Information card for entry 1507357

Structure parameters

• Formula: C50 H46 Cl14 N2 O6 P2 Pt
• Calculated formula: C48 H44 Cl8 N2 O6 P2 Pt
• SMILES: [Pt]1(Cl)(Cl)[P]2(O[C@@H]([C@H](O[P]31[C@@H]1C(=C([C@H]3[C@H]3C(=O)N(C(=O)[C@@H]13)c1ccccc1)C)C)c1ccccc1)c1ccccc1)[C@@H]1C(=C([C@H]2[C@@H]2[C@H]1C(=O)N(C2=O)c1ccccc1)C)C.ClC(Cl)Cl.ClC(Cl)Cl
• Title of publication: Phosphinites derived from the 7-phosphanorbornene skeleton: first results in asymmetric catalysis.
• Authors of publication: Clochard, Magali; Mattmann, Eric; Mercier, François; Ricard, Louis; Mathey, François
• Journal of publication: Organic letters
• Year of publication: 2003
• Journal volume: 5
• Journal issue: 17
• Pages of publication: 3093 - 3094
• a: 15.186 ± 0.001 Å
• b: 13.755 ± 0.001 Å
• c: 16.028 ± 0.001 Å
• α: 90°
• β: 112.33 ± 0.001°
• γ: 90°
• Cell volume: 3096.9 ± 0.4 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 1 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0672
• Residual factor for significantly intense reflections: 0.0598
• Weighted residual factors for significantly intense reflections: 0.1583
• Weighted residual factors for all reflections included in the refinement: 0.1628
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No