Ester Coordinated Organobismuth Compounds
Organometallics, 2008, 27, 747
4070771 CIFC25 H32 Cl Ir N2 O2P 21 21 2113.0031; 18.1724; 20.0288
90; 90; 90
4732.8Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4070803 CIFC34 H36 Br2 F6 N4 O2 PdP 21 21 218.8307; 13.1779; 30.571
90; 90; 90
3557.5Wanniarachchi, Yoshitha A.; Kogiso, Yuri; Slaughter, LeGrande M.
Chiral Palladium Bis(acyclic diaminocarbene) Complexes as Enantioselective Catalysts for the Aza-Claisen Rearrangement
Organometallics, 2008, 27, 21
4070827 CIFC67 H70 N7 Si2 SmP 21 21 2111.515; 21.46; 24.2
90; 90; 90
5980Zi, Guofu; Xiang, Li; Song, Haibin
Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2′-(dimethylamino)-1,1′-binaphthyl
Organometallics, 2008, 27, 1242
4070828 CIFC67 H70 N7 Si2 YP 21 21 2111.4444; 21.5082; 24.216
90; 90; 90
5960.7Zi, Guofu; Xiang, Li; Song, Haibin
Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2′-(dimethylamino)-1,1′-binaphthyl
Organometallics, 2008, 27, 1242
4070829 CIFC67 H70 N7 Si2 YbP 21 21 2111.4379; 21.5061; 24.2427
90; 90; 90
5963.3Zi, Guofu; Xiang, Li; Song, Haibin
Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2′-(dimethylamino)-1,1′-binaphthyl
Organometallics, 2008, 27, 1242
4070844 CIFC31 H62 N2 Os P2P 21 21 2111.396; 13.801; 21.64
90; 90; 90
3403Eguillor, Beatriz; Esteruelas, Miguel A.; Oliván, Montserrat; Puerta, Marta
Abnormal and Normal N-Heterocyclic Carbene Osmium Polyhydride Complexes Obtained by Direct Metalation of Imidazolium Salts
Organometallics, 2008, 27, 445
4070883 CIFC95 H63 Cl7 F30 Fe2 P4 Pd2P 21 21 2112.3737; 26.457; 29.0299
90; 90; 90
9503.5Wang, Yaping; Sturm, Thomas; Steurer, Marianne; Arion, Vladimir B.; Mereiter, Kurt; Spindler, Felix; Weissensteiner, Walter
Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Organometallics, 2008, 27, 1119
4070884 CIFC51 H39 Cl11 F12 Fe O2 P2 PdP 21 21 2110.4499; 23.0779; 24.5543
90; 90; 90
5921.6Wang, Yaping; Sturm, Thomas; Steurer, Marianne; Arion, Vladimir B.; Mereiter, Kurt; Spindler, Felix; Weissensteiner, Walter
Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Organometallics, 2008, 27, 1119
4070885 CIFC20 H23 Br Fe I NP 21 21 219.433; 12.543; 17.474
90; 90; 90
2067.5Wang, Yaping; Sturm, Thomas; Steurer, Marianne; Arion, Vladimir B.; Mereiter, Kurt; Spindler, Felix; Weissensteiner, Walter
Synthesis, Coordination Behavior, and Use in Asymmetric Hydrogenations of Walphos-Type Ligands
Organometallics, 2008, 27, 1119
4070908 CIFC28 H34 Cr O4 SiP 21 21 2110.7012; 10.8019; 22.171
90; 90; 90
2562.8Paramahamsan, Harinandini; Pearson, Anthony J.; Pinkerton, A. Alan; Zhurova, Elizabeth A.
Toward an Understanding of 1,5-Asymmetric Induction during Nucleophilic Addition to (Arene)chromium Tricarbonyl Complexes: Conformational Preference of the Chromium Tricarbonyl Tripod for Transmission of Chirality
Organometallics, 2008, 27, 900
4070941 CIFC36 H33 N2 Ni P3P 21 21 217.663; 19.375; 21.757
90; 90; 90
3230.3Acosta-Ramírez, Alberto; Flores-Álamo, Marcos; Jones, William D.; García, Juventino J.
P−C Bond Scission at the TRIPHOS Ligand and C−CN Bond Cleavage in 2-Methyl-3-butenenitrile with [Ni(COD)2]
Organometallics, 2008, 27, 1834
4070984 CIFC28 H23 Cr N O7P 21 21 2112.693; 13.031; 15.808
90; 90; 90
2614.68Meca, Luděk; Císařová, Ivana; Drahoňovský, Dušan; Dvořák, Dalimil
Enantiomerically Pure Axially Chiral Aminocarbene Complexes of Chromium
Organometallics, 2008, 27, 1850
4070989 CIFC40 H86 Ca2 N2 O4 Si4P 21 21 2115.269; 17.846; 18.96
90; 90; 90
5166.4He, Xuyang; Hurley, Erin; Noll, Bruce C.; Henderson, Kenneth W.
Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Organometallics, 2008, 27, 3094
4071041 CIFC24 H46 N P2 RhP 21 21 2113.052; 13.841; 14.526
90; 90; 90
2624.16Hanson, Susan Kloek; Heinekey, D. Michael; Goldberg, Karen I.
C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water
Organometallics, 2008, 27, 1454
4071088 CIFC19 H27 F6 Fe N2 P PdP 21 21 219.717; 14.296; 16.165
90; 90; 90
2245.5Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4071098 CIFC30 H36 Cl F6 N O3 P2 RuP 21 21 2110.554; 13.15; 23.409
90; 90; 90
3248.8Weber, Immo; Heinemann, Frank W.; Bauer, Walter; Superchi, Stefano; Zahl, Achim; Richter, Daniela; Zenneck, Ulrich
Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6Salts: Kinetic versus Thermodynamic Preferences
Organometallics, 2008, 27, 4116
4071100 CIFC39 H49 O P3 Ru2P 21 21 219.3624; 19.378; 21.286
90; 90; 90
3861.8Takemoto, Shin; Kimura, Yu; Kamikawa, Ken; Matsuzaka, Hiroyuki
P−H Bond Addition to a Dinuclear Ruthenium Imido Complex: Synthesis and Reactivity of an Amido Phosphido Complex
Organometallics, 2008, 27, 1780
4071101 CIFC37 H49 O2 P Ru2P 21 21 2110.61; 15.178; 21.35
90; 90; 90
3438.2Takemoto, Shin; Kimura, Yu; Kamikawa, Ken; Matsuzaka, Hiroyuki
P−H Bond Addition to a Dinuclear Ruthenium Imido Complex: Synthesis and Reactivity of an Amido Phosphido Complex
Organometallics, 2008, 27, 1780
4071113 CIFC25 H28 Cl Mn N2 O4P 21 21 219.4528; 12.0818; 21.7123
90; 90; 90
2479.7Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4071115 CIFC25 H29 Mn N2 O4P 21 21 2110.5344; 13.924; 16.439
90; 90; 90
2411.3Jacques, Béatrice; Eloi, Antoine; Chavarot-Kerlidou, Murielle; Rose-Munch, Françoise; Rose, Eric; Gérard, Hélène; Herson, Patrick
Unprecedented (η5-Formylcyclohexadienyl)Mn(CO)3Complexes: Synthesis, Structural and Theoretical Characterizations, and Resolution of the Planar Chirality
Organometallics, 2008, 27, 2505
4071116 CIFC25 H33 Li Ni O2P 21 21 219.8482; 14.5816; 15.6829
90; 90; 90
2252.1Buchalski, Piotr; Grabowska, Ilona; Kamińska, Elżbieta; Suwińska, Kinga
Synthesis and Structures of 9-Nickelafluorenyllithium Complexes
Organometallics, 2008, 27, 2346
4071137 CIFC24 H17 Fe4 N O9 Te2P 21 21 219.325; 15.1222; 20.0419
90; 90; 90
2826.2Mathur, Pradeep; Singh, Amrendra K.; Mohanty, Jamini R.; Chatterjee, Saurav; Mobin, Shaikh M.
Formation of N-Methylated Cyclic Ligand Systems from Unusual Reactions between TrimethylamineN-Oxide and Acetylenes on Fe3Te2(CO)9and Contrast with Reactions on Fe3E2(CO)9(E = S, Se)
Organometallics, 2008, 27, 5094
4071160 CIFC20 H34 Cl2 SnP 21 21 216.9891; 15.683; 19.816
90; 90; 90
2172Beckmann, Jens; Duthie, Andrew; Grassmann, Marian; Semisch, Annetta
Optically Active Organotin Compounds Derived from β-Pinene. The Quest for Chiral Polystannanes†
Organometallics, 2008, 27, 1495
4071199 CIFC39 H70 N3 O Si2 YP 21 21 2112.9822; 17.637; 18.8875
90; 90; 90
4324.6Ge, Shaozhong; Meetsma, Auke; Hessen, Bart
Highly Efficient Hydrosilylation of Alkenes by Organoyttrium Catalysts with Sterically Demanding Amidinate and Guanidinate Ligands
Organometallics, 2008, 27, 3131
4071255 CIFC39 H35 F6 N O2 P Pd SbP 21 21 2111.1708; 14.5431; 21.674
90; 90; 90
3521.12Mikhel, Igor S.; Rüegger, Heinz; Butti, Pietro; Camponovo, Francesco; Huber, Dominik; Mezzetti, Antonio
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes
Organometallics, 2008, 27, 2937
4071256 CIFC43 H38 Cl N O2 P RhP 21 21 219.052; 11.3595; 34.266
90; 90; 90
3523.4Mikhel, Igor S.; Rüegger, Heinz; Butti, Pietro; Camponovo, Francesco; Huber, Dominik; Mezzetti, Antonio
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes
Organometallics, 2008, 27, 2937
4071257 CIFC44 H42 Cl N O2 P RhP 21 21 2112.052; 12.7854; 23.726
90; 90; 90
3655.9Mikhel, Igor S.; Rüegger, Heinz; Butti, Pietro; Camponovo, Francesco; Huber, Dominik; Mezzetti, Antonio
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes
Organometallics, 2008, 27, 2937
4071258 CIFC43 H38 F6 N O2 P Rh SbP 21 21 2111.2449; 15.0329; 22.3759
90; 90; 90
3782.5Mikhel, Igor S.; Rüegger, Heinz; Butti, Pietro; Camponovo, Francesco; Huber, Dominik; Mezzetti, Antonio
A Chiral Phosphoramidite beyond Monodentate Coordination: Secondary π-Interactions Turn a Dangling Aryl into a Two-, Four-, or Six-Electron Donor in d6and d8Complexes
Organometallics, 2008, 27, 2937
4071274 CIFC15 H25 Cl2 P RuP 21 21 217.467; 13.096; 17.923
90; 90; 90
1752.7Aznar, Rosario; Muller, Guillermo; Sainz, Daniel; Font-Bardia, Mercè; Solans, Xavier
Synthesis and Reactivity of P-Chiral Tethered (η1:η6-phosphinoarene)ruthenium Complexes
Organometallics, 2008, 27, 1967
4071356 CIFC30 H33 Cl3 Ir NP 21 21 2111.557; 11.913; 20.31
90; 90; 90
2796.3Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071400 CIFC36 H33 Br P2 RuP 21 21 2112.45942; 15.52669; 15.69572
90; 90; 90
3036.39Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071402 CIFC36 H33 I P2 RuP 21 21 2112.5156; 15.5113; 15.8381
90; 90; 90
3074.7Brunner, Henri; Muschiol, Manfred; Tsuno, Takashi; Takahashi, Takemoto; Zabel, Manfred
Pyramidal Stability of Chiral-at-Metal Half-Sandwich 16-Electron Fragments [CpRu(P−P′)]
Organometallics, 2008, 27, 3514
4071424 CIFC106 H136 Cl O25 P5 Sn5P 21 21 2115.6035; 22.6982; 32.5487
90; 90; 90
11527.8Murugavel, Ramaswamy; Shanmugan, Swaminathan
Asymmetric Pentameric and Tetrameric Organooxotin Clusters: Insights into Their Formation through Partial Dearylation
Organometallics, 2008, 27, 2784
4071425 CIFC108 H140 Cl O25 P5 Sn5P 21 21 2115.7555; 22.6489; 32.587
90; 90; 90
11628.5Murugavel, Ramaswamy; Shanmugan, Swaminathan
Asymmetric Pentameric and Tetrameric Organooxotin Clusters: Insights into Their Formation through Partial Dearylation
Organometallics, 2008, 27, 2784
4071456 CIFC28 H33 Cl2 N2 O VP 21 21 2111.2178; 14.2133; 16.9951
90; 90; 90
2709.73Onishi, Yoshifumi; Katao, Shohei; Fujiki, Michiya; Nomura, Kotohiro
Synthesis and Structural Analysis of (Arylimido)vanadium(V) Complexes Containing Phenoxyimine Ligands: New, Efficient Catalyst Precursors for Ethylene Polymerization
Organometallics, 2008, 27, 2590
4071462 CIFC23 H30 N2P 21 21 218.3994; 10.519; 22.0339
90; 90; 90
1946.8Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071465 CIFC29 H41 Ag Br Cl3 N2P 21 21 2110.7457; 16.723; 17.9327
90; 90; 90
3222.51Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071507 CIFC37 H53 Cl2 N O2 ZrP 21 21 219.861; 16.787; 22.046
90; 90; 90
3649.4Gott, Andrew L.; Clarke, Adam J.; Clarkson, Guy J.; Munslow, Ian J.; Wade, Andrew R.; Scott, Peter
Single Diastereomer Half-Sandwich Salicyloxazoline Complexes of Titanium and Zirconium
Organometallics, 2008, 27, 2706
4071513 CIFC18 H28 F3 N3 O4 Pd SP 21 21 2112.8466; 12.9925; 13.6154
90; 90; 90
2272.5Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4071574 CIFC16 H21 I N2 PtP 21 21 214.6146; 11.7364; 29.866
90; 90; 90
1617.51Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071576 CIFC16 H19 F2 I N2 PtP 21 21 214.5846; 11.894; 30.144
90; 90; 90
1643.7Calmuschi-Cula, Beatrice; Englert, Ulli
Orthoplatination of Primary Amines
Organometallics, 2008, 27, 3124
4071625 CIFC26 H21 Cl N P Pd S2P 21 21 2112.7414; 12.7768; 15.1936
90; 90; 90
2473.43Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Gutsul, E. I.; Puntus, L. N.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides: Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic Activity, and Photophysical Properties
Organometallics, 2008, 27, 4062
4071731 CIFC41 H47 N P2 RuP 21 21 2112.3804; 15.0022; 18.9812
90; 90; 90
3525.4Derrah, Eric J.; Giesbrecht, Karina E.; McDonald, Robert; Rosenberg, Lisa
Ruthenated Acetonitrile: Unusual Brønsted Acidity of a Polar “Aprotic” Solvent
Organometallics, 2008, 27, 5025
4071745 CIFC27 H38 I Ir P2P 21 21 217.4979; 16.7508; 20.6495
90; 90; 90
2593.5Romero, Patricio E.; Whited, Matthew T.; Grubbs, Robert H.
