Crystallography Open Database

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4065684 CIFBr12 Si6C 1 2/c 118.324; 10.0813; 14.2797
90; 110.015; 90
2478.6Dai, Xuliang; Schulz, Douglas L.; Braun, Christopher W.; Ugrinov, Angel; Boudjouk, Philip
“Inverse Sandwich” Complexes of Perhalogenated Cyclohexasilane
Organometallics, 2010, 29, 2203
4065627 CIFC H1.5 Cl2.5 SiP -16.1896; 8.3969; 9.0412
89.363; 80.569; 78.809
454.63Hong, Soon Hyun; Hyun, Sang Il; Jung, Il Nam; Han, Won-Sik; Kim, Min-Hye; Yun, Hoseop; Nam, Suk-Woo; Kang, Sang Ook
[Bu4P]+Cl−-Catalyzed Reactions of Trichlorosilane and Dichloromethylsilane with Vinyltrichlorosilane: New Synthetic Method for 1,1,4,4-Tetrachloro-2,5-bis(trichlorosilyl)-1,4-disilacyclohexane Compounds
Organometallics, 2010, 29, 3054
4066669 CIFC10 H12 Br N OP 21 21 217.5481; 11.1754; 12.3578
90; 90; 90
1042.42Eloi, Antoine; Rose-Munch, Françoise; Rose, Eric; Pille, Ariane; Lesot, Philippe; Herson, Patrick
Cationic Planar Chiral (η6-Arene)Mn(CO)3+Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+Complexes
Organometallics, 2010, 29, 3876
4067355 CIFC10 H12 Cl F6 N4 O P Pt SP -19.2567; 9.6582; 10.1176
89.924; 73.19; 76.363
839.31Villalobos, Janette M.; Hickman, Amanda J.; Sanford, Melanie S.
Platinum(II) Complexes Containing Quaternized Nitrogen Ligands: Synthesis, Stability, and Evaluation as Catalysts for Methane and Benzene H/D Exchange
Organometallics, 2010, 29, 257
4067467 CIFC10 H13 B7 Fe N2 O3R -3 :H27.73; 27.73; 11.6194
90; 90; 120
7737.7Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067136 CIFC10 H15 B N TiP b c a9.4046; 9.6243; 22.776
90; 90; 90
2061.5Wolstenholme, David J.; Traboulsee, Kyle T.; Decken, Andreas; McGrady, G. Sean
Structure and Bonding of Titanocene Amidoborane Complexes: A Common Bonding Motif with Their β-Agostic Organometallic Counterparts
Organometallics, 2010, 29, 5769
4067484 CIFC10 H15 Br2 Ge N2P 1 21/c 18.9596; 8.1184; 19.024
90; 100.39; 90
1361.1Ruddy, Adam J.; Rupar, Paul A.; Bladek, Kamila J.; Allan, Christopher J.; Avery, Jessica C.; Baines, Kim M.
On the Bonding in N-Heterocyclic Carbene Complexes of Germanium(II)
Organometallics, 2010, 29, 1362
4065924 CIFC10 H15 Cl GeP 1 21/n 19.0939; 6.879; 17.395
90; 102.54; 90
1062.2Rohr, Ahleah D.; Kampf, Jeff W.; Wolfe, John P.; Banaszak Holl, Mark M.
Parallelograms and Ladders: Polymorphic Solid-State Structures and Solution Equilibria of Cp*GeCl†
Organometallics, 2010, 29, 5004
4065925 CIFC10 H15 Cl GeC 1 2/c 116.3143; 12.0713; 11.8225
90; 109.368; 90
2196.5Rohr, Ahleah D.; Kampf, Jeff W.; Wolfe, John P.; Banaszak Holl, Mark M.
Parallelograms and Ladders: Polymorphic Solid-State Structures and Solution Equilibria of Cp*GeCl†
Organometallics, 2010, 29, 5004
4067080 CIFC10 H15 Cl Ni O2 P2P 1 21/c 19.1889; 9.5488; 31.4741
90; 90.509; 90
2761.52Zhang, Jie; Medley, Christopher M.; Krause, Jeanette A.; Guan, Hairong
Mechanistic Insights into C−S Cross-Coupling Reactions Catalyzed by Nickel Bis(phosphinite) Pincer Complexes
Organometallics, 2010, 29, 6393
4066732 CIFC10 H15 Cl O P Pt0.5P -17.955; 8.069; 9.667
101.8; 104.01; 96.4
580.806Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Gimbert, Yves; Buono, Gérard
Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Organometallics, 2010, 29, 3936
4067483 CIFC10 H15 Cl2 Ge N2P 1 21/n 19.1392; 10.396; 13.647
90; 90.52; 90
1296.6Ruddy, Adam J.; Rupar, Paul A.; Bladek, Kamila J.; Allan, Christopher J.; Avery, Jessica C.; Baines, Kim M.
On the Bonding in N-Heterocyclic Carbene Complexes of Germanium(II)
Organometallics, 2010, 29, 1362
4066499 CIFC10 H16 N4 S2 SiP n a 2116.8497; 11.5975; 7.1424
90; 90; 90
1395.73Wagler, Jörg; Heine, Thomas; Hill, Anthony F.
Poly(methimazolyl)silanes: Syntheses and Molecular Structures†
Organometallics, 2010, 29, 5607
4066440 CIFC10 H17 Cl N2 O3 Si2P b c a11.19; 13.114; 19.667
90; 90; 90
2886Kertsnus-Banchik, Evgenia; Gostevskii, Boris; Botoshansky, Mark; Kalikhman, Inna; Kost, Daniel
Dinuclear Silicon Complexes of Uracil, Barbituric Acid, and 5,5-Dimethylbarbituric Acid: Hydrolytic Formation of Cyclic Oligomers(1)†
Organometallics, 2010, 29, 5435
4067101 CIFC10 H19 Li2 N3P m m n :29.469; 10.559; 6.18
90; 90; 90
617.9Michel, Reent; Herbst-Irmer, Regine; Stalke, Dietmar
Unprecedented CpLi Ammoniacates
Organometallics, 2010, 29, 6169
4065894 CIFC10 H23 B2 Cl ZrP 1 21/n 17.2274; 14.5425; 13.4015
90; 93.176; 90
1406.4Liu, Fu-Chen; Chu, Yong-Jui; Yang, Chien-Chan; Lee, Gene-Hsian; Peng, Shie-Ming
Syntheses and Structures of Zirconium Tetranuclear Polyhydrides
Organometallics, 2010, 29, 2685
4067704 CIFC10 H23 B9 Fe SP 21 21 218.8361; 12.1482; 14.5361
90; 90; 90
1560.34Kudinov, Alexander R.; Zanello, Piero; Herber, Rolfe H.; Loginov, Dmitry A.; Vinogradov, Mikhail M.; Vologzhanina, Anna V.; Starikova, Zoya A.; Corsini, Maddalena; Giorgi, Gianluca; Nowik, Israel
Ferracarborane Benzene Complexes [(η-9-L-7,8-C2B9H10)Fe(η-C6H6)]+(L = SMe2, NMe3): Synthesis, Reactivity, Electrochemistry, Mössbauer Effect Studies, and Bonding
Organometallics, 2010, 29, 2260
4063493 CIFC10 H24 Cl2 Ge N6P 1 21/n 110.0347; 11.4752; 14.8505
90; 97.796; 90
1694.2Chen, Tianniu; Hunks, William; Chen, Philip S.; Xu, Chongying; DiPasquale, Antonio G.; Rheingold, Arnold L.
Synthesis, Structural Characterization, and Thermal Properties of the First Germanium N,N,N',N'-Tetraalkylguanidinates
Organometallics, 2010, 29, 501-504
4067530 CIFC10 H31 N Si6C 1 2/c 117.902; 7.3368; 16.269
90; 106.75; 90
2046.2Stueger, Harald; Fuerpass, Gottfried; Mitterfellner, Thomas; Baumgartner, Judith
Synthesis and Reactivity of NH2Derivatives of Dodecamethylcyclohexasilane
Organometallics, 2010, 29, 618
4066670 CIFC10 H7 B Br F4 Mn O4P 1 21 17.1425; 12.341; 15.3631
90; 93.477; 90
1351.7Eloi, Antoine; Rose-Munch, Françoise; Rose, Eric; Pille, Ariane; Lesot, Philippe; Herson, Patrick
Cationic Planar Chiral (η6-Arene)Mn(CO)3+Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+Complexes
Organometallics, 2010, 29, 3876
4083389 CIFC10 H7 B Br F4 Mn O4P 1 21 17.138; 12.326; 15.347
90; 93.63; 90
1347.6Eloi, Antoine; Rose-Munch, Françoise; Rose, Eric; Pille, Ariane; Lesot, Philippe; Herson, Patrick
Cationic Planar Chiral (η6-Arene)Mn(CO)3+Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+Complexes
Organometallics, 2010, 29, 3876
4066466 CIFC100 H100 Cl12 O12 P4 Pt2P -113.8451; 15.0585; 15.7499
61.876; 77.895; 64.178
2606.74Leung, Sammual Yu-Lut; Lam, Wai Han; Zhu, Nianyong; Yam, Vivian Wing-Wah
Synthesis, Structural Characterization, and Photophysical Study of Luminescent Face-to-Face Dinuclear Platinum(II) Alkynyl Phosphine Complexes and Their Tetranuclear Mixed-Metal Platinum(II)−Silver(I) and −Copper(I) Complexes†
Organometallics, 2010, 29, 5558
4066760 CIFC100 H108 B2 N2 V2P 1 21/c 111.6718; 24.059; 15.146
90; 104.37; 90
4120.1Jordan, Markus; Saak, Wolfgang; Haase, Detlev; Beckhaus, Rüdiger
Bridging Azines in the Coordination Sphere of Low-Valent Vanadocene Derivatives†
Organometallics, 2010, 29, 5859
4063343 CIFC100 H78 N16 O12 Re4P 1 21/c 112.13; 17.621; 22.118
90; 102.221; 90
4620Chuan-Hung Chuang; Malaichamy Sathiyendiran; Yi-Hsiu Tseng; Jing-Yun Wu; Kung-Chung Hsu; Chen-Hsiung Hung; Yuh-Sheng Wen; Kuang-Lieh Lu
A Rigidity-Modulated Approach toward the Construction of Metallacycles from a Flexible Tetratopic Ligand
Organometallics, 2010, 29, 283
4066479 CIFC102 H172 B4 Br2 N2 O4 P4 Pt2 Si2P -111.4059; 12.142; 20.5196
82.86; 76.086; 78.028
2690.09Braunschweig, Holger; Matz, Ferdinand; Radacki, Krzysztof; Schneider, Achim
Reactivity of Platinum Iminoboryl Complexes toward Covalent Element−Hydrogen Bonds of Opposing Polarity
Organometallics, 2010, 29, 3457
4066677 CIFC103 H129 N6 S4 Si2P -110.9167; 19.022; 23.425
89.86; 83.91; 74.496
4659.2Kong, Lingbing; Cui, Chunming
Synthesis and Reactivity of a Base-Free N-Heterocyclic Silanimine†
Organometallics, 2010, 29, 5738
4066554 CIFC103 H161 N3 O7 Sm2P 1 21/n 117.6169; 39.9745; 19.4487
90; 116.224; 90
12286.6Dyer, Hellen E.; Huijser, Saskia; Susperregui, Nicolas; Bonnet, Fanny; Schwarz, Andrew D.; Duchateau, Robbert; Maron, Laurent; Mountford, Philip
Ring-Opening Polymerization ofrac-Lactide by Bis(phenolate)amine-Supported Samarium Borohydride Complexes: An Experimental and DFT Study
Organometallics, 2010, 29, 3602
4066890 CIFC103 H172 Cs3 N4 O7 P5C 1 2/c 160.21; 10.9354; 35.649
90; 107.523; 90
22383Ionkin, Alex S.; Marshall, William J.; Fish, Brian M.; Howe, Laurie A.
Fragmentation of an N-Substituted One-Coordinate Phosphorus (Phosphaalkyne): Plausible Generation of Monovalent Phosphorus Species†
Organometallics, 2010, 29, 4154
4065902 CIFC104 H110 O5 P4 Ru2P 1 21/c 113.1206; 14.4846; 25.5142
90; 100.653; 90
4765.3Torker, Sebastian; Müller, Andre; Sigrist, Raphael; Chen, Peter
Tuning the Steric Properties of a Metathesis Catalyst for Copolymerization of Norbornene and Cyclooctene toward Complete Alternation
Organometallics, 2010, 29, 2735
4065941 CIFC104 H130 Li2 O13 Y4P -113.182; 14.988; 15.408
118.992; 96.419; 92.928
2627Li, Xiaoqing; Liu, Ruiting; Zhang, Zhengxing; Mu, Xiaoming; Weng, Linhong; Zhou, Xigeng
Unexpected Tandem Reactions of Tris(cyclopentadieny1)lanthanide with Diphenylketene and Regeneration of the η5-Bonding Mode: One-Pot Synthesis of Heteroleptic Yttrocenes from Simple (C5H5)3Y Precursors
Organometallics, 2010, 29, 3298
4067264 CIFC105 H96 B2 N2 O2 P2P b c n17.2935; 20.5469; 23.7107
90; 90; 90
8425.1Ireland, Benjamin J.; Wheaton, Craig A.; Hayes, Paul G.
Cationic Organomagnesium Complexes as Highly Active Initiators for the Ring-Opening Polymerization of ε-Caprolactone
Organometallics, 2010, 29, 1079
4067726 CIFC105.4 H103.44 Cl7.32 P4 Zn4P -111.4075; 13.3666; 17.1784
86.488; 71.105; 87.171
2472.3MacIntosh, Ian S.; Sherren, Cody N.; Robertson, Katherine N.; Masuda, Jason D.; Pye, Cory C.; Clyburne, Jason A. C.
Isolation and Structures of Two New Organozinc Anions from Solutions Rich in Halide Ions
Organometallics, 2010, 29, 2063
4065727 CIFC106 H108 Al0 B Cl5 F20 Gd3 N6P -114.875; 15.109; 24.265
90.985; 98.54; 92.317
5387Li, Danfeng; Li, Shihui; Cui, Dongmei; Zhang, Xuequan
β-Diketiminato Rare-Earth Metal Complexes. Structures, Catalysis, and Active Species for Highlycis-1,4-Selective Polymerization of Isoprene
Organometallics, 2010, 29, 2186
4065568 CIFC108 H106 Fe4 P4P 1 21/c 112.1381; 10.5715; 34.004
90; 97.06; 90
4330.2Lohan, Manja; Justaud, Frédéric; Roisnel, Thierry; Ecorchard, Petra; Lang, Heinrich; Lapinte, Claude
1′,1′′′-Bis(ethynyl)biferrocenyl-Bridged Fe(dppe)Cp* Units: Synthesis, Solid-State Structures, and Electronic Couplings§
Organometallics, 2010, 29, 4804
4083386 CIFC11 H10 B F4 Mn O4P 1 21 110.0577; 10.8143; 13.1328
90; 100.152; 90
1406.1Eloi, Antoine; Rose-Munch, Françoise; Rose, Eric; Pille, Ariane; Lesot, Philippe; Herson, Patrick
Cationic Planar Chiral (η6-Arene)Mn(CO)3+Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+Complexes
Organometallics, 2010, 29, 3876
4067306 CIFC11 H10 Cr N2 O4P 21 21 219.2068; 11.1401; 11.8643
90; 90; 90
1216.9Tian, Xiaohui; Song, Li; Yuan, Yizhong; Lin, Jiaping
Two New Receptors for Carboxylate Anions with an IR-Active Reporting Group
Organometallics, 2010, 29, 509
4067374 CIFC11 H10 Fe O7P 21 21 218.022; 8.178; 18.127
90; 90; 90
1189.2Ali Khan, Monika; Mahon, Mary F.; Stewart, Alan J. W.; Lewis, Simon E.
Iron(0) Tricarbonyl Complexes of Microbially Derived Cyclohexadiene Ligands Containing Quaternary Stereocenters
Organometallics, 2010, 29, 199
4067463 CIFC11 H13 B7 Fe N2 O5P 1 21/n 17.1973; 14.6216; 16.3759
90; 99.126; 90
1701.52Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4066159 CIFC11 H13 Cl O3 S Sn2 WP -18.5946; 8.6557; 12.2209
95.284; 103.395; 106.793
834.26Bera, Holger; Braunschweig, Holger; Dörfler, Rainer; Kupfer, Thomas; Radacki, Krzysztof; Seeler, Fabian
Half-Sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-Bound Functional Stannyl Groups and Their Transformation intoAnsaComplexes†
Organometallics, 2010, 29, 5111
4066157 CIFC11 H13 Cl3 O3 Sn2 WC 1 2/c 127.875; 10.6733; 12.9899
90; 105.295; 90
3727.8Bera, Holger; Braunschweig, Holger; Dörfler, Rainer; Kupfer, Thomas; Radacki, Krzysztof; Seeler, Fabian
Half-Sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-Bound Functional Stannyl Groups and Their Transformation intoAnsaComplexes†
Organometallics, 2010, 29, 5111
4065693 CIFC11 H14 Cl N O3 PdP 1 21/c 19.6781; 9.8431; 13.617
90; 107.968; 90
1233.92Vicente, José; Arcas, Aurelia; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Organometallic Complexes of Palladium(II) Derived from 2,6-Diacetylpyridine Dimethylketal
Organometallics, 2010, 29, 3066
4067464 CIFC11 H15 B7 Fe N2 O3C 1 2/c 133.19; 7.603; 12.716
90; 90.621; 90
3208.6Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4066896 CIFC11 H15 CoP 1 n 15.6233; 12.5738; 6.7557
90; 100.803; 90
469.2Hapke, Marko; Weding, Nico; Spannenberg, Anke
Highly Reactive Cyclopentadienylcobalt(I) Olefin Complexes
Organometallics, 2010, 29, 4298
4066895 CIFC11 H15 Co OP 1 21/n 111.3734; 7.482; 11.7728
90; 106.919; 90
958.45Hapke, Marko; Weding, Nico; Spannenberg, Anke
Highly Reactive Cyclopentadienylcobalt(I) Olefin Complexes
Organometallics, 2010, 29, 4298
4066920 CIFC11 H15 Mo N7 O2P -110.6504; 10.7583; 14.8762
94.424; 90.975; 118.888
1485.09Liu, Fu-Chen; Lin, Yu-Liang; Yang, Pei-Shan; Lee, Gene-Hsian; Peng, Shie-Ming
[3+2] Cycloadditions of Molybdenum(II) Azide Complexes with Nitriles and an Alkyne
Organometallics, 2010, 29, 4282
4066230 CIFC11 H18 Co O3 PP 1 21/n 16.2947; 13.87; 16.203
90; 95.183; 90
1408.9Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4063450 CIFC11 H20 Au Cl3 N2P 1 21/c 19.091; 15.134; 11.724
90; 96.69; 90
1602Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4066513 CIFC11 H20 Cl2 N2 Pd SP -17.828; 9.1978; 10.931
83.665; 85.152; 71.768
741.92Fliedel, Christophe; Braunstein, Pierre
Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-(S,CNHC) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag4I4(S,CNHC)2Planar Cluster†
Organometallics, 2010, 29, 5614
4067757 CIFC11 H20 N2 OP 21 21 218.9984; 10.1229; 12.283
90; 90; 90
1118.86Snead, David R.; Inagaki, Sebastien; Abboud, Khalil A.; Hong, Sukwon
Bis(2-alkylpyrrolidin-1-yl)methylidenes as Chiral Acyclic Diaminocarbene Ligands
Organometallics, 2010, 29, 1729
4066229 CIFC11 H23 Co O2 P2P 1 21/n 19.7576; 11.1403; 14.0125
90; 100.413; 90
1498.11Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4066748 CIFC11 H8 B Co2 F4 O5P 21 21 217.4109; 12.9909; 15.0675
90; 90; 90
1450.61Aguirre-Etcheverry, Paulina; Ashley, Andrew E.; Balázs, Gábor; Green, Jennifer C.; Cowley, Andrew R.; Thompson, Amber L.; O’Hare, Dermot
Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
Organometallics, 2010, 29, 5847
4067375 CIFC11 H8 Fe N0 O7P 16.688; 6.701; 46.634
85.896; 85.972; 60.254
1808.47Ali Khan, Monika; Mahon, Mary F.; Stewart, Alan J. W.; Lewis, Simon E.
Iron(0) Tricarbonyl Complexes of Microbially Derived Cyclohexadiene Ligands Containing Quaternary Stereocenters
Organometallics, 2010, 29, 199
4066469 CIFC110 H118 Ag2 B2 F8 N2 O16 P4 Pt2C 1 2/c 123.472; 23.37; 21.29
90; 102.184; 90
11415.4Leung, Sammual Yu-Lut; Lam, Wai Han; Zhu, Nianyong; Yam, Vivian Wing-Wah
Synthesis, Structural Characterization, and Photophysical Study of Luminescent Face-to-Face Dinuclear Platinum(II) Alkynyl Phosphine Complexes and Their Tetranuclear Mixed-Metal Platinum(II)−Silver(I) and −Copper(I) Complexes†
Organometallics, 2010, 29, 5558
4066470 CIFC110 H118 Cu2 F12 N2 O16 P6 Pt2C 1 2/c 123.973; 22.983; 21.57
90; 102.229; 90
11615Leung, Sammual Yu-Lut; Lam, Wai Han; Zhu, Nianyong; Yam, Vivian Wing-Wah
Synthesis, Structural Characterization, and Photophysical Study of Luminescent Face-to-Face Dinuclear Platinum(II) Alkynyl Phosphine Complexes and Their Tetranuclear Mixed-Metal Platinum(II)−Silver(I) and −Copper(I) Complexes†
Organometallics, 2010, 29, 5558
4066117 CIFC111 H166 Cl2 Gd2 Li2 N4 O4 Si2P -115.144; 15.458; 15.565
119.65; 108.29; 93.98
2893.1Luo, Yunjie; Li, Wenyi; Lin, Dan; Yao, Yingming; Zhang, Yong; Shen, Qi
Lanthanide Alkyl Complexes Supported by a Piperazidine-Bridged Bis(phenolato) Ligand: Synthesis, Structural Characterization, and Catalysis for the Polymerization ofl-Lactide andrac-Lactide
Organometallics, 2010, 29, 3507
4067396 CIFC112 H116 Cl16 F12 Ir4 N4 O20 S8P -111.719; 14.77; 21.002
97.772; 94.503; 103.604
3478Jia, Ai-Quan; Han, Ying-Feng; Lin, Yue-Jian; Jin, Guo-Xin
Syntheses and Reactions of Half-Sandwich Iridium, Rhodium, and Ruthenium Metallacycles Containing 4-Pyridyl Dithioether Ligands
Organometallics, 2010, 29, 232-240
4083378 CIFC113 H90 Cl4 N10 O12 Sb4P -114.0727; 17.181; 21.7428
93.338; 105.911; 99.635
4954.2Jami, Ananda Kumar; Prabhu, M. Santhana Raj; Baskar, Viswanathan
Isolation of Tetranuclear Organoantimony Oxo Clusters and Hexa-decanuclear Polyoxostibonates
Organometallics, 2010, 29, 1137
4065567 CIFC114 H100 Fe4 N6 P4P -116.035; 18.1012; 18.2591
97.839; 104.244; 96.104
5034.5Lohan, Manja; Justaud, Frédéric; Roisnel, Thierry; Ecorchard, Petra; Lang, Heinrich; Lapinte, Claude
1′,1′′′-Bis(ethynyl)biferrocenyl-Bridged Fe(dppe)Cp* Units: Synthesis, Solid-State Structures, and Electronic Couplings§
Organometallics, 2010, 29, 4804
4066759 CIFC114 H140 B2 N2 O4 V2C 1 2/c 119.5977; 15.623; 32.2035
90; 91.522; 90
9856.4Jordan, Markus; Saak, Wolfgang; Haase, Detlev; Beckhaus, Rüdiger
Bridging Azines in the Coordination Sphere of Low-Valent Vanadocene Derivatives†
Organometallics, 2010, 29, 5859
4065731 CIFC116 H123 Cl4 N17 Ni4 O30P 1 21/c 123.8448; 20.2926; 24.8296
90; 96.57; 90
11935.5Lee, Way-Zen; Tseng, Huan-Sheng; Wang, Tzu-Li; Tsai, Hui-Lien; Kuo, Ting-Shen
Bioinspired Catalytic Conjugate Additions of Thiophenols to α,β-Enones by a Disubstituted Benzoate-Bridged Nickel Mimic for the Active Site of Urease
Organometallics, 2010, 29, 2874
4065579 CIFC116 H124 Ag12 F48 N44 O2 P8P -113.943; 14.111; 23.283
84.22; 89.721; 89.16
4557Liu, Bo; Liu, Bin; Zhou, Yongbo; Chen, Wanzhi
Copper(II) Hydroxide Complexes of N-Heterocyclic Carbenes and Catalytic Oxidative Amination of Arylboronic Acids
Organometallics, 2010, 29, 1457
4065932 CIFC116 H162 N14 O20 P8 Pt4P -110.404; 17.934; 19.064
81.16; 86.77; 85.21
3499.1Shanmugaraju, Sankarasekaran; Bar, Arun Kumar; Chi, Ki-Whan; Mukherjee, Partha Sarathi
Coordination-Driven Self-Assembly of Metallamacrocycles via a New PtII2Organometallic Building Block with 90° Geometry and Optical Sensing of Anions
Organometallics, 2010, 29, 2971
4067395 CIFC12 H12 N2 S2P 1 21/c 19.441; 14.999; 9.799
90; 118.147; 90
1223.5Jia, Ai-Quan; Han, Ying-Feng; Lin, Yue-Jian; Jin, Guo-Xin
Syntheses and Reactions of Half-Sandwich Iridium, Rhodium, and Ruthenium Metallacycles Containing 4-Pyridyl Dithioether Ligands
Organometallics, 2010, 29, 232-240
4067490 CIFC12 H13 Br Mo N2 O2P 21 21 217.7917; 11.5324; 14.8374
90; 90; 90
1333.24Li, Shenyu; Kee, Choon Wee; Huang, Kuo-Wei; Hor, T. S. Andy; Zhao, Jin
Cyclopentadienyl Molybdenum(II/VI) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Reactivity under Oxidative Conditions
Organometallics, 2010, 29, 1924
4067466 CIFC12 H14 B7 Fe N O4P 1 21/c 18.3973; 12.6216; 31.446
90; 100.023; 90
3282Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067721 CIFC12 H14 Br2 N2 Pd SP -18.6338; 9.641; 9.7985
107.453; 103.622; 101.368
723.96Huynh, Han Vinh; Yeo, Chun Hui; Chew, Ying Xia
Syntheses, Structures, and Catalytic Activities of Hemilabile Thioether-Functionalized NHC Complexes
Organometallics, 2010, 29, 1479
4066598 CIFC12 H14 N2 O2 PdP 21 21 214.5852; 14.8783; 16.8496
90; 90; 90
1149.48Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Abellán-López, Antonio; Bautista, Delia
Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†
Organometallics, 2010, 29, 5693
4066156 CIFC12 H16 Cl2 O3 Sn2 WP 1 21/c 113.9594; 17.3667; 16.3223
90; 113.237; 90
3636.01Bera, Holger; Braunschweig, Holger; Dörfler, Rainer; Kupfer, Thomas; Radacki, Krzysztof; Seeler, Fabian
Half-Sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-Bound Functional Stannyl Groups and Their Transformation intoAnsaComplexes†
Organometallics, 2010, 29, 5111
4066409 CIFC12 H17 B Mn N O3P 1 21/n 110.9481; 11.1176; 11.369
90; 95.951; 90
1376.34Eckensberger, U. David; Weber, Mitra; Wildt, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactivity of [(C5Me5)Fe(C5H4BBr2)] and [(OC)3Mn(C5H4BBr2)] toward Et3SiH: Facile Access to [(OC)3Mn(C5H4BH2)]2and to Boron-Bridged Dinuclear Organometallics†
Organometallics, 2010, 29, 5301
4065790 CIFC12 H18 F6 N3 Os PP b c m7.2245; 13.747; 16.602
90; 90; 90
1648.8Batuecas, María; Esteruelas, Miguel A.; García-Yebra, Cristina; Oñate, Enrique
Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate
Organometallics, 2010, 29, 2166
4065820 CIFC12 H20 Cl2 N RhP 1 21/n 18.258; 9.123; 18.596
90; 99.194; 90
1383Ito, Masato; Tejima, Noriko; Yamamura, Masahiro; Endo, Yoshinori; Ikariya, Takao
Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes
Organometallics, 2010, 29, 1886
4066919 CIFC12 H22 Mo N6 O2P 1 21/c 111.1095; 12.4776; 12.109
90; 101.432; 90
1645.25Liu, Fu-Chen; Lin, Yu-Liang; Yang, Pei-Shan; Lee, Gene-Hsian; Peng, Shie-Ming
[3+2] Cycloadditions of Molybdenum(II) Azide Complexes with Nitriles and an Alkyne
Organometallics, 2010, 29, 4282
4065674 CIFC12 H23 Ge I3 N2P 21 21 2110.246; 12.522; 14.85
90; 90; 90
1905.3Rupar, Paul A.; Staroverov, Viktor N.; Baines, Kim M.
Reactivity Studies of N-Heterocyclic Carbene Complexes of Germanium(II)†
Organometallics, 2010, 29, 4871
4065751 CIFC12 H26 Ga2 O6P 1 21 17.16603; 16.0451; 7.92429
90; 91.443; 90
910.84Horeglad, Paweł; Kruk, Przemysław; Pécaut, Jacques
Heteroselective Polymerization ofrac-Lactide in the Presence of Dialkylgallium Alkoxides: The Effect of Lewis Base on Polymerization Stereoselectivity
Organometallics, 2010, 29, 3729
4066234 CIFC12 H27 Co F3 O5 P3 SP 1 21/c 114.8592; 8.339; 18.0971
90; 107.585; 90
2137.6Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4067685 CIFC12 H32 Al2 N2 O2P 1 21/n 16.5609; 9.9473; 13.1716
90; 95.2425; 90
856.03Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4066747 CIFC12 H8 Co2 O6P -16.6398; 6.7052; 8.146
88.3649; 78.8043; 76.2844
345.56Aguirre-Etcheverry, Paulina; Ashley, Andrew E.; Balázs, Gábor; Green, Jennifer C.; Cowley, Andrew R.; Thompson, Amber L.; O’Hare, Dermot
Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
Organometallics, 2010, 29, 5847
4066607 CIFC122 H150 O Si3C 1 2/c 124.1635; 15.3773; 29.543
90; 107.695; 90
10457.9Corey, Joyce Y.; Trankler, Kevin A.; Braddock-Wilking, Janet; Rath, Nigam P.
Reactions of (Et2NCH2CH2NEt2)·H2SiCl2with Selected Diorganometallic Reagents of Magnesium and Lithium†
Organometallics, 2010, 29, 5708
4065776 CIFC123 H172 Al2 N2 O8 Ti2P -114.8862; 19.019; 21.2587
78.8979; 81.5674; 89.0994
5841.8Gurubasavaraj, Prabhuodeyara M.; Nomura, Kotohiro
Hetero-bimetallic Complexes of Titanatranes with Aluminum Alkyls: Synthesis, Structural Analysis, and Their Use in Catalysis for Ethylene Polymerization
Organometallics, 2010, 29, 3500
4067397 CIFC124 H148 Cl8 F12 Ir4 N4 O24 S8P 1 21/c 118.71; 26.661; 14.8575
90; 90.984; 90
7410.2Jia, Ai-Quan; Han, Ying-Feng; Lin, Yue-Jian; Jin, Guo-Xin
Syntheses and Reactions of Half-Sandwich Iridium, Rhodium, and Ruthenium Metallacycles Containing 4-Pyridyl Dithioether Ligands
Organometallics, 2010, 29, 232-240
4066343 CIFC124 H164 Al4 N8P 1 21/n 113.6963; 17.2583; 23.8216
90; 95.751; 90
5602.5Maheswari, K.; Rajendran, N. M.; Meyer, Jens; Reddy, N. Dastagiri
Reactions of an Aluminum Amide with Aromatic Nitriles: Formation of Al−N−C Frameworks
Organometallics, 2010, 29, 3799
4067087 CIFC125 H94 Cl2 F12 N24 O4 Pd4P -112.526; 12.809; 19.525
99.602; 95.938; 111.943
2817.6Sie, Ming-Han; Hsieh, Yuan-Hsin; Tsai, Yi-Hua; Wu, Jia-Rong; Chen, Shih-Jung; Kumar, P. Vijaya; Lii, Jenn-Huei; Lee, Hon Man
A Heteroleptic Palladium(II) Complex Containing a Bidentate Carbene/Amido Ligand and 3-(Trifluoromethyl)-5-(2-pyridyl)pyrazolate: Fast Catalyst Activation in the Heck Coupling Reaction
Organometallics, 2010, 29, 6473
4083383 CIFC126 H120 Br16 N12 O42 Sb16P 1 21/n 118.548; 19.193; 24.981
90; 108.415; 90
8437.6Jami, Ananda Kumar; Prabhu, M. Santhana Raj; Baskar, Viswanathan
Isolation of Tetranuclear Organoantimony Oxo Clusters and Hexa-decanuclear Polyoxostibonates
Organometallics, 2010, 29, 1137
4083382 CIFC126 H120 Cl16 N12 O36 Sb16P 1 21/n 118.4669; 19.0133; 25.074
90; 108.453; 90
8351.2Jami, Ananda Kumar; Prabhu, M. Santhana Raj; Baskar, Viswanathan
Isolation of Tetranuclear Organoantimony Oxo Clusters and Hexa-decanuclear Polyoxostibonates
Organometallics, 2010, 29, 1137
4066317 CIFC126.5 H198 B Lu N6 OP 1 21/c 114.2069; 37.457; 23.45
90; 100.034; 90
12288Saliu, Kuburat O.; Cheng, Jianhua; McDonald, Robert; Ferguson, Michael J.; Takats, Josef
Reactions of Scorpionate-Anchored Yttrium and Lutetium Dialkyls with Terminal Alkynes: From Bimetallic Complexes with Bridging Enynediyl Ligands to Monomeric Terminal Dialkynyl Complexes†
Organometallics, 2010, 29, 4950
4065757 CIFC128 H112 Cl12 N2 O4 Os2 P6P -113.2136; 13.7646; 18.1729
103.599; 99.835; 95.375
3134.35Huang, Jinbo; Lin, Ran; Wu, Liqiong; Zhao, Qianyi; Zhu, Congqing; Wen, Ting Bin; Xia, Haiping
Synthesis, Characterization, and Electrochemical Properties of Bisosmabenzenes Bridged by Diisocyanides
Organometallics, 2010, 29, 2916
4066891 CIFC128 H220 Cs2 N4 O26 P6P -114.607; 21.454; 23.662
92.847; 91.262; 103.893
7185Ionkin, Alex S.; Marshall, William J.; Fish, Brian M.; Howe, Laurie A.
Fragmentation of an N-Substituted One-Coordinate Phosphorus (Phosphaalkyne): Plausible Generation of Monovalent Phosphorus Species†
Organometallics, 2010, 29, 4154
4067044 CIFC13 H11 Fe2 O7 P S2P 1 21/c 110.88; 13.543; 24.808
90; 90.89; 90
3655Song, Li-Cheng; Zhao, Pei-Hua; Du, Zong-Qiang; Tang, Ming-Yi; Hu, Qing-Mei
Unexpected Synthesis of Tetrahedral Fe/S Clusters via Highly Reactive Butterfly Intermediates (μ-HS)2Fe2(CO)5[RP(CH2OH)2]
Organometallics, 2010, 29, 5751
4065593 CIFC13 H11 O4 RhP 1 21/n 110.408; 7.836; 15.9878
90; 103.213; 90
1269.4Hopmann, Kathrin H.; Stuurman, Nomampondomise F.; Muller, Alfred; Conradie, Jeanet
Substitution and Isomerization of Asymmetric β-Diketonato Rhodium(I) Complexes: A Crystallographic and Computational Study
Organometallics, 2010, 29, 2446
4067416 CIFC13 H12P 1 21/c 15.8395; 24.4958; 14.0249
90; 91.506; 90
2005.47Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2Systems
Organometallics, 2010, 29, 860
4067275 CIFC13 H15 Cl3 O3 Re RhP 1 21/n 19.5709; 14.7376; 12.0776
90; 90.189; 90
1703.56Huang, Shih-Huang; Watson, William H.; Carrano, Carl J.; Wang, Xiaoping; Richmond, Michael G.
Directed Synthesis of the Triangular Mixed-Metal Cluster H2RhRe2Cp*(CO)9: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of CO, Halogenated Solvents, and Thiols
Organometallics, 2010, 29, 61
4067621 CIFC13 H15 F6 N O5P c m n6.6689; 14.6578; 17.1651
90; 90; 90
1677.91Zhu, Di; Janssen, Femke F. B. J.; Budzelaar, Peter H. M.
(Py)2Co(CH2SiMe3)2As an Easily Accessible Source of “CoR2”
Organometallics, 2010, 29, 1897
4066609 CIFC13 H16 Au Cl N2P 1 21/n 111.0773; 8.7542; 15.175
90; 110.291; 90
1380.2Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066614 CIFC13 H16 Au Cl3 N2P b c a8.382; 13.732; 28.061
90; 90; 90
3229.9Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4067078 CIFC13 H17 I N2 PtC 1 2/m 116.2374; 13.2518; 7.8193
90; 117.454; 90
1493Nabavizadeh, S. Masoud; Habibzadeh, Sepideh; Rashidi, Mehdi; Puddephatt, Richard J.
Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications
Organometallics, 2010, 29, 6359
4066765 CIFC13 H19 Bi N2 S3P 1 21/c 111.8121; 8.831; 18.9362
90; 121.873; 90
1677.45Dostál, Libor; Jambor, Roman; Růžička, Aleš; Jirásko, Robert; Černošková, Eva; Beneš, Ludvík; Proft, Frank de
[2 + 2] Cycloaddition of Carbon Disulfide to NCN-Chelated†Organoantimony(III) and Organobismuth(III) Sulfides: Evidence for Terminal Sb−S and Bi−S Bonds in Solution‡
Organometallics, 2010, 29, 4486
4066922 CIFC13 H19 Mo N5 O6P 1 21/c 17.9487; 11.2699; 19.7532
90; 91.518; 90
1768.89Liu, Fu-Chen; Lin, Yu-Liang; Yang, Pei-Shan; Lee, Gene-Hsian; Peng, Shie-Ming
[3+2] Cycloadditions of Molybdenum(II) Azide Complexes with Nitriles and an Alkyne
Organometallics, 2010, 29, 4282
4066764 CIFC13 H19 N2 S3 SbP 1 21/c 111.5541; 8.735; 18.9419
90; 121.371; 90
1632.25Dostál, Libor; Jambor, Roman; Růžička, Aleš; Jirásko, Robert; Černošková, Eva; Beneš, Ludvík; Proft, Frank de
[2 + 2] Cycloaddition of Carbon Disulfide to NCN-Chelated†Organoantimony(III) and Organobismuth(III) Sulfides: Evidence for Terminal Sb−S and Bi−S Bonds in Solution‡
Organometallics, 2010, 29, 4486
4066140 CIFC13 H20 Br N3P 1 21/n 18.7213; 25.988; 13.2891
90; 91.499; 90
3010.9Alonso-Moreno, Carlos; Carrillo-Hermosilla, Fernando; Garcés, Andrés; Otero, Antonio; López-Solera, Isabel; Rodríguez, Ana M.; Antiñolo, Antonio
Simple, Versatile, and Efficient Catalysts for Guanylation of Amines
Organometallics, 2010, 29, 2789
4065819 CIFC13 H22 Cl2 N RhP b c a16.2809; 14.3063; 25.6018
90; 90; 90
5963.2Ito, Masato; Tejima, Noriko; Yamamura, Masahiro; Endo, Yoshinori; Ikariya, Takao
Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes
Organometallics, 2010, 29, 1886
4065694 CIFC13 H22 Cl3 N O4 PdP -19.6256; 9.9998; 11.0056
101.138; 99.345; 115.648
900Vicente, José; Arcas, Aurelia; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Organometallic Complexes of Palladium(II) Derived from 2,6-Diacetylpyridine Dimethylketal
Organometallics, 2010, 29, 3066
4067678 CIFC13 H23 N3 O4 S2P 1 21/n 19.3901; 15.3139; 11.9953
90; 108.443; 90
1636.32Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4066227 CIFC13 H32 Co O P3P n a 2118.8012; 7.9575; 12.068
90; 90; 90
1805.5Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4066462 CIFC13 H39 B8 P2 RhP 1 21/n 116.009; 9.9401; 16.347
90; 118.278; 90
2290.9Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Two Metal−Monocarbollide Relatives of the {B20H18} Double-Cluster Boranes†
Organometallics, 2010, 29, 4790
4067274 CIFC133 H202 Mn2 NP 1 21/n 120.9514; 14.3494; 41.6416
90; 98.222; 90
12390.5Ni, Chengbao; Fettinger, James C.; Power, Philip P.
Intramolecular C−H Activation by Putative Terminal Two-Coordinate Manganese(III) Imido Intermediates: Hydrogen Abstraction from a Phenyl Group
Organometallics, 2010, 29, 269
4067261 CIFC14 H10 Br2 N2 O7 OsP 1 21/c 16.6047; 19.573; 13.3682
90; 93.611; 90
1724.7Jänis, Janne; Jakonen, Minna; Oresmaa, Larisa; Hirva, Pipsa; Laurila, Elina; Vlasova, Liubov; Vainiotalo, Pirjo; Haukka, Matti
Fragmentation Pathways of [MX2(CO)2(dcbpy)] (M = Ru, Os; X = Cl, Br, I; dcbpy = 2,2′-bipyridine-4,4′-dicarboxylic acid) Complexes
Organometallics, 2010, 29, 1070
4066107 CIFC14 H10 Hg O2P -14.1612; 16.324; 18.291
89.074; 83.55; 88.05
1233.8Patel, Upali; Sharma, Sagar; Singh, Harkesh B.; Dey, Sandip; Jain, Vimal K.; Wolmershäuser, Gotthelf; Butcher, Ray J.
Intermetallic Bonds in Metallophilic Mercuraazametallamacrocycles of Synthetic Design
Organometallics, 2010, 29, 4265
4067262 CIFC14 H10 I2 N2 O7 OsP 1 21/c 16.8746; 19.6521; 13.6786
90; 96.161; 90
1837.31Jänis, Janne; Jakonen, Minna; Oresmaa, Larisa; Hirva, Pipsa; Laurila, Elina; Vlasova, Liubov; Vainiotalo, Pirjo; Haukka, Matti
Fragmentation Pathways of [MX2(CO)2(dcbpy)] (M = Ru, Os; X = Cl, Br, I; dcbpy = 2,2′-bipyridine-4,4′-dicarboxylic acid) Complexes
Organometallics, 2010, 29, 1070
4066846 CIFC14 H10 N2 O9 Os3P 1 21/c 18.8493; 17.5956; 14.0691
90; 102.775; 90
2136.45Cabeza, Javier A.; del Río, Ignacio; Fernández-Colinas, José M.; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela; Vázquez-García, Digna
Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study§
Organometallics, 2010, 29, 3828
4066326 CIFC14 H12 Au NP 1 21/c 16.393; 7.2809; 25.1246
90; 97.161; 90
1160.3Kilpin, Kelly J.; Horvath, Raphael; Jameson, Geoffrey B.; Telfer, Shane G.; Gordon, Keith C.; Crowley, James D.
Pyridyl Gold(I) Alkynyls: A Synthetic, Structural, Spectroscopic, and Computational Study
Organometallics, 2010, 29, 6186
4067429 CIFC14 H12 Fe2 O10 S2P -17.9643; 11.486; 11.532
95.098; 94.811; 106.411
1001.4Song, Li-Cheng; Liu, Xu-Feng; Ming, Jiang-Bo; Ge, Jian-Hua; Xie, Zhao-Jun; Hu, Qing-Mei
Reactions Starting from Diiron Propanedithiolate [(μ-SCH2)2CH(OH)]Fe2(CO)6Leading to Malonyl-, PPh3-, and [60]Fullerene-Containing Compounds Relevant to the Active Site of FeFe-Hydrogenases
Organometallics, 2010, 29, 610
4067710 CIFC14 H13 Cl F N PtP b c n15.3935; 7.3366; 22.4051
90; 90; 90
2530.34Crosby, Sarah H.; Clarkson, Guy J.; Deeth, Robert J.; Rourke, Jonathan P.
Platinum(IV) DMSO Complexes: Synthesis, Isomerization, and Agostic Intermediates
Organometallics, 2010, 29, 1966
4065647 CIFC14 H14 Au Cl N2 O4P 1 21/n 17.1495; 18.0815; 12.6678
90; 96.71; 90
1626.4Cocco, Fabio; Cinellu, Maria A.; Minghetti, Giovanni; Zucca, Antonio; Stoccoro, Sergio; Maiore, Laura; Manassero, Mario
Intramolecular C(sp2)−H Bond Activation in 6,6′-Dimethoxy-2,2′-Bipyridine with Gold(III). Crystal and Molecular Structure of the First N′,C(3) “Rollover” Cycloaurated Derivative
Organometallics, 2010, 29, 1064
4067413 CIFC14 H14 Cl2 ZrC 1 2/c 114.576; 6.6746; 14.2549
90; 102.03; 90
1356.39Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2Systems
Organometallics, 2010, 29, 860
4067414 CIFC14 H14 Cl2 ZrP 1 21/n 19.0085; 12.1008; 12.0467
90; 91.086; 90
1312.98Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2Systems
Organometallics, 2010, 29, 860
4067707 CIFC14 H14 Cl6 F N O Pt SP -18.4226; 10.1642; 13.2591
72.298; 78.893; 67.789
997.22Crosby, Sarah H.; Clarkson, Guy J.; Deeth, Robert J.; Rourke, Jonathan P.
Platinum(IV) DMSO Complexes: Synthesis, Isomerization, and Agostic Intermediates
Organometallics, 2010, 29, 1966
4066106 CIFC14 H14 Hg O2P 1 21/n 14.9461; 18.807; 12.9982
90; 94.976; 90
1204.6Patel, Upali; Sharma, Sagar; Singh, Harkesh B.; Dey, Sandip; Jain, Vimal K.; Wolmershäuser, Gotthelf; Butcher, Ray J.
