Crystallography Open Database

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4088748 CIFC7 H8 Co N3 O3P -17.1478; 7.763; 9.4028
75.97; 71.492; 76.53
473.05Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088284 CIFC15 H12 N2 O2P 1 21 13.8617; 14.2043; 11.0554
90; 95.734; 90
603.38Wu, Hung-Chou; Chu, Jean-Ho; Li, Chin-Wei; Hwang, Long-Chih; Wu, Ming-Jung
Palladium-Catalyzed Regioselective Arylation of Pyrazolo[1,5-a]pyridines via C‒H Activation and Synthetic Applications on P38 Kinase Inhibitors
Organometallics, 2016, 35, 288
4086548 CIFC26 H42 B Fe NP 17.3391; 9.4771; 9.9193
102.177; 103.396; 105.969
616.8Bhattacharjee, Hridaynath; Martell, Jonathon D.; Khozeimeh Sarbisheh, Elaheh; Sadeh, Saeid; Quail, J. Wilson; Müller, Jens
Insight into the Formation of Highly Strained [1]Ferrocenophanes with Boron in Bridging Position
Organometallics, 2016, 35, 2156
4086360 CIFC7 H13 B Cl3 N TiP 1 21 16.6239; 12.6714; 7.725
90; 106.865; 90
620.5Chen, Yang; Fang, Xiangdong; Dan, Wenyan
1,2-Azaborolyl-Ligated Titanium(IV) Half-Metallocenes: Synthesis, Characterization, and Catalytic Activity in Ethylene Polymerization
Organometallics, 2016, 35, 15
4088692 CIFC4 H24 B9 NP 1 21 16.4166; 10.3935; 9.5956
90; 100.278; 90
629.67Tanaka, Naoki; Shoji, Yoshiaki; Fukushima, Takanori
Convenient Route to Monocarba-closo-dodecaborate Anions
Organometallics, 2016, 35, 2022
4086541 CIFC10 H9 Co F6 N3 PP -16.3656; 8.237; 12.7564
105.592; 98.174; 93.475
634.27Vanicek, Stefan; Kopacka, Holger; Wurst, Klaus; Müller, Thomas; Hassenrück, Christopher; Winter, Rainer F.; Bildstein, Benno
Monofunctionalized Cobaltocenium Compounds by Dediazoniation Reactions of Cobaltoceniumdiazonium Bis(hexafluorophosphate)
Organometallics, 2016, 35, 2101
4089109 CIFC5 H6 Au Cl2 N11P -17.3637; 7.9901; 11.2943
93.039; 101.379; 95.607
646.56Schuh, Esther; Werner, Svenja; Otte, Daniela; Monkowius, Uwe; Mohr, Fabian
A Neutral, Carbene-Stabilized Gold(III) Triazide
Organometallics, 2016, 35, 3448
4088618 CIFC14 H13 N3 O2P -17.7506; 8.3383; 11.2037
81.165; 70.895; 71.729
648.636Holtrichter-Rößmann, Thorsten; Häger, Ina; Daniliuc, Constantin-Gabriel; Fröhlich, Roland; Bergander, Klaus; Troll, Carsten; Rieger, Bernhard; Rojas, René S.; Würthwein, Ernst-Ulrich
Catalytically Active N-Acylamidine‒Zirconium Complexes: Synthesis, Structures, and Application in Ethylene Polymerization
Organometallics, 2016, 35, 1906
4088468 CIFC24 H38 Al2 N6 O2P -17.6535; 9.2634; 10.463
113.086; 91.855; 105.457
649.8Stienen, Christian; Gondzik, Sebastian; Gehlhaar, Alexander; Haack, Rebekka; Wölper, Christoph; Jansen, Georg; Schulz, Stephan
(MeZn)2(μ-η2:η2-N6Ph2): A Powerful Starting Reagent for the Synthesis of Metal Hexazene Complexes
Organometallics, 2016, 35, 1022
4088905 CIFC15 H20 MnP -17.865; 8.2036; 12.163
101.645; 96.985; 118.493
653.5Walter, Marc D.; Burns, Carol J.; Matsunaga, Phillip T.; Smith, Michael E.; Andersen, Richard A.
Synthesis and Physical Properties of Pentamethylmanganocene, (C5Me5)Mn(C5H5), and the Inclusion Compounds [(C5Me5)2Yb]2[(C5H5)2M] (Where M = V, Cr, Fe, Co)
Organometallics, 2016, 35, 3488
4086544 CIFC13 H21 O3 ReP 1 21/m 16.3051; 19.326; 6.3244
90; 118.867; 90
674.89Raju, Suresh; van Slagmaat, Christian A. M. R.; Li, Jing; Lutz, Martin; Jastrzebski, Johann T. B. H.; Moret, Marc-Etienne; Klein Gebbink, Robertus J. M.
Synthesis of Cyclopentadienyl-Based Trioxo-rhenium Complexes and Their Use as Deoxydehydration Catalysts
Organometallics, 2016, 35, 2178
4088860 CIFC11 H17 B N4 O4P -17.8797; 8.5109; 10.1918
90.0104; 96.5593; 91.4265
678.81Allen, Thomas H.; Geib, Steven J.; Curran, Dennis P.
Radical and Thermal Reactions of N-Heterocyclic Carbene Boranes with Diazo Compounds
Organometallics, 2016, 35, 2975
4088957 CIFC26 H42 Cl4 Ir2P -18.7695; 8.8947; 9.5445
109.693; 100.752; 92.206
684.49Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088973 CIFC28 H42 Cl4 Rh2P -18.2629; 8.7503; 10.5777
99.237; 109.338; 96.151
701.66Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088966 CIFC26 H42 Cl4 Rh2P -18.5876; 8.7956; 9.9373
74.904; 76.432; 82.203
702.24Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4086623 CIFC38 H28 N2P -15.61635; 11.25535; 11.73665
104.289; 98.3322; 93.168
708.16Shynkaruk, Olena; Qi, Yanyu; Cottrell-Callbeck, Aiden; Torres Delgado, William; McDonald, Robert; Ferguson, Michael J.; He, Gang; Rivard, Eric
Modular Synthesis of Diarylalkynes and Their Efficient Conversion into Luminescent Tetraarylbutadienes
Organometallics, 2016, 35, 2232
4086803 CIFC28 H42 P2 S2P -18.0198; 9.2558; 11.4204
111.061; 93.96; 112.432
710.04Fischer, Reinald; Görls, Helmar; Westerhausen, Matthias
Reactivity Studies of [(thf)2Mg{μ-C(CH3)2C2H4C(CH3)2}]2: Scrambling Reactions and Diverse Reactions with Dichlorophenylphosphane
Organometallics, 2016, 35, 3861
4088962 CIFC28 H42 Cl4 Ir2P -18.2486; 8.8636; 10.6121
99.228; 109.651; 96.017
710.63Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4086476 CIFC6 H2 F2 N2 O4P 43 21 25.8849; 5.8849; 21.4266
90; 90; 90
742.05Korb, Marcus; Swarts, Pieter J.; Miesel, Dominique; Hildebrandt, Alexander; Swarts, Jannie C.; Lang, Heinrich
Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers
Organometallics, 2016, 35, 1287
4088418 CIFC14 H20 Ni2 S2P -18.106; 9.644; 10.354
88.053; 69.956; 88.644
759.9Chambers, Geoffrey M.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Effect of Pyramidalization of the M2(SR)2Center: The Case of (C5H5)2Ni2(SR)2
Organometallics, 2016, 35, 836
4088749 CIFC13 H20 Co N3 O3P -18.6254; 9.184; 11.326
70.209; 78.048; 64.995
762.92Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088638 CIFC36 H36 Fe2 O2 S2 SnP 17.6712; 10.7861; 10.8306
64.332; 83.343; 77.207
787.46Chen, Jiawei; Tagne Kuate, Alain C.; Lalancette, Roger A.; Jäkle, Frieder
Heteroatom-Bridged ortho-Biferrocenes: Stereoselective Synthesis, Structural Features, and Electrochemical Properties
Organometallics, 2016, 35, 1964
4086622 CIFC20 H22P 1 21/c 110.6089; 9.247; 8.2942
90; 103.078; 90
792.56Shynkaruk, Olena; Qi, Yanyu; Cottrell-Callbeck, Aiden; Torres Delgado, William; McDonald, Robert; Ferguson, Michael J.; He, Gang; Rivard, Eric
Modular Synthesis of Diarylalkynes and Their Efficient Conversion into Luminescent Tetraarylbutadienes
Organometallics, 2016, 35, 2232
4088964 CIFC26 H42 Cl8 Rh2P -18.7683; 9.0638; 10.9372
81.339; 84.115; 71.983
815.73Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4087906 CIFC35 H49 Cl N O P PdP 19.3334; 9.4708; 11.3733
104.439; 108.41; 107.365
842.33Gorunova, Olga N.; Novitskiy, Ivan M.; Grishin, Yuri K.; Gloriozov, Igor P.; Roznyatovsky, Vitaly A.; Khrustalev, Victor N.; Kochetkov, Konstantin A.; Dunina, Valery V.
Determination of the Absolute Configuration of CN-Palladacycles by 31P{1H} NMR Spectroscopy Using (1R,2S,5R)-Menthyloxydiphenylphosphine as the Chiral Derivatizing Agent: Efficient Chirality Transfer in Phosphinite Adducts
Organometallics, 2016, 35, 75
4088681 CIFC20 H28 HfP -17.4644; 8.8177; 13.872
96.197; 98.933; 106.408
854.06Chadwick, F. Mark; Cooper, Robert T.; O’Hare, Dermot
Zirconium and Hafnium Permethylpentalene Compounds
Organometallics, 2016, 35, 2092
4088682 CIFC20 H28 ZrP -17.5632; 8.7831; 14.0811
95.1349; 99.086; 108.575
865.71Chadwick, F. Mark; Cooper, Robert T.; O’Hare, Dermot
Zirconium and Hafnium Permethylpentalene Compounds
Organometallics, 2016, 35, 2092
4088325 CIFC32 H64 Mg2 O4P -18.4905; 9.2287; 12.9872
70.008; 80.746; 64.989
866.47Fischer, Reinald; Görls, Helmar; Langer, Jens; Enke, Marcel; Westerhausen, Matthias
Magnesiacycloalkanes with Different Ring Sizes
Organometallics, 2016, 35, 587
4088402 CIFC35 H26 Cl2 N8 Ni O8 S2P -19.134; 9.293; 12.052
103.787; 98.329; 112.385
886.5Hoover, Andrew J.; Lazari, Mark; Ren, Hong; Narayanam, Maruthi Kumar; Murphy, Jennifer M.; van Dam, R. Michael; Hooker, Jacob M.; Ritter, Tobias
A Transmetalation Reaction Enables the Synthesis of [<sup>18</sup>F]5-Fluorouracil from [<sup>18</sup>F]Fluoride for Human PET Imaging.
Organometallics, 2016, 35, 1008-1014
4086626 CIFC20 H14 S4P 1 21/c 111.6007; 6.5548; 12.6109
90; 110.62; 90
897.5Shynkaruk, Olena; Qi, Yanyu; Cottrell-Callbeck, Aiden; Torres Delgado, William; McDonald, Robert; Ferguson, Michael J.; He, Gang; Rivard, Eric
Modular Synthesis of Diarylalkynes and Their Efficient Conversion into Luminescent Tetraarylbutadienes
Organometallics, 2016, 35, 2232
4088645 CIFC22 H27 Co N2P -19.3575; 10.5822; 10.6591
113.522; 106.077; 93.945
910.48Nagaoka, Masahiro; Kawashima, Takashi; Suzuki, Hiroharu; Takao, Toshiro
Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt
Organometallics, 2016, 35, 2348
4086481 CIFC17 H11 F3 Fe N2 O7 SP -17.4788; 8.7046; 14.8166
99.292; 92.546; 105.141
915.05Korb, Marcus; Swarts, Pieter J.; Miesel, Dominique; Hildebrandt, Alexander; Swarts, Jannie C.; Lang, Heinrich
Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers
Organometallics, 2016, 35, 1287
4086673 CIFC19 H26 Ir N O2 SP -18.7906; 9.2091; 11.8914
83.178; 83.27; 74.448
917.17Frasco, Daniel A.; Mukherjee, Sriparna; Sommer, Roger D.; Perry, Cody M.; Lambic, Nikola S.; Abboud, Khalil A.; Jakubikova, Elena; Ison, Elon A.
Nondirected C‒H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study
Organometallics, 2016, 35, 2435
4088626 CIFC15 H7 Cl7 O TiP 1 21/m 16.37; 13.996; 10.509
90; 101.353; 90
918.6Zhao, Weizhen; Yan, Qing; Tsutsumi, Ken; Nomura, Kotohiro
Efficient Norbornene (NBE) Incorporation in Ethylene/NBE Copolymerization by Half-Titanocene Catalysts Containing Chlorinated Aryloxo Ligands
Organometallics, 2016, 35, 1895
4088411 CIFC16 H22 Ni3 S4P 1 21/n 15.6021; 19.865; 8.345
90; 90.321; 90
928.7Chambers, Geoffrey M.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Effect of Pyramidalization of the M2(SR)2Center: The Case of (C5H5)2Ni2(SR)2
Organometallics, 2016, 35, 836
4088986 CIFC42 H31 As2 Br2 Cl PtP -19.0753; 9.9531; 10.7614
100.763; 94.6827; 100.088
933.59Imoto, Hiroaki; Tanaka, Susumu; Kato, Takuji; Yumura, Takashi; Watase, Seiji; Matsukawa, Kimihiro; Naka, Kensuke
Molecular Shape Recognition by Using a Switchable Luminescent Nonporous Molecular Crystal
Organometallics, 2016, 35, 3647
4086547 CIFC9 H13 O3 ReP n m a5.9964; 13.1856; 12.0268
90; 90; 90
950.91Raju, Suresh; van Slagmaat, Christian A. M. R.; Li, Jing; Lutz, Martin; Jastrzebski, Johann T. B. H.; Moret, Marc-Etienne; Klein Gebbink, Robertus J. M.
Synthesis of Cyclopentadienyl-Based Trioxo-rhenium Complexes and Their Use as Deoxydehydration Catalysts
Organometallics, 2016, 35, 2178
4088345 CIFC20 H27 Cl N2 TiP -19.492; 10.2189; 10.52
97.84; 92.207; 106.896
963.95Večeřa, Miloš; Varga, Vojtech; Císařová, Ivana; Pinkas, Jiří; Kucharczyk, Pavel; Sedlařík, Vladimír; Lamač, Martin
Group 4 Metal Complexes of Chelating Cyclopentadienyl-ketimide Ligands
Organometallics, 2016, 35, 785
4088605 CIFC18 H20 Fe N O4 PP -18.7551; 9.5037; 11.971
98.0645; 96.1747; 93.5514
977.48Wit, Jan B. M.; de Jong, G. Bas; Schakel, Marius; Lutz, Martin; Ehlers, Andreas W.; Slootweg, J. Chris; Lammertsma, Koop
iPr2N‒P═Fe(CO)4 in Olefinic Solvents: A Reservoir of a Transient Phosphinidene Complex Capable of Substrate Hopping
Organometallics, 2016, 35, 1170
4086605 CIFC36 H72 P2 Pt Ru2P -18.5749; 10.4703; 12.9177
66.245; 74.156; 68.998
979.7Kuzutani, Takuya; Torihata, Yushi; Suzuki, Hiroharu; Takao, Toshiro
Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment
Organometallics, 2016, 35, 2543
4088565 CIFC28 H24 N2P 1 21/c 112.19; 5.566; 18.721
90; 129.16; 90
984.9Zhang, Fanjun; Jia, Jiong; Dong, Shuli; Wang, Wenguang; Tung, Chen-Ho
Hydride Transfer from Iron(II) Hydride Compounds to NAD(P)+ Analogues
Organometallics, 2016, 35, 1151
4086740 CIFC42 H62 Ge4P -19.4578; 10.709; 11.485
106.109; 99.15; 108.601
1019.3Komanduri, Sangeetha P.; Shumaker, F. Alexander; Roewe, Kimberly D.; Wolf, Melanie; Uhlig, Frank; Moore, Curtis E.; Rheingold, Arnold L.; Weinert, Charles S.