Multiple C−H Activations of Methyltert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1
Organometallics, 2008, 27, 3422
4071763 CIFC43 H44 F12 N12 O P2 PdP 21 21 218.4236; 12.5375; 46.354
90; 90; 90
4895.5Zhang, Xiaoming; Xi, Zhenxing; Liu, Ailing; Chen, Wanzhi
Facile and Efficient Olefination of Aryl Halides Catalyzed by a Palladium Complex Containing a Heteroarene-Functionalized N-Heterocyclic Carbene
Organometallics, 2008, 27, 4401
4071844 CIFC37 H39 Cl2 F6 N2 P Ru2P 21 21 219.072; 12.085; 32.693
90; 90; 90
3584.3Pannetier, Nicolas; Sortais, Jean-Baptiste; Dieng, Pape Sylla; Barloy, Laurent; Sirlin, Claude; Pfeffer, Michel
Kinetics and Mechanism of Ruthenacycle-Catalyzed Asymmetric Hydrogen Transfer
Organometallics, 2008, 27, 5852
4071846 CIFC25 H43 Fe N O2 P2P 21 21 2111.7404; 14.5944; 15.3327
90; 90; 90
2627.2Pelczar, Elizabeth M.; Emge, Thomas J.; Krogh-Jespersen, Karsten; Goldman, Alan S.
Unusual Structural and Spectroscopic Features of Some PNP-Pincer Complexes of Iron
Organometallics, 2008, 27, 5759
4071869 CIFC30 H31 Br N2 O2 PdP 21 21 216.6808; 19.625; 20.422
90; 90; 90
2677.5Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4071870 CIFC18 H25 Cl N2 Ni O7P 21 21 216.1341; 11.6353; 29.016
90; 90; 90
2070.9Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4071872 CIFC112 H108 Br4 N8 Ni4 O8P 21 21 216.2679; 10.9501; 35.488
90; 90; 90
2435.7Bugarin, Alejandro; Connell, Brian T.
Chiral Nickel(II) and Palladium(II) NCN-Pincer Complexes Based on Substituted Benzene: Synthesis, Structure, and Lewis Acidity
Organometallics, 2008, 27, 4357
4071895 CIFC17 H21 Fe N O2P 21 21 217.3992; 12.9482; 15.2689
90; 90; 90
1462.86Tebben, Ludger; Bussmann, Kathrin; Hegemann, Michael; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Ferrocene-Derived Bioorganometallic Chemistry: Preparation of a [3]Ferrocenophane γ-Amino Acid for Use in Peptide Synthesis
Organometallics, 2008, 27, 4269
4071897 CIFC48 H62 Cl N2 P PdP 21 21 2112.3007; 18.7039; 19.5365
90; 90; 90
4494.78Esposito, Oriana; Gois, Pedro M. P.; de K. Lewis, Alexandra K.; Caddick, Stephen; Cloke, F. Geoffrey N.; Hitchcock, Peter B.
Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties
Organometallics, 2008, 27, 6411
4071927 CIFC22 H31 B Mo N8 O2P 21 21 219.9952; 15.9318; 31.234
90; 90; 90
4973.75Cordiner, Richard L.; Hill, Anthony F.; Wagler, Jörg
Reactions of [Mo(CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes
Organometallics, 2008, 27, 4532
4071954 CIFC44 H32 N2P 21 21 219.0367; 10.8324; 32.327
90; 90; 90
3164.5Matsuzawa, Hiroshi; Tanabe, Yoshiaki; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Synthesis of Optically ActiveN,N,N′,N′-Tetraphenyl-1,1′-binaphthyl-2,2′-diamine Derivatives as Analogues of BINAP
Organometallics, 2008, 27, 4021
4071976 CIFC43 H0 Br2 F6 N2 P Pd SbP 21 21 2110.3604; 19.119; 22.51
90; 90; 90
4458.8Schnitzler, Verena; Nonglaton, Guillaume; Roussière, Hélène; Maillet, Céline; Evain, Michel; Janvier, Pascal; Bujoli, Bruno; Petit, Marc
Nitrogen-Based Chirality Effects in Novel Mixed Phosphorus/Nitrogen Ligands Applied to Palladium-Catalyzed Allylic Substitutions
Organometallics, 2008, 27, 5997
4071977 CIFC32 H38 Br2 N2 O9 P SP 21 21 217.0672; 11.0184; 46.319
90; 90; 90
3606.8Schnitzler, Verena; Nonglaton, Guillaume; Roussière, Hélène; Maillet, Céline; Evain, Michel; Janvier, Pascal; Bujoli, Bruno; Petit, Marc
Nitrogen-Based Chirality Effects in Novel Mixed Phosphorus/Nitrogen Ligands Applied to Palladium-Catalyzed Allylic Substitutions
Organometallics, 2008, 27, 5997
4072018 CIFC13 H20 Cl3 Cr N4 SP 21 21 219.233; 12.9405; 14.769
90; 90; 90
1764.6Zhang, Jun; Braunstein, Pierre; Hor, T. S. Andy
Highly Selective Chromium(III) Ethylene Trimerization Catalysts with [NON] and [NSN] Heteroscorpionate Ligands
Organometallics, 2008, 27, 4277
4072032 CIFC18 H18 N4P 21 21 2110.8815; 14.5747; 19.4944
90; 90; 90
3091.7Ros, Abel; Alcarazo, Manuel; Iglesias-Sigüenza, Javier; Díez, Elena; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Stereoselective Synthesis of Rhodium(I) 4-(Dialkylamino)triazol-5-ylidene Complexes
Organometallics, 2008, 27, 4555
4072035 CIFC37 H50 F6 N4 Rh S SbP 21 21 2110.9659; 14.9455; 23.038
90; 90; 90
3775.7Ros, Abel; Alcarazo, Manuel; Iglesias-Sigüenza, Javier; Díez, Elena; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Stereoselective Synthesis of Rhodium(I) 4-(Dialkylamino)triazol-5-ylidene Complexes
Organometallics, 2008, 27, 4555
4072145 CIFC35 H40 F24 La N4 O4P 21 21 2117.5672; 18.3588; 27.1018
90; 90; 90
8740.7Grunova, Ekaterina; Kirillov, Evgueni; Roisnel, Thierry; Carpentier, Jean-François
Group 3 Metal Complexes of Salen-like Fluorous Dialkoxy−Diimino Ligands: Synthesis, Structure, and Application in Ring-Opening Polymerization ofrac-Lactide andrac-β-Butyrolactone
Organometallics, 2008, 27, 5691
4072153 CIFC32 H47 I O UP 21 21 2116.5602; 18.6484; 19.595
90; 90; 90
6051.4Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
Organometallics, 2008, 27, 5371
4072159 CIFC25 H33 As Cl N PdP 21 21 219.9468; 13.537; 18.6809
90; 90; 90
2515.38Coote, Michelle L.; Krenske, Elizabeth H.; Porter, Keith A.; Weir, Michelle L.; Willis, Anthony C.; Zhou, Xiangting; Wild, S. Bruce
Asymmetric Synthesis of a Tertiary Arsine by Nucleophilic Addition to a Chiral Phosphine-Stabilized Arsenium Salt
Organometallics, 2008, 27, 5099
4072169 CIFC37 H44 Cl2 P2 PtP 21 21 219.8524; 18.986; 19.524
90; 90; 90
3652.1Sadowy, Amber L.; Ferguson, Michael J.; McDonald, Robert; Tykwinski, Rik R.
Chiralcis-Platinum Acetylide Complexes via Diphosphine Ligand Exchange: Effect of the Ligand
Organometallics, 2008, 27, 6321
4072174 CIFC4 H15 B10 N OP 21 21 218.8115; 10.4327; 12.6598
90; 90; 90
1163.8Mukhin, Sergey N.; Kabytaev, Kuanysh Z.; Zhigareva, Galina G.; Glukhov, Ivan V.; Starikova, Zoya A.; Bregadze, Vladimir I.; Beletskaya, Irina P.
Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom
Organometallics, 2008, 27, 5937
4072175 CIFC10.5 H20 B10 Cl N OP 21 21 2111.0222; 15.039; 20.857
90; 90; 90
3457.3Mukhin, Sergey N.; Kabytaev, Kuanysh Z.; Zhigareva, Galina G.; Glukhov, Ivan V.; Starikova, Zoya A.; Bregadze, Vladimir I.; Beletskaya, Irina P.
Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom
Organometallics, 2008, 27, 5937
4072234 CIFC26 H41 Cl Si TiP 21 21 2110.4972; 11.3834; 20.923
90; 90; 90
2500.17Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072263 CIFC20 H34 P2 Si VP 21 21 2115.365; 17.074; 17.199
90; 90; 90
4512Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4072296 CIFC48 H78 Ca N2 O2 SiP 21 21 2113.297; 16.628; 21.755
90; 90; 90
4810.09Barrett, Anthony G. M.; Crimmin, Mark R.; Hill, Michael S.; Hitchcock, Peter B.; Lomas, Sarah L.; Mahon, Mary F.; Procopiou, Panayiotis A.; Suntharalingam, Kogularamanan
β-Diketiminato Calcium Acetylides: Synthesis, Solution Dimerization, and Catalytic Carbon−Carbon Bond Formation
Organometallics, 2008, 27, 6300
4072328 CIFC40 H48 B2 N3 Si2 YP 21 21 218.6743; 17.8926; 25.385
90; 90; 90
3939.9Yuan, Yuanyuan; Chen, Yaofeng; Li, Guangyu; Xia, Wei
Reactions of Boratabenzene Yttrium Complexes with KN(SiMe3)2: Salt Elimination and π-Ligand Displacement
Organometallics, 2008, 27, 6307
4072355 CIFC16 H14 N2 O4 SiP 21 21 217.3257; 13.6736; 14.8738
90; 90; 90
1489.89Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072387 CIFC21 H42 B F4 N2 P PdP 21 21 218.1831; 16.9422; 18.5709
90; 90; 90
2574.66Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072396 CIFC45 H53 F6 Mo N2 O PP 21 21 2113.7643; 16.5149; 18.7349
90; 90; 90
4258.7Marinescu, Smaranda C.; Singh, Rojendra; Hock, Adam S.; Wampler, Keith M.; Schrock, Richard R.; Müller, Peter
Syntheses and Structures of Molybdenum Imido Alkylidene Pyrrolide and Indolide Complexes
Organometallics, 2008, 27, 6570
4072397 CIFC45 H50 Fe P2P 21 21 2114.55; 15.3; 34.447
90; 90; 90
7668Takita, Ryo; Takada, Yuko; Jensen, Rader S.; Okazaki, Masaaki; Ozawa, Fumiyuki
Synthesis and Ligand Properties of 1-Phosphaethenyl-2-phosphanylferrocenes
Organometallics, 2008, 27, 6279
4072398 CIFC51 H66 Fe O P2 PtP 21 21 2110.4639; 17.2101; 25.5495
90; 90; 90
4601.08Takita, Ryo; Takada, Yuko; Jensen, Rader S.; Okazaki, Masaaki; Ozawa, Fumiyuki
Synthesis and Ligand Properties of 1-Phosphaethenyl-2-phosphanylferrocenes
Organometallics, 2008, 27, 6279
4072412 CIFC16 H39 B F4 P4 RuP 21 21 219.8335; 15.5702; 16.4684
90; 90; 90
2521.5Field, Leslie D.; Magill, Alison M.; Jensen, Paul
Butenynyl and Vinylidene Complexes of Ruthenium
Organometallics, 2008, 27, 6539
4072427 CIFC30 H27 Ir O2P 21 21 218.0561; 19.3133; 29.9033
90; 90; 90
4652.7Panichakul, Duanghathai; Su, Yan; Li, Yongxin; Deng, Weiqiao; Zhao, Jing; Li, Xingwei
A Rare η3Binding Mode of Aryloxides in Iridium, Rhodium, and Ruthenium Complexes
Organometallics, 2008, 27, 6390
4072429 CIFC30 H27 O2 RhP 21 21 218.0134; 19.4063; 29.9106
90; 90; 90
4651.4Panichakul, Duanghathai; Su, Yan; Li, Yongxin; Deng, Weiqiao; Zhao, Jing; Li, Xingwei
A Rare η3Binding Mode of Aryloxides in Iridium, Rhodium, and Ruthenium Complexes
Organometallics, 2008, 27, 6390
4072431 CIFC16 H19 Br N2 NiP 21 21 2110.2497; 10.7909; 14.198
90; 90; 90
1570.35Hahn, F. Ekkehardt; Radloff, Christian; Pape, Tania; Hepp, Alexander
A Nickel(II)-Cornered Molecular Rectangle with Biscarbene and 4,4′-Bipyridine Bridging Groups
Organometallics, 2008, 27, 6408
4072435 CIFC21.25 H33.5 Cl2.5 N O1.5 P PdP 21 21 2117.1172; 17.4726; 33.072
90; 90; 90
9891.2Rubina, Marina; Sherrill, William M.; Rubin, Michael
Dramatic Stereo- and Enantiodivergency in the Intermolecular Asymmetric Heck Reaction Catalyzed by Palladium Complexes with Cyclopropane-Based PHOX Ligands
Organometallics, 2008, 27, 6393
4083504 CIFC27 H44 Cl2 Si2 ZrP 21 21 218.7249; 11.4772; 28.8269
90; 90; 90
2886.65Min, Endy Y.-J.; Byers, Jeffery A.; Bercaw, John E.
Catalyst Site Epimerization during the Kinetic Resolution of Chiral α-Olefins by Polymerization
Organometallics, 2008, 27, 2179
4071090 CIFC25 H31 F6 Fe N2 P PdP 21 c n11.248; 12.039; 19.803
90; 90; 90
2682Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4070839 CIFC25 H30 N NbP 3 1 c11.2683; 11.2683; 10.2514
90; 90; 120
1127.3Arteaga-Müller, Rocío; Sánchez-Nieves, Javier; Ramos, Javier; Royo, Pascual; Mosquera, Marta E. G.
Isolobal Zwitterionic Niobium and Tantalum Imido and Zirconium Monocyclopentadienyl Complexes: Theoretical and Methyl Methacrylate Polymerization Studies
Organometallics, 2008, 27, 1417
4072092 CIFC57 H61 B Hf N6P 31 2 120.872; 20.872; 21.022
90; 90; 120
7931Lee, Han; Nienkemper, Katrin; Jordan, Richard F.
Synthesis and Reactivity of a Sterically Crowded Tris(pyrazolyl)borate Hafnium Benzyl Complex
Organometallics, 2008, 27, 5075
4072144 CIFC42 H54 F24 N4 O10 Y2P 31 2 124.6268; 24.6268; 11.061
90; 90; 120
5809.5Grunova, Ekaterina; Kirillov, Evgueni; Roisnel, Thierry; Carpentier, Jean-François
Group 3 Metal Complexes of Salen-like Fluorous Dialkoxy−Diimino Ligands: Synthesis, Structure, and Application in Ring-Opening Polymerization ofrac-Lactide andrac-β-Butyrolactone
Organometallics, 2008, 27, 5691
4071104 CIFC42 H43 F6 N2 O2 P PdP 41 21 210.4019; 10.4019; 34.9279
90; 90; 90
3779.18Gosiewska, Silvia; Martinez Herreras, Sara; Lutz, Martin; Spek, Anthony L.; Havenith, Remco W. A.; van Klink, Gerard P. M.; van Koten, Gerard; Gebbink, Robertus J. M. Klein
Synthesis, Structure, and Catalytic Performance of Diastereopure Five-Coordinated NCN-Pincer Palladium(II) Complexes Bearing Bulky Amino Acid Substituents
Organometallics, 2008, 27, 2549
4071105 CIFC42 H43 B F4 N2 O2 PdP 41 21 210.3592; 10.3592; 33.8828
90; 90; 90
3636.07Gosiewska, Silvia; Martinez Herreras, Sara; Lutz, Martin; Spek, Anthony L.; Havenith, Remco W. A.; van Klink, Gerard P. M.; van Koten, Gerard; Gebbink, Robertus J. M. Klein
Synthesis, Structure, and Catalytic Performance of Diastereopure Five-Coordinated NCN-Pincer Palladium(II) Complexes Bearing Bulky Amino Acid Substituents
Organometallics, 2008, 27, 2549
4071291 CIFC16 H38 Fe O4 P4P 41 21 28.99; 8.99; 28.589
90; 90; 90
2310.6Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4071628 CIFC35 H27 BP 41 21 210.099; 10.099; 25.157
90; 90; 90
2566So, Cheuk-Wai; Watanabe, Daisuke; Wakamiya, Atsushi; Yamaguchi, Shigehiro
Synthesis and Structural Characterization of Pentaarylboroles and Their Dianions
Organometallics, 2008, 27, 3496
4071899 CIFC21 H27 B F4 N2P 41 21 27.4997; 7.4997; 38.126
90; 90; 90
2144.4Grisi, Fabia; Costabile, Chiara; Gallo, Emanuela; Mariconda, Annaluisa; Tedesco, Consiglia; Longo, Pasquale
Ruthenium-Based Complexes Bearing Saturated Chiral N-Heterocyclic Carbene Ligands: Dynamic Behavior and Catalysis
Organometallics, 2008, 27, 4649
4071956 CIFC60 H56 B2 F8 N2 Rh2P 41 21 213.8106; 13.8106; 26.083
90; 90; 90
4974.9Matsuzawa, Hiroshi; Tanabe, Yoshiaki; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Synthesis of Optically ActiveN,N,N′,N′-Tetraphenyl-1,1′-binaphthyl-2,2′-diamine Derivatives as Analogues of BINAP
Organometallics, 2008, 27, 4021
4072057 CIFC48 H64 N4 Na4P 41 21 212.366; 12.366; 29.154
90; 90; 90
4458Liu, Yanyan; Yang, Peiju; Yu, Jie; Yang, Xiao-Juan; Zhang, Jun D.; Chen, Zhongfang; Schaefer, Henry F.; Wu, Biao
Sodium and Magnesium Complexes with Dianionic α-Diimine Ligands
Organometallics, 2008, 27, 5830
4072133 CIFC30 H46 F2 ZrP 4215.502; 15.502; 5.8576
90; 90; 90
1407.7Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072135 CIFC30 H46 Cl2 HfP 4215.3372; 15.3372; 6.4757
90; 90; 90
1523.28Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072136 CIFC30 H46 F2 TiP 4215.3556; 15.3556; 5.7986
90; 90; 90
1367.3Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4072137 CIFC30 H46 F2 HfP 4215.4892; 15.4892; 5.86566
90; 90; 90
1407.26Klahn, Marcus; Arndt, Perdita; Spannenberg, Anke; Gansäuer, Andreas; Rosenthal, Uwe
Menthyl-Substituted Group 4 Metallocene Dihalides
Organometallics, 2008, 27, 5846
4070591 CIFC28 H26 Cl2 F8 N2 O2 TiP 42/n :225.7113; 25.7113; 9.8977
90; 90; 90
6543.1Ye, Wei-Ping; Zhan, Jie; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis and Characterization of Titanium Complexes Bearing Two β-Enaminoketonato Ligands with Electron-Withdrawing Groups and Their Behavior in Ethylene Polymerization
Organometallics, 2008, 27, 3642
4070863 CIFC17 H26 Cl2 O2 RuP 42/n :221.1522; 21.1522; 8.4509
90; 90; 90
3781.1Fairchild, Robert M.; Holman, K. Travis
[(η5-C5Me4CH2R)Ru(η6-arene)]+and [(η5-C5Me4CH2R)Ru(CH3CN)3]+Compounds Possessing Pendant Arms
Organometallics, 2008, 27, 1823
4071733 CIFC25 H40 Cl2 F3 O3 P Ru2 SP 42/n :219.1907; 19.1907; 16.3113
90; 90; 90
6007.2Miyake, Yoshihiro; Endo, Satoshi; Nomaguchi, Yohei; Yuki, Masahiro; Nishibayashi, Yoshiaki
Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Catalytic Activity toward Reactions of Propargylic Alcohols with Aromatic Compounds
Organometallics, 2008, 27, 4017
4070805 CIFC54 H87 B30 Co3 N6 S6P 42/n c m :234.927; 34.927; 16.073
90; 90; 90
19607Zhang, Jia-Sheng; Liu, Shuang; Wang, Guo-Liang; Lin, Yue-Jian; Jin, Guo-Xin
Self-Assembly of Trinuclear Half-Sandwich Metal (Co and Ru) Complexes Containing Ancillaryortho-Carborane-1,2-dithiolato Ligands
Organometallics, 2008, 27, 1112
4072158 CIFC38.73 H37.2 As Cl0.53 F6 O1.37 P2P 61 2 216.4243; 16.4243; 47.099
90; 90; 120
11003.1Coote, Michelle L.; Krenske, Elizabeth H.; Porter, Keith A.; Weir, Michelle L.; Willis, Anthony C.; Zhou, Xiangting; Wild, S. Bruce
Asymmetric Synthesis of a Tertiary Arsine by Nucleophilic Addition to a Chiral Phosphine-Stabilized Arsenium Salt
Organometallics, 2008, 27, 5099
4070515 CIFC43 H32 O6 P2 Ru3 Te4P b c a19.621; 22.168; 23.948
90; 90; 90
10416Begum, Noorjahan; Hyder, Md. Iqbal; Hassan, Mohammad R.; Kabir, Shariff E.; Bennett, Dennis W.; Haworth, Daniel T.; Siddiquee, Tasneem A.; Rokhsana, Dalia; Sharmin, Ayesha; Rosenberg, Edward
Facile E−E and E−C Bond Activation of PhEEPh (E = Te, Se, S) by Ruthenium Carbonyl Clusters: Formation of Di- and Triruthenium Complexes Bearing Bridging dppm and Phenylchalcogenide and Capping Chalcogenido Ligands
Organometallics, 2008, 27, 1550
4070538 CIFC20 H34 Fe I2 N2 O Si2 UP b c a15.1641; 17.782; 20.8018
90; 90; 90
5609.2Monreal, Marisa J.; Diaconescu, Paula L.
