Information card for entry 1503941

Structure parameters

• Formula: C77 H42 Cl4 F24 O4 P4 Rh2
• Calculated formula: C77 H42 Cl4 F24 O4 P4 Rh2
• Title of publication: Electron-poor chiral diphosphine ligands: high performance for Rh-catalyzed asymmetric 1,4-addition of arylboronic acids at room temperature.
• Authors of publication: Korenaga, Toshinobu; Osaki, Kazutaka; Maenishi, Ryota; Sakai, Takashi
• Journal of publication: Organic letters
• Year of publication: 2009
• Journal volume: 11
• Journal issue: 11
• Pages of publication: 2325 - 2328
• a: 14.085 ± 0.002 Å
• b: 14.146 ± 0.002 Å
• c: 19.443 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3873.9 ± 1 ų
• Cell temperature: 120 K
• Ambient diffraction temperature: 120 K
• Number of distinct elements: 7
• Space group number: 18
• Hermann-Mauguin space group symbol: P 21 21 2
• Hall space group symbol: P 2 2ab
• Residual factor for all reflections: 0.1159
• Residual factor for significantly intense reflections: 0.0781
• Weighted residual factors for significantly intense reflections: 0.1951
• Weighted residual factors for all reflections included in the refinement: 0.211
• Goodness-of-fit parameter for all reflections included in the refinement: 1.13
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No