Information card for entry 1521288

Structure parameters

• Chemical name: mu-carbido-[(2,2':6',2''-terpyridine)silver(I)-dichlorobis(tricyclohexylphosphine)ruthenium(VI)]triflate
• Formula: C55 H79 Ag Cl8 F3 N3 O3 P2 Ru S
• Calculated formula: C55 H79 Ag Cl8 F3 N3 O3 P2 Ru S
• SMILES: [Ru](Cl)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)(Cl)#C[Ag]12[n]3c(c4[n]1c(ccc4)c1[n]2cccc1)cccc3.ClC(Cl)Cl.S(=O)(=O)(C(F)(F)F)[O-].ClC(Cl)Cl
• Title of publication: Carbide complexes as π-acceptor ligands
• Authors of publication: Reinholdt, Anders; Vibenholt, Johan E.; Morsing, Thorbjørn J.; Schau-Magnussen, Magnus; Reeler, Nini E. A.; Bendix, Jesper
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 10
• Pages of publication: 5815
• a: 14.248 ± 0.0009 Å
• b: 15.814 ± 0.0018 Å
• c: 16.607 ± 0.0018 Å
• α: 70.503 ± 0.009°
• β: 74.933 ± 0.005°
• γ: 68.534 ± 0.009°
• Cell volume: 3241.9 ± 0.6 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 10
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0921
• Residual factor for significantly intense reflections: 0.0605
• Weighted residual factors for significantly intense reflections: 0.1373
• Weighted residual factors for all reflections included in the refinement: 0.1571
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No