Intermetallic Bonds in Metallophilic Mercuraazametallamacrocycles of Synthetic Design
Organometallics, 2010, 29, 4265
4065772 CIFC14 H15 Cr F3 O3P n a 2116.457; 9.668; 8.982
90; 90; 90
1429.1Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948
4065773 CIFC14 H15 F3 O3 WP n a 2116.913; 9.751; 9.135
90; 90; 90
1506.5Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948
4067276 CIFC14 H15 O4 Rh3 S2P 1 21/n 18.442; 23.212; 10.2361
90; 103.347; 90
1951.6Huang, Shih-Huang; Watson, William H.; Carrano, Carl J.; Wang, Xiaoping; Richmond, Michael G.
Directed Synthesis of the Triangular Mixed-Metal Cluster H2RhRe2Cp*(CO)9: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of CO, Halogenated Solvents, and Thiols
Organometallics, 2010, 29, 61
4067670 CIFC14 H16 N4 S2 SiP -17.1934; 8.7353; 13.617
105.738; 95.836; 96.114
811.23Hill, Anthony F.; Neumann, Horst; Wagler, Jörg
Bis(methimazolyl)silyl Complexes of Ruthenium
Organometallics, 2010, 29, 1026
4067489 CIFC14 H17 Br Mo N2 O2P 1 21/c 112.2315; 15.0658; 8.4076
90; 100.563; 90
1523.08Li, Shenyu; Kee, Choon Wee; Huang, Kuo-Wei; Hor, T. S. Andy; Zhao, Jin
Cyclopentadienyl Molybdenum(II/VI) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Reactivity under Oxidative Conditions
Organometallics, 2010, 29, 1924
4066705 CIFC14 H17 Cl N2 O PdP b c a16.112; 9.467; 19.243
90; 90; 90
2935.2D’Amora, Angela; Fanfoni, Lidia; Cozzula, Daniela; Guidolin, Nicol; Zangrando, Ennio; Felluga, Fulvia; Gladiali, Serafino; Benedetti, Fabio; Milani, Barbara
Addressing the Poly- to Oligo-ketone Selectivity in Styrene Carbonylation Catalyzed by Palladium/bpy Complexes. Effect of the 6-Alkyl Substitution
Organometallics, 2010, 29, 4472
4066918 CIFC14 H18 Mo N6 O2P -17.6295; 9.8074; 11.8453
110.416; 102.06; 91.906
806.86Liu, Fu-Chen; Lin, Yu-Liang; Yang, Pei-Shan; Lee, Gene-Hsian; Peng, Shie-Ming
[3+2] Cycloadditions of Molybdenum(II) Azide Complexes with Nitriles and an Alkyne
Organometallics, 2010, 29, 4282
4065877 CIFC14 H19 Cl F3 Ir N2 O2 SP -19.413; 14.029; 14.353
76.665; 87.742; 85.661
1838.5Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4065874 CIFC14 H19 Cl F3 N2 O2 Rh SP -19.455; 14.086; 14.423
76.758; 87.957; 85.835
1864.5Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4065618 CIFC14 H19 F4 IrC 1 c 123.741; 8.6351; 13.9713
90; 92.813; 90
2860.7Yuan, Jian; Hughes, Russell P.; Golen, James A.; Rheingold, Arnold L.
Synthesis and Structural and Computational Studies of a Conformationally Locked (η1-Perfluoroalkylidene)(η2-alkene) Transition Metal Complex: Ir(Cp*)(CFCF3)(C2H4)
Organometallics, 2010, 29, 1942
4067076 CIFC14 H19 I N2 PtP -19.9002; 11.7696; 13.4227
88.49; 88.747; 85.119
1557.52Nabavizadeh, S. Masoud; Habibzadeh, Sepideh; Rashidi, Mehdi; Puddephatt, Richard J.
Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications
Organometallics, 2010, 29, 6359
4066610 CIFC14 H20 Au Cl N2P 1 21/c 116.519; 6.8234; 13.1359
90; 104.583; 90
1432.9Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066615 CIFC14 H20 Au Cl3 N2P 21 21 218.6649; 12.3061; 15.6164
90; 90; 90
1665.19Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4067541 CIFC14 H21 Br N2 ZnP 1 21/c 114.752; 8.8467; 24.777
90; 102.18; 90
3160.8Dochnahl, Maximilian; Löhnwitz, Karolin; Lühl, Anja; Pissarek, Jens-Wolfgang; Biyikal, Mustafa; Roesky, Peter W.; Blechert, Siegfried
Functionalized Aminotroponiminate Zinc Complexes as Catalysts for the Intramolecular Hydroamination of Alkenes
Organometallics, 2010, 29, 2637
4067542 CIFC14 H21 I N2 ZnP 1 21/c 115.1756; 8.5077; 25.432
90; 100.226; 90
3231.4Dochnahl, Maximilian; Löhnwitz, Karolin; Lühl, Anja; Pissarek, Jens-Wolfgang; Biyikal, Mustafa; Roesky, Peter W.; Blechert, Siegfried
Functionalized Aminotroponiminate Zinc Complexes as Catalysts for the Intramolecular Hydroamination of Alkenes
Organometallics, 2010, 29, 2637
4065821 CIFC14 H22 Cl2 N RhP 1 21 18.303; 15.3941; 11.5884
90; 103.892; 90
1437.9Ito, Masato; Tejima, Noriko; Yamamura, Masahiro; Endo, Yoshinori; Ikariya, Takao
Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes
Organometallics, 2010, 29, 1886
4066441 CIFC14 H22 F6 N2 O9 S2 Si2P 1 21/c 115.212; 12.222; 15.921
90; 117.75; 90
2619.6Kertsnus-Banchik, Evgenia; Gostevskii, Boris; Botoshansky, Mark; Kalikhman, Inna; Kost, Daniel
Dinuclear Silicon Complexes of Uracil, Barbituric Acid, and 5,5-Dimethylbarbituric Acid: Hydrolytic Formation of Cyclic Oligomers(1)†
Organometallics, 2010, 29, 5435
4066155 CIFC14 H22 O3 Sn2 WP 1 21/c 111.6374; 7.5447; 21.632
90; 95.02; 90
1892Bera, Holger; Braunschweig, Holger; Dörfler, Rainer; Kupfer, Thomas; Radacki, Krzysztof; Seeler, Fabian
Half-Sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-Bound Functional Stannyl Groups and Their Transformation intoAnsaComplexes†
Organometallics, 2010, 29, 5111
4067303 CIFC14 H24 Mo N4 O6 TiP 1 21/n 113.714; 11.1816; 14.228
90; 99.902; 90
2149.28Lorber, Christian; Vendier, Laure
Imido−Titanium/Molybdenum Heterobimetallic Systems. Switching from η6-Arene to Fischer-Type Aminocarbene Complexes by Tuning Reactivity Conditions
Organometallics, 2010, 29, 1127
4065743 CIFC14 H25 Cl O2 P RhP 1 21/c 130.0493; 8.1298; 14.4869
90; 101.648; 90
3466.19Chaplin, Adrian B.; Weller, Andrew S.
C−C Bond Activation of a Cyclopropyl Phosphine: Isolation and Reactivity of a Tetrameric Rhodacyclobutane
Organometallics, 2010, 29, 2332
4063482 CIFC14 H27 Au B N4 P S2P n a 217.712; 24.039; 11.097
90; 90; 90
2057.3Hill, Anthony F.; Smith, Matthew K.; Tshabang, Never; Willis, Anthony C.
Bimetallic Dihydrobis(methimazolyl)borate Coordination: Structure [Mo2{μ2-H2B(mt)2}(CO)7][Au2(μ2-H2B(mt)2}](PEt3)2] (mt = methimazolyl)
Organometallics, 2010, 29, 473-477
4065793 CIFC14 H28 Ag N4 Na3 O16 S4P -15.6376; 9.6811; 13.497
104.309; 96.955; 96.131
701.34Almássy, Ambroz; Nagy, Csilla E.; Bényei, Attila C.; Joó, Ferenc
Novel Sulfonated N-Heterocyclic Carbene Gold(I) Complexes: Homogeneous Gold Catalysis for the Hydration of Terminal Alkynes in Aqueous Media
Organometallics, 2010, 29, 2484
4065794 CIFC14 H28 Au N4 Na3 O16 S4P -15.5943; 9.6469; 13.5881
105.027; 97.045; 95.592
696.47Almássy, Ambroz; Nagy, Csilla E.; Bényei, Attila C.; Joó, Ferenc
Novel Sulfonated N-Heterocyclic Carbene Gold(I) Complexes: Homogeneous Gold Catalysis for the Hydration of Terminal Alkynes in Aqueous Media
Organometallics, 2010, 29, 2484
4066252 CIFC14 H29 Cl2 Cr O3P 1 21/c 18.9517; 13.2013; 14.913
90; 91.22; 90
1761.93Peitz, Stephan; Peulecke, Normen; Aluri, Bhaskar R.; Müller, Bernd H.; Spannenberg, Anke; Rosenthal, Uwe; Al-Hazmi, Mohammed H.; Mosa, Fuad M.; Wöhl, Anina; Müller, Wolfgang
Metalation and Transmetalation Studies on Ph2PN(iPr)P(Ph)N(iPr)H for Selective Ethene Trimerization to 1-Hexene⊥
Organometallics, 2010, 29, 5263
4066416 CIFC14 H30 B P Si2P 1 21/c 113.792; 10.686; 13.1277
90; 92.447; 90
1933Izod, Keith; Wills, Corinne; Clegg, William; Harrington, Ross W.
Synthesis, Structure, and Solution Behavior of a Phosphine−Borane-Stabilized 1,3-Dicarbanion†
Organometallics, 2010, 29, 4774
4066833 CIFC14 H32 B10 Ni P2P 1 21 18.9372; 15.8861; 17.5452
90; 104.205; 90
2414.9Qiu, Zaozao; Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 10 Metal−Carboryne Complexes
Organometallics, 2010, 29, 4541
4067187 CIFC14 H32 Cl4 Ni P2 SiP 21 21 218.8414; 13.6132; 18.7005
90; 90; 90
2250.79Smith, Erin E.; Du, Guodong; Fanwick, Phillip E.; Abu-Omar, Mahdi M.
Dehydrocoupling of Organosilanes with a Dinuclear Nickel Hydride Catalyst and Isolation of a Nickel Silyl Complex
Organometallics, 2010, 29, 6527
4066232 CIFC14 H33 Co F3 O4 P3 SP -18.4154; 10.1041; 13.1407
90.567; 98.475; 92.082
1104.29Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4067294 CIFC14 H34 N2 ZnC 1 2/c 116.865; 9.1648; 13.088
90; 124.06; 90
1675.9Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4063494 CIFC14 H36 Ge N8P 1 21/n 18.6692; 15.743; 14.9497
90; 100.319; 90
2007.32Chen, Tianniu; Hunks, William; Chen, Philip S.; Xu, Chongying; DiPasquale, Antonio G.; Rheingold, Arnold L.
Synthesis, Structural Characterization, and Thermal Properties of the First Germanium N,N,N',N'-Tetraalkylguanidinates
Organometallics, 2010, 29, 501-504
4067623 CIFC14 H38 Co N2 Si2C 1 2/c 125.565; 10.1487; 17.3758
90; 100.104; 90
4438.3Zhu, Di; Janssen, Femke F. B. J.; Budzelaar, Peter H. M.
(Py)2Co(CH2SiMe3)2As an Easily Accessible Source of “CoR2”
Organometallics, 2010, 29, 1897
4067453 CIFC14 H39 B8 Fe O P2P 1 21/c 113.9797; 10.4948; 16.2278
90; 103.008; 90
2319.75Adams, Christopher J.; Franken, Andreas; Hodson, Bruce E.; McGrath, Thomas D.; Stone, F. Gordon A.
Paramagnetic 10-Vertex Ferramonocarboranes
Organometallics, 2010, 29, 2377
4066465 CIFC14 H48 B16 P2 Pt2P 1 21/c 113.5666; 14.9867; 15.0419
90; 93.577; 90
3052.3Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Two Metal−Monocarbollide Relatives of the {B20H18} Double-Cluster Boranes†
Organometallics, 2010, 29, 4790
4066464 CIFC14 H48 B16 P2 Rh2P -110.777; 12.169; 13.447
66.678; 67.893; 74.935
1487.6Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Two Metal−Monocarbollide Relatives of the {B20H18} Double-Cluster Boranes†
Organometallics, 2010, 29, 4790
4067025 CIFC14 H5 B F10 OC 1 2/c 117.7676; 15.2406; 10.8971
90; 97.496; 90
2925.6Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4066955 CIFC14 H6 Fe Mn O8 PP 1 21/c 110.242; 14.193; 11.935
90; 97.927; 90
1718.3Colson, Adam C.; Whitmire, Kenton H.
Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH2and μ-PPhH Complexes FeMn(CO)8(μ-PH2) and FeMn(CO)8(μ-PPhH)‡
Organometallics, 2010, 29, 4611
4065825 CIFC14 H7 B F10 SP 1 21/n 110.257; 13.0169; 12.2595
90; 109.639; 90
1541.6Fuller, Anna-Marie; Hughes, David L.; Lancaster, Simon J.; White, Callum M.
Synthesis and Structure of the Dimethyl Sulfide Adducts of Mono- and Bis(pentafluorophenyl)borane
Organometallics, 2010, 29, 2194
4067260 CIFC14 H8 Cl2 N2 O6 OsP 1 21/c 113.9787; 6.58; 18.9576
90; 109.153; 90
1647.2Jänis, Janne; Jakonen, Minna; Oresmaa, Larisa; Hirva, Pipsa; Laurila, Elina; Vlasova, Liubov; Vainiotalo, Pirjo; Haukka, Matti
Fragmentation Pathways of [MX2(CO)2(dcbpy)] (M = Ru, Os; X = Cl, Br, I; dcbpy = 2,2′-bipyridine-4,4′-dicarboxylic acid) Complexes
Organometallics, 2010, 29, 1070
4066505 CIFC145 H155.5 B2 F49.5 Ir2 P4P -113.051; 19.5769; 28.2597
90.4772; 96.9176; 99.64
7063.53Alcaraz, Gilles; Chaplin, Adrian B.; Stevens, Charlotte J.; Clot, Eric; Vendier, Laure; Weller, Andrew S.; Sabo-Etienne, Sylviane
Ruthenium, Rhodium, and Iridium Bis(σ-B−H) Diisopropylaminoborane Complexes†
Organometallics, 2010, 29, 5591
4066743 CIFC147 H110 Cl10 Ir4 N16P 1 21/n 113.478; 24.877; 38.426
90; 93.949; 90
12853Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4067285 CIFC15 H11 Fe N O5P n a 217.9145; 15.2319; 12.0601
90; 90; 90
1453.88Ortega-Jiménez, Fernando; Benavides, Adriana; Delgado, Francisco; Jiménez-Vázquez, Hugo A.; Tamariz, Joaquín
Synthesis and Reactivity of η4-Diene-Fe(CO)3Complexes fromexo-2-Oxazolidinone Dienes. A Facile Generation of Stable Conjugated Enol-Enamido Species
Organometallics, 2010, 29, 149
4067286 CIFC15 H11 Fe N O5P 1 21/n 18.957; 13.1959; 13.1775
90; 108.289; 90
1478.85Ortega-Jiménez, Fernando; Benavides, Adriana; Delgado, Francisco; Jiménez-Vázquez, Hugo A.; Tamariz, Joaquín
Synthesis and Reactivity of η4-Diene-Fe(CO)3Complexes fromexo-2-Oxazolidinone Dienes. A Facile Generation of Stable Conjugated Enol-Enamido Species
Organometallics, 2010, 29, 149
4066809 CIFC15 H11 K O11 RuP 1 21/c 18.812; 16.115; 24.011
90; 97.69; 90
3379Micallef, Leanne S.; Loughrey, Bradley T.; Healy, Peter C.; Parsons, Peter G.; Williams, Michael L.
Synthesis, Spectroscopic Characterization, and Cytotoxic Evaluation of Pentasubstituted Ruthenocenyl Esters
Organometallics, 2010, 29, 6237
4067433 CIFC15 H12 Cr O9P -19.486; 9.511; 10.054
100.853; 113.551; 94.245
805.4Baeza, Beatriz; Casarrubios, Luis; Gómez-Gallego, Mar; Sierra, Miguel A.; Oliván, Montserrat
Multicomponent Synthesis of Pyran-2-ylidene Chromium(0) and Tungsten(0) Fischer Carbene Complexes
Organometallics, 2010, 29, 1607
4066517 CIFC15 H14 Br Fe NC 1 2/c 130.0908; 7.6044; 12.5316
90; 112.616; 90
2647.01Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4066810 CIFC15 H14 O12 RuP -18.527; 8.7479; 12.457
95.51; 102.35; 101.183
881.3Micallef, Leanne S.; Loughrey, Bradley T.; Healy, Peter C.; Parsons, Peter G.; Williams, Michael L.
Synthesis, Spectroscopic Characterization, and Cytotoxic Evaluation of Pentasubstituted Ruthenocenyl Esters
Organometallics, 2010, 29, 6237
4066518 CIFC15 H15 Br Fe O2P 1 21/n 111.2962; 8.8876; 14.5359
90; 107.437; 90
1392.29Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4065768 CIFC15 H15 Cr F3 O4P 1 21/c 114.438; 8.2587; 14.853
90; 115.79; 90
1594.7Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948
4065769 CIFC15 H15 F3 O4 WP m c 2111.4088; 8.4128; 16.984
90; 90; 90
1630.1Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948
4065766 CIFC15 H15 F5 Mo O3P 1 21/c 114.6162; 8.4293; 15.0114
90; 118.161; 90
1630.54Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948
4066514 CIFC15 H15 Fe NP 1 21 17.095; 10.146; 8.336
90; 102.58; 90
585.67Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4066096 CIFC15 H15 N SeP b c a10.785; 9.856; 25.027
90; 90; 90
2660Murai, Toshiaki; Hori, Rumi; Maruyama, Toshifumi; Shibahara, Fumitoshi
(Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization
Organometallics, 2010, 29, 2400
4066515 CIFC15 H16 Fe O2P 1 21/n 17.423; 10.329; 16.609
90; 99.63; 90
1255.5Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4065812 CIFC15 H16 N2 O8 Ru3P 21 21 219.4617; 13.8364; 15.833
90; 90; 90
2072.79Cabeza, Javier A.; del Río, Ignacio; Fernández-Colinas, José M.; Pérez-Carreño, Enrique; Vázquez-García, Digna
From Allenes to Edge-Bridging Allyl Ligands or Face-Capping Alkenyl Ligands on a Triruthenium Hydrido Carbonyl Cluster: An Experimental and DFT Computational Study†
Organometallics, 2010, 29, 4818
4066220 CIFC15 H18 Cl2 N P PdP 1 21 110.1398; 8.5738; 19.062
90; 98.478; 90
1639.1Chen, Shuli; Ng, Joseph Kok-Peng; Pullarkat, Sumod A.; Liu, Fengli; Li, Yongxin; Leung, Pak-Hing
Asymmetric Synthesis of New Diphosphines and Pyridylphosphines via a Kinetic Resolution Process Promoted and Controlled by a Chiral Palladacycle
Organometallics, 2010, 29, 3374
4066406 CIFC15 H19 B Br2 FeP -17.2326; 8.662; 13.1522
92.874; 91.017; 106.655
787.96Eckensberger, U. David; Weber, Mitra; Wildt, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactivity of [(C5Me5)Fe(C5H4BBr2)] and [(OC)3Mn(C5H4BBr2)] toward Et3SiH: Facile Access to [(OC)3Mn(C5H4BH2)]2and to Boron-Bridged Dinuclear Organometallics†
Organometallics, 2010, 29, 5301
4066706 CIFC15 H19 Cl N2 PdP 1 21/n 110.518; 8.562; 16.933
90; 104.8; 90
1474.3D’Amora, Angela; Fanfoni, Lidia; Cozzula, Daniela; Guidolin, Nicol; Zangrando, Ennio; Felluga, Fulvia; Gladiali, Serafino; Benedetti, Fabio; Milani, Barbara
Addressing the Poly- to Oligo-ketone Selectivity in Styrene Carbonylation Catalyzed by Palladium/bpy Complexes. Effect of the 6-Alkyl Substitution
Organometallics, 2010, 29, 4472
4067301 CIFC15 H19 Mo N O3P 21 21 217.8652; 13.455; 14.318
90; 90; 90
1515.2Lorber, Christian; Vendier, Laure
Imido−Titanium/Molybdenum Heterobimetallic Systems. Switching from η6-Arene to Fischer-Type Aminocarbene Complexes by Tuning Reactivity Conditions
Organometallics, 2010, 29, 1127
4066511 CIFC15 H20 Cl2 N2 Pd SP -18.1019; 9.1229; 12.9251
91.079; 101.68; 112.159
861.66Fliedel, Christophe; Braunstein, Pierre
Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-(S,CNHC) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag4I4(S,CNHC)2Planar Cluster†
Organometallics, 2010, 29, 5614
4065878 CIFC15 H21 Cl F3 Ir N2 O2 SP 21 21 219.804; 12.7434; 14.8864
90; 90; 90
1859.9Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4065875 CIFC15 H21 Cl F3 N2 O2 Rh SP 21 21 219.7944; 12.732; 14.907
90; 90; 90
1858.9Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4066849 CIFC15 H21 Co N2 OP n a 2112.0087; 9.7552; 12.9835
90; 90; 90
1521Vélez, Carmen L; Markwick, Phineus R. L.; Holland, Ryan L.; Dipasquale, Antonio G.; Rheingold, Arnold L.; O'Connor, Joseph M
Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes: Synthesis, Solid-State Structures, and Quantum Chemistry Calculations.
Organometallics, 2010, 29, 6695-6702
4066503 CIFC15 H22 Cl2 N6 S3 SiP 1 21/n 110.8429; 17.0694; 12.8979
90; 113.057; 90
2196.47Wagler, Jörg; Heine, Thomas; Hill, Anthony F.
Poly(methimazolyl)silanes: Syntheses and Molecular Structures†
Organometallics, 2010, 29, 5607
4063468 CIFC15 H24 Cl F6 Mo2 P S4P 21 21 2112.7338; 13.393; 13.9952
90; 90; 90
2386.79Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
Carbon‒Sulfur and Carbon‒Halogen Bond Cleavage of Acyclic or Cyclic Thioethers, Thiophenes, and Dihaloalkanes with the Trithiolato-Bridged Cation [Mo2Cp2(μ-SMe)3(MeCN)2]+
Organometallics, 2010, 29, 448-462
4066701 CIFC15 H24 Cl2 N3 O2 P Ru SC 1 2/c 128.692; 6.6083; 23.5466
90; 119.812; 90
3873.7Sternberg, Michelle; Suresh, Cherumuttathu H.; Mohr, Fabian
2-Thia-1,3,5-triaza-7-phosphaadamantane-2,2-dioxide Revisited: Computational and Experimental Studies of a Neglected Phosphine
Organometallics, 2010, 29, 3922
4066697 CIFC15 H25 Cl2 N3 O2 P Rh SP 1 21/c 110.314; 7.2646; 25.8648
90; 91.221; 90
1937.53Sternberg, Michelle; Suresh, Cherumuttathu H.; Mohr, Fabian
2-Thia-1,3,5-triaza-7-phosphaadamantane-2,2-dioxide Revisited: Computational and Experimental Studies of a Neglected Phosphine
Organometallics, 2010, 29, 3922
4067697 CIFC15 H27 Mg N Si2P -110.0894; 10.2655; 11.1908
63.035; 70.686; 89.924
959.57Forret, Robert; Kennedy, Alan R.; Klett, Jan; Mulvey, Robert E.; Robertson, Stuart D.
Multistep Self-Assembly of Heteroleptic Magnesium and Sodium−Magnesium Benzamidinate Complexes
Organometallics, 2010, 29, 1436
4066930 CIFC15 H28 O Si3P 1 21/c 113.3164; 8.2981; 34.292
90; 93.436; 90
3782.5Gluyas, Josef B. G.; Burschka, Christian; Kraft, Philip; Tacke, Reinhold
5,6-Disubstituted 1,2,3-Trisilaindanes as Silicon Analogues of Phantolide-Type Musk Odorants: Synthesis, Structure, Reactivity, and Olfactory Properties§
Organometallics, 2010, 29, 5897
4066893 CIFC15 H29 Co Si2P -16.8151; 11.5177; 11.9438
77.994; 75.525; 87.846
887.8Hapke, Marko; Weding, Nico; Spannenberg, Anke
Highly Reactive Cyclopentadienylcobalt(I) Olefin Complexes
Organometallics, 2010, 29, 4298
4063488 CIFC15 H3 Al F18 O6P -3 c 117.7778; 17.7778; 12.1417
90; 90; 120
3323.3Bouyahyi, Miloud; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated β-Diketonate Ligands: Syntheses, Structures, Intramolecular Reduction, and Use in Ring-Opening Polymerization of Lactide
Organometallics, 2010, 29, 491-500
4067486 CIFC15 H30 Ge N2 O2P b c a16.623; 9.0607; 24.332
90; 90; 90
3664.8Ruddy, Adam J.; Rupar, Paul A.; Bladek, Kamila J.; Allan, Christopher J.; Avery, Jessica C.; Baines, Kim M.
On the Bonding in N-Heterocyclic Carbene Complexes of Germanium(II)
Organometallics, 2010, 29, 1362
4066654 CIFC15 H30 N P2 VP 1 21/c 115.132; 8.9402; 13.711
90; 102.48; 90
1811Batinas, Aurora A.; Dam, Jeroen; Meetsma, Auke; Hessen, Bart; Bouwkamp, Marco W.
Thermolysis of Half-Sandwich Vanadium(V) Imido Complexes to Generate Vanadium(III) Imido Species via a Vanadium(IV) Intermediate
Organometallics, 2010, 29, 6230
4066233 CIFC15 H35 Co F3 O4 P3 SP 1 21/c 116.5274; 15.302; 18.7319
90; 90.855; 90
4736.8Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4066540 CIFC15 H35 N3 O7 S2 TiP 1 21/c 114.7911; 9.5434; 17.0501
90; 110.508; 90
2254.21Schwarz, Andrew D.; Herbert, Katherine R.; Paniagua, Cristina; Mountford, Philip
Ligand Variations in New Sulfonamide-Supported Group 4 Ring-Opening Polymerization Catalysts
Organometallics, 2010, 29, 4171
4066924 CIFC15 H36 Cl N2 Os PP 1 21/c 117.0286; 15.1283; 14.5231
90; 99.836; 90
3686.4Baya, Miguel; Esteruelas, Miguel A.; Oñate, Enrique
Efficient Concatenation of C═C Reduction, C−H Bond Activation, and C−C and C−N Coupling Reactions on Osmium: Assembly of Two Allylamines and an Allene
Organometallics, 2010, 29, 6298
4066228 CIFC15 H36 Co O P3P 1 21/n 18.7078; 16.0967; 14.2582
90; 93.93; 90
1993.83Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4066221 CIFC15.5 H19 Cl3 N P PdP 43 21 28.5216; 8.5216; 49.3018
90; 90; 90
3580.18Chen, Shuli; Ng, Joseph Kok-Peng; Pullarkat, Sumod A.; Liu, Fengli; Li, Yongxin; Leung, Pak-Hing
Asymmetric Synthesis of New Diphosphines and Pyridylphosphines via a Kinetic Resolution Process Promoted and Controlled by a Chiral Palladacycle
Organometallics, 2010, 29, 3374
4063445 CIFC15.5 H25 Au Cl4 N2P 1 21/c 115.1152; 17.8557; 15.9701
90; 108.417; 90
4089.5Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4067273 CIFC156 H228 Mn2 N2I 1 2/a 125.0687; 27.979; 25.2421
90; 118.513; 90
15557Ni, Chengbao; Fettinger, James C.; Power, Philip P.
Intramolecular C−H Activation by Putative Terminal Two-Coordinate Manganese(III) Imido Intermediates: Hydrogen Abstraction from a Phenyl Group
Organometallics, 2010, 29, 269
4066408 CIFC16 H12 B2 Mn2 O6P 1 21/c 16.6618; 11.1029; 12.2334
90; 102.1; 90
884.7Eckensberger, U. David; Weber, Mitra; Wildt, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactivity of [(C5Me5)Fe(C5H4BBr2)] and [(OC)3Mn(C5H4BBr2)] toward Et3SiH: Facile Access to [(OC)3Mn(C5H4BH2)]2and to Boron-Bridged Dinuclear Organometallics†
Organometallics, 2010, 29, 5301
4065587 CIFC16 H12 Bi F12 O2 ReP b c a14.6191; 17.5119; 15.7302
90; 90; 90
4027.06Schiwon, Rafael; Knispel, Christina; Limberg, Christian
Heterometallic Complexes with Re−Bi Metal Bonds
Organometallics, 2010, 29, 1670
4067287 CIFC16 H12 Cl Fe N O5P n a 217.3729; 12.4058; 19.0773
90; 90; 90
1744.9Ortega-Jiménez, Fernando; Benavides, Adriana; Delgado, Francisco; Jiménez-Vázquez, Hugo A.; Tamariz, Joaquín
Synthesis and Reactivity of η4-Diene-Fe(CO)3Complexes fromexo-2-Oxazolidinone Dienes. A Facile Generation of Stable Conjugated Enol-Enamido Species
Organometallics, 2010, 29, 149
4066898 CIFC16 H12 Fe O2 SeP -16.7194; 8.6243; 13.679
105.948; 97.141; 96.818
746.5Caldwell, Lorraine M.; Hill, Anthony F.; Hulkes, Alexander G.; McQueen, Caitlin M. A.; White, Andrew J. P.; Williams, David J.
Alkynyl Selenolate Complexes of Iron, Nickel, and Molybdenum
Organometallics, 2010, 29, 6350
4065685 CIFC16 H14 Br12 N2 Si6P 1 21/c 110.6; 10.905; 15.979
90; 101.058; 90
1812.8Dai, Xuliang; Schulz, Douglas L.; Braun, Christopher W.; Ugrinov, Angel; Boudjouk, Philip
“Inverse Sandwich” Complexes of Perhalogenated Cyclohexasilane
Organometallics, 2010, 29, 2203
4066112 CIFC16 H15 F6 Hg2 N2 O PP n m a8.7266; 17.9057; 12.5696
90; 90; 90
1964.1Patel, Upali; Sharma, Sagar; Singh, Harkesh B.; Dey, Sandip; Jain, Vimal K.; Wolmershäuser, Gotthelf; Butcher, Ray J.
Intermetallic Bonds in Metallophilic Mercuraazametallamacrocycles of Synthetic Design
Organometallics, 2010, 29, 4265
4065771 CIFC16 H15 F7 Mo O3P 1 21/n 18.575; 16.7549; 12.8756
90; 96.355; 90
1838.5Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948
4066520 CIFC16 H16 Fe O4P -18.2998; 12.6189; 14.334
94.541; 104.679; 94.069
1441.24Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4066519 CIFC16 H17 Br Fe O2P 1 21 113.0508; 7.4657; 22.5114
90; 92.649; 90
2191.02Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4067046 CIFC16 H17 Fe2 O7 P S2P -18.3336; 9.1887; 13.767
78.68; 78.59; 83.32
1010Song, Li-Cheng; Zhao, Pei-Hua; Du, Zong-Qiang; Tang, Ming-Yi; Hu, Qing-Mei
Unexpected Synthesis of Tetrahedral Fe/S Clusters via Highly Reactive Butterfly Intermediates (μ-HS)2Fe2(CO)5[RP(CH2OH)2]
Organometallics, 2010, 29, 5751
4066455 CIFC16 H18 Cl2 ZrC 1 2/c 114.2011; 6.6487; 16.7868
90; 97.411; 90
1571.75Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4066458 CIFC16 H18 Cl2 ZrP 1 21/n 18.2449; 15.6556; 11.8931
90; 90.727; 90
1535.02Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4067708 CIFC16 H18 Cl6 F N O Pt SP 1 21/c 18.1883; 13.9875; 19.7052
90; 101.853; 90
2208.79Crosby, Sarah H.; Clarkson, Guy J.; Deeth, Robert J.; Rourke, Jonathan P.
Platinum(IV) DMSO Complexes: Synthesis, Isomerization, and Agostic Intermediates
Organometallics, 2010, 29, 1966
4066710 CIFC16 H18 F6 N3 P PdC 1 2/c 114.155; 22.725; 12.775
90; 109.47; 90
3874.4D’Amora, Angela; Fanfoni, Lidia; Cozzula, Daniela; Guidolin, Nicol; Zangrando, Ennio; Felluga, Fulvia; Gladiali, Serafino; Benedetti, Fabio; Milani, Barbara
Addressing the Poly- to Oligo-ketone Selectivity in Styrene Carbonylation Catalyzed by Palladium/bpy Complexes. Effect of the 6-Alkyl Substitution
Organometallics, 2010, 29, 4472
4066516 CIFC16 H18 Fe O2P 1 21/c 17.3326; 23.931; 15.6434
90; 101.148; 90
2693.25Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4066110 CIFC16 H18 Hg N2C m c 2121.7105; 7.1769; 8.9718
90; 90; 90
1397.9Patel, Upali; Sharma, Sagar; Singh, Harkesh B.; Dey, Sandip; Jain, Vimal K.; Wolmershäuser, Gotthelf; Butcher, Ray J.
Intermetallic Bonds in Metallophilic Mercuraazametallamacrocycles of Synthetic Design
Organometallics, 2010, 29, 4265
4067709 CIFC16 H19 Cl3 F N O Pt SP -18.6007; 14.1997; 16.4235
105.974; 96.165; 95.714
1899.59Crosby, Sarah H.; Clarkson, Guy J.; Deeth, Robert J.; Rourke, Jonathan P.
Platinum(IV) DMSO Complexes: Synthesis, Isomerization, and Agostic Intermediates
Organometallics, 2010, 29, 1966
4067448 CIFC16 H19 Fe NP 1 21/c 111.8168; 16.2924; 14.0456
90; 102.25; 90
2642.55Schwendemann, Sina; Tumay, Tülay Aslı; Axenov, Kirill V.; Peuser, Ilona; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Metal-Free Frustrated Lewis Pair Catalyzed 1,4-Hydrogenation of Conjugated Metallocene Dienamines
Organometallics, 2010, 29, 1067
4065847 CIFC16 H20 Cl3 N3 RuP 1 21/c 17.5561; 15.3044; 15.2179
90; 104.439; 90
1704.24Fukui, Sohei; Suzuki, Noriyuki; Wada, Tohru; Tanaka, Koji; Nagao, Hirotaka
Formation and Structure of an (Iminium ion)ruthenium Complex and Reaction of the Iminium Ion Moiety with Alcohols
Organometallics, 2010, 29, 1534
4063346 CIFC16 H20 Cl4 Cu2 N8C 1 2/c 116.0805; 10.8127; 14.4679
90; 113.338; 90
2309.77Sabiah, Shahulhameed; Lee, Chen-Shiang; Hwang, Wen-Shu; Lin, Ivan J. B.
Facile C—N Bond Cleavage Promoted by Cuprous Oxide: Formation of C—C-Coupled Biimidazole from Its Methylene-Bridged Congener
Organometallics, 2010, 29, 290-293
4067491 CIFC16 H21 Br Mo N2 O2P 1 21/n 115.2517; 7.853; 15.3594
90; 106.746; 90
1761.6Li, Shenyu; Kee, Choon Wee; Huang, Kuo-Wei; Hor, T. S. Andy; Zhao, Jin
Cyclopentadienyl Molybdenum(II/VI) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Reactivity under Oxidative Conditions
Organometallics, 2010, 29, 1924
4067549 CIFC16 H21 Cl N6 ZnP 1 21 17.8808; 17.5757; 13.2885
90; 90.282; 90
1840.58Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4065848 CIFC16 H21 Cl3 N3 RuP 1 21/n 17.7766; 14.6864; 15.2361
90; 100.205; 90
1712.59Fukui, Sohei; Suzuki, Noriyuki; Wada, Tohru; Tanaka, Koji; Nagao, Hirotaka
Formation and Structure of an (Iminium ion)ruthenium Complex and Reaction of the Iminium Ion Moiety with Alcohols
Organometallics, 2010, 29, 1534
4065879 CIFC16 H23 Cl F3 Ir N2 O2 SP 1 21/c 111.16; 8.6411; 20.518
90; 97.199; 90
1963Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4065876 CIFC16 H23 Cl F3 N2 O2 Rh SP 1 21/c 111.1322; 8.5738; 20.592
90; 97.201; 90
1949.9Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4063471 CIFC16 H24 Cl F6 Mo2 P S3P -110.8501; 13.5873; 17.1418
68.456; 89.075; 81.857
2325.1Ojo, Wilfried-Solo; Pétillon, François Y.; Schollhammer, P.; Talarmin, Jean
Carbon‒Sulfur and Carbon‒Halogen Bond Cleavage of Acyclic or Cyclic Thioethers, Thiophenes, and Dihaloalkanes with the Trithiolato-Bridged Cation [Mo2Cp2(μ-SMe)3(MeCN)2]+
Organometallics, 2010, 29, 448-462
4066718 CIFC16 H24 F6 N6 P RhP 1 21 18.1083; 14.2434; 8.6479
90; 96.46; 90
992.4Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4067194 CIFC16 H24 Fe Si2P 21 21 217.5376; 12.8337; 17.2964
90; 90; 90
1673.2Sunada, Yusuke; Imaoka, Tsuyoshi; Nagashima, Hideo
Half-Sandwich (η6-Arene)iron(II) Dinitrogen Complexes Bearing a Disilaferracycle Skeleton as a Precursor for Double Silylation of Ethylene and Alkynes
Organometallics, 2010, 29, 6157
4066728 CIFC16 H24 N2 O2P 1 21/c 19.1061; 17.833; 9.8945
90; 107.239; 90
1534.6Tabernero, Vanessa; Mosquera, Marta E. G.; Cuenca, Tomás
Synthesis and Structural Characterization of a Novel Aluminum Amidato Derivative Exhibiting a Rare 16-Membered Wheel Containing Four Aluminum Centers
Organometallics, 2010, 29, 3642
4067569 CIFC16 H24 N2 O2 WP 1 21/c 19.2164; 17.4223; 11.4165
90; 106.903; 90
1753.96Semproni, Scott P.; McNeil, W. Stephen; Baillie, Rhett A.; Patrick, Brian O.; Campana, Charles F.; Legzdins, Peter
Ground-State Electronic Asymmetry in Cp*W(NO)(η1-isonitrile)2Complexes
Organometallics, 2010, 29, 867
4066789 CIFC16 H26 B10 Cl2 N2 PdP 1 21/n 18.9577; 14.3902; 18.5339
90; 102.028; 90
2336.63Terrasson, Vincent; Planas, José Giner; Viñas, Clara; Teixidor, Francesc; Prim, Damien; Light, Mark E.; Hursthouse, Michael B.
closo-o-Carboranylmethylamine−Pyridine Associations: Synthesis, Characterization, and First Complexation Studies
Organometallics, 2010, 29, 4130
4066791 CIFC16 H26 B10 N2P 21 21 218.6992; 12.0556; 19.1699
90; 90; 90
2010.43Terrasson, Vincent; Planas, José Giner; Viñas, Clara; Teixidor, Francesc; Prim, Damien; Light, Mark E.; Hursthouse, Michael B.
closo-o-Carboranylmethylamine−Pyridine Associations: Synthesis, Characterization, and First Complexation Studies
Organometallics, 2010, 29, 4130
4067521 CIFC16 H26 Cl2 N2 O2 Pd S2P 1 21/n 112.9314; 5.7541; 15.1045
90; 110.45; 90
1053.07Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4066749 CIFC16 H26 Co2 O4 P2P -16.8755; 8.7561; 8.95
87.994; 75.764; 85.041
520.26Aguirre-Etcheverry, Paulina; Ashley, Andrew E.; Balázs, Gábor; Green, Jennifer C.; Cowley, Andrew R.; Thompson, Amber L.; O’Hare, Dermot
Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
Organometallics, 2010, 29, 5847
4065791 CIFC16 H28 F6 N O2 Os PP n a 2112.497; 19.794; 8.1791
90; 90; 90
2023.2Batuecas, María; Esteruelas, Miguel A.; García-Yebra, Cristina; Oñate, Enrique
Redox Isomerization of Allylic Alcohols Catalyzed by Osmium and Ruthenium Complexes Containing a Cyclopentadienyl Ligand with a Pendant Amine or Phosphoramidite Group: X-ray Structure of an η3-1-Hydroxyallyl-Metal-Hydride Intermediate
Organometallics, 2010, 29, 2166
4066679 CIFC16 H28 F6 Os P2P 1 21/c 115.859; 7.4122; 17.417
90; 103.397; 90
1991.7Castro-Rodrigo, Ruth; Esteruelas, Miguel A.; López, Ana M.; Mozo, Silvia; Oñate, Enrique
C−H Bond Activation Reactions in π-Allene−Osmium−Triisopropylphosphine Complexes with Cyclopentadienyl or Hydridotris(pyrazolyl)borate Ligands: Formation of Isopropenyldiisopropylphosphine versus Hydride−Alkenylcarbyne Derivatives
Organometallics, 2010, 29, 4071
4066929 CIFC16 H28 O Si3P 1 21/c 110.8718; 35.093; 10.3208
90; 89.999; 90
3937.6Gluyas, Josef B. G.; Burschka, Christian; Kraft, Philip; Tacke, Reinhold
5,6-Disubstituted 1,2,3-Trisilaindanes as Silicon Analogues of Phantolide-Type Musk Odorants: Synthesis, Structure, Reactivity, and Olfactory Properties§
Organometallics, 2010, 29, 5897
4083396 CIFC16 H29 Cl3 N2 Si ZrP -18.8636; 15.54; 17.668
65.26; 85.408; 81.493
2185.5Yuan, Shifang; Wei, Xuehong; Tong, Hongbo; Zhang, Liping; Liu, Diansheng; Sun, Wen-Hua
μ2,η1-N-[(N,N-Dimethylamino)dimethylsilyl]-2,6-diisopropylanilido Metal (Li, Zr, Hf) Compounds and the Catalytic Behaviors of the IVB Compounds in Ethylene (Co)Polymerizationξ
Organometallics, 2010, 29, 2085
4066812 CIFC16 H29 O2 P RuP 1 21/n 19.095; 14.037; 13.74
90; 102.164; 90
1714.8Hirano, Masafumi; Hiroi, Yuki; Komine, Nobuyuki; Komiya, Sanshiro
Catalytic Tail-to-Tail Selective Dimerization of Methyl Methacrylate Promoted by a Ruthenium(0) Complex
Organometallics, 2010, 29, 3690
4067299 CIFC16 H31 Cl2 N3 TiP 1 21/n 19.8809; 22.4338; 10.2598
90; 113.557; 90
2084.7Lorber, Christian; Vendier, Laure
Imido−Titanium/Molybdenum Heterobimetallic Systems. Switching from η6-Arene to Fischer-Type Aminocarbene Complexes by Tuning Reactivity Conditions
Organometallics, 2010, 29, 1127
4067352 CIFC16 H34 I2 O5 SrP 1 21/c 117.1871; 8.9208; 16.1756
90; 99.6; 90
2445.36Langer, Jens; Görls, Helmar; Westerhausen, Matthias
Stability and Reactivity of Phenylstrontium Compounds in Solution
Organometallics, 2010, 29, 2034
4066925 CIFC16 H36 Cl N2 O Os PP -18.3543; 10.685; 12.0981
81.434; 70.245; 82.22
1000.85Baya, Miguel; Esteruelas, Miguel A.; Oñate, Enrique
Efficient Concatenation of C═C Reduction, C−H Bond Activation, and C−C and C−N Coupling Reactions on Osmium: Assembly of Two Allylamines and an Allene
Organometallics, 2010, 29, 6298
4066231 CIFC16 H36 Co2 O4 P4P 1 21/c 110.972; 13.2483; 18.019
90; 107.156; 90
2502.7Bleeke, John R.; Lutes, Bryn L.; Lipschutz, Michael; Sakellariou-Thompson, Donastas; Lee, John Seonghyun; Rath, Nigam P.
Synthesis, Structure, Spectroscopy, and Reactivity of Oxapentadienyl−Cobalt−Phosphine Complexes†,(1)
Organometallics, 2010, 29, 5057
4067353 CIFC16 H36 I2 O6 SrC 1 2/c 115.0594; 10.0303; 16.9646
90; 106.462; 90
2457.5Langer, Jens; Görls, Helmar; Westerhausen, Matthias
Stability and Reactivity of Phenylstrontium Compounds in Solution
Organometallics, 2010, 29, 2034
4066730 CIFC16 H38 Cl2 O2 P2 PtP 1 21/n 18.4943; 14.6501; 9.3488
90; 95.551; 90
1157.93Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Gimbert, Yves; Buono, Gérard
Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Organometallics, 2010, 29, 3936
4067756 CIFC16 H40 B18 Ir2P 1 21/c 111.6122; 17.8637; 14.1173
90; 110.418; 90
2744.46Alekseev, Leonid S.; Dolgushin, Fedor M.; Godovikov, Ivan A.; Chizhevsky, Igor T.
Electronically-Deficient Biiridacarbaborane Clusters with a Bridging μ,η-COD Ligand
Organometallics, 2010, 29, 1707
4067296 CIFC16 H40 N4 Zn2P 1 21/n 111.998; 7.218; 12.46
90; 99.112; 90
1065.4Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4066278 CIFC16 H42 Al Li N6P 1 21/c 18.3824; 15.4957; 18.4008
90; 99.7841; 90
2355.34Kamps, Ina; Neumann, Beate; Stammler, Hans-Georg; Mitzel, Norbert W.
A Chain Aggregate of Methyllithium Tetramers†
Organometallics, 2010, 29, 4746
4067727 CIFC16 H48 Si8P -19.1197; 9.4068; 9.87
76.07; 81.57; 65.31
745.7Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4066410 CIFC16 H8 B Br Mn2 O6P 1 21/c 112.3192; 12.6324; 22.76
90; 96.661; 90
3518Eckensberger, U. David; Weber, Mitra; Wildt, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactivity of [(C5Me5)Fe(C5H4BBr2)] and [(OC)3Mn(C5H4BBr2)] toward Et3SiH: Facile Access to [(OC)3Mn(C5H4BH2)]2and to Boron-Bridged Dinuclear Organometallics†
Organometallics, 2010, 29, 5301
4067099 CIFC17 H15 Br Fe OP 21 21 218.0597; 11.2942; 15.5563
90; 90; 90
1416.06Lotz, Matthias; Schuecker, Raffael; Mereiter, Kurt; Knochel, Paul
Synthesis of Exclusively Centrostereogenic 1,3-Bidentate Ferrocenyldiphosphane Ligands and Their Use in Enantioselective Hydrogenations
Organometallics, 2010, 29, 6503
4065765 CIFC17 H15 F7 Mo O4P 1 21/n 18.76; 16.094; 13.782
90; 93.123; 90
1940.1Huang, Hui; Hughes, Russell P.; Rheingold, Arnold L.
Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds
Organometallics, 2010, 29, 1948-1955
4067610 CIFC17 H16 Br Cl N2 PtP -18.8175; 9.5511; 10.6372
87.2887; 73.8058; 81.2471
850.256Forniés, Juan; Sicilia, Violeta; Larraz, Carmen; Camerano, José A.; Martín, Antonio; Casas, José M.; Tsipis, Athanassios C.
One-Pot and Step-by-Step N-Assisted CPh−H Activation in 2-(4-Bromophenyl)imidazol[1,2-a]pyridine: Synthesis of a New C,N-Cyclometalated Compound [{Pt(C∧N)(μ-Cl)}2] as Precursor of Luminescent Platinum(II) Compounds
Organometallics, 2010, 29, 1396
4067039 CIFC17 H16 F N OP 21 21 217.5353; 7.8131; 23.437
90; 90; 90
1379.83Paul, Susann; Schweizer, W. Bernd; Ebert, Marc-Olivier; Gilmour, Ryan
A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology
Organometallics, 2010, 29, 4424
4066611 CIFC17 H17 Au Cl N3P 1 21/c 19.1706; 14.5846; 12.8993
90; 91.438; 90
1724.73Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066616 CIFC17 H17 Au Cl3 N3P 1 21/n 19.088; 14.856; 13.789
90; 101.882; 90
1821.8Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066980 CIFC17 H18 Cl I2 N3 PdP 1 21/c 114.9614; 8.8691; 16.6518
90; 108.87; 90
2090.8Xu, Xiangya; Xu, Baochang; Li, Yongxin; Hong, Soon Hyeok
Abnormal N-Heterocyclic Carbene Promoted Suzuki−Miyaura Coupling Reaction: A Comparative Study
Organometallics, 2010, 29, 6343
4066795 CIFC17 H18 O3P 1 21/c 19.2272; 12.3242; 13.7756
90; 113.227; 90
1439.56Lee, Jhen-Yi; Cheng, Pi-Yun; Tsai, Yi-Hua; Lin, Guan-Ru; Liu, Shih-Pu; Sie, Ming-Han; Lee, Hon Man
Efficient Heck Reactions Catalyzed by Palladium(0) and -(II) Complexes Bearing N-Heterocyclic Carbene and Amide Functionalities
Organometallics, 2010, 29, 3901
4066766 CIFC17 H20 Fe O5P 1 21/n 17.388; 13.21; 16.46
90; 91.78; 90
1605.6Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Synthesis and Biological Evaluation of Ferrocene-Containing Bioorganometallics Inspired by the Antibiotic Platensimycin Lead Structure
Organometallics, 2010, 29, 4312
4065629 CIFC17 H21 F6 N7 O6 Pd S2P n m a13.423; 10.167; 19.551
90; 90; 90
2668Xiao, Xu-Qiong; Jia, Ai-Quan; Lin, Yue-Jian; Jin, Guo-Xin
Self-Assembly of Palladium-Based Macrocycles with N-Heterocyclic Carbene as the “Corner” Ligand†
Organometallics, 2010, 29, 4842
4067474 CIFC17 H22 B7 Fe I N O2 PP -19.0292; 10.2857; 13.4485
92.818; 103.85; 111.942
1111.43Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067191 CIFC17 H22 Fe O Si2P 1 21/c 117.753; 13.866; 28.437
90; 91.362; 90
6998Sunada, Yusuke; Imaoka, Tsuyoshi; Nagashima, Hideo
Half-Sandwich (η6-Arene)iron(II) Dinitrogen Complexes Bearing a Disilaferracycle Skeleton as a Precursor for Double Silylation of Ethylene and Alkynes
Organometallics, 2010, 29, 6157
4067077 CIFC17 H22 I N2 PtP -19.391; 10.5204; 10.7511
67.924; 70.377; 70.536
900.69Nabavizadeh, S. Masoud; Habibzadeh, Sepideh; Rashidi, Mehdi; Puddephatt, Richard J.
Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications
Organometallics, 2010, 29, 6359
4065813 CIFC17 H22 N2 O8 Ru3 SiP 1 21/c 19.5519; 9.4221; 26.6438
90; 95.45; 90
2387.07Cabeza, Javier A.; del Río, Ignacio; Fernández-Colinas, José M.; Pérez-Carreño, Enrique; Vázquez-García, Digna
From Allenes to Edge-Bridging Allyl Ligands or Face-Capping Alkenyl Ligands on a Triruthenium Hydrido Carbonyl Cluster: An Experimental and DFT Computational Study†
Organometallics, 2010, 29, 4818
4067470 CIFC17 H23 B7 Fe N O2 PP 1 21/c 18.9301; 14.5508; 16.3094
90; 99.078; 90
2092.7Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067145 CIFC17 H23 Br Li2 N O1.5P 1 21/m 19.3319; 22.498; 10.143
90; 112.34; 90
1969.68Bhadbhade, Mohan; Clentsmith, Guy K. B.; Field, Leslie D.
Sterically Hindered Diazabutadienes (DABs): Competing Reaction Pathways with MeLi
Organometallics, 2010, 29, 6509
4067068 CIFC17 H24 Cl2 Ir NP -17.6373; 10.1289; 12.916
111.566; 91.287; 98.66
915.31Kumaran, Elumalai; Sridevi, Venugopal Shanmugham; Leong, Weng Kee
Orthometalated Amino-Carbene Derivatives of Iridium via Anilines and Terminal Alkynes
Organometallics, 2010, 29, 6417
4065827 CIFC17 H25 N3 O Zn2P c c a26.6205; 8.4091; 16.9137
90; 90; 90
3786.21Kahnes, Marcel; Görls, Helmar; González, Leticia; Westerhausen, Matthias
Synthesis and Catalytic Reactivity of Bis(alkylzinc)-hydride-di(2-pyridylmethyl)amides
Organometallics, 2010, 29, 3098
4066361 CIFC17 H26 O2 WP 21 21 2111.6528; 11.7581; 12.1589
90; 90; 90
1665.95Egbert, Jonathan D.; Heinekey, D. Michael
Dihydrogen Complexes of the Chromium Group: Synthesis and Characterization of (Arene)M(CO)2(H2) Complexes
Organometallics, 2010, 29, 3387
4065598 CIFC17 H27 Ir N4 O6P 1 21/c 116.2935; 8.2233; 16.1922
90; 115.223; 90
1962.68Feng, Yuee; Jiang, Bi; Boyle, Paul A.; Ison, Elon A.
Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes
Organometallics, 2010, 29, 2857
4067760 CIFC17 H28 Cl N2 RhP 1 21/n 16.5715; 18.7963; 13.799
90; 94.439; 90
1699.3Snead, David R.; Inagaki, Sebastien; Abboud, Khalil A.; Hong, Sukwon
Bis(2-alkylpyrrolidin-1-yl)methylidenes as Chiral Acyclic Diaminocarbene Ligands
Organometallics, 2010, 29, 1729
4063441 CIFC17 H29 O PP 42/n :223.7985; 23.7985; 5.9808
90; 90; 90
3387.3Chapp, Timothy W.; Glueck, David S.; Golen, James A.; Moore, Curtis E.; Rheingold, Arnold L.
Platinum-Catalyzed Asymmetric Alkylation of Bis(isitylphosphino)ethane: Stereoselectivity Reversal in Successive Formation of Two P−C Bonds
Organometallics, 2010, 29, 378
4065675 CIFC17 H30 Cl2 Ge N2P 1 21/c 115.9298; 8.353; 16.5558
90; 115.812; 90
1983.15Rupar, Paul A.; Staroverov, Viktor N.; Baines, Kim M.
Reactivity Studies of N-Heterocyclic Carbene Complexes of Germanium(II)†
Organometallics, 2010, 29, 4871
4065739 CIFC17 H30 P RhP -18.8535; 10.5003; 12.5616
66.733; 77.5152; 89.7025
1043.25Chaplin, Adrian B.; Weller, Andrew S.
C−C Bond Activation of a Cyclopropyl Phosphine: Isolation and Reactivity of a Tetrameric Rhodacyclobutane
Organometallics, 2010, 29, 2332
4065857 CIFC17 H33 Cl2 Fe N3 P2F d d 226.6478; 43.3956; 9.4129
90; 90; 90
10885.1Benito-Garagorri, David; Alves, Luis Gonçalo; Veiros, Luis F.; Standfest-Hauser, Christina M.; Tanaka, Shinji; Mereiter, Kurt; Kirchner, Karl
Kinetically Controlled Formation of Octahedraltrans-Dicarbonyl Iron(II) PNP Pincer Complexes: The Decisive Role of Spin-State Changes§
Organometallics, 2010, 29, 4932
4067755 CIFC17 H42 B18 Cl2 Ir2P 1 21/c 112.3498; 18.0535; 14.1564
90; 108.799; 90
2987.9Alekseev, Leonid S.; Dolgushin, Fedor M.; Godovikov, Ivan A.; Chizhevsky, Igor T.
Electronically-Deficient Biiridacarbaborane Clusters with a Bridging μ,η-COD Ligand
Organometallics, 2010, 29, 1707
4066043 CIFC17 H7 Br Mn N O4P -16.4995; 10.8762; 11.2558
92.791; 104.229; 100.301
755.24Dubarle Offner, Julien; Schnakenburg, Gregor; Rose-Munch, Françoise; Rose, Eric; Dötz, Karl Heinz
Dibenzo[f,h]quinoline Cr(CO)3Complexes: Synthesis by Chromium-Templated Benzannulation, Cyclomanganation, and Haptotropic Chromium Migration
Organometallics, 2010, 29, 3308
4066700 CIFC17.25 H22 Cl2 N4 O2 P Pd SP 1 21/n 110.1513; 18.4785; 12.206
90; 111.01; 90
2137.39Sternberg, Michelle; Suresh, Cherumuttathu H.; Mohr, Fabian
2-Thia-1,3,5-triaza-7-phosphaadamantane-2,2-dioxide Revisited: Computational and Experimental Studies of a Neglected Phosphine
Organometallics, 2010, 29, 3922
4066694 CIFC17.5 H9 N O9 Ru3P -19.63; 9.91; 12.358
80.472; 71.785; 79.735
1094.7Cabeza, Javier A.; del Río, Ignacio; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela; Vázquez-García, Digna
Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters
Organometallics, 2010, 29, 4464
4066816 CIFC175 H228 N9 Nb3 O15P -112.8639; 23.269; 27.346
105.298; 91.241; 100.978
7728.6Neshat, Abdollah; Schmidt, Joseph A. R.
Derivatization of Niobium Complexes Bearing Imido and Acetophenone Imine Ligands
Organometallics, 2010, 29, 6219
4066825 CIFC176 H127 B2 F49 Mn2 N2 O2 P8P -116.8661; 22.756; 24.8001
64.656; 89.588; 80.394
8459.6Welch, Kevin D.; Dougherty, William G.; Kassel, W. Scott; DuBois, Daniel L.; Bullock, R. Morris
Synthesis, Structures, and Reactions of Manganese Complexes Containing Diphosphine Ligands with Pendant Amines
Organometallics, 2010, 29, 4532
4067290 CIFC18 H11 F9 Ge O2P 1 21/c 119.612; 14.042; 13.579
90; 105.02; 90
3611.8Bombicz, Petra; Kovács, Ilona; Nyulászi, László; Szieberth, Dénes; Terleczky, Péter
Neutral Pentacoordinate Group 14 Compounds with β-Diketonato ligands
Organometallics, 2010, 29, 1100
4065677 CIFC18 H13 F3 O2 S2P -18.2373; 8.4549; 12.193
79.27; 83.503; 87.168
828.63Cetiner, Derya; Norel, Lucie; Tranchier, Jean-Philippe; Rose-Munch, Françoise; Rose, Eric; Herson, Patrick
Synthesis and Reactivity of (η5-Hydroxyalkylcyclohexadienyl)Mn(CO)3Complexes
Organometallics, 2010, 29, 1778
4066411 CIFC18 H14 B Mn2 N O6P 1 21/c 16.9727; 18.4166; 14.9855
90; 101.853; 90
1883.31Eckensberger, U. David; Weber, Mitra; Wildt, Julia; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactivity of [(C5Me5)Fe(C5H4BBr2)] and [(OC)3Mn(C5H4BBr2)] toward Et3SiH: Facile Access to [(OC)3Mn(C5H4BH2)]2and to Boron-Bridged Dinuclear Organometallics†
Organometallics, 2010, 29, 5301
4067465 CIFC18 H17 B7 Br2 Fe N2 O3P -17.0436; 11.0543; 15.872
75.372; 83.398; 88.434
1187.84Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4066713 CIFC18 H17 N2 PP 1 21/c 116.1084; 5.5316; 17.9425
90; 111.486; 90
1487.67Objartel, Ina; Pott, Nils A.; John, Michael; Stalke, Dietmar
Coordination Site SelectiveJanus HeadLigands†
Organometallics, 2010, 29, 5670
4067305 CIFC18 H18 Cr N2 O5P 1 21/c 119.4093; 6.9993; 13.6169
90; 94.866; 90
1843.2Tian, Xiaohui; Song, Li; Yuan, Yizhong; Lin, Jiaping
Two New Receptors for Carboxylate Anions with an IR-Active Reporting Group
Organometallics, 2010, 29, 509
4066612 CIFC18 H19 Au Cl N3P 1 21/n 19.9142; 16.023; 11.1007
90; 93.781; 90
1759.6Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066617 CIFC18 H19 Au Cl3 N3P 1 21/n 19.7635; 14.867; 14.1505
90; 103.77; 90
1994.97Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4065713 CIFC18 H19 NP 1 21/n 18.5; 10.082; 17.82
90; 94.548; 90
1522.3Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4066523 CIFC18 H20 Fe O4P -18.5684; 9.1993; 11.2742
78.934; 73.376; 72.526
806.75Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4066855 CIFC18 H20 Mn3 N O10 Se4P 1 21/c 114.1388; 11.0309; 18.2238
90; 93.449; 90
2837.1Ho, Chia-Hua; Chu, Yen-Yi; Lin, Chien-Nan; Chen, Horng-Wen; Huang, Chung-Yi; Shieh, Minghuey
Selenium−Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations
Organometallics, 2010, 29, 4396
4066456 CIFC18 H22 Cl2 ZrC 1 2/c 121.5459; 6.6692; 14.8521
90; 126.245; 90
1721.19Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4066459 CIFC18 H22 Cl2 ZrP -112.4775; 14.3156; 16.5925
76.369; 86.137; 66.616
2642.61Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4066098 CIFC18 H23 Ge N SeP -19.009; 10.836; 11.526
66.29; 73.83; 62.71
909.4Murai, Toshiaki; Hori, Rumi; Maruyama, Toshifumi; Shibahara, Fumitoshi
(Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization
Organometallics, 2010, 29, 2400
4066097 CIFC18 H23 N Se SiP -18.917; 10.442; 11.518
99.815; 106.75; 112.716
897.8Murai, Toshiaki; Hori, Rumi; Maruyama, Toshifumi; Shibahara, Fumitoshi
(Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization
Organometallics, 2010, 29, 2400
4063347 CIFC18 H24 Cu2 F12 N8 P2P n m a17.292; 13.006; 12.943
90; 90; 90
2910.9Sabiah, Shahulhameed; Lee, Chen-Shiang; Hwang, Wen-Shu; Lin, Ivan J. B.
Facile C—N Bond Cleavage Promoted by Cuprous Oxide: Formation of C—C-Coupled Biimidazole from Its Methylene-Bridged Congener
Organometallics, 2010, 29, 290-293
4067481 CIFC18 H25 P Se ZrP 1 21 110.0011; 12.1287; 14.506
90; 102.074; 90
1720.66Büschel, Susanne; Daniliuc, Constantin; Jones, Peter G.; Tamm, Matthias
Ambiphilic Reactivity of a Phosphane-Functionalized Cycloheptatrienyl−Cyclopentadienyl Zirconium Sandwich Complex
Organometallics, 2010, 29, 671
4066962 CIFC18 H26 Br Cl3 N2 O PdP 1 21/n 113.7835; 7.7422; 22.1079
90; 102.136; 90
2306.5Vicente, José; Saura-Llamas, Isabel; García-López, José-Antonio; Bautista, Delia
Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†
Organometallics, 2010, 29, 4320
4066721 CIFC18 H26 F6 N4 P RhP 1 21/c 110.3207; 12.7488; 15.8197
90; 102.754; 90
2030.14Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4066480 CIFC18 H28 Br4 N8 O2 PtP 1 21/c 17.68; 20.122; 8.318
90; 93.595; 90
1282.9Meyer, Dirk; Ahrens, Sebastian; Strassner, Thomas
Platinum(IV) Complexes with Chelating N-Heterocyclic Carbene Ligands
Organometallics, 2010, 29, 3392
4066655 CIFC18 H28 N P2 VP 1 21/c 110.404; 10.939; 17.404
90; 95.317; 90
1972.2Batinas, Aurora A.; Dam, Jeroen; Meetsma, Auke; Hessen, Bart; Bouwkamp, Marco W.
Thermolysis of Half-Sandwich Vanadium(V) Imido Complexes to Generate Vanadium(III) Imido Species via a Vanadium(IV) Intermediate
Organometallics, 2010, 29, 6230
4067291 CIFC18 H28 N2 ZnP 1 21/c 19.3518; 13.822; 14.401
90; 92.67; 90
1859.5Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4066982 CIFC18 H29 B Br N3P 1 21/c 115.1258; 10.3124; 13.6752
90; 112.852; 90
1965.68Tsai, Jie-Hong; Lin, Shen-Ta; Yang, Richard Bing-Gong; Yap, Glenn P. A.; Ong, Tiow-Gan
Two-Way Street Transformation of Boronium and Borane Complexes Facilitated by Amino-Linked N-Heterocyclic Carbene
Organometallics, 2010, 29, 4004
4065596 CIFC18 H29 Cl2 Ir N2 O4 SP 1 21/c 18.6416; 24.5383; 11.1459
90; 112.212; 90
2188.1Feng, Yuee; Jiang, Bi; Boyle, Paul A.; Ison, Elon A.
Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes
Organometallics, 2010, 29, 2857
4063456 CIFC18 H29 F3 N2 O4 Pd SP 1 21/c 18.4184; 17.7346; 15.4582
90; 105.713; 90
2221.6Vicente, José; Abad, José Antonio; López-Sáez, María-José; Jones, Peter G.
Carbopalladation of Maleate and Fumarate Esters and 1,1-Dimethylallene with Ortho-Substituted Aryl Palladium Complexes
Organometallics, 2010, 29, 409
4066662 CIFC18 H3 B F12A e a 28.9262; 17.7039; 10.453
90; 90; 90
1651.87Ullrich, Matthias; Lough, Alan J.; Stephan, Douglas W.
Dihydrogen Activation by B(p-C6F4H)3and Phosphines
Organometallics, 2010, 29, 3647
4066984 CIFC18 H30 B N3P 1 21/n 18.937; 23.8169; 9.1486
90; 112.187; 90
1803.1Tsai, Jie-Hong; Lin, Shen-Ta; Yang, Richard Bing-Gong; Yap, Glenn P. A.; Ong, Tiow-Gan
Two-Way Street Transformation of Boronium and Borane Complexes Facilitated by Amino-Linked N-Heterocyclic Carbene
Organometallics, 2010, 29, 4004
4066790 CIFC18 H30 B10 N2P 1 21/n 110.3191; 17.9523; 11.9854
90; 99.871; 90
2187.45Terrasson, Vincent; Planas, José Giner; Viñas, Clara; Teixidor, Francesc; Prim, Damien; Light, Mark E.; Hursthouse, Michael B.
closo-o-Carboranylmethylamine−Pyridine Associations: Synthesis, Characterization, and First Complexation Studies
Organometallics, 2010, 29, 4130
4066983 CIFC18 H33 B2 N3P 1 21/c 17.3822; 11.1731; 23.8716
90; 94.432; 90
1963.09Tsai, Jie-Hong; Lin, Shen-Ta; Yang, Richard Bing-Gong; Yap, Glenn P. A.; Ong, Tiow-Gan
Two-Way Street Transformation of Boronium and Borane Complexes Facilitated by Amino-Linked N-Heterocyclic Carbene
Organometallics, 2010, 29, 4004
4067385 CIFC18 H36 N2 Si2 ZrP 1 21/n 110.9417; 13.1856; 16.3703
90; 108.379; 90
2241.3Sudupe, María; Cano, Jesús; Royo, Pascual; Mosquera, Marta E. G.; Frutos, Luis M.; Castaño, Obis
Regioselective Synthesis of 1,2- and 1,3-Di(silylamido)cyclopentadienyl Zirconium Complexes
Organometallics, 2010, 29, 263
4066783 CIFC18 H36 P2 Pd Si2P 1 21/n 19.3937; 13.7246; 18.2952
90; 104.44; 90
2284.2Li, Yong-Hua; Shimada, Shigeru
Ligand-Dependent Selective Formation of Unique Silylpalladium Complexes by the Reaction of 1-(Dimethylsilyl)-2-silylbenzene and [{1,2-C6H4(SiMe2)(SiH2)}Pd(R2PCH2CH2PR2)]
Organometallics, 2010, 29, 4406
4067354 CIFC18 H37 Ca I N4C m c 2113.252; 11.3612; 15.6074
90; 90; 90
2349.8Langer, Jens; Görls, Helmar; Westerhausen, Matthias
Stability and Reactivity of Phenylstrontium Compounds in Solution
Organometallics, 2010, 29, 2034
4066090 CIFC18 H37 N O2 Si2 WP -19.9833; 10.6781; 12.7497
110.998; 111.235; 95.911
1139.64Graham, Peter M.; Buschhaus, Miriam S. A.; Baillie, Rhett A.; Semproni, Scott P.; Legzdins, Peter
Hydroperoxide-Initiated Intramolecular Insertions of NO into Metal−Carbon Bonds†
Organometallics, 2010, 29, 5068
4065619 CIFC18 H39 Li N2P 21 21 2114.264; 16.541; 16.7437
90; 90; 90
3950.5Gessner, Viktoria H.; Strohmann, Carsten
Lithiation of Diamine Ligands to Chiral Building Blocks: Syntheses, Selectivities, and Lithiated Intermediates
Organometallics, 2010, 29, 1858
4067295 CIFC18 H40 N2 ZnC 1 2/c 118.546; 9.3694; 13.01
90; 114.528; 90
2056.7Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4067155 CIFC18 H40 N4 Zn2P 43 21 211.3479; 11.3479; 17.819
90; 90; 90
2294.6Schmidt, Sarah; Schulz, Stephan; Bläser, Dieter; Boese, Roland; Bolte, Michael
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
Organometallics, 2010, 29, 6097
4066735 CIFC18 H40 O4 P2 PtP 1 21/a 115.0494; 18.1995; 17.5116
90; 95.986; 90
4770.13Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Gimbert, Yves; Buono, Gérard
Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Organometallics, 2010, 29, 3936
4066402 CIFC18 H46 N4 O4 Zn3P 1 21/c 18.2358; 20.3; 16.5998
90; 97.066; 90
2754.19Hollingsworth, Nathan; Johnson, Andrew L.; Kingsley, Andrew; Kociok-Köhn, Gabriele; Molloy, Kieran C.
Structural Study of the Reaction of Methylzinc Amino Alcoholates with Oxygen
Organometallics, 2010, 29, 3318
4066463 CIFC18 H48 B8 N P2 RhC 1 c 110.471; 16.207; 17.48
90; 102.567; 90
2895Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Two Metal−Monocarbollide Relatives of the {B20H18} Double-Cluster Boranes†
Organometallics, 2010, 29, 4790
4066268 CIFC18 H48 Ge4 SiR 3 :H14.591; 14.591; 10.863
90; 90; 120
2002.9Hlina, Johann; Baumgartner, Judith; Marschner, Christoph
Polygermane Building Blocks†
Organometallics, 2010, 29, 5289
4066266 CIFC18 H54 Ge8R -3 :H15.968; 15.968; 11.19
90; 90; 120
2470.9Hlina, Johann; Baumgartner, Judith; Marschner, Christoph
Polygermane Building Blocks†
Organometallics, 2010, 29, 5289
4067045 CIFC18.5 H18 Cl Fe3 O7 P S2P b c n29.729; 8.597; 18.939
90; 90; 90
4840.4Song, Li-Cheng; Zhao, Pei-Hua; Du, Zong-Qiang; Tang, Ming-Yi; Hu, Qing-Mei
Unexpected Synthesis of Tetrahedral Fe/S Clusters via Highly Reactive Butterfly Intermediates (μ-HS)2Fe2(CO)5[RP(CH2OH)2]
Organometallics, 2010, 29, 5751
4066761 CIFC186 H206 B3 F8 N6 V3P 3 c 122.8523; 22.8523; 18.2102
90; 90; 120
8235.8Jordan, Markus; Saak, Wolfgang; Haase, Detlev; Beckhaus, Rüdiger
Bridging Azines in the Coordination Sphere of Low-Valent Vanadocene Derivatives†
Organometallics, 2010, 29, 5859
4067365 CIFC19 H12 Fe4 O12 S5C 1 2/c 124.812; 9.725; 26.843
90; 114.184; 90
5909Song, Li-Cheng; Cheng, Jia; Yan, Jing; Liu, Chun-Rong; Hu, Qing-Mei
Two Novel μ-CO-Containing Butterfly Fe/S Cluster Anions Formed from Trithiol MeC(CH2SH)3, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles to Produce the Corresponding Neutral Triple- and Double-Butterfly Cluster Complexes
Organometallics, 2010, 29, 205
4065718 CIFC19 H13 Br OP 1 21 113.393; 5.7699; 20.266
90; 107.784; 90
1491.2Kanao, Keiichiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols
Organometallics, 2010, 29, 2126
4065676 CIFC19 H15 Mn O5 S2P -19.0856; 10.5404; 11.8873
101.426; 103.627; 113.916
954.53Cetiner, Derya; Norel, Lucie; Tranchier, Jean-Philippe; Rose-Munch, Françoise; Rose, Eric; Herson, Patrick
Synthesis and Reactivity of (η5-Hydroxyalkylcyclohexadienyl)Mn(CO)3Complexes
Organometallics, 2010, 29, 1778
4066413 CIFC19 H17 B F4 N2 O5P 1 21/n 18.03604; 13.4879; 18.4796
90; 92.7252; 90
2000.73Dobereiner, Graham E.; Chamberlin, Catherine A.; Schley, Nathan D.; Crabtree, Robert H.
Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis†
Organometallics, 2010, 29, 5728
4066327 CIFC19 H19 Au Fe N2P -110.736; 10.83; 14.924
89.845; 89.908; 72.099
1651.2Kilpin, Kelly J.; Horvath, Raphael; Jameson, Geoffrey B.; Telfer, Shane G.; Gordon, Keith C.; Crowley, James D.
Pyridyl Gold(I) Alkynyls: A Synthetic, Structural, Spectroscopic, and Computational Study
Organometallics, 2010, 29, 6186
4066899 CIFC19 H19 Cl N PP 21 21 219.362; 10.198; 18.283
90; 90; 90
1745.5Cao, Thi-Phuong-Anh; Payet, Elina; Auffrant, Audrey; Le Goff, Xavier F.; Le Floch, Pascal
Facile Synthesis of Bifunctional Ligands using LiCH2PPh2═NPh Obtained from [PhNH−PPh3+][Br−]
Organometallics, 2010, 29, 3991
4066613 CIFC19 H21 Au Cl N3P -112.0132; 17.2839; 18.2012
95.656; 97.585; 90.586
3726.9Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066618 CIFC19 H21 Au Cl3 N3P 1 21/n 19.5563; 15.1585; 14.4511
90; 101.112; 90
2054.13Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4067315 CIFC19 H21 B Cl F4 N3 PtP 1 21/n 110.3133; 18.4483; 11.0279
90; 105.517; 90
2021.72O, Wylie W. N.; Lough, Alan J.; Morris, Robert H.
Palladium(II) and Platinum(II) Complexes Featuring a Nitrile-Functionalized N-Heterocyclic Carbene Ligand
Organometallics, 2010, 29, 570
4067231 CIFC19 H21 Br Cl2 Fe N2 O4P -18.555; 11.224; 12.97
69.062; 82.751; 69.821
1091.8Hosokawa, Satomi; Ito, Jun-ichi; Nishiyama, Hisao
A Chiral Iron Complex Containing a Bis(oxazolinyl)phenyl Ligand: Preparation and Asymmetric Hydrosilylation of Ketones
Organometallics, 2010, 29, 5773
4067288 CIFC19 H21 Fe N O5P 1 21/n 16.7712; 26.8224; 10.7305
90; 95.76; 90
1939.03Ortega-Jiménez, Fernando; Benavides, Adriana; Delgado, Francisco; Jiménez-Vázquez, Hugo A.; Tamariz, Joaquín
Synthesis and Reactivity of η4-Diene-Fe(CO)3Complexes fromexo-2-Oxazolidinone Dienes. A Facile Generation of Stable Conjugated Enol-Enamido Species
Organometallics, 2010, 29, 149
4065816 CIFC19 H21 N2 O8 Ru3P b c a11.2152; 12.4955; 34.8874
90; 90; 90
4889.1Cabeza, Javier A.; del Río, Ignacio; Fernández-Colinas, José M.; Pérez-Carreño, Enrique; Vázquez-García, Digna
From Allenes to Edge-Bridging Allyl Ligands or Face-Capping Alkenyl Ligands on a Triruthenium Hydrido Carbonyl Cluster: An Experimental and DFT Computational Study†
Organometallics, 2010, 29, 4818
4066525 CIFC19 H22 Au Cl N2P 1 21 19.8671; 8.2509; 12.0106
90; 109.031; 90
924.4Gung, Benjamin W.; Bailey, Lauren N.; Craft, Derek T.; Barnes, Charles L.; Kirschbaum, Kristin
Preparation and Characterization of Two New N-Heterocyclic Carbene Gold(I) Complexes and Comparison of Their Catalytic Activity to Au(IPr)Cl
Organometallics, 2010, 29, 3450
4067050 CIFC19 H23 Cl N O RhP 1 21/c 114.9391; 8.3631; 14.2215
90; 97.611; 90
1761.1Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066939 CIFC19 H24 I Ir N2P 1 21/n 18.7133; 14.6752; 14.886
90; 103.326; 90
1852.2Magriz, Antonio; Gómez-Bujedo, Silvia; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes
Organometallics, 2010, 29, 5941
4066936 CIFC19 H24 I N2 RhP 1 21/n 18.6835; 14.6611; 14.8322
90; 103.186; 90
1838.5Magriz, Antonio; Gómez-Bujedo, Silvia; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes
Organometallics, 2010, 29, 5941
4066608 CIFC19 H24 I N3 OP 1 21/c 18.276; 10.122; 22.9684
90; 95.161; 90
1916.25Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4063487 CIFC19 H25 Al Cl4 Fe2 N O3 PP 1 21 110.3218; 12.557; 10.3342
90; 98.259; 90
1325.5Vaheesar, Kandasamy; Bolton, Timothy M.; East, Allan L. L.; Sterenberg, Brian T.
Si‒H Bond Activation by Electrophilic Phosphinidene Complexes
Organometallics, 2010, 29, 484-490
4067475 CIFC19 H25 B7 Fe N O4 PC 1 2/c 139.2433; 7.4402; 20.8096
90; 121.487; 90
5181.3Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4063344 CIFC19 H25 Cl2 N5 PtP -110.3263; 11.8733; 12.352
62.968; 67.171; 72.603
1229.37Lee, Chen-Shiang; Sabiah, Shahulhameed; Wang, Ju-Chun; Hwang, Wen-Shu; Lin, Ivan J. B.
Water-Induced Changes of Photoluminescence of a Pincer-Type N-Heterocyclic Carbene Platinum(II) Complex
Organometallics, 2010, 29, 286
4063345 CIFC19 H25 Cl2 N5 PtP -110.502; 10.504; 12.428
103.212; 114.349; 102.06
1142.7Lee, Chen-Shiang; Sabiah, Shahulhameed; Wang, Ju-Chun; Hwang, Wen-Shu; Lin, Ivan J. B.
Water-Induced Changes of Photoluminescence of a Pincer-Type N-Heterocyclic Carbene Platinum(II) Complex
Organometallics, 2010, 29, 286
4067495 CIFC19 H26 Cl F6 P Pd Ru S2P b c a14.86958; 12.21797; 25.8649
90; 90; 90
4699.03Bonnet, Sylvestre; Lutz, Martin; Spek, Anthony L.; van Koten, Gerard; Klein Gebbink, Robertus J. M.
Bimetallic η6,η1SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure, and Catalytic Activity
Organometallics, 2010, 29, 1157
4066986 CIFC19 H27 N3 NiP 1 21/n 18.3593; 12.7819; 16.1523
90; 92.934; 90
1723.6Breitenfeld, Jan; Vechorkin, Oleg; Corminboeuf, Clémence; Scopelliti, Rosario; Hu, Xile
Why Are (NN2)Ni Pincer Complexes Active for Alkyl−Alkyl Coupling: β-H Elimination Is Kinetically Accessible but Thermodynamically Uphill
Organometallics, 2010, 29, 3686
4066892 CIFC19 H28 NC m c m16.888; 11.023; 9.623
90; 90; 90
1791.4Ionkin, Alex S.; Marshall, William J.; Fish, Brian M.; Howe, Laurie A.
Fragmentation of an N-Substituted One-Coordinate Phosphorus (Phosphaalkyne): Plausible Generation of Monovalent Phosphorus Species†
Organometallics, 2010, 29, 4154
4067563 CIFC19 H29 B N7 O4 P WP 1 21/n 112.217; 13.545; 15.293
90; 109.223; 90
2389.6Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4067494 CIFC19 H29 B2 Fe N3P 1 21/n 19.8191; 20.866; 9.8839
90; 106.474; 90
1941.9Bauer, Florian; Braunschweig, Holger; Schwab, Katrin
1,1-Diboration of Isocyanides with [2]Borametalloarenophanes
Organometallics, 2010, 29, 934
4063453 CIFC19 H29 F3 N2 O8 Pd SP 1 21/c 115.6847; 10.1913; 15.3249
90; 94.045; 90
2443.5Vicente, José; Abad, José Antonio; López-Sáez, María-José; Jones, Peter G.
Carbopalladation of Maleate and Fumarate Esters and 1,1-Dimethylallene with Ortho-Substituted Aryl Palladium Complexes
Organometallics, 2010, 29, 409
4067300 CIFC19 H31 Cl2 Mo N3 O3 TiP -110.2058; 11.2671; 12.201
92.43; 108.638; 108.186
1247.16Lorber, Christian; Vendier, Laure
Imido−Titanium/Molybdenum Heterobimetallic Systems. Switching from η6-Arene to Fischer-Type Aminocarbene Complexes by Tuning Reactivity Conditions
Organometallics, 2010, 29, 1127
4067761 CIFC19 H32 Cl N2 RhP 1 21 110.4422; 11.988; 15.3266
90; 93.832; 90
1914.3Snead, David R.; Inagaki, Sebastien; Abboud, Khalil A.; Hong, Sukwon
Bis(2-alkylpyrrolidin-1-yl)methylidenes as Chiral Acyclic Diaminocarbene Ligands
Organometallics, 2010, 29, 1729
4065853 CIFC19 H33 B Cl F4 Fe N3 O2 P2P 1 21 18.0019; 29.868; 11.398
90; 107.434; 90
2599Benito-Garagorri, David; Alves, Luis Gonçalo; Veiros, Luis F.; Standfest-Hauser, Christina M.; Tanaka, Shinji; Mereiter, Kurt; Kirchner, Karl
Kinetically Controlled Formation of Octahedraltrans-Dicarbonyl Iron(II) PNP Pincer Complexes: The Decisive Role of Spin-State Changes§
Organometallics, 2010, 29, 4932
4065597 CIFC19 H33 F6 Ir N2 O9 S2P -112.4934; 14.2746; 16.3037
89.626; 88.616; 80.801
2869.3Feng, Yuee; Jiang, Bi; Boyle, Paul A.; Ison, Elon A.
Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes
Organometallics, 2010, 29, 2857
4065762 CIFC19 H34 Cl3 N P2 S2 Sn2P 1 21/c 128.75; 7.821; 28.33
90; 109.53; 90
6004Leung, Wing-Por; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heavier Group 14 Metal Compounds from 2,6-Lutidylbis(phosphoranosulfide)
Organometallics, 2010, 29, 1890
4066928 CIFC19 H35 B O2 Si3P 1 21 19.9177; 11.9574; 10.3355
90; 98.14; 90
1213.3Gluyas, Josef B. G.; Burschka, Christian; Kraft, Philip; Tacke, Reinhold
5,6-Disubstituted 1,2,3-Trisilaindanes as Silicon Analogues of Phantolide-Type Musk Odorants: Synthesis, Structure, Reactivity, and Olfactory Properties§
Organometallics, 2010, 29, 5897
4066487 CIFC19 H49 N2 Si3 TaP -111.58; 11.882; 20.84
90.005; 90.129; 94.043
2860Chen, Shu-Jian; Xue, Zi-Ling
Preparation of the Alkyl Complex Ta(═NSiMe3)[N(SiMe3)2](CH2But)2. Preferential Oxygen Insertion in Its Reaction with O2and a Ligand Exchange in the Alkoxide Ta(═NSiMe3)[N(SiMe3)2](OCH2But)2†
Organometallics, 2010, 29, 5579
4066956 CIFC19 H5 Fe Mn2 O13 PP -112.325; 14.204; 14.926
107.6; 106.384; 95.561
2341.7Colson, Adam C.; Whitmire, Kenton H.
Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH2and μ-PPhH Complexes FeMn(CO)8(μ-PH2) and FeMn(CO)8(μ-PPhH)‡
Organometallics, 2010, 29, 4611
4067735 CIFC19 H57 Si10C 1 2 116.16; 10.545; 22.036
90; 106.59; 90
3598.8Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4066964 CIFC19.33 H33.67 Cl1.67 N2 O2 PdP -111.1431; 18.3285; 18.4872
60.82; 88.523; 89.449
3295.5Vicente, José; Saura-Llamas, Isabel; García-López, José-Antonio; Bautista, Delia
Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†
Organometallics, 2010, 29, 4320
4065822 CIFC19.5 H23 Cl F6 N3 O4 Rh S2P 1 21/a 116.135; 17.906; 17.808
90; 104.503; 90
4981Ito, Masato; Tejima, Noriko; Yamamura, Masahiro; Endo, Yoshinori; Ikariya, Takao
Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes
Organometallics, 2010, 29, 1886
4066958 CIFC20 H10 Fe Mn O8 PP b c n16.774; 16.969; 15.385
90; 90; 90
4379.2Colson, Adam C.; Whitmire, Kenton H.
Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH2and μ-PPhH Complexes FeMn(CO)8(μ-PH2) and FeMn(CO)8(μ-PPhH)‡
Organometallics, 2010, 29, 4611
4066044 CIFC20 H11 Cr N O6P 1 21/n 16.6296; 11.197; 23.8845
90; 90.67; 90
1772.9Dubarle Offner, Julien; Schnakenburg, Gregor; Rose-Munch, Françoise; Rose, Eric; Dötz, Karl Heinz
Dibenzo[f,h]quinoline Cr(CO)3Complexes: Synthesis by Chromium-Templated Benzannulation, Cyclomanganation, and Haptotropic Chromium Migration
Organometallics, 2010, 29, 3308
4066062 CIFC20 H13 Fe2 N O6 S2P 1 21/n 114.073; 10.611; 15.801
90; 112.86; 90
2174.2Song, Li-Cheng; Mei, Shu-Zhen; Feng, Cui-Ping; Gong, Feng-Hua; Ge, Jian-Hua; Hu, Qing-Mei
Reactions of Monoanions [(μ-RE)(μ-E)Fe2(CO)6]−and Dianions [(μ-E)2Fe2(CO)6]2−(E = Se, S) with N-Substituted Benzimidoyl Chlorides, Leading to Novel Butterfly Fe/E Cluster Complexes†
Organometallics, 2010, 29, 5050
4066061 CIFC20 H13 Fe2 N O6 Se2P n a 217.8259; 18.98; 14.842
90; 90; 90
2204.6Song, Li-Cheng; Mei, Shu-Zhen; Feng, Cui-Ping; Gong, Feng-Hua; Ge, Jian-Hua; Hu, Qing-Mei
Reactions of Monoanions [(μ-RE)(μ-E)Fe2(CO)6]−and Dianions [(μ-E)2Fe2(CO)6]2−(E = Se, S) with N-Substituted Benzimidoyl Chlorides, Leading to Novel Butterfly Fe/E Cluster Complexes†
Organometallics, 2010, 29, 5050
4063481 CIFC20 H14C 1 2/c 123.555; 7.215; 19.145
90; 119.881; 90
2821Chan, Kai-Ting; Tsai, Yi-Hua; Lin, Wu-Shien; Wu, Jia-Rong; Chen, Shih-Jung; Liao, Fu-Xing; Hu, Ching-Han; Lee, Hon Man
Palladium Complexes with Carbene and Phosphine Ligands: Synthesis, Structural Characterization, and Direct Arylation Reactions between Aryl Halides and Alkynes
Organometallics, 2010, 29, 463-472
4067675 CIFC20 H16 Cl N3 O6 PdP 21 21 217.8948; 11.6296; 22.1963
90; 90; 90
2037.92Roiban, Gheorghe-Doru; Serrano, Elena; Soler, Tatiana; Contel, Maria; Grosu, Ion; Cativiela, Carlos; Urriolabeitia, Esteban P.
Ortho-Palladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones. Structure and Functionalization
Organometallics, 2010, 29, 1428
4067516 CIFC20 H17 Cl N O2 P Pd SP 1 21/c 113.3324; 10.8818; 14.5024
90; 114.223; 90
1918.77Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4066836 CIFC20 H18 N4 O3 PdP 1 21/n 113.2712; 10.2858; 14.3004
90; 105.392; 90
1882.1Warsink, Stefan; Chang, I-Hsin; Weigand, Jan J.; Hauwert, Peter; Chen, Jwu-Ting; Elsevier, Cornelis J.
NHC Ligands with a Secondary Pyrimidyl Donor for Electron-Rich Palladium(0) Complexes
Organometallics, 2010, 29, 4555
4065588 CIFC20 H19 Bi Re2P 1 21/c 120.054; 7.6906; 10.8238
90; 92.596; 90
1667.61Schiwon, Rafael; Knispel, Christina; Limberg, Christian
Heterometallic Complexes with Re−Bi Metal Bonds
Organometallics, 2010, 29, 1670
4066206 CIFC20 H20 B4 F4 Mn2 O4P 21 21 218.9357; 14.007; 17.48
90; 90; 90
2187.8Dai, Wei; Kim, Sang Bok; Pike, Robert D.; Cahill, Christopher L.; Sweigart, Dwight A.
Electrochemical Study of Manganese and Rhenium Arene Complexes (C6R6)M(CO)3+(R = Me, Et)§
Organometallics, 2010, 29, 5173
4066854 CIFC20 H20 Mn4 N O12 Se5C 1 2/c 135.472; 11.5808; 20.6387
90; 104.652; 90
8202.5Ho, Chia-Hua; Chu, Yen-Yi; Lin, Chien-Nan; Chen, Horng-Wen; Huang, Chung-Yi; Shieh, Minghuey
Selenium−Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations
Organometallics, 2010, 29, 4396
4066158 CIFC20 H20 O6 Sn2 W2P b c a12.7023; 12.7894; 14.3692
90; 90; 90
2334.35Bera, Holger; Braunschweig, Holger; Dörfler, Rainer; Kupfer, Thomas; Radacki, Krzysztof; Seeler, Fabian
Half-Sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-Bound Functional Stannyl Groups and Their Transformation intoAnsaComplexes†
Organometallics, 2010, 29, 5111
4067407 CIFC20 H21 O7 P WP -110.7147; 13.2996; 16.8471
75.655; 83.494; 70.934
2196.92Bode, Maren; Schnakenburg, Gregor; Daniels, Jörg; Marinetti, Angela; Streubel, Rainer
Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
Organometallics, 2010, 29, 656
4066461 CIFC20 H22 Cl2 HfP 1 21/c 112.6151; 12.3113; 13.3022
90; 117.275; 90
1836.24Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4066978 CIFC20 H22 Cl2 I2 N2 PdP 1 21/c 19.674; 19.8592; 12.649
90; 100.348; 90
2390.57Xu, Xiangya; Xu, Baochang; Li, Yongxin; Hong, Soon Hyeok
Abnormal N-Heterocyclic Carbene Promoted Suzuki−Miyaura Coupling Reaction: A Comparative Study
Organometallics, 2010, 29, 6343
4066460 CIFC20 H22 Cl2 ZrP 1 21/c 112.6867; 12.2749; 13.3417
90; 117.529; 90
1842.44Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4067134 CIFC20 H23 Br Fe O SiP 1 21/c 113.042; 12.521; 12.967
90; 118.354; 90
1863.5Schuecker, Raffael; Weissensteiner, Walter; Mereiter, Kurt; Lotz, Matthias; Spindler, Felix
Synthesis of Ferrocenyl Diphosphine Ligands: Substitution of α-Methoxy or α-Dimethylamino Groups by Phosphines. Retention versus Inversion: A Stereochemical Study
Organometallics, 2010, 29, 6443
4065792 CIFC20 H23 Cl F6 N3 P RuP 1 21 17.9159; 13.188; 10.8503
90; 110.163; 90
1063.3Romain, Charles; Gaillard, Sylvain; Elmkaddem, Mohammed K.; Toupet, Loïc; Fischmeister, Cédric; Thomas, Christophe M.; Renaud, Jean-Luc
New Dipyridylamine Ruthenium Complexes for Transfer Hydrogenation of Aryl Ketones in Water
Organometallics, 2010, 29, 1992
4065696 CIFC20 H23 Cl N2 O3 PdP 1 21/n 18.9235; 13.3711; 17.1832
90; 104.841; 90
1981.9Vicente, José; Arcas, Aurelia; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Organometallic Complexes of Palladium(II) Derived from 2,6-Diacetylpyridine Dimethylketal
Organometallics, 2010, 29, 3066
4065697 CIFC20 H23 Cl N2 O3 PdP -19.5126; 9.9473; 11.0615
66.547; 85.846; 84.091
954.55Vicente, José; Arcas, Aurelia; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Organometallic Complexes of Palladium(II) Derived from 2,6-Diacetylpyridine Dimethylketal
Organometallics, 2010, 29, 3066
4066194 CIFC20 H23 Fe2 N2 O3 PP 1 21/n 112.018; 11.601; 14.223
90; 91.31; 90
1982.5Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Reactions of the Phosphinidene-Bridged Complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph, 2,4,6-C6H2tBu3) with Diazoalkanes. Formation and Rearrangements of Phosphadiazadiene-Bridged Derivatives†
Organometallics, 2010, 29, 5140
4067409 CIFC20 H23 O8 P WP 1 21/n 111.4434; 14.0714; 14.2623
90; 101.036; 90
2254.11Bode, Maren; Schnakenburg, Gregor; Daniels, Jörg; Marinetti, Angela; Streubel, Rainer
Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
Organometallics, 2010, 29, 656
4066195 CIFC20 H24 B F4 Fe2 N2 O3 PP 21 21 2110.723; 12.889; 16.683
90; 90; 90
2305.7Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Reactions of the Phosphinidene-Bridged Complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph, 2,4,6-C6H2tBu3) with Diazoalkanes. Formation and Rearrangements of Phosphadiazadiene-Bridged Derivatives†
Organometallics, 2010, 29, 5140
4067316 CIFC20 H24 Cl N3 O PtP -17.8325; 10.162; 14.027
69.53; 85.66; 68.29
969.92O, Wylie W. N.; Lough, Alan J.; Morris, Robert H.
