Information card for entry 1518337

Structure parameters

• Formula: C75 H60 B Cl3 F24 Ir2 N2
• Calculated formula: C75 H60 B Cl3 F24 Ir2 N2
• Title of publication: Efficient hydrosilylation of imines using catalysts based on iridium(iii) metallacycles
• Authors of publication: Corre, Y.; Iali, W.; Hamdaoui, M.; Trivelli, X.; Djukic, J.-P.; Agbossou-Niedercorn, F.; Michon, C.
• Journal of publication: Catal. Sci. Technol.
• Year of publication: 2015
• Journal volume: 5
• Journal issue: 3
• Pages of publication: 1452
• a: 19.0059 ± 0.0005 Å
• b: 21.9914 ± 0.0005 Å
• c: 22.092 ± 0.0007 Å
• α: 114.003 ± 0.001°
• β: 107.666 ± 0.001°
• γ: 99.412 ± 0.002°
• Cell volume: 7588 ± 0.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1925
• Residual factor for significantly intense reflections: 0.0985
• Weighted residual factors for significantly intense reflections: 0.2244
• Weighted residual factors for all reflections included in the refinement: 0.2624
• Goodness-of-fit parameter for all reflections included in the refinement: 1.001
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No