Information card for entry 1508764

Structure parameters

• Formula: C34 H45 N O7 Si
• Calculated formula: C34 H45 N O7 Si
• SMILES: [Si](OC[C@H]1CC([C@@H](N2[C@H]([C@H](OC2=O)c2ccccc2)c2ccccc2)C(=C1)CC)(C(=O)OC)C(=O)OC)(C(C)(C)C)(C)C
• Title of publication: Asymmetric total synthesis of an iboga-type indole alkaloid, voacangalactone, newly isolated from Voacanga africana.
• Authors of publication: Harada, Masaya; Asaba, Ken Nunettsu; Iwai, Masumi; Kogure, Noriyuki; Kitajima, Mariko; Takayama, Hiromitsu
• Journal of publication: Organic letters
• Year of publication: 2012
• Journal volume: 14
• Journal issue: 22
• Pages of publication: 5800 - 5803
• a: 25.936 ± 0.01 Å
• b: 11.367 ± 0.004 Å
• c: 12.416 ± 0.005 Å
• α: 90°
• β: 112.285 ± 0.005°
• γ: 90°
• Cell volume: 3387 ± 2 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 5
• Space group number: 5
• Hermann-Mauguin space group symbol: C 1 2 1
• Hall space group symbol: C 2y
• Residual factor for all reflections: 0.3213
• Residual factor for significantly intense reflections: 0.0879
• Weighted residual factors for significantly intense reflections: 0.1731
• Weighted residual factors for all reflections included in the refinement: 0.301
• Goodness-of-fit parameter for all reflections included in the refinement: 0.904
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No