Palladium(II) and Platinum(II) Complexes Featuring a Nitrile-Functionalized N-Heterocyclic Carbene Ligand
Organometallics, 2010, 29, 570
4065823 CIFC20 H24 F6 N3 O4 Rh S2P 1 21/c 115.097; 9.169; 18.188
90; 99.961; 90
2479.7Ito, Masato; Tejima, Noriko; Yamamura, Masahiro; Endo, Yoshinori; Ikariya, Takao
Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes
Organometallics, 2010, 29, 1886
4066777 CIFC20 H24 Fe OP 1 21/c 17.439; 13.6225; 15.4467
90; 101.816; 90
1532.17Schaarschmidt, Dieter; Lang, Heinrich
Copper(I)-Mediated Synthesis of Ferrocenyl Alkyl Ethers†
Organometallics, 2010, 29, 4196
4066651 CIFC20 H26 Bi S2 Si2P 1 21/n 114.7703; 6.5197; 25.225
90; 100.969; 90
2384.7Ohshita, Joji; Matsui, Shigenori; Yamamoto, Roh; Mizumo, Tomonobu; Ooyama, Yousuke; Harima, Yutaka; Murafuji, Toshihiro; Tao, Keisuke; Kuramochi, Yusuke; Kaikoh, Takashi; Higashimura, Hideyuki
Synthesis of Dithienobismoles as Novel Phosphorescence Materials
Organometallics, 2010, 29, 3239
4066938 CIFC20 H26 Cl N2 RhP 21 21 218.4515; 14.4911; 14.7224
90; 90; 90
1803.07Magriz, Antonio; Gómez-Bujedo, Silvia; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes
Organometallics, 2010, 29, 5941
4066851 CIFC20 H26 Co N2 O2 SP b c a14.704; 14.0265; 18.9878
90; 90; 90
3916.15Vélez, Carmen L; Markwick, Phineus R. L.; Holland, Ryan L.; Dipasquale, Antonio G.; Rheingold, Arnold L.; O'Connor, Joseph M
Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes: Synthesis, Solid-State Structures, and Quantum Chemistry Calculations.
Organometallics, 2010, 29, 6695-6702
4066850 CIFC20 H26 Co N2 SP 1 21/c 111.024; 11.152; 16.276
90; 104.56; 90
1937Vélez, Carmen L; Markwick, Phineus R. L.; Holland, Ryan L.; Dipasquale, Antonio G.; Rheingold, Arnold L.; O'Connor, Joseph M
Cobalt 1,3-Diisopropyl-1H-imidazol-2-ylidene Complexes: Synthesis, Solid-State Structures, and Quantum Chemistry Calculations.
Organometallics, 2010, 29, 6695-6702
4065824 CIFC20 H26 F6 N3 O5 Rh S2P 1 21/n 110.416; 13.126; 19.447
90; 91.56; 90
2658Ito, Masato; Tejima, Noriko; Yamamura, Masahiro; Endo, Yoshinori; Ikariya, Takao
Synthesis and Structure of Protic Amine Tethered Rhodium(III) Peralkylcyclopentadienyl Complexes
Organometallics, 2010, 29, 1886
4066778 CIFC20 H26 Fe OP 21 21 217.5316; 14.2548; 15.2078
90; 90; 90
1632.73Schaarschmidt, Dieter; Lang, Heinrich
Copper(I)-Mediated Synthesis of Ferrocenyl Alkyl Ethers†
Organometallics, 2010, 29, 4196
4067543 CIFC20 H26 N2 Se ZnP -19.7435; 10.2851; 11.3486
106.45; 98.432; 111.941
970.13Dochnahl, Maximilian; Löhnwitz, Karolin; Lühl, Anja; Pissarek, Jens-Wolfgang; Biyikal, Mustafa; Roesky, Peter W.; Blechert, Siegfried
Functionalized Aminotroponiminate Zinc Complexes as Catalysts for the Intramolecular Hydroamination of Alkenes
Organometallics, 2010, 29, 2637
4067047 CIFC20 H27 Cl N RhP -17.5294; 8.7262; 15.273
90.179; 95.679; 115.261
901.9Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066963 CIFC20 H27 Cl N2 O PdP 1 21/c 18.2796; 17.1677; 27.9086
90; 90.535; 90
3966.8Vicente, José; Saura-Llamas, Isabel; García-López, José-Antonio; Bautista, Delia
Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†
Organometallics, 2010, 29, 4320
4066776 CIFC20 H28 Fe OP 1 21 15.7938; 8.0913; 18.6108
90; 94.025; 90
870.31Schaarschmidt, Dieter; Lang, Heinrich
Copper(I)-Mediated Synthesis of Ferrocenyl Alkyl Ethers†
Organometallics, 2010, 29, 4196
4067560 CIFC20 H29 B Cl2 N7 O2 P WP -19.235; 14.198; 30.968
98.639; 96.143; 102.731
3874.2Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4067565 CIFC20 H29 B N7 O2 P WC 1 2/c 130.398; 8.582; 20.3
90; 112.994; 90
4875Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4066987 CIFC20 H29 N3 NiP 1 21/n 18.123; 13.87; 16.295
90; 93.43; 90
1832.6Breitenfeld, Jan; Vechorkin, Oleg; Corminboeuf, Clémence; Scopelliti, Rosario; Hu, Xile
Why Are (NN2)Ni Pincer Complexes Active for Alkyl−Alkyl Coupling: β-H Elimination Is Kinetically Accessible but Thermodynamically Uphill
Organometallics, 2010, 29, 3686
4067564 CIFC20 H31 B Cl2 N7 O4 P WP 1 21/n 112.401; 14.607; 15.174
90; 101.156; 90
2696.7Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4065964 CIFC20 H32 Cl2 Rh2P 1 21/c 111.0987; 14.4483; 12.7931
90; 94.926; 90
2043.9Jellema, Erica; Jongerius, Anna L.; Walters, Annemarie J. C.; Smits, Jan M. M.; Reek, Joost N. H.; de Bruin, Bas
Ligand Design in Rh(diene)-Mediated “Carbene” Polymerization; Efficient Synthesis of High-Mass, Highly Stereoregular, and Fully Functionalized Carbon-Chain Polymers
Organometallics, 2010, 29, 2823
4067573 CIFC20 H32 Cl4 N2 RuP 1 21/n 110.0156; 17.2504; 13.6315
90; 92.134; 90
2353.52Zhang, Yao; Chen, Cheng; Ghosh, Subhash Chandra; Li, Yongxin; Hong, Soon Hyeok
Well-Defined N-Heterocyclic Carbene Based Ruthenium Catalysts for Direct Amide Synthesis from Alcohols and Amines
Organometallics, 2010, 29, 1374
4067292 CIFC20 H32 N2 ZnC 1 2/c 115.794; 7.8917; 17.541
90; 115.96; 90
1965.7Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4067293 CIFC20 H32 N2 ZnP -110.216; 10.645; 11.735
75.73; 65.33; 65.33
1049.8Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4065854 CIFC20 H33 Cl F3 Fe N3 O5 P2 SP 1 21 111.3222; 10.2793; 12.6768
90; 111.342; 90
1374.21Benito-Garagorri, David; Alves, Luis Gonçalo; Veiros, Luis F.; Standfest-Hauser, Christina M.; Tanaka, Shinji; Mereiter, Kurt; Kirchner, Karl
Kinetically Controlled Formation of Octahedraltrans-Dicarbonyl Iron(II) PNP Pincer Complexes: The Decisive Role of Spin-State Changes§
Organometallics, 2010, 29, 4932
4067567 CIFC20 H33 N3 O WP -113.4169; 14.0093; 15.6949
96.891; 102.975; 117.591
2460.6Semproni, Scott P.; McNeil, W. Stephen; Baillie, Rhett A.; Patrick, Brian O.; Campana, Charles F.; Legzdins, Peter
Ground-State Electronic Asymmetry in Cp*W(NO)(η1-isonitrile)2Complexes
Organometallics, 2010, 29, 867
4067188 CIFC20 H37 Cl Ni P2P b c a15.9009; 14.0408; 19.9763
90; 90; 90
4459.94Smith, Erin E.; Du, Guodong; Fanwick, Phillip E.; Abu-Omar, Mahdi M.
Dehydrocoupling of Organosilanes with a Dinuclear Nickel Hydride Catalyst and Isolation of a Nickel Silyl Complex
Organometallics, 2010, 29, 6527
4066089 CIFC20 H37 Mo N O2P -18.6671; 10.2287; 13.5257
103.417; 105.869; 100.361
1083.32Graham, Peter M.; Buschhaus, Miriam S. A.; Baillie, Rhett A.; Semproni, Scott P.; Legzdins, Peter
Hydroperoxide-Initiated Intramolecular Insertions of NO into Metal−Carbon Bonds†
Organometallics, 2010, 29, 5068
4067174 CIFC20 H37 N2 TiP 1 21/n 115.717; 16.961; 17.638
90; 115.06; 90
4259.3Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4066698 CIFC20 H38 Cl2 N6 O5 P2 Rh S2P 1 21/n 19.6662; 12.841; 22.4541
90; 92.357; 90
2784.73Sternberg, Michelle; Suresh, Cherumuttathu H.; Mohr, Fabian
2-Thia-1,3,5-triaza-7-phosphaadamantane-2,2-dioxide Revisited: Computational and Experimental Studies of a Neglected Phosphine
Organometallics, 2010, 29, 3922
4066355 CIFC20 H41 Cl N P2 RhP 1 n 110.9515; 14.1024; 15.331
90; 97.331; 90
2348.4Urtel, Heiko; Meier, Claudia; Rominger, Frank; Hofmann, Peter
Neutralcis-Alkyl Olefin Rhodium(I) Complexes: Models of Intermediates in Late Transition Metal Olefin Polymerization with Surprising Structure†
Organometallics, 2010, 29, 5496
4065673 CIFC20 H41 Ge I N2 O2P 1 21/c 111.821; 13.765; 15.378
90; 92.14; 90
2500.5Rupar, Paul A.; Staroverov, Viktor N.; Baines, Kim M.
Reactivity Studies of N-Heterocyclic Carbene Complexes of Germanium(II)†
Organometallics, 2010, 29, 4871
4067257 CIFC20 H50 Al2 Cl4 N2 O Si2 UC 1 2/c 121.767; 9.263; 20.422
90; 115.757; 90
3708.5Hayes, Cassandra E.; Leznoff, Daniel B.
Diamido-Ether Uranium(IV) Alkyl Complexes as Single-Component Ethylene Polymerization Catalysts
Organometallics, 2010, 29, 767
4066400 CIFC20 H52 N4 O2 Zn4P -18.0653; 9.5037; 10.5151
93.155; 112.003; 100.315
728.58Hollingsworth, Nathan; Johnson, Andrew L.; Kingsley, Andrew; Kociok-Köhn, Gabriele; Molloy, Kieran C.
Structural Study of the Reaction of Methylzinc Amino Alcoholates with Oxygen
Organometallics, 2010, 29, 3318
4066267 CIFC20 H60 Ge9C 1 2/c 117.164; 9.2516; 24.439
90; 106.31; 90
3724.6Hlina, Johann; Baumgartner, Judith; Marschner, Christoph
Polygermane Building Blocks†
Organometallics, 2010, 29, 5289
4067430 CIFC21 H12 Fe4 O16 S4P -19.371; 12.755; 14.676
72.226; 72.158; 66.825
1500.5Song, Li-Cheng; Liu, Xu-Feng; Ming, Jiang-Bo; Ge, Jian-Hua; Xie, Zhao-Jun; Hu, Qing-Mei
Reactions Starting from Diiron Propanedithiolate [(μ-SCH2)2CH(OH)]Fe2(CO)6Leading to Malonyl-, PPh3-, and [60]Fullerene-Containing Compounds Relevant to the Active Site of FeFe-Hydrogenases
Organometallics, 2010, 29, 610
4066638 CIFC21 H13 N O5 Ru2P -19.016; 9.2492; 13.378
70.03; 79.719; 73.811
1002.7Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066035 CIFC21 H14 Cr O6P 21 21 217.3508; 11.578; 44.049
90; 90; 90
3748.9Hegele, Peter; Santhamma, Bindu; Schnakenburg, Gregor; Fröhlich, Roland; Kataeva, Olga; Nieger, Martin; Kotsis, Konstantinos; Neese, Frank; Dötz, Karl Heinz
Hydroquinoid Chromium Complexes Bearing an Acyclic Conjugated Bridge: Chromium-Templated Synthesis, Molecular Structure, and Haptotropic Metal Migration
Organometallics, 2010, 29, 6172
4066433 CIFC21 H14 F6 N2P 1 21/n 113.0834; 10.4979; 14.0277
90; 92.188; 90
1925.28Enk, Barbara; Eisenstecken, Daniela; Kopacka, Holger; Wurst, Klaus; Müller, Thomas; Pevny, Florian; Winter, Rainer F.; Bildstein, Benno
Doubly N-Functionalized Pentafulvenes and Redox-Responsive [N,N]- and [N,C,N]-Pincer Bis(imidoyl)pentamethylruthenocene Metalloligands
Organometallics, 2010, 29, 3169
4066063 CIFC21 H15 Fe2 N O6 S2P -111.816; 16.939; 24.318
70.94; 88.46; 87.73
4596.3Song, Li-Cheng; Mei, Shu-Zhen; Feng, Cui-Ping; Gong, Feng-Hua; Ge, Jian-Hua; Hu, Qing-Mei
Reactions of Monoanions [(μ-RE)(μ-E)Fe2(CO)6]−and Dianions [(μ-E)2Fe2(CO)6]2−(E = Se, S) with N-Substituted Benzimidoyl Chlorides, Leading to Novel Butterfly Fe/E Cluster Complexes†
Organometallics, 2010, 29, 5050
4065678 CIFC21 H16 B F4 Mn O5 SP 1 21/c 110.583; 39.81; 10.614
90; 97.09; 90
4438Cetiner, Derya; Norel, Lucie; Tranchier, Jean-Philippe; Rose-Munch, Françoise; Rose, Eric; Herson, Patrick
Synthesis and Reactivity of (η5-Hydroxyalkylcyclohexadienyl)Mn(CO)3Complexes
Organometallics, 2010, 29, 1778
4067085 CIFC21 H17 F3 N6 O PdP -17.7528; 11.5739; 12.441
74.197; 89.651; 72.023
1017.99Sie, Ming-Han; Hsieh, Yuan-Hsin; Tsai, Yi-Hua; Wu, Jia-Rong; Chen, Shih-Jung; Kumar, P. Vijaya; Lii, Jenn-Huei; Lee, Hon Man
A Heteroleptic Palladium(II) Complex Containing a Bidentate Carbene/Amido Ligand and 3-(Trifluoromethyl)-5-(2-pyridyl)pyrazolate: Fast Catalyst Activation in the Heck Coupling Reaction
Organometallics, 2010, 29, 6473
4067088 CIFC21 H17 F3 N6 O PtP -17.837; 11.7; 12.451
74.083; 88.881; 71.196
1036.3Sie, Ming-Han; Hsieh, Yuan-Hsin; Tsai, Yi-Hua; Wu, Jia-Rong; Chen, Shih-Jung; Kumar, P. Vijaya; Lii, Jenn-Huei; Lee, Hon Man
A Heteroleptic Palladium(II) Complex Containing a Bidentate Carbene/Amido Ligand and 3-(Trifluoromethyl)-5-(2-pyridyl)pyrazolate: Fast Catalyst Activation in the Heck Coupling Reaction
Organometallics, 2010, 29, 6473
4066672 CIFC21 H18 Br F3 O7 Ru2 SP -113.4275; 13.843; 15.539
72.481; 74.723; 75.042
2606.4Chin, Robert M.; Simonson, Andrew; Mauldin, Joshua; Criswell, Jared; Brennessel, William
Syntheses and Characterization of Ruthenium Complexes Containing a Doubly Linked Dicyclopentadienyl Ligand and Acetonitrile Ligands
Organometallics, 2010, 29, 3868
4067580 CIFC21 H19 B3 N2 O3P 1 21/c 116.5925; 10.3829; 11.7514
90; 95.687; 90
2014.5Mutseneck, Elena V.; Reus, Christian; Schödel, Frauke; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactions of [Cp*RuCl]4and [(p-cymene)RuCl2]2with the Tridentate Ligand [Ph(pz)B(μ-O)(μ-pz)B(pz)Ph]−
Organometallics, 2010, 29, 966
4067019 CIFC21 H20 B Cl F9 PP 1 21/c 110.0403; 12.7948; 17.9642
90; 104.693; 90
2232.3Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4067020 CIFC21 H20 B F10 PP 1 21/c 18.8871; 15.9516; 15.7683
90; 98.7; 90
2209.6Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4066596 CIFC21 H20 N2 O2 PdP 1 21/c 115.313; 7.7347; 15.3771
90; 98.874; 90
1799.5Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Abellán-López, Antonio; Bautista, Delia
Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†
Organometallics, 2010, 29, 5693
4067023 CIFC21 H22 B F8 PP 1 21/n 18.4845; 15.6453; 16.591
90; 101.627; 90
2157.1Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4063446 CIFC21 H24 Au Cl3 N2P 21 21 2110.635; 13.808; 15.447
90; 90; 90
2268.4Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4067540 CIFC21 H24 Cl F4 N O2 SiP 1 21 118.074; 7.0906; 18.197
90; 110.189; 90
2188.8Tacke, Reinhold; Nguyen, Binh; Burschka, Christian; Lippert, W. Peter; Hamacher, Alexandra; Urban, Christian; Kassack, Matthias U.
Sila-Trifluperidol, a Silicon Analogue of the Dopamine (D2) Receptor Antagonist Trifluperidol: Synthesis and Pharmacological Characterization
Organometallics, 2010, 29, 1652
4067026 CIFC21 H25 B Cl F4 PP b c a12.3167; 17.5802; 19.4216
90; 90; 90
4205.4Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4066671 CIFC21 H25 Mn O5P 1 21 112.152; 27.425; 12.8037
90; 103.796; 90
4144Eloi, Antoine; Rose-Munch, Françoise; Rose, Eric; Pille, Ariane; Lesot, Philippe; Herson, Patrick
Cationic Planar Chiral (η6-Arene)Mn(CO)3+Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+Complexes
Organometallics, 2010, 29, 3876
4083387 CIFC21 H25 Mn O5P 1 21 17.3987; 9.934; 13.8457
90; 91.739; 90
1017.2Eloi, Antoine; Rose-Munch, Françoise; Rose, Eric; Pille, Ariane; Lesot, Philippe; Herson, Patrick
Cationic Planar Chiral (η6-Arene)Mn(CO)3+Complexes: Resolution, NMR Study in Chiral-Oriented Solvents, and Applications to the Enantioselective Synthesis of 4-Substituted Cyclohexenones and (η6-Phosphinoarene)Mn(CO)3+Complexes
Organometallics, 2010, 29, 3876
4065956 CIFC21 H26 Cl F6 N4 Ni PP 21 21 218.067; 14.0748; 20.5513
90; 90; 90
2333.4Newman, Paul D.; Cavell, Kingsley J.; Kariuki, Benson M.
Metal Complexes of Chiral NHCs Containing a Fused Six- and Seven-Membered Central Ring
Organometallics, 2010, 29, 2724
4065831 CIFC21 H26 N2 ZnP -19.4077; 9.4416; 21.4629
92.702; 93.216; 98.523
1879.4Drouin, Frédéric; Oguadinma, Paul O.; Whitehorne, Todd J. J.; Prud’homme, Robert E.; Schaper, Frank
Lactide Polymerization with Chiral β-Diketiminate Zinc Complexes
Organometallics, 2010, 29, 2139
4065952 CIFC21 H27 F6 N4 PP 1 21 110.573; 11.853; 18.613
90; 100.724; 90
2291.87Newman, Paul D.; Cavell, Kingsley J.; Kariuki, Benson M.
Metal Complexes of Chiral NHCs Containing a Fused Six- and Seven-Membered Central Ring
Organometallics, 2010, 29, 2724
4067095 CIFC21 H28 B Mo N7 O2 SP 1 21/n 111.2972; 17.1306; 14.0712
90; 107.119; 90
2602.52Colebatch, Annie L.; Hill, Anthony F.; Shang, Rong; Willis, Anthony C.
Synthesis of a Thiocarbamoyl Alkylidyne Complex and Caveats Associated with the Use of [Mo(≡CLi)(CO)2(Tp*)] (Tp* = Hydrotris(3,5-dimethylpyrazol-1-yl)borate)
Organometallics, 2010, 29, 6482
4065746 CIFC21 H28 Co2 O7 SiP 1 21 112.7295; 10.6561; 17.9422
90; 90.754; 90
2433.6Moore, Angela; Ortin, Yannick; Müller-Bunz, Helge; McGlinchey, Michael J.
Alkynyl-Dicobalt Hexacarbonyl Complexes of Menthyl Cations: Isolobal Substitution of [Co(CO)3]+by Fe(CO)3as a Structural Model†
Organometallics, 2010, 29, 4882
4066366 CIFC21 H28 N2P 1 21/n 110.8009; 12.2469; 14.077
90; 92.447; 90
1860.4Collins, Mary S.; Rosen, Evelyn L.; Lynch, Vincent M.; Bielawski, Christopher W.
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
Organometallics, 2010, 29, 3047
4066557 CIFC21 H29 B N3 O3 TlP 1 21/c 110.479; 13.706; 16.172
90; 100.133; 90
2286.5Ho, Hung-An; Dunne, James F.; Ellern, Arkady; Sadow, Aaron D.
Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition
Organometallics, 2010, 29, 4105
4067339 CIFC21 H29 I N2P 1 21/n 110.6781; 11.0004; 17.8963
90; 90.41; 90
2102.1Rosen, Evelyn L.; Sung, Daphne H.; Chen, Zheng; Lynch, Vincent M.; Bielawski, Christopher W.
Olefin Metathesis Catalysts Containing Acyclic Diaminocarbenes
Organometallics, 2010, 29, 250
4067626 CIFC21 H31 B F3 N8 O4 P S WP -18.3085; 12.2187; 14.4688
93.2828; 98.3464; 94.3924
1445.55Salomon, Rebecca J.; Todd, Michael A.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Single and Double Electrophilic Addition Reactions to the Aniline Ring Promoted by a Tungsten π-Base
Organometallics, 2010, 29, 707
4065599 CIFC21 H31 F6 Ir N2 O6P -18.7435; 11.7537; 13.1222
74.617; 84.887; 82.879
1287.98Feng, Yuee; Jiang, Bi; Boyle, Paul A.; Ison, Elon A.
Effect of Ancillary Ligands and Solvents on H/D Exchange Reactions Catalyzed by Cp*Ir Complexes
Organometallics, 2010, 29, 2857
4065695 CIFC21 H32 Cl N3 O3 PdP c a 2117.7339; 16.8224; 16.5342
90; 90; 90
4932.6Vicente, José; Arcas, Aurelia; Juliá-Hernández, Francisco; Bautista, Delia; Jones, Peter G.
Organometallic Complexes of Palladium(II) Derived from 2,6-Diacetylpyridine Dimethylketal
Organometallics, 2010, 29, 3066
4067472 CIFC21 H33 B7 Fe N O4 PP 1 21/c 117.9304; 8.372; 18.5982
90; 101.997; 90
2730.86Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067658 CIFC21 H33 N3 SiP 1 21/n 16.438; 26.097; 12.577
90; 96.66; 90
2098.8Zheng, Pengzhi; Hong, Jianquan; Liu, Ruiting; Zhang, Zhengxing; Pang, Zhen; Weng, Linhong; Zhou, Xigeng
Synthesis and Reactivities of Guanidinate Dianion Complexes of Heterobimetallic Lanthanide−Lithium Cp2Ln[(CyN)2CNPh]Li(THF)3
Organometallics, 2010, 29, 1284
4066716 CIFC21 H34 F6 N6 P RhP -114.2261; 17.9423; 20.972
77.0719; 82.9578; 86.4399
5174.7Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4066349 CIFC21 H37 Rh SiP -18.8037; 9.6272; 13.0123
79.33; 81.354; 82.559
1065.59Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
Organometallics, 2010, 29, 5481
4066927 CIFC21 H41 F6 N O2 Os P2 SiP 1 21/c 130.456; 12.727; 14.731
90; 90.44; 90
5709.8Baya, Miguel; Esteruelas, Miguel A.; Oñate, Enrique
Efficient Concatenation of C═C Reduction, C−H Bond Activation, and C−C and C−N Coupling Reactions on Osmium: Assembly of Two Allylamines and an Allene
Organometallics, 2010, 29, 6298
4067590 CIFC21 H46 N6 TiP 1 21/c 112.776; 11.125; 18.248
90; 105.929; 90
2494.1Panda, Tarun K.; Tsurugi, Hayato; Pal, Kuntal; Kaneko, Hiroshi; Mashima, Kazushi
Highly Reactive Metal−Nitrogen Bond Induced C−H Bond Activation and Azametallacycle Formation
Organometallics, 2010, 29, 34
4066933 CIFC21 H46 O3 Si5P -19.8311; 11.0157; 15.9346
79.739; 84.82; 63.886
1524.6Berkefeld, André; Troegel, Dennis; Burschka, Christian; Tacke, Reinhold
Synthesis and Characterization of {[Tris(trimethylsilyl)silyl]methyl}silanes of the Formula Type Me4−nSi[CH2Si(SiMe3)3]n(n= 1−3) and Derivatives
Organometallics, 2010, 29, 4548
4066265 CIFC21 H51 Ge4 K O6P 1 21/c 19.984; 17.401; 20.229
90; 103.34; 90
3419.6Hlina, Johann; Baumgartner, Judith; Marschner, Christoph
Polygermane Building Blocks†
Organometallics, 2010, 29, 5289
4066632 CIFC21 H9 N O7 Ru3P -17.1276; 9.6244; 16.457
104.779; 97.07; 103.93
1038.8Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4063451 CIFC21.73 H27.45 Au Cl4.45 N2P 1 21/c 18.419; 15.8293; 19.2834
90; 94.75; 90
2561.01Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4066056 CIFC22 H13 Au Cl F4 PP 1 21/n 112.395; 9.059; 17.9686
90; 108.073; 90
1918.08Stanek, Kyrill; Czarniecki, Barbara; Aardoom, Raphael; Rüegger, Heinz; Togni, Antonio
Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
Organometallics, 2010, 29, 2540
4066652 CIFC22 H13 Bi S2P 1 21/a 118.3723; 5.1602; 19.2084
90; 95.2419; 90
1813.4Ohshita, Joji; Matsui, Shigenori; Yamamoto, Roh; Mizumo, Tomonobu; Ooyama, Yousuke; Harima, Yutaka; Murafuji, Toshihiro; Tao, Keisuke; Kuramochi, Yusuke; Kaikoh, Takashi; Higashimura, Hideyuki
Synthesis of Dithienobismoles as Novel Phosphorescence Materials
Organometallics, 2010, 29, 3239
4066049 CIFC22 H13 F4 PC 1 2/c 130.75; 6.9862; 15.815
90; 100.295; 90
3342.8Stanek, Kyrill; Czarniecki, Barbara; Aardoom, Raphael; Rüegger, Heinz; Togni, Antonio
Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
Organometallics, 2010, 29, 2540
4066489 CIFC22 H15 N O2P 1 21/n 110.102; 13.9441; 12.1262
90; 97.269; 90
1694.41Chu, Jean-Ho; Lin, Pi-Shan; Wu, Ming-Jung
Palladium(II)-CatalyzedOrthoArylation of 2-Phenoxypyridines with Potassium Aryltrifluoroborates via C−H Functionalization
Organometallics, 2010, 29, 4058
4065688 CIFC22 H17 Cl2 F N2 O TiP -19.3284; 10.682; 12.068
97.12; 94.93; 96.97
1178.2Liu, Shaofeng; Sun, Wen-Hua; Zeng, Yanning; Wang, Deligeer; Zhang, Wenjuan; Li, Yan
Syntheses, Characterization, and Ethylene (Co-)Polymerization Screening of Amidate Half-Titanocene Dichlorides
Organometallics, 2010, 29, 2459
4067415 CIFC22 H18 Cl2 ZrP 21 21 218.4432; 14.5666; 14.9388
90; 90; 90
1837.3Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2Systems
Organometallics, 2010, 29, 860
4066692 CIFC22 H18 F3 N O2 PtP -18.5878; 10.7454; 11.5209
62.888; 86.95; 84.698
942.2Velusamy, Marappan; Chen, Chih-Hsin; Wen, Yuh S.; Lin, Jiann T.; Lin, Chao-Chen; Lai, Chin-Hung; Chou, Pi-Tai
Cyclometalated Platinum(II) Complexes of Lepidine-Based Ligands as Highly Efficient Electrophosphors
Organometallics, 2010, 29, 3912
4066756 CIFC22 H18 N2 VP -17.9771; 14.1609; 15.86
89.351; 87.114; 75.525
1732.5Jordan, Markus; Saak, Wolfgang; Haase, Detlev; Beckhaus, Rüdiger
Bridging Azines in the Coordination Sphere of Low-Valent Vanadocene Derivatives†
Organometallics, 2010, 29, 5859
4065698 CIFC22 H19 O5 P Si WP 1 21 19.5783; 9.7533; 12.4712
90; 90.589; 90
1165Panichakul, Duanghathai; Lim, Yi Wee; Mathey, François
Reactivity of 2-Silyl- and 2-Stannyl-Substituted Phosphirenes
Organometallics, 2010, 29, 1985
4067022 CIFC22 H20 B F12 O3 P SP 1 21/n 110.897; 14.7165; 16.2526
90; 92.259; 90
2604.3Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4066521 CIFC22 H21 Cl Fe O2P 1 21/c 111.333; 11.8267; 26.8044
90; 93.889; 90
3584.37Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4063478 CIFC22 H21 Cl2 N3 PdP 1 21/n 19.0547; 25.3595; 9.7807
90; 111.778; 90
2085.6Chan, Kai-Ting; Tsai, Yi-Hua; Lin, Wu-Shien; Wu, Jia-Rong; Chen, Shih-Jung; Liao, Fu-Xing; Hu, Ching-Han; Lee, Hon Man
Palladium Complexes with Carbene and Phosphine Ligands: Synthesis, Structural Characterization, and Direct Arylation Reactions between Aryl Halides and Alkynes
Organometallics, 2010, 29, 463-472
4066100 CIFC22 H21 N Pt SP -18.7046; 10.154; 11.044
69.73; 80.06; 88.4
901.4Nabavizadeh, S. Masoud; Haghighi, Mohsen Golbon; Esmaeilbeig, Ahmad R.; Raoof, Fatemeh; Mandegani, Zeinab; Jamali, Sirous; Rashidi, Mehdi; Puddephatt, Richard J.
Assembly of Symmetrical or Unsymmetrical Cyclometalated Organoplatinum Complexes through a Bridging Diphosphine Ligand†
Organometallics, 2010, 29, 4893
4063477 CIFC22 H23 Cl2 N3 PdP 1 21/c 119.941; 10.116; 22.057
90; 93.222; 90
4442Chan, Kai-Ting; Tsai, Yi-Hua; Lin, Wu-Shien; Wu, Jia-Rong; Chen, Shih-Jung; Liao, Fu-Xing; Hu, Ching-Han; Lee, Hon Man
Palladium Complexes with Carbene and Phosphine Ligands: Synthesis, Structural Characterization, and Direct Arylation Reactions between Aryl Halides and Alkynes
Organometallics, 2010, 29, 463-472
4067027 CIFC22 H23 Cl2 O P SP -18.3935; 10.3039; 12.5565
91.016; 92.609; 103.638
1053.79Duffy, Matthew P.; Lin, Yuhan; Ho, Feny; Mathey, Francois
Synthesis and Chemistry of 2-Phosphafurans
Organometallics, 2010, 29, 5757
4067411 CIFC22 H23 Cl3 D O10 P WP 1 21/n 112.0292; 18.2659; 12.725
90; 98.664; 90
2764.08Bode, Maren; Schnakenburg, Gregor; Daniels, Jörg; Marinetti, Angela; Streubel, Rainer
Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
Organometallics, 2010, 29, 656
4067069 CIFC22 H23 F12 N P2 Ru S2P -19.391; 10.564; 15.151
96.954; 105.272; 105.829
1364.5Singh, Pradhumn; Singh, Ajai K.
Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Organometallics, 2010, 29, 6433
4067539 CIFC22 H24 Cl F4 N O2C 1 2/c 137.5474; 7.01; 15.8691
90; 91.993; 90
4174.3Tacke, Reinhold; Nguyen, Binh; Burschka, Christian; Lippert, W. Peter; Hamacher, Alexandra; Urban, Christian; Kassack, Matthias U.
Sila-Trifluperidol, a Silicon Analogue of the Dopamine (D2) Receptor Antagonist Trifluperidol: Synthesis and Pharmacological Characterization
Organometallics, 2010, 29, 1652
4066362 CIFC22 H24 Cl2 Co N2 O2P 1 21/n 115.555; 10.169; 28.108
90; 90.88; 90
4445.6Volpe, Emily C.; Manke, David R.; Bartholomew, Erika R.; Wolczanski, Peter T.; Lobkovsky, Emil B.
Aryl−Oxazoline Chelates of First-Row Transition Metals: Structures of {κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}FeCl(py) and [(κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}Cr(μ-Cl)]2‡
Organometallics, 2010, 29, 6642
4066222 CIFC22 H24 Cl2 P2 PdP 1 21 18.6884; 14.7236; 9.3534
90; 109.031; 90
1131.13Chen, Shuli; Ng, Joseph Kok-Peng; Pullarkat, Sumod A.; Liu, Fengli; Li, Yongxin; Leung, Pak-Hing
Asymmetric Synthesis of New Diphosphines and Pyridylphosphines via a Kinetic Resolution Process Promoted and Controlled by a Chiral Palladacycle
Organometallics, 2010, 29, 3374
4066886 CIFC22 H24.67 B0.67P -112.395; 14.662; 15.449
83.122; 81.769; 86.749
2756.5Wang, Nan; Hudson, Zachary M.; Wang, Suning
Reactivity of Aryldimesitylboranes under Suzuki−Miyaura Coupling Conditions
Organometallics, 2010, 29, 4007
4067071 CIFC22 H25 Cl F6 N O P Ru S2P -19.753; 11.004; 14.276
78.704; 83.444; 63.762
1347Singh, Pradhumn; Singh, Ajai K.
Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Organometallics, 2010, 29, 6433
4067072 CIFC22 H25 F12 N P2 Ru S SeP n a 219.6427; 20.2263; 13.7617
90; 90; 90
2684Singh, Pradhumn; Singh, Ajai K.
Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Organometallics, 2010, 29, 6433
4066272 CIFC22 H25 Fe NP 1 21/n 18.387; 10.1298; 21.4898
90; 93.807; 90
1821.72Unverhau, Kerstin; Lübbe, Gerrit; Wibbeling, Birgit; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework†
Organometallics, 2010, 29, 5320
4066365 CIFC22 H26 Cl Fe N2 OP 1 21/c 115.872; 9.0323; 15.5493
90; 109.904; 90
2096Volpe, Emily C.; Manke, David R.; Bartholomew, Erika R.; Wolczanski, Peter T.; Lobkovsky, Emil B.
Aryl−Oxazoline Chelates of First-Row Transition Metals: Structures of {κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}FeCl(py) and [(κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}Cr(μ-Cl)]2‡
Organometallics, 2010, 29, 6642
4066699 CIFC22 H26 Cl N4 O4 P Pd SP 1 21/c 114.2326; 16.3432; 10.3295
90; 100.316; 90
2363.87Sternberg, Michelle; Suresh, Cherumuttathu H.; Mohr, Fabian
2-Thia-1,3,5-triaza-7-phosphaadamantane-2,2-dioxide Revisited: Computational and Experimental Studies of a Neglected Phosphine
Organometallics, 2010, 29, 3922
4066457 CIFC22 H26 Cl2 HfC 1 c 127.612; 6.6102; 12.0125
90; 103.162; 90
2134.93Greger, Ingo; Kehr, Gerald; Fröhlich, Roland; Erker, Gerhard
Dynamic Topochemical Reaction Control−A Principle and Its Application inansa-Metallocene Synthesis†
Organometallics, 2010, 29, 3210
4067314 CIFC22 H27 B F4 N4 O PdP -18.0035; 9.9223; 16.6421
95.775; 103.256; 107.764
1204.13O, Wylie W. N.; Lough, Alan J.; Morris, Robert H.
Palladium(II) and Platinum(II) Complexes Featuring a Nitrile-Functionalized N-Heterocyclic Carbene Ligand
Organometallics, 2010, 29, 570
4067317 CIFC22 H27 B F4 N4 O PtP -18.0398; 9.8791; 16.6686
95.799; 102.562; 108.283
1206.36O, Wylie W. N.; Lough, Alan J.; Morris, Robert H.
Palladium(II) and Platinum(II) Complexes Featuring a Nitrile-Functionalized N-Heterocyclic Carbene Ligand
Organometallics, 2010, 29, 570
4066900 CIFC22 H27 Br0.5 Cl0.5 N P SiC 1 2/c 118.378; 11.475; 22.068
90; 108.329; 90
4417.8Cao, Thi-Phuong-Anh; Payet, Elina; Auffrant, Audrey; Le Goff, Xavier F.; Le Floch, Pascal
Facile Synthesis of Bifunctional Ligands using LiCH2PPh2═NPh Obtained from [PhNH−PPh3+][Br−]
Organometallics, 2010, 29, 3991
4066196 CIFC22 H27 Fe2 N2 O4 PP -111.0876; 13.7702; 15.7119
72.167; 72.183; 77.026
2151.32Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Reactions of the Phosphinidene-Bridged Complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph, 2,4,6-C6H2tBu3) with Diazoalkanes. Formation and Rearrangements of Phosphadiazadiene-Bridged Derivatives†
Organometallics, 2010, 29, 5140
4067028 CIFC22 H28 Al2 N2P 1 21/c 17.9554; 18.7424; 14.6172
90; 104.945; 90
2105.75Kingsley, Nicholas B.; Kirschbaum, Kristin; Mason, Mark R.
Confirmation of BridgingN-Indolides in 3-Methylindole and Di- and Tri(3-methylindolyl)methane Complexes of Dimethyl-, Diethyl-, and Diisobutylaluminum
Organometallics, 2010, 29, 5927
4066653 CIFC22 H29 Bi S2 Si2P b c a15.4332; 17.7471; 18.5611
90; 90; 90
5083.78Ohshita, Joji; Matsui, Shigenori; Yamamoto, Roh; Mizumo, Tomonobu; Ooyama, Yousuke; Harima, Yutaka; Murafuji, Toshihiro; Tao, Keisuke; Kuramochi, Yusuke; Kaikoh, Takashi; Higashimura, Hideyuki
Synthesis of Dithienobismoles as Novel Phosphorescence Materials
Organometallics, 2010, 29, 3239
4066166 CIFC22 H30 Br N O5P 1 21 19.9053; 11.2911; 11.0981
90; 109.586; 90
1169.4Liu, Zhen; Shi, Min
Catalytic Enantioselective Addition of Cyclic β-Keto Esters with Activated Olefins and N-Boc Imines Using ChiralC2-Symmetric Cationic Pd2+N-Heterocyclic Carbene (NHC) Diaqua Complexes
Organometallics, 2010, 29, 2831
4066033 CIFC22 H30 Cl2 Pd2 S2P 1 21/c 18.1701; 5.7673; 25.136
90; 97.2075; 90
1175.03Takeda, Nobuhiro; Watanabe, Daisuke; Nakamura, Tetsu; Unno, Masafumi
Synthesis and Complexation of a New Tripodal Tetradentate Ligand, a Silyl Ligand Tethered with Three Thioether Moieties
Organometallics, 2010, 29, 2839
4066605 CIFC22 H30 Cr2 F6 O3F d d 213.91; 40.474; 8.675
90; 90; 90
4884Huang, Hui; Rheingold, Arnold L.; Hughes, Russell P.
Synthesis and X-ray Structure of a Diamagnetic Oxo-Bridged Trifluoromethyl−Chromium(V) Complex: Structural and Computational Comparisons between CF3and CH3Ligands in Two Different Oxidation States of Chromium
Organometallics, 2010, 29, 3672
4066248 CIFC22 H30 Fe O2 SiP b c a15.1433; 9.2167; 30.8421
90; 90; 90
4304.7Jutzi, Peter; Leszczyńska, Kinga; Mix, Andreas; Neumann, Beate; Rummel, Britta; Schoeller, Wolfgang; Stammler, Hans-Georg
Synthesis and Characterization of the Ferrio-Substituted Silicon(II) Compound Me5C5(CO)2FeSiC5Me5†
Organometallics, 2010, 29, 4759
4067066 CIFC22 H31 Cl Ir NP 1 21/c 111.2917; 9.0419; 21.549
90; 104.668; 90
2128.4Kumaran, Elumalai; Sridevi, Venugopal Shanmugham; Leong, Weng Kee
Orthometalated Amino-Carbene Derivatives of Iridium via Anilines and Terminal Alkynes
Organometallics, 2010, 29, 6417
4067557 CIFC22 H31 Fe O4 PP 1 21/c 16.8549; 11.1429; 28.2174
90; 90.715; 90
2155.2Escobar, Aholibama; Mathey, François
Synthesis of 2,5-Difunctional Phosphaferrocenes
Organometallics, 2010, 29, 1053
4066197 CIFC22 H31 Fe2 N2 O2 P SiP 1 21/c 118.5613; 10.1935; 12.5422
90; 102.496; 90
2316.83Alvarez, M. Angeles; García, M. Esther; González, Rocío; Ruiz, Miguel A.
Reactions of the Phosphinidene-Bridged Complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph, 2,4,6-C6H2tBu3) with Diazoalkanes. Formation and Rearrangements of Phosphadiazadiene-Bridged Derivatives†
Organometallics, 2010, 29, 5140
4067559 CIFC22 H31 O4 PP -19.098; 10.0408; 12.7079
110.535; 94.298; 99.804
1059.77Escobar, Aholibama; Mathey, François
Synthesis of 2,5-Difunctional Phosphaferrocenes
Organometallics, 2010, 29, 1053
4066149 CIFC22 H32 Ni O4P 1 21/c 110.6932; 9.8476; 19.4131
90; 103.946; 90
1984Ohashi, Masato; Taniguchi, Tomoaki; Ogoshi, Sensuke
[3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient Alkylidenecyclopropanes
Organometallics, 2010, 29, 2386
4066786 CIFC22 H34 Ir2P -16.7259; 8.2968; 10.4452
68.933; 79.531; 67.621
502.27Nakai, Hidetaka; Nakano, Saori; Imai, Shunsuke; Isobe, Kiyoshi
Extraction of Hydrogen from Alcohols by a Methylene-Bridged Iridium(I) Dinuclear Complex Having a Short Ir−Ir Double Bond
Organometallics, 2010, 29, 4210
4066329 CIFC22 H34 N2 O4 Si WP 1 21/n 18.9831; 16.8823; 15.7119
90; 94.7457; 90
2374.6Suzuki, Eiji; Komuro, Takashi; Kanno, Yuto; Okazaki, Masaaki; Tobita, Hiromi
Facile 1,2-Migration of a Methyl Group on a {Dimethoxy(methyl)silyl}tungsten Complex: Formation of a Base-Stabilized (Dimethoxysilylene)(methyl) Complex†
Organometallics, 2010, 29, 5296
4066308 CIFC22 H35 B Cl2 F4 Ir N2 O4 PP 1 21/c 118.5507; 8.8012; 17.5506
90; 97.04; 90
2843.9Torres, Olga; Martín, Marta; Sola, Eduardo
Versatile κ2,η2-CLigands Assembled at Iridium via [2+2] Oxidative Cyclization
Organometallics, 2010, 29, 3201
4066482 CIFC22 H36 Cl2 F12 N8 O2 P2 Pt S2P -18.749; 10.065; 11.625
65.348; 74.88; 87.513
895.67Meyer, Dirk; Ahrens, Sebastian; Strassner, Thomas
Platinum(IV) Complexes with Chelating N-Heterocyclic Carbene Ligands
Organometallics, 2010, 29, 3392
4066787 CIFC22 H36 Ir2P 1 21/n 111.1666; 13.0931; 14.6548
90; 101.245; 90
2101.5Nakai, Hidetaka; Nakano, Saori; Imai, Shunsuke; Isobe, Kiyoshi
Extraction of Hydrogen from Alcohols by a Methylene-Bridged Iridium(I) Dinuclear Complex Having a Short Ir−Ir Double Bond
Organometallics, 2010, 29, 4210
4065557 CIFC22 H36 N2 Ni P2P 1 21/n 18.9798; 13.987; 18.626
90; 94.019; 90
2333.7Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4065565 CIFC22 H36 N2 Ni P2P 1 21/n 18.5767; 18.769; 14.628
90; 97.356; 90
2335.4Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4066884 CIFC22 H37 Cl Ru S Si2P -111.6073; 14.0285; 16.6412
67.495; 87.09; 89.219
2500.1Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand
Organometallics, 2010, 29, 4148
4066750 CIFC22 H38 Co2 O4 P2P 1 21/n 16.9927; 14.0728; 13.3788
90; 101.281; 90
1291.13Aguirre-Etcheverry, Paulina; Ashley, Andrew E.; Balázs, Gábor; Green, Jennifer C.; Cowley, Andrew R.; Thompson, Amber L.; O’Hare, Dermot
Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
Organometallics, 2010, 29, 5847
4067552 CIFC22 H39 Cd N7 Si2P 1 21/n 116.001; 25.203; 16.326
90; 119.02; 90
5757Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4065897 CIFC22 H39 Cl2 O0.5 Zr2P -4 21 m16.0703; 16.0703; 9.6812
90; 90; 90
2500.2Liu, Fu-Chen; Chu, Yong-Jui; Yang, Chien-Chan; Lee, Gene-Hsian; Peng, Shie-Ming
Syntheses and Structures of Zirconium Tetranuclear Polyhydrides
Organometallics, 2010, 29, 2685
4067545 CIFC22 H39 Mg N7 Si2P 1 21/n 116.3849; 24.5357; 16.1402
90; 119.546; 90
5644.82Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4067550 CIFC22 H39 N7 Si2 ZnP 1 21/n 18.0645; 24.312; 14.299
90; 90.57; 90
2803.4Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4066512 CIFC22 H40 Cl2 N4 Pd S2P -17.9669; 12.5972; 15.1836
109.441; 90.829; 98.612
1417.37Fliedel, Christophe; Braunstein, Pierre
Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-(S,CNHC) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag4I4(S,CNHC)2Planar Cluster†
Organometallics, 2010, 29, 5614
4067729 CIFC22 H40 Si5P -19.1751; 9.5607; 18.183
75.97; 81.92; 62
1365.6Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4066392 CIFC22 H41 B N4P 1 21/c 112.133; 10.5005; 19.2542
90; 107.933; 90
2333.86Saly, Mark J.; Winter, Charles H.
