Information card for entry 1506775

Structure parameters

• Formula: C27 H60 O Si3
• Calculated formula: C27 H59 O Si3
• SMILES: [Si](O[Si](C)(C)C(C)(C)C)([C@H](C[SiH](C(C)(C)C)C(C)(C)C)C(=C)C)(C(C)(C)C)C(C)(C)C
• Title of publication: Metal-catalyzed rearrangement of homoallylic ethers to silylmethyl allylic silanes in the presence of a Di-tert-butylsilylene source.
• Authors of publication: Cleary, Pamela A.; Woerpel, K. A.
• Journal of publication: Organic letters
• Year of publication: 2005
• Journal volume: 7
• Journal issue: 24
• Pages of publication: 5531 - 5533
• a: 9.2671 ± 0.0013 Å
• b: 14.343 ± 0.002 Å
• c: 12.2312 ± 0.0017 Å
• α: 90°
• β: 95.604 ± 0.002°
• γ: 90°
• Cell volume: 1618 ± 0.4 ų
• Cell temperature: 163 ± 2 K
• Ambient diffraction temperature: 163 ± 2 K
• Number of distinct elements: 4
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.1215
• Residual factor for significantly intense reflections: 0.1043
• Weighted residual factors for significantly intense reflections: 0.2569
• Weighted residual factors for all reflections included in the refinement: 0.2778
• Goodness-of-fit parameter for all reflections included in the refinement: 1.094
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No