A Weak Interaction between Iron and Uranium in Uranium Alkyl Complexes Supported by Ferrocene Diamide Ligands
Organometallics, 2008, 27, 1702
4070561 CIFC55 H75 K La N3 O11 S6P b c a25.1934; 23.1439; 21.3284
90; 90; 90
12436Roger, Mathieu; Belkhiri, Lotfi; Arliguie, Thérèse; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
Uranium and Lanthanide Complexes with the 2-Mercapto Benzothiazolate Ligand: Evidence for a Specific Covalent Binding Site in the Differentiation of Isostructural Lanthanide(III) and Actinide(III) Compounds
Organometallics, 2008, 27, 33
4070562 CIFC55 H75 Ce K N3 O11 S6P b c a25.1464; 23.1691; 21.3386
90; 90; 90
12432.3Roger, Mathieu; Belkhiri, Lotfi; Arliguie, Thérèse; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
Uranium and Lanthanide Complexes with the 2-Mercapto Benzothiazolate Ligand: Evidence for a Specific Covalent Binding Site in the Differentiation of Isostructural Lanthanide(III) and Actinide(III) Compounds
Organometallics, 2008, 27, 33
4070563 CIFC55 H75 K N3 Nd O11 S6P b c a25.0619; 23.1566; 21.2957
90; 90; 90
12358.9Roger, Mathieu; Belkhiri, Lotfi; Arliguie, Thérèse; Thuéry, Pierre; Boucekkine, Abdou; Ephritikhine, Michel
Uranium and Lanthanide Complexes with the 2-Mercapto Benzothiazolate Ligand: Evidence for a Specific Covalent Binding Site in the Differentiation of Isostructural Lanthanide(III) and Actinide(III) Compounds
Organometallics, 2008, 27, 33
4070590 CIFC28 H30 Cl2 F6 N2 O2 TiP b c a19.2495; 16.5177; 19.7412
90; 90; 90
6276.9Ye, Wei-Ping; Zhan, Jie; Pan, Li; Hu, Ning-Hai; Li, Yue-Sheng
Synthesis and Characterization of Titanium Complexes Bearing Two β-Enaminoketonato Ligands with Electron-Withdrawing Groups and Their Behavior in Ethylene Polymerization
Organometallics, 2008, 27, 3642
4070606 CIFC13 H26 B7 Fe O3 PP b c a13.1331; 15.1294; 19.8109
90; 90; 90
3936.3Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
A 10-Vertex Iron−Dicarbollide System Formed by Insertion of {Fe(CO)4} into 8-Vertex [closo-1-CB7H8]−: Synthesis and Reactivity Studies
Organometallics, 2008, 27, 908
4070657 CIFC37 H57 Fe N3 Si2P b c a15.4995; 19.5284; 24.9868
90; 90; 90
7563Fernández, Ignacio; Trovitch, Ryan J.; Lobkovsky, Emil; Chirik, Paul J.
Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3and FeCH2CMe3Derivatives
Organometallics, 2008, 27, 109
4070660 CIFC21 H32 N4 O3 RuP b c a9.258; 16.667; 29.194
90; 90; 90
4504.72Ellul, Charles E.; Saker, Olly; Mahon, Mary F.; Apperley, David C.; Whittlesey, Michael K.
Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)
Organometallics, 2008, 27, 100
4070672 CIFC42 H76 Cl F6 P3 Pd2P b c a17.3322; 19.32; 27.697
90; 90; 90
9274.6Szuromi, Endre; Shen, Han; Goodall, Brian L.; Jordan, Richard F.
Polymerization of Norbornene and Methyl Acrylate by a Bimetallic Palladium(II) Allyl Complex
Organometallics, 2008, 27, 402
4070673 CIFC28 H39 N2 Ni O PP b c a15.268; 17.585; 20.729
90; 90; 90
5565.5Boardman, Brycelyn M.; Valderrama, Juan M.; Muñoz, Flor; Wu, Guang; Bazan, Guillermo C.; Rojas, Rene
Remote Activation of Nickel Complexes by Coordination of B(C6F5)3to an Exocyclic Carbonitrile Functionality
Organometallics, 2008, 27, 1671
4070697 CIFC25 H38 B2 F8 Mo N7P b c a20.015; 14.9142; 20.075
90; 90; 90
5992.5Petrovic, Dejan; Hrib, Cristian G.; Randoll, Sören; Jones, Peter G.; Tamm, Matthias
Synthesis and Reactivity of 16-Electron Cycloheptatrienyl-Molybdenum(0) Complexes with Bis(imidazolin-2-imine) Ligands
Organometallics, 2008, 27, 778
4070724 CIFC24 H27 B F Fe N SnP b c a12.0378; 15.882; 23.9342
90; 90; 90
4575.84Boshra, Ramez; Doshi, Ami; Jäkle, Frieder
Fluoride-Promoted Aryl and Allyl Migration from Boron to Tin in 1-Stannyl-2-borylferrocenes
Organometallics, 2008, 27, 1534
4070733 CIFC22 H34 Cl Ir2 N O3 SP b c a16.469; 15.342; 20.655
90; 90; 90
5219Arita, Hiroko; Ishiwata, Koji; Kuwata, Shigeki; Ikariya, Takao
Acid‒Base Bifunction and Umpolung of the Bridging Hydride in a Coordinatively Unsaturated Mesylimido- and Hydrido-Bridged Diiridium Complex
Organometallics, 2008, 27, 493
4070741 CIFC38 H66 B Br2 N P2 PtP b c a17.1174; 19.8926; 23.6733
90; 90; 90
8061Braunschweig, Holger; Leech, Ralph; Rais, Daniela; Radacki, Krzysztof; Uttinger, Katharina
Conversion oftrans-Bromoboryl Platinum Complexes into theircis-Analogues upon Treatment with Chelating Bisphosphines
Organometallics, 2008, 27, 418
4070760 CIFC31 H35 Ir N2 O2 SP b c a15.6216; 17.8559; 20.3673
90; 90; 90
5681.2Heiden, Zachariah M.; Gorecki, Bradford J.; Rauchfuss, Thomas B.
Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity
Organometallics, 2008, 27, 1542
4070764 CIFC32 H36 B F4 Ir N2 O3 SP b c a13.4004; 16.9251; 28.495
90; 90; 90
6462.8Heiden, Zachariah M.; Gorecki, Bradford J.; Rauchfuss, Thomas B.
Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity
Organometallics, 2008, 27, 1542
4070769 CIFC15 H20 Cl2 Ir N SP b c a9.11; 16; 23.7
90; 90; 90
3455Han, Ying-Feng; Huang, Yuan-Biao; Lin, Yue-Jian; Jin, Guo-Xin
Synthesis, Characterization, and Norbornene Polymerization Behavior of the Half-Sandwich Complexes [Cp*3M3(μ3-L)Cl3] and [Cp*M(2-SPyH)Cl2] (M = Ir, M = Rh, [L]3−= 1,3,5-Triazine-2,4,6-trithiolato, 2-SPy = 2-Pyridinethione)
Organometallics, 2008, 27, 961
4070770 CIFC15 H20 Cl2 N Rh SP b c a9.0377; 16.064; 23.757
90; 90; 90
3449.1Han, Ying-Feng; Huang, Yuan-Biao; Lin, Yue-Jian; Jin, Guo-Xin
Synthesis, Characterization, and Norbornene Polymerization Behavior of the Half-Sandwich Complexes [Cp*3M3(μ3-L)Cl3] and [Cp*M(2-SPyH)Cl2] (M = Ir, M = Rh, [L]3−= 1,3,5-Triazine-2,4,6-trithiolato, 2-SPy = 2-Pyridinethione)
Organometallics, 2008, 27, 961
4070815 CIFC15 H22 B F3 O PtP b c a13.6535; 11.685; 18.6671
90; 90; 90
2978.2Wu, Jianguo; Sharp, Paul R.
A Family of Platinaoxetanes
Organometallics, 2008, 27, 1234
4070836 CIFC37 H53 F6 P Ru3P b c a17.9482; 19.5298; 20.9501
90; 90; 90
7343.5Takao, Toshiro; Moriya, Makoto; Suzuki, Hiroharu
Insertion of Acetylene and Nitriles into a Ru‒C Bond of a Dicationic Triruthenium Complex Having a μ~3~-η^3^-C~3~ Ring: Formation of Six-Membered Ruthenacycles on a Triruthenium Core
Organometallics, 2008, 27, 1044-1054
4070912 CIFC52 H112 N12 Sr2P b c a15.289; 23.481; 34.845
90; 90; 90
12509Cameron, Thomas M.; Xu, Chongying; Dipasquale, Antonio G.; Rheingold, Arnold L.
Synthesis and Structure of Strontium and Barium Guanidinates and Mixed-Ligand Guanidinate Pentamethylcyclopentadienyl Complexes
Organometallics, 2008, 27, 1596
4070918 CIFC15 H19 Co I N SP b c a8.376; 16.629; 23.453
90; 90; 90
3267Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4070920 CIFC17 H30 B10 Co N S2P b c a10.934; 19.396; 23.402
90; 90; 90
4963Liu, Shu; Wang, Hui; Zhang, Peng-Cheng; Weng, Lin-Hong; Hou, Xiu-Feng
Synthesis and Structure of Half-Sandwich Pyridine-2-thiolato Cobalt(III) and Rhodium(III) Complexes and Their Reactivity toward Monodentate or Bidentate 1,2-Dicarba-closo-dodecaborane Thiolate Ligands
Organometallics, 2008, 27, 713
4070925 CIFC27 H34 Cl F6 Ir N2 P2P b c a12.837; 18.8931; 23.392
90; 90; 90
5673.3Song, Guoyong; Wang, Xinjiao; Li, Yongxin; Li, Xingwei
Iridium Abnormal N-Heterocyclic Carbene Hydrides via Highly Selective C−H Activation
Organometallics, 2008, 27, 1187
4070938 CIFC33 H44 B Cl4 P RuP b c a17.312; 13.681; 28.015
90; 90; 90
6635Vergnaud, Jérôme; Grellier, Mary; Bouhadir, Ghenwa; Vendier, Laure; Sabo-Etienne, Sylviane; Bourissou, Didier
Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]
Organometallics, 2008, 27, 1140
4070963 CIFC46 H64 Fe N6P b c a17.6967; 18.5086; 25.923
90; 90; 90
8490.8Sciarone, Timo J. J.; Nijhuis, Christian A.; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Paramagnetic Amino-amidinate Iron(II) Complexes:19F NMR Evidence for Interactions with Weakly Coordinating Anions
Organometallics, 2008, 27, 2058
4070975 CIFC22 H52 Cl0.37 N2.26 P2 Rh Si2P b c a15.1597; 12.5004; 31.331
90; 90; 90
5937.3Verat, Alexander Y.; Pink, Maren; Fan, Hongjun; Tomaszewski, John; Caulton, Kenneth G.
[(tBu2PCH2SiMe2)2N]RhI? Rapidly Reversible H−C(sp3) and H−C(sp2) Bond Cleavage by Rhodium(I)
Organometallics, 2008, 27, 166
4070985 CIFC22 H56 Hf Li2 N4P b c a21.61; 17.342; 32.154
90; 90; 90
12050Morse, Paige M.; Shelby, Quinetta D.; Kim, Do Young; Girolami, Gregory S.
Ethylene Complexes of the Early Transition Metals: Crystal Structures of [HfEt4(C2H4)2−] and the Negative-Oxidation-State Species [TaHEt(C2H4)33−] and [WH(C2H4)43−]
Organometallics, 2008, 27, 984
4070987 CIFC26 H65 Li3 N6 WP b c a15.3935; 13.3225; 34.6471
90; 90; 90
7105.4Morse, Paige M.; Shelby, Quinetta D.; Kim, Do Young; Girolami, Gregory S.
Ethylene Complexes of the Early Transition Metals: Crystal Structures of [HfEt4(C2H4)2−] and the Negative-Oxidation-State Species [TaHEt(C2H4)33−] and [WH(C2H4)43−]
Organometallics, 2008, 27, 984
4070997 CIFC29 H51 O2 P3 Ru Si2P b c a17.0553; 20.1437; 19.2039
90; 90; 90
6597.6Okazaki, Masaaki; Yamahira, Nobukazu; Minglana, Jim Josephus Gabrillo; Komuro, Takashi; Ogino, Hiroshi; Tobita, Hiromi
[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
Organometallics, 2008, 27, 918
4071046 CIFC34 H48 Cl8 O Os P4P b c a16.1222; 17.089; 32.257
90; 90; 90
8887.2Gong, Lei; Lin, Yumei; He, Guomei; Zhang, Hong; Wang, Huijuan; Wen, Ting Bin; Xia, Haiping
Synthesis and Characterization of an Air-Stablep-Osmaphenol
Organometallics, 2008, 27, 309
4071109 CIFC18 H40 P4 TiP b c a13.78; 17.776; 18.726
90; 90; 90
4587You, Yujian; Girolami, Gregory S.
Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Dimerization and Trimerization Catalysis
Organometallics, 2008, 27, 3172
4071148 CIFC38 H41 N Ni P2P b c a10.827; 16.74; 36.494
90; 90; 90
6614Liang, Lan-Chang; Chien, Pin-Shu; Lee, Pei-Ying
Phosphorus and Olefin Substituent Effects on the Insertion Chemistry of Nickel(II) Hydride Complexes Containing Amido Diphosphine Ligands
Organometallics, 2008, 27, 3082
4071163 CIFC26 H36 Br2 N4 NiP b c a17.0371; 9.4576; 17.5727
90; 90; 90
2831.5Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071165 CIFC30 H44 Br2 N4 NiP b c a11.2799; 15.3817; 18.4142
90; 90; 90
3194.9Huynh, Han Vinh; Wong, Ling Rong; Ng, Pearly Shuyi
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II)
Organometallics, 2008, 27, 2231
4071187 CIFC18 H27 Cl OsP b c a14.18; 13.87; 16.468
90; 90; 90
3238.9Dub, Pavel A.; Belkova, Natalia V.; Lyssenko, Konstantin A.; Silantyev, Gleb A.; Epstein, Lina M.; Shubina, Elena S.; Daran, Jean-Claude; Poli, Rinaldo
Synthesis and Protonation Studies of Cp*Os(dppe)H: Kinetic versus Thermodynamic Control
Organometallics, 2008, 27, 3307
4071229 CIFC18 H46 Ir P3 SiP b c a15.8275; 17.7785; 17.9098
90; 90; 90
5039.6Bleeke, John R.; Thananatthanachon, Todsapon; Rath, Nigam P.
Silapentadienyl−Iridium−Phosphine Chemistry(1)
Organometallics, 2008, 27, 2436
4071236 CIFC18 H22 N2 O2 PdP b c a10.1646; 17.4207; 18.9964
90; 90; 90
3363.8Giri, Ramesh; Maugel, Nathan; Foxman, Bruce M.; Yu, Jin-Quan
Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex
Organometallics, 2008, 27, 1667
4071261 CIFC27 H45 N2 Si SmP b c a16.093; 21.424; 33.139
90; 90; 90
11426Evans, William J.; Montalvo, Elizabeth; Champagne, Timothy M.; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.
Diazomethane Insertion into Lanthanide− and Yttrium−C(allyl) Bonds To Form the η2-Hydrazonato Complexes (C5Me5)2Ln[η2(N,N′)-RNNCHSiMe3] (R = C3H5)
Organometallics, 2008, 27, 3582
4071292 CIFC14 H34 Fe O6 P4P b c a16.5175; 16.1088; 16.6269
90; 90; 90
4424.04Allen, Olivia R.; Dalgarno, Scott J.; Field, Leslie D.; Jensen, Paul; Turnbull, Anthony J.; Willis, Anthony C.
Addition of CO2to Alkyl Iron Complexes, Fe(PP)2Me2
Organometallics, 2008, 27, 2092
4071342 CIFC37 H44 N4 TiP b c a20.6472; 12.2032; 25.668
90; 90; 90
6467.4Vujkovic, Nadia; Fillol, Julio Lloret; Ward, Benjamin D.; Wadepohl, Hubert; Mountford, Philip; Gade, Lutz H.
Insertions into Azatitanacyclobutenes: New Insights into Three-Component Coupling Reactions Involving Imidotitanium Intermediates
Organometallics, 2008, 27, 2518
4071343 CIFC38 H46 N4 TiP b c a21.266; 12.788; 24.435
90; 90; 90
6645Vujkovic, Nadia; Fillol, Julio Lloret; Ward, Benjamin D.; Wadepohl, Hubert; Mountford, Philip; Gade, Lutz H.
Insertions into Azatitanacyclobutenes: New Insights into Three-Component Coupling Reactions Involving Imidotitanium Intermediates
Organometallics, 2008, 27, 2518
4071351 CIFC27 H40 Cl2 N4 TiP b c a16.2363; 17.0367; 43.781
90; 90; 90
12110.4Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071357 CIFC19 H27 Cl Ir NP b c a21.0572; 15.9155; 22.0458
90; 90; 90
7388.3Arita, Sachiko; Koike, Takashi; Kayaki, Yoshihito; Ikariya, Takao
Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands
Organometallics, 2008, 27, 2795
4071416 CIFC23 H37 Mo N OP b c a8.8589; 17.727; 27.619
90; 90; 90
4337.3Graham, Peter M.; Buschhaus, Miriam S. A.; Pamplin, Craig B.; Legzdins, Peter
Reactivity of Cp*Mo(NO)(CHCMe3) with Olefins and Dienes: C−H Activation Reactions of Molybdenacyclobutanes
Organometallics, 2008, 27, 2840
4071421 CIFC32 H51 O3 S2 Sc SiP b c a10.604; 17.3; 38.19
90; 90; 90
7006Konkol, Marcin; Kondracka, Malgorzata; Voth, Peter; Spaniol, Thomas P.; Okuda, Jun
Rare-Earth Metal Alkyl and Hydrido Complexes Containing a Thioether-Functionalized Bis(phenolato) Ligand: Efficient Catalysts for Olefin Hydrosilylation
Organometallics, 2008, 27, 3774
4071435 CIFC55 H94 B22 Ir N4 O P2 Sn2P b c a18.7819; 21.2139; 35.3915
90; 90; 90
14101.3Kirchmann, Marius; Fleischhauer, Sebastian; Wesemann, Lars
Iridium Coordination Compounds of Stanna-closo-dodecaborate
Organometallics, 2008, 27, 2803
4071452 CIFC21 H17 Cl N3 P PdP b c a15.467; 15.8451; 15.8451
90; 90; 90
3883.3Inés, Blanca; SanMartin, Raul; Churruca, Fátima; Domínguez, Esther; Urtiaga, Miren Karmele; Arriortua, María Isabel
A Nonsymmetric Pincer-Type Palladium Catalyst In Suzuki, Sonogashira, and Hiyama Couplings in Neat Water
Organometallics, 2008, 27, 2833
4071471 CIFC22 H42 Cl2 Ir N3P b c a13.539; 23.098; 32.279
90; 90; 90
10094.4Gott, Andrew L.; McGowan, Patrick C.; Temple, Claire N.
Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
Organometallics, 2008, 27, 2852
4071516 CIFC40 H40 N4 O2 Pd2P b c a19.0732; 15.3618; 24.6074
90; 90; 90
7209.9Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Jones, Peter G.; Bautista, Delia
New Palladacycles Containing Terdentate [C,N,O]n−(n= 0, 1, 2) or Tetradentate [N,C,O,N′]n−(n= 1, 2) Ligands. The First 1,2-Dihydroquinazoline-4-yl Complexes
Organometallics, 2008, 27, 3254
4071565 CIFC34 H75 N O8 Zr2P b c a17.1407; 19.184; 26.3148
90; 90; 90
8653Lorber, Christian; Choukroun, Robert; Vendier, Laure
Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling
Organometallics, 2008, 27, 5017
4071584 CIFC39 H34 Fe2 N2 O2P b c a16.871; 9.3341; 37.956
90; 90; 90
5977.1Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4071654 CIFC36 H51 Cl2 N3 P2 RuP b c a18.0783; 14.7973; 27.1111
90; 90; 90
7252.5Zhang, Jing; Gandelman, Mark; Shimon, Linda J. W.; Milstein, David
Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes
Organometallics, 2008, 27, 3526
4071692 CIFC32 H29 O P RuP b c a16.843; 19.073; 15.619
90; 90; 90
5018Hirano, Masafumi; Kuga, Toshinori; Kitamura, Mariko; Kanaya, Susumu; Komine, Nobuyuki; Komiya, Sanshiro
Acid-Promoted Hydrogen Migration in (2-Allylphenoxo)ruthenium(II) To Form an η3-Allyl Complex
Organometallics, 2008, 27, 3635
4071715 CIFC11 H17 Cl O PdP b c a8.2836; 13.7315; 19.6036
90; 90; 90
2229.8Vicente, José; Arcas, Aurelia; Fernández-Hernández, Jesús M.; Bautista, Delia
New Acetonyl Palladium(II) Complexes
Organometallics, 2008, 27, 3978
4071723 CIFC32 H37 Fe PP b c a15.499; 15.257; 22.8414
90; 90; 90
5401.27Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki
Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C6F5)3†
Organometallics, 2008, 27, 5279
4071749 CIFC32 H34 Cl3 Cr N2 P2P b c a10.8132; 17.3988; 34.178
90; 90; 90
6430.1Teo, Shihui; Weng, Zhiqiang; Hor, T. S. Andy
Unusual Ligand Transformation Mediated by Chromium(III): Hydrolytic Disintegration of a [PNP] Hybrid Ligand with CH3CN Insertion
Organometallics, 2008, 27, 4188
4071772 CIFC14 H20 Co F6 P Si2P b c a13.1738; 12.7807; 21.3933
90; 90; 90
3602Braunschweig, Holger; Breher, Frank; Kaupp, Martin; Gross, Manuela; Kupfer, Thomas; Nied, Dominik; Radacki, Krzysztof; Schinzel, Sandra
Synthesis, Crystal Structure, EPR and DFT Studies, and Redox Properties of [2]Tetramethyldisilacobaltocenophane
Organometallics, 2008, 27, 6427
4071829 CIFC27 H47 Cl2 P RuP b c a16.7222; 14.4243; 22.8272
90; 90; 90
5506.1Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4071889 CIFC17 H34 B9 NP b c a9.3447; 13.4617; 34.022
90; 90; 90
4279.8Liu, Dongmei; Wang, Yaorong; Chan, Hoi-Shan; Tang, Yong; Xie, Zuowei
Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3−
Organometallics, 2008, 27, 5295
4071903 CIFC29 H35 Cl N O6 Os PP b c a17.82; 16.545; 19.229
90; 90; 90
5669.3Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique; Valencia, Marta
Osmium-Catalyzed Allylic Alkylation
Organometallics, 2008, 27, 4892
4072023 CIFC39 H61 P3P b c a21.285; 12.164; 29.355
90; 90; 90
7600Ionkin, Alex S.; Marshall, William J.; Fish, Brian M.; Marchione, Alexander A.; Howe, Laurie A.; Davidson, Fredric; McEwen, Charles N.
Dual Supermesityl Stabilization: 1-Alkyl-1H-[1,2,4]triphospholes, with Among the Most Planar and Least Sterically Hindered σ3,λ3-Phosphorus Atoms, and Novel C2P3S4Folded Heterocycles†
Organometallics, 2008, 27, 5118
4072038 CIFC24 H58 N3 Sc Si3P b c a18.668; 17.479; 19.473
90; 90; 90
6354Ge, Shaozhong; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Rare Earth Metal Alkyl and Benzyl Compounds with the 1,4,6-Trimethyl-6-pyrrolidin-1-yl-1,4-diazepane Ligand and Their Performance in the Catalytic Hydroamination/Cyclization of Aminoalkenes
Organometallics, 2008, 27, 5339
4072039 CIFC24 H58 N3 Si3 YP b c a17.211; 17.984; 20.309
90; 90; 90
6286.1Ge, Shaozhong; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Rare Earth Metal Alkyl and Benzyl Compounds with the 1,4,6-Trimethyl-6-pyrrolidin-1-yl-1,4-diazepane Ligand and Their Performance in the Catalytic Hydroamination/Cyclization of Aminoalkenes
Organometallics, 2008, 27, 5339
4072043 CIFC34 H76 Br4 Ni2 P4P b c a23.6525; 14.4554; 27.611
90; 90; 90
9440.4Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072049 CIFC17 H37 Br2 Ni P2P b c a14.0098; 16.2434; 38.914
90; 90; 90
8855.5Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4072122 CIFC58 H46 Au2 Fe3 P2P b c a14.6431; 11.779; 27.4725
90; 90; 90
4738.5Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Reactions of Gold(I) Acetylides with 1,1′-Diisocyanoferrocene: From Orthodox to Unorthodox Behavior
Organometallics, 2008, 27, 6419
4072124 CIFC10 H24 B9 Fe N SP b c a9.441; 15.717; 22.341
90; 90; 90
3315.1Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4072206 CIFC36 H42 Cl2 N3 PdP b c a13.6779; 14.7453; 32.7016
90; 90; 90
6595.4Broggi, Julie; Clavier, Hervé; Nolan, Steven P.