Highly Distorted κ3-N,N,H Bonding of Bis(3,5-di-tert-butylpyrazolyl)borate Ligands to the Heavier Group 2 Elements†
Organometallics, 2010, 29, 5472
4067182 CIFC22 H41 Cl N2 TiP 1 21 19.018; 14.354; 9.5822
90; 107.457; 90
1183.2Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4067183 CIFC22 H41 Cl N2 TiP n a 2117.7997; 8.8741; 14.9214
90; 90; 90
2356.93Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4067175 CIFC22 H41 N2 TiP 1 21/n 111.1945; 16.3777; 12.7894
90; 94.435; 90
2337.79Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4067176 CIFC22 H41 N2 TiP 1 21/n 18.7567; 17.7135; 14.9997
90; 90.682; 90
2326.47Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4066350 CIFC22 H43 Rh Si3P 21 21 219.8836; 13.5588; 19.9952
90; 90; 90
2679.55Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
Organometallics, 2010, 29, 5481
4066264 CIFC22 H46 Si4P -19.708; 11.504; 14.97
63.935; 70.324; 67.875
1361.5Kato, Nobu; Tamura, Yusuke; Kashiwabara, Taigo; Sanji, Takanobu; Tanaka, Masato
AlCl3-Catalyzed Hydrosilylation of Alkynes with Hydropolysilanes†
Organometallics, 2010, 29, 5274
4066734 CIFC22 H52 Cl2 N O2 P2 PtP 1 21/n 19.6173; 19.0187; 18.0287
90; 92.511; 90
3294.44Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Gimbert, Yves; Buono, Gérard
Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Organometallics, 2010, 29, 3936
4063337 CIFC22 H54 Mg O2 Si4C 1 2/c 118.1694; 9.5586; 18.669
90; 109.452; 90
3057.25Merle Arrowsmith; Michael S. Hill; Gabriele Kociok-Kḧon
Dearomatization and C‒H Deprotonation with Heavier Group 2 Alkyls: Does Size Matter?
Organometallics, 2010, 29, 4203-4206
4066277 CIFC22 H57 Li4 N9R 3 :H21.3969; 21.3969; 12.3807
90; 90; 120
4908.8Kamps, Ina; Neumann, Beate; Stammler, Hans-Georg; Mitzel, Norbert W.
A Chain Aggregate of Methyllithium Tetramers†
Organometallics, 2010, 29, 4746
4066931 CIFC22 H64 Si9P 1 21/c 116.138; 13.614; 18.046
90; 93.836; 90
3955.9Berkefeld, André; Troegel, Dennis; Burschka, Christian; Tacke, Reinhold
Synthesis and Characterization of {[Tris(trimethylsilyl)silyl]methyl}silanes of the Formula Type Me4−nSi[CH2Si(SiMe3)3]n(n= 1−3) and Derivatives
Organometallics, 2010, 29, 4548
4066305 CIFC22 H8 B F15 O SP 1 21/n 111.3535; 9.8755; 19.2199
90; 94.3; 90
2148.9Birkmann, Birgit; Voss, Tanja; Geier, Stephen J.; Ullrich, Matthias; Kehr, Gerald; Erker, Gerhard; Stephan, Douglas W.
Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane†
Organometallics, 2010, 29, 5310
4067771 CIFC220 H276 O20 Si16C 1 2/m 122.911; 30.535; 18.608
90; 124.05; 90
10786Kawakami, Yoshiteru; Sakuma, Yoshinobu; Wakuda, Takashi; Nakai, Tatsuya; Shirasaka, Masayoshi; Kabe, Yoshio
Hydrogen-Bonding 3D Networks by Polyhedral Organosilanols: Selective Inclusion of Hydrocarbons in Open Frameworks
Organometallics, 2010, 29, 3281
4066561 CIFC222 H206 Lu2 N12 O3 Si8P -113.2071; 14.3767; 22.701
95.503; 94.395; 94.845
4259.5Schupak, Elena A.; Lyubov, Dmitrii M.; Baranov, Evguenii V.; Fukin, Georgii K.; Suvorova, Olga N.; Trifonov, Alexander A.
New Type of Reaction of Lanthanide Hydrido Complexes with C60: Oxidative Dehydrogenation vs Addition. The Reversible σ-C60−C60Bond Formation in Complex [{(Me3Si)2NC(NCy)2}2Lu(Et2O)+](C60−•)
Organometallics, 2010, 29, 6141
4066640 CIFC23 H15 N O7 Ru2P 1 21/c 19.894; 13.51; 17.462
90; 103.87; 90
2266.1Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4067235 CIFC23 H17 N3 O6 WC 1 c 139.965; 24.458; 18.51
90; 94.111; 90
18046Chakraborty, Amarnath; Dey, Surjendu; Sawoo, Sudeshna; Adarsh, N. N.; Sarkar, Amitabha
Regioselective 1,3-Dipolar Cycloaddition Reaction of Azides with Alkoxy Alkynyl Fischer Carbene Complexes
Organometallics, 2010, 29, 6619
4065687 CIFC23 H20 Cl2 N2 O TiP -19.2588; 11.149; 12.038
98.33; 92.77; 100.39
1205.8Liu, Shaofeng; Sun, Wen-Hua; Zeng, Yanning; Wang, Deligeer; Zhang, Wenjuan; Li, Yan
Syntheses, Characterization, and Ethylene (Co-)Polymerization Screening of Amidate Half-Titanocene Dichlorides
Organometallics, 2010, 29, 2459
4065893 CIFC23 H21 Cl F6 N7 Os PP 1 21/n 114.7557; 13.193; 14.9139
90; 93.475; 90
2897.98Wong, Chun-Yuen; Lai, Lo-Ming; Pat, Pak-Kei; Chung, Lai-Hon
Osmium Complexes Containing N-Heterocyclic Carbene-Based C,N,C-Pincer Ligands
Organometallics, 2010, 29, 2533
4066522 CIFC23 H21 Fe N O2P b c a11.6877; 11.3921; 27.5719
90; 90; 90
3671.13Usener, Carolin; Kehr, Gerald; Fröhlich, Roland; Wibbeling, Birgit; Mück-Lichtenfeld, Christian; Erker, Gerhard
Developing a Reliable Synthetic Route tocis-1,3-Bridge-Disubstituted [3]Ferrocenophane Systems
Organometallics, 2010, 29, 3852
4066526 CIFC23 H22 Au Cl N2P 1 21 19.321; 9.326; 11.811
90; 105.639; 90
988.7Gung, Benjamin W.; Bailey, Lauren N.; Craft, Derek T.; Barnes, Charles L.; Kirschbaum, Kristin
Preparation and Characterization of Two New N-Heterocyclic Carbene Gold(I) Complexes and Comparison of Their Catalytic Activity to Au(IPr)Cl
Organometallics, 2010, 29, 3450
4067021 CIFC23 H23 B F9 O2 PP -19.8007; 10.1025; 12.4051
81.432; 80.647; 79.211
1181.6Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4067519 CIFC23 H23 Cl N O P Pd SP b c a15.55; 16.818; 16.818
90; 90; 90
4398.2Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4063461 CIFC23 H23 Cl N2 RuP b c a12.0093; 17.815; 18.282
90; 90; 90
3911.4Phillips, Andrew D.; Zava, Olivier; Scopelitti, Rosario; Nazarov, Alexey A.; Dyson, Paul J.
Rational Design of Highly Cytotoxic η6-Arene β-Diketiminato−Ruthenium Complexes
Organometallics, 2010, 29, 417
4066673 CIFC23 H24 Br F3 N2 O5 Ru2 SC 1 c 18.4019; 15.8995; 19.762
90; 90.06; 90
2639.9Chin, Robert M.; Simonson, Andrew; Mauldin, Joshua; Criswell, Jared; Brennessel, William
Syntheses and Characterization of Ruthenium Complexes Containing a Doubly Linked Dicyclopentadienyl Ligand and Acetonitrile Ligands
Organometallics, 2010, 29, 3868
4067128 CIFC23 H24 Fe N O2 PP 21 21 217.4296; 15.3027; 17.9529
90; 90; 90
2041.12Yu, Insun; Wallis, Christopher J.; Patrick, Brian O.; Diaconescu, Paula L.; Mehrkhodavandi, Parisa
Phosphine-Tethered Carbene Ligands: Template Synthesis and Reactivity of Cyclic and Acyclic Functionalized Carbenes
Organometallics, 2010, 29, 6065
4067515 CIFC23 H24 N O P SP 1 21/c 126.116; 9.5744; 17.7198
90; 107.978; 90
4214.4Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4067018 CIFC23 H25 B F9 O PP b c a10.263; 20.5092; 45.27
90; 90; 90
9528.7Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4067052 CIFC23 H25 Cl Ir NP 1 21/c 116.154; 14.4567; 8.3482
90; 90.43; 90
1949.5Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4067053 CIFC23 H25 Cl N RhP -18.4386; 14.676; 16.346
78.351; 81.627; 90.045
1960.6Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066121 CIFC23 H25 N O2P c a 2115.333; 9.79; 25.859
90; 90; 90
3881.7Chen, Ying; Mandal, Sukhendu; Sen, Ayusman
Synthesis of (N−O)-Ligated Palladium(II) Complexes and Their Use in Ethene Homopolymerization and Norbornene Copolymerizations
Organometallics, 2010, 29, 3160
4067024 CIFC23 H26 B F8 O PP b c a10.1201; 20.4708; 45.668
90; 90; 90
9460.9Schnurr, Anna; Vitze, Hannes; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Rigid, Fluoroarene-Containing Phosphonium Borates and Boranes: Syntheses and Reactivity Studies
Organometallics, 2010, 29, 6012
4066216 CIFC23 H26 Cl2 P2 PdP 1 21 19.0468; 14.4313; 9.6325
90; 111.908; 90
1166.77Chen, Shuli; Ng, Joseph Kok-Peng; Pullarkat, Sumod A.; Liu, Fengli; Li, Yongxin; Leung, Pak-Hing
Asymmetric Synthesis of New Diphosphines and Pyridylphosphines via a Kinetic Resolution Process Promoted and Controlled by a Chiral Palladacycle
Organometallics, 2010, 29, 3374
4066217 CIFC23 H26 Cl2 P2 PdP 1 21 18.9434; 13.022; 10.8172
90; 112.444; 90
1164.36Chen, Shuli; Ng, Joseph Kok-Peng; Pullarkat, Sumod A.; Liu, Fengli; Li, Yongxin; Leung, Pak-Hing
Asymmetric Synthesis of New Diphosphines and Pyridylphosphines via a Kinetic Resolution Process Promoted and Controlled by a Chiral Palladacycle
Organometallics, 2010, 29, 3374
4066270 CIFC23 H27 Cl Fe N2P 1 21/c 19.4638; 12.4287; 17.306
90; 97.385; 90
2018.69Unverhau, Kerstin; Lübbe, Gerrit; Wibbeling, Birgit; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework†
Organometallics, 2010, 29, 5320
4067048 CIFC23 H27 Cl N RhP 1 21/c 115.7511; 7.2007; 17.3962
90; 94.321; 90
1967.45Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066370 CIFC23 H28 Cl Ir N2 O2P 1 21/n 111.0866; 14.647; 14.935
90; 105.078; 90
2341.7Collins, Mary S.; Rosen, Evelyn L.; Lynch, Vincent M.; Bielawski, Christopher W.
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
Organometallics, 2010, 29, 3047
4066371 CIFC23 H28 Cl Ir N2 O2P 1 21/n 111.1249; 16.3484; 12.8143
90; 102.406; 90
2276.17Collins, Mary S.; Rosen, Evelyn L.; Lynch, Vincent M.; Bielawski, Christopher W.
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
Organometallics, 2010, 29, 3047
4065708 CIFC23 H28 Er NP b c a27.581; 8.893; 33.879
90; 90; 90
8310Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4065709 CIFC23 H28 N YbP -4 21 c22.078; 22.078; 8.932
90; 90; 90
4354Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4066558 CIFC23 H29 B N3 O5 RhP 1 21/c 111.5814; 9.4035; 22.773
90; 101.517; 90
2430.2Ho, Hung-An; Dunne, James F.; Ellern, Arkady; Sadow, Aaron D.
Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition
Organometallics, 2010, 29, 4105
4065951 CIFC23 H29 F6 N2 PP 21 21 2111.0984; 14.5283; 14.7057
90; 90; 90
2371.16Newman, Paul D.; Cavell, Kingsley J.; Kariuki, Benson M.
Metal Complexes of Chiral NHCs Containing a Fused Six- and Seven-Membered Central Ring
Organometallics, 2010, 29, 2724
4066510 CIFC23 H29 F6 N2 P SP 1 21/c 111.1279; 19.1377; 15.6504
90; 130.591; 90
2531Fliedel, Christophe; Braunstein, Pierre
Thioether-Functionalized N-Heterocyclic Carbenes: Mono- and Bis-(S,CNHC) Palladium Complexes, Catalytic C−C Coupling, and Characterization of a Unique Ag4I4(S,CNHC)2Planar Cluster†
Organometallics, 2010, 29, 5614
4066796 CIFC23 H30P 1 21/c 19.9567; 11.2769; 17.4701
90; 100.638; 90
1927.84Lee, Jhen-Yi; Cheng, Pi-Yun; Tsai, Yi-Hua; Lin, Guan-Ru; Liu, Shih-Pu; Sie, Ming-Han; Lee, Hon Man
Efficient Heck Reactions Catalyzed by Palladium(0) and -(II) Complexes Bearing N-Heterocyclic Carbene and Amide Functionalities
Organometallics, 2010, 29, 3901
4067243 CIFC23 H30 Cl2 N2 O2 Pt SP -18.029; 13.059; 13.179
80.77; 82.94; 68.1
1263Tomooka, Katsuhiko; Shimada, Maki; Uehara, Kazuhiro; Ito, Masato
A Unique Functional Group Transformation of Planar Chiral Diolefinic Organonitrogen Cycles Utilizing PtCl2(2,4,6-trimethylpyridine) Complexes
Organometallics, 2010, 29, 6632
4067711 CIFC23 H30 F6 Ir N2 O PC 1 2/c 125.528; 12.89; 15.351
90; 95.196; 90
5030.6Davies, David L.; Al-Duaij, Omar; Fawcett, John; Singh, Kuldip
Reactions of Cyclometalated Oxazoline Half-Sandwich Complexes of Iridium and Ruthenium with Alkynes and CO
Organometallics, 2010, 29, 1413
4065624 CIFC23 H31 Au N2P 1 21/n 113.358; 13.1952; 13.4743
90; 116.401; 90
2127.3Venugopal, Ajay; Ghosh, Manik Kumer; Jürgens, Hannes; Törnroos, Karl W.; Swang, Ole; Tilset, Mats; Heyn, Richard H.
(β-Diketiminato)dimethylgold(III): Synthesis, Structure, and Reactivity
Organometallics, 2010, 29, 2248
4067364 CIFC23 H32 Fe2 N2 O6 SP b c a18.929; 12.633; 22.822
90; 90; 90
5457Song, Li-Cheng; Cheng, Jia; Yan, Jing; Liu, Chun-Rong; Hu, Qing-Mei
Two Novel μ-CO-Containing Butterfly Fe/S Cluster Anions Formed from Trithiol MeC(CH2SH)3, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles to Produce the Corresponding Neutral Triple- and Double-Butterfly Cluster Complexes
Organometallics, 2010, 29, 205
4065635 CIFC23 H32 O9 Ru Si2P 21 21 217.3911; 17.4; 22.35
90; 90; 90
2874.3Yamamoto, Yoshihiko; Yamashita, Ken; Nakamura, Mitsutaka
Synthesis of Organometallic Analogues of SpirocyclicC-Arylribosides
Organometallics, 2010, 29, 1472
4065637 CIFC23 H32 O9 Ru Si2P 21 21 217.775; 18.5454; 20.0881
90; 90; 90
2896.5Yamamoto, Yoshihiko; Yamashita, Ken; Nakamura, Mitsutaka
Synthesis of Organometallic Analogues of SpirocyclicC-Arylribosides
Organometallics, 2010, 29, 1472
4067681 CIFC23 H34 Al N3 O5 S2P 1 n 17.8591; 12.9952; 12.7598
90; 99.7066; 90
1284.51Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4067051 CIFC23 H34 Cl Ir N2 OP 1 21/c 19.623; 15.255; 15.9
90; 92.486; 90
2331.9Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066599 CIFC23 H34 I N3 O5 PdP c a 2116.4206; 8.4472; 38.9101
90; 90; 90
5397.1Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Abellán-López, Antonio; Bautista, Delia
Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†
Organometallics, 2010, 29, 5693
4066310 CIFC23 H34 Ir O7 PP 1 21/c 18.839; 34.989; 8.603
90; 114.591; 90
2419.3Torres, Olga; Martín, Marta; Sola, Eduardo
Versatile κ2,η2-CLigands Assembled at Iridium via [2+2] Oxidative Cyclization
Organometallics, 2010, 29, 3201
4067561 CIFC23 H35 B Cl2 F3 N7 O5 P2 S WP 1 21/n 17.978; 36.776; 11.876
90; 100.51; 90
3425.9Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4067140 CIFC23 H35 F4 Ni PP 1 21/c 110.2723; 12.3685; 18.484
90; 98.796; 90
2320.8Hatnean, Jillian A.; Beck, Robert; Borrelli, Jenna D.; Johnson, Samuel A.
Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation
Organometallics, 2010, 29, 6077
4066247 CIFC23 H35 N2 O2 YP b c n29.7025; 9.454; 16.4829
90; 90; 90
4628.5Casely, Ian J.; Suh, YoungSung; Ziller, Joseph W.; Evans, William J.
Formation of a [ONN(allyl)O]−Anion via NO Insertion and Coupling Using Yttrium and Lanthanide Allyl Metallocenes†
Organometallics, 2010, 29, 5209
4066203 CIFC23 H35 O TiP -18.6373; 8.9208; 15.1205
85.006; 75.619; 69.674
1058.28Gyepes, Róbert; Varga, Vojtech; Horáček, Michal; Kubišta, Jiří; Pinkas, Jiří; Mach, Karel
Influence of the Ti−O−C Angle on the Oxygen-to-Titanium π-Donation in [Cp2*Ti(III)OR] Complexes∥
Organometallics, 2010, 29, 3780
4066994 CIFC23 H37 Cl Si UP 1 21/c 19.7385; 15.5793; 16.2137
90; 104.249; 90
2384.2Montalvo, Elizabeth; Miller, Kevin A.; Ziller, Joseph W.; Evans, William J.
Reactivity of Tuck-in and Tuck-over Uranium Metallocene Complexes
Organometallics, 2010, 29, 4159
4066681 CIFC23 H38 B N6 Os PP -18.2181; 8.7108; 19.098
89.467; 77.641; 78.37
1307.2Castro-Rodrigo, Ruth; Esteruelas, Miguel A.; López, Ana M.; Mozo, Silvia; Oñate, Enrique
C−H Bond Activation Reactions in π-Allene−Osmium−Triisopropylphosphine Complexes with Cyclopentadienyl or Hydridotris(pyrazolyl)borate Ligands: Formation of Isopropenyldiisopropylphosphine versus Hydride−Alkenylcarbyne Derivatives
Organometallics, 2010, 29, 4071
4067471 CIFC23 H38 B7 Fe N2 O3 PP 1 21/c 119.51; 9.6131; 30.723
90; 99.041; 90
5690.6Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067762 CIFC23 H40 Cl N2 RhP 21 21 219.5397; 12.2604; 19.335
90; 90; 90
2261.4Snead, David R.; Inagaki, Sebastien; Abboud, Khalil A.; Hong, Sukwon
Bis(2-alkylpyrrolidin-1-yl)methylidenes as Chiral Acyclic Diaminocarbene Ligands
Organometallics, 2010, 29, 1729
4066356 CIFC23 H41 Cl N3 P2 RhP 1 21/n 110.8889; 15.4067; 16.1672
90; 95.629; 90
2699.16Urtel, Heiko; Meier, Claudia; Rominger, Frank; Hofmann, Peter
Neutralcis-Alkyl Olefin Rhodium(I) Complexes: Models of Intermediates in Late Transition Metal Olefin Polymerization with Surprising Structure†
Organometallics, 2010, 29, 5496
4065855 CIFC23 H43 B Br F4 Fe N3 O3 P2F d d d :211.5251; 24.5644; 42.952
90; 90; 90
12160Benito-Garagorri, David; Alves, Luis Gonçalo; Veiros, Luis F.; Standfest-Hauser, Christina M.; Tanaka, Shinji; Mereiter, Kurt; Kirchner, Karl
Kinetically Controlled Formation of Octahedraltrans-Dicarbonyl Iron(II) PNP Pincer Complexes: The Decisive Role of Spin-State Changes§
Organometallics, 2010, 29, 4932
4067179 CIFC23 H43 Cl N2 TiP 21 21 219.0865; 14.6621; 17.8517
90; 90; 90
2378.33Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4063430 CIFC23 H43 F6 Ir N3 P RuP 1 21/n 18.6647; 15.1351; 21.3172
90; 92.483; 90
2792.94Shima, Takanori; Namura, Kyo; Kameo, Hajime; Kakuta, Satoshi; Suzuki, Hiroharu
Synthesis and Structure of a Novel Ruthenium Hydrido Bis(dihydrogen) Complex with 1,4,7-Trimethyl-1,4,7-triazacyclononane Ligand: A Useful Precursor for Synthesis of Heterometallic Complexes
Organometallics, 2010, 29, 337
4067177 CIFC23 H43 N2 TiP b c a16.0967; 16.5501; 18.3592
90; 90; 90
4890.93Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4067572 CIFC23 H43 P4 RuP -19.0216; 9.1604; 17.2534
96.199; 92.234; 104.126
1371.5Field, Leslie D.; Magill, Alison M.; Shearer, Timothy K.; Colbran, Stephen B.; Lee, Sang T.; Dalgarno, Scott J.; Bhadbhade, Mohan M.
Controlled Synthesis of Dinuclear Acetylide-Bridged Ruthenium Complexes
Organometallics, 2010, 29, 957
4065758 CIFC23 H44 Li N O P2 S2P 21 21 2111.834; 14.601; 16.589
90; 90; 90
2866.4Leung, Wing-Por; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis of Heavier Group 14 Metal Compounds from 2,6-Lutidylbis(phosphoranosulfide)
Organometallics, 2010, 29, 1890
4066813 CIFC23 H48 O3 Si4 WC 1 2 115.7384; 8.9528; 20.893
90; 94.745; 90
2933.8Ray, Mausumi; Nakao, Yoshihide; Sato, Hirofumi; Sakaki, Shigeyoshi; Watanabe, Takahito; Hashimoto, Hisako; Tobita, Hiromi
Experimental and Theoretical Study of a Tungsten Dihydride Silyl Complex: New Insight into Its Bonding Nature and Fluxional Behavior
Organometallics, 2010, 29, 6267
4065920 CIFC23 H50 Cl2 Os P2P -18.5698; 11.1789; 15.86
98.265; 94.965; 112.038
1377.3Collado, Alba; Esteruelas, Miguel A.; López, Fernando; Mascareñas, José L.; Oñate, Enrique; Trillo, Beatriz
C−H Bond Activation of Terminal Allenes: Formation of Hydride-Alkenylcarbyne-Osmium and Disubstituted Vinylidene-Ruthenium Derivatives∥
Organometallics, 2010, 29, 4966
4066629 CIFC23 H9 N O9 Ru3P -19.3755; 11.0167; 12.1641
87.708; 74.862; 78.775
1189.5Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4067067 CIFC23.25 H33.5 Cl1.5 Ir NI -422.7532; 22.7532; 9.0625
90; 90; 90
4691.7Kumaran, Elumalai; Sridevi, Venugopal Shanmugham; Leong, Weng Kee
Orthometalated Amino-Carbene Derivatives of Iridium via Anilines and Terminal Alkynes
Organometallics, 2010, 29, 6417
4065852 CIFC234 H270 K6 Mn6 O18P 6319.125; 19.125; 32.076
90; 90; 120
10160Crisp, Jeffrey A.; Meier, Ryan M.; Overby, Jason S.; Hanusa, Timothy P.; Rheingold, Arnold L.; Brennessel, William W.
Indenyl Complexes of Manganese(II). Conformational Flexibility of the Manganese(II)−(RnC9H7−n) Bond
Organometallics, 2010, 29, 2322
4066045 CIFC24 H10 Cr Mn N O10P 1 21/c 16.6603; 12.9097; 26.8855
90; 96.4883; 90
2296.88Dubarle Offner, Julien; Schnakenburg, Gregor; Rose-Munch, Françoise; Rose, Eric; Dötz, Karl Heinz
Dibenzo[f,h]quinoline Cr(CO)3Complexes: Synthesis by Chromium-Templated Benzannulation, Cyclomanganation, and Haptotropic Chromium Migration
Organometallics, 2010, 29, 3308
4067748 CIFC24 H10 O15 Ru5P -18.9357; 10.2097; 16.7545
99.856; 98.711; 92.187
1485.4Osintseva, Svetlana V.; Dolgushin, Fedor M.; Shtel’tser, Nikolay A.; Petrovskii, Pavel V.; Peregudov, Alexander S.; Kreindlin, Arkadii Z.; Antipin, Mikhail Yu.
Isolation and Characterization of New Mono- and Polynuclear Complexes Formed in the Thermal Reaction of Ru3(CO)12with 1-(4-Tolyl)-3-phenylaminoprop-2-en-1-one
Organometallics, 2010, 29, 1012
4067366 CIFC24 H12 Fe6 O18 S5F d d 232.674; 55.01; 8.6148
90; 90; 90
15484Song, Li-Cheng; Cheng, Jia; Yan, Jing; Liu, Chun-Rong; Hu, Qing-Mei
Two Novel μ-CO-Containing Butterfly Fe/S Cluster Anions Formed from Trithiol MeC(CH2SH)3, Fe3(CO)12, and Et3N: Their Reactions with Electrophiles to Produce the Corresponding Neutral Triple- and Double-Butterfly Cluster Complexes
Organometallics, 2010, 29, 205
4066847 CIFC24 H14 N2 O9 Os3C 1 2/c 135.5574; 7.8812; 22.7345
90; 109.31; 90
6012.59Cabeza, Javier A.; del Río, Ignacio; Fernández-Colinas, José M.; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela; Vázquez-García, Digna
Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study§
Organometallics, 2010, 29, 3828
4066634 CIFC24 H16 N O2 RuC 1 2/c 116.451; 14.35; 17.25
90; 112.454; 90
3763.5Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066635 CIFC24 H16 N2 O2 RuP 1 21/c 19.0164; 13.376; 16.487
90; 97.947; 90
1969.3Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066663 CIFC24 H18 B F12 PP 1 21/c 111.8572; 11.2477; 18.1725
90; 106.045; 90
2329.2Ullrich, Matthias; Lough, Alan J.; Stephan, Douglas W.
Dihydrogen Activation by B(p-C6F4H)3and Phosphines
Organometallics, 2010, 29, 3647
4065640 CIFC24 H19 Br FeP 1 21 16.0896; 7.8142; 18.7986
90; 95.268; 90
890.76McAdam, C. John; Robinson, Brian H.; Simpson, Jim; Tagg, Tei
Ferrocenyl−Naphthalimide Donor−Acceptor Dyads with Aromatic Spacer Groups
Organometallics, 2010, 29, 2474
4067042 CIFC24 H20 Au Cl F N3P 21 21 219.8352; 20.1882; 27.0406
90; 90; 90
5369.05Paul, Susann; Schweizer, W. Bernd; Ebert, Marc-Olivier; Gilmour, Ryan
A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology
Organometallics, 2010, 29, 4424
4067040 CIFC24 H21 B F5 N3C 1 2 116.8056; 6.9654; 18.7706
90; 105.241; 90
2119.96Paul, Susann; Schweizer, W. Bernd; Ebert, Marc-Olivier; Gilmour, Ryan
A Novel Fluorinated Gold(I) N-Heterocyclic Carbene Complex: Exploiting Fluorine Stereoelectronic Effects To Control Molecular Topology
Organometallics, 2010, 29, 4424
4067488 CIFC24 H21 Cl Mo N2 O2P -18.3736; 11.306; 12.541
77.76; 75.775; 76.807
1105.1Li, Shenyu; Kee, Choon Wee; Huang, Kuo-Wei; Hor, T. S. Andy; Zhao, Jin
Cyclopentadienyl Molybdenum(II/VI) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Reactivity under Oxidative Conditions
Organometallics, 2010, 29, 1924
4066594 CIFC24 H22 N2 O4 Pd2F 2 d d10.4757; 16.1086; 24.6965
90; 90; 90
4167.5Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Abellán-López, Antonio; Bautista, Delia
Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†
Organometallics, 2010, 29, 5693
4065659 CIFC24 H23 F3 N O5 P SP 1 c 17.6328; 7.6138; 21.2288
90; 93.837; 90
1230.94Tian, Rongqiang; Mathey, François
7-Phosphanorbornenium Borohydrides: A Powerful Route to Functional Secondary Phosphine−Borane Complexes
Organometallics, 2010, 29, 1873
4065586 CIFC24 H24 Bi ReP 1 21/c 113.6349; 16.8562; 17.6871
90; 89.964; 90
4065.07Schiwon, Rafael; Knispel, Christina; Limberg, Christian
Heterometallic Complexes with Re−Bi Metal Bonds
Organometallics, 2010, 29, 1670
4066981 CIFC24 H24 Cl I2 N3 PdP 1 21/n 111.6209; 10.1227; 21.8342
90; 91.097; 90
2567.99Xu, Xiangya; Xu, Baochang; Li, Yongxin; Hong, Soon Hyeok
Abnormal N-Heterocyclic Carbene Promoted Suzuki−Miyaura Coupling Reaction: A Comparative Study
Organometallics, 2010, 29, 6343
4065745 CIFC24 H24 Co2 O7P 19.4908; 10.492; 12.481
81.668; 80.035; 79.356
1194.8Moore, Angela; Ortin, Yannick; Müller-Bunz, Helge; McGlinchey, Michael J.
Alkynyl-Dicobalt Hexacarbonyl Complexes of Menthyl Cations: Isolobal Substitution of [Co(CO)3]+by Fe(CO)3as a Structural Model†
Organometallics, 2010, 29, 4882
4066271 CIFC24 H25 F3 Fe N2P 1 21/n 19.9315; 13.6542; 16.0667
90; 104.814; 90
2106.33Unverhau, Kerstin; Lübbe, Gerrit; Wibbeling, Birgit; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework†
Organometallics, 2010, 29, 5320
4066869 CIFC24 H25 F6 N2 P Ru S3P 21 21 2110.6871; 12.3212; 19.86
90; 90; 90
2615.1Wong, Chun-Yuen; Lai, Lo-Ming; Chan, Siu-Chung; Tai, Lai-Hung
Photophysical and Theoretical Studies of Ruthenium(II)−Acetylide and −Cyanide Complexes with Aromatic Diimine and Trithiacyclononane
Organometallics, 2010, 29, 6259
4066871 CIFC24 H26 Cl F6 N6 P Ru S3P -18.2985; 12.4067; 15.4189
112.63; 94.271; 94.603
1450.93Wong, Chun-Yuen; Lai, Lo-Ming; Chan, Siu-Chung; Tai, Lai-Hung
Photophysical and Theoretical Studies of Ruthenium(II)−Acetylide and −Cyanide Complexes with Aromatic Diimine and Trithiacyclononane
Organometallics, 2010, 29, 6259
4066128 CIFC24 H27 B Mo N6 O7P 21 21 217.908; 15.9173; 21.9238
90; 90; 90
2759.6Coombs, Thomas C.; Huang, Wenwei; Garnier-Amblard, Ethel C; Liebeskind, Lanny S.
Novel Substitutions of 1-Alkoxy- and 1-Arylsulfonyloxy-η-Allylmolybdenum Complexes. A Case for η-Alkenyl Carbene Complexes as Intermediates.
Organometallics, 2010, 29, 5083-5097
4067126 CIFC24 H27 Cl Fe I N2 O PP 6520.232; 20.232; 10.5999
90; 90; 120
3757.6Yu, Insun; Wallis, Christopher J.; Patrick, Brian O.; Diaconescu, Paula L.; Mehrkhodavandi, Parisa
Phosphine-Tethered Carbene Ligands: Template Synthesis and Reactivity of Cyclic and Acyclic Functionalized Carbenes
Organometallics, 2010, 29, 6065
4067373 CIFC24 H27 Cl Ge O3P -19.2445; 11.218; 23.106
94.474; 98.982; 106.334
2252.4Yoder, Claude H.; Agee, Tamara M.; Griffith, Allison K.; Schaeffer, Charles D.; Carroll, Mary J.; DeToma, Alaina S.; Fleisher, Adam J.; Gettel, Cameron J.; Rheingold, Arnold L.
Use of73Ge NMR Spectroscopy and X-ray Crystallography for the Study of Electronic Interactions in Substituted Tetrakis(phenyl)-, -(phenoxy)-, and -(thiophenoxy)germanes
Organometallics, 2010, 29, 582
4066273 CIFC24 H27 F3 Fe N2P -17.4963; 9.2434; 15.785
95.678; 100.152; 99.068
1054.11Unverhau, Kerstin; Lübbe, Gerrit; Wibbeling, Birgit; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework†
Organometallics, 2010, 29, 5320
4067060 CIFC24 H28 Cl F3 Ir N O2P b c n26.006; 13.287; 14.461
90; 90; 90
4996.9Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4067061 CIFC24 H28 Cl F3 N O2 RhP b c n25.927; 13.338; 14.438
90; 90; 90
4992.9Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4067372 CIFC24 H28 Ge O3P -18.8594; 11.422; 11.5301
78.028; 80.456; 69.188
1061.48Yoder, Claude H.; Agee, Tamara M.; Griffith, Allison K.; Schaeffer, Charles D.; Carroll, Mary J.; DeToma, Alaina S.; Fleisher, Adam J.; Gettel, Cameron J.; Rheingold, Arnold L.
Use of73Ge NMR Spectroscopy and X-ray Crystallography for the Study of Electronic Interactions in Substituted Tetrakis(phenyl)-, -(phenoxy)-, and -(thiophenoxy)germanes
Organometallics, 2010, 29, 582
4066977 CIFC24 H28 I2 N4 PdP -18.6567; 8.7067; 10.3222
102.88; 92.338; 118.385
657.4Xu, Xiangya; Xu, Baochang; Li, Yongxin; Hong, Soon Hyeok
Abnormal N-Heterocyclic Carbene Promoted Suzuki−Miyaura Coupling Reaction: A Comparative Study
Organometallics, 2010, 29, 6343
4065998 CIFC24 H28 N6 Ni S2C 1 2/c 117.0446; 14.3126; 10.7475
90; 97.304; 90
2600.6Jothibasu, Ramasamy; Huang, Kuo-Wei; Huynh, Han Vinh
Synthesis ofcis- andtrans-Diisothiocyanato−Bis(NHC) Complexes of Nickel(II) and Applications in the Kumada−Corriu Reaction
Organometallics, 2010, 29, 3746
4067049 CIFC24 H29 Cl N RhP 1 21/n 18.7242; 12.0445; 19.9275
90; 95.271; 90
2085.1Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4067167 CIFC24 H29 N3P 1 21/n 110.3543; 21.0372; 10.4706
90; 112.054; 90
2113.88Cabrera, Alan R.; Schneider, Yanika; Valderrama, Mauricio; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard; Rojas, Rene S.
Synthesis of a [(π-Cyano-nacnac)Cp]zirconium Complex and Its Remote Activation for Ethylene Polymerization
Organometallics, 2010, 29, 6104
4067168 CIFC24 H29 N3P 1 21/n 112.3225; 12.9163; 13.6889
90; 97.482; 90
2160.19Cabrera, Alan R.; Schneider, Yanika; Valderrama, Mauricio; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard; Rojas, Rene S.
Synthesis of a [(π-Cyano-nacnac)Cp]zirconium Complex and Its Remote Activation for Ethylene Polymerization
Organometallics, 2010, 29, 6104
4066120 CIFC24 H30 Au2 N6 P2 S2P 1 21/n 16.215; 18.705; 22.755
90; 90.069; 90
2645Vergara, Elena; Cerrada, Elena; Casini, Angela; Zava, Olivier; Laguna, Mariano; Dyson, Paul. J.
Antiproliferative Activity of Gold(I) Alkyne Complexes Containing Water-Soluble Phosphane Ligands
Organometallics, 2010, 29, 2596
4067055 CIFC24 H30 Cl N O2 RhC 1 c 115.3248; 13.1132; 12.2913
90; 117.318; 90
2194.6Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4065617 CIFC24 H30 F10 I2 Ir2P b c a12.8514; 13.9753; 16.3838
90; 90; 90
2942.6Yuan, Jian; Hughes, Russell P.; Golen, James A.; Rheingold, Arnold L.
Synthesis and Structural and Computational Studies of a Conformationally Locked (η1-Perfluoroalkylidene)(η2-alkene) Transition Metal Complex: Ir(Cp*)(CFCF3)(C2H4)
Organometallics, 2010, 29, 1942
4066274 CIFC24 H30 Fe N2P 1 21/n 113.9568; 9.0606; 17.0797
90; 109.42; 90
2036.97Unverhau, Kerstin; Lübbe, Gerrit; Wibbeling, Birgit; Fröhlich, Roland; Kehr, Gerald; Erker, Gerhard
Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework†
Organometallics, 2010, 29, 5320
4065850 CIFC24 H30 Mn Si2P 1 21/c 111.826; 8.128; 12.663
90; 113.469; 90
1116.5Crisp, Jeffrey A.; Meier, Ryan M.; Overby, Jason S.; Hanusa, Timothy P.; Rheingold, Arnold L.; Brennessel, William W.
Indenyl Complexes of Manganese(II). Conformational Flexibility of the Manganese(II)−(RnC9H7−n) Bond
Organometallics, 2010, 29, 2322
4065625 CIFC24 H31 Au F3 I N2 O3 SP 21 21 2111.1621; 12.896; 19.3602
90; 90; 90
2786.8Venugopal, Ajay; Ghosh, Manik Kumer; Jürgens, Hannes; Törnroos, Karl W.; Swang, Ole; Tilset, Mats; Heyn, Richard H.
(β-Diketiminato)dimethylgold(III): Synthesis, Structure, and Reactivity
Organometallics, 2010, 29, 2248
4067584 CIFC24 H32 F6 N3 O P RhP 1 21/n 19.3568; 21.675; 13.098
90; 92.54; 90
2653.8Dzik, Wojciech I.; Creusen, Charlotte; de Gelder, René; Peters, Theo P. J.; Smits, Jan M. M.; de Bruin, Bas
Carbonyl Complexes of Rhodium with N-Donor Ligands: Factors Determining the Formation of Terminal versus Bridging Carbonyls
Organometallics, 2010, 29, 1629
4067391 CIFC24 H33 Cl Ir P3P -19.8452; 11.7899; 12.8026
63.724; 83.542; 66.008
1213.23Langer, Jens; Imhof, Wolfgang; Fabra, Maria José; García-Orduña, Pilar; Görls, Helmar; Lahoz, Fernando J.; Oro, Luis A.; Westerhausen, Matthias
Reversible CO2Fixation by Iridium(I) Complexes Containing Me2PhP as Ligand
Organometallics, 2010, 29, 1642
4066733 CIFC24 H33 Cl O2 P2 PtP -19.2775; 11.7432; 12.7385
71.5854; 86.316; 78.548
1290.55Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Gimbert, Yves; Buono, Gérard
Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Organometallics, 2010, 29, 3936
4065913 CIFC24 H34 Mn OP 1 21/n 110.7433; 16.4739; 12.5466
90; 102.132; 90
2170.95Cámpora, Juan; Palma, Pilar; Pérez, Carmen M.; Rodríguez-Delgado, Antonio; Álvarez, Eleuterio; Gutiérrez-Puebla, Enrique
Synthesis and Reactions of Manganese(II) Dialkyl Complexes Containing Monodentate and Bidentate Nitrogen Ligands
Organometallics, 2010, 29, 2960
4066538 CIFC24 H34 N2 O4 S2P -17.8913; 8.2462; 19.0435
88.423; 89.411; 75.9003
1201.43Schwarz, Andrew D.; Herbert, Katherine R.; Paniagua, Cristina; Mountford, Philip
Ligand Variations in New Sulfonamide-Supported Group 4 Ring-Opening Polymerization Catalysts
Organometallics, 2010, 29, 4171
4083400 CIFC24 H35 Cl3 N2 Si ZrP 1 21/n 19.2515; 15.407; 19.695
90; 91.581; 90
2806.2Yuan, Shifang; Bai, Shengdi; Liu, Diansheng; Sun, Wen-Hua
(η3-Azaallyl)zirconium Chlorides: Synthesis, Characterization, and Ethylene (Co-)polymerization Activity
Organometallics, 2010, 29, 2132
4067037 CIFC24 H36 Al Cl2 N Si3 ZrP 1 21/c 19.6578; 15.4967; 19.8486
90; 105.055; 90
2868.66Lund, Clinton L.; Hanson, Samuel S.; Schatte, Gabriele; Quail, J. Wilson; Müller, Jens
ansa-Zirconocenes with Aluminum or Gallium in Bridging Positions
Organometallics, 2010, 29, 6038
4067496 CIFC24 H36 B Cl F4 Pd Ru S2P b c a14.6653; 14.08899; 26.2077
90; 90; 90
5415.02Bonnet, Sylvestre; Lutz, Martin; Spek, Anthony L.; van Koten, Gerard; Klein Gebbink, Robertus J. M.
Bimetallic η6,η1SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure, and Catalytic Activity
Organometallics, 2010, 29, 1157
4067562 CIFC24 H36 B Cl6 N8 O4 P WP 1 21/c 119.315; 10.897; 18.924
90; 115.879; 90
3583.6Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4066600 CIFC24 H36 Cl2 I N3 O5 PdP 1 21/c 112.4477; 15.4666; 15.6411
90; 94.502; 90
3002Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Abellán-López, Antonio; Bautista, Delia
Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†
Organometallics, 2010, 29, 5693
4065634 CIFC24 H36 Cl3 O Si TaP 1 21/n 19.6996; 15.375; 17.381
90; 96.316; 90
2576.3Senda, Taichi; Hanaoka, Hidenori; Oda, Yoshiaki; Tsurugi, Hayato; Mashima, Kazushi
Silicon-Bridged Tetramethylcyclopentadienyl−Phenoxy Complexes of Tantalum: Preparation and Alkylation of Et2Si(η5-C5Me4)(3-tBu-5-Me-2-C6H2O)TaCl3and Generation of Its Cationic Complex
Organometallics, 2010, 29, 2080
4067038 CIFC24 H37 Al Cl3 N Si3 ZrP 1 21/c 116.851; 10.516; 17.334
90; 103.36; 90
2988.5Lund, Clinton L.; Hanson, Samuel S.; Schatte, Gabriele; Quail, J. Wilson; Müller, Jens
ansa-Zirconocenes with Aluminum or Gallium in Bridging Positions
Organometallics, 2010, 29, 6038
4066001 CIFC24 H37 F6 N Os P2P -19.0594; 11.3173; 12.848
75.6; 88.431; 87.158
1274.2Castro-Rodrigo, Ruth; Esteruelas, Miguel A.; López, Ana M.; López, Fernando; Mascareñas, José L.; Mozo, Silvia; Oñate, Enrique; Saya, Lucía
Ring Expansion versusexo−endoIsomerization in (2-Pyridyl)methylenecyclobutane Coordinated to Hydrido(trispyrazolyl)borate- and Cyclopentadienyl-Osmium Complexes
Organometallics, 2010, 29, 2372
4066002 CIFC24 H37 F6 N Os P2P 1 21/n 111.5346; 16.098; 13.7695
90; 96.538; 90
2540.1Castro-Rodrigo, Ruth; Esteruelas, Miguel A.; López, Ana M.; López, Fernando; Mascareñas, José L.; Mozo, Silvia; Oñate, Enrique; Saya, Lucía
Ring Expansion versusexo−endoIsomerization in (2-Pyridyl)methylenecyclobutane Coordinated to Hydrido(trispyrazolyl)borate- and Cyclopentadienyl-Osmium Complexes
Organometallics, 2010, 29, 2372
4067035 CIFC24 H38 Al N Si3P 1 21/c 119.14; 9.174; 15.447
90; 103.03; 90
2642.51Lund, Clinton L.; Hanson, Samuel S.; Schatte, Gabriele; Quail, J. Wilson; Müller, Jens
ansa-Zirconocenes with Aluminum or Gallium in Bridging Positions
Organometallics, 2010, 29, 6038
4063436 CIFC24 H38 F3 Fe N O3 P3 SP 1 21/c 124.159; 12.6587; 18.8974
90; 93.255; 90
5769.9Volpe, Emily C.; Wolczanski, Peter T.; Lobkovsky, Emil B.