A Series of Isopropyl-Substituted Oligogermanes Pri3Ge(GePh2)nGePri3(n= 0‒3) Featuring a Luminescent and Dichroic Pentagermane Pri3Ge(GePh2)3GePri3
Organometallics, 2016, 35, 3240
4088941 CIFC6 H13 O Re S3P 1 21/c 17.2497; 18.072; 8.0726
90; 104.951; 90
1021.84Robbins, Leanna K.; Lilly, Cassandra P.; Sommer, Roger D.; Ison, Elon A.
Effect of the Ancillary Ligand on the Mechanism for CO Migratory Insertion in High-Valent Oxorhenium Complexes
Organometallics, 2016, 35, 3530
4088938 CIFC6 H11 O2 Re S3P n m a9.1938; 11.5524; 9.6348
90; 90; 90
1023.32Robbins, Leanna K.; Lilly, Cassandra P.; Sommer, Roger D.; Ison, Elon A.
Effect of the Ancillary Ligand on the Mechanism for CO Migratory Insertion in High-Valent Oxorhenium Complexes
Organometallics, 2016, 35, 3530
4086607 CIFC38 H68 O2 P2 Pt Ru2P -18.752; 10.7962; 12.7446
67.263; 74.113; 69.112
1024.65Kuzutani, Takuya; Torihata, Yushi; Suzuki, Hiroharu; Takao, Toshiro
Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment
Organometallics, 2016, 35, 2543
4086609 CIFC38 H72 P2 Pt Ru2P -18.5555; 11.451; 12.2442
71.344; 76.054; 65.607
1026.79Kuzutani, Takuya; Torihata, Yushi; Suzuki, Hiroharu; Takao, Toshiro
Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment
Organometallics, 2016, 35, 2543
4088469 CIFC46 H44 N10 Zn2P -18.9002; 10.8554; 11.3702
101.272; 105.138; 95.015
1028.78Stienen, Christian; Gondzik, Sebastian; Gehlhaar, Alexander; Haack, Rebekka; Wölper, Christoph; Jansen, Georg; Schulz, Stephan
(MeZn)2(μ-η2:η2-N6Ph2): A Powerful Starting Reagent for the Synthesis of Metal Hexazene Complexes
Organometallics, 2016, 35, 1022
4086608 CIFC40 H76 P2 Pt Ru2P -18.6625; 10.8809; 12.8072
68.185; 75.376; 68.479
1033.1Kuzutani, Takuya; Torihata, Yushi; Suzuki, Hiroharu; Takao, Toshiro
Synthesis of a Heterometallic Trinuclear Cluster of Ruthenium and Platinum with a Linear Alignment
Organometallics, 2016, 35, 2543
4088887 CIFC26 H21 Br N2P -16.7389; 10.7415; 14.8797
80.161; 78.902; 82.421
1035.92Thenarukandiyil, Ranjeesh; Thrikkykkal, Hridya; Choudhury, Joyanta
Rhodium(III)-Catalyzed Nonaromatic sp2 C‒H Activation/Annulation Using NHC as a Directing and Functionalizable Group
Organometallics, 2016, 35, 3007
4086722 CIFC22 H30 Mg O2P 1 21 19.37; 9.0598; 12.5313
90; 100.684; 90
1045.34Sandoval, John J.; Palma, Pilar; Álvarez, Eleuterio; Cámpora, Juan; Rodríguez-Delgado, Antonio
Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers
Organometallics, 2016, 35, 3197
4089022 CIFC15 H22 Au Cl5 N2 OP -17.5167; 9.491; 15.2776
101.664; 98.71; 95.481
1046.11Anisimova, Tatyana B.; Kinzhalov, Mikhail A.; Kuznetsov, Maxim L.; Guedes da Silva, M. Fátima C.; Zolotarev, Andrey A.; Kukushkin, Vadim Yu.; Pombeiro, Armando J. L.; Luzyanin, Konstantin V.
1,3-Dipolar Cycloaddition of Nitrones to Gold(III)-Bound Isocyanides
Organometallics, 2016, 35, 3569
4088283 CIFC13 H9 Cl N2P 1 c 112.6083; 11.4037; 7.3882
90; 96.485; 90
1055.49Wu, Hung-Chou; Chu, Jean-Ho; Li, Chin-Wei; Hwang, Long-Chih; Wu, Ming-Jung
Palladium-Catalyzed Regioselective Arylation of Pyrazolo[1,5-a]pyridines via C‒H Activation and Synthetic Applications on P38 Kinase Inhibitors
Organometallics, 2016, 35, 288
4086589 CIFC56 H36 O4 Si2P -19.838; 10.725; 10.786
97.131; 106.276; 99.722
1058.9Zhang, Fei-Bao; Adachi, Yohei; Ooyama, Yousuke; Ohshita, Joji
Synthesis and Properties of Benzofuran-Fused Silole and Germole Derivatives: Reversible Dimerization and Crystal Structures of Monomers and Dimers
Organometallics, 2016, 35, 2327
4088951 CIFC26 H27 Fe N3 O3P -17.5135; 10.3652; 13.7177
89.835; 85.137; 88.132
1063.91Sansook, Supojjanee; Tuo, Wei; Lemaire, Lucas; Tourteau, Aurélien; Barczyk, Amélie; Dezitter, Xavier; Klupsch, Frédérique; Leleu-Chavain, Natascha; Tizzard, Graham J.; Coles, Simon J.; Millet, Régis; Spencer, John
Synthesis of Bioorganometallic Nanomolar-Potent CB2Agonists Containing a Ferrocene Unit
Organometallics, 2016, 35, 3361
4086588 CIFC56 H36 Ge2 O4P -19.7837; 10.8094; 10.8576
98.3; 106.103; 99.866
1064.3Zhang, Fei-Bao; Adachi, Yohei; Ooyama, Yousuke; Ohshita, Joji
Synthesis and Properties of Benzofuran-Fused Silole and Germole Derivatives: Reversible Dimerization and Crystal Structures of Monomers and Dimers
Organometallics, 2016, 35, 2327
4086477 CIFC26 H20 Fe2 N2 O6P 1 21 17.6777; 10.0784; 14.2577
90; 105.261; 90
1064.34Korb, Marcus; Swarts, Pieter J.; Miesel, Dominique; Hildebrandt, Alexander; Swarts, Jannie C.; Lang, Heinrich
Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers
Organometallics, 2016, 35, 1287
4086743 CIFC19 H33 Ir O3 P2P -17.8388; 9.9117; 15.1225
105.935; 92.176; 107.411
1068.76Goldberg, Jonathan M.; Cherry, Sophia D. T.; Guard, Louise M.; Kaminsky, Werner; Goldberg, Karen I.; Heinekey, D. Michael
Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors
Organometallics, 2016, 35, 3546
4088436 CIFC13 H23 B10 Co O4 S2P -17.3158; 12.3742; 12.4309
103.377; 94.162; 97.031
1080.62Dai, Huimin; Liu, Guifeng; Zhang, Xiaolei; Yan, Hong; Lu, Changsheng
Pyrrolylmethyl Functionalized o-Carborane Derivatives
Organometallics, 2016, 35, 1488
4086591 CIFC38 H40 Au2 F6 N4 O6 P2 S2P -18.4651; 11.4271; 12.8696
68.237; 71.193; 87.701
1089.96Reiner, Benjamin R.; Bezpalko, Mark W.; Foxman, Bruce M.; Wade, Casey R.
Lewis Acid Catalysis with Cationic Dinuclear Gold(II,II) and Gold(III,III) Phosphorus Ylide Complexes
Organometallics, 2016, 35, 2830
4088420 CIFC47.72 H46 Br2 Cu2 Fe2 N2 O2P 18.846; 11.295; 12.422
72.46; 73.915; 70.961
1096.5Deb, Mayukh; Kumar, Dheeraj; Singh, Jatinder; Elias, Anil J.
Unprecedented Formation of π-Copper Complexes during Sonogashira Coupling: Synthesis of a Unique, Recyclable, Ethynyl Ferrocene Derived Cu(I) Specific Ligand
Organometallics, 2016, 35, 1086
4088327 CIFC9 H18 Cl2P 1 21/c 15.9425; 9.8998; 18.6847
90; 92.551; 90
1098.12Fischer, Reinald; Görls, Helmar; Langer, Jens; Enke, Marcel; Westerhausen, Matthias
Magnesiacycloalkanes with Different Ring Sizes
Organometallics, 2016, 35, 587
4088746 CIFC23 H24 Co N3 O3P -17.6104; 8.3315; 19.219
78.957; 87.909; 68.579
1112.7Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4087887 CIFC20 H28 B N7 O WP -19.9474; 10.1924; 12.0642
91.531; 104.687; 108.251
1116.15Beattie, Ross J.; White, Peter S.; Templeton, Joseph L.
Regioselectivity of Addition to the Azavinylidene Ligand in Tp′W(CO)(η2-HC≡CH)(N═CHMe): Electrophilic Addition versus Oxidation and Radical Coupling
Organometallics, 2015, 35, 32
4086784 CIFC31 H23 PP -110.8081; 11.035; 11.218
85.096; 65.459; 67.681
1121.7Iwai, Tomohiro; Tanaka, Ryotaro; Sawamura, Masaya
Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines
Organometallics, 2016, 35, 3959
4088790 CIFC24 H32 N2 Na2P 1 21/c 111.4543; 11.3694; 8.8489
90; 103.044; 90
1122.64Flynn, Matthew T.; Stott, Rachel; Blair, Victoria L.; Andrews, Philip C.
Loss of Chirality through Facile Lewis Base Mediated Aza-enolate Formation in Na and K (S)-N-(α-Methylbenzyl)methallylamides
Organometallics, 2016, 35, 2707
4088422 CIFC24 H38 O Ru2P -18.5051; 10.0519; 13.1631
88.11; 88.364; 88.211
1123.76Shimogawa, Ryuichi; Konishi, Gen-ichi; Takao, Toshiro; Suzuki, Hiroharu
Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon‒Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes
Organometallics, 2016, 35, 1446
4089120 CIFC22 H34 B Cl N PP 1 21 18.159; 13.4167; 10.9519
90; 110.021; 90
1126.42Devillard, Marc; Bouhadir, Ghenwa; Mallet-Ladeira, Sonia; Miqueu, Karinne; Bourissou, Didier
Amino and Alkyl B-Substituted P-Stabilized Borenium Salts
Organometallics, 2016, 35, 3788
4088392 CIFC15.5 H37 B9 N TaP -18.7882; 9.7167; 14.6889
78.685; 75.511; 69.628
1130.21Xiang, Li; Xie, Zuowei
Reaction of [η1:η5-(R2NCH2CH2)C2B9H10]TaMe3 with Isonitriles: Effects of Nitrogen Substituents on Product Formation
Organometallics, 2016, 35, 1430
4088522 CIFC40 H40 Al2 Cl8 N2 O8P -19.9177; 10.0942; 11.7946
81.813; 83.686; 77.774
1138.34Gao, Pengfei; Zhao, Zhiwen; Chen, Lijuan; Yuan, Dan; Yao, Yingming
Dinuclear Aluminum Poly(phenolate) Complexes as Efficient Catalysts for Cyclic Carbonate Synthesis
Organometallics, 2016, 35, 1707
4088823 CIFC27 H32 Fe N2P 18.191; 9.559; 15.583
97.767; 99.295; 105.53
1139.5Lee, Heejun; Campbell, Michael G.; Hernández Sánchez, Raúl; Börgel, Jonas; Raynaud, Jean; Parker, Sarah E.; Ritter, Tobias
Mechanistic Insight Into High-Spin Iron(I)-Catalyzed Butadiene Dimerization
Organometallics, 2016, 35, 2923
4089029 CIFC23 H43 Ga N2P 1 21/m 19.0062; 12.5202; 10.7172
90; 107.054; 90
1155.33Uhl, Werner; Willeke, Matthias; Hengesbach, Frank; Hepp, Alexander; Layh, Marcus
Aluminum and Gallium Hydrazides as Active Lewis Pairs: Cooperative C‒H Bond Activation with H‒C≡C‒Ph and Pentafluorobenzene
Organometallics, 2016, 35, 3701
4086631 CIFC50 H62 Al2 N4P -18.7138; 11.5602; 12.2481
77.218; 87.061; 74.191
1157.7Wei, Yun; Wang, Shaowu; Zhu, Xiancui; Zhou, Shuangliu; Mu, Xiaolong; Huang, Zeming; Hong, Dongjing
Aluminum Complexes Bearing N-Protected 2-Amino- or 2-Imino-Functionalized Pyrrolyl Ligands: Synthesis, Structure, and Catalysis for Preparation of Pyrrolyl-End-Functionalized Polyesters
Organometallics, 2016, 35, 2621
4088641 CIFC28 H27 B Fe2 SiP 1 21 19.0969; 7.333; 17.4165
90; 93.957; 90
1159.04Chen, Jiawei; Tagne Kuate, Alain C.; Lalancette, Roger A.; Jäkle, Frieder
Heteroatom-Bridged ortho-Biferrocenes: Stereoselective Synthesis, Structural Features, and Electrochemical Properties
Organometallics, 2016, 35, 1964
4088189 CIFC16 H36 Pb Si4C 1 m 111.7157; 17.054; 6.2809
90; 112.405; 90
1160.2Lee, Vladimir Ya.; Gapurenko, Olga A.; Ito, Yuki; Meguro, Takahiko; Sugasawa, Haruka; Sekiguchi, Akira; Minyaev, Ruslan M.; Minkin, Vladimir I.; Herber, Rolfe H.; Gornitzka, Heinz
Pyramidanes: The Covalent Form of the Ionic Compounds
Organometallics, 2016, 35, 346
4086542 CIFC10 H9 Co I2P n m a11.4449; 8.934; 11.4723
90; 90; 90
1173.03Vanicek, Stefan; Kopacka, Holger; Wurst, Klaus; Müller, Thomas; Hassenrück, Christopher; Winter, Rainer F.; Bildstein, Benno
Monofunctionalized Cobaltocenium Compounds by Dediazoniation Reactions of Cobaltoceniumdiazonium Bis(hexafluorophosphate)
Organometallics, 2016, 35, 2101
4088017 CIFC14 H38 B10 O2 P2P -18.4021; 9.9365; 15.45
74.825; 85.943; 71.725
1182.02Eleazer, Bennett J.; Smith, Mark D.; Peryshkov, Dmitry V.
Metal- and Ligand-Centered Reactivity of meta-Carboranyl-Backbone Pincer Complexes of Rhodium
Organometallics, 2016, 35, 106
4086546 CIFC12 H17 O3 ReP n a 2110.9327; 8.1327; 13.2961
90; 90; 90
1182.19Raju, Suresh; van Slagmaat, Christian A. M. R.; Li, Jing; Lutz, Martin; Jastrzebski, Johann T. B. H.; Moret, Marc-Etienne; Klein Gebbink, Robertus J. M.
