Information card for entry 1529326

Structure parameters

• Formula: C44.67 H56.5 As F9 N6.83 O9 S3
• Calculated formula: C44.6667 H56.5 As F9 N6.83333 O9 S3
• Title of publication: Bipyridine complexes of E3+(E = P, As, Sb, Bi): strong Lewis acids, sources of E(OTf)3and synthons for EIand EVcations
• Authors of publication: Chitnis, Saurabh S.; Robertson, Alasdair P. M.; Burford, Neil; Patrick, Brian O.; McDonald, Robert; Ferguson, Michael J.
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 11
• Pages of publication: 6545
• a: 15.0217 ± 0.0006 Å
• b: 18.4434 ± 0.0008 Å
• c: 31.1243 ± 0.0013 Å
• α: 93.909 ± 0.0006°
• β: 101.339 ± 0.0006°
• γ: 99.3536 ± 0.0006°
• Cell volume: 8297.5 ± 0.6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0734
• Residual factor for significantly intense reflections: 0.0451
• Weighted residual factors for significantly intense reflections: 0.1061
• Weighted residual factors for all reflections included in the refinement: 0.1208
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No