Aryl-Containing Pyridine-Imine and Azaallyl Chelates of Iron toward Strong Field Coordination Compounds
Organometallics, 2010, 29, 364
4067036 CIFC24 H38 Ga N Si3P 1 21/c 116.2099; 9.7061; 19.5175
90; 122.358; 90
2593.95Lund, Clinton L.; Hanson, Samuel S.; Schatte, Gabriele; Quail, J. Wilson; Müller, Jens
ansa-Zirconocenes with Aluminum or Gallium in Bridging Positions
Organometallics, 2010, 29, 6038
4067612 CIFC24 H38 O P2 PtP 1 21/n 110.5428; 15.1627; 14.9567
90; 92.063; 90
2389.39Robinson, Robert; Sharp, Paul R.
Syntheses, Structures, and Reductive Elimination Studies of Six-Membered Diaryl Platinacycle Complexes
Organometallics, 2010, 29, 1388
4066236 CIFC24 H38 Si2 TiC 1 2/c 19.113; 15.7688; 16.683
90; 104.722; 90
2318.66Pinkas, Jiří; Lukešová, Lenka; Gyepes, Róbert; Císařová, Ivana; Kubišta, Jiří; Horáček, Michal; Mach, Karel
Reduction-Induced Exclusive Activation of theansa-1,2-Bis(dimethylsilylene)ethane Chain inansa-Permethyltitanocene Compounds§
Organometallics, 2010, 29, 5199
4066238 CIFC24 H39 Cl Si2 TiP -18.6733; 8.975; 16.973
86.187; 82.613; 70.6677
1235.98Pinkas, Jiří; Lukešová, Lenka; Gyepes, Róbert; Císařová, Ivana; Kubišta, Jiří; Horáček, Michal; Mach, Karel
Reduction-Induced Exclusive Activation of theansa-1,2-Bis(dimethylsilylene)ethane Chain inansa-Permethyltitanocene Compounds§
Organometallics, 2010, 29, 5199
4066237 CIFC24 H40 Cl Si2 TiP -18.6462; 9.6866; 16.503
84.7673; 78.7793; 68.0239
1256.98Pinkas, Jiří; Lukešová, Lenka; Gyepes, Róbert; Císařová, Ivana; Kubišta, Jiří; Horáček, Michal; Mach, Karel
Reduction-Induced Exclusive Activation of theansa-1,2-Bis(dimethylsilylene)ethane Chain inansa-Permethyltitanocene Compounds§
Organometallics, 2010, 29, 5199
4067124 CIFC24 H42 Cl6 Fe I N2 O PP 1 21/c 115.1631; 14.9065; 16.089
90; 111.237; 90
3389.6Yu, Insun; Wallis, Christopher J.; Patrick, Brian O.; Diaconescu, Paula L.; Mehrkhodavandi, Parisa
Phosphine-Tethered Carbene Ligands: Template Synthesis and Reactivity of Cyclic and Acyclic Functionalized Carbenes
Organometallics, 2010, 29, 6065
4066396 CIFC24 H42 Ir N O P2P b c a11.8998; 15.5324; 27.9034
90; 90; 90
5157.5Schwartsburd, Leonid; Iron, Mark A.; Konstantinovski, Leonid; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization
Organometallics, 2010, 29, 3817
4067139 CIFC24 H43 F4 Ni P2P 1 21/c 113.137; 11.9971; 17.7312
90; 95.243; 90
2782.8Hatnean, Jillian A.; Beck, Robert; Borrelli, Jenna D.; Johnson, Samuel A.
Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation
Organometallics, 2010, 29, 6077
4065828 CIFC24 H43 N3 O Si2 Zn2P -110.1235; 10.4059; 14.147
89.213; 88.402; 84.352
1482.4Kahnes, Marcel; Görls, Helmar; González, Leticia; Westerhausen, Matthias
Synthesis and Catalytic Reactivity of Bis(alkylzinc)-hydride-di(2-pyridylmethyl)amides
Organometallics, 2010, 29, 3098
4067138 CIFC24 H44 F4 Ni P2P 1 21/c 110.887; 13.494; 20.7527
90; 113.002; 90
2806.4Hatnean, Jillian A.; Beck, Robert; Borrelli, Jenna D.; Johnson, Samuel A.
Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation
Organometallics, 2010, 29, 6077
4066678 CIFC24 H45 Cl2 F6 N Os P2 SiP -110.3264; 12.0488; 13.6302
89.589; 72.938; 87.127
1619.2Castro-Rodrigo, Ruth; Esteruelas, Miguel A.; López, Ana M.; Mozo, Silvia; Oñate, Enrique
C−H Bond Activation Reactions in π-Allene−Osmium−Triisopropylphosphine Complexes with Cyclopentadienyl or Hydridotris(pyrazolyl)borate Ligands: Formation of Isopropenyldiisopropylphosphine versus Hydride−Alkenylcarbyne Derivatives
Organometallics, 2010, 29, 4071
4083393 CIFC24 H45 Cl4 Li N2 O2 Si ZrP -19.001; 10.826; 19.583
104.77; 101.15; 95.94
1786.7Yuan, Shifang; Wei, Xuehong; Tong, Hongbo; Zhang, Liping; Liu, Diansheng; Sun, Wen-Hua
μ2,η1-N-[(N,N-Dimethylamino)dimethylsilyl]-2,6-diisopropylanilido Metal (Li, Zr, Hf) Compounds and the Catalytic Behaviors of the IVB Compounds in Ethylene (Co)Polymerizationξ
Organometallics, 2010, 29, 2085
4066731 CIFC24 H46 Cl2 O2 P2 PtP 1 21/n 19.8206; 8.7246; 16.2229
90; 90.457; 90
1389.95Achard, Thierry; Giordano, Laurent; Tenaglia, Alphonse; Gimbert, Yves; Buono, Gérard
Steric Control in the Synthesis of Phosphinous Acid-Coordinated Mono- and Binuclear Platinum(II) Complexes
Organometallics, 2010, 29, 3936
4083395 CIFC24 H49 Cl4 Hf Li N2 O2 SiP 1 21/c 114.164; 14.759; 17.027
90; 108.485; 90
3375.8Yuan, Shifang; Wei, Xuehong; Tong, Hongbo; Zhang, Liping; Liu, Diansheng; Sun, Wen-Hua
μ2,η1-N-[(N,N-Dimethylamino)dimethylsilyl]-2,6-diisopropylanilido Metal (Li, Zr, Hf) Compounds and the Catalytic Behaviors of the IVB Compounds in Ethylene (Co)Polymerizationξ
Organometallics, 2010, 29, 2085
4083394 CIFC24 H49 Cl4 Li N2 O2 Si ZrP 1 21/c 114.163; 14.743; 17.029
90; 108.56; 90
3370.8Yuan, Shifang; Wei, Xuehong; Tong, Hongbo; Zhang, Liping; Liu, Diansheng; Sun, Wen-Hua
μ2,η1-N-[(N,N-Dimethylamino)dimethylsilyl]-2,6-diisopropylanilido Metal (Li, Zr, Hf) Compounds and the Catalytic Behaviors of the IVB Compounds in Ethylene (Co)Polymerizationξ
Organometallics, 2010, 29, 2085
4067546 CIFC24 H50 Mg N8 Si4P 1 21/n 111.3901; 18.6622; 16.4869
90; 104.834; 90
3387.72Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4067141 CIFC24 H52 Ni P2C 1 2/c 112.854; 11.5975; 18.859
90; 102.332; 90
2746.5Hatnean, Jillian A.; Beck, Robert; Borrelli, Jenna D.; Johnson, Samuel A.
Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation
Organometallics, 2010, 29, 6077
4066353 CIFC24 H53 P2 RhP 1 21/c 111.2157; 11.7153; 21.1546
90; 101.08; 90
2727.8Urtel, Heiko; Meier, Claudia; Rominger, Frank; Hofmann, Peter
Neutralcis-Alkyl Olefin Rhodium(I) Complexes: Models of Intermediates in Late Transition Metal Olefin Polymerization with Surprising Structure†
Organometallics, 2010, 29, 5496
4065921 CIFC24 H54 Cl2 P2 Ru SiC 1 2/c 119.498; 12.003; 15.441
90; 120.064; 90
3128Collado, Alba; Esteruelas, Miguel A.; López, Fernando; Mascareñas, José L.; Oñate, Enrique; Trillo, Beatriz
C−H Bond Activation of Terminal Allenes: Formation of Hydride-Alkenylcarbyne-Osmium and Disubstituted Vinylidene-Ruthenium Derivatives∥
Organometallics, 2010, 29, 4966
4067156 CIFC24 H54 I3 Li N4 O2 Zn2P 21 21 2114.0039; 15.3589; 17.6619
90; 90; 90
3798.8Schmidt, Sarah; Schulz, Stephan; Bläser, Dieter; Boese, Roland; Bolte, Michael
Synthesis and Structural Characterization of New Zinc Amidinate Complexes
Organometallics, 2010, 29, 6097
4066081 CIFC24 H56 P8 Pd2P 1 21/n 111.778; 11.869; 14.363
90; 92.983; 90
2005.1Tanabe, Makoto; Hanzawa, Masaya; Osakada, Kohtaro
Preparation and Thermal Reaction of Tetrastannapalladacyclopentane. Sn−Sn Bond Formation and Cleavage
Organometallics, 2010, 29, 3535
4065912 CIFC24 H60 Mn2 O2 Si4P 1 21/c 110.1623; 15.533; 12.7114
90; 113.513; 90
1839.9Cámpora, Juan; Palma, Pilar; Pérez, Carmen M.; Rodríguez-Delgado, Antonio; Álvarez, Eleuterio; Gutiérrez-Puebla, Enrique
Synthesis and Reactions of Manganese(II) Dialkyl Complexes Containing Monodentate and Bidentate Nitrogen Ligands
Organometallics, 2010, 29, 2960
4067731 CIFC24 H72 Si12P c a 2124.391; 19.863; 18.147
90; 90; 90
8792Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4067070 CIFC24.5 H27 F12 N1.5 O P2 Ru S TeC 1 2/c 121.614; 11.1952; 27.619
90; 109.987; 90
6280.5Singh, Pradhumn; Singh, Ajai K.
Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Organometallics, 2010, 29, 6433
4066358 CIFC24.5 H28 B F N O0.5 SP 1 21/n 18.948; 35.296; 13.556
90; 96.815; 90
4251Matsumoto, Takeshi; Wade, Casey R.; Gabbaï, François P.
Synthesis and Lewis Acidic Behavior of a Cationic 9-Thia-10-boraanthracene†
Organometallics, 2010, 29, 5490
4066474 CIFC25 H15 Co2 O7 PP 21 21 217.9383; 10.553; 30.5205
90; 90; 90
2556.79Ungvári, Neszta; Fördős, Eszter; Balogh, János; Kégl, Tamás; Párkányi, László; Ungváry, Ferenc
Triphenylphosphane-Modified Cobalt Catalysts for the Selective Carbonylation of Ethyl Diazoacetate
Organometallics, 2010, 29, 3837
4066639 CIFC25 H16 N2 O4 Ru2P 1 21/n 19.4777; 15.288; 16.231
90; 106.233; 90
2258Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066298 CIFC25 H17 B F15 N OP -110.1478; 11.5115; 13.3066
93.857; 106.083; 107.488
1405.2Birkmann, Birgit; Voss, Tanja; Geier, Stephen J.; Ullrich, Matthias; Kehr, Gerald; Erker, Gerhard; Stephan, Douglas W.
Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane†
Organometallics, 2010, 29, 5310
4066053 CIFC25 H18 Cl F4 P PdP 1 21/c 112.554; 13.458; 14.177
90; 108.461; 90
2272Stanek, Kyrill; Czarniecki, Barbara; Aardoom, Raphael; Rüegger, Heinz; Togni, Antonio
Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
Organometallics, 2010, 29, 2540
4066052 CIFC25 H18 Cl F4 P PtP 1 21/c 112.451; 13.463; 14.172
90; 108.346; 90
2254.9Stanek, Kyrill; Czarniecki, Barbara; Aardoom, Raphael; Rüegger, Heinz; Togni, Antonio
Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
Organometallics, 2010, 29, 2540
4066588 CIFC25 H18 Fe O10 Os3 SiP 1 21/n 110.0652; 20.451; 14.215
90; 93.625; 90
2920.2Nievas, Ángel; Medel, María; Hernández, Elisa; Delgado, Esther; Martín, Avelino; Casado, Carmen M.; Alonso, Beatriz
Redox-Active Heterometallic Ferrocenylalkynyl Carbosilane Dendrimers Incorporating Os3(CO)10Clusters
Organometallics, 2010, 29, 4291
4066444 CIFC25 H19 Cl4 N2 Ni SiP 1 21/c 114.9511; 10.0728; 15.782
90; 97.116; 90
2358.45Yang, Jian; Del Rosal, Iker; Fasulo, Meg; Sangtrirutnugul, Preeyanuch; Maron, Laurent; Tilley, T. Don
Nickel Complexes with Bis(8-quinolyl)silyl Ligands. An Unusual Ni3Si2Cluster Containing Six-Coordinate Silicon†
Organometallics, 2010, 29, 5544
4066642 CIFC25 H19 N O6 Ru2P 21 21 2110.174; 13.461; 17.46
90; 90; 90
2391.2Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066643 CIFC25 H19 N O6 Ru2P 1 21/c 18.503; 24.246; 11.983
90; 108.543; 90
2342Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4065603 CIFC25 H20 Al Cl P2 S2P 1 21/c 111.5467; 19.957; 12.4806
90; 105.873; 90
2766.3Leung, Wing-Por; Wan, Chi-Ling; Mak, Thomas C. W.
Synthesis and Structure of Magnesium and Group 13 Metal Bis(thiophosphinoyl)methanediide Complexes
Organometallics, 2010, 29, 1622
4065605 CIFC25 H20 Cl In P2 S2P 1 21/c 111.6775; 20.458; 12.5404
90; 108.184; 90
2846.3Leung, Wing-Por; Wan, Chi-Ling; Mak, Thomas C. W.
Synthesis and Structure of Magnesium and Group 13 Metal Bis(thiophosphinoyl)methanediide Complexes
Organometallics, 2010, 29, 1622
4067514 CIFC25 H20 N O P SP 1 21/n 110.108; 16.831; 12.13
90; 91.406; 90
2063Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4067361 CIFC25 H20 P2 Pb S2 SeP 1 21/n 113.317; 10.7311; 18.023
90; 107.877; 90
2451.2Leung, Wing-Por; Wan, Chi-Ling; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis, Structure, and Reactivity of Group 14 Bis(thiophosphinoyl) Metal Complexes
Organometallics, 2010, 29, 814
4067357 CIFC25 H21 Cl Ge P2 S2P 1 21/n 116.213; 8.9053; 18.961
90; 113.28; 90
2514.7Leung, Wing-Por; Wan, Chi-Ling; Kan, Kwok-Wai; Mak, Thomas C. W.
Synthesis, Structure, and Reactivity of Group 14 Bis(thiophosphinoyl) Metal Complexes
Organometallics, 2010, 29, 814
4066693 CIFC25 H21 N O2 PtP 1 21/n 111.4588; 7.2054; 24.1972
90; 95.98; 90
1986.98Velusamy, Marappan; Chen, Chih-Hsin; Wen, Yuh S.; Lin, Jiann T.; Lin, Chao-Chen; Lai, Chin-Hung; Chou, Pi-Tai
Cyclometalated Platinum(II) Complexes of Lepidine-Based Ligands as Highly Efficient Electrophosphors
Organometallics, 2010, 29, 3912
4066641 CIFC25 H21 N O7 Ru2P -110.344; 11.453; 11.747
66.805; 66.35; 74.733
1162.5Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066475 CIFC25 H22 Co O5 PP 1 21/c 19.3676; 18.0352; 15.0701
90; 113.208; 90
2340.02Ungvári, Neszta; Fördős, Eszter; Balogh, János; Kégl, Tamás; Párkányi, László; Ungváry, Ferenc
Triphenylphosphane-Modified Cobalt Catalysts for the Selective Carbonylation of Ethyl Diazoacetate
Organometallics, 2010, 29, 3837
4066263 CIFC25 H22 I O Os P SP 21 n b7.8046; 16.4655; 18.1317
90; 90; 90
2330.04Johns, Paul M.; Roper, Warren R.; Woodgate, Scott D.; Wright, L. James
Thermal Rearrangement of Osmabenzenes to Osmium Cyclopentadienyl Complexes†
Organometallics, 2010, 29, 5358
4066856 CIFC25 H23 Cr Ni O3 PP -18.3909; 10.9602; 13.1562
97.727; 108.487; 102.647
1092.1Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066865 CIFC25 H23 Cr O3 P PdP -18.5082; 11.1139; 13.2573
73.955; 71.866; 76.402
1129.6Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066857 CIFC25 H23 Mo Ni O3 PP -18.45; 10.938; 13.325
74.115; 72.014; 78.008
1116.4Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066866 CIFC25 H23 Mo O3 P PdP -18.5989; 11.1644; 13.3408
73.565; 72.234; 78.113
1159.7Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066858 CIFC25 H23 Ni O3 P WP -18.4096; 10.9171; 13.3079
73.957; 71.755; 77.82
1104.7Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066867 CIFC25 H23 O3 P Pd WP -18.5381; 11.2989; 13.2368
72.732; 73.085; 78.033
1156.4Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066333 CIFC25 H25 Cl2 Fe N P2P 1 21/n 18.8526; 9.7236; 28.518
90; 97.079; 90
2436.09Limburg, Carolin; Lönnecke, Peter; Gómez-Ruiz, Santiago; Hey-Hawkins, Evamarie
Synthesis of Racemic Aminoalkylferrocenyldichlorophosphanes and -dialkylphosphonites and Their Conversion to Primary Phosphanes†
Organometallics, 2010, 29, 5427
4065621 CIFC25 H27 Cl2 Fe2 N O6 SeP 1 21/n 18.8137; 24.972; 12.8501
90; 104.709; 90
2735.6Busetto, Luigi; Marchetti, Fabio; Renili, Filippo; Zacchini, Stefano; Zanotti, Valerio
Addition of Alkynes to Zwitterionic μ-Vinyliminium Diiron Complexes: New Selenophene (Thiophene) and Vinyl Chalcogenide Functionalized Bridging Ligands
Organometallics, 2010, 29, 1797
4067129 CIFC25 H27 Fe I N O2 PC 1 c 18.6529; 20.7218; 13.1388
90; 99.379; 90
2324.34Yu, Insun; Wallis, Christopher J.; Patrick, Brian O.; Diaconescu, Paula L.; Mehrkhodavandi, Parisa
Phosphine-Tethered Carbene Ligands: Template Synthesis and Reactivity of Cyclic and Acyclic Functionalized Carbenes
Organometallics, 2010, 29, 6065
4065630 CIFC25 H28 Br2 N4 PdP 1 21 17.832; 16.907; 11.731
90; 92.313; 90
1552.1Xiao, Xu-Qiong; Jia, Ai-Quan; Lin, Yue-Jian; Jin, Guo-Xin
Self-Assembly of Palladium-Based Macrocycles with N-Heterocyclic Carbene as the “Corner” Ligand†
Organometallics, 2010, 29, 4842
4067774 CIFC25 H28 F3 N3 Ni O2P 21 21 219.455; 10.986; 23.714
90; 90; 90
2463Kieltsch, Iris; Dubinina, Galyna G.; Hamacher, Claudia; Kaiser, André; Torres-Nieto, Jorge; Hutchison, John M.; Klein, Axel; Budnikova, Yulia; Vicic, David A.
Magnitudes of Electron-Withdrawing Effects of the Trifluoromethyl Ligand in Organometallic Complexes of Copper and Nickel
Organometallics, 2010, 29, 1451
4066504 CIFC25 H28 N6 S3 SiP 1 21/n 112.7358; 14.504; 14.6495
90; 93.037; 90
2702.26Wagler, Jörg; Heine, Thomas; Hill, Anthony F.
Poly(methimazolyl)silanes: Syntheses and Molecular Structures†
Organometallics, 2010, 29, 5607
4066151 CIFC25 H30 Cl N5P -111.2342; 11.2603; 11.4874
111.193; 91.473; 115.376
1195.68Al Thagfi, Jameel; Dastgir, Sarim; Lough, Alan J.; Lavoie, Gino G.
Synthesis and Structural Characterization of the First Copper(I) Complexes with Bis(imino)-N-heterocyclic Carbene NCN Pincer Ligands
Organometallics, 2010, 29, 3133
4067073 CIFC25 H30 F12 N2 O P2 Ru S TeP -110.182; 11.275; 15.173
96.173; 98.567; 109.155
1604.1Singh, Pradhumn; Singh, Ajai K.
Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
Organometallics, 2010, 29, 6433
4067033 CIFC25 H30 Ir N O3 PP -113.0064; 13.386; 14.1812
90.959; 102.327; 109.466
2263.8Liniger, Marc; Gschwend, Björn; Neuburger, Markus; Schaffner, Silvia; Pfaltz, Andreas
Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage
Organometallics, 2010, 29, 5953
4063486 CIFC25 H31 Al Cl4 Fe N O2 P SiP n a 2124.434; 10.1909; 12.7949
90; 90; 90
3186Vaheesar, Kandasamy; Bolton, Timothy M.; East, Allan L. L.; Sterenberg, Brian T.
Si‒H Bond Activation by Electrophilic Phosphinidene Complexes
Organometallics, 2010, 29, 484-490
4067773 CIFC25 H31 N3 Ni O2P 21 21 219.244; 10.575; 24.129
90; 90; 90
2358.7Kieltsch, Iris; Dubinina, Galyna G.; Hamacher, Claudia; Kaiser, André; Torres-Nieto, Jorge; Hutchison, John M.; Klein, Axel; Budnikova, Yulia; Vicic, David A.
Magnitudes of Electron-Withdrawing Effects of the Trifluoromethyl Ligand in Organometallic Complexes of Copper and Nickel
Organometallics, 2010, 29, 1451
4066124 CIFC25 H31 N3 O3 PdP 1 21/n 18.3518; 11.94; 26.064
90; 91.688; 90
2598Chen, Ying; Mandal, Sukhendu; Sen, Ayusman
Synthesis of (N−O)-Ligated Palladium(II) Complexes and Their Use in Ethene Homopolymerization and Norbornene Copolymerizations
Organometallics, 2010, 29, 3160
4067677 CIFC25 H31 N3 O4 S2P 1 21/c 111.8932; 10.8548; 19.8155
90; 97.2262; 90
2537.83Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4067232 CIFC25 H32 Cl F6 N4 P RuP n a 2122.358; 12.9581; 19.088
90; 90; 90
5530.1Ghattas, Wadih; Müller-Bunz, Helge; Albrecht, Martin
[Ru(bpy)3]2+Analogues Containing an N-Heterocyclic Carbene Ligand
Organometallics, 2010, 29, 6782
4065968 CIFC25 H33 Cl N2 O2 P PdP 21 21 2110.182; 11.955; 21.988
90; 90; 90
2676.5Zhang, Ben-Shang; Wang, Wei; Shao, Dan-Dan; Hao, Xin-Qi; Gong, Jun-Fang; Song, Mao-Ping
Unsymmetrical Chiral PCN Pincer Palladium(II) and Nickel(II) Complexes of (Imidazolinyl)aryl Phosphinite Ligands: Synthesis via Ligand C−H Activation, Crystal Structures, and Catalytic Studies
Organometallics, 2010, 29, 2579
4065947 CIFC25 H33 Cl2 O4.5 P2 Ru S4P b c a12.856; 22.4052; 23.8151
90; 90; 90
6859.7Wang, Xi-Ying; Li, Yan; Ma, Qing; Zhang, Qian-Feng
Ruthenium Complexes with Dithiophosphonates [Ar(RO)PS2]−and [Fc(RO)PS2]−(Ar =p-CH3OC6H4, Fc = Fe(η5-C5H4)(η5-C5H5))
Organometallics, 2010, 29, 2752
4066351 CIFC25 H33 O2 RhP 1 21/c 19.1973; 16.598; 15.441
90; 94.38; 90
2350.3Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
Organometallics, 2010, 29, 5481
4065870 CIFC25 H34 B Cl N7 PtC 1 c 112.6745; 24.5151; 9.8781
90; 119.46; 90
2672.4Engelman, Kristi L.; White, Peter S.; Templeton, Joseph L.
Synthesis of Isonitrile, Iminoacyl, and Aminocarbene Tp′Pt Complexes†
Organometallics, 2010, 29, 4943
4065868 CIFC25 H34 B N7 PtP 1 21/n 110.9517; 19.4849; 12.2946
90; 93.826; 90
2617.73Engelman, Kristi L.; White, Peter S.; Templeton, Joseph L.
Synthesis of Isonitrile, Iminoacyl, and Aminocarbene Tp′Pt Complexes†
Organometallics, 2010, 29, 4943
4067244 CIFC25 H34 Cl2 N2 O2 Pt SP 1 21/n 17.625; 15.749; 23.59
90; 101.158; 90
2779Tomooka, Katsuhiko; Shimada, Maki; Uehara, Kazuhiro; Ito, Masato
A Unique Functional Group Transformation of Planar Chiral Diolefinic Organonitrogen Cycles Utilizing PtCl2(2,4,6-trimethylpyridine) Complexes
Organometallics, 2010, 29, 6632
4067245 CIFC25 H34 Cl2 N2 O3 Pt SP 1 21/c 17.529; 15.667; 23.236
90; 96.763; 90
2721.8Tomooka, Katsuhiko; Shimada, Maki; Uehara, Kazuhiro; Ito, Masato
A Unique Functional Group Transformation of Planar Chiral Diolefinic Organonitrogen Cycles Utilizing PtCl2(2,4,6-trimethylpyridine) Complexes
Organometallics, 2010, 29, 6632
4067487 CIFC25 H34 Ge N2P b c a14.35; 16.739; 19.434
90; 90; 90
4668.1Ruddy, Adam J.; Rupar, Paul A.; Bladek, Kamila J.; Allan, Christopher J.; Avery, Jessica C.; Baines, Kim M.
On the Bonding in N-Heterocyclic Carbene Complexes of Germanium(II)
Organometallics, 2010, 29, 1362
4065764 CIFC25 H35 Mo2 O2 P Se3P -323.367; 23.367; 9.183
90; 90; 120
4342.3Esther García, M.; García-Vivó, Daniel; Ruiz, Miguel A.
Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C−E Bond Formation and C−O Bond Cleavage Processes in the Reactions of [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(μ-CO)] with Severalp-Block Elements (E) and Their Hydride Derivatives
Organometallics, 2010, 29, 2157
4067198 CIFC25 H36 F6 Ir2 N O PC 1 2/c 127.7377; 8.8279; 22.6147
90; 94.363; 90
5521.5Royer, Aaron M.; Rauchfuss, Thomas B.; Gray, Danielle L.
Organoiridium Pyridonates and Their Role in the Dehydrogenation of Alcohols
Organometallics, 2010, 29, 6763
4065558 CIFC25 H39 N Ni P2C 1 c 18.5271; 18.755; 15.7321
90; 103.621; 90
2445.2Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4065559 CIFC25 H39 N Ni P2P -18.2245; 10.6224; 14.7022
91.606; 106.009; 95.109
1227.87Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4065833 CIFC25 H39 N3 Si2 ZnP -18.1588; 11.0074; 15.8174
90.658; 98.133; 102.576
1371.18Drouin, Frédéric; Oguadinma, Paul O.; Whitehorne, Todd J. J.; Prud’homme, Robert E.; Schaper, Frank
Lactide Polymerization with Chiral β-Diketiminate Zinc Complexes
Organometallics, 2010, 29, 2139
4065658 CIFC25 H40 B F4 O P RuP -112.2618; 14.8597; 15.2625
110.465; 97.596; 92.709
2569.4Yi, Chae S.; Lee, Do W.
Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation.
Organometallics, 2010, 29, 1883-1885
4067497 CIFC25 H40 Cl F6 P3 Pd RuP 1 21/c 115.5266; 11.4714; 19.2563
90; 117.13; 90
3052.41Bonnet, Sylvestre; Lutz, Martin; Spek, Anthony L.; van Koten, Gerard; Klein Gebbink, Robertus J. M.
Bimetallic η6,η1SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure, and Catalytic Activity
Organometallics, 2010, 29, 1157
4065672 CIFC25 H40 Cl2 Ge N2 O2P -18.5449; 8.8873; 18.88
78.89; 79.44; 81.13
1372.5Rupar, Paul A.; Staroverov, Viktor N.; Baines, Kim M.
Reactivity Studies of N-Heterocyclic Carbene Complexes of Germanium(II)†
Organometallics, 2010, 29, 4871
4066852 CIFC25 H40 Mn3 N2 O9 Se3P -110.28; 12.077; 15.155
104.021; 97.014; 110.291
1667.67Ho, Chia-Hua; Chu, Yen-Yi; Lin, Chien-Nan; Chen, Horng-Wen; Huang, Chung-Yi; Shieh, Minghuey
Selenium−Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations
Organometallics, 2010, 29, 4396
4066328 CIFC25 H40 N2 O2 Si WP b c a13.4319; 28.3133; 13.6054
90; 90; 90
5174.15Suzuki, Eiji; Komuro, Takashi; Kanno, Yuto; Okazaki, Masaaki; Tobita, Hiromi
Facile 1,2-Migration of a Methyl Group on a {Dimethoxy(methyl)silyl}tungsten Complex: Formation of a Base-Stabilized (Dimethoxysilylene)(methyl) Complex†
Organometallics, 2010, 29, 5296
4065725 CIFC25 H41 B2 N2 O YP 1 21/n 112.6209; 16.4405; 13.805
90; 109.947; 90
2692.6Li, Danfeng; Li, Shihui; Cui, Dongmei; Zhang, Xuequan
β-Diketiminato Rare-Earth Metal Complexes. Structures, Catalysis, and Active Species for Highlycis-1,4-Selective Polymerization of Isoprene
Organometallics, 2010, 29, 2186
4066017 CIFC25 H45 P3 Ru S2P 21 21 2116.183; 18.546; 10.144
90; 90; 90
3044.5Hirano, Masafumi; Togashi, Sayaka; Ito, Muneaki; Sakaguchi, Yuko; Komine, Nobuyuki; Komiya, Sanshiro
Carbon−Hydrogen Bond Cleavage Reaction in 5-Coordinate Bis(2,6-dimethylbenzenethiolato)ruthenium(II) Complexes
Organometallics, 2010, 29, 3146
4067178 CIFC25 H46 N3 TiP 1 21/c 110.501; 14.624; 16.936
90; 96.09; 90
2586.1Trunkely, Emily F.; Epshteyn, Albert; Zavalij, Peter Y.; Sita, Lawrence R.
Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens
Organometallics, 2010, 29, 6587
4066442 CIFC25 H47 Cl4 N3 NiP n m a27.4381; 14.4903; 7.8339
90; 90; 90
3114.7Yang, Jian; Del Rosal, Iker; Fasulo, Meg; Sangtrirutnugul, Preeyanuch; Maron, Laurent; Tilley, T. Don
Nickel Complexes with Bis(8-quinolyl)silyl Ligands. An Unusual Ni3Si2Cluster Containing Six-Coordinate Silicon†
Organometallics, 2010, 29, 5544
4067014 CIFC25 H48 Cl2 Ir2 N2 O2 S2P 1 21/c 113.288; 12.823; 19.34
90; 90.969; 90
3295Ito, Masato; Watanabe, Akira; Shibata, Yuji; Ikariya, Takao
Synthesis and Reactivity of 2-Aminoethanethiolato-Bridged Dinuclear Ru(hmb) Complexes (hmb = η6-hexamethylbenzene): Mechanistic Consideration on Transfer Hydrogenation with Bifunctional [RuCl2(hmb)]2/2-Aminoethanethiol Catalyst System
Organometallics, 2010, 29, 4584
4067383 CIFC25 H50 Li2 N2 O2 Si2P 21 21 2110.394; 14.923; 19.5851
90; 90; 90
3037.8Sudupe, María; Cano, Jesús; Royo, Pascual; Mosquera, Marta E. G.; Frutos, Luis M.; Castaño, Obis
Regioselective Synthesis of 1,2- and 1,3-Di(silylamido)cyclopentadienyl Zirconium Complexes
Organometallics, 2010, 29, 263
4067728 CIFC25 H62 K O6 Si7P 1 21/c 110.366; 19.171; 21.17
90; 90.37; 90
4207Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4066560 CIFC25.25 H33 B Cl0.5 F3 N3 O8 Rh SP 1 21/c 116.0976; 9.3701; 21.069
90; 103.651; 90
3088.2Ho, Hung-An; Dunne, James F.; Ellern, Arkady; Sadow, Aaron D.
Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition
Organometallics, 2010, 29, 4105
4063340 CIFC258 H330 N18 O6 Sr6P a -328.6787; 28.6787; 28.6787
90; 90; 90
23587.3Merle Arrowsmith; Michael S. Hill; Gabriele Kociok-Kḧon
Dearomatization and C‒H Deprotonation with Heavier Group 2 Alkyls: Does Size Matter?
Organometallics, 2010, 29, 4203-4206
4067749 CIFC26 H15 N O11 Ru4P -19.1494; 12.2864; 13.4511
104.05; 91.887; 91.709
1464.93Osintseva, Svetlana V.; Dolgushin, Fedor M.; Shtel’tser, Nikolay A.; Petrovskii, Pavel V.; Peregudov, Alexander S.; Kreindlin, Arkadii Z.; Antipin, Mikhail Yu.
Isolation and Characterization of New Mono- and Polynuclear Complexes Formed in the Thermal Reaction of Ru3(CO)12with 1-(4-Tolyl)-3-phenylaminoprop-2-en-1-one
Organometallics, 2010, 29, 1012
4063489 CIFC26 H18 Al2 F24 O10P -19.455; 12.262; 17.853
73.155; 85.258; 73.524
1899.7Bouyahyi, Miloud; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated β-Diketonate Ligands: Syntheses, Structures, Intramolecular Reduction, and Use in Ring-Opening Polymerization of Lactide
Organometallics, 2010, 29, 491-500
4067517 CIFC26 H21 Cl3 N O P Pd SC 1 2/c 131.0174; 9.9746; 17.4994
90; 109.13; 90
5115.1Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4067520 CIFC26 H21 Cl3 N O2 P PdC 1 2/c 130.418; 9.9067; 17.049
90; 104.959; 90
4963.5Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4067431 CIFC26 H21 Fe2 O6 P S2P 1 21/c 19.2085; 17.506; 16.61
90; 102.28; 90
2616.3Song, Li-Cheng; Liu, Xu-Feng; Ming, Jiang-Bo; Ge, Jian-Hua; Xie, Zhao-Jun; Hu, Qing-Mei
Reactions Starting from Diiron Propanedithiolate [(μ-SCH2)2CH(OH)]Fe2(CO)6Leading to Malonyl-, PPh3-, and [60]Fullerene-Containing Compounds Relevant to the Active Site of FeFe-Hydrogenases
Organometallics, 2010, 29, 610
4066535 CIFC26 H22P 1 21/c 129.3956; 6.5728; 9.5187
90; 99.019; 90
1816.38Tse, Sunny Kai San; Bai, Wei; Sung, Herman Ho-Yung; Williams, Ian Duncan; Jia, Guochen
Substituted Cyclopentadienyl Osmium Complexes from the Reactions of OsH3Cl(PPh3)3with Fulvenes and Cyclopentadienes
Organometallics, 2010, 29, 3571
4066665 CIFC26 H22 B F12 PP 1 21 19.1404; 14.5553; 9.6209
90; 95.758; 90
1273.52Ullrich, Matthias; Lough, Alan J.; Stephan, Douglas W.
Dihydrogen Activation by B(p-C6F4H)3and Phosphines
Organometallics, 2010, 29, 3647
4066770 CIFC26 H24 Fe2 N0 O4P 1 21/c 115.826; 10.417; 12.881
90; 92.109; 90
2122.1Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Synthesis and Biological Evaluation of Ferrocene-Containing Bioorganometallics Inspired by the Antibiotic Platensimycin Lead Structure
Organometallics, 2010, 29, 4312
4066859 CIFC26 H25 Cr Ni O3 PP 1 21/n 111.393; 8.755; 22.628
90; 93.019; 90
2253.9Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066860 CIFC26 H25 Mo Ni O3 PP 1 21/c 18.2327; 16.7888; 17.0404
90; 97.879; 90
2333Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066861 CIFC26 H25 Ni O3 P WP 1 21/c 18.2117; 16.7981; 16.9721
90; 97.758; 90
2319.7Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4067408 CIFC26 H25 O7 P WC 1 2/c 132.9185; 8.9633; 20.9422
90; 120.628; 90
5317.1Bode, Maren; Schnakenburg, Gregor; Daniels, Jörg; Marinetti, Angela; Streubel, Rainer
Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
Organometallics, 2010, 29, 656
4067148 CIFC26 H25 P Ru S2P 1 21/n 110.3945; 13.3983; 16.7759
90; 95.676; 90
2324.9Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Preparation of Thiolate-Bridged Dinuclear Ruthenium Complexes Bearing a Phosphine Ligand and Application to Propargylic Reduction of Propargylic Alcohols with 2-Propanol
Organometallics, 2010, 29, 5994
4066580 CIFC26 H26 B Br FeP 1 21/c 118.58; 8.489; 14.824
90; 112.392; 90
2162Morgan, Ian R.; Broomsgrove, Alexander E. J.; Fitzpatrick, Philip; Vidovic, Dragoslav; Thompson, Amber L.; Fallis, Ian A.; Aldridge, Simon
Anion Recognition by Highly Sterically Encumbered 1,2-Diborylferrocenes§
Organometallics, 2010, 29, 4762
4066740 CIFC26 H26 Cl Ir N2P -17.8523; 8.8868; 15.8642
99.095; 90.4; 107.603
1040.16Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4067171 CIFC26 H26 Cl O4 PC 1 2/c 127.352; 10.2322; 20.664
90; 125.869; 90
4686.5Xu, Tao; Gong, Wei-tao; Ye, Jun-wei; Lin, Yuan; Ning, Gui-ling
Unprecedented Ring Transformation of an α,α′-Monosubstituted 2,4,5-Triphenylpyrylium Salt with η3-Phosphines: Efficient Synthesis of Aryl- and Alkylphosphonium Triphenylcyclopentadienylides
Organometallics, 2010, 29, 6744
4067169 CIFC26 H26 Cl O5 PP 1 21/n 110.6802; 22.1133; 11.5904
90; 114.767; 90
2485.6Xu, Tao; Gong, Wei-tao; Ye, Jun-wei; Lin, Yuan; Ning, Gui-ling
Unprecedented Ring Transformation of an α,α′-Monosubstituted 2,4,5-Triphenylpyrylium Salt with η3-Phosphines: Efficient Synthesis of Aryl- and Alkylphosphonium Triphenylcyclopentadienylides
Organometallics, 2010, 29, 6744
4066737 CIFC26 H26 I Ir N2P -18.452; 8.8909; 15.7666
98.728; 91.87; 109.643
1098.46Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4067410 CIFC26 H27 O8 P WP 21 21 2110.2703; 11.9683; 21.9
90; 90; 90
2691.9Bode, Maren; Schnakenburg, Gregor; Daniels, Jörg; Marinetti, Angela; Streubel, Rainer
Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
Organometallics, 2010, 29, 656
4066719 CIFC26 H28 F6 N6 P RhP 1 21/c 112.544; 30.2673; 14.2925
90; 90.896; 90
5425.81Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4065639 CIFC26 H28 O9 Ru SiP 418.3891; 8.3891; 39.28
90; 90; 90
2764.4Yamamoto, Yoshihiko; Yamashita, Ken; Nakamura, Mitsutaka
Synthesis of Organometallic Analogues of SpirocyclicC-Arylribosides
Organometallics, 2010, 29, 1472
4066870 CIFC26 H29 F6 N2 P Ru S3P 1 21/c 115.6662; 12.0021; 15.9451
90; 108.707; 90
2839.7Wong, Chun-Yuen; Lai, Lo-Ming; Chan, Siu-Chung; Tai, Lai-Hung
Photophysical and Theoretical Studies of Ruthenium(II)−Acetylide and −Cyanide Complexes with Aromatic Diimine and Trithiacyclononane
Organometallics, 2010, 29, 6259
4066974 CIFC26 H29 P PdP -19.3455; 9.9853; 13.943
72.6291; 83.6782; 70.4556
1170.16Wu, Jianguo; Green, Jennifer C.; Hazari, Nilay; Hruszkewycz, Damian P.; Incarvito, Christopher D.; Schmeier, Timothy J.
The Reaction of Carbon Dioxide with Palladium Allyl Bonds.
Organometallics, 2010, 29, 6369-6376
4067127 CIFC26 H30 Cl2 Fe I N2 O PP 1 21/c 18.6746; 22.2743; 14.2245
90; 100.86; 90
2699.24Yu, Insun; Wallis, Christopher J.; Patrick, Brian O.; Diaconescu, Paula L.; Mehrkhodavandi, Parisa
Phosphine-Tethered Carbene Ligands: Template Synthesis and Reactivity of Cyclic and Acyclic Functionalized Carbenes
Organometallics, 2010, 29, 6065
4066205 CIFC26 H30 F5 O TiC 1 2/c 110.7005; 15.342; 14.6337
90; 101.854; 90
2351.14Gyepes, Róbert; Varga, Vojtech; Horáček, Michal; Kubišta, Jiří; Pinkas, Jiří; Mach, Karel
Influence of the Ti−O−C Angle on the Oxygen-to-Titanium π-Donation in [Cp2*Ti(III)OR] Complexes∥
Organometallics, 2010, 29, 3780
4066725 CIFC26 H30 F6 N4 P RhC 1 2/c 116.148; 17.1483; 20.4711
90; 93.2324; 90
5659.6Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4066075 CIFC26 H30 Fe2 O Si2P -17.5914; 14.408; 23.51
73.749; 83.146; 78.529
2413.8Bruña, Sonia; González-Vadillo, Ana M; Nieto, Daniel; Pastor, César; Cuadrado, Isabel
Vinyl-Functionalized Silanes and Disiloxanes with Electronically Communicated Ferrocenyl Units†
Organometallics, 2010, 29, 2796
4067553 CIFC26 H30 Mg N12C 1 2/m 135.6839; 13.3948; 8.075
90; 94.3134; 90
3848.7Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4065849 CIFC26 H30 Mn O2P -19.094; 9.775; 13.066
80.539; 72.62; 71.148
1046Crisp, Jeffrey A.; Meier, Ryan M.; Overby, Jason S.; Hanusa, Timothy P.; Rheingold, Arnold L.; Brennessel, William W.
Indenyl Complexes of Manganese(II). Conformational Flexibility of the Manganese(II)−(RnC9H7−n) Bond
Organometallics, 2010, 29, 2322
4066130 CIFC26 H33 B Mo N6 O9P 21 21 2110.3216; 16.393; 17.924
90; 90; 90
3032.8Coombs, Thomas C.; Huang, Wenwei; Garnier-Amblard, Ethel C; Liebeskind, Lanny S.
Novel Substitutions of 1-Alkoxy- and 1-Arylsulfonyloxy-η-Allylmolybdenum Complexes. A Case for η-Alkenyl Carbene Complexes as Intermediates.
Organometallics, 2010, 29, 5083-5097
4067393 CIFC26 H33 Cl Ir O4 P3P 1 21/n 19.8246; 12.7951; 22.0739
90; 96.089; 90
2759.18Langer, Jens; Imhof, Wolfgang; Fabra, Maria José; García-Orduña, Pilar; Görls, Helmar; Lahoz, Fernando J.; Oro, Luis A.; Westerhausen, Matthias
Reversible CO2Fixation by Iridium(I) Complexes Containing Me2PhP as Ligand
Organometallics, 2010, 29, 1642
4066123 CIFC26 H33 N O3 Pd SP 1 21/n 19.628; 15.109; 17.184
90; 95.874; 90
2486.6Chen, Ying; Mandal, Sukhendu; Sen, Ayusman
Synthesis of (N−O)-Ligated Palladium(II) Complexes and Their Use in Ethene Homopolymerization and Norbornene Copolymerizations
Organometallics, 2010, 29, 3160
4067578 CIFC26 H34 Cl F6 N4 P Ru2P -19.7135; 11.8784; 14.03
82.334; 76.888; 72.988
1503.7Mutseneck, Elena V.; Reus, Christian; Schödel, Frauke; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Reactions of [Cp*RuCl]4and [(p-cymene)RuCl2]2with the Tridentate Ligand [Ph(pz)B(μ-O)(μ-pz)B(pz)Ph]−
Organometallics, 2010, 29, 966
4067544 CIFC26 H34 N2 S ZnP 1 21/c 115.422; 9.7429; 17.688
90; 113.713; 90
2433.3Dochnahl, Maximilian; Löhnwitz, Karolin; Lühl, Anja; Pissarek, Jens-Wolfgang; Biyikal, Mustafa; Roesky, Peter W.; Blechert, Siegfried
Functionalized Aminotroponiminate Zinc Complexes as Catalysts for the Intramolecular Hydroamination of Alkenes
Organometallics, 2010, 29, 2637
4067252 CIFC26 H36 Cl6 Ir2 O13P 1 21/m 17.9845; 23.481; 10.7492
90; 106.231; 90
1935Bischof, Steven M.; Ess, Daniel H.; Meier, Steven K.; Oxgaard, Jonas; Nielsen, Robert J.; Bhalla, Gaurav; Goddard, William A.; Periana, Roy A.