Synthesis of Cyclopentadienyl-Based Trioxo-rhenium Complexes and Their Use as Deoxydehydration Catalysts
Organometallics, 2016, 35, 2178
4088503 CIFC21 H30 F6 Ir N2 SbP 1 21 18.616; 8.9487; 15.58
90; 91.808; 90
1200.7Sato, Yasuhiro; Kayaki, Yoshihito; Ikariya, Takao
Cationic Iridium and Rhodium Complexes with C‒N Chelating Primary Benzylic Amine Ligands as Potent Catalysts for Hydrogenation of Unsaturated Carbon‒Nitrogen Bonds
Organometallics, 2016, 35, 1257
4088505 CIFC21 H30 F6 N2 Rh SbP -18.502; 11.007; 13.633
96.292; 93.694; 106.951
1206.8Sato, Yasuhiro; Kayaki, Yoshihito; Ikariya, Takao
Cationic Iridium and Rhodium Complexes with C‒N Chelating Primary Benzylic Amine Ligands as Potent Catalysts for Hydrogenation of Unsaturated Carbon‒Nitrogen Bonds
Organometallics, 2016, 35, 1257
4088613 CIFC24 H31 N3 O4 RuP 1 21 19.367; 10.864; 12.295
90; 105.106; 90
1207.9Ito, Jun-ichi; Sugino, Kanae; Matsushima, Satoru; Sakaguchi, Hiroki; Iwata, Hiroshi; Ishihara, Takahiro; Nishiyama, Hisao
Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction
Organometallics, 2016, 35, 1885
4088768 CIFC17 H29 Cl5 Si Ta2P -18.912; 10.386; 13.515
94.684; 97.881; 99.817
1213.9Yamamoto, Keishi; Nagae, Haruki; Tsurugi, Hayato; Mashima, Kazushi
Synthesis and Reactions of Ditantalum—Allyl Complexes Derived from Intramolecular C‒H Bond Activation of the Methylene of the Ethyl Group Bound to Ditantallacyclopentadiene
Organometallics, 2016, 35, 2384
4088290 CIFC11 H10 Br N S2P 21 21 216.298; 8.218; 23.779
90; 90; 90
1230.7Leopold, Hendrik; Tronnier, Alexander; Wagenblast, Gerhard; Münster, Ingo; Strassner, Thomas
Photoluminescence of a New Material: Cyclometalated C∧C* Thiazole-2-ylidene Platinum(II) Complexes
Organometallics, 2016, 35, 959
4088956 CIFC22 H34 Cl4 Ir2P 1 21/c 17.6921; 14.9787; 11.3445
90; 109.567; 90
1231.6Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088459 CIFC27 H34 N4P -18.5413; 9.5405; 15.9126
76.1641; 85.1754; 78.7076
1233.75Song, Zhiyi; Hsieh, Yi-Fang; Nakajima, Kiyohiko; Kanno, Ken-ichiro; Takahashi, Tamotsu
Separation of Five Linearly Aligned Carbons into Two-Carbon and Three-Carbon Groups on Titanium
Organometallics, 2016, 35, 1092
4088939 CIFC10 H13 O Re S3P 1 21/n 18.2013; 15.5245; 9.8861
90; 101.121; 90
1235.07Robbins, Leanna K.; Lilly, Cassandra P.; Sommer, Roger D.; Ison, Elon A.
Effect of the Ancillary Ligand on the Mechanism for CO Migratory Insertion in High-Valent Oxorhenium Complexes
Organometallics, 2016, 35, 3530
4086676 CIFC22 H39 Ir O5 SP -18.8769; 9.5555; 14.9869
85.124; 84.523; 78.209
1235.93Frasco, Daniel A.; Mukherjee, Sriparna; Sommer, Roger D.; Perry, Cody M.; Lambic, Nikola S.; Abboud, Khalil A.; Jakubikova, Elena; Ison, Elon A.
Nondirected C‒H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study
Organometallics, 2016, 35, 2435
4088773 CIFC9 H25 Mn N2P 1 21/c 18.5099; 13.0628; 14.0488
90; 127.285; 90
1242.55Stalzer, Madelyn M.; Telser, Joshua; Krzystek, Jurek; Motta, Alessandro; Delferro, Massimiliano; Marks, Tobin J.
A Neutrally Charged Trimethylmanganese(III) Complex: Synthesis, Characterization, and Disproportionation Chemistry
Organometallics, 2016, 35, 2683
4088265 CIFC16 H21 F6 O6 P Si2 WP -18.9748; 10.3623; 15.417
70.869; 79.168; 66.889
1243Kyri, Andreas W.; Schnakenburg, Gregor; Streubel, Rainer
C-Trifluoromethyl-Substituted 1,2-Oxaphosphetane Complexes: Synthetic and Structural Study
Organometallics, 2016, 35, 563
4086659 CIFC29 H22 Fe N O4 PP -18.6636; 11.5678; 13.4797
77.8353; 72.9507; 77.268
1244.24Chu, Wan-Yi; Richers, Casseday P.; Kahle, Elizabeth R.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Imine-Centered Reactions in Imino-Phosphine Complexes of Iron Carbonyls
Organometallics, 2016, 35, 2782
4089122 CIFC22 H34 Au B Cl2 N PP -18.3246; 10.9975; 14.0449
88.883; 81.291; 78.296
1244.47Devillard, Marc; Bouhadir, Ghenwa; Mallet-Ladeira, Sonia; Miqueu, Karinne; Bourissou, Didier
Amino and Alkyl B-Substituted P-Stabilized Borenium Salts
Organometallics, 2016, 35, 3788
4088416 CIFC18 H26 Ni5 S8P 1 21/c 111.7655; 7.7431; 14.3399
90; 107.707; 90
1244.49Chambers, Geoffrey M.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Effect of Pyramidalization of the M2(SR)2Center: The Case of (C5H5)2Ni2(SR)2
Organometallics, 2016, 35, 836
4088423 CIFC26 H42 O Ru2P -18.5163; 11.2111; 13.221
88.343; 87.845; 85.305
1256.8Shimogawa, Ryuichi; Konishi, Gen-ichi; Takao, Toshiro; Suzuki, Hiroharu
Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon‒Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes
Organometallics, 2016, 35, 1446
4088182 CIFC25 H40 O2 P2 RuP -110.288; 10.829; 13.322
85.368; 72.18; 63.267
1259.1Zhang, Yuxuan; Fang, Huaquan; Yao, Wubing; Leng, Xuebing; Huang, Zheng
Synthesis of Pincer Hydrido Ruthenium Olefin Complexes for Catalytic Alkane Dehydrogenation
Organometallics, 2016, 35, 181
4088751 CIFC10 H14 Co N3 O3P 1 21/n 18.5902; 17.2237; 8.8972
90; 106.334; 90
1263.25Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088263 CIFC27 H18 F3 O6 P WP -19.6002; 10.5444; 13.8429
71.032; 76.087; 75.469
1263.3Kyri, Andreas W.; Schnakenburg, Gregor; Streubel, Rainer
C-Trifluoromethyl-Substituted 1,2-Oxaphosphetane Complexes: Synthetic and Structural Study
Organometallics, 2016, 35, 563
4088534 CIFC56 H56 Br4 N4 Ni2 O2P -19.5363; 10.2016; 14.0506
96.9349; 97.0991; 107.722
1273.81Chen, Zhou; Allen, Kate E.; White, Peter S.; Daugulis, Olafs; Brookhart, Maurice
Synthesis of Branched Polyethylene with “Half-Sandwich” Pyridine-Imine Nickel Complexes
Organometallics, 2016, 35, 1756
4086458 CIFC32 H30 N O2 P PdP -19.113; 11.339; 13.81
109.376; 105.198; 93.408
1282.2Ren, Zhi; Dong, Guangbin
Direct Observation of C‒H Cyclopalladation at Tertiary Positions Enabled by an Exo-Directing Group
Organometallics, 2016, 35, 1057
4088307 CIFC27 H43 B N3 O2P 1 21 18.8352; 12.6874; 12.1513
90; 109.329; 90
1285.3Lastovickova, Dominika N.; Bielawski, Christopher W.
Diamidocarbene Induced B‒H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents
Organometallics, 2016, 35, 706
4088218 CIFC40 H34 Cl14 N6 Pd2P -110.3614; 11.4558; 12.0112
71.254; 74.8; 88.602
1300.05Kinzhalov, Mikhail A.; Timofeeva, Svetlana A.; Luzyanin, Konstantin V.; Boyarskiy, Vadim P.; Yakimanskiy, Anton A.; Haukka, Matti; Kukushkin, Vadim Yu.
Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Structure of the Nucleophile
Organometallics, 2016, 35, 218
4089110 CIFC7 H9 Au Cl2 N6 SP n m a8.0461; 6.7554; 23.9279
90; 90; 90
1300.59Schuh, Esther; Werner, Svenja; Otte, Daniela; Monkowius, Uwe; Mohr, Fabian
A Neutral, Carbene-Stabilized Gold(III) Triazide
Organometallics, 2016, 35, 3448
4088981 CIFC31 H28 Fe N O4 PP -19.9841; 11.0287; 13.6068
81.4675; 75.3722; 64.057
1302.38Škoch, Karel; Císařová, Ivana; Štěpnička, Petr
Synthesis of a Polar Phosphinoferrocene Amidosulfonate Ligand and Its Application in Pd-Catalyzed Cross-Coupling Reactions of Aromatic Boronic Acids and Acyl Chlorides in an Aqueous Medium
Organometallics, 2016, 35, 3378
4088965 CIFC24 H38 Cl4 Rh2P 1 21/c 18.82203; 8.85285; 17.2213
90; 103.678; 90
1306.84Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088899 CIFC25 H38 B F4 O2 RhP -18.817; 8.9463; 18.1443
95.973; 95.706; 110.448
1319.52Shvydkiy, Nikita V.; Trifonova, Evgeniya A.; Shved, Andrei M.; Nelyubina, Yulia V.; Chusov, Denis; Perekalin, Dmitry S.; Kudinov, Alexander R.
Cyclobutadiene Arene Complexes of Rhodium and Iridium
Organometallics, 2016, 35, 3025
4088861 CIFC11 H14 B Br N4 OC 1 c 112.4966; 8.4594; 13.3671
90; 110.504; 90
1323.56Allen, Thomas H.; Geib, Steven J.; Curran, Dennis P.
Radical and Thermal Reactions of N-Heterocyclic Carbene Boranes with Diazo Compounds
Organometallics, 2016, 35, 2975
4089036 CIFC28 H27 F10 Ga N2P -110.1498; 10.981; 12.7022
82.472; 72.5308; 79.9641
1325.09Uhl, Werner; Willeke, Matthias; Hengesbach, Frank; Hepp, Alexander; Layh, Marcus
Aluminum and Gallium Hydrazides as Active Lewis Pairs: Cooperative C‒H Bond Activation with H‒C≡C‒Ph and Pentafluorobenzene
Organometallics, 2016, 35, 3701
4089076 CIFC30 H35 Cl O3 RuP -18.5895; 10.1957; 16.2215
75.318; 76.184; 80.418
1326Pettinari, Riccardo; Marchetti, Fabio; Petrini, Agnese; Pettinari, Claudio; Lupidi, Giulio; Smoleński, Piotr; Scopelliti, Rosario; Riedel, Tina; Dyson, Paul J.
From Sunscreen to Anticancer Agent: Ruthenium(II) Arene Avobenzone Complexes Display Potent Anticancer Activity
Organometallics, 2016, 35, 3734
4088846 CIFC30 H43 N P2P 1 21/m 15.6899; 25.685; 9.5148
90; 107.034; 90
1329.54Stolley, Ryan M.; Darmon, Jonathan M.; Das, Parthapratim; Helm, Monte L.
Nickel Bis-Diphosphine Complexes: Controlling the Binding and Heterolysis of H2
Organometallics, 2016, 35, 2965
4088891 CIFC25 H17 F3 N5 O6 Re SP -19.8664; 10.8251; 13.6341
70.788; 80.269; 76.658
1331.09Coe, Benjamin J.; Foxon, Simon P.; Pilkington, Rachel A.; Sánchez, Sergio; Whittaker, Daniel; Clays, Koen; Van Steerteghem, Nick; Brunschwig, Bruce S.
Rhenium(I) Tricarbonyl Complexes with Peripheral N-Coordination Sites: A Foundation for Heterotrimetallic Nonlinear Optical Chromophores
Organometallics, 2016, 35, 3014
4088893 CIFC23.5 H13 F3 N6 O6.5 Re SP -110.6015; 12.0951; 12.427
89.784; 66.738; 67.606
1333.2Coe, Benjamin J.; Foxon, Simon P.; Pilkington, Rachel A.; Sánchez, Sergio; Whittaker, Daniel; Clays, Koen; Van Steerteghem, Nick; Brunschwig, Bruce S.
Rhenium(I) Tricarbonyl Complexes with Peripheral N-Coordination Sites: A Foundation for Heterotrimetallic Nonlinear Optical Chromophores
Organometallics, 2016, 35, 3014
4088313 CIFC27 H31 B Cl3 N2 O2P -19.518; 10.87; 14.271
102.578; 108.45; 97.337
1335.8Lastovickova, Dominika N.; Bielawski, Christopher W.
Diamidocarbene Induced B‒H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents
Organometallics, 2016, 35, 706
4088622 CIFC11 H8 Cl4 O TiP 1 21/c 114.46; 7.286; 13.2538
90; 106.504; 90
1338.8Zhao, Weizhen; Yan, Qing; Tsutsumi, Ken; Nomura, Kotohiro
Efficient Norbornene (NBE) Incorporation in Ethylene/NBE Copolymerization by Half-Titanocene Catalysts Containing Chlorinated Aryloxo Ligands
Organometallics, 2016, 35, 1895
4086475 CIFC16 H13 Fe N O3P 1 21/n 111.065; 10.792; 11.8254
90; 107.86; 90
1344.1Korb, Marcus; Swarts, Pieter J.; Miesel, Dominique; Hildebrandt, Alexander; Swarts, Jannie C.; Lang, Heinrich
Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers
Organometallics, 2016, 35, 1287
4086654 CIFC30 H28 Cl Fe N O2 P2P -110.8245; 11.3704; 12.7062
104.288; 94.2083; 115.034
1344.66Chu, Wan-Yi; Richers, Casseday P.; Kahle, Elizabeth R.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Imine-Centered Reactions in Imino-Phosphine Complexes of Iron Carbonyls
Organometallics, 2016, 35, 2782
4086386 CIFC22 H32 N4 O Zn2P -19.6213; 10.033; 15.394
73.399; 72.122; 79.147
1347Honrado, Manuel; Otero, Antonio; Fernández-Baeza, Juan; Sánchez-Barba, Luis F.; Garcés, Andrés; Lara-Sánchez, Agustín; Rodríguez, Ana M.
Copolymerization of Cyclic Esters Controlled by Chiral NNO-Scorpionate Zinc Initiators
Organometallics, 2016, 35, 189
4088699 CIFC24 H53 Ir P2P -18.4709; 11.7388; 15.6404
103.61; 100.537; 110.861
1350.23Polukeev, Alexey V.; Marcos, Rocío; Ahlquist, Mårten S. G.; Wendt, Ola F.