N-Heterocyclic Carbenes (NHCs) ContainingN-C-Palladacycle Complexes: Synthesis and Reactivity in Aryl Amination Reactions
Organometallics, 2008, 27, 5525
4072218 CIFC18 H18 Cl2 N2 O4 S SiP b c a12.2777; 16.159; 20.531
90; 90; 90
4073.3Metz, Stefan; Burschka, Christian; Tacke, Reinhold
A Neutral Pentacoordinate Silicon(IV) Complex with a Monodentate Nitrato Ligand: Synthesis and Structural Characterization
Organometallics, 2008, 27, 6032
4072230 CIFC30 H45 TiP b c a14.953; 17.0466; 21.464
90; 90; 90
5471.1Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072267 CIFC30 H46 Ge2 N4P b c a20.397; 14.12; 21.943
90; 90; 90
6319.7Nagendran, Selvarajan; Sen, Sakya S.; Roesky, Herbert W.; Koley, Debasis; Grubmüller, Helmut; Pal, Aritra; Herbst-Irmer, Regine
RGe(I)Ge(I)R Compound (R = PhC(NtBu)2) with a Ge−Ge Single Bond and a Comparison with the Gauche Conformation of Hydrazine†
Organometallics, 2008, 27, 5459
4072303 CIFC51 H59 N P2 RuP b c a15.986; 22.708; 23.811
90; 90; 90
8643.6Rankin, Matthew A.; Schatte, Gabriele; McDonald, Robert; Stradiotto, Mark
Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage
Organometallics, 2008, 27, 6286
4072349 CIFC58 H65 B F20 N P TiP b c a21.327; 20.487; 26.1
90; 90; 90
11404Friesen, Dawn M.; Piers, Warren E.; Parvez, Masood
Selective Catalytic Dimerization of Neohexene by [Cp*Ti(NPtBu3)Me][B(C6F5)4]
Organometallics, 2008, 27, 6596
4072353 CIFC10 H13 N O2 SiP b c a12.1828; 9.7269; 18.0635
90; 90; 90
2140.54Wagler, Jörg; Hill, Anthony F.
Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Organometallics, 2008, 27, 6579
4072407 CIFC84 H124 B2 F2 N2P b c a19.6359; 19.7648; 22.712
90; 90; 90
8814.5Zhao, Shu-Bin; Wucher, Philipp; Hudson, Zachary M.; McCormick, Theresa M.; Liu, Xiang-Yang; Wang, Suning; Feng, Xiao-Dong; Lu, Zheng-Hong
Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes2Groups and the Peculiar Behavior of 1,6-(BMes2)2pyrene
Organometallics, 2008, 27, 6446
4071836 CIFC25 H39 Cl4 Ir2 N3 OP b c m8.4528; 15.0376; 23.8627
90; 90; 90
3033.2Zanardi, Alessandro; Corberán, Rosa; Mata, José A.; Peris, Eduardo
Homo- and Heterodinuclear Complexes with Triazolyl-diylidene. An Easy Approach to Tandem Catalysts⊥
Organometallics, 2008, 27, 3570
4070582 CIFC32 H50 Cl2 N4 Rh2P b c n11.8636; 22.2177; 12.4686
90; 90; 90
3286.5Wells, Kyle D.; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
A-Frame Complexes of Dirhodium Bridged by Dicarbene and Diphosphine Ligands
Organometallics, 2008, 27, 691
4070656 CIFC34 H46 Fe N3P b c n32.313; 9.3004; 22.451
90; 90; 90
6747.1Fernández, Ignacio; Trovitch, Ryan J.; Lobkovsky, Emil; Chirik, Paul J.
Synthesis of Bis(imino)pyridine Iron Di- and Monoalkyl Complexes: Stability Differences between FeCH2SiMe3and FeCH2CMe3Derivatives
Organometallics, 2008, 27, 109
4070713 CIFC53 H65 N3 P Rh Si4 SnP b c n42.049; 12.9598; 19.6423
90; 90; 90
10704Kilian, Michaela; Wadepohl, Hubert; Gade, Lutz H.
Triamidostannates(II) as Sterically Demanding Ligands for Rhodium and Iridium
Organometallics, 2008, 27, 524
4070789 CIFC34 H54 N4 O2 SrP b c n15.9678; 11.0432; 19.2699
90; 90; 90
3398Datta, Simmi; Gamer, Michael T.; Roesky, Peter W.
Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
Organometallics, 2008, 27, 1207
4070790 CIFC34 H54 Ba N4 O2P b c n15.5788; 11.1267; 19.8676
90; 90; 90
3443.9Datta, Simmi; Gamer, Michael T.; Roesky, Peter W.
Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
Organometallics, 2008, 27, 1207
4070973 CIFC49 H46 N4 O3 Pd Si2P b c n8.8297; 27.9592; 18.1044
90; 90; 90
4469.46Sangtrirutnugul, Preeyanuch; Tilley, T. Don
Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand
Organometallics, 2008, 27, 2223
4071136 CIFC14 H20 Mo S2P b c n13.271; 6.9263; 15.256
90; 90; 90
1402.3Kuo, Louis Y.; Adint, Tyler T.; Akagi, Allison E.; Zakharov, Lev
Degradation of a VX Analogue: First Organometallic Reagent To Promote Phosphonothioate Hydrolysis Through Selective P−S Bond Scission
Organometallics, 2008, 27, 2560
4071337 CIFC58 H42 Cl6 P2P b c n21.604; 31.37; 23.903
90; 90; 90
16199Doherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William
Biaryl-Like CATPHOS Diphosphines via Double Diels‒Alder Cycloaddition between 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne and Anthracenes: Efficient Ligands for the Palladium-Catalyzed Amination of Aromatic Bromides and α-Arylation of Ketones
Organometallics, 2008, 27, 1679
4071686 CIFC76 H105 Fe P4 Pt Si6P b c n28.8668; 23.9088; 22.9488
90; 90; 90
15838.6Nagahora, Noriyoshi; Sasamori, Takahiro; Tokitoh, Norihiro
A Ferrocenyldiphosphene−Platinum Complex: Structural Features and Theoretical Calculations
Organometallics, 2008, 27, 4265
4071833 CIFC22 H41 Cl5 P Ru2P b c n18.0407; 13.7759; 22.9357
90; 90; 90
5700.1Wolf, Joffrey; Thommes, Katrin; Briel, Oliver; Scopelliti, Rosario; Severin, Kay
Dinuclear Ruthenium Ethylene Complexes: Syntheses, Structures, and Catalytic Applications in ATRA and ATRC Reactions
Organometallics, 2008, 27, 4464
4072182 CIFC26 H41 F6 Mo N O8.5 S2P b c n34.32; 14.82; 14.379
90; 90; 90
7313Lokare, Kapil S.; Staples, Richard J.; Odom, Aaron L.
Synthesis, Properties, and Structure of Tethered Molybdenum Alkylidenes
Organometallics, 2008, 27, 5130
4072410 CIFC45 H63 B F NP b c n18.9303; 23.0165; 19.0849
90; 90; 90
8315.5Zhao, Shu-Bin; Wucher, Philipp; Hudson, Zachary M.; McCormick, Theresa M.; Liu, Xiang-Yang; Wang, Suning; Feng, Xiao-Dong; Lu, Zheng-Hong
Impact of the Linker on the Electronic and Luminescent Properties of Diboryl Compounds: Molecules with Two BMes2Groups and the Peculiar Behavior of 1,6-(BMes2)2pyrene
Organometallics, 2008, 27, 6446
4070806 CIFC99 H141 B30 Co3 N6 S9P c a 2126.785; 11.49; 37.643
90; 90; 90
11585Zhang, Jia-Sheng; Liu, Shuang; Wang, Guo-Liang; Lin, Yue-Jian; Jin, Guo-Xin
Self-Assembly of Trinuclear Half-Sandwich Metal (Co and Ru) Complexes Containing Ancillaryortho-Carborane-1,2-dithiolato Ligands
Organometallics, 2008, 27, 1112
4070807 CIFC99 H141 B30 Co3 N6 S9P c a 2126.785; 11.49; 37.643
90; 90; 90
11585Zhang, Jia-Sheng; Liu, Shuang; Wang, Guo-Liang; Lin, Yue-Jian; Jin, Guo-Xin
Self-Assembly of Trinuclear Half-Sandwich Metal (Co and Ru) Complexes Containing Ancillaryortho-Carborane-1,2-dithiolato Ligands
Organometallics, 2008, 27, 1112
4071047 CIFC37 H32 N O3 P3 SP c a 2116.1548; 9.2541; 22.0546
90; 90; 90
3297.12Cadierno, Victorio; Díez, Josefina; García-Álvarez, Joaquín; Gimeno, José
(η6-Arene)−Ruthenium(II) Complexes Containing Methanide and Methandiide Anions of Ph2P(S)CH2P(NR)Ph2: Unprecedented Insertion of Isocyanide into a Ruthenium−Carbene Bond
Organometallics, 2008, 27, 1809
4072052 CIFC29 H37 YP c a 2116.4646; 10.5009; 14.7315
90; 90; 90
2547Quiroga Norambuena, Victor F.; Heeres, André; Heeres, Hero J.; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
Organometallics, 2008, 27, 5672
4072083 CIFC32 H28 N2 O11 Os4P c a 2127.9147; 16.5133; 15.2219
90; 90; 90
7016.7Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4072123 CIFC5 H20 B9 N SP c a 2118.4915; 6.7105; 10.2849
90; 90; 90
1276.22Perekalin, Dmitry S.; Glukhov, Ivan V.; Holub, Josef; Císařova, Ivana; Štíbr, Bohumil; Kudinov, Alexander R.
Iron and Cobalt Complexes with Thiacarborane Ligands
Organometallics, 2008, 27, 5273
4072176 CIFC6 H17 B10 N OP c a 2116.7029; 7.4094; 19.8847
90; 90; 90
2460.9Mukhin, Sergey N.; Kabytaev, Kuanysh Z.; Zhigareva, Galina G.; Glukhov, Ivan V.; Starikova, Zoya A.; Bregadze, Vladimir I.; Beletskaya, Irina P.
Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom
Organometallics, 2008, 27, 5937
4072232 CIFC32 H53 Si3 TiP c a 2119.3155; 12.015; 28.9179
90; 90; 90
6711.1Pinkas, J.; Císařová, I.; Gyepes, R.; Horáček, M.; Kubišta, J.; Čejka, J.; Gómez-Ruiz, S.; Hey-Hawkins, E.; Mach, K.
Insertion of Internal Alkynes and Ethene into Permethylated Singly Tucked-in Titanocene
Organometallics, 2008, 27, 5532
4072346 CIFC19 H53 Li2 N7 ZnP c a 2117.316; 9.1221; 17.9321
90; 90; 90
2832.52Armstrong, David R.; Dougan, Christine; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Synthesis and Structural Elucidation of Alkyl, Amido, and Mixed Alkyl−Amido “Highly-Coordinated” Zincates
Organometallics, 2008, 27, 6063
4071089 CIFC24 H29 F6 Fe N2 P PdP c a b16.99; 17.24; 17.647
90; 90; 90
5168.9Pérez, Sonia; López, Concepción; Bosque, Ramon; Solans, Xavier; Font-Bardía, Mercè; Roig, Anna; Molins, Elies; van Leeuwen, Piet W. N. M.; van Strijdonck, Gino P. F.; Freixa, Zoraida
Chelate-Size Effects on the Structures, Chemical Behavior, Properties, and Catalytic Activity of the New Palladium(II)−Allyl Complexes [Pd(η3-1-R1-C3H4){FcCHN-CH2-(CH2)n-NMe2}][PF6] {Fc = (η5-C5H5)Fe(η5-C5H4),n= 2 or 1, and R1= H or Ph}
Organometallics, 2008, 27, 4288
4071349 CIFC35 H48 Cl2 N4 TiP c a b13.2517; 42.872; 13.2474
90; 90; 90
7526.2Lorber, Christian; Vendier, Laure
Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes
Organometallics, 2008, 27, 2774
4071688 CIFC17 H21 Cl2 N TiP c a b13.201; 14.92; 17.373
90; 90; 90
3421.77Wu, Chun Ji; Lee, Sang Hoon; Yu, Seung Tack; Na, Sung Jae; Yun, Hoseop; Lee, Bun Yeoul
CO2-Mediatedortho-Lithiation ofN-Alkylanilines and Its Use for the Construction of Polymerization Catalysts
Organometallics, 2008, 27, 3907
4071633 CIFC26 H37 N2 O10.5 S2P c c a27.712; 10.5495; 20.635
90; 90; 90
6033Ananikov, Valentine P.; Orlov, Nikolay V.; Kabeshov, Mikhail A.; Beletskaya, Irina P.; Starikova, Zoya A.
Stereodefined Synthesis of a New Type of 1,3-Dienes by Ligand-Controlled Carbon−Carbon and Carbon−Heteroatom Bond Formation in Nickel-Catalyzed Reaction of Diaryldichalcogenides with Alkynes
Organometallics, 2008, 27, 4056
4070617 CIFC16 H12 N4 O8 Re2P c c n12.0644; 14.0753; 11.8832
90; 90; 90
2017.89Wu, Jing-Yun; Thanasekaran, P.; Cheng, Yi-Wei; Lee, Chung-Chou; Manimaran, B.; Rajendran, T.; Liao, Rong-Tang; Lee, Gene-Hsiang; Peng, Shie-Ming; Lu, Kuang-Lieh
Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles
Organometallics, 2008, 27, 2141
4071215 CIFC26 H36 Hf2 P2P c c n17.472; 22.229; 12.832
90; 90; 90
4983.8Zirngast, Michaela; Marschner, Christoph; Baumgartner, Judith
Group 4 Metallocene Complexes of Tris(trimethylsilyl)silylacetylene and Related Alkynes
Organometallics, 2008, 27, 2570
4071336 CIFC44 H48 N4 Ni O2P c c n10.7392; 18.4417; 20.2836
90; 90; 90
4017.1Scott, Natalie M.; Clavier, Hervé; Mahjoor, Parisa; Stevens, Edwin D.; Nolan, Steven P.