Benzene C−H Bond Activation in Carboxylic Acids Catalyzed by O-Donor Iridium(III) Complexes: An Experimental and Density Functional Study
Organometallics, 2010, 29, 742
4066255 CIFC26 H36 Ni O4 P2P -18.4311; 8.955; 10.1684
65.472; 79.661; 75.752
674.35Ananikov, Valentine P.; Gayduk, Konstantin A.; Starikova, Zoya A.; Beletskaya, Irina P.
Ni(acac)2/Phosphine as an Excellent Precursor of Nickel(0) for Catalytic Systems†
Organometallics, 2010, 29, 5098
4067679 CIFC26 H37 Al N2 O5 S2P 1 21/c 110.6103; 16.4039; 16.3028
90; 92.3235; 90
2835.17Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4067143 CIFC26 H37 Li N2 OP c a 2116.436; 8.7758; 17.154
90; 90; 90
2474.3Bhadbhade, Mohan; Clentsmith, Guy K. B.; Field, Leslie D.
Sterically Hindered Diazabutadienes (DABs): Competing Reaction Pathways with MeLi
Organometallics, 2010, 29, 6509
4066754 CIFC26 H38 Co2P 1 21/c 19.5675; 14.2717; 8.9283
90; 111.827; 90
1131.71Aguirre-Etcheverry, Paulina; Ashley, Andrew E.; Balázs, Gábor; Green, Jennifer C.; Cowley, Andrew R.; Thompson, Amber L.; O’Hare, Dermot
Synthesis, Structure, and Ligand Exchange Reactions of Tetramethyleneethane Complexes of Cobalt
Organometallics, 2010, 29, 5847
4065561 CIFC26 H38 N2 Ni P2P 1 21/c 116.819; 10.654; 15.636
90; 111.709; 90
2603.1Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4065562 CIFC26 H38 N2 Ni P2P -110.3484; 16.1122; 16.7162
71.985; 81.383; 77.661
2578.8Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4067302 CIFC26 H41 Mo N5 O6 TiP -110.1513; 13.5008; 15.0634
100.794; 108.827; 103.517
1820.8Lorber, Christian; Vendier, Laure
Imido−Titanium/Molybdenum Heterobimetallic Systems. Switching from η6-Arene to Fischer-Type Aminocarbene Complexes by Tuning Reactivity Conditions
Organometallics, 2010, 29, 1127
4067312 CIFC26 H42.5 F6 N4 O2.75 P Pd2C 1 2 128.2448; 8.7037; 13.8195
90; 97.382; 90
3369.1Ficks, Arne; Sibbald, Connor; John, Michael; Dechert, Sebastian; Meyer, Franc
Dinuclear Allylpalladium Complexes ofC2-Symmetric Pyrazolate-Bridged Bis(oxazoline) Ligands (pyrbox's): Structures, Dynamic Behavior, and Application in Asymmetric Allylic Alkylation
Organometallics, 2010, 29, 1117
4067304 CIFC26 H43 Mo N5 O6 TiP 1 21/n 110.6408; 25.6907; 13.1933
90; 113.001; 90
3319.9Lorber, Christian; Vendier, Laure
Imido−Titanium/Molybdenum Heterobimetallic Systems. Switching from η6-Arene to Fischer-Type Aminocarbene Complexes by Tuning Reactivity Conditions
Organometallics, 2010, 29, 1127
4067593 CIFC26 H44 Hf N6P n a 2113.693; 14.262; 14.705
90; 90; 90
2871.7Panda, Tarun K.; Tsurugi, Hayato; Pal, Kuntal; Kaneko, Hiroshi; Mashima, Kazushi
Highly Reactive Metal−Nitrogen Bond Induced C−H Bond Activation and Azametallacycle Formation
Organometallics, 2010, 29, 34
4067592 CIFC26 H44 N6 ZrP n a 2113.737; 14.285; 14.705
90; 90; 90
2885.6Panda, Tarun K.; Tsurugi, Hayato; Pal, Kuntal; Kaneko, Hiroshi; Mashima, Kazushi
Highly Reactive Metal−Nitrogen Bond Induced C−H Bond Activation and Azametallacycle Formation
Organometallics, 2010, 29, 34
4063495 CIFC26 H44 O4 Si2P -17.9041; 12.4809; 16.3912
111.863; 90.997; 99.96
1472.1Chen, Jingjin; Liu, Yuanhong
Highly Stereoselective Synthesis of Trisubstituted cis-[3]Cumulenols from Alkynylated Oxatitanacycles in the Presence of Lewis acids
Organometallics, 2010, 29, 505-508
4066199 CIFC26 H46 N2 O2 P2 PdP 1 21/c 110.226; 7.2469; 20.575
90; 113.33; 90
1400.1Kessler, Florian; Weibert, Bernhard; Fischer, Helmut
Bis(allenylidene) Complexes of Palladium and Platinum†
Organometallics, 2010, 29, 5154
4066784 CIFC26 H46 P2 Pd Si4P n a 2115.7495; 18.0326; 11.3822
90; 90; 90
3232.6Li, Yong-Hua; Shimada, Shigeru
Ligand-Dependent Selective Formation of Unique Silylpalladium Complexes by the Reaction of 1-(Dimethylsilyl)-2-silylbenzene and [{1,2-C6H4(SiMe2)(SiH2)}Pd(R2PCH2CH2PR2)]
Organometallics, 2010, 29, 4406
4066235 CIFC26 H46 Si2 TiP 1 21/c 19.8715; 34.7068; 8.403
90; 114.441; 90
2620.94Pinkas, Jiří; Lukešová, Lenka; Gyepes, Róbert; Císařová, Ivana; Kubišta, Jiří; Horáček, Michal; Mach, Karel
Reduction-Induced Exclusive Activation of theansa-1,2-Bis(dimethylsilylene)ethane Chain inansa-Permethyltitanocene Compounds§
Organometallics, 2010, 29, 5199
4067547 CIFC26 H47 Ca N7 O Si2C 1 2/c 139.3059; 8.599; 20.6529
90; 110.691; 90
6530.3Cushion, Michael G.; Meyer, Jens; Heath, Alex; Schwarz, Andrew D.; Fernández, Ignacio; Breher, Frank; Mountford, Philip
Syntheses and Structural Diversity of Group 2 and Group 12 Tris(pyrazolyl)methaneand Zwitterionic Tris(pyrazolyl)methanideCompounds
Organometallics, 2010, 29, 1174
4065809 CIFC26 H48.667 Cl Ir P2P 6516.316; 16.316; 19.1731
90; 90; 120
4420.3Punji, Benudhar; Emge, Thomas J.; Goldman, Alan S.
A Highly Stable Adamantyl-Substituted Pincer-Ligated Iridium Catalyst for Alkane Dehydrogenation
Organometallics, 2010, 29, 2702
4066395 CIFC26 H50 Ir N O P2P 1 21/n 18.5056; 20.0077; 16.4676
90; 101.969; 90
2741.49Schwartsburd, Leonid; Iron, Mark A.; Konstantinovski, Leonid; Diskin-Posner, Yael; Leitus, Gregory; Shimon, Linda J. W.; Milstein, David
Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization
Organometallics, 2010, 29, 3817
4065830 CIFC26 H51 N3 Si4 Zn2P -19.1445; 13.1954; 16.4616
71.47; 75.791; 70.081
1749.6Kahnes, Marcel; Görls, Helmar; González, Leticia; Westerhausen, Matthias
Synthesis and Catalytic Reactivity of Bis(alkylzinc)-hydride-di(2-pyridylmethyl)amides
Organometallics, 2010, 29, 3098
4065916 CIFC26 H54 Mn2 N2 Si4C 1 2/c 117.769; 10.917; 20.009
90; 110.27; 90
3641.1Cámpora, Juan; Palma, Pilar; Pérez, Carmen M.; Rodríguez-Delgado, Antonio; Álvarez, Eleuterio; Gutiérrez-Puebla, Enrique
Synthesis and Reactions of Manganese(II) Dialkyl Complexes Containing Monodentate and Bidentate Nitrogen Ligands
Organometallics, 2010, 29, 2960
4066445 CIFC26 H54 O Si5P 1 21/n 111.464; 16.126; 16.845
90; 90.059; 90
3114.1Ishida, Shintaro; Iwamoto, Takeaki; Kira, Mitsuo
Reactions of an Isolable Dialkylsilylene with Ketones†
Organometallics, 2010, 29, 5526
4066926 CIFC26 H55 F6 N2 O2.5 Os P2 SiP 1 21/c 114.676; 15.476; 16.336
90; 109.164; 90
3505Baya, Miguel; Esteruelas, Miguel A.; Oñate, Enrique
Efficient Concatenation of C═C Reduction, C−H Bond Activation, and C−C and C−N Coupling Reactions on Osmium: Assembly of Two Allylamines and an Allene
Organometallics, 2010, 29, 6298
4066354 CIFC26 H55 O2 P2 RhP 1 21/c 19.0537; 17.0093; 19.0625
90; 94.062; 90
2928.2Urtel, Heiko; Meier, Claudia; Rominger, Frank; Hofmann, Peter
Neutralcis-Alkyl Olefin Rhodium(I) Complexes: Models of Intermediates in Late Transition Metal Olefin Polymerization with Surprising Structure†
Organometallics, 2010, 29, 5496
4067639 CIFC26 H72 Si11P 1 21/n 113.572; 18.57; 17.526
90; 92.864; 90
4411.6Iwamoto, Takeaki; Furiya, Yuichi; Kobayashi, Hideki; Isobe, Hiroyuki; Kira, Mitsuo
Synthesis and Facile Ring Expansion of Silylenecyclotetrasilane
Organometallics, 2010, 29, 1869
4067640 CIFC26 H72 Si11P 21 21 2111.85; 16.464; 22.984
90; 90; 90
4484.1Iwamoto, Takeaki; Furiya, Yuichi; Kobayashi, Hideki; Isobe, Hiroyuki; Kira, Mitsuo
Synthesis and Facile Ring Expansion of Silylenecyclotetrasilane
Organometallics, 2010, 29, 1869
4067683 CIFC26.25 H31.5 Al Cl3.5 N3 O4 S2P 1 21/n 19.6887; 24.7319; 25.5491
90; 90.8599; 90
6121.38Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4066965 CIFC26.5 H33.5 Cl2.5 N2 PdP -18.9523; 11.2509; 13.0758
86.83; 76.836; 86.417
1278.76Vicente, José; Saura-Llamas, Isabel; García-López, José-Antonio; Bautista, Delia
Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†
Organometallics, 2010, 29, 4320
4063460 CIFC27 H13 Cl F18 N2 RuP 1 21/c 113.2799; 12.6155; 17.3582
90; 99.075; 90
2871.66Phillips, Andrew D.; Zava, Olivier; Scopelitti, Rosario; Nazarov, Alexey A.; Dyson, Paul J.
Rational Design of Highly Cytotoxic η6-Arene β-Diketiminato−Ruthenium Complexes
Organometallics, 2010, 29, 417
4066637 CIFC27 H17 N O5 Ru2P 1 21/c 18.8321; 17.606; 15.6816
90; 94.609; 90
2430.6Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066589 CIFC27 H18 Fe O10 Os3 SiC 1 2/c 140.583; 11.9443; 12.891
90; 98.608; 90
6178Nievas, Ángel; Medel, María; Hernández, Elisa; Delgado, Esther; Martín, Avelino; Casado, Carmen M.; Alonso, Beatriz
Redox-Active Heterometallic Ferrocenylalkynyl Carbosilane Dendrimers Incorporating Os3(CO)10Clusters
Organometallics, 2010, 29, 4291
4063457 CIFC27 H19 Cl F12 N2 RuP 1 21/c 112.9439; 16.1117; 13.2348
90; 92.751; 90
2756.9Phillips, Andrew D.; Zava, Olivier; Scopelitti, Rosario; Nazarov, Alexey A.; Dyson, Paul J.
Rational Design of Highly Cytotoxic η6-Arene β-Diketiminato−Ruthenium Complexes
Organometallics, 2010, 29, 417
4063423 CIFC27 H20 F3 O P TeP 1 21/n 113.39; 6.393; 29.221
90; 93.13; 90
2498Kawaguchi, Shin-ichi; Ohe, Takashi; Shirai, Takamune; Nomoto, Akihiro; Sonoda, Motohiro; Ogawa, Akiya
Highly Selective Phosphinotelluration of Terminal Alkynes Using a (Ph2P)2‒(PhTe)2Mixed System upon Visible Light Irradiation: Straightforward Access to 1-Phosphino-2-telluro-alkenes
Organometallics, 2010, 29, 312-316
4067086 CIFC27 H21 F3 N6 O PdP -112.7589; 14.0925; 14.1825
92.171; 95.885; 103.868
2457.54Sie, Ming-Han; Hsieh, Yuan-Hsin; Tsai, Yi-Hua; Wu, Jia-Rong; Chen, Shih-Jung; Kumar, P. Vijaya; Lii, Jenn-Huei; Lee, Hon Man
A Heteroleptic Palladium(II) Complex Containing a Bidentate Carbene/Amido Ligand and 3-(Trifluoromethyl)-5-(2-pyridyl)pyrazolate: Fast Catalyst Activation in the Heck Coupling Reaction
Organometallics, 2010, 29, 6473
4066182 CIFC27 H22 Cl2 Fe N P PdP 1 21/n 115.4619; 10.5555; 15.9837
90; 114.448; 90
2374.77Štěpnička, Petr; Schulz, Jiří; Klemann, Thorsten; Siemeling, Ulrich; Císařová, Ivana
Synthesis, Structural Characterization, and Catalytic Evaluation of Palladium Complexes with Homologous Ferrocene-Based Pyridylphosphine Ligands
Organometallics, 2010, 29, 3187
4066622 CIFC27 H24 Au Cl2 F5 N2P 43 21 212.4281; 12.4281; 24.766
90; 90; 90
3825.3Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4066620 CIFC27 H24 Au F5 N2C 1 2/c 129.524; 13.0862; 23.59
90; 120.391; 90
7861.8Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4067518 CIFC27 H25 Cl N O2.35 P Pd S0.65C 1 2/c 130.0806; 9.9516; 17.4966
90; 104.716; 90
5065.8Kozlov, V. A.; Aleksanyan, D. V.; Nelyubina, Yu. V.; Lyssenko, K. A.; Vasil’ev, A. A.; Petrovskii, P. V.; Odinets, I. L.
Cyclopalladation ofmeta-(Diphenylthiophosphoryloxy)benzaldimines:NCSand UnexpectedNCO5,6-Membered Pincer Palladium Complexes
Organometallics, 2010, 29, 2054
4065787 CIFC27 H25 Cl2 Fe N2 P PdP 21 21 2110.5341; 13.8362; 17.5315
90; 90; 90
2555.2Debono, Nathalie; Labande, Agnès; Manoury, Eric; Daran, Jean-Claude; Poli, Rinaldo
Palladium Complexes of Planar Chiral Ferrocenyl Phosphine-NHC Ligands: New Catalysts for the Asymmetric Suzuki−Miyaura Reaction
Organometallics, 2010, 29, 1879
4067622 CIFC27 H25 F6 N3I 4114.9916; 14.9916; 11.1077
90; 90; 90
2496.4Zhu, Di; Janssen, Femke F. B. J.; Budzelaar, Peter H. M.
(Py)2Co(CH2SiMe3)2As an Easily Accessible Source of “CoR2”
Organometallics, 2010, 29, 1897
4067596 CIFC27 H25 N2 O PP -19.3963; 12.0852; 20.8958
92.021; 100.289; 108.447
2203.99Meeuwissen, Jurjen; Sandee, Albertus J.; de Bruin, Bas; Siegler, Maxime A.; Spek, Anthony L.; Reek, Joost N. H.
Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde
Organometallics, 2010, 29, 2413
4067008 CIFC27 H26 Au Cl N2 O2P 1 21/n 112.6721; 15.0441; 13.0708
90; 95.875; 90
2478.7Hudnall, Todd W.; Tennyson, Andrew G.; Bielawski, Christopher W.
A Seven-MemberedN,N′-Diamidocarbene
Organometallics, 2010, 29, 4569
4066970 CIFC27 H26 Fe N O2 PP 21 21 218.7544; 12.073; 22.141
90; 90; 90
2340.1Thiesen, Kurtis E.; Maitra, Kalyani; Olmstead, Marilyn M.; Attar, Saeed
Synthesis and Characterization of New, Chiral P−N Ligands and Their Use in Asymmetric Allylic Alkylation
Organometallics, 2010, 29, 6334
4066767 CIFC27 H26 Fe2 O4P -111.61; 12.633; 17.403
109.481; 95.275; 108.598
2223.8Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Synthesis and Biological Evaluation of Ferrocene-Containing Bioorganometallics Inspired by the Antibiotic Platensimycin Lead Structure
Organometallics, 2010, 29, 4312
4066769 CIFC27 H26 Fe2 O4P -112.285; 12.365; 16.608
69.725; 71.668; 72.633
2194.9Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Synthesis and Biological Evaluation of Ferrocene-Containing Bioorganometallics Inspired by the Antibiotic Platensimycin Lead Structure
Organometallics, 2010, 29, 4312
4067740 CIFC27 H27 N P2 S2P 1 21/c 115.3111; 7.7994; 21.3862
90; 103.533; 90
2483Lounissi, Sondès; Capon, Jean-François; Gloaguen, Frédéric; Matoussi, Fatma; Pétillon, François Y.; Schollhammer, Philippe; Talarmin, Jean
Reactivity of [Fe2(CO)6(μ-S2)] toward a Base-Containing Diphosphine (Ph2PCH2)2NCH3: Formation of Diiron Carbonyl Compounds Having Polydentate Heterofunctionalized Phosphine (PNS = Ph2PCH2N(CH3)CH2S) and Bidentate Thiophosphinito (Ph2PS = PS) Bridges
Organometallics, 2010, 29, 1296
4067380 CIFC27 H27 N3 O2 RuP b c a14.7586; 13.6043; 24.0237
90; 90; 90
4823.5Gallagher, Michelle; Wieder, Noah L.; Dioumaev, Vladimir K.; Carroll, Patrick J.; Berry, Donald H.
Low-Valent Ruthenium Complexes of the Non-innocent 2,6-Bis(imino)pyridine Ligand
Organometallics, 2010, 29, 591
4066742 CIFC27 H28 Cl Ir N2P -110.0776; 11.0501; 11.8549
66.381; 71.959; 68.485
1104.57Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4066414 CIFC27 H28 Cl Ir N2 O5C 1 2/c 124.6931; 11.4909; 17.7679
90; 92.3027; 90
5037.5Dobereiner, Graham E.; Chamberlin, Catherine A.; Schley, Nathan D.; Crabtree, Robert H.
Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis†
Organometallics, 2010, 29, 5728
4066619 CIFC27 H29 Au N2P -19.9083; 15.5827; 16.2631
78.847; 83.689; 76.998
2394.61Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4067277 CIFC27 H29 Cl O3 Re Rh S2P -110.0727; 11.3045; 13.8148
105.33; 105.702; 105.9
1355.57Huang, Shih-Huang; Watson, William H.; Carrano, Carl J.; Wang, Xiaoping; Richmond, Michael G.
Directed Synthesis of the Triangular Mixed-Metal Cluster H2RhRe2Cp*(CO)9: Ligand Fluxionality and Facile Cluster Fragmentation in the Presence of CO, Halogenated Solvents, and Thiols
Organometallics, 2010, 29, 61
4067440 CIFC27 H30 Cl2 N O P Pd RuP 1 21/n 113.8455; 9.4914; 21.3557
90; 105.924; 90
2698.73Luo, Ding; Li, Yongxin; Pullarkat, Sumod A.; Cockle, Kirsty E.; Leung, Pak-Hing
Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions
Organometallics, 2010, 29, 893
4065636 CIFC27 H30 Cl2 O9 Ru SiP 21 21 2110.9899; 12.6076; 21.938
90; 90; 90
3039.6Yamamoto, Yoshihiko; Yamashita, Ken; Nakamura, Mitsutaka
Synthesis of Organometallic Analogues of SpirocyclicC-Arylribosides
Organometallics, 2010, 29, 1472
4066717 CIFC27 H30 F6 N6 P RhP -18.1208; 13.0244; 13.2509
78.837; 86.614; 89.874
1372.55Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4066359 CIFC27 H31 B N2 O SP b c a16.585; 13.446; 21.832
90; 90; 90
4868.6Matsumoto, Takeshi; Wade, Casey R.; Gabbaï, François P.
Synthesis and Lewis Acidic Behavior of a Cationic 9-Thia-10-boraanthracene†
Organometallics, 2010, 29, 5490
4067056 CIFC27 H31 Cl Ir N O2P -111.0411; 16.0222; 16.1837
63.143; 87.654; 72.193
2415.8Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4067057 CIFC27 H31 Cl N O2 RhP -110.9998; 16.0239; 16.1639
63.356; 87.854; 72.148
2407.1Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066707 CIFC27 H31 F6 N4 O2 P PdP -110.303; 11.188; 14.192
100.55; 108.3; 97.26
1497D’Amora, Angela; Fanfoni, Lidia; Cozzula, Daniela; Guidolin, Nicol; Zangrando, Ennio; Felluga, Fulvia; Gladiali, Serafino; Benedetti, Fabio; Milani, Barbara
Addressing the Poly- to Oligo-ketone Selectivity in Styrene Carbonylation Catalyzed by Palladium/bpy Complexes. Effect of the 6-Alkyl Substitution
Organometallics, 2010, 29, 4472
4067297 CIFC27 H32 N2 ZnP -110.787; 11.093; 11.889
71.019; 72.879; 85.313
1285.5Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4065648 CIFC27 H32 N6 Ni O4C 1 2/c 114.7743; 16.0012; 12.3916
90; 112.797; 90
2700.6Jean-Baptiste dit Dominique, François; Gornitzka, Heinz; Hemmert, Catherine
Chiral Variation of a Hybrid Bis(carbene-amido) Ligand System
Organometallics, 2010, 29, 2868
4066969 CIFC27 H33 F3 N2 O3 SP -19.6895; 10.3646; 13.2662
90.106; 106.203; 103.98
1238.05Vicente, José; Saura-Llamas, Isabel; García-López, José-Antonio; Bautista, Delia
Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†
Organometallics, 2010, 29, 4320
4067680 CIFC27 H34 Al N3 O4 S2P 1 21/c 112.6637; 15.0088; 15.4108
90; 108.642; 90
2775.4Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4063443 CIFC27 H34 Au Cl3 N2C 1 2 120.894; 14.139; 22.956
90; 113.173; 90
6235Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4066878 CIFC27 H34 B Ir N6 O4P b c a8.4658; 19.9508; 33.6138
90; 90; 90
5677.4Cristóbal, Crispín; García-Rubín, Silvia; Hernández, Yohar A.; López-Serrano, Joaquín; Paneque, Margarita; Posadas, Cristina M.; Poveda, Manuel L.; Rendón, Nuria; Álvarez, Eleuterio
Iridafurans by Coupling of Alkynes and Aldehydes on a TpMe2Ir System. Facile Demethoxycarbonylation of a β-CO2Me Substituent
Organometallics, 2010, 29, 5744
4067682 CIFC27 H35 Al Cl2 N4 O4 S2P 1 21/n 18.2076; 38.2977; 9.6734
90; 96.4865; 90
3021.2Schwarz, Andrew D.; Chu, Zengyong; Mountford, Philip
Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization ofrac-Lactide
Organometallics, 2010, 29, 1246
4066174 CIFC27 H36 Cl3 N2 PP 1 21/n 110.6288; 13.9767; 19.8632
90; 103.215; 90
2872.6Wang, Yuzhong; Xie, Yaoming; Abraham, Mariham Y.; Gilliard, Robert J.; Wei, Pingrong; Schaefer, Henry F.; Schleyer, Paul v. R.; Robinson, Gregory H.
Carbene-Stabilized Parent Phosphinidene†
Organometallics, 2010, 29, 4778
4066688 CIFC27 H36 I4 N2P -110.0574; 10.0847; 16.5285
89.812; 72.816; 77.802
1562.28Lin, Bo-Lin; Kang, Peng; Stack, T Daniel P
Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions.
Organometallics, 2010, 29, 3683-3685
4065710 CIFC27 H36 N O YP 1 21/n 113.126; 8.896; 20.839
90; 96.019; 90
2419.9Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4066949 CIFC27 H37 Cu N2 OP 1 21/c 112.463; 9.096; 22.738
90; 97.757; 90
2554.1Fortman, George C.; Slawin, Alexandra M. Z.; Nolan, Steven P.
A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)
Organometallics, 2010, 29, 3966
4066178 CIFC27 H37 N3 Si2 ZnP 1 21/n 114.9418; 11.6911; 17.1955
90; 106.712; 90
2876.94Kahnes, Marcel; Görls, Helmar; Westerhausen, Matthias
Synthesis of Dinuclear Zinc Alkynyls and Their Use in Catalytic Silicon−Carbon Bond Formation
Organometallics, 2010, 29, 3490
4066471 CIFC27 H39 AsP -110.5768; 10.995; 11.1954
90.824; 106.305; 110.27
1163.14Chmely, Stephen C.; Hanusa, Timothy P.; Rheingold, Arnold L.
Influence of Ring Methylation in Group 15 Tetramethylcyclopentadienyl Complexes, M(C5Me4H)nI3−n(M = As, Sb)†
Organometallics, 2010, 29, 5551
4065869 CIFC27 H39 B Cl2 I N7 PtP -111.0982; 11.9831; 12.536
86.822; 75.098; 76.798
1568.5Engelman, Kristi L.; White, Peter S.; Templeton, Joseph L.
Synthesis of Isonitrile, Iminoacyl, and Aminocarbene Tp′Pt Complexes†
Organometallics, 2010, 29, 4943
4066472 CIFC27 H39 SbP -110.5877; 10.8991; 11.8207
64.975; 79.434; 88.204
1213.4Chmely, Stephen C.; Hanusa, Timothy P.; Rheingold, Arnold L.
Influence of Ring Methylation in Group 15 Tetramethylcyclopentadienyl Complexes, M(C5Me4H)nI3−n(M = As, Sb)†
Organometallics, 2010, 29, 5551
4065867 CIFC27 H40 B N7 PtP -110.9293; 11.9574; 22.0161
78.747; 83.337; 78.822
2759.19Engelman, Kristi L.; White, Peter S.; Templeton, Joseph L.
Synthesis of Isonitrile, Iminoacyl, and Aminocarbene Tp′Pt Complexes†
Organometallics, 2010, 29, 4943
4066367 CIFC27 H40 N2P b c a13.3419; 17.3132; 21.511
90; 90; 90
4968.8Collins, Mary S.; Rosen, Evelyn L.; Lynch, Vincent M.; Bielawski, Christopher W.
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
Organometallics, 2010, 29, 3047
4065611 CIFC27 H41 N2 O Sc Si2P -110.8063; 10.9221; 14.216
96.066; 106.887; 109.362
1476.33Liu, Dongtao; Luo, Yunjie; Gao, Wei; Cui, Dongmei
Stereoselective Polymerization of Styrene with Cationic Scandium Precursors Bearing Quinolyl Aniline Ligands
Organometallics, 2010, 29, 1916
4065692 CIFC27 H41 N3 UP -18.6188; 9.2322; 17.4294
82.0205; 84.9103; 67.1607
1264.8Montalvo, Elizabeth; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Evans, William J.
Utility of the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)−, in Stabilizing Uranium Metallocene Mono-Alkyl and “Tuck-in” Complexes
Organometallics, 2010, 29, 2104
4066348 CIFC27 H41 RhC 1 c 19.2708; 23.2398; 11.5998
90; 96.688; 90
2482.19Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
Organometallics, 2010, 29, 5481
4065691 CIFC27 H42 I N3 UP 1 21/n 18.9362; 18.274; 16.592
90; 93.455; 90
2704.6Montalvo, Elizabeth; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Evans, William J.
Utility of the 1,3,4,6,7,8-Hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)−, in Stabilizing Uranium Metallocene Mono-Alkyl and “Tuck-in” Complexes
Organometallics, 2010, 29, 2104
4063435 CIFC27 H47 Fe N2 P3P 1 21/c 116.9889; 9.3446; 19.4216
90; 105.431; 90
2972.12Volpe, Emily C.; Wolczanski, Peter T.; Lobkovsky, Emil B.
Aryl-Containing Pyridine-Imine and Azaallyl Chelates of Iron toward Strong Field Coordination Compounds
Organometallics, 2010, 29, 364
4067350 CIFC27 H48 I2 O5 SrC 1 2/c 121.7972; 13.9236; 13.8943
90; 126.763; 90
3378.2Langer, Jens; Görls, Helmar; Westerhausen, Matthias
Stability and Reactivity of Phenylstrontium Compounds in Solution
Organometallics, 2010, 29, 2034
4067281 CIFC27 H53 Dy O Si4P 1 21/n 114.2015; 16.031; 15.788
90; 92.893; 90
3589.8Xu, Xin; Chen, Yaofeng; Feng, Jian; Zou, Gang; Sun, Jie
Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)2C9H5)Ln(CH2SiMe3)2(THF)
Organometallics, 2010, 29, 549
4067280 CIFC27 H53 Lu O Si4P 1 21/n 110.2276; 15.9273; 22.0779
90; 97.619; 90
3564.7Xu, Xin; Chen, Yaofeng; Feng, Jian; Zou, Gang; Sun, Jie
Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)2C9H5)Ln(CH2SiMe3)2(THF)
Organometallics, 2010, 29, 549
4067279 CIFC27 H53 O Si4 YP 1 21/n 114.219; 16.076; 15.857
90; 93.051; 90
3619.5Xu, Xin; Chen, Yaofeng; Feng, Jian; Zou, Gang; Sun, Jie
Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)2C9H5)Ln(CH2SiMe3)2(THF)
Organometallics, 2010, 29, 549
4066448 CIFC27 H58 O Si5P -110.409; 18.12; 28.274
82.639; 85.349; 84.839
5254.3Ishida, Shintaro; Iwamoto, Takeaki; Kira, Mitsuo
Reactions of an Isolable Dialkylsilylene with Ketones†
Organometallics, 2010, 29, 5526
4067589 CIFC27 H59 N9 TiP 1 21/c 130.991; 10.561; 21.32
90; 109.55; 90
6576Panda, Tarun K.; Tsurugi, Hayato; Pal, Kuntal; Kaneko, Hiroshi; Mashima, Kazushi
Highly Reactive Metal−Nitrogen Bond Induced C−H Bond Activation and Azametallacycle Formation
Organometallics, 2010, 29, 34
4066352 CIFC27 H59 Rh Si3P -110.415; 10.5078; 15.705
88.196; 84.251; 67.076
1574.98Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
Organometallics, 2010, 29, 5481
4063454 CIFC27.5 H28 F3 N2 O8.5 Pd SP -19.362; 11.3529; 14.6379
99.933; 90.461; 109.265
1443.1Vicente, José; Abad, José Antonio; López-Sáez, María-José; Jones, Peter G.
Carbopalladation of Maleate and Fumarate Esters and 1,1-Dimethylallene with Ortho-Substituted Aryl Palladium Complexes
Organometallics, 2010, 29, 409
4063447 CIFC27.5 H37 Au Cl4 N2P -110.553; 16.412; 19.067
91.649; 105.992; 107.01
3014.1Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4063452 CIFC27.5 H39 Au Cl4 N2P 1 21/c 110.624; 16.102; 19.124
90; 99.749; 90
3224.3Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4066905 CIFC273 H305 O4 P16 Si4 Sn4 W4P -112.3443; 16.1288; 34.9284
88.543; 89.504; 85.639
6931.7Semenov, Sergey N.; Blacque, Olivier; Fox, Thomas; Venkatesan, Koushik; Berke, Heinz
[W(CO)(dppe)2] Cumulenylidene and Acetylide Complexes Accessed via Stannylated Acetylenes and Butadiynes
Organometallics, 2010, 29, 6321
4067217 CIFC28 H12 B F15 SP 1 21/c 120.2284; 14.5997; 18.3315
90; 104.952; 90
5230.5Dureen, Meghan A.; Brown, Christopher C.; Stephan, Douglas W.
Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
Organometallics, 2010, 29, 6594
4065865 CIFC28 H12 B F18 N4 O2 P2 RhP 1 21/n 111.8043; 17.4829; 16.1498
90; 106.718; 90
3192.02Christiansen, Andrea; Selent, Detlef; Spannenberg, Anke; Baumann, Wolfgang; Franke, Robert; Börner, Armin
Reaction of Secondary Phosphine Oxides with Rhodium(I)
Organometallics, 2010, 29, 3139
4065907 CIFC28 H16 F12 Ir N8 PP -19.538; 10.937; 16.426
77.22; 76.753; 68.676
1535.7Chen, Jing-Lin; Wu, Yu-Hui; He, Li-Hua; Wen, He-Rui; Liao, Jinsheng; Hong, Ruijin
Iridium(III) Bis-tridentate Complexes with 6-(5-Trifluoromethylpyrazol-3-yl)-2,2′-bipyridine Chelating Ligands: Synthesis, Characterization, and Photophysical Properties
Organometallics, 2010, 29, 2882
4067533 CIFC28 H17 Cl F2 N4 O TiP -17.3555; 10.336; 16.367
85.21; 79.56; 89.62
1219.4Sun, Wen-Hua; Liu, Shaofeng; Zhang, Wenjuan; Zeng, Yanning; Wang, Deligeer; Liang, Tongling
Syntheses, Characterization, and the Ethylene (Co-)Polymerization Screening of 2-Benzimidazolyl-N-phenylquinoline-8-carboxamide Half-Titanocene Chlorides
Organometallics, 2010, 29, 732
4066696 CIFC28 H20 N2 O15 Ru5P 1 21/n 19.3856; 39.4723; 9.4818
90; 100.59; 90
3452.9Cabeza, Javier A.; del Río, Ignacio; Pérez-Carreño, Enrique; Sánchez-Vega, M. Gabriela; Vázquez-García, Digna
Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters
Organometallics, 2010, 29, 4464
4063491 CIFC28 H22 Al2 F24 O10P 1 21/c 19.741; 18.539; 10.909
90; 107.676; 90
1877Bouyahyi, Miloud; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated β-Diketonate Ligands: Syntheses, Structures, Intramolecular Reduction, and Use in Ring-Opening Polymerization of Lactide
Organometallics, 2010, 29, 491-500
4063492 CIFC28 H22 Al2 F24 O12P 1 21/n 19.0798; 12.2806; 18.0264
90; 97.954; 90
1990.7Bouyahyi, Miloud; Roisnel, Thierry; Carpentier, Jean-François
Aluminum Complexes of Fluorinated β-Diketonate Ligands: Syntheses, Structures, Intramolecular Reduction, and Use in Ring-Opening Polymerization of Lactide
Organometallics, 2010, 29, 491-500
4066300 CIFC28 H24 B F15 N2 OP 1 21/c 111.0576; 12.6641; 20.5009
90; 94.936; 90
2860.2Birkmann, Birgit; Voss, Tanja; Geier, Stephen J.; Ullrich, Matthias; Kehr, Gerald; Erker, Gerhard; Stephan, Douglas W.
Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane†
Organometallics, 2010, 29, 5310
4066181 CIFC28 H24 Fe N O PP -110.8511; 10.9227; 11.1448
111.135; 106.679; 101.205
1112.74Štěpnička, Petr; Schulz, Jiří; Klemann, Thorsten; Siemeling, Ulrich; Císařová, Ivana
Synthesis, Structural Characterization, and Catalytic Evaluation of Palladium Complexes with Homologous Ferrocene-Based Pyridylphosphine Ligands
Organometallics, 2010, 29, 3187
4066997 CIFC28 H25 O YP -18.352; 12.126; 12.525
110.628; 102.559; 99.626
1116.7Li, Xiaoqing; Hong, Jianquan; Liu, Ruiting; Weng, Linhong; Zhou, Xigeng
Reactions of Cp3Y with Benzophenone: A Simple and Efficient Method for Transformation of Unsubstituted Cyclopentadienyl to Bridgedansa-Cyclopentadienyl/Alkoxyl Ligand
Organometallics, 2010, 29, 4606
4063458 CIFC28 H27 Cl3 F6 N2 RuP -17.9718; 10.1896; 18.2714
91.374; 95.367; 106.896
1411.84Phillips, Andrew D.; Zava, Olivier; Scopelitti, Rosario; Nazarov, Alexey A.; Dyson, Paul J.
Rational Design of Highly Cytotoxic η6-Arene β-Diketiminato−Ruthenium Complexes
Organometallics, 2010, 29, 417
4065786 CIFC28 H27 Cl4 Fe N2 P PdP -19.8781; 10.7098; 14.9399
81.134; 71.512; 73
1430.17Debono, Nathalie; Labande, Agnès; Manoury, Eric; Daran, Jean-Claude; Poli, Rinaldo
Palladium Complexes of Planar Chiral Ferrocenyl Phosphine-NHC Ligands: New Catalysts for the Asymmetric Suzuki−Miyaura Reaction
Organometallics, 2010, 29, 1879
4066862 CIFC28 H27 Cr Ni O3 PP 1 21/n 19.1878; 11.3446; 22.8954
90; 96.09; 90
2373Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066797 CIFC28 H27 Ge Ir O2P 1 21/n 19.1269; 15.9576; 16.6473
90; 94.507; 90
2417.07Adams, Richard D.; Trufan, Eszter
Iridium−Germanium and −Tin Carbonyl Complexes
Organometallics, 2010, 29, 4346
4066798 CIFC28 H27 Ir O2 SnP 1 21/n 19.3637; 15.9094; 16.8632
90; 94.597; 90
2504Adams, Richard D.; Trufan, Eszter
Iridium−Germanium and −Tin Carbonyl Complexes
Organometallics, 2010, 29, 4346
4066863 CIFC28 H27 Mo Ni O3 PP 1 21/n 19.3808; 11.3623; 22.969
90; 97.013; 90
2429.9Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4066864 CIFC28 H27 Ni O3 P WP 1 21/n 19.3742; 11.3543; 22.954
90; 97.355; 90
2423.1Fischer, Paul J.; Neary, Michelle C.; Heerboth, Aaron P.; Sullivan, Kevin P.
Allylnickel(II) and Allylpalladium(II) Derivatives of [(2-(Diphenylphosphino)ethyl)cyclopentadienyl]tricarbonylmetalates: Reactions with Free Radicals
Organometallics, 2010, 29, 4562
4065646 CIFC28 H28 Au2 P2R 3 m :H32.5214; 32.5214; 8.7601
90; 90; 120
8023.8Nguyen, Minh-Hai; Yip, John H. K.
Gold(I) and Platinum(II) Tetracenes and Tetracenyldiacetylides: Structural and Fluorescence Color Changes Induced by σ-Metalation
Organometallics, 2010, 29, 2422
4063425 CIFC28 H28 B Cl3 Ir N4 O P S2P -19.3509; 9.7847; 19.1038
92.7592; 99.6612; 110.926
1598.35Crossley, Ian R.; Hill, Anthony F.; Willis, Anthony C.
Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls
Organometallics, 2010, 29, 326
4067149 CIFC28 H28 Fe P S2P 1 21/n 110.4176; 22.2562; 10.4326
90; 90.655; 90
2418.7Yuki, Masahiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
Preparation of Thiolate-Bridged Dinuclear Ruthenium Complexes Bearing a Phosphine Ligand and Application to Propargylic Reduction of Propargylic Alcohols with 2-Propanol
Organometallics, 2010, 29, 5994
4066768 CIFC28 H28 Fe2 O4P 1 21/n 113.714; 12.304; 14.015
90; 97.3; 90
2346Patra, Malay; Gasser, Gilles; Wenzel, Michaela; Merz, Klaus; Bandow, Julia E.; Metzler-Nolte, Nils
Synthesis and Biological Evaluation of Ferrocene-Containing Bioorganometallics Inspired by the Antibiotic Platensimycin Lead Structure
Organometallics, 2010, 29, 4312
4067368 CIFC28 H28 Ge O4P -18.5326; 8.8304; 16.6832
80.629; 82.178; 89.63
1228.5Yoder, Claude H.; Agee, Tamara M.; Griffith, Allison K.; Schaeffer, Charles D.; Carroll, Mary J.; DeToma, Alaina S.; Fleisher, Adam J.; Gettel, Cameron J.; Rheingold, Arnold L.
Use of73Ge NMR Spectroscopy and X-ray Crystallography for the Study of Electronic Interactions in Substituted Tetrakis(phenyl)-, -(phenoxy)-, and -(thiophenoxy)germanes
Organometallics, 2010, 29, 582
4067370 CIFC28 H28 Ge O4 S4P 1 21/n 118.619; 7.7442; 19.302
90; 101.55; 90
2726.8Yoder, Claude H.; Agee, Tamara M.; Griffith, Allison K.; Schaeffer, Charles D.; Carroll, Mary J.; DeToma, Alaina S.; Fleisher, Adam J.; Gettel, Cameron J.; Rheingold, Arnold L.
Use of73Ge NMR Spectroscopy and X-ray Crystallography for the Study of Electronic Interactions in Substituted Tetrakis(phenyl)-, -(phenoxy)-, and -(thiophenoxy)germanes
Organometallics, 2010, 29, 582
4067371 CIFC28 H28 Ge S4C 1 2/c 17.414; 25.203; 14.182
90; 104.424; 90
2566.4Yoder, Claude H.; Agee, Tamara M.; Griffith, Allison K.; Schaeffer, Charles D.; Carroll, Mary J.; DeToma, Alaina S.; Fleisher, Adam J.; Gettel, Cameron J.; Rheingold, Arnold L.
Use of73Ge NMR Spectroscopy and X-ray Crystallography for the Study of Electronic Interactions in Substituted Tetrakis(phenyl)-, -(phenoxy)-, and -(thiophenoxy)germanes
Organometallics, 2010, 29, 582
4065997 CIFC28 H28 N6 Ni S2C 1 2/c 114.5167; 13.9716; 14.0918
90; 100.996; 90
2805.6Jothibasu, Ramasamy; Huang, Kuo-Wei; Huynh, Han Vinh
Synthesis ofcis- andtrans-Diisothiocyanato−Bis(NHC) Complexes of Nickel(II) and Applications in the Kumada−Corriu Reaction
Organometallics, 2010, 29, 3746
4067492 CIFC28 H29 Br Mo N2 O2P 1 21/n 112.5547; 12.694; 17.0096
90; 105.73; 90
2609.3Li, Shenyu; Kee, Choon Wee; Huang, Kuo-Wei; Hor, T. S. Andy; Zhao, Jin
Cyclopentadienyl Molybdenum(II/VI) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Reactivity under Oxidative Conditions
Organometallics, 2010, 29, 1924
4066968 CIFC28 H29 Cl N P PdP -19.9381; 11.6534; 12.6531
98.737; 108.481; 113.649
1205.64Vicente, José; Saura-Llamas, Isabel; García-López, José-Antonio; Bautista, Delia
Eight-Membered Palladacycles Derived from the Insertion of Olefins into the Pd−C Bond of Ortho-Palladated Pharmaceuticals Phenethylamine and Phentermine. Synthesis of Stable Heck-Type Intermediates Containing Accessible β-Hydrogens and Its Use in the Synthesis of 2-Styrylphenethylamines, Tetrahydroisoquinolines, and Eight-Membered Cyclic Amidines†
Organometallics, 2010, 29, 4320
4067062 CIFC28 H29 Cl4 F3 Ir N O2P -19.3278; 12.0705; 14.423
98.172; 105.692; 110.036
1418.4Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066739 CIFC28 H29 Ir N2 O2P 1 21/a 113.278; 10.29652; 17.7101
90; 109.412; 90
2283.63Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4066709 CIFC28 H30 Cl F6 N4 P Pd2I 1 2/a 110.868; 16.494; 16.664
90; 93.66; 90
2981D’Amora, Angela; Fanfoni, Lidia; Cozzula, Daniela; Guidolin, Nicol; Zangrando, Ennio; Felluga, Fulvia; Gladiali, Serafino; Benedetti, Fabio; Milani, Barbara
Addressing the Poly- to Oligo-ketone Selectivity in Styrene Carbonylation Catalyzed by Palladium/bpy Complexes. Effect of the 6-Alkyl Substitution
Organometallics, 2010, 29, 4472
4066741 CIFC28 H30 Cl Ir N2C 1 2/c 121.6578; 12.9925; 19.4057
90; 120.291; 90
4715.05Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4066738 CIFC28 H30 I Ir N2P 1 21/c 110.38686; 15.7892; 15.4226
90; 106.883; 90
2420.3Tsurugi, Hayato; Fujita, Shingo; Choi, Gyeongshin; Yamagata, Tsuneaki; Ito, Syoji; Miyasaka, Hiroshi; Mashima, Kazushi
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Complexes withN-Phenylperimidine-Based Carbene Ligands
Organometallics, 2010, 29, 4120
4065711 CIFC28 H30 N YbP 1 21/n 110.039; 18.244; 13.75
90; 110.457; 90
2359.5Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4066621 CIFC28 H31 Au Cl4 N2R -3 :H23.8356; 23.8356; 29.0459
90; 90; 120
14291.2Pažický, Marek; Loos, Annette; Ferreira, Maria João; Serra, Daniel; Vinokurov, Nikolai; Rominger, Frank; Jäkel, Christoph; Hashmi, A. Stephen K.; Limbach, Michael
Synthesis, Reactivity, and Electrochemical Studies of Gold(I) and Gold(III) Complexes Supported by N-Heterocyclic Carbenes and Their Application in Catalysis
Organometallics, 2010, 29, 4448-4458
4065649 CIFC28 H31 Cl3 N6 Ni O3P 1 21/c 110.5437; 14.9883; 19.1501
90; 100.537; 90
2975.3Jean-Baptiste dit Dominique, François; Gornitzka, Heinz; Hemmert, Catherine
Chiral Variation of a Hybrid Bis(carbene-amido) Ligand System
Organometallics, 2010, 29, 2868
4067437 CIFC28 H31 Cl5 N P Pd RuP 1 21/n 115.5945; 12.6641; 15.7896
90; 102.418; 90
3045.3Luo, Ding; Li, Yongxin; Pullarkat, Sumod A.; Cockle, Kirsty E.; Leung, Pak-Hing
Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions
Organometallics, 2010, 29, 893
4065607 CIFC28 H31 I N2 O5 P2 PdP 110.3714; 11.8544; 13.054
89.198; 84.462; 68.804
1489.01Li, Jie; Lutz, Martin; Spek, Anthony L.; van Klink, Gerard P. M.; van Koten, Gerard; Klein Gebbink, Robertus J. M.
