Information card for entry 1503368

Structure parameters

• Formula: C34 H56 Cl2 O2 Rh2
• Calculated formula: C34 H56 Cl2 O2 Rh2
• SMILES: [Rh]1234([Cl][Rh]567([Cl]1)[C]1(=[CH]5[C@@H]5[CH]6=[CH]7[C@H]1CC5)C(O)(CC(C)C)CC(C)C)[C]1([C@H]5[CH]2=[CH]3[C@@H]([CH]4=1)CC5)C(O)(CC(C)C)CC(C)C
• Title of publication: Catalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysis.
• Authors of publication: Brown, M. Kevin; Corey, E. J.
• Journal of publication: Organic letters
• Year of publication: 2010
• Journal volume: 12
• Journal issue: 1
• Pages of publication: 172 - 175
• a: 9.2436 ± 0.0017 Å
• b: 15.171 ± 0.003 Å
• c: 24.757 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3471.8 ± 1.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0529
• Residual factor for significantly intense reflections: 0.0413
• Weighted residual factors for significantly intense reflections: 0.0875
• Weighted residual factors for all reflections included in the refinement: 0.0935
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No