Synthetic, Structural, and Thermochemical Studies of N-Heterocyclic Carbene (NHC) and Tertiary Phosphine Ligands in the [(L)2Ni(CO)2] (L = PR3, NHC) System
Organometallics, 2008, 27, 3181
4071673 CIFC68 H15 Mo N O3 S2P c c n27.28; 14.993; 19.193
90; 90; 90
7850.1Matsuo, Yutaka; Iwashita, Akihiko; Nakamura, Eiichi
Group 6 Metal Complexes of the η5-Pentamethyl[60]fullerene
Organometallics, 2008, 27, 4611
4071748 CIFC33 H48 Ir N O P2P c c n11.0661; 14.367; 20.2719
90; 90; 90
3222.96Romero, Patricio E.; Whited, Matthew T.; Grubbs, Robert H.
Multiple C−H Activations of Methyltert-Butyl Ether at Pincer Iridium Complexes: Synthesis and Thermolysis of Ir(I) Fischer Carbenes1
Organometallics, 2008, 27, 3422
4071957 CIFC29 H40 Si2 ZrP c c n37.304; 16.6904; 8.9689
90; 90; 90
5584.2Alonso-Moreno, Carlos; Lancaster, Simon J.; Wright, Joseph A.; Hughes, David L.; Zuccaccia, Cristiano; Correa, Andrea; Macchioni, Alceo; Cavallo, Luigi; Bochmann, Manfred
Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)
Organometallics, 2008, 27, 5474
4072112 CIFC30 H52 Ca N3 O Si2P c c n34.0276; 10.3059; 19.5596
90; 90; 90
6859.3Piesik, Dirk F.-J.; Range, Sven; Harder, Sjoerd
Bimetallic Calcium and Zinc Complexes with Bridged β-Diketiminate Ligands: Investigations on Epoxide/CO2Copolymerization
Organometallics, 2008, 27, 6178
4083501 CIFC73.5 H86 Cl4 F12 Ir4 N4 O22.5 S4P c c n21.38; 29.82; 32.3
90; 90; 90
20593Han, Ying-Feng; Lin, Yue-Jian; Jia, Wei-Guo; Jin, Guo-Xin
Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands†
Organometallics, 2008, 27, 4088
4071876 CIFC26 H53 B F4 O2 Os P2P m m n :213.041; 14.089; 8.462
90; 90; 90
1554.8Buil, María L.; Esteruelas, Miguel A.; Garcés, Karin; Oliván, Montserrat; Oñate, Enrique
Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands
Organometallics, 2008, 27, 4680
4071587 CIFC53 H46 Cl4 Fe2 N2 O2P m n 2128.871; 7.5729; 10.514
90; 90; 90
2298.8Li, Jie; Ma, Jian-Ping; Liu, Fengling; Wu, Xiang-Wen; Dong, Yu-Bin; Huang, Ru-Qi
A New Approach for Ferrocenyl-Cyclopentenone and Ferrocenyl-Cyclopentenedione Compound Synthesis
Organometallics, 2008, 27, 5446
4070527 CIFC21 H24 Cl3 N3 PtP n a 2125.7528; 6.9451; 24.4159
90; 90; 90
4366.92Batema, Guido D.; Lutz, Martin; Spek, Anthony L.; van Walree, Cornelis A.; Donegá, Celso de Mello; Meijerink, Andries; Havenith, Remco W. A.; Pérez-Moreno, Javier; Clays, Koen; Büchel, Michael; Dijken, Addy van; Bryce, David L.; van Klink, Gerard P. M.; Koten, Gerard van
Substituted 4,4′-Stilbenoid NCN-Pincer Platinum(II) Complexes. Luminescence and Tuning of the Electronic and NLO Properties and the Application in an OLED
Organometallics, 2008, 27, 1690
4070537 CIFC71 H90 B Fe N2 O Si2 UP n a 2116.1229; 21.8507; 18.5574
90; 90; 90
6537.7Monreal, Marisa J.; Diaconescu, Paula L.
A Weak Interaction between Iron and Uranium in Uranium Alkyl Complexes Supported by Ferrocene Diamide Ligands
Organometallics, 2008, 27, 1702
4070779 CIFC13 H20 Cl Ir N2 O2P n a 2110.7068; 10.3756; 14.2075
90; 90; 90
1578.3Kelly III, Roy A.; Clavier, Hervé; Giudice, Simona; Scott, Natalie M.; Stevens, Edwin D.; Bordner, Jon; Samardjiev, Ivan; Hoff, Carl D.; Cavallo, Luigi; Nolan, Steven P.
Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System
Organometallics, 2008, 27, 202
4071124 CIFC55 H51 Cl4 Fe N P2P n a 2117.499; 15.7403; 17.3715
90; 90; 90
4784.8Montigny, Frédéric de; Argouarch, Gilles; Roisnel, Thierry; Toupet, Loic; Lapinte, Claude; Lam, Sally Chan-Fung; Tao, Chi-Hang; Yam, Vivian Wing-Wah
Syntheses, Structures, and Properties of Some Piano-Stool Iron Acetylides Bearing a Functional Anthracenyl Group
Organometallics, 2008, 27, 1912
4071152 CIFC23 H18 Br N2 Ni PP n a 2118.8941; 8.8776; 11.9195
90; 90; 90
1999.3Han, Fu-Bin; Zhang, Yu-Liang; Sun, Xiu-Li; Li, Bao-Guo; Guo, Yang-Hui; Tang, Yong
Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization
Organometallics, 2008, 27, 1924
4071153 CIFC23 H18 Cl N2 Ni PP n a 2118.787; 8.8927; 11.8928
90; 90; 90
1986.9Han, Fu-Bin; Zhang, Yu-Liang; Sun, Xiu-Li; Li, Bao-Guo; Guo, Yang-Hui; Tang, Yong
Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization
Organometallics, 2008, 27, 1924
4071154 CIFC23 H18 Cl N2 P PdP n a 2118.8885; 8.9493; 11.9998
90; 90; 90
2028.4Han, Fu-Bin; Zhang, Yu-Liang; Sun, Xiu-Li; Li, Bao-Guo; Guo, Yang-Hui; Tang, Yong
Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization
Organometallics, 2008, 27, 1924
4071407 CIFC32 H37 Mn O3P n a 2126.234; 16.479; 6.3671
90; 90; 90
2752.6Price, Craig J.; Zeits, Paul D.; Reibenspies, Joseph H.; Miller, Stephen A.
Octamethyloctahydrodibenzofluorenyl: Electronic Comparisons between a Sterically Expanded Ligand and Its Cyclopentadienyl Analogues
Organometallics, 2008, 27, 3722
4071418 CIFC41 H39 B2 Fe2 NP n a 219.5763; 19.3314; 17.4565
90; 90; 90
3231.6Pakkirisamy, Thilagar; Venkatasubbaiah, Krishnan; Kassel, W. Scott; Rheingold, Arnold L.; Jäkle, Frieder
Examination of the Pyridine Binding to the Bifunctional Lewis Acid B,B′-Diphenyldiboradiferrocene
Organometallics, 2008, 27, 3056
4071467 CIFC21 H26 Ag I N2P n a 2116.288; 15.495; 8.3719
90; 90; 90
2112.9Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071568 CIFC22 H50 B9 Cl2 Na O6 ZrP n a 2130.143; 12.9155; 18.608
90; 90; 90
7244.3Wang, Yaorong; Liu, Dongmei; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me2C(C5H4)(C2B9H10)]3−
Organometallics, 2008, 27, 2825
4071635 CIFC34 H26 Ni3P n a 2118.3002; 9.116; 14.8054
90; 90; 90
2469.91Buchalski, Piotr; Grabowska, Ilona; Karaskiewicz, Anna; Suwińska, Kinga; Jerzykiewicz, Lucjan
Novel 9-Nickelafluorenyl Sandwich Complexes of Nickel(II) and Cobalt(II)
Organometallics, 2008, 27, 3316
4071784 CIFC24 H31 N O WP n a 2116.821; 12.6397; 9.6412
90; 90; 90
2049.84Buschhaus, Miriam S. A.; Pamplin, Craig B.; Blackmore, Ian J.; Legzdins, Peter
Transformations of Cyclic Olefins Mediated by Tungsten Nitrosyl Complexes
Organometallics, 2008, 27, 4724
4072012 CIFC16 H27 I Pd S2P n a 2117.195; 11.49; 9.75
90; 90; 90
1926.3Grushin, Vladimir V.; Marshall, William J.
Fluorination of Nonactivated Haloarenes via Arynes under Mild Conditions, Resulting from Further Studies toward Ar−F Reductive Elimination from Palladium(II)
Organometallics, 2008, 27, 4825
4072041 CIFC33 H46 La N3P n a 2117.907; 12.848; 12.995
90; 90; 90
2989.7Ge, Shaozhong; Meetsma, Auke; Hessen, Bart
Neutral and Cationic Rare Earth Metal Alkyl and Benzyl Compounds with the 1,4,6-Trimethyl-6-pyrrolidin-1-yl-1,4-diazepane Ligand and Their Performance in the Catalytic Hydroamination/Cyclization of Aminoalkenes
Organometallics, 2008, 27, 5339
4072050 CIFC29 H37 LaP n a 2120.064; 10.051; 12.233
90; 90; 90
2466.9Quiroga Norambuena, Victor F.; Heeres, André; Heeres, Hero J.; Meetsma, Auke; Teuben, Jan H.; Hessen, Bart
Synthesis, Structure, and Reactivity of Rare-Earth Metallocene η3-Propargyl/Allenyl Complexes
Organometallics, 2008, 27, 5672
4072085 CIFC32 H27 Cl N2 O11 Os4P n a 2124.1236; 11.6068; 31.1183
90; 90; 90
8713.1Cooke, Craig E.; Jennings, Michael C.; Katz, Michael J.; Pomeroy, R. K.; Clyburne, Jason A. C.
NHC Complexes of Osmium Clusters: A Structural and Reactivity Study
Organometallics, 2008, 27, 5777
4072098 CIFC18 H19 O5 PP n a 2119.555; 12.571; 7.3292
90; 90; 90
1801.7Duan, Zheng; Zhang, Jianzhen; Tian, Rongqiang; Bai, Liuying; Mathey, Francois
Reinvestigation of the Reactions of 1-Phenyl-3,4-dimethylphosphole with Dimethyl Acetylenedicarboxylate
Organometallics, 2008, 27, 5169
4072264 CIFC29 H37 Cl2 P2 Si VP n a 2117.424; 9.493; 17.8481
90; 90; 90
2952.2Shinohara, Akihiro; McBee, Jennifer; Waterman, Rory; Tilley, T. Don
Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity
Organometallics, 2008, 27, 5717
4072343 CIFC27 H39 Cl Co N3 O P2P n a 2117.122; 10.182; 32.959
90; 90; 90
5745.9Wang, Aichen; Sun, Hongjian; Li, Xiaoyan
N-Assisted Carbon−Hydrogen Bond Activation by Cobalt(I) Complexes
Organometallics, 2008, 27, 5434
4072383 CIFC14 H25 Cl N2 PdP n a 2111.476; 10.767; 12.971
90; 90; 90
1602.72Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072385 CIFC35 H45 B F4 N2 O3 P PdP n a 2117.938; 11.256; 18.367
90; 90; 90
3708.48Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4072386 CIFC33 H60 B F4 N2 P PdP n a 2115.22; 12.327; 19.148
90; 90; 90
3592.49Normand, Adrien T.; Stasch, Andreas; Ooi, Li-Ling; Cavell, Kingsley J.
Design of Cationic Mixed Phosphine/N-Heterocyclic Carbene Palladium(II) π-Allyl Complexes as Monoligated Phosphine Pd(0) Precatalysts: Synthesis, Structural Studies, Catalysis, and Reactivity
Organometallics, 2008, 27, 6507
4070503 CIFC11 H30 B8 N2 PtP n m a11.6161; 17.703; 9.5129
90; 90; 90
1956.2Carr, Michael J.; McGrath, Thomas D.; Stone, F. Gordon A.