Iridium Hydride Complexes with Cyclohexyl-Based Pincer Ligands: Fluxionality and Deuterium Exchange
Organometallics, 2016, 35, 2600
4086635 CIFC56 H78 Al2 N4 O2P -110.7701; 11.2577; 11.7012
95.089; 95.951; 105.241
1351.5Wei, Yun; Wang, Shaowu; Zhu, Xiancui; Zhou, Shuangliu; Mu, Xiaolong; Huang, Zeming; Hong, Dongjing
Aluminum Complexes Bearing N-Protected 2-Amino- or 2-Imino-Functionalized Pyrrolyl Ligands: Synthesis, Structure, and Catalysis for Preparation of Pyrrolyl-End-Functionalized Polyesters
Organometallics, 2016, 35, 2621
4086401 CIFC24 H40 Cl Ir N O6 PP 1 21 19.7702; 11.7884; 11.7937
90; 91.0496; 90
1358.11Grajeda, Javier; Kita, Matthew R.; Gregor, Lauren C.; White, Peter S.; Miller, Alexander J. M.
Diverse Cation-Promoted Reactivity of Iridium Carbonyl Pincer-Crown Ether Complexes
Organometallics, 2016, 35, 306-316
4088453 CIFC29 H31 Cl F0.5 Fe N2 SiP -19.7299; 11.4681; 12.7531
83.672; 74.459; 85.048
1360.3Tondreau, Aaron M.; Scott, Brian L.; Boncella, James M.
A Tertiary Carbon‒Iron Bond as an FeICl Synthon and the Reductive Alkylation of Diphosphine-Supported Iron(II) Chloride Complexes to Low-Valent Iron
Organometallics, 2016, 35, 1643
4088408 CIFC26 H32 Ni4 S4P -110.149; 12.274; 12.417
110.675; 97.652; 103.3
1368.7Chambers, Geoffrey M.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Effect of Pyramidalization of the M2(SR)2Center: The Case of (C5H5)2Ni2(SR)2
Organometallics, 2016, 35, 836
4088662 CIFC28 H36 B I N Nd O SiP -19.2648; 11.2797; 15.106
102.536; 103.535; 108.87
1376.8Wang, Chunhong; Xiang, Li; Leng, Xuebing; Chen, Yaofeng
Synthesis and Structure of Silicon-Bridged Boratabenzene Fluorenyl Rare-Earth Metal Complexes
Organometallics, 2016, 35, 1995
4088661 CIFC28 H36 B I La N O SiP -19.258; 11.3088; 15.0949
102.362; 103.967; 108.241
1382.8Wang, Chunhong; Xiang, Li; Leng, Xuebing; Chen, Yaofeng
Synthesis and Structure of Silicon-Bridged Boratabenzene Fluorenyl Rare-Earth Metal Complexes
Organometallics, 2016, 35, 1995
4088477 CIFC27 H38 Br2 Fe N2 OP -18.4392; 12.4618; 13.7286
78.655; 80.812; 80.569
1384.28Dunsford, Jay J.; Evans, David J.; Pugh, Thomas; Shah, Sachin N.; Chilton, Nicholas F.; Ingleson, Michael J.
Three-Coordinate Iron(II) Expanded Ring N-Heterocyclic Carbene Complexes
Organometallics, 2016, 35, 1098
4088623 CIFC11 H7 Cl5 O TiP n m a13.01; 12.359; 8.615
90; 90; 90
1385.2Zhao, Weizhen; Yan, Qing; Tsutsumi, Ken; Nomura, Kotohiro
Efficient Norbornene (NBE) Incorporation in Ethylene/NBE Copolymerization by Half-Titanocene Catalysts Containing Chlorinated Aryloxo Ligands
Organometallics, 2016, 35, 1895
4087888 CIFC21 H29 B2 Cl2 F4 N7 O WP -111.494; 11.7784; 12.1042
69.12; 76.651; 65.414
1385.66Beattie, Ross J.; White, Peter S.; Templeton, Joseph L.
Regioselectivity of Addition to the Azavinylidene Ligand in Tp′W(CO)(η2-HC≡CH)(N═CHMe): Electrophilic Addition versus Oxidation and Radical Coupling
Organometallics, 2015, 35, 32
4086370 CIFC32 H28 Cl O P S SiP -110.9149; 11.5973; 11.6182
107.644; 94.044; 95.38
1387.71Molitor, Sebastian; Schwarz, Christopher; Gessner, Viktoria H.
Mono- and Bis-Cyclometalated Palladium Complexes: Synthesis, Characterization, and Catalytic Activity
Organometallics, 2016, 35, 159
4086430 CIFC13 H15 F3 N2 O2 TiP n m a9.502; 7.282; 20.079
90; 90; 90
1389.3Wright, Luka A.; Hope, Eric G.; Solan, Gregory A.; Cross, Warren B.; Singh, Kuldip
Active O,Npy,N-Titanium(IV) Fluoride Precatalysts for Ethylene Polymerization: Exploring “Fluoride Effects” on Polymer Properties and Catalytic Performance
Organometallics, 2016, 35, 1183
4086639 CIFC56 H52 Ag2 F6 N4 O6 S6P -111.099; 12.343; 12.467
64.294; 65.426; 84.926
1390.7Morosaki, Tomohito; Suzuki, Tsubasa; Fujii, Takayoshi
Syntheses and Structural Characterization of Mono-, Di-, and Tetranuclear Silver Carbone Complexes
Organometallics, 2016, 35, 2715
4086604 CIFC40 H62 Cl2 Mo2 N4 O4P -19.894; 11.863; 12.757
102.557; 106.21; 93.427
1391.76Robinson, Thomas P.; Johnson, Andrew L.; Raithby, Paul R.; Kociok-Kohn, Gabriele
N-Heterocyclic Carbene Adducts of Molybdenum Tetracarboxylate Complexes
Organometallics, 2016, 35, 2494
4088747 CIFC11 H16 Co N3 O3P 1 21/n 112.5393; 7.8237; 15.1292
90; 110.084; 90
1393.98Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088740 CIFC11 H16 Co N5 O2P n a 2115.318; 10.6428; 8.5508
90; 90; 90
1394Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088256 CIFC36 H36 Si ZrP -111.5502; 11.6399; 11.7376
69.799; 86.134; 70.671
1395.53Theurkauff, Gabriel; Bader, Manuela; Marquet, Nicolas; Bondon, Arnaud; Roisnel, Thierry; Guegan, Jean-Paul; Amar, Anissa; Boucekkine, Abdou; Carpentier, Jean-François; Kirillov, Evgueni
Discrete Ionic Complexes of Highly Isoselective Zirconocenes. Solution Dynamics, Trimethylaluminum Adducts, and Implications in Propylene Polymerization
Organometallics, 2016, 35, 258
4088225 CIFC29 H42 Cl N O2 UP -18.4285; 10.3929; 17.363
94.9062; 95.2116; 111.159
1401Webster, Christopher L.; Langeslay, Ryan R.; Ziller, Joseph W.; Evans, William J.
Synthetic Utility of Tetrabutylammonium Salts in Uranium Metallocene Chemistry
Organometallics, 2016, 35, 520
4086406 CIFC14 H16 N2 O3 SP 1 21/c 17.5564; 7.6588; 24.263
90; 93.228; 90
1401.9Ruff, Andrew; Kirby, Christopher; Chan, Benny C.; O'Connor, Abby R.
Base-Free Transfer Hydrogenation of Ketones Using Cp*Ir(pyridinesulfonamide)Cl Precatalysts
Organometallics, 2016, 35, 327-335
4088571 CIFC30 H40 Ge N2 O PP -18.9086; 11.8758; 14.6478
96.071; 96.99; 111.786
1409Wu, Yile; Liu, Liu; Su, Jue; Zhu, Jun; Ji, Zhe; Zhao, Yufen
Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene
Organometallics, 2016, 35, 1593
4086602 CIFC58 H84 Mo2 N4 O8P -18.548; 11.901; 15.001
100.631; 102.629; 102.087
1413.08Robinson, Thomas P.; Johnson, Andrew L.; Raithby, Paul R.; Kociok-Kohn, Gabriele
N-Heterocyclic Carbene Adducts of Molybdenum Tetracarboxylate Complexes
Organometallics, 2016, 35, 2494
4088967 CIFC26 H42 Cl4 Rh2P 1 21/c 17.92156; 16.4923; 10.8961
90; 96.935; 90
1413.1Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4089037 CIFC30 H25.5 F12.5 Ga N2P -111.4372; 11.6551; 11.7123
94.385; 112.509; 97.741
1415.14Uhl, Werner; Willeke, Matthias; Hengesbach, Frank; Hepp, Alexander; Layh, Marcus
Aluminum and Gallium Hydrazides as Active Lewis Pairs: Cooperative C‒H Bond Activation with H‒C≡C‒Ph and Pentafluorobenzene
Organometallics, 2016, 35, 3701
4088310 CIFC30 H41 B N2 O4P -18.119; 11.875; 14.958
82.73; 86.7; 82.128
1415.9Lastovickova, Dominika N.; Bielawski, Christopher W.
Diamidocarbene Induced B‒H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents
Organometallics, 2016, 35, 706
4086801 CIFC14 H21 P SP 21 21 218.2833; 12.1905; 14.026
90; 90; 90
1416.31Fischer, Reinald; Görls, Helmar; Westerhausen, Matthias
Reactivity Studies of [(thf)2Mg{μ-C(CH3)2C2H4C(CH3)2}]2: Scrambling Reactions and Diverse Reactions with Dichlorophenylphosphane
Organometallics, 2016, 35, 3861
4086431 CIFC18 H12 O2P 1 21/c 114.4047; 7.1775; 14.602
90; 110.212; 90
1416.7Gao, Bao; Liu, Song; Lan, Yu; Huang, Hanmin
Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C‒H Bond Activation
Organometallics, 2016, 35, 1480
4086809 CIFC30 H18 F10 O4 P ReP -110.6325; 12.3889; 12.828
61.4248; 73.9864; 77.9876
1420.54Utegenov, Kamil I.; Krivykh, Vasilii V.; Mazhuga, Andrei M.; Chudin, Oleg S.; Smol'yakov, Aleksander F.; Dolgushin, Fedor M.; Goryunov, Evgenii I.; Ustynyuk, Nikolai A.
Reactions of Manganese and Rhenium Vinylidene Complexes with Hydrophosphoryl Compounds
Organometallics, 2016, 35, 3903-3913
4088958 CIFC26 H42 Cl4 Ir2P 1 21/c 17.88539; 16.9849; 10.7692
90; 97.759; 90
1429.14Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4086444 CIFC22 H42 O2 Si4 WP -19.259; 12.6926; 13.2925
68.987; 89.604; 79.879
1432.9Fukuda, Tetsuya; Yoshimoto, Takashi; Hashimoto, Hisako; Tobita, Hiromi
Synthesis of a Tungsten‒Silylyne Complex via Stepwise Proton and Hydride Abstraction from a Hydrido Hydrosilylene Complex
Organometallics, 2016, 35, 921
4086429 CIFC26 H28 Cl6 N2 O TiP 1 21 112.167; 10.002; 12.546
90; 110.017; 90
1434.5Wright, Luka A.; Hope, Eric G.; Solan, Gregory A.; Cross, Warren B.; Singh, Kuldip
Active O,Npy,N-Titanium(IV) Fluoride Precatalysts for Ethylene Polymerization: Exploring “Fluoride Effects” on Polymer Properties and Catalytic Performance
Organometallics, 2016, 35, 1183
4087884 CIFC23 H33 B F3 N7 O4 S WP -18.0823; 12.4028; 14.563
82.414; 84.135; 89.855
1439.4Beattie, Ross J.; White, Peter S.; Templeton, Joseph L.
Regioselectivity of Addition to the Azavinylidene Ligand in Tp′W(CO)(η2-HC≡CH)(N═CHMe): Electrophilic Addition versus Oxidation and Radical Coupling
Organometallics, 2015, 35, 32
4089032 CIFC31 H53 Al N4P -111.2344; 11.2633; 12.9804
93.348; 105.684; 111.948
1443.2Uhl, Werner; Willeke, Matthias; Hengesbach, Frank; Hepp, Alexander; Layh, Marcus
Aluminum and Gallium Hydrazides as Active Lewis Pairs: Cooperative C‒H Bond Activation with H‒C≡C‒Ph and Pentafluorobenzene
Organometallics, 2016, 35, 3701
4088214 CIFC25 H26 Cl6 N4 PdP -19.7816; 11.4718; 13.8868
88.356; 84.728; 69.234
1450.87Kinzhalov, Mikhail A.; Timofeeva, Svetlana A.; Luzyanin, Konstantin V.; Boyarskiy, Vadim P.; Yakimanskiy, Anton A.; Haukka, Matti; Kukushkin, Vadim Yu.
Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Structure of the Nucleophile
Organometallics, 2016, 35, 218
4086681 CIFC24 H25 Cl2 F3 N6 O3 Os SP -18.7097; 13.2661; 13.7956
69.446; 80.397; 78.817
1455.7Esteruelas, Miguel A.; Oñate, Enrique; Palacios, Adrián; Tsai, Jui-Yi; Xia, Chuanjun
Preparation of Capped Octahedral OsHC6Complexes by Sequential Carbon-Directed C‒H Bond Activation Reactions
Organometallics, 2016, 35, 2532
4086545 CIFC14 H23 O3 ReP 1 21/n 18.5282; 12.0181; 14.2586
90; 93.993; 90
1457.86Raju, Suresh; van Slagmaat, Christian A. M. R.; Li, Jing; Lutz, Martin; Jastrzebski, Johann T. B. H.; Moret, Marc-Etienne; Klein Gebbink, Robertus J. M.
Synthesis of Cyclopentadienyl-Based Trioxo-rhenium Complexes and Their Use as Deoxydehydration Catalysts
Organometallics, 2016, 35, 2178
4086474 CIFC16 H12 Fe N2 O5P -17.6575; 12.3403; 16.1955
104.659; 92.163; 98.373
1460.35Korb, Marcus; Swarts, Pieter J.; Miesel, Dominique; Hildebrandt, Alexander; Swarts, Jannie C.; Lang, Heinrich
Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers
Organometallics, 2016, 35, 1287
4088627 CIFC13 H13 Cl3 O TiP 1 21/n 17.583; 12.613; 15.659
90; 102.326; 90
1463.2Zhao, Weizhen; Yan, Qing; Tsutsumi, Ken; Nomura, Kotohiro
Efficient Norbornene (NBE) Incorporation in Ethylene/NBE Copolymerization by Half-Titanocene Catalysts Containing Chlorinated Aryloxo Ligands
Organometallics, 2016, 35, 1895
4088616 CIFC18 H14 N4 OP 1 21/n 19.2275; 15.4621; 10.472
90; 100.328; 90
1469.9Holtrichter-Rößmann, Thorsten; Häger, Ina; Daniliuc, Constantin-Gabriel; Fröhlich, Roland; Bergander, Klaus; Troll, Carsten; Rieger, Bernhard; Rojas, René S.; Würthwein, Ernst-Ulrich
Catalytically Active N-Acylamidine‒Zirconium Complexes: Synthesis, Structures, and Application in Ethylene Polymerization
Organometallics, 2016, 35, 1906
4088398 CIFC22 H45 B9 N3 TaP -110.7718; 11.4195; 12.8909
78.912; 83.025; 71.449
1472.14Xiang, Li; Xie, Zuowei
Reaction of [η1:η5-(R2NCH2CH2)C2B9H10]TaMe3 with Isonitriles: Effects of Nitrogen Substituents on Product Formation
Organometallics, 2016, 35, 1430
4088767 CIFC58 H64 Cl10 Ta4P -19.4688; 12.3457; 12.8125
92.462; 95.7; 93.168
1486.3Yamamoto, Keishi; Nagae, Haruki; Tsurugi, Hayato; Mashima, Kazushi
Synthesis and Reactions of Ditantalum—Allyl Complexes Derived from Intramolecular C‒H Bond Activation of the Methylene of the Ethyl Group Bound to Ditantallacyclopentadiene
Organometallics, 2016, 35, 2384
4088757 CIFC32 H35 Co N Na O4P -111.2666; 12.1163; 12.1953
104.217; 111.985; 90.688
1486.4Carpenter, Alex E.; Chan, Chinglin; Rheingold, Arnold L.; Figueroa, Joshua S.
