Information card for entry 1532484

Structure parameters

• Formula: C53 H70 N2 O Si Sn
• Calculated formula: C53 H70 N2 O Si Sn
• SMILES: [Sn](ON1C(CCCC1(C)C)(C)C)N([Si](C(C)C)(C(C)C)C(C)C)c1c(cc(cc1C(c1ccccc1)c1ccccc1)C(C)C)C(c1ccccc1)c1ccccc1
• Title of publication: Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
• Authors of publication: Hadlington, Terrance J.; Hermann, Markus; Frenking, Gernot; Jones, Cameron
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 12
• Pages of publication: 7249
• a: 14.604 ± 0.003 Å
• b: 15.84 ± 0.003 Å
• c: 20.773 ± 0.004 Å
• α: 88.61 ± 0.03°
• β: 82.84 ± 0.03°
• γ: 84.99 ± 0.03°
• Cell volume: 4749.2 ± 1.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0377
• Residual factor for significantly intense reflections: 0.034
• Weighted residual factors for significantly intense reflections: 0.0857
• Weighted residual factors for all reflections included in the refinement: 0.0877
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation wavelength: 0.7109 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No