Chiral Amino Alcohol Derived Bis-phosphoramidite Pincer Palladium Complexes and Their Applications in Asymmetric Allylation of Aldimines
Organometallics, 2010, 29, 1379
4067441 CIFC28 H32 Cl2 N O P Pd RuP 1 21 110.2816; 13.3428; 10.4877
90; 108.825; 90
1361.8Luo, Ding; Li, Yongxin; Pullarkat, Sumod A.; Cockle, Kirsty E.; Leung, Pak-Hing
Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions
Organometallics, 2010, 29, 893
4066256 CIFC28 H32 Ni P2 S2P -18.0853; 8.9069; 10.0072
90.397; 110.57; 101.009
660.15Ananikov, Valentine P.; Gayduk, Konstantin A.; Starikova, Zoya A.; Beletskaya, Irina P.
Ni(acac)2/Phosphine as an Excellent Precursor of Nickel(0) for Catalytic Systems†
Organometallics, 2010, 29, 5098
4066675 CIFC28 H32 Ru2P b c a13.2933; 12.4533; 26.2599
90; 90; 90
4347.2Chin, Robert M.; Simonson, Andrew; Mauldin, Joshua; Criswell, Jared; Brennessel, William
Syntheses and Characterization of Ruthenium Complexes Containing a Doubly Linked Dicyclopentadienyl Ligand and Acetonitrile Ligands
Organometallics, 2010, 29, 3868
4067338 CIFC28 H33 Cr N2 O2P 1 21/n 18.2143; 13.597; 22.03
90; 90.978; 90
2460.2Champouret, Yohan; MacLeod, K. Cory; Baisch, Ulrich; Patrick, Brian O.; Smith, Kevin M.; Poli, Rinaldo
Cyclopentadienyl Chromium β-Diketiminate Complexes: Initiators, Ligand Steric Effects, and Deactivation Processes in the Controlled Radical Polymerization of Vinyl Acetate
Organometallics, 2010, 29, 167
4067444 CIFC28 H33 Mo2 O5 P RuP -19.8055; 10.1325; 15.635
92.55; 90.46; 116.682
1385.93Alvarez, M. Angeles; García, M. Esther; Martínez, M. Eugenia; Ruiz, Miguel A.
Heterometallic Derivatives of the Unsaturated Methyl-Bridged Complex [Mo2(η5-C5H5)2(μ-CH3)(μ-PCy2)(CO)2]. Photochemical Generation of Methylidyne-Bridged Clusters
Organometallics, 2010, 29, 904
4067568 CIFC28 H33 N3 O WP 1 21/c 114.3244; 24.9425; 13.9735
90; 90.087; 90
4992.5Semproni, Scott P.; McNeil, W. Stephen; Baillie, Rhett A.; Patrick, Brian O.; Campana, Charles F.; Legzdins, Peter
Ground-State Electronic Asymmetry in Cp*W(NO)(η1-isonitrile)2Complexes
Organometallics, 2010, 29, 867
4066880 CIFC28 H34 B Ir N6 O5P 1 21/c 114.963; 7.9519; 27.0615
90; 95.017; 90
3207.56Cristóbal, Crispín; García-Rubín, Silvia; Hernández, Yohar A.; López-Serrano, Joaquín; Paneque, Margarita; Posadas, Cristina M.; Poveda, Manuel L.; Rendón, Nuria; Álvarez, Eleuterio
Iridafurans by Coupling of Alkynes and Aldehydes on a TpMe2Ir System. Facile Demethoxycarbonylation of a β-CO2Me Substituent
Organometallics, 2010, 29, 5744
4066830 CIFC28 H34 B10 Ni P2P -111.8119; 15.6978; 17.794
89.942; 84.805; 74.483
3165.1Qiu, Zaozao; Deng, Liang; Chan, Hoi-Shan; Xie, Zuowei
Synthesis and Structural Characterization of Group 10 Metal−Carboryne Complexes
Organometallics, 2010, 29, 4541
4067333 CIFC28 H34 Cr N2C 1 2/c 116.4341; 9.3651; 16.498
90; 101.508; 90
2488.1Champouret, Yohan; MacLeod, K. Cory; Baisch, Ulrich; Patrick, Brian O.; Smith, Kevin M.; Poli, Rinaldo
Cyclopentadienyl Chromium β-Diketiminate Complexes: Initiators, Ligand Steric Effects, and Deactivation Processes in the Controlled Radical Polymerization of Vinyl Acetate
Organometallics, 2010, 29, 167
4067447 CIFC28 H35 Fe Mo2 O5 PP 1 21/c 18.4495; 16.7274; 20.156
90; 100.35; 90
2802.46Alvarez, M. Angeles; García, M. Esther; Martínez, M. Eugenia; Ruiz, Miguel A.
Heterometallic Derivatives of the Unsaturated Methyl-Bridged Complex [Mo2(η5-C5H5)2(μ-CH3)(μ-PCy2)(CO)2]. Photochemical Generation of Methylidyne-Bridged Clusters
Organometallics, 2010, 29, 904
4067445 CIFC28 H35 Fe Mo2 O6 PP 1 21/c 19.7313; 20.2819; 16.6023
90; 118.749; 90
2872.87Alvarez, M. Angeles; García, M. Esther; Martínez, M. Eugenia; Ruiz, Miguel A.
Heterometallic Derivatives of the Unsaturated Methyl-Bridged Complex [Mo2(η5-C5H5)2(μ-CH3)(μ-PCy2)(CO)2]. Photochemical Generation of Methylidyne-Bridged Clusters
Organometallics, 2010, 29, 904
4065926 CIFC28 H36 As4 Cl2 O16 PtP -110.982; 13.792; 15.089
106.649; 105.276; 107.58
1928Arita, Manabu; Naka, Kensuke; Shimamoto, Tatsuo; Yumura, Takashi; Nakahashi, Akiko; Morisaki, Yasuhiro; Chujo, Yoshiki
1,4-Dihydro-1,4-diarsinine-Bridged Dinucleartrans-Dihaloplatinum(II) Complexes: Synthesis and Controlled Pt−Pt Interaction by Halogen Substitution Induced Conformational Change§
Organometallics, 2010, 29, 4992
4063448 CIFC28 H36 Au Cl7 N2C m c a17.02; 18.662; 21.278
90; 90; 90
6758Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4067718 CIFC28 H36 Br2 N4 Pd S2P 1 21/c 18.8744; 18.5864; 9.4114
90; 93.744; 90
1549.03Huynh, Han Vinh; Yeo, Chun Hui; Chew, Ying Xia
Syntheses, Structures, and Catalytic Activities of Hemilabile Thioether-Functionalized NHC Complexes
Organometallics, 2010, 29, 1479
4066364 CIFC28 H36 Cl2 Cr2 N2 O2P 1 21/c 16.9943; 26.459; 8.1697
90; 104.974; 90
1460.6Volpe, Emily C.; Manke, David R.; Bartholomew, Erika R.; Wolczanski, Peter T.; Lobkovsky, Emil B.
Aryl−Oxazoline Chelates of First-Row Transition Metals: Structures of {κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}FeCl(py) and [(κ-C,N-(o-C6H4)CMe2(COCH2CMe2N)}Cr(μ-Cl)]2‡
Organometallics, 2010, 29, 6642
4067377 CIFC28 H36 Cl2 N3 P RuP c a 2119.005; 9.9701; 14.6711
90; 90; 90
2779.9Gallagher, Michelle; Wieder, Noah L.; Dioumaev, Vladimir K.; Carroll, Patrick J.; Berry, Donald H.
Low-Valent Ruthenium Complexes of the Non-innocent 2,6-Bis(imino)pyridine Ligand
Organometallics, 2010, 29, 591
4066690 CIFC28 H36 Cu F3 N2 O3 SP 21 21 2110.4856; 14.0928; 20.2195
90; 90; 90
2987.87Lin, Bo-Lin; Kang, Peng; Stack, T Daniel P
Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions.
Organometallics, 2010, 29, 3683-3685
4066950 CIFC28 H36 Cu N3P n a 2120.157; 10.568; 12.577
90; 90; 90
2679.1Fortman, George C.; Slawin, Alexandra M. Z.; Nolan, Steven P.
A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)
Organometallics, 2010, 29, 3966
4065880 CIFC28 H36 F3 Ir N3 O5 S2P 1 21 19.5809; 16.3451; 10.2339
90; 104.031; 90
1554.8Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4067267 CIFC28 H36 F3 N3 Ni O4 SP -19.0451; 9.9916; 18.6756
80.53; 80.528; 68.562
1539.57Varonka, Matthew S.; Warren, Timothy H.
Three-Coordinate N-Heterocyclic Carbene Nickel Nitrosyl Complexes
Organometallics, 2010, 29, 717
4065994 CIFC28 H36 N6 Ni S2P 1 21/c 18.799; 18.152; 9.661
90; 91.646; 90
1542.4Jothibasu, Ramasamy; Huang, Kuo-Wei; Huynh, Han Vinh
Synthesis ofcis- andtrans-Diisothiocyanato−Bis(NHC) Complexes of Nickel(II) and Applications in the Kumada−Corriu Reaction
Organometallics, 2010, 29, 3746
4066309 CIFC28 H37 Cl2 Ir N O4 PP 1 21/c 111.4457; 12.3481; 20.3787
90; 95.733; 90
2865.8Torres, Olga; Martín, Marta; Sola, Eduardo
Versatile κ2,η2-CLigands Assembled at Iridium via [2+2] Oxidative Cyclization
Organometallics, 2010, 29, 3201
4066691 CIFC28 H38 Cl3 F6 N2 SbP -110.3722; 11.1818; 16.0498
77.68; 75.882; 66.338
1639.43Lin, Bo-Lin; Kang, Peng; Stack, T Daniel P
Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions.
Organometallics, 2010, 29, 3683-3685
4083397 CIFC28 H40 Br Mg N O2P 1 21 18.413; 17.455; 9.899
90; 108.337; 90
1379.8Yuan, Shifang; Bai, Shengdi; Liu, Diansheng; Sun, Wen-Hua
(η3-Azaallyl)zirconium Chlorides: Synthesis, Characterization, and Ethylene (Co-)polymerization Activity
Organometallics, 2010, 29, 2132
4066559 CIFC28 H42 B N3 O7 P RhP 1 21/n 112.0774; 13.9002; 19.2172
90; 90.164; 90
3226.1Ho, Hung-An; Dunne, James F.; Ellern, Arkady; Sadow, Aaron D.
Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition
Organometallics, 2010, 29, 4105
4067094 CIFC28 H42 B2 Li2 O4P -18.5547; 10.8865; 16.236
101.971; 104.514; 100.804
1385.5Lorbach, Andreas; Bolte, Michael; Lerner, Hans-Wolfram; Wagner, Matthias
Dilithio 9,10-Diborataanthracene: Molecular Structure and 1,4-Addition Reactions
Organometallics, 2010, 29, 5762
4066379 CIFC28 H42 Cl F6 Fe P3 RuP -19.8697; 11.5712; 15.49
68.224; 77.69; 72.681
1557.7Sixt, Torsten; Sieger, Monika; Krafft, Michael J.; Bubrin, Denis; Fiedler, Jan; Kaim, Wolfgang
Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1′-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent” Intermediates†
Organometallics, 2010, 29, 5511
4067524 CIFC28 H42 Cl3 Li2 N2 O4 ThP b c n17.3301; 15.0454; 12.5834
90; 90; 90
3281Korobkov, Ilia; Vidjayacoumar, Balamurugan; Gorelsky, Serge I.; Billone, Paul; Gambarotta, Sandro
Attempting to Reduce the Irreducible: Preparation of a Rare Paramagnetic Thorium Species
Organometallics, 2010, 29, 692
4066722 CIFC28 H42 F6 N4 P RhP 1 21/c 114.3658; 14.8458; 15.3017
90; 108.713; 90
3090.91Riederer, Stephanie K. U.; Gigler, Peter; Högerl, Manuel P.; Herdtweck, Eberhardt; Bechlars, Bettina; Herrmann, Wolfgang A.; Kühn, Fritz E.
Impact of Ligand Modification on Structures and Catalytic Activities of Chelating Bis-Carbene Rhodium(I) Complexes†
Organometallics, 2010, 29, 5681
4067571 CIFC28 H46 P4 RuP 1 21/n 19.6302; 12.118; 26.325
90; 91.897; 90
3070.4Field, Leslie D.; Magill, Alison M.; Shearer, Timothy K.; Colbran, Stephen B.; Lee, Sang T.; Dalgarno, Scott J.; Bhadbhade, Mohan M.
Controlled Synthesis of Dinuclear Acetylide-Bridged Ruthenium Complexes
Organometallics, 2010, 29, 957
4063434 CIFC28 H48 F3 Fe N2 O3 P3 SP -19.1821; 13.7066; 14.5326
97.486; 105.873; 102.504
1682.2Volpe, Emily C.; Wolczanski, Peter T.; Lobkovsky, Emil B.
Aryl-Containing Pyridine-Imine and Azaallyl Chelates of Iron toward Strong Field Coordination Compounds
Organometallics, 2010, 29, 364
4065801 CIFC28 H52 N2 O8 Se5 WP b c a12.903; 18.625; 31.683
90; 90; 90
7614Chiu, Wai-Hang; Zhang, Qian-Feng; Williams, Ian D.; Leung, Wa-Hung
Addition of Dimethyl Acetylenedicarboxylate to the [WSe4]2−Anion
Organometallics, 2010, 29, 2631
4065960 CIFC28 H56 N5 P Si3 ZrP 1 21/n 112.3884; 15.0561; 19.1663
90; 94.313; 90
3564.8Roering, Andrew J.; Leshinski, Sarah E.; Chan, Stephanie M.; Shalumova, Tamila; MacMillan, Samantha N.; Tanski, Joseph M.; Waterman, Rory
Insertion Reactions and Catalytic Hydrophosphination by Triamidoamine-Supported Zirconium Complexes
Organometallics, 2010, 29, 2557
4065555 CIFC28 H66 Ni2 P4C 1 2/c 110.7217; 15.767; 20.716
90; 91.007; 90
3501.5Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4065885 CIFC28 H66 P4 Rh2 S0.5P 1 21/n 110.059; 21.923; 16.31
90; 102.755; 90
3508Oster, Stephen S.; Grochowski, Matthew R.; Lachicotte, Rene J.; Brennessel, William W.; Jones, William D.
Carbon−Sulfur Bond Activation of Dibenzothiophenes and Phenoxythiin by [Rh(dippe)(μ-H)]2and [Rh2(dippe)2(μ-Cl)(μ-H)]†
Organometallics, 2010, 29, 4923
4066935 CIFC28 H80 Si12P 1 21/n 119.2212; 26.902; 19.271
90; 95.416; 90
9920.3Berkefeld, André; Troegel, Dennis; Burschka, Christian; Tacke, Reinhold
Synthesis and Characterization of {[Tris(trimethylsilyl)silyl]methyl}silanes of the Formula Type Me4−nSi[CH2Si(SiMe3)3]n(n= 1−3) and Derivatives
Organometallics, 2010, 29, 4548
4067730 CIFC28 H84 Si13P 1 21/n 19.7399; 31.897; 16.617
90; 94.52; 90
5146.4Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4067439 CIFC28.5 H32 Cl4 N P Pd RuP 21 21 218.791; 13.6179; 26.1332
90; 90; 90
3128.53Luo, Ding; Li, Yongxin; Pullarkat, Sumod A.; Cockle, Kirsty E.; Leung, Pak-Hing
Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions
Organometallics, 2010, 29, 893
4066000 CIFC28.5 H43 B Cl F6 N7 Os P2P c c n14.9919; 31.304; 14.8308
90; 90; 90
6960.2Castro-Rodrigo, Ruth; Esteruelas, Miguel A.; López, Ana M.; López, Fernando; Mascareñas, José L.; Mozo, Silvia; Oñate, Enrique; Saya, Lucía
Ring Expansion versusexo−endoIsomerization in (2-Pyridyl)methylenecyclobutane Coordinated to Hydrido(trispyrazolyl)borate- and Cyclopentadienyl-Osmium Complexes
Organometallics, 2010, 29, 2372
4066626 CIFC28.5 H77 B4 F16 N12 O1.5 Ru4P 1 21/n 111.9546; 21.077; 20.2021
90; 93.99; 90
5077.9Namura, Kyo; Kakuta, Satoshi; Suzuki, Hiroharu
Synthesis of Ruthenium Polyhydride Clusters with 1,4,7-Triazacyclononane-Type Ligands: Stereo and Electronic Effects of Ancillary Ligands
Organometallics, 2010, 29, 4305
4066295 CIFC29 H17 B F15 N OP n a 2117.4334; 10.6793; 14.4679
90; 90; 90
2693.6Birkmann, Birgit; Voss, Tanja; Geier, Stephen J.; Ullrich, Matthias; Kehr, Gerald; Erker, Gerhard; Stephan, Douglas W.
Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane†
Organometallics, 2010, 29, 5310
4066304 CIFC29 H17 B F15 N O2P 1 21/n 110.7712; 17.1693; 15.3473
90; 101.361; 90
2782.6Birkmann, Birgit; Voss, Tanja; Geier, Stephen J.; Ullrich, Matthias; Kehr, Gerald; Erker, Gerhard; Stephan, Douglas W.
Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane†
Organometallics, 2010, 29, 5310
4065641 CIFC29 H17 N O2P b c a9.5527; 18.179; 23.3617
90; 90; 90
4056.96McAdam, C. John; Robinson, Brian H.; Simpson, Jim; Tagg, Tei
Ferrocenyl−Naphthalimide Donor−Acceptor Dyads with Aromatic Spacer Groups
Organometallics, 2010, 29, 2474
4067135 CIFC29 H27 B Br Fe PP 1 21/c 120.7001; 7.2546; 17.2963
90; 107.297; 90
2479.94Schuecker, Raffael; Weissensteiner, Walter; Mereiter, Kurt; Lotz, Matthias; Spindler, Felix
Synthesis of Ferrocenyl Diphosphine Ligands: Substitution of α-Methoxy or α-Dimethylamino Groups by Phosphines. Retention versus Inversion: A Stereochemical Study
Organometallics, 2010, 29, 6443
4066940 CIFC29 H28 Br Ir N2P -110.1122; 11.188; 12.1894
101.66; 94.637; 116.052
1190.61Magriz, Antonio; Gómez-Bujedo, Silvia; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes
Organometallics, 2010, 29, 5941
4066937 CIFC29 H28 Br N2 RhP -110.0945; 11.196; 12.099
101.853; 94.531; 116.28
1177.21Magriz, Antonio; Gómez-Bujedo, Silvia; Álvarez, Eleuterio; Fernández, Rosario; Lassaletta, José M.
Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes
Organometallics, 2010, 29, 5941
4066528 CIFC29 H28 Cl2 O P2 PdP 1 21 110.865; 15.4156; 16.3015
90; 100.227; 90
2687Yuan, Mingjun; Pullarkat, Sumod A.; Li, Yongxin; Lee, Zhi-Yi; Leung, Pak-Hing
Novel Synthesis of Chiral 1,3-Diphosphines via Palladium Template Promoted Hydrophosphination and Functional Group Transformation Reactions
Organometallics, 2010, 29, 3582
4067556 CIFC29 H29 Cl2 Co N3C 1 2/c 137.761; 8.1979; 20.037
90; 121.87; 90
5268Zhang, Shu; Sun, Wen-Hua; Xiao, Tianpengfei; Hao, Xiang
Ferrous and Cobaltous Chlorides Bearing 2,8-Bis(imino)quinolines: Highly Active Catalysts for Ethylene Polymerization at High Temperature
Organometallics, 2010, 29, 1168
4067311 CIFC29 H31 B F4 N4 O2 Pd2P 6113.5487; 13.5487; 27.8944
90; 90; 120
4434.5Ficks, Arne; Sibbald, Connor; John, Michael; Dechert, Sebastian; Meyer, Franc
Dinuclear Allylpalladium Complexes ofC2-Symmetric Pyrazolate-Bridged Bis(oxazoline) Ligands (pyrbox's): Structures, Dynamic Behavior, and Application in Asymmetric Allylic Alkylation
Organometallics, 2010, 29, 1117
4067029 CIFC29 H32 Al2 N2P -111.9211; 12.4867; 18.489
91.419; 107.696; 101.049
2563.2Kingsley, Nicholas B.; Kirschbaum, Kristin; Mason, Mark R.
Confirmation of BridgingN-Indolides in 3-Methylindole and Di- and Tri(3-methylindolyl)methane Complexes of Dimethyl-, Diethyl-, and Diisobutylaluminum
Organometallics, 2010, 29, 5927
4067473 CIFC29 H32 B7 Fe N O4 P2P 1 21/c 117.3766; 10.7273; 19.2288
90; 114.023; 90
3273.9Franken, Andreas; McGrath, Thomas D.; Stone, F. Gordon A.
Toward Supramolecular Assembly of 10-Vertex {closo-2,1,10-FeC2B7} Clusters: Intramolecular Imidate Formation and Polymetallic, Polycluster Species
Organometallics, 2010, 29, 2234
4067438 CIFC29 H32 Cl6 N P Pd RuP 1 21 110.0546; 13.1269; 13.0716
90; 110.007; 90
1621.15Luo, Ding; Li, Yongxin; Pullarkat, Sumod A.; Cockle, Kirsty E.; Leung, Pak-Hing
Syntheses of Bimetallic Zwitterionic Complexes Containing Stereogenic Bifunctionalized Phosphine through Stepwise Insertion and Hydration Reactions
Organometallics, 2010, 29, 893
4065701 CIFC29 H32 Er NP 1 21/n 120.675; 10.789; 23.493
90; 112.187; 90
4852Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4065700 CIFC29 H32 N YP 1 21/n 120.75; 10.82; 23.573
90; 112.204; 90
4900Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4065702 CIFC29 H32 N YbP 1 21/n 120.688; 10.76; 23.461
90; 112.248; 90
4834Zhang, Zhengxing; Bu, Xiuli; Zhang, Jie; Liu, Ruiting; Zhou, Xigeng; Weng, Linhong
Insertion of Ketenimines into the Ln−C σ-Bond of Organolanthanides: A New Strategy for Synthesis of Lanthanide 1-Azaallyl Complexes
Organometallics, 2010, 29, 2111
4066122 CIFC29 H32 N2 O2 PdP 1 21/c 19.605; 30.963; 17.097
90; 96.724; 90
5050Chen, Ying; Mandal, Sukhendu; Sen, Ayusman
Synthesis of (N−O)-Ligated Palladium(II) Complexes and Their Use in Ethene Homopolymerization and Norbornene Copolymerizations
Organometallics, 2010, 29, 3160
4067058 CIFC29 H33 Cl Ir N O2P 1 21/c 116.747; 10.059; 16.216
90; 108.107; 90
2596.4Li, Ling; Jiao, Yunzhe; Brennessel, William W.; Jones, William D.
Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes
Organometallics, 2010, 29, 4593
4066703 CIFC29 H33 Cl N2 O2 SiP 1 21/c 112.2971; 18.4375; 11.5359
90; 95.673; 90
2602.7Tavčar, Gašper; Sen, Sakya S.; Roesky, Herbert W.; Hey, Jakob; Kratzert, Daniel; Stalke, Dietmar
Reactions of a Bis-silylene (LSi−SiL, L = PhC(NtBu)2) and a Heteroleptic Chloro Silylene (LSiCl) with Benzil: Formation of Bis(siladioxolene) and Monosiladioxolene Analogue with Five-Coordinate Silicon Atoms in Both Ring Systems
Organometallics, 2010, 29, 3930
4067185 CIFC29 H33 F6 P2 Rh SP 1 21/n 19.6976; 15.7258; 19.2429
90; 97.177; 90
2911.6Block, Michael; Kluge, Tim; Bette, Martin; Schmidt, Jürgen; Steinborn, Dirk
On the Reactivity of Rhodium(I) Complexes with κP-Coordinated γ-Phosphino-Functionalized Propyl Phenyl Sulfide Ligands: Routes to Cyclic Rhodium Complexes with κC,κP- and κP,κS-Coordinated Ligands as Well as Bis(diphenylphosphino)methanide Ligands
Organometallics, 2010, 29, 6749
4066942 CIFC29 H34 Cl Ir N2 O2P 1 21/n 111.379; 15.204; 15.915
90; 98.18; 90
2725.4Braun, Markus; Frank, Walter; Reiss, Guido J.; Ganter, Christian
An N-Heterocyclic Carbene Ligand with an Oxalamide Backbone
Organometallics, 2010, 29, 4418
4066218 CIFC29 H34 Cl N2 O4 P PdP 21 21 2110.1048; 11.6626; 24.207
90; 90; 90
2852.75Chen, Shuli; Ng, Joseph Kok-Peng; Pullarkat, Sumod A.; Liu, Fengli; Li, Yongxin; Leung, Pak-Hing
Asymmetric Synthesis of New Diphosphines and Pyridylphosphines via a Kinetic Resolution Process Promoted and Controlled by a Chiral Palladacycle
Organometallics, 2010, 29, 3374
4066058 CIFC29 H34 Cl N2 RhC 1 c 117.2031; 11.6106; 12.3438
90; 98.397; 90
2439.1Li, Jean; Stewart, Ian C.; Grubbs, Robert H.
Synthesis and Structure of Fused N-Heterocylic Carbenes and Their Rhodium Complexes.
Organometallics, 2010, 29, 3765-3768
4066902 CIFC29 H34 Cl2 P2 PtP c a 2119.1456; 8.5058; 16.9601
90; 90; 90
2761.9Lavery, Christopher B.; Ferguson, Michael J.; Stradiotto, Mark
Platinum-Catalyzed Alkene Cyclohydroamination: Evaluating the Utility of Bidentate P,N/P,P Ligation and Phosphine-Free Catalyst Systems
Organometallics, 2010, 29, 6125
4066118 CIFC29 H34 Cl2 Si2P b c a8.9277; 17.0219; 36.188
90; 90; 90
5499.4Spirk, Stefan; Belaj, Ferdinand; Albering, Jörg H.; Pietschnig, Rudolf
Formation of a Silylated 1-Silaallene via an Intermediate 1-Chloro-1-silaallene
Organometallics, 2010, 29, 2981
4065623 CIFC29 H34 Fe2 N2 O6 SeP 21 21 219.3836; 17.76; 18.128
90; 90; 90
3021.1Busetto, Luigi; Marchetti, Fabio; Renili, Filippo; Zacchini, Stefano; Zanotti, Valerio
Addition of Alkynes to Zwitterionic μ-Vinyliminium Diiron Complexes: New Selenophene (Thiophene) and Vinyl Chalcogenide Functionalized Bridging Ligands
Organometallics, 2010, 29, 1797
4066711 CIFC29 H34 O2 Si2 WC 1 c 125.249; 15.334; 17.601
90; 123.546; 90
5680Sakaba, Hiroyuki; Yabe-Yoshida, Mako; Oike, Hiroyuki; Kabuto, Chizuko
Conversion of an Acetylide−Silylene Complex to an Alkenylcarbyne Complex by Consecutive Ketone Addition and Base-Induced Silanone Elimination
Organometallics, 2010, 29, 4115
4066708 CIFC29 H35 F6 N4 P PdP 1 21/c 112.624; 23.917; 10.31
90; 90.61; 90
3112.7D’Amora, Angela; Fanfoni, Lidia; Cozzula, Daniela; Guidolin, Nicol; Zangrando, Ennio; Felluga, Fulvia; Gladiali, Serafino; Benedetti, Fabio; Milani, Barbara
Addressing the Poly- to Oligo-ketone Selectivity in Styrene Carbonylation Catalyzed by Palladium/bpy Complexes. Effect of the 6-Alkyl Substitution
Organometallics, 2010, 29, 4472
4067446 CIFC29 H35 Fe Mo2 O6 PP 1 21/c 110.267; 18.524; 15.1115
90; 91.566; 90
2872.92Alvarez, M. Angeles; García, M. Esther; Martínez, M. Eugenia; Ruiz, Miguel A.
Heterometallic Derivatives of the Unsaturated Methyl-Bridged Complex [Mo2(η5-C5H5)2(μ-CH3)(μ-PCy2)(CO)2]. Photochemical Generation of Methylidyne-Bridged Clusters
Organometallics, 2010, 29, 904
4066334 CIFC29 H35 Fe N O2 P2P -19.9909; 10.5284; 13.2106
92.11; 93.214; 103.366
1348.06Limburg, Carolin; Lönnecke, Peter; Gómez-Ruiz, Santiago; Hey-Hawkins, Evamarie
Synthesis of Racemic Aminoalkylferrocenyldichlorophosphanes and -dialkylphosphonites and Their Conversion to Primary Phosphanes†
Organometallics, 2010, 29, 5427
4063442 CIFC29 H36 Ag Cl9 N2C 1 2/c 121.232; 10.757; 16.9
90; 100.89; 90
3790.3Gaillard, Sylvain; Slawin, Alexandra M. Z.; Bonura, Allen T.; Stevens, Edwin D.; Nolan, Steven P.
Synthetic and Structural Studies of [AuCl3(NHC)] Complexes
Organometallics, 2010, 29, 394
4067566 CIFC29 H36 B Cl6 N8 O6 P S WP 1 21/c 115.4166; 15.7337; 18.6582
90; 96.957; 90
4492.41Zottig, Victor E.; Todd, Michael A.; Nichols-Nielander, Adam C.; Harrison, Daniel P.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Epoxidation, Cyclopropanation, and Electrophilic Addition Reactions at themetaPosition of Phenol andmeta-Cresol§
Organometallics, 2010, 29, 4793
4066877 CIFC29 H36 B Ir N6 O6P 1 21/c 115.025; 8.2245; 25.8801
90; 104.348; 90
3098.33Cristóbal, Crispín; García-Rubín, Silvia; Hernández, Yohar A.; López-Serrano, Joaquín; Paneque, Margarita; Posadas, Cristina M.; Poveda, Manuel L.; Rendón, Nuria; Álvarez, Eleuterio
Iridafurans by Coupling of Alkynes and Aldehydes on a TpMe2Ir System. Facile Demethoxycarbonylation of a β-CO2Me Substituent
Organometallics, 2010, 29, 5744
4066951 CIFC29 H36 Cu F6 N3 O4 S2C 1 2/c 116.188; 10.971; 19.954
90; 112.5; 90
3274Fortman, George C.; Slawin, Alexandra M. Z.; Nolan, Steven P.
A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)
Organometallics, 2010, 29, 3966
4066393 CIFC29 H36 F3 N5 O3 Pd SP -19.5963; 11.0135; 16.1259
70.3568; 76.7089; 67.2874
1470.81Warsink, Stefan; Drost, Ruben M.; Lutz, Martin; Spek, Anthony L.; Elsevier, Cornelis J.
Modular Synthesis of Bidentate Triazolyl-Functionalized N-Heterocyclic Carbenes and Their Palladium Complexes
Organometallics, 2010, 29, 3109
4067382 CIFC29 H36 N3 O P RuP 1 21/c 114.83; 9.657; 18.883
90; 99.623; 90
2666.2Gallagher, Michelle; Wieder, Noah L.; Dioumaev, Vladimir K.; Carroll, Patrick J.; Berry, Donald H.
Low-Valent Ruthenium Complexes of the Non-innocent 2,6-Bis(imino)pyridine Ligand
Organometallics, 2010, 29, 591
4065650 CIFC29 H36 N6 Ni O4C 1 2/c 115.4796; 18.1846; 10.6625
90; 104.303; 90
2908.36Jean-Baptiste dit Dominique, François; Gornitzka, Heinz; Hemmert, Catherine
Chiral Variation of a Hybrid Bis(carbene-amido) Ligand System
Organometallics, 2010, 29, 2868
4067335 CIFC29 H37 Cl Cr N2P 1 21/c 113.1109; 15.2995; 14.4144
90; 112.818; 90
2665.11Champouret, Yohan; MacLeod, K. Cory; Baisch, Ulrich; Patrick, Brian O.; Smith, Kevin M.; Poli, Rinaldo
Cyclopentadienyl Chromium β-Diketiminate Complexes: Initiators, Ligand Steric Effects, and Deactivation Processes in the Controlled Radical Polymerization of Vinyl Acetate
Organometallics, 2010, 29, 167
4065881 CIFC29 H37 Cl2 F3 Ir N3 O4 S2P 1 21 117.713; 15.819; 18.844
90; 105.997; 90
5076Ito, Masato; Endo, Yoshinori; Tejima, Noriko; Ikariya, Takao
Bifunctional Triflylamide-Tethered Cp′Rh and Cp′Ir Complexes: A New Entry for Asymmetric Hydrogenation Catalysts
Organometallics, 2010, 29, 2397
4065655 CIFC29 H37 Cl4 P2 PtP 1 21/c 125.8721; 14.8743; 17.4941
90; 100.803; 90
6612.9Fanjul, Tamara; Eastham, Graham; Fey, Natalie; Hamilton, Alex; Orpen, A. Guy; Pringle, Paul G.; Waugh, Mark
Palladium Complexes of the Heterodiphosphineo-C6H4(CH2PtBu2)(CH2PPh2) Are Highly Selective and Robust Catalysts for the Hydromethoxycarbonylation of Ethene
Organometallics, 2010, 29, 2292
4066953 CIFC29 H37 Cu N4P 1 21/c 112.073; 15.012; 15.983
90; 98.396; 90
2866Fortman, George C.; Slawin, Alexandra M. Z.; Nolan, Steven P.
A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)
Organometallics, 2010, 29, 3966
4067627 CIFC29 H38 B F3 N9 O4 P S WC 1 c 118.5656; 15.6461; 14.586
90; 126.103; 90
3423.27Salomon, Rebecca J.; Todd, Michael A.; Sabat, Michal; Myers, William H.; Harman, W. Dean
Single and Double Electrophilic Addition Reactions to the Aniline Ring Promoted by a Tungsten π-Base
Organometallics, 2010, 29, 707
4066689 CIFC29 H38 Br Cl2 F3 N2 O3 SP -110.3704; 11.644; 16.0199
89.195; 75.283; 63.576
1664.53Lin, Bo-Lin; Kang, Peng; Stack, T Daniel P
Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions.
Organometallics, 2010, 29, 3683-3685
4067006 CIFC29 H38 Cl N2 O4 RhP 1 21/m 18.407; 15.2225; 10.5861
90; 101.503; 90
1327.6Hudnall, Todd W.; Tennyson, Andrew G.; Bielawski, Christopher W.
A Seven-MemberedN,N′-Diamidocarbene
Organometallics, 2010, 29, 4569
4065652 CIFC29 H38 Cl4 P2 PtP 1 21 110.45; 14.957; 10.8664
90; 118.458; 90
1493.2Fanjul, Tamara; Eastham, Graham; Fey, Natalie; Hamilton, Alex; Orpen, A. Guy; Pringle, Paul G.; Waugh, Mark
Palladium Complexes of the Heterodiphosphineo-C6H4(CH2PtBu2)(CH2PPh2) Are Highly Selective and Robust Catalysts for the Hydromethoxycarbonylation of Ethene
Organometallics, 2010, 29, 2292
4067625 CIFC29 H38 Co N3 SiP 1 21/m 17.6802; 21.277; 8.5207
90; 99.1876; 90
1374.52Zhu, Di; Janssen, Femke F. B. J.; Budzelaar, Peter H. M.
(Py)2Co(CH2SiMe3)2As an Easily Accessible Source of “CoR2”
Organometallics, 2010, 29, 1897
4065653 CIFC29 H39 Cl P2 PdP 1 21/c 112.777; 12.854; 17.241
90; 105.25; 90
2731.9Fanjul, Tamara; Eastham, Graham; Fey, Natalie; Hamilton, Alex; Orpen, A. Guy; Pringle, Paul G.; Waugh, Mark
Palladium Complexes of the Heterodiphosphineo-C6H4(CH2PtBu2)(CH2PPh2) Are Highly Selective and Robust Catalysts for the Hydromethoxycarbonylation of Ethene
Organometallics, 2010, 29, 2292
4066368 CIFC29 H40 Cl Ir N2P 1 21/c 19.7109; 11.0074; 24.4849
90; 101.983; 90
2560.2Collins, Mary S.; Rosen, Evelyn L.; Lynch, Vincent M.; Bielawski, Christopher W.
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
Organometallics, 2010, 29, 3047
4066372 CIFC29 H40 Cl Ir N2 O2P b c a19.6592; 19.2293; 15.481
90; 90; 90
5852.3Collins, Mary S.; Rosen, Evelyn L.; Lynch, Vincent M.; Bielawski, Christopher W.
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
Organometallics, 2010, 29, 3047
4065723 CIFC29 H41 Cl2 N2 O2 Si0 YP b c a18.9721; 14.9681; 21.0475
90; 90; 90
5977Li, Danfeng; Li, Shihui; Cui, Dongmei; Zhang, Xuequan
β-Diketiminato Rare-Earth Metal Complexes. Structures, Catalysis, and Active Species for Highlycis-1,4-Selective Polymerization of Isoprene
Organometallics, 2010, 29, 2186
4065563 CIFC29 H41 N Ni P2P 1 21/c 110.4467; 15.224; 17.21
90; 94.607; 90
2728.2Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4065564 CIFC29 H41 N Ni P2P 1 21/c 110.4043; 16.1151; 17.189
90; 107.045; 90
2755.4Li, Ting; García, Juventino J.; Brennessel, William W.; Jones, William D.
C−CN Bond Activation of Aromatic Nitriles and Fluxionality of the η2-Arene Intermediates: Experimental and Theoretical Investigations
Organometallics, 2010, 29, 2430
4063496 CIFC29 H42 O Si2P -111.753; 11.987; 12.419
93.71; 107.894; 116.474
1448Chen, Jingjin; Liu, Yuanhong
Highly Stereoselective Synthesis of Trisubstituted cis-[3]Cumulenols from Alkynylated Oxatitanacycles in the Presence of Lewis acids
Organometallics, 2010, 29, 505-508
4067298 CIFC29 H44 N2 ZnP 1 21/c 113.4621; 12.1885; 17.359
90; 96.49; 90
2830.1Lennartson, Anders; Hedström, Anna; Håkansson, Mikael
Toward Total Spontaneous Resolution ofsec-Butylzinc Complexes
Organometallics, 2010, 29, 177
4066087 CIFC29 H45 Al2 N YC 1 2/c 127.0059; 12.8286; 17.3669
90; 101.484; 90
5896.3Litlabø, Rannveig; Enders, Markus; Törnroos, Karl W.; Anwander, Reiner
Bis(tetramethylaluminate) Complexes of Yttrium and Lanthanum Supported by a Quinolyl-Substituted Cyclopentadienyl Ligand: Synthesis and Performance in Isoprene Polymerization
Organometallics, 2010, 29, 2588
4065609 CIFC29 H45 N2 O Sc Si2P -19.5815; 11.3419; 16.1671
78.288; 73.593; 68.657
1559.9Liu, Dongtao; Luo, Yunjie; Gao, Wei; Cui, Dongmei
Stereoselective Polymerization of Styrene with Cationic Scandium Precursors Bearing Quinolyl Aniline Ligands
Organometallics, 2010, 29, 1916
4066446 CIFC29 H50 O Si5P 1 21/a 112.543; 17.317; 14.967
90; 99.651; 90
3205Ishida, Shintaro; Iwamoto, Takeaki; Kira, Mitsuo
Reactions of an Isolable Dialkylsilylene with Ketones†
Organometallics, 2010, 29, 5526
4066447 CIFC29 H50 O Si5P 1 21/c 117.796; 9.411; 20.505
90; 112.669; 90
3168.8Ishida, Shintaro; Iwamoto, Takeaki; Kira, Mitsuo
Reactions of an Isolable Dialkylsilylene with Ketones†
Organometallics, 2010, 29, 5526
4067227 CIFC29 H56 Ba N2 O5 Si2P 1 21/c 113.1638; 15.5426; 17.7016
90; 97.109; 90
3593.9Sarazin, Yann; Roşca, Dragoş; Poirier, Valentin; Roisnel, Thierry; Silvestru, Anca; Maron, Laurent; Carpentier, Jean-François
Bis(dimethylsilyl)amide Complexes of the Alkaline-Earth Metals Stabilized by β-Si−H Agostic Interactions: Synthesis, Characterization, and Catalytic Activity
Organometallics, 2010, 29, 6569
4067570 CIFC29 H56 P4 RuP -110.109; 13.5; 13.66
77.7; 72.79; 68.84
1648.8Field, Leslie D.; Magill, Alison M.; Shearer, Timothy K.; Colbran, Stephen B.; Lee, Sang T.; Dalgarno, Scott J.; Bhadbhade, Mohan M.
Controlled Synthesis of Dinuclear Acetylide-Bridged Ruthenium Complexes
Organometallics, 2010, 29, 957
4066285 CIFC29 H60 N4 O2 ZrP 1 21/c 113.7893; 15.7596; 15.9037
90; 107.176; 90
3301.96Leitch, David C.; Schafer, Laurel L.
Zirconium Alkyl Complexes Supported by Ureate Ligands: Synthesis, Characterization, and Precursors to Metal−Element Multiple Bonds†
Organometallics, 2010, 29, 5162
4067240 CIFC29 H60 N8 Zn4C 1 2/c 111.1432; 18.004; 17.722
90; 97.395; 90
3525.9Gutschank, Benjamin; Schulz, Stephan; Bläser, Dieter; Boese, Roland; Wölper, Christoph
Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex
Organometallics, 2010, 29, 6133
4067733 CIFC29 H75 K O6 Si9P 1 21/n 110.144; 21.284; 22.641
90; 96.56; 90
4856.3Wallner, Andreas; Hlina, Johann; Konopa, Tina; Wagner, Harald; Baumgartner, Judith; Marschner, Christoph; Flörke, Ulrich
Cyclic and Bicyclic Methylpolysilanes and Some Oligosilanylene-Bridged Derivatives
Organometallics, 2010, 29, 2660
4067318 CIFC29.5 H37 B Cl2 F4 N2 PtC 1 c 123.9715; 8.226; 30.7848
90; 99.703; 90
5983.6O, Wylie W. N.; Lough, Alan J.; Morris, Robert H.
Palladium(II) and Platinum(II) Complexes Featuring a Nitrile-Functionalized N-Heterocyclic Carbene Ligand
Organometallics, 2010, 29, 570
4067772 CIFC298 H274 O20 Si16C 1 2/m 126.089; 29.765; 20.783
90; 127.19; 90
12857Kawakami, Yoshiteru; Sakuma, Yoshinobu; Wakuda, Takashi; Nakai, Tatsuya; Shirasaka, Masayoshi; Kabe, Yoshio
Hydrogen-Bonding 3D Networks by Polyhedral Organosilanols: Selective Inclusion of Hydrocarbons in Open Frameworks
Organometallics, 2010, 29, 3281
4067528 CIFC3 H6 As4 O3P -17.3954; 11.4072; 11.5554
118.772; 90.38; 90.766
854.3Lu, Di; Rae, A. David; Salem, Geoff; Weir, Michelle L.; Willis, Anthony C.; Wild, S. Bruce
Arsenicin A, A Natural Polyarsenical: Synthesis and Crystal Structure
Organometallics, 2010, 29, 32
4067686 CIFC3 H6 Cl6 Si3P -16.269; 8.241; 12.869
73.79; 81.34; 80.18
625.329Hong, Soon Hyun; Hyun, Sang Il; Jung, Il Nam; Han, Won-Sik; Kim, Min-Hye; Yun, Hoseop; Nam, Suk-Woo; Kang, Sang Ook
Phosphine-Catalyzed Si−C Coupling of Bissilylmethanes: Preparation of Cyclic (Cl2SiCH2)2and Linear Cl2Si(CH2SiCl3)2via Silylene and Silene Intermediates
Organometallics, 2010, 29, 687
4066633 CIFC30 H20 N2 O2 RuP 1 21/c 114.857; 8.9139; 18.954
90; 112.26; 90
2323.1Chen, Dafa; Zhang, Xi; Xu, Shansheng; Song, Haibin; Wang, Baiquan
Pyridyl-Substituted Indenyl Ruthenium Complexes: Synthesis, Structures, and Reactivities
Organometallics, 2010, 29, 3418
4066054 CIFC30 H25 Cl F4 Ir PP 1 21/c 19.856; 12.286; 21.289
90; 100.966; 90
2530.8Stanek, Kyrill; Czarniecki, Barbara; Aardoom, Raphael; Rüegger, Heinz; Togni, Antonio
Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
Organometallics, 2010, 29, 2540
4066055 CIFC30 H25 Cl F4 P RhP 1 21/c 111.6216; 14.2972; 15.6137
90; 100.768; 90
2548.6Stanek, Kyrill; Czarniecki, Barbara; Aardoom, Raphael; Rüegger, Heinz; Togni, Antonio
Remote C−F−Metal Interactions in Late-Transition-Metal Complexes
Organometallics, 2010, 29, 2540
4066597 CIFC30 H26 N O2 P PdP c a 2128.719; 10.7837; 8.0015
90; 90; 90
2478Vicente, José; Chicote, María Teresa; Martínez-Martínez, Antonio Jesús; Abellán-López, Antonio; Bautista, Delia
Reactivity ofortho-β-Enaminone-phenyl Palladium Complexes. Insertion of CO into the Pd−C Bond to Give the First Acyl C,N,O-Pincer Complexes. Sequential Insertion of Dimethylacetylenedicarboxylate into the Enaminone C−H Bond and of Isocyanide into the Pd−C Bond. A New Photooxigenation/Cyclization Process†
Organometallics, 2010, 29, 5693
4065594 CIFC30 H26 O3 P RhP -18.9967; 15.7725; 19.3044
90.051; 94.536; 104.963
2637.49Hopmann, Kathrin H.; Stuurman, Nomampondomise F.; Muller, Alfred; Conradie, Jeanet
Substitution and Isomerization of Asymmetric β-Diketonato Rhodium(I) Complexes: A Crystallographic and Computational Study
Organometallics, 2010, 29, 2446
4066078 CIFC30 H27 Cu2 I2 N3 S3P -18.9141; 19.3304; 19.511
98.955; 102.73; 97.077
3195.8Han, Xiaoyan; Koh, Lip-Lin; Liu, Zhi-Pan; Weng, Zhiqiang; Hor, T. S. Andy
Must an N-Heterocyclic Carbene Be a Terminal Ligand?
Organometallics, 2010, 29, 2403

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