A Well-Defined Isocyano Analogue of HCo(CO)4. 2: Relative Brønsted Acidity as a Function of Isocyanide Ligation
Organometallics, 2016, 35, 2319
4088291 CIFC11 H11 Br F6 N P SP 1 21/c 111.871; 9.496; 14.914
90; 117.62; 90
1489.6Leopold, Hendrik; Tronnier, Alexander; Wagenblast, Gerhard; Münster, Ingo; Strassner, Thomas
Photoluminescence of a New Material: Cyclometalated C∧C* Thiazole-2-ylidene Platinum(II) Complexes
Organometallics, 2016, 35, 959
4088854 CIFC7 H9 Cl3 Ga O4 Os PP n a 2112.502; 8.8053; 13.5439
90; 90; 90
1490.96Bissert, Robin; Braunschweig, Holger; Dewhurst, Rian D.; Schneider, Christoph
Metal-Only Lewis Pairs Based on Zerovalent Osmium
Organometallics, 2016, 35, 2567
4088486 CIFC40 H29 BP -111.0877; 11.9227; 12.2107
68.21; 88.182; 85.905
1495.01Barnard, Jonathan H.; Yruegas, Sam; Couchman, Shannon A.; Wilson, David J. D.; Dutton, Jason L.; Martin, Caleb D.
Reactivity of a Phosphaalkyne with Pentaarylboroles
Organometallics, 2016, 35, 929
4086358 CIFC10 H19 B Cl3 N TiP 1 21/n 16.6479; 17.3208; 13.0773
90; 95.456; 90
1498.99Chen, Yang; Fang, Xiangdong; Dan, Wenyan
1,2-Azaborolyl-Ligated Titanium(IV) Half-Metallocenes: Synthesis, Characterization, and Catalytic Activity in Ethylene Polymerization
Organometallics, 2016, 35, 15
4086796 CIFC36 H38 Hf N2 OP -19.601; 11.974; 13.526
91.855; 100.13; 100.99
1499Lopez, Michael J.; Kondo, Ai; Nagae, Haruki; Yamamoto, Koji; Tsurugi, Hayato; Mashima, Kazushi
C(sp3)‒H Alkenylation Catalyzed by Cationic Alkylhafnium Complexes: Stereoselective Synthesis of Trisubstituted Alkenes from 2,6-Dimethylpyridines and Internal Alkynes
Organometallics, 2016, 35, 3816
4088338 CIFC11 H21 F6 N2 PP n m a11.922; 14.727; 8.545
90; 90; 90
1500.3Ohki, Yasuhiro; Hoshino, Ryoko; Tatsumi, Kazuyuki
N-Heterocyclic Carbene Complexes of Three- and Four-Coordinate Fe(I)
Organometallics, 2016, 35, 1368
4089038 CIFC28 H54 Ga2P 1 21/c 19.8665; 16.3423; 9.8666
90; 109.266; 90
1501.81Uhl, Werner; Willeke, Matthias; Hengesbach, Frank; Hepp, Alexander; Layh, Marcus
Aluminum and Gallium Hydrazides as Active Lewis Pairs: Cooperative C‒H Bond Activation with H‒C≡C‒Ph and Pentafluorobenzene
Organometallics, 2016, 35, 3701
4088412 CIFC12 H14 B F4 Ni2 S2P n m a12.854; 10.221; 11.434
90; 90; 90
1502.2Chambers, Geoffrey M.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Effect of Pyramidalization of the M2(SR)2Center: The Case of (C5H5)2Ni2(SR)2
Organometallics, 2016, 35, 836
4088917 CIFC36 H64 F K O34 Si8P -110.687; 11.839; 12.269
82.019; 78.529; 84.78
1503.4El Aziz, Youssef; Taylor, Peter G.; Bassindale, Alan R.; Coles, Simon J.; Pitak, Mateusz B.
Synthesis and Structures of Novel Molecular Ionic Compounds Based on Encapsulation of Anions and Cations
Organometallics, 2016, 35, 4004
4086629 CIFC28 H33 Au Cl4 Fe N4P -110.7513; 10.7753; 14.3647
81.906; 75.409; 69.238
1503.44Ibáñez, Susana; Poyatos, Macarena; Dawe, Louise N.; Gusev, Dmitry; Peris, Eduardo
Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand
Organometallics, 2016, 35, 2747
4086667 CIFC28 H50 O Si2 Ti2P -19.4728; 9.5535; 16.739
90.435; 90.748; 95.455
1507.8González-Pérez, Juan I.; Martín, Avelino; Mena, Miguel; Santamaría, Cristina
C‒H Activation on an Oxo-Bridged Dititanium Complex: From Alkyl to μ-Alkylidene Functionalities
Organometallics, 2016, 35, 2488
4088713 CIFC33 H47 Ir N P2P 1 21 111.0667; 7.8272; 17.821
90; 100.684; 90
1516.9Vilanova, Sean P.; Iluc, Vlad M.
Aryl and Benzyl C‒H Activation of N-Substituted PNP Ligands
Organometallics, 2016, 35, 2110
4088513 CIFC28 H40 Cl2 N4 PdP -19.785; 11.2806; 14.3842
96.504; 99.873; 100.678
1519.79Mikhaylov, Vladimir N.; Sorokoumov, Viktor N.; Korvinson, Kirill A.; Novikov, Alexander S.; Balova, Irina A.
Synthesis and Simple Immobilization of Palladium(II) Acyclic Diaminocarbene Complexes on Polystyrene Support as Efficient Catalysts for Sonogashira and Suzuki‒Miyaura Cross-Coupling
Organometallics, 2016, 35, 1684
4088361 CIFC30 H50 Au Cl N2P -19.0146; 9.6658; 19.561
80.2718; 77.666; 66.636
1521.8Wurm, Thomas; Mulks, Florian; Böhling, Constantin R. N.; Riedel, Dominic; Zargaran, Poorya; Rudolph, Matthias; Rominger, Frank; Hashmi, A. Stephen K.
Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
Organometallics, 2016, 35, 1070
4086797 CIFC37 H39 Hf N3P -19.46; 12.221; 13.656
90.9; 100.097; 101.295
1522Lopez, Michael J.; Kondo, Ai; Nagae, Haruki; Yamamoto, Koji; Tsurugi, Hayato; Mashima, Kazushi
C(sp3)‒H Alkenylation Catalyzed by Cationic Alkylhafnium Complexes: Stereoselective Synthesis of Trisubstituted Alkenes from 2,6-Dimethylpyridines and Internal Alkynes
Organometallics, 2016, 35, 3816
4088632 CIFC28 H59 B2 N P2P -16.4856; 15.051; 17.126
68.713; 89.288; 78.376
1522.4Schneck, Felix; Assmann, Maik; Balmer, Markus; Harms, Klaus; Langer, Robert
Selective Hydrogenation of Amides to Amines and Alcohols Catalyzed by Improved Iron Pincer Complexes
Organometallics, 2016, 35, 1931
4088358 CIFC20 H17 Fe N OP 1 21/n 112.2332; 9.8643; 13.7723
90; 113.591; 90
1523Wang, Shao-Bo; Zheng, Jun; You, Shu-Li
Synthesis of Ferrocene-Based Pyridinones through Rh(III)-Catalyzed Direct C‒H Functionalization Reaction
Organometallics, 2016, 35, 1420
4086800 CIFC14 H22 Cl P SP c a 2111.8438; 11.954; 10.761
90; 90; 90
1523.55Fischer, Reinald; Görls, Helmar; Westerhausen, Matthias
Reactivity Studies of [(thf)2Mg{μ-C(CH3)2C2H4C(CH3)2}]2: Scrambling Reactions and Diverse Reactions with Dichlorophenylphosphane
Organometallics, 2016, 35, 3861
4086451 CIFC32 H54 P2P -19.8594; 11.751; 14.647
101.584; 109.156; 99.1
1523.6Magnuson, Kevin W.; Oshiro, Shelly M.; Gurr, Joshua R.; Yoshida, Wesley Y.; Gembicky, Milan; Rheingold, Arnold L.; Hughes, Russell P.; Cain, Matthew F.
Streamlined Preparation and Coordination Chemistry of Hybrid Phosphine‒Phosphaalkene Ligands
Organometallics, 2016, 35, 855-859
4088324 CIFC14 H28 Mg O2P 1 21/n 17.9111; 11.4856; 16.9013
90; 96.841; 90
1524.78Fischer, Reinald; Görls, Helmar; Langer, Jens; Enke, Marcel; Westerhausen, Matthias
Magnesiacycloalkanes with Different Ring Sizes
Organometallics, 2016, 35, 587
4086742 CIFC36 H32 Ge3P -19.6058; 10.9421; 14.6843
89.045; 83.682; 85.038
1528.27Komanduri, Sangeetha P.; Shumaker, F. Alexander; Roewe, Kimberly D.; Wolf, Melanie; Uhlig, Frank; Moore, Curtis E.; Rheingold, Arnold L.; Weinert, Charles S.
A Series of Isopropyl-Substituted Oligogermanes Pri3Ge(GePh2)nGePri3(n= 0‒3) Featuring a Luminescent and Dichroic Pentagermane Pri3Ge(GePh2)3GePri3
Organometallics, 2016, 35, 3240
4088643 CIFC26 H40 Fe O7 P2P -110.928; 11.64; 13.281
97.867; 91.907; 113.01
1533.3Taylor, Kathleen H.; Kalman, Steven E.; Gunnoe, T. Brent; Sabat, Michal
Combined Furan C‒H Activation and Furyl Ring-Opening by an Iron(II) Complex
Organometallics, 2016, 35, 1978
4086491 CIFC17 H16 Br N3 NiP -110.6057; 10.6136; 15.5632
96.408; 109.303; 107.351
1534.59Patel, Ulhas N.; Pandey, Dilip K.; Gonnade, Rajesh G.; Punji, Benudhar
Synthesis of Quinoline-Based NNN-Pincer Nickel(II) Complexes: A Robust and Improved Catalyst System for C‒H Bond Alkylation of Azoles with Alkyl Halides
Organometallics, 2016, 35, 1785
4086432 CIFC19 H17 O4P 1 21/n 113.7169; 7.4369; 15.9131
90; 108.119; 90
1542.8Gao, Bao; Liu, Song; Lan, Yu; Huang, Hanmin
Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C‒H Bond Activation
Organometallics, 2016, 35, 1480
4088970 CIFC32 H38 Cl4 Rh2P 1 21/c 18.6517; 8.7062; 20.4873
90; 90.354; 90
1543.14Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4089183 CIFC38 H40 N2 O P RhP -19.4911; 12.682; 13.2312
82.5351; 83.8707; 78.7654
1543.39Takano, Shotaro; Kochi, Takuya; Kakiuchi, Fumitoshi
Synthesis and Reactivity of Phosphine-Quinolinolato Rhodium Complexes: Intermediacy of Vinylidene and (Amino)carbene Complexes in the Catalytic Hydroamination of Terminal Alkynes
Organometallics, 2016, 35, 4112
4088378 CIFC33 H39 Fe N2 O3 PP -19.396; 9.9612; 16.94
85.736; 85.929; 78.23
1545.3Braunschweig, Holger; Dewhurst, Rian D.; Schneider, Christoph
Steric Control between Neutral Metal-Only Lewis Pairs and Metal-Stabilized Gallenium and Gallinium Cations
Organometallics, 2016, 35, 1002
4088684 CIFC36 H41 Li O2 ZrP -19.9544; 9.9584; 17.9494
74.4529; 80.4795; 64.7984
1548.36Chadwick, F. Mark; Cooper, Robert T.; O’Hare, Dermot
Zirconium and Hafnium Permethylpentalene Compounds
Organometallics, 2016, 35, 2092
4086490 CIFC17 H16 Cl N3 NiP -110.267; 12.072; 13.731
68.644; 79.66; 80.28
1549.3Patel, Ulhas N.; Pandey, Dilip K.; Gonnade, Rajesh G.; Punji, Benudhar
Synthesis of Quinoline-Based NNN-Pincer Nickel(II) Complexes: A Robust and Improved Catalyst System for C‒H Bond Alkylation of Azoles with Alkyl Halides
Organometallics, 2016, 35, 1785
4088348 CIFC30 H48 Cl2 N2 Ti2P 1 21/n 19.6985; 13.1527; 12.3263
90; 99.228; 90
1552Večeřa, Miloš; Varga, Vojtech; Císařová, Ivana; Pinkas, Jiří; Kucharczyk, Pavel; Sedlařík, Vladimír; Lamač, Martin
Group 4 Metal Complexes of Chelating Cyclopentadienyl-ketimide Ligands
Organometallics, 2016, 35, 785
4088399 CIFC25 H49 B9 N3 TaP -110.2023; 11.987; 13.8917
90.009; 100.465; 111.292
1552.53Xiang, Li; Xie, Zuowei
Reaction of [η1:η5-(R2NCH2CH2)C2B9H10]TaMe3 with Isonitriles: Effects of Nitrogen Substituents on Product Formation
Organometallics, 2016, 35, 1430
4086789 CIFC36 H27 F6 P PdP -110.732; 11.145; 14.509
102.877; 93.952; 111.326
1554.3Iwai, Tomohiro; Tanaka, Ryotaro; Sawamura, Masaya
Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines
Organometallics, 2016, 35, 3959
4088413 CIFC13 H16 B F4 Ni2 S2P n m a13.5362; 10.0545; 11.4337
90; 90; 90
1556.12Chambers, Geoffrey M.; Rauchfuss, Thomas B.; Arrigoni, Federica; Zampella, Giuseppe
Effect of Pyramidalization of the M2(SR)2Center: The Case of (C5H5)2Ni2(SR)2
Organometallics, 2016, 35, 836
4086553 CIFC36 H39 N4 P TiP -19.06; 11.614; 15.921
81.263; 89.363; 70.231
1556.8Batke, Sonja; Sietzen, Malte; Merz, Lukas; Wadepohl, Hubert; Ballmann, Joachim
Closely Related Benzylene-Linked Diamidophosphine Scaffolds and Their Zirconium and Hafnium Complexes: How Small Changes of the Ligand Result in Different Complex Stabilities and Reactivities
Organometallics, 2016, 35, 2294
4086720 CIFC32 H27 Cl N3 O6 ReP -19.434; 10.4154; 16.3142
92.057; 96.839; 101.301
1557.86Slootweg, Jack C.; Albada, H. Bauke; Siegmund, Daniel; Metzler-Nolte, Nils
Efficient Reagent-Saving Method for the N-Terminal Labeling of Bioactive Peptides with Organometallic Carboxylic Acids by Solid-Phase Synthesis
Organometallics, 2016, 35, 3192
4086425 CIFC66 H80 N8 O10 RuP -18.906; 12.166; 15.992
106.291; 105.192; 97.839
1563.3Song, Li-Cheng; Luo, Fei-Xian; Liu, Bei-Bei; Gu, Zhen-Chao; Tan, Hao
Novel Ruthenium Phthalocyanine-Containing Model Complex for the Active Site of [FeFe]-Hydrogenases: Synthesis, Structural Characterization, and Catalytic H2Evolution
Organometallics, 2016, 35, 1399
4086674 CIFC14 H24 Cl2 Ir N OP 1 21/c 115.4301; 7.6155; 14.5741
90; 114.059; 90
1563.79Frasco, Daniel A.; Mukherjee, Sriparna; Sommer, Roger D.; Perry, Cody M.; Lambic, Nikola S.; Abboud, Khalil A.; Jakubikova, Elena; Ison, Elon A.
