Information card for entry 1518667

Structure parameters

• Chemical name: [(Me3P)3(nacnac)Sb4][OTf]3
• Formula: C43 H71 F9 N3 O9 P3 S3 Sb4
• Calculated formula: C43 H71 F9 N3 O9 P3 S3 Sb4
• SMILES: [Sb]1([Sb]([Sb]([Sb]1[P+](C)(C)C)[P+](C)(C)C)[P+](C)(C)C)C(/C(=N/c1c(cccc1C(C)C)C(C)C)C)C(=N\c1c(cccc1C(C)C)C(C)C)\C.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F.N#CC
• Title of publication: Synthesis and reactivity of cyclo-tetra(stibinophosphonium) tetracations: redox and coordination chemistry of phosphine‒antimony complexes
• Authors of publication: Chitnis, Saurabh S.; Robertson, Alasdair P. M.; Burford, Neil; Weigand, Jan J.; Fischer, Roland
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 4
• Pages of publication: 2559
• a: 11.4789 ± 0.0003 Å
• b: 11.9874 ± 0.0003 Å
• c: 26.0864 ± 0.0007 Å
• α: 91.82 ± 0.001°
• β: 97.564 ± 0.001°
• γ: 112.074 ± 0.001°
• Cell volume: 3284.57 ± 0.15 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 99.99 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0565
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for significantly intense reflections: 0.1047
• Weighted residual factors for all reflections included in the refinement: 0.1174
• Goodness-of-fit parameter for all reflections included in the refinement: 1.173
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No