Information card for entry 1532477

Structure parameters

• Formula: C52 H68 N Si Sn
• Calculated formula: C52 H68 N Si Sn
• Title of publication: Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
• Authors of publication: Hadlington, Terrance J.; Hermann, Markus; Frenking, Gernot; Jones, Cameron
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 12
• Pages of publication: 7249
• a: 10.2591 ± 0.0009 Å
• b: 13.6505 ± 0.001 Å
• c: 17.3164 ± 0.0015 Å
• α: 99.111 ± 0.007°
• β: 105.293 ± 0.008°
• γ: 95.189 ± 0.007°
• Cell volume: 2287.3 ± 0.3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1164
• Residual factor for significantly intense reflections: 0.0668
• Weighted residual factors for significantly intense reflections: 0.1044
• Weighted residual factors for all reflections included in the refinement: 0.1259
• Goodness-of-fit parameter for all reflections included in the refinement: 0.963
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No