Nondirected C‒H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study
Organometallics, 2016, 35, 2435
4088888 CIFC39 H28 Cl3 N3 OP -18.6492; 14.5632; 14.5731
63.439; 73.677; 88.306
1565.81Thenarukandiyil, Ranjeesh; Thrikkykkal, Hridya; Choudhury, Joyanta
Rhodium(III)-Catalyzed Nonaromatic sp2 C‒H Activation/Annulation Using NHC as a Directing and Functionalizable Group
Organometallics, 2016, 35, 3007
4088364 CIFC31 H52 Au Cl N2 OP -19.164; 10.1233; 19.4137
90.397; 102.347; 115.982
1571.12Wurm, Thomas; Mulks, Florian; Böhling, Constantin R. N.; Riedel, Dominic; Zargaran, Poorya; Rudolph, Matthias; Rominger, Frank; Hashmi, A. Stephen K.
Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
Organometallics, 2016, 35, 1070
4088714 CIFC33 H50 Ir N P2P -18.3236; 9.9365; 20.4872
90.814; 97.759; 109.517
1579.3Vilanova, Sean P.; Iluc, Vlad M.
Aryl and Benzyl C‒H Activation of N-Substituted PNP Ligands
Organometallics, 2016, 35, 2110
4088654 CIFC10 H10 MnP 1 21/c 114.9991; 9.8929; 11.4925
90; 111.814; 90
1583.2Reiners, Matthias; Baabe, Dirk; Freytag, Matthias; Jones, Peter G.; Walter, Marc D.
Closing the Gap: Preparation and Characterization of the First Half-Open and Open Manganocene Complexes
Organometallics, 2016, 35, 1986
4086550 CIFC36 H39 N4 P ZrP -18.975; 11.713; 16.176
81.466; 89.451; 70.647
1585.2Batke, Sonja; Sietzen, Malte; Merz, Lukas; Wadepohl, Hubert; Ballmann, Joachim
Closely Related Benzylene-Linked Diamidophosphine Scaffolds and Their Zirconium and Hafnium Complexes: How Small Changes of the Ligand Result in Different Complex Stabilities and Reactivities
Organometallics, 2016, 35, 2294
4088744 CIFC13 H20 Co N3 O3P n m a16.0481; 9.5636; 10.3892
90; 90; 90
1594.5Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088119 CIFC32 H48 Br N3 O3P -19.591; 10.87; 16.325
74.296; 76.993; 87.31
1596.2Wan, Li; Zhang, Dao
Brønsted Base-Induced Rearrangement and Nucleophilic Addition of O/N-Functionalized NHCs and Relative Group 4 Metal Complexes for Ethylene Polymerization Catalysis
Organometallics, 2016, 35, 138
4088240 CIFC8 H26 B9 O TaP 1 21/n 18.3504; 16.9616; 11.3968
90; 96.84; 90
1602.7Xiang, Li; Xie, Zuowei
Tantallacarborane Mediated Consecutive C‒C and C‒N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N-Heterocycles
Organometallics, 2016, 35, 233
4088921 CIFC44 H72 F K N8 O18 Si8P -110.841; 10.8627; 14.0694
92.776; 90.134; 104.358
1603.04El Aziz, Youssef; Taylor, Peter G.; Bassindale, Alan R.; Coles, Simon J.; Pitak, Mateusz B.
Synthesis and Structures of Novel Molecular Ionic Compounds Based on Encapsulation of Anions and Cations
Organometallics, 2016, 35, 4004
4088584 CIFC28 H43 I Li N6 TaP -110.4676; 11.0982; 15.7331
96.432; 92.191; 117.377
1604.45Helgert, Theodore R.; Zhang, Xiaofei; Box, Hannah K.; Denny, Jason A.; Valle, Henry U.; Oliver, Allen G.; Akurathi, Gopalakrishna; Webster, Charles Edwin; Hollis, T. Keith
Extreme π-Loading as a Design Element for Accessing Imido Ligand Reactivity. A CCC-NHC Pincer Tantalum Bis(imido) Complex: Synthesis, Characterization, and Catalytic Oxidative Amination of Alkenes
Organometallics, 2016, 35, 3452
4088833 CIFC16 H50 Ge O Si8P 1 2/c 112.715; 8.6713; 16.752
90; 119.13; 90
1613.4Walewska, Małgorzata; Hlina, Johann; Baumgartner, Judith; Müller, Thomas; Marschner, Christoph
Basic Reactivity Pattern of a Cyclic Disilylated Germylene.
Organometallics, 2016, 35, 2728-2737
4088691 CIFC39 H46 Au O PP -110.509; 12.2859; 13.7859
78.988; 78.948; 69.197
1618.31Brooner, Rachel E. M.; Brown, Timothy J.; Chee, Mark A.; Widenhoefer, Ross A.
Effect of Substitution, Ring Size, and Counterion on the Intermediates Generated in the Gold-Catalyzed Intramolecular Hydroalkoxylation of Allenes
Organometallics, 2016, 35, 2014
4088293 CIFC16 H16 Br N O2 Pt SP 1 21/c 111.518; 7.56; 21.82
90; 121.46; 90
1620.7Leopold, Hendrik; Tronnier, Alexander; Wagenblast, Gerhard; Münster, Ingo; Strassner, Thomas
Photoluminescence of a New Material: Cyclometalated C∧C* Thiazole-2-ylidene Platinum(II) Complexes
Organometallics, 2016, 35, 959
4088625 CIFC15 H9 Cl5 O TiP 1 21/c 114.302; 7.178; 16.465
90; 106.473; 90
1620.9Zhao, Weizhen; Yan, Qing; Tsutsumi, Ken; Nomura, Kotohiro
Efficient Norbornene (NBE) Incorporation in Ethylene/NBE Copolymerization by Half-Titanocene Catalysts Containing Chlorinated Aryloxo Ligands
Organometallics, 2016, 35, 1895
4088232 CIFC36 H26 As2 Cl2 PtP -18.9443; 9.6885; 19.3879
97.1321; 100.579; 96.5769
1622.43Imoto, Hiroaki; Tanaka, Susumu; Kato, Takuji; Watase, Seiji; Matsukawa, Kimihiro; Yumura, Takashi; Naka, Kensuke
Highly Efficient Solid-State Phosphorescence of Platinum Dihalide Complexes with 9-Phenyl-9-arsafluorene Ligands
Organometallics, 2016, 35, 364
4086373 CIFC34 H35 Cl P2 Pd S SiP -111.989; 12.008; 13.579
81.286; 66.326; 65.501
1628.9Molitor, Sebastian; Schwarz, Christopher; Gessner, Viktoria H.
Mono- and Bis-Cyclometalated Palladium Complexes: Synthesis, Characterization, and Catalytic Activity
Organometallics, 2016, 35, 159
4088971 CIFC34 H42 Cl4 Rh2P 1 21/c 18.19747; 14.7032; 14.0876
90; 105.933; 90
1632.73Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088309 CIFC38 H49 B N2 O2P 1 21 18.172; 16.783; 12.13
90; 100.44; 90
1636.1Lastovickova, Dominika N.; Bielawski, Christopher W.
Diamidocarbene Induced B‒H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents
Organometallics, 2016, 35, 706
4088832 CIFC32 H96 Ge2 Si16 Te2P -19.7437; 12.745; 14.836
102.8; 98.99; 109.42
1640.6Walewska, Małgorzata; Hlina, Johann; Baumgartner, Judith; Müller, Thomas; Marschner, Christoph
Basic Reactivity Pattern of a Cyclic Disilylated Germylene.
Organometallics, 2016, 35, 2728-2737
4088233 CIFC36.5 H27 As2 Br2 Cl PtP -18.9649; 9.8619; 19.2946
96.9662; 100.312; 97.5634
1645.25Imoto, Hiroaki; Tanaka, Susumu; Kato, Takuji; Watase, Seiji; Matsukawa, Kimihiro; Yumura, Takashi; Naka, Kensuke
Highly Efficient Solid-State Phosphorescence of Platinum Dihalide Complexes with 9-Phenyl-9-arsafluorene Ligands
Organometallics, 2016, 35, 364
4088260 CIFC20 H19 B N4C 1 c 14.1473; 20.9249; 19.065
90; 94.7599; 90
1648.79Chang, Mu-Chieh; Otten, Edwin
Intramolecular Hydride Transfer Reactions in (Formazanate)Boron Dihydride Complexes
Organometallics, 2016, 35, 534
4088961 CIFC34 H42 Cl4 Ir2P 1 21/c 18.24614; 14.78789; 14.1153
90; 105.581; 90
1658.01Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088824 CIFC20 H24 Fe N2P 1 21/c 19.6363; 21.525; 8.328
90; 106.176; 90
1659Lee, Heejun; Campbell, Michael G.; Hernández Sánchez, Raúl; Börgel, Jonas; Raynaud, Jean; Parker, Sarah E.; Ritter, Tobias
Mechanistic Insight Into High-Spin Iron(I)-Catalyzed Butadiene Dimerization
Organometallics, 2016, 35, 2923
4088788 CIFC32 H38 Cl F6 N3 O2.5 P RuP -18.0477; 12.1034; 18.7685
71.477; 79.56; 74.539
1661.36Wambang, Nathalie; Schifano-Faux, Nadège; Martoriati, Alain; Henry, Natacha; Baldeyrou, Brigitte; Bal-Mahieu, Christine; Bousquet, Till; Pellegrini, Sylvain; Meignan, Samuel; Cailliau, Katia; Goossens, Jean-François; Bodart, Jean-François; T. Ndifon, Peter; Pélinski, Lydie
Synthesis, Structure, and Antiproliferative Activity of Ruthenium(II) Arene Complexes of Indenoisoquinoline Derivatives
Organometallics, 2016, 35, 2868
4088900 CIFC16 H26 F2 O2 P RhP 21 21 218.354; 9.2101; 21.622
90; 90; 90
1663.6Shvydkiy, Nikita V.; Trifonova, Evgeniya A.; Shved, Andrei M.; Nelyubina, Yulia V.; Chusov, Denis; Perekalin, Dmitry S.; Kudinov, Alexander R.
Cyclobutadiene Arene Complexes of Rhodium and Iridium
Organometallics, 2016, 35, 3025
4088294 CIFC17 H19 N O3 Pt SP 1 21/c 19.574; 7.295; 24.706
90; 105.09; 90
1666Leopold, Hendrik; Tronnier, Alexander; Wagenblast, Gerhard; Münster, Ingo; Strassner, Thomas
Photoluminescence of a New Material: Cyclometalated C∧C* Thiazole-2-ylidene Platinum(II) Complexes
Organometallics, 2016, 35, 959
4087848 CIFC16 H23 Ge N3P 1 21/c 113.187; 16.231; 7.8031
90; 91.281; 90
1669.7Siwatch, Rahul Kumar; Karwasara, Surendar; Sharma, Mahendra Kumar; Mondal, Santigopal; Mukherjee, Goutam; Rajaraman, Gopalan; Nagendran, Selvarajan
Reactivity of LGe‒NR2 and LGe(E)‒NR2 over LGe‒Cl and LGe(E)‒Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN)
Organometallics, 2016, 35, 429
4086479 CIFC18 H17 Fe N3 O5P 21 21 217.5258; 10.2827; 21.647
90; 90; 90
1675.2Korb, Marcus; Swarts, Pieter J.; Miesel, Dominique; Hildebrandt, Alexander; Swarts, Jannie C.; Lang, Heinrich
Nucleophilic Aromatic Substitution Reactions for the Synthesis of Ferrocenyl Aryl Ethers
Organometallics, 2016, 35, 1287
4086374 CIFC34 H35 I P2 Pd S SiP -110.6034; 12.6786; 13.9842
89.381; 74.26; 68.635
1676.99Molitor, Sebastian; Schwarz, Christopher; Gessner, Viktoria H.
Mono- and Bis-Cyclometalated Palladium Complexes: Synthesis, Characterization, and Catalytic Activity
Organometallics, 2016, 35, 159
4088731 CIFC38 H42 N2 O4 RuP -110.141; 10.531; 18.1578
95.94; 103.763; 113.256
1687.57Yuan, Jian; Fracaroli, Alejandro M.; Klemperer, Walter G.
Convergent Synthesis of a Metal‒Organic Framework Supported Olefin Metathesis Catalyst
Organometallics, 2016, 35, 2149
4086454 CIFC16 H23 Cl Ge N2P 1 21/n 18.7947; 16.4126; 11.7594
90; 95.918; 90
1688.4Seow, Celestine; Xi, Hong-Wei; Li, Yongxin; So, Cheuk-Wai
Synthesis of a Germylidenide Anion from the C‒C Bond Activation of a Bis(germylene)
Organometallics, 2016, 35, 1060
4088561 CIFC36 H64 Fe P2P -18.8911; 10.513; 18.9627
99.1226; 100.212; 98.7086
1692.69Zhang, Fanjun; Jia, Jiong; Dong, Shuli; Wang, Wenguang; Tung, Chen-Ho
Hydride Transfer from Iron(II) Hydride Compounds to NAD(P)+ Analogues
Organometallics, 2016, 35, 1151
4086786 CIFC37 H36 Cl3 O2 P PdP -112.0788; 12.4978; 13.3752
69.029; 65.152; 74.163
1692.8Iwai, Tomohiro; Tanaka, Ryotaro; Sawamura, Masaya
Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines
Organometallics, 2016, 35, 3959
4086730 CIFC40.5 H59 N ZrP -19.9539; 10.2631; 17.0973
93.234; 100.79; 97.676
1694.41Valadez, Travis N.; Norton, Jack R.; Neary, Michelle C.; Quinlivan, Patrick J.
Reaction of Cp*2Zr(2,3-dimethylbutadiene) with Isonitriles and CO
Organometallics, 2016, 35, 3163
4088972 CIFC30 H46 Cl4 Rh2P 1 21/c 110.6334; 19.1231; 8.762
90; 107.806; 90
1696.35Brown, Loren C.; Ressegue, Emily; Merola, Joseph S.
