Information card for entry 1531937

Structure parameters

• Chemical name: [(Et2O)TlPd(CNArDipp2]BArF
• Formula: C98 H96 B F24 N2 O Pd Tl
• Calculated formula: C98 H96 B F24 N2 O Pd Tl
• Title of publication: Metal-only Lewis pairs between group 10 metals and Tl(i) or Ag(i): insights into the electronic consequences of Z-type ligand binding
• Authors of publication: Barnett, Brandon R.; Moore, Curtis E.; Chandrasekaran, Perumalreddy; Sproules, Stephen; Rheingold, Arnold L.; DeBeer, Serena; Figueroa, Joshua S.
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 12
• Pages of publication: 7169
• a: 12.7422 ± 0.0009 Å
• b: 26.6786 ± 0.0018 Å
• c: 28.5026 ± 0.0019 Å
• α: 99.098 ± 0.001°
• β: 90.144 ± 0.001°
• γ: 90.509 ± 0.001°
• Cell volume: 9566.9 ± 1.1 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.079
• Residual factor for significantly intense reflections: 0.0454
• Weighted residual factors for significantly intense reflections: 0.0803
• Weighted residual factors for all reflections included in the refinement: 0.0887
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No