Synthesis and Reactivity of 10-Vertexarachno-Platinacarboranes
Organometallics, 2008, 27, 2099
4070766 CIFC27 H22 N2 PtP n m a19.8057; 18.9645; 5.3313
90; 90; 90
2002.46De Crisci, Antonio G.; Lough, Alan J.; Multani, Kanwarpal; Fekl, Ulrich
9,10-Dihydroplatinaanthracenes with Aromatic Diimine Ligands: Syntheses and Spectroscopic and Computational Studies of New Luminescent Materials
Organometallics, 2008, 27, 1765
4070996 CIFC28 H36 N4 O2 Ru Si2P n m a22.3683; 14.0012; 9.5533
90; 90; 90
2991.93Okazaki, Masaaki; Yamahira, Nobukazu; Minglana, Jim Josephus Gabrillo; Komuro, Takashi; Ogino, Hiroshi; Tobita, Hiromi
[Ru(xantsil)(CO)(η6-toluene)]: Synthon for a Highly Unsaturated Ruthenium(II) Complex through Facile Dissociation of the Toluene Ligand [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]
Organometallics, 2008, 27, 918
4071391 CIFC32 H50 N2 TiP n m a14.245; 22.068; 10.071
90; 90; 90
3165.9Nikiforov, Grigory B.; Roesky, Herbert W.; Heisen, Burkhard C.; Oswald, Rainer B.
Formation of a Titanium Complex with a TiCHAl2Structural Unit from LTiMe3and Trimethylaluminum§
Organometallics, 2008, 27, 2544
4071470 CIFC22 H28 N2P n m a9.87; 22.911; 8.2427
90; 90; 90
1863.9Iglesias, Manuel; Beetstra, Dirk J.; Knight, James C.; Ooi, Li-Ling; Stasch, Andreas; Coles, Simon; Male, Louise; Hursthouse, Michael B.; Cavell, Kingsley J.; Dervisi, Athanasia; Fallis, Ian A.
Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures
Organometallics, 2008, 27, 3279
4071554 CIFC60 H88 N8 Sb4P n m a22.928; 22.602; 12.236
90; 90; 90
6340.9Dostál, Libor; Jambor, Roman; Růžička, Aleš; Holeček, Jaroslav
Syntheses and Structures of Ar3Sb5and Ar4Sb4Compounds (Ar = C6H3-2,6-(CH2NMe2)2)
Organometallics, 2008, 27, 2169
4072143 CIFC24 H34 P2 Pt S2 SiP n m a17.707; 13.5049; 11.8162
90; 90; 90
2825.6Lee, Kyung-Eun; Chang, Xiaohong; Kim, Yong-Joo; Huh, Hyun Sue; Lee, Soon W.
Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes,cis-[Pt(S2CNPh)L2] andcis-[Pt(S2SiPh2)L2] (L = PMe2Ph, PEt3; L-L = dppp)
Organometallics, 2008, 27, 5566
4072165 CIFC28 H46 B F4 N6 O4 Rh2P n m a20.7453; 16.8043; 9.9841
90; 90; 90
3480.6Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.
Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds
Organometallics, 2008, 27, 5836
4071285 CIFC74 H94 Cl4 N4 O8 Pd3P n n 213.101; 29.389; 10.898
90; 90; 90
4196Chitanda, Jackson M.; Prokopchuk, Demyan E.; Quail, J. Wilson; Foley, Stephen R.
From Pyrroles to Isoindolines: Synthesis of a γ-Diimine Ligand for Applications in Palladium Coordination Chemistry and Catalysis
Organometallics, 2008, 27, 2337
4072195 CIFC34 H58 Li2 N4 O2P n n 216.4657; 12.1496; 8.7833
90; 90; 90
1757.11Armstrong, David R.; Drummond, Allison M.; Balloch, Liam; Graham, David V.; Hevia, Eva; Kennedy, Alan R.
Metalation of 2,4,6-Trimethylacetophenone Using Organozinc Reagents: The Role of the Base in Determining Composition and Structure of the Developing Enolate
Organometallics, 2008, 27, 5860
4070898 CIFC38 H78 B9 N9 ZrP n n a17.773; 22.528; 12.7374
90; 90; 90
5099.9Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4070899 CIFC44 H84 B9 N9 ZrP n n a17.7855; 22.6517; 13.1899
90; 90; 90
5313.8Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4070900 CIFC44 H84 B9 Hf N9P n n a17.7492; 22.5137; 13.1185
90; 90; 90
5242.2Shen, Hao; Chan, Hoi-Shan; Xie, Zuowei
Synthesis, Structural Characterization, and Reactivity of Group 4 Metal Complexes Derived from 1-Indenyl-1,2-carborane
Organometallics, 2008, 27, 1157
4071106 CIFC32.5 H16 N1.5 O11.5 Si Zn2P n n a12.4868; 13.0255; 23.7555
90; 90; 90
3863.8Lambert, Joseph B.; Liu, Zhongqiang; Liu, Chunqing
Metal−Organic Frameworks from Silicon- and Germanium-Centered Tetrahedral Ligands
Organometallics, 2008, 27, 1464
4071340 CIFC60 H48 Cl4 O2 P2P n n a23.504; 20.767; 10.3578
90; 90; 90
5056Doherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William
Biaryl-Like CATPHOS Diphosphines via Double Diels‒Alder Cycloaddition between 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne and Anthracenes: Efficient Ligands for the Palladium-Catalyzed Amination of Aromatic Bromides and α-Arylation of Ketones
Organometallics, 2008, 27, 1679
4070804 CIFC55 H85 B30 Cl3 N6 Ru3 S6P n n m20.384; 22.015; 24.629
90; 90; 90
11052Zhang, Jia-Sheng; Liu, Shuang; Wang, Guo-Liang; Lin, Yue-Jian; Jin, Guo-Xin
Self-Assembly of Trinuclear Half-Sandwich Metal (Co and Ru) Complexes Containing Ancillaryortho-Carborane-1,2-dithiolato Ligands
Organometallics, 2008, 27, 1112
4071099 CIFC33 H42 N O P Ru2P n n m13.066; 15.12; 16.021
90; 90; 90
3165.1Takemoto, Shin; Kimura, Yu; Kamikawa, Ken; Matsuzaka, Hiroyuki
P−H Bond Addition to a Dinuclear Ruthenium Imido Complex: Synthesis and Reactivity of an Amido Phosphido Complex
Organometallics, 2008, 27, 1780
4071838 CIFC11 H15 B Mo N5 O3.5 S2P n n m17.4413; 6.7479; 15.0143
90; 90; 90
1767.07Abernethy, Robyn J.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Tshabang, Never; Willis, Anthony C.; Young, Rowan D.
Poly(methimazolyl)borato Nitrosyl Complexes of Molybdenum and Tungsten
Organometallics, 2008, 27, 4455
4070914 CIFC52 H112 Ba2 N12P n n n :210.435; 14.508; 19.957
90; 90; 90
3021.3Cameron, Thomas M.; Xu, Chongying; Dipasquale, Antonio G.; Rheingold, Arnold L.
Synthesis and Structure of Strontium and Barium Guanidinates and Mixed-Ligand Guanidinate Pentamethylcyclopentadienyl Complexes
Organometallics, 2008, 27, 1596
4071107 CIFC37 H37 Ge N3 O11 Zn1.5P n n n :214.2546; 23.6813; 24.0132
90; 90; 90
8106.1Lambert, Joseph B.; Liu, Zhongqiang; Liu, Chunqing
Metal−Organic Frameworks from Silicon- and Germanium-Centered Tetrahedral Ligands
Organometallics, 2008, 27, 1464
4070557 CIFC16 H28 Cl2 N3 RhR -3 :H36.9644; 36.9644; 7.2845
90; 90; 120
8619.8Jiménez, M. Victoria; Pérez-Torrente, Jesús J.; Bartolomé, M. Isabel; Gierz, Verena; Lahoz, Fernando J.; Oro, Luis A.
Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts
Organometallics, 2008, 27, 224
4071025 CIFC82 H92 Cl8 N3 O12 P3 Ru3R -3 :H26.3433; 26.3433; 21.6192
90; 90; 120
12993Mothes, Emmanuelle; Sentets, Stephane; Luquin, Maria Asuncion; Mathieu, René; Lugan, Noël; Lavigne, Guy
New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation
Organometallics, 2008, 27, 1193
4071244 CIFC56 H55 Fe3 O2 P3 S3R -3 :H49.621; 49.621; 25.425
90; 90; 120
54215.4Mizuta, Tsutomu; Aotani, Tomoyuki; Imamura, Yuki; Kubo, Kazuyuki; Miyoshi, Katsuhiko
Structure and Properties of the Macrocyclic Tridentate Ferrocenylphosphine Ligand (−PhPC5H4FeC5H4−)3
Organometallics, 2008, 27, 2457
4071537 CIFC99 H210 Mn2 Na O9 S7 Si6R -3 :H14.638; 14.638; 101.57
90; 90; 120
18847.8Kückmann, Theresa I.; Schödel, Frauke; Sänger, Inge; Bolte, Michael; Wagner, Matthias; Lerner, Hans-Wolfram
Mixed-Valence Manganese Carbonyl Complexes with Supersilyl Thiolate Ligands: [(OC)4Mn(μ-SSitBu3)2Mn(THF)X] (X = Br, SSitBu3) and Na(THF)6[(OC)3Mn(μ-SSitBu3)3MnSSitBu3]
Organometallics, 2008, 27, 3272
4071634 CIFC20 H22 O2 S2R -3 :H24.993; 24.993; 7.3862
90; 90; 120
3995.7Ananikov, Valentine P.; Orlov, Nikolay V.; Kabeshov, Mikhail A.; Beletskaya, Irina P.; Starikova, Zoya A.
Stereodefined Synthesis of a New Type of 1,3-Dienes by Ligand-Controlled Carbon−Carbon and Carbon−Heteroatom Bond Formation in Nickel-Catalyzed Reaction of Diaryldichalcogenides with Alkynes
Organometallics, 2008, 27, 4056
4071993 CIFC30 H22 B2 Mn2 N12 O6R -3 :H11.6044; 11.6044; 23.935
90; 90; 120
2791.3Morawitz, Thorsten; Zhang, Fan; Bolte, Michael; Bats, Jan W.; Lerner, Hans-Wolfram; Wagner, Matthias
Di- and Tritopic Poly(pyrazol-1-yl)borate Ligands: Synthesis, Characterization, and Reactivity toward [Mn(CO)5Br]
Organometallics, 2008, 27, 5067
4071995 CIFC38 H34 B2R -3 :H30.2192; 30.2192; 8.4832
90; 90; 120
6709Chen, Jinhui; Kampf, Jeff W.; Ashe, Arthur J.
Syntheses and Structures of 6,13-Dihydro-6,13-diborapentacenes: π-Stacking in Heterocyclic Analogues of Pentacene
Organometallics, 2008, 27, 3639
4072048 CIFC20 H35 Br Ni P2R -3 c :H25.2547; 25.2547; 20.6154
90; 90; 120
11386.9Castonguay, Annie; Beauchamp, André L.; Zargarian, Davit
Preparation and Reactivities of PCP-Type Pincer Complexes of Nickel. Impact of Different Ligand Skeletons and Phosphine Substituents
Organometallics, 2008, 27, 5723
4070991 CIFC57 H129 Ca3 N3 O9 Si6R 3 :H17.8268; 17.8268; 20.7329
90; 90; 120
5706.07He, Xuyang; Hurley, Erin; Noll, Bruce C.; Henderson, Kenneth W.
Regio- and Stereoselective Enolizations Using Calcium Bis(hexamethyldisilazide) as a Base: Synthetic, Solid-State, and Solution Studies
Organometallics, 2008, 27, 3094
4071837 CIFC14 H16 B N7 O3 S3 WR 3 :H14.2437; 14.2437; 17.8872
90; 90; 120
3142.81Abernethy, Robyn J.; Foreman, Mark R. St.-J.; Hill, Anthony F.; Tshabang, Never; Willis, Anthony C.; Young, Rowan D.
Poly(methimazolyl)borato Nitrosyl Complexes of Molybdenum and Tungsten
Organometallics, 2008, 27, 4455
4071946 CIFC80 H116 Mg2 O8 S2R 3 :R19.5642; 19.5642; 19.5642
101.023; 101.023; 101.023
7010.1Wu, Jincai; Chen, Yi-Zhen; Hung, Wen-Chou; Lin, Chu-Chieh
Preparation, Characterization, and Catalytic Studies of Magnesium Phenoxides: Highly Active Initiators for Ring-Opening Polymerization ofl-Lactide
Organometallics, 2008, 27, 4970

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