Rapid Access to Derivatized, Dimeric, Ring-Substituted Dichloro(cyclopentadienyl)rhodium(III) and Iridium(III) Complexes
Organometallics, 2016, 35, 4014
4088184 CIFC36 H46 Cl O2 P3 RuP -110.1857; 10.318; 18.04
73.459; 85.247; 69.059
1697.05Zhang, Yuxuan; Fang, Huaquan; Yao, Wubing; Leng, Xuebing; Huang, Zheng
Synthesis of Pincer Hydrido Ruthenium Olefin Complexes for Catalytic Alkane Dehydrogenation
Organometallics, 2016, 35, 181
4086507 CIFC33 H51 Cl N4 Si2P -111.571; 12.215; 12.525
100.28; 91.594; 101.848
1700.9Li, Jianfeng; Ma, Bing; Cui, Chunming
Selective Silylation of Nitriles with an NHC-Stabilized Silylene to 1,2-Disilylimines and Subsequent Synthesis of Silaaziridines
Organometallics, 2016, 35, 1358
4086424 CIFC33 H42 Cl3 N4 O4P -17.949; 14.096; 15.683
87.595; 82.722; 77.709
1703Song, Li-Cheng; Luo, Fei-Xian; Liu, Bei-Bei; Gu, Zhen-Chao; Tan, Hao
Novel Ruthenium Phthalocyanine-Containing Model Complex for the Active Site of [FeFe]-Hydrogenases: Synthesis, Structural Characterization, and Catalytic H2Evolution
Organometallics, 2016, 35, 1399
4088425 CIFC34 H54 N2 O Ru2P -111.273; 12.396; 12.556
85.37; 80.494; 80.253
1703Shimogawa, Ryuichi; Konishi, Gen-ichi; Takao, Toshiro; Suzuki, Hiroharu
Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon‒Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes
Organometallics, 2016, 35, 1446
4088433 CIFC27 H38 B10 Cl0 Co N O4 S2P -18.7697; 13.03; 15.463
94.746; 103.907; 92.549
1705.5Dai, Huimin; Liu, Guifeng; Zhang, Xiaolei; Yan, Hong; Lu, Changsheng
Pyrrolylmethyl Functionalized o-Carborane Derivatives
Organometallics, 2016, 35, 1488
4088434 CIFC27 H38 B10 Co N O4 S2P -110.133; 10.719; 16.148
97.856; 97.291; 97.06
1705.8Dai, Huimin; Liu, Guifeng; Zhang, Xiaolei; Yan, Hong; Lu, Changsheng
Pyrrolylmethyl Functionalized o-Carborane Derivatives
Organometallics, 2016, 35, 1488
4088304 CIFC27 H30 B Br Cl6 F5 N4 RhP -111.379; 11.578; 14.258
103.404; 109.985; 91.438
1706Aznarez, Francisco; Sanz Miguel, Pablo J.; Tan, Tristan T. Y.; Hahn, F. Ekkehardt
Preparation of Rhodium(III) Di-NHC Chelate Complexes Featuring Two Different NHC Donors via a Mild NaOAc-Assisted C‒H Activation
Organometallics, 2016, 35, 410
4088730 CIFC28 H48 B4 O8 SeP 1 21 110.469; 13.8325; 11.9952
90; 100.723; 90
1706.7Torres Delgado, William; Shahin, Fatemeh; Ferguson, Michael J.; McDonald, Robert; He, Gang; Rivard, Eric
Selective Placement of Bromide and Pinacolboronate Groups about a Tellurophene: New Building Blocks for Optoelectronic Applications
Organometallics, 2016, 35, 2140
4086727 CIFC15 H28 B F3 N2P n a 2112.637; 13.9619; 9.6818
90; 90; 90
1708.22Huchenski, Blake S. N.; Adams, Matt R.; McDonald, Robert; Ferguson, Michael J.; Speed, Alexander W. H.
Synthesis and Catalytic Reactivity of Bis(amino)cyclopropenylidene Carbene‒Borane Adducts
Organometallics, 2016, 35, 3101
4088649 CIFC36 H54 Ir N Ru2P -110.8621; 11.0651; 15.7699
99.09; 91.631; 113.366
1709.4Nagaoka, Masahiro; Kawashima, Takashi; Suzuki, Hiroharu; Takao, Toshiro
Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt
Organometallics, 2016, 35, 2348
4087999 CIFC26 H57 N Si6P -19.8837; 12.1135; 15.9823
101.921; 90.777; 112.977
1714.24Wendel, Daniel; Eisenreich, Wolfgang; Jandl, Christian; Pöthig, Alexander; Rieger, Bernhard
Reactivity of an Acyclic Silylsilylene toward Ethylene: Migratory Insertion into the Si‒Si Bond
Organometallics, 2015, 35, 1
4088322 CIFC23 H50 Br2 Mg2 O8 Si2P 1 n 110.28; 13.6336; 12.6894
90; 104.668; 90
1720.5Fischer, Reinald; Görls, Helmar; Langer, Jens; Enke, Marcel; Westerhausen, Matthias
Magnesiacycloalkanes with Different Ring Sizes
Organometallics, 2016, 35, 587
4088238 CIFC25 H57 B9 N5 TaP -19.5732; 11.5853; 16.3387
78.036; 88.547; 76.38
1722.36Xiang, Li; Xie, Zuowei
Tantallacarborane Mediated Consecutive C‒C and C‒N Coupling Reactions of Alkyl Isonitriles: A Facile Route to N-Heterocycles
Organometallics, 2016, 35, 233
4089150 CIFC36 H41 Cl2 N3 Ru S2P -18.3833; 11.7203; 18.6217
97.169; 93.071; 107.313
1725.15Mikus, Malte S.; Torker, Sebastian; Xu, Chaofan; Li, Bo; Hoveyda, Amir H.
Pentacoordinate Ruthenium(II) Catecholthiolate and Mercaptophenolate Catalysts for Olefin Metathesis: Anionic Ligand Exchange and Ease of Initiation
Organometallics, 2016, 35, 3878
4088350 CIFC18 H21 Cl2 N TiP 1 21/c 17.0709; 13.5193; 18.3809
90; 100.332; 90
1728.61Večeřa, Miloš; Varga, Vojtech; Císařová, Ivana; Pinkas, Jiří; Kucharczyk, Pavel; Sedlařík, Vladimír; Lamač, Martin
Group 4 Metal Complexes of Chelating Cyclopentadienyl-ketimide Ligands
Organometallics, 2016, 35, 785
4088647 CIFC36 H51 Co F3 N Ru2P -19.0941; 10.9854; 17.6963
84.25; 88.121; 80.34
1733.84Nagaoka, Masahiro; Kawashima, Takashi; Suzuki, Hiroharu; Takao, Toshiro
Dehydrogenative Coupling of 4-Substituted Pyridines Catalyzed by a Trinuclear Complex of Ruthenium and Cobalt
Organometallics, 2016, 35, 2348
4086627 CIFC28 H35.83 Au B Cl3 F4 Fe N4 O0.42P -110.6273; 10.7075; 17.7058
106.334; 93.67; 113.637
1735.07Ibáñez, Susana; Poyatos, Macarena; Dawe, Louise N.; Gusev, Dmitry; Peris, Eduardo
Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand
Organometallics, 2016, 35, 2747
4088897 CIFC80 H102 N6P -110.6161; 12.0195; 14.2961
82.469; 73.813; 86.482
1736.17Sandoval, John J.; Melero, Cristóbal; Palma, Pilar; Álvarez, Eleuterio; Rodríguez-Delgado, Antonio; Cámpora, Juan
Oxygen-Induced Dimerization of Alkyl-Manganese(II) 2,6-Bisiminopyridine Complexes: Selective Synthesis of a New Ditopic NNN-Pincer Ligand
Organometallics, 2016, 35, 3336
4087843 CIFC15 H23 Br Ge N2P 1 21/c 111.57; 10.8627; 14.18
90; 102.667; 90
1738.8Siwatch, Rahul Kumar; Karwasara, Surendar; Sharma, Mahendra Kumar; Mondal, Santigopal; Mukherjee, Goutam; Rajaraman, Gopalan; Nagendran, Selvarajan
Reactivity of LGe‒NR2 and LGe(E)‒NR2 over LGe‒Cl and LGe(E)‒Cl toward Me3SiX (L = Aminotroponiminate; NR2 = N(SiMe3)2/NC4H4; E = S/Se; X = Br/CN)
Organometallics, 2016, 35, 429
4089047 CIFC68 H84 Cl8 N4 Pd2P -110.282; 11.538; 15.223
80.14; 78.85; 83.87
1740.6Rottschäfer, Dennis; Schürmann, Christian J.; Lamm, Jan-Hendrik; Paesch, Alexander N.; Neumann, Beate; Ghadwal, Rajendra S.
Abnormal-NHC Palladium(II) Complexes: Rational Synthesis, Structural Elucidation, and Catalytic Activity
Organometallics, 2016, 35, 3421
4088269 CIFC18 H26 N Na OP 1 21/c 112.072; 17.469; 8.7466
90; 109.19; 90
1742Border, Emily C.; Koutsaplis, Magdaline; Andrews, Philip C.
The Strange Case of Sodium (S)-N-α-(Methylbenzyl)allylamide: Anion Rearrangement, Decomposition, and a Peculiar Propyl Addition
Organometallics, 2016, 35, 303
4088138 CIFC33 H45 N12 YP -110.6958; 11.91; 15.3329
91.922; 96.08; 115.751
1742.43Lyubov, Dmitry M.; Cherkasov, Anton V.; Fukin, Georgy K.; Trifonov, Alexander A.
Selective Intermolecular C‒H Bond Activation: A Straightforward Synthetic Approach to Heteroalkyl Yttrium Complexes Containing a Bis(pyrazolyl)methyl Ligand
Organometallics, 2016, 35, 126
4088282 CIFC66 H66 N12 O24 Pd3P -111.4986; 13.5826; 13.5911
102.551; 109.767; 109.802
1742.45Wu, Hung-Chou; Chu, Jean-Ho; Li, Chin-Wei; Hwang, Long-Chih; Wu, Ming-Jung
Palladium-Catalyzed Regioselective Arylation of Pyrazolo[1,5-a]pyridines via C‒H Activation and Synthetic Applications on P38 Kinase Inhibitors
Organometallics, 2016, 35, 288
4086492 CIFC19 H20 Br N3 NiP 1 21/c 17.901; 27.393; 8.476
90; 108.169; 90
1743Patel, Ulhas N.; Pandey, Dilip K.; Gonnade, Rajesh G.; Punji, Benudhar
Synthesis of Quinoline-Based NNN-Pincer Nickel(II) Complexes: A Robust and Improved Catalyst System for C‒H Bond Alkylation of Azoles with Alkyl Halides
Organometallics, 2016, 35, 1785
4088743 CIFC15 H24 Co N5 O2P 1 21/c 110.4885; 8.2084; 20.4826
90; 98.606; 90
1743.6Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4089156 CIFC37 H40 Cl2 N2 Ru S2P -18.4562; 12.3417; 17.4107
88.469; 86.779; 73.987
1743.67Mikus, Malte S.; Torker, Sebastian; Xu, Chaofan; Li, Bo; Hoveyda, Amir H.
Pentacoordinate Ruthenium(II) Catecholthiolate and Mercaptophenolate Catalysts for Olefin Metathesis: Anionic Ligand Exchange and Ease of Initiation
Organometallics, 2016, 35, 3878
4088347 CIFC16 H25 Cl2 N TiP -19.1253; 12.2397; 16.2459
105.719; 90.49; 92.654
1744.37Večeřa, Miloš; Varga, Vojtech; Císařová, Ivana; Pinkas, Jiří; Kucharczyk, Pavel; Sedlařík, Vladimír; Lamač, Martin
Group 4 Metal Complexes of Chelating Cyclopentadienyl-ketimide Ligands
Organometallics, 2016, 35, 785
4088742 CIFC15 H24 Co N5 O2P 1 21/n 19.2608; 11.1303; 17.2042
90; 99.803; 90
1747.44Hering, Florian; Berthel, Johannes H. J.; Lubitz, Katharina; Paul, Ursula S. D.; Schneider, Heidi; Härterich, Marcel; Radius, Udo
Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes
Organometallics, 2016, 35, 2806
4088296 CIFC37 H37 Co2 Ga O7P -110.0677; 10.2348; 17.7124
82.247; 78.6991; 82.3595
1762.7McCrea-Hendrick, Madison L.; Caputo, Christine A.; Roberts, Christopher J.; Fettinger, James C.; Tuononen, Heikki M.; Power, Philip P.
Reactions of Terphenyl-Substituted Digallene AriPr4GaGaAriPr4 (AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with Transition Metal Carbonyls and Theoretical Investigation of the Mechanism of Addition
Organometallics, 2016, 35, 579
4089020 CIFC11 H20 Au Cl3 N2 OP 1 21/c 18.5106; 17.114; 12.1496
90; 94.468; 90
1764.2Anisimova, Tatyana B.; Kinzhalov, Mikhail A.; Kuznetsov, Maxim L.; Guedes da Silva, M. Fátima C.; Zolotarev, Andrey A.; Kukushkin, Vadim Yu.; Pombeiro, Armando J. L.; Luzyanin, Konstantin V.
1,3-Dipolar Cycloaddition of Nitrones to Gold(III)-Bound Isocyanides
Organometallics, 2016, 35, 3569
4089170 CIFC21 H21 Mn N2 O2P 1 21/n 111.5849; 12.3559; 12.3781
90; 94.879; 90
1765.4Valyaev, Dmitry A.; Wei, Duo; Elangovan, Saravanakumar; Cavailles, Matthieu; Dorcet, Vincent; Sortais, Jean-Baptiste; Darcel, Christophe; Lugan, Noël
Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation
Organometallics, 2016, 35, 4090
4086601 CIFC26 H32 F12 Mo2 N4 O8P -111.3739; 12.0093; 13.5043
90.405; 106.754; 91.534
1765.44Robinson, Thomas P.; Johnson, Andrew L.; Raithby, Paul R.; Kociok-Kohn, Gabriele
N-Heterocyclic Carbene Adducts of Molybdenum Tetracarboxylate Complexes
Organometallics, 2016, 35, 2494
4088706 CIFC37 H55 Cl Ir N O P2P -110.944; 11.9479; 15.3618
103.302; 107.999; 102.224
1770.2Vilanova, Sean P.; Iluc, Vlad M.
Aryl and Benzyl C‒H Activation of N-Substituted PNP Ligands
Organometallics, 2016, 35, 2110
4088722 CIFC19 H20 Fe2 O2 SP 1 21/c 17.3927; 13.293; 18.042
90; 90.62; 90
1772.9Marchetti, Fabio; Zacchini, Stefano; Zanotti, Valerio
Photochemical Alkyne Insertions into the Iron‒Thiocarbonyl Bond of [Fe2(CS)(CO)3(Cp)2]
Organometallics, 2016, 35, 2630
4088835 CIFC20 H54 Ge O2 Si8P -19.5187; 11.025; 17.622
103.03; 92; 99.13
1774.1Walewska, Małgorzata; Hlina, Johann; Baumgartner, Judith; Müller, Thomas; Marschner, Christoph
Basic Reactivity Pattern of a Cyclic Disilylated Germylene.
Organometallics, 2016, 35, 2728-2737
4088614 CIFC22 H20 N2 OP 1 21/c 111.4914; 13.9557; 11.4576
90; 104.649; 90
1777.73Holtrichter-Rößmann, Thorsten; Häger, Ina; Daniliuc, Constantin-Gabriel; Fröhlich, Roland; Bergander, Klaus; Troll, Carsten; Rieger, Bernhard; Rojas, René S.; Würthwein, Ernst-Ulrich
Catalytically Active N-Acylamidine‒Zirconium Complexes: Synthesis, Structures, and Application in Ethylene Polymerization
Organometallics, 2016, 35, 1906
4086368 CIFC16 H20 I P S SiP 1 21/c 18.6586; 12.4576; 16.964
90; 103.642; 90
1778.21Molitor, Sebastian; Schwarz, Christopher; Gessner, Viktoria H.
Mono- and Bis-Cyclometalated Palladium Complexes: Synthesis, Characterization, and Catalytic Activity
Organometallics, 2016, 35, 159
4088988 CIFC72 H72 Ag6 Fe6 N6 S6P -19.754; 12.461; 16.332
109.71; 106.676; 90.193
1779.1Kienz, Torben; Förster, Christoph; Heinze, Katja
Generation and Oligomerization ofN-Ferrocenyl Ketenimines via Open-Shell Intermediates
Organometallics, 2016, 35, 3681
4088763 CIFC34.5 H42 B Cl F4 N3 O3 ReP -19.1424; 9.8897; 20.4731
80.728; 77.828; 83.623
1780.12Lambic, Nikola S.; Lilly, Cassandra P.; Robbins, Leanna K.; Sommer, Roger D.; Ison, Elon A.
Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids
Organometallics, 2016, 35, 2822
4086378 CIFC38 H44 O P2 Pd S SiP -110.6786; 11.8158; 14.7036
81.058; 81.789; 78.133
1781.7Molitor, Sebastian; Schwarz, Christopher; Gessner, Viktoria H.
Mono- and Bis-Cyclometalated Palladium Complexes: Synthesis, Characterization, and Catalytic Activity
Organometallics, 2016, 35, 159
4086649 CIFC35 H38 B Fe N4 O3P 1 21/m 18.7519; 18.4759; 11.7496
90; 110.301; 90
1781.9Hickey, Anne K.; Lee, Wei-Tsung; Chen, Chun-Hsing; Pink, Maren; Smith, Jeremy M.
A Bidentate Carbene Ligand Stabilizes a Low-Coordinate Iron(0) Carbonyl Complex
Organometallics, 2016, 35, 3069
4086421 CIFC58 H72 B2 Cl8 F8 Ir2 N4 P4P -111.1147; 12.9222; 14.0055
102.598; 105.229; 105.141
1782.56Betoré, M. Pilar; Casado, Miguel A.; García-Orduña, Pilar; Lahoz, Fernando J.; Polo, Víctor; Oro, Luis A.
Oxidative Addition of the N‒H Bond of Ammonia to Iridium Bis(phosphane) Complexes: A Combined Experimental and Theoretical Study
Organometallics, 2016, 35, 720
4088806 CIFC40 H38 Cl2 Co2 N4 P2P 1 21/c 18.5561; 9.1862; 22.7389
90; 93.696; 90
1783.5Chu, Wan-Yi; Gilbert-Wilson, Ryan; Rauchfuss, Thomas B.; van Gastel, Maurice; Neese, Frank
Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis
Organometallics, 2016, 35, 2900
4088859 CIFC14 H22 B N5 O4P 1 21/c 112.044; 9.0062; 16.9281
90; 102.976; 90
1789.31Allen, Thomas H.; Geib, Steven J.; Curran, Dennis P.
Radical and Thermal Reactions of N-Heterocyclic Carbene Boranes with Diazo Compounds
Organometallics, 2016, 35, 2975
4089061 CIFC33 H47 B10 N4 O2 PP -19.9583; 12.4732; 15.1134
75.084; 85.019; 84.536
1801.97Bolotin, Dmitrii S.; Burianova, Valeria K.; Novikov, Alexander S.; Demakova, Marina Ya.; Pretorius, Carla; Mokolokolo, Pennie Petrus; Roodt, Andreas; Bokach, Nadezhda A.; Suslonov, Vitaliy V.; Zhdanov, Andrey P.; Zhizhin, Konstantin Yu.; Kuznetsov, Nikolay T.; Kukushkin, Vadim Yu.
Nucleophilicity of Oximes Based upon Addition to a Nitriliumcloso-Decaborate Cluster
Organometallics, 2016, 35, 3612
4086633 CIFC38 H54 Al2 N4P 1 21/n 110.506; 11.787; 14.9351
90; 101.71; 90
1811Wei, Yun; Wang, Shaowu; Zhu, Xiancui; Zhou, Shuangliu; Mu, Xiaolong; Huang, Zeming; Hong, Dongjing
Aluminum Complexes Bearing N-Protected 2-Amino- or 2-Imino-Functionalized Pyrrolyl Ligands: Synthesis, Structure, and Catalysis for Preparation of Pyrrolyl-End-Functionalized Polyesters
Organometallics, 2016, 35, 2621
4089107 CIFC38 H43 Br2 Fe2 N P2P 19.5717; 13.1857; 15.5566
100.365; 95.972; 107.632
1814.11Zirakzadeh, Afrooz; Kirchner, Karl; Roller, Alexander; Stöger, Berthold; Widhalm, Michael; Morris, Robert H.
Iron(II) Complexes Containing Chiral Unsymmetrical PNP′ Pincer Ligands: Synthesis and Application in Asymmetric Hydrogenations
Organometallics, 2016, 35, 3781
4088387 CIFC33 H51 Li N3 O PP -18.2117; 12.9279; 18.0555
81.097; 78.611; 76.631
1816.1Simler, Thomas; Karmazin, Lydia; Bailly, Corinne; Braunstein, Pierre; Danopoulos, Andreas A.
Potassium and Lithium Complexes with Monodeprotonated, Dearomatized PNP and PNCNHC Pincer-Type Ligands
Organometallics, 2016, 35, 903
4088404 CIFC37 H51 Cl3 N P Rh2P -110.428; 11.901; 14.709
86.78; 87; 87
1817.8van Dijk, Tom; Rong, Mark K.; Borger, Jaap E.; Nieger, Martin; Slootweg, J. Chris; Lammertsma, Koop
Bis(imino)phosphanes: Synthesis and Coordination Chemistry
Organometallics, 2016, 35, 827
4089048 CIFC20 H28 O4 RuP 1 21/c 111.667; 9.966; 15.7
90; 94.4; 90
1820.1Kiyota, Sayori; In, Seonyong; Saito, Ryo; Komine, Nobuyuki; Hirano, Masafumi
Ru(0)-Catalyzed Direct Coupling of Internal Alkynes with Conjugated Dienes: An Efficient Access to Conjugated Trienes
Organometallics, 2016, 35, 4033
4086586 CIFC38 H38 B N6 O2 P WP -112.2295; 12.8837; 13.0374
66.331; 78.549; 77.752
1823.76Colebatch, Annie L.; Hill, Anthony F.
Chlorophosphino Carbyne Complexes of Tungsten
Organometallics, 2016, 35, 2249
4086435 CIFC20 H25 N2 Na OP 21 21 2111.9995; 12.218; 12.4666
90; 90; 90
1827.73Lichtenberg, Crispin
Aminotroponiminates: Alkali Metal Compounds Reveal Unprecedented Coordination Modes
Organometallics, 2016, 35, 894
4088707 CIFC40 H55 Cl Ir N P2P -110.1952; 11.4033; 16.521
102.99; 100.621; 92.946
1830.8Vilanova, Sean P.; Iluc, Vlad M.
Aryl and Benzyl C‒H Activation of N-Substituted PNP Ligands
Organometallics, 2016, 35, 2110
4088424 CIFC38 H66 O Ru2P 1 n 110.2806; 11.8219; 15.4868
90; 103.059; 90
1833.53Shimogawa, Ryuichi; Konishi, Gen-ichi; Takao, Toshiro; Suzuki, Hiroharu
Photoinduced Reactions of Diruthenium Tetrahydride Complexes: Carbon‒Hydrogen Bond Cleavage of Tetrahydrofuran Leading to Bridging Cyclic Fischer-Type Carbene Complexes
Organometallics, 2016, 35, 1446
4088848 CIFC39 H28 Cl4 Cu F3 N2 O3 SP -111.7606; 12.1587; 12.8938
85; 88.881; 87.642
1834.92Klimovica, Kristine; Kirschbaum, Kristin; Daugulis, Olafs
Synthesis and Properties of "Sandwich" Diimine-Coinage Metal Ethylene Complexes.
Organometallics, 2016, 35, 2938-2943
4086672 CIFC19 H27 Ir O2 SP 21 21 219.1162; 13.3585; 15.0708
90; 90; 90
1835.3Frasco, Daniel A.; Mukherjee, Sriparna; Sommer, Roger D.; Perry, Cody M.; Lambic, Nikola S.; Abboud, Khalil A.; Jakubikova, Elena; Ison, Elon A.
Nondirected C‒H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study
Organometallics, 2016, 35, 2435
4088479 CIFC78 H100 Br4 Fe2 N4P -110.6547; 12.2902; 16.2704
70.448; 88.517; 67.228
1838Dunsford, Jay J.; Evans, David J.; Pugh, Thomas; Shah, Sachin N.; Chilton, Nicholas F.; Ingleson, Michael J.
Three-Coordinate Iron(II) Expanded Ring N-Heterocyclic Carbene Complexes
Organometallics, 2016, 35, 1098
4088020 CIFC28 H45 B10 D6 I N O2 P2 RhP -110.6949; 11.3884; 16.3856
76.18; 72.455; 80.535
1838.57Eleazer, Bennett J.; Smith, Mark D.; Peryshkov, Dmitry V.
Metal- and Ligand-Centered Reactivity of meta-Carboranyl-Backbone Pincer Complexes of Rhodium
Organometallics, 2016, 35, 106
4086436 CIFC20 H25 K N2 OP 1 21/n 111.1238; 8.0223; 21.1968
90; 103.547; 90
1838.9Lichtenberg, Crispin
Aminotroponiminates: Alkali Metal Compounds Reveal Unprecedented Coordination Modes
Organometallics, 2016, 35, 894
4086702 CIFC42 H44 Cs2 O7P -111.041; 11.602; 16.6071
92.756; 106.607; 112.989
1845.68Spisak, Sarah N.; Li, Jingbai; Rogachev, Andrey Yu.; Wei, Zheng; Papaianina, Olena; Amsharov, Konstantin; Rybalchenko, Alexey V.; Goryunkov, Alexey A.; Petrukhina, Marina A.
From Corannulene to Indacenopicene: Effect of Carbon Framework Topology on Aromaticity and Reduction Limits
Organometallics, 2016, 35, 3105
4088363 CIFC34 H49 Cl4 N3 PdP 1 21 110.28; 15.25; 12.261
90; 105.961; 90
1848.1Wurm, Thomas; Mulks, Florian; Böhling, Constantin R. N.; Riedel, Dominic; Zargaran, Poorya; Rudolph, Matthias; Rominger, Frank; Hashmi, A. Stephen K.
Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
Organometallics, 2016, 35, 1070
4089042 CIFC38 H44 Cl1.74 I1.26 N3 PdP -19.151; 11.811; 18.42
103.33; 96.42; 103.24
1857Rottschäfer, Dennis; Schürmann, Christian J.; Lamm, Jan-Hendrik; Paesch, Alexander N.; Neumann, Beate; Ghadwal, Rajendra S.
Abnormal-NHC Palladium(II) Complexes: Rational Synthesis, Structural Elucidation, and Catalytic Activity
Organometallics, 2016, 35, 3421
4088762 CIFC17 H12 F10 N3 O ReP 1 21/m 18.1014; 19.6607; 11.7352
90; 94.836; 90
1862.52Lambic, Nikola S.; Lilly, Cassandra P.; Robbins, Leanna K.; Sommer, Roger D.; Ison, Elon A.
Reductive Carbonylation of Oxorhenium Hydrides Induced by Lewis Acids
Organometallics, 2016, 35, 2822
4086567 CIFC46 H41 Hf N2 PP -19.6903; 13.2661; 15.1478
100.832; 92.9449; 101.485
1866.3Batke, Sonja; Sietzen, Malte; Merz, Lukas; Wadepohl, Hubert; Ballmann, Joachim
Closely Related Benzylene-Linked Diamidophosphine Scaffolds and Their Zirconium and Hafnium Complexes: How Small Changes of the Ligand Result in Different Complex Stabilities and Reactivities
Organometallics, 2016, 35, 2294
4086577 CIFC19 H22 Au N O2 S2P n n a9.6573; 14.9056; 13.0267
90; 90; 90
1875.2Nilakantan, Lakshmi; McMillin, David R.; Sharp, Paul R.
Emissive Biphenyl Cyclometalated Gold(III) Diethyl Dithiocarbamate Complexes
Organometallics, 2016, 35, 2339
4086498 CIFC25 H62 N2 Si6 SmP -111.4634; 11.8589; 16.2723
72.595; 84.882; 62.847
1875.3Pindwal, Aradhana; Ellern, Arkady; Sadow, Aaron D.
Homoleptic Divalent Dialkyl Lanthanide-Catalyzed Cross-Dehydrocoupling of Silanes and Amines
Organometallics, 2016, 35, 1674
4088815 CIFC90 H94 N2 O4 P2 PtP -19.5706; 13.1673; 16.6608
71.273; 86.786; 71.249
1880.28Al-Owaedi, Oday A.; Milan, David C.; Oerthel, Marie-Christine; Bock, Sören; Yufit, Dmitry S.; Howard, Judith A. K.; Higgins, Simon J.; Nichols, Richard J.; Lambert, Colin J.; Bryce, Martin R.; Low, Paul J.
Experimental and Computational Studies of the Single-Molecule Conductance of Ru(II) and Pt(II) trans-Bis(acetylide) Complexes
Organometallics, 2016, 35, 2944
4089044 CIFC38 H45 Cl0.15 I1.85 N3 PdP -19.2685; 11.7625; 18.2798
101.143; 96.316; 102.93
1881.1Rottschäfer, Dennis; Schürmann, Christian J.; Lamm, Jan-Hendrik; Paesch, Alexander N.; Neumann, Beate; Ghadwal, Rajendra S.
Abnormal-NHC Palladium(II) Complexes: Rational Synthesis, Structural Elucidation, and Catalytic Activity
Organometallics, 2016, 35, 3421
4088954 CIFC40 H34 F6 Fe2 N2 O3 S2P -110.6747; 13.1639; 14.6246
108.022; 91.905; 103.904
1884.04Hess, Jeannine; Patra, Malay; Pierroz, Vanessa; Spingler, Bernhard; Jabbar, Abdul; Ferrari, Stefano; Gasser, Robin B.; Gasser, Gilles
Synthesis, Characterization, and Biological Activity of Ferrocenyl Analogues of the Anthelmintic Drug Monepantel
Organometallics, 2016, 35, 3369
4088452 CIFC24.566 H61.633 Fe2 N2 P8P -19.2918; 9.614; 23.399
90.684; 90.764; 115.56
1885.2Tondreau, Aaron M.; Scott, Brian L.; Boncella, James M.
A Tertiary Carbon‒Iron Bond as an FeICl Synthon and the Reductive Alkylation of Diphosphine-Supported Iron(II) Chloride Complexes to Low-Valent Iron
Organometallics, 2016, 35, 1643
4088826 CIFC43 H44 Fe N2 O4P -110.1393; 10.7878; 18.1314
77.341; 80.516; 79.342
1885.6Bhunia, Mrinal; Hota, Pradip Kumar; Vijaykumar, Gonela; Adhikari, Debashis; Mandal, Swadhin K.
A Highly Efficient Base-Metal Catalyst: Chemoselective Reduction of Imines to Amines Using An Abnormal-NHC‒Fe(0) Complex
Organometallics, 2016, 35, 2930
4089181 CIFC23 H17 N O2 P RhP 1 21/n 111.9073; 13.9158; 12.1176
90; 109.92; 90
1887.7Takano, Shotaro; Kochi, Takuya; Kakiuchi, Fumitoshi
Synthesis and Reactivity of Phosphine-Quinolinolato Rhodium Complexes: Intermediacy of Vinylidene and (Amino)carbene Complexes in the Catalytic Hydroamination of Terminal Alkynes
Organometallics, 2016, 35, 4112
4088279 CIFC37 H68 Cl2 P2 RuP -110.2601; 10.6107; 18.071
100.204; 98.7088; 96.6684
1893.12Lummiss, Justin A. M.; Perras, Frédéric A.; McDonald, Robert; Bryce, David L.; Fogg, Deryn E.
Sterically Driven Olefin Metathesis: The Impact of Alkylidene Substitution on Catalyst Activity
Organometallics, 